www.wunan.com.

tw
(02)2705-5066

 www.wunan.com.tw
(02)2705-5066

\
()()
()()()
()(1)
(2)(3)(4)(5)
(6)(7)(8)X(9)
(1)(2)
(1)(2)(3)
(4)(5)(6)
(1)(2)
(3)(1)
(2)(1)
(2)(3)(4)

www.wunan.com.tw
(02)2705-5066

1-1

1-2

1-2-1

1-2-2

1-3AD

10

1-4

10

1-5

11

1-6

18

21

2-1

21

2-2

25

2-2-1

25

2-2-2

27

2-2-3

28

2-2-4

29

2-2-5

30

2-2-6

32

2-2-7

33

2-2-8

34

2-3

www.wunan.com.tw
(02)2705-5066

36

3-1

43
43

3-1-1

44

3-1-2

48

3-1-3

51

3-2

54

3-2-1

54

3-2-2

58

3-2-3

59

3-2-4

64

3-2-5

68

3-3

71

3-3-1

71

3-3-2

73

3-3-3

74

3-3-4NO2/CH3OH

75

3-3-5-Job method

77

81

4-1

81

4-1-1

82

4-1-2Vibrational Energy/Frequency

83

4-2

86

4-2-1

87

4-2-2

88

4-2-3Sample Cell

89

4-2-4

90

4-3

www.wunan.com.tw
(02)2705-5066

93

4-3-1

93

4-3-2CONDIR

95

4-4

99

101

5-1

101

5-2

104

5-3

105

5-4FT-Raman

109

5-5

110

115

6-1

116

6-2

120

6-3Quantum yield

122

6-4

125

6-5

129

6-6

131

135

7-1

135

7-2

144

7-2-1

144

7-2-2

145

7-2-3

148

7-2-4

151

www.wunan.com.tw
(02)2705-5066

7-2-5

155

7-2-6

159

7-3

162

7-3-1

163

7-3-2

164

7-3-3

166

7-3-4

167

7-3-5

168

7-3-6

170

7-4

171

7-5

174

175

8-1

175

8-2FTNMR

180

8-3

184

8-4

191

8-5

195

8-6

198

8-6-1

199

8-6-2

200

8-7

201

8-8

204

209

9-1

209

9-2

212

9-3

215

www.wunan.com.tw
(02)2705-5066

219

10-1XX

220

10-1-1X

221

10-1-2X

224

10-1-3X

230

10-2X

232

10-3XXRF

237

10-4X

240

10-5X

246

249

11-1

250

11-2

253

11-2-1

253

11-2-2

255

11-2-3

257

11-2-4ESI/TSI

259

11-2-5LaserMALDI

261

11-2-6TI

263

11-2-7Ion sourceSIMS

264

11-2-8FAB

266

11-2-9

267

11-2-10

269

11-3

270

11-4

272

11-4-1

272

11-4-2

274

11-4-3

275

www.wunan.com.tw
(02)2705-5066

11-4-4TOF

279

11-4-5

280

11-4-6FTMS

282

11-5

284

11-6

287

11-7

291

299

12-1

300

12-1-1

300

12-1-2

304

12-2

305

12-2-1

305

12-2-2HETPN

308

12-2-3R

311

12-3Van Deemter equation

313

12-4Snyder equation

317

319

13-1

320

13-2

324

13-2-1TCD

325

13-2-2FIDAFI

326

13-2-3ECD

328

13-2-4FPD

329

13-2-5

330

www.wunan.com.tw
(02)2705-5066

13-3Kovats Index

331

13-4

333

13-5

334

13-6

335

14-1HPLC

339
339

14-1-1HPLC

340

14-1-2

342

14-1-3HPLC

343

14-1-4HPLCLC/MS

346

14-2

351

14-3

356

14-4GPC

361

14-5FIA

367

14-6High Performance TLC

368

14-7

371

14-7-1

371

14-7-2

372

14-7-3

373

14-8

375

() 381
15-1

382

15-1-1ANDNANDORNORNOT

382

15-1-2EOR or XORENOR or XNOR

386

www.wunan.com.tw
(02)2705-5066

15-1-3
15-2

388
390

15-2-1

390

15-2-2OPA

393

15-3

401

15-3-1DAC

401

15-3-2ADC

404

15-3-3

410

()
16-1

413
414

16-1-1PPI 8255/8155

414

16-1-2PIA 6821

417

16-1-3

420

16-1-4

422

16-2

425

