Reao 3H2 + N2 2NH3 Equaes No estado padro

G 0 = - RT ln(Ke 0 )
n

DG = n iGf i0 = n A Gf A0 +n B Gf B0 +n C GfC0
0 i=1 n

DH = n i Hf i0 = n A Hf A0 +n B Hf B0 +n C Hf C0
0 R i=1

Assumindo modelo ideal para a fase gasosa

n n n n Ke = f i i Pi i i=1 i=1
0 n n n n Ke 0 = [f n A .f n B .f CC ][ PA A PB B PC C ] A B

Gs ideal

A = f B = f C = 1
n n n K e0 = PA A PB B PC C

As presses parciais
0 PA = P.y A 0 PB = P.y B 0 PC = P.yC

Balano de massa da reao

Entra Reage Sai

H2 (A) N A0
0 N A 0 .x A 0 0 N A = N A 0 (1 - x A 0 ) 1

N2 (B) N B0
3 0 N A0 x A0 1 3 0 N A0 x A0

NH3 0 2 N x0 3 A0 A0
0 NC = 2 3 N A 0 x A 0

N B = N B0 -