16-2-1

425

16-2-2

428

16-3

430

16-3-1MCS-4851

432

16-3-2PIC-16C7x16F8x

434

16-3-3

436

16-3-4

438

16-4

439

16-4-1RS232

440

16-4-2IEEE488

442

www.wunan.com.tw
(02)2705-5066

()
17-1

443
443

17-1-1

444

17-1-2

447

17-1-3

449

17-2

450

17-2-1

450

17-2-2

453

17-2-3

458

17-3

462

17-4

465

17-5RC/LR

467

17-5-1RC

468

17-5-2LR

476

17-6

479

17-6-1S/N

479

17-6-2

481

17-6-3

483

18-1

489
489

18-1-1

490

18-1-2

492

18-1-3

494

18-2

495

18-2-1

495

www.wunan.com.tw
(02)2705-5066

10

18-2-2Nernst Equation

496

18-2-3

499

18-3

501

18-3-1

502

18-3-2pH

503

18-3-3

514

18-3-4

516

18-4

519

18-5KspKaKf

522

525

19-1

526

19-2

527

19-2-1

528

19-2-2

532

19-2-3

533

19-2-4

534

19-3CV

535

19-4

538

19-5

540

19-5-1Voltammetric O2 Electrode

540

19-5-2

542

19-5-3

544

19-5-4

545

19-6

20-1

www.wunan.com.tw
(02)2705-5066

548

551
551

11

20-2

555

20-3

556

20-3-1

557

20-3-2

558

20-3-3

559

20-3-4

560

20-4

562

20-4-1

562

20-4-2

565

20-4-3

566

21.1

571
572

21-1-1

572

21-1-2

574

21-1-3

576

21-1-4

579

21-1-5

581

21-2SEM

583

21-3TEM

586

21-4ESCAXXPS

589

21-5AES

597

21-6EPMAXEE-EDS
603
21-7

608

21-8EELS

612

www.wunan.com.tw
(02)2705-5066

12

617

22-1

618

22-2

622

22-2-1STM

622

22-2-2AFM

626

22-2-3CFM/FFM
C-SFM

632

22-3NC-SFMMFM/
EFM

635

22-4SNFM

637

22-5

643

22-5-1FIM

643

22-5-2HIM

644

22-5-3FIB

646

22-5-4RBS

649

655

23-1

656

23-2

661

23-3

666

23-4

673

23-4-1NAA

674

23-4-2

676

23-5

678

23-5-1

678

23-5-2

680

www.wunan.com.tw
(02)2705-5066

13

23-5-3

683

23-6

685

23-6-1

685

23-6-2Co-60P-32/Y-90/I-131

692

24-1

697
698

24-1-1CO

699

24-1-2

702

24-1-3SO2

709

24-1-4CO2

713

24-1-5

715

24-1-6

723

24-2

724

24-2-1

724

24-2-2

732

24-3PCB

736

24-4

738

741

25-1

742

25-2PZ

743

25-3SAW

751

25-4

759

25-5

763

25-6-ATRSPR

766

25-6-1ATR

766

25-6-2SPR

768

www.wunan.com.tw
(02)2705-5066

14

25-7

771

25-8

774

26-1

781
782

26-1-1MEMS

782

26-1-2LOC

783

26-1-3MEMS Technique

784

26-1-4NEMS

786

26-2

787

26-2-1

787

26-2-2

788

26-2-3

792

26-3

794

26-4

800

26-4-1

801

26-4-2

804

26-4-3

807

26-4-4

809

26-5

811

26-5-1

811

26-5-2

813

26-5-3

814

26-5-4-GC Chip

815

26-6

816

26-6-1

816

26-6-2

818

26-6-3

821

26-6-4

823

www.wunan.com.tw
(02)2705-5066

15

825

27-1TGA

826

27-2DTA

829

27-3DSC

830

835

869

www.wunan.com.tw
(02)2705-5066

www.wunan.com.tw
(02)2705-5066

 www.wunan.com.tw
(02)2705-5066

A . S c h o p e n h a u e r, 1 7 8 8 - 1 8 6 0

1-1
Analytical instruments

www.wunan.com.tw
(02)2705-5066

1-2

D a t a D o m a i n s [1-2]

Tr a n s d u c e r

1 - 2 - 1 [1-2]

1-1

T1

PMT

Data Domain, D2
Data Domain, D1

T2

Data Domain, D3

1-1

1 - 1 D 1
D 2 D 3

Tr a n s d u c e r
1 - 1 T 1 D 1
D 2 P h o t o m u l t i p l i e r t u b e

www.wunan.com.tw
(02)2705-5066

E n e rg y Tr a n s d u c e r s
Tr a n s d u c e r s

D 2 D 3 T 2
T 1 T 2

Non-electricElectric
[2] 1 - 2 D o m a i n m a p

Non-Electric Domains

v
i
A
Analog

Binary
(1
Signa, 0)
ls

C-14

pulse wave wave

Electric Domains

D
(Digital)
T(Time)
q

1-2[2]

H +

ivq
fPulse, p1, 0Binary signals
-14Decay
Digital
Signal, DAnalog Signal, A
10-14

1.1, 1.2, 1.3

Ti m e

www.wunan.com.tw
(02)2705-5066

domain, T

1 - 2 1 - 1 D 1
D 2 D 3
Tr a n s d u c e r

1-2-2
Trans ducers
(1)(2)
(3)

Recognition Module

1-3PMT
Ag-CsAgAg*CsCs
DynodeAg-Cs

Recognition element
Thermocouple1-4a
N i , C r 1 - 4 a Tr
T Vo Vo

A ( T - Tr )

A S e n s i t i v i t y Vo T
Vcc1-4b

StarterAu
Au-PbAu-Pb
4-2-4

www.wunan.com.tw
(02)2705-5066

7
PMT(Photomultiplier Tube)
Dynode

3e-

h
eAg-Cs
(1) + AgAg*
(2)Ag* + CsCs* + Ag
(3)Cs*Cs+ + e-

ne-

106e-
1-3Photo-multiplier tube, PMT
Thermocouple

Vo
Ni

Cr

Ni

Vcc

Cr

Ni

Ni
gas

Tr

Vo = A(T - Tr)

TC

TH

(b)
(a)
1-4Thermocouple(a)(b)Starter

Oxygen
electrode1-5
O 2 O 2-
1-5aI1-5b
Biologic
Oxygen Demand, BOD

www.wunan.com.tw
(02)2705-5066

Oxygen (O2) ElectrodeO2

I

Pt
tip

O2

O2-

Pt

e-

Ag/AgCl

O2 + e-

%O2
(b)

(a)

1-5Oxygen (O 2) electrode(a)(b)
O2 %

Current meter1-6

Currnet meteri

coil

(1)Torque = iwB
(2) = ki
Angular Deection
kiB
w

1-6Current meter

= 0.5iwB
1-1a
wB
= Ki

1-1b

www.wunan.com.tw
(02)2705-5066

Q u a r t z C r y s t a l M i c r o b a l a n c e , Q C M [ 3 ]
< g
Piezoelectric crystal1-7a

1 - 7 b V 1
Ultrasonic wavef

4-20 MHz1-7c
f
[4] Q C M

P L Z T P b , L a , Z r, Ti O x L i Ta O 3

+
ee+
V1
-
+

f
(a)

(b)

(c)

1-7(a)(b)(c)

www.wunan.com.tw
(02)2705-5066

10

1-3AD
Analog
signalDigital signal1(5 V)
0(0 V)Analog signal
ADC, Analog to Digital Converter1-8
V 1 D 0 D 7 8 2 5 5
ICSignal acquisitionData
processing
DAC, Digital to Analog Converter1-8
D 0 D 7 Vo

Vo

D
DAC

D
V1
ADC

D7

D7

CPU

1-8AD

1-4
1-9

Recognition ModuleRecognition
elementPMTAg-CsPt

www.wunan.com.tw
(02)2705-5066

11

O 2

Analog Signal

converter

Transducer
ADC

Digital Signal

DAC

CPU

1-9

Amplifier
ADC

D i g i t a l t o A n a l o g c o n v e r t e r, D A C

1 - 5 [5-8]
M i c r o c o m p u t e r, C
1-10
Central processing Unit, CPU
Arithmetic logic unit, ALUControl
unit, CU
CPUIC
M i c r o p r o c e s s o r 1 - 11 Z - 8 0

www.wunan.com.tw
(02)2705-5066

12

8CPU
1-12AZ-801-12BIntel64
Pentium 4-CPU
Microcomputer
Contriol

CU

Arithmetic
Logic Unit (ALU)
Input(I)

Memory

Output(O)

CPU (Central processing Unit, CU + ALU)

(1)CPUCentral Processing Unit
(2)Buses
Control BusesINT, W, R
Data BusesD D1 D2D3
Address BusesA A1A3
(3)Memory
ROM (Read Only Memory)
EPROM (Erasable programming ROM)
EEPROM (Electric EPROM)
RAM (Random Access Memory)
(4)IC (Logic gates, Decoders, Registers)
IC
(5)I/O (Input/Output)
RS 232, IEEE 488
(6)ADC/DAC, PPI 8255
(7)Program
(software)
1-10

Memory
RAMRandom access memoryROMRead only memory
RAM
1 - 11 6 11 6
RAMROM
ROMROM

www.wunan.com.tw
(02)2705-5066

13

5V

Vcc
D D

5V

Vcc

P
4 MHz

D7 D7
AA

Z-80

410 MHz

Vcc
D D

M
2764

W
R
INT
RESTT

A12
A13
A14
A15

A11A11

CS

PA
I/O

A
M

D7 D7
AA

6116 A
A1

Pentium-4

Vcc
DD

A11A11

D7 D7

2
A
A1

Port A(I/O)
PA7
PB

5
5

Port B(I/O)
PB7
PC

CS

Decorder

Keyboard

CS

PC7

1-11

ROM
ROMEPROMErasable Programming
ROMEPROMUV
EPROMEEPROMElectric
E P R O M 1 - 11 2 7 6 4 1 - 1 2 C E P R O M

EPROM

2764

(a)

(b)

(c)

1-12(A)CPUZ80 [9] (B)Intel Pentium 4

CPU [10] (C)EPROM-2764AB(A)From Wikipedia,
the free encyclopedia, http://upload. wikimedia.org/wikipedia/commons/1/19/
Zilog_Z80.jpg(B)From Wikipedia, the free encyclopediahttp://upload.
wikimedia.org/wikipedia/en/thumb/3/34/Pentium4ds.jpg/200px-Pentium4ds.
jpg

www.wunan.com.tw
(02)2705-5066

14

CPU

Buses(1)
Control buses(2)Data buses(3)
Address buses
1 - 11 C P U W, R , I N T R E S E T C P U
WriteReadInterruptReset
1 - 11 C P U D 0 D 7
8, 16, 24, 32, 48, 6448
488D 0 D 7 8
8Byte8 = 1 Byte8D 0 D 7
120Data1-13
12020D 0 0D 2
D = 120Binary0111 10008D 0 D 7
105 V0 V1 = 5 V0 = 0 V
D7D6 D5D4D3D2D1D
27 26 2524 23 22 21 20
0 1 1 1 1 0 0 0120 =
0 64 + 32 + 16 + 8 + 0 0 0120
2 120
2 60 0D
2 30 0D1
2 15 0D2
2 4 1D3
2 3 1D4
2 1 1D5
0 1D6
0D7
1-13120

Address buses
CPUCPU

www.wunan.com.tw
(02)2705-5066

15

ROMRAM320
1-1401 0100 0000A9A0
105 V0 V
16A0-A154864
D9D8D7D6 D5D4D3D2D1D
29 28 27 26 2524 23 22 21 20
0 1 0 1 0 0 0 0 0 0320
256+64
320
2 320
2 160 0A
2 80 0A1
2 40 0A2
2 20 0A3
2 10 0A4
2 5 0A5
2 2 1A6
2 1 0A7
0 1A8
0A9
1-14320

Output/Input, I/ORS232IEEE488
D0D7SerialD0D1
ParallelD0-D7
DDigitalAAnalog
I/OADCAD
1-15AADC0804
DAC1-15B
DAC1408
I/OIC82551-11
IC68212-3Ports
PortI/O

www.wunan.com.tw
(02)2705-5066

16

ADC0804

(a)

DAC1408

(b)

1-15(A)ADC-0804(B)DAC-1408

1 - 11
ICLogic gatesRegisters
Decoders8255
0 1 - 11 8 2 5 5 C S C h i p
selector1-114-10
MHzOscillatorHardware
Software

One-Chip Microcomputer
CPU, ROM, RAM, Data Bus, Address Bus, Control BusInput/
OutputADC

1-161-178951
PIC16F8778951Port 0Port 3
TX/RXEEPROMRAM16F877
Port APort ETX/RX
EEPROMRAM8ADCAD0AD7
895116F877
Assembly LanguageBinary
Wr i t e r R e a d

www.wunan.com.tw
(02)2705-5066

17

89C51

P1.0 1
2
3
4
Port 1
5
6
7
8
P1.7
9 MCS 8951
RST
P3.0 10 (RX)
11 (TX)
12
13
Port 3
14
15
16
17
P3.7
18
19
Vss

20

Vcc
40
P0.0/AD0
39
38
37
36
Port
35
34
33
32
P0.7/AD7
31
EA
30
ALE
29
PSEN
28 P2.7/A15
27
26
25
Port2
24
23
22
21
P2.7/A8

AD/RA
Port A

16F877

AD3/RA3
RA4
AD4/RA5
Port E AD5/RE0
(E0-E2) AD6/RE1
AD7/RE2
VDD
VSS

Port C
(CC3)
Port D
(DD1)

RC
RC3
RD
RD1

1
2
3
4
5
6
7
8 PIC 16F877
9
10
11
12
13
14
(RX)
15
(TX)
16
17
18
19
20

40 RB7
39
38
37
36
35
34
33
RB
32
VDD
31
30
29
28
27
26
25
24
23
22
21

VSS
RD7
RD4
RC7
RC4
RD3
RD2

1-17MC-PIC16F877

www.wunan.com.tw
(02)2705-5066

Port D Port C Port D

(D2-D3)(C4-C7) (D4-D7)

AD
Vpp

Port B

1-16MC8951

18

1-6
Data bus, D0-D7
Address bus, A15-A010
Binary1-18
2 0 1 1 - 1 8 ( A ) 1 - 1 3 2 0 1 11 0 0
10011-18(B)

Hex1-18(C)
( 1 ) 11 0 0 1 0 0 1
1 0 I I I 2 3 2 2 2 1 2 0
I I 1 6 1 11 0 0 2 3 + 2 2
= 1 2 1 0 A = 1 0 B = 11 C = 1 2 D = 1 3 E = 1 4 F = 1 5
1 6 1 C = 1 2 C I
1 6 0 1 0 0 1 2 3 + 2 0 = 9 1 6 0
9 11 0 0 1 0 0 1 C 9 C
1 6 1 9 1 6 0 D = 1 2 1 6 1 + 9 1 6 0 = 2 0 1
1-18(D)
2 0 1 1 6 1 6 0 9
1 6 1 1 2 1 2 C C 9

www.wunan.com.tw
(02)2705-5066

19
(A)201
(B)Binary
2201
2100 1D(20)
2 50 0D1 1 1 0 0 1 0 0 1
2 25 0D2 D7D4 D5D
2 12 1D327 26 25 24 23 22 21 20
2 6 0D4
2 3 0D5 128 64
8
1
2 1 1D6
0 1D7(27)
(C)Hex

(1)
D7 1 1 0 0 1 0 0 1 D
(2) 23 22 21 2023 22 21 2023222120

8 + 4 = 12 8
+ 1
(3)129
(161) (160)

(4) C9
(A = 10, B = 11, C = 12, D = 13, E = 14, F = 15)

(5)12161 + 9160 = 201
(D)Hex
16201
16 12 9160Hex
0 12161Hex
C = 12
C9
C161 + 1609 = 201
C = 12
1-18

www.wunan.com.tw
(02)2705-5066

Optical spectroscopy
Absorb
Ground stateExciteExcited state

2-1
Electromagnetic radiation2-1a
, Wa v e l e n g t h , F r e q u e n c y

= Vc / 

2-1

Vc Ve l o c i t y c m ,
Wa v e n u m b e r

www.wunan.com.tw
(02)2705-5066

.
., 2012.12

ISBN 978-957-11-6907-1 ()
1.
342

101022598

5BE9

Principles and Applications of Instrumental Analysis

237032

(02)8671-1111

(02)8671-1274

http//www.naer.edu.tw






106 3 3 9 4
(02)2705-5066(02)2706-6100
http://www.wunan.com.tw
wunanwunan.com.tw
0 1 0 6 8 9 5 3

104-852091
(02)2518-0207()
http://www.govbooks.com.tw


GPN1010103251
ISBN978-957-11-6907-1

/400-426
(04)2223-0891(04)2223-3549
/800290
(07)2358-702 (07)2350-236

2 0 1 2 1 2
1 0 0 0

www.wunan.com.tw
(02)2705-5066