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T C

1000
1050
1100
1150
1200
1250
1300
1350
1400
1450
1500
1550
1600

C+0,5O2=CO
C+O2=CO2
C+CO2=2CO

G
"-26840-20,85T"
"-94074-0,49T"
"40394-41,21T"

TK
1273.15
1323.15
1373.15
1423.15
1473.15
1523.15
1573.15
1623.15
1673.15
1723.15
1773.15
1823.15
1873.15

G cal
-12072.5115
-14133.0115
-16193.5115
-18254.0115
-20314.5115
-22375.0115
-24435.5115
-26496.0115
-28556.5115
-30617.0115
-32677.5115
-34738.0115
-36798.5115

C+0,5O2=CO
C+O2=CO2
2Cr+1,5O2=Cr2O3

G
"-26840-20,85T"
"-94074-0,49T"
"-271300+61,82T"

1/3Cr2O3+CO=2/3Cr+CO2

"23199,33-0,25T"

T C
1000
1050
1100
1150
1200
1250
1300
1350
1400
1450

TK
1273.15
1323.15
1373.15
1423.15
1473.15
1523.15
1573.15
1623.15
1673.15
1723.15

K cte. equ.
118.1809626
216.0716651
378.0630508
636.0016047
1032.804472
1624.628366
2483.042166
3697.123866
5375.406437
7647.605273
10666.07102
14606.9246
19670.84488

1/T
7.85E-04
7.56E-04
7.28E-04
7.03E-04
6.79E-04
6.57E-04
6.36E-04
6.16E-04
5.98E-04
5.80E-04
5.64E-04
5.49E-04
5.34E-04

90433.33333 A
20.60666667 B
23199.33 A
-0.25 B

G cal
22881.0425
22868.5425
22856.0425
22843.5425
22831.0425
22818.5425
22806.0425
22793.5425
22781.0425
22768.5425

K cte. equ.
0.000118005
0.000166879
0.000230114
0.000310227
0.000409836
0.000531619
0.000678279
0.000852507
0.001056947
0.001294168

1773.15
1823.15
1873.15

22756.0425
22743.5425
22731.0425

0.001566638
0.001876703
0.002226565

Temperatura termodinmica mnima para reduo do xido:

-2
-2.25
-2.5

log (pCO2 / pCO)

1500
1550
1600

Grficos justapostos

-2.75
-3
-3.25
-3.5
-3.75
-4
-4.25
-4.5
5.0E-04

5.5E-04

6.0E-04

6.5E-04

1/T (K-1

log(PCO2/pCO)
-2.076176565
-2.336593963
-2.578708439
-2.804139458
-3.014438001
-3.211021105
-3.395158893
-3.567981422
-3.730492078
-3.883582241
-4.028045185
-4.164588516
-4.293845095

-2.3

log (pCO2 / pCO)

pCO
0.991678638
0.995414255
0.997368839
0.998432602
0.999033633
0.999385231
0.999597592
0.999729666
0.999814037
0.999869274
0.999906262
0.999931549
0.999949169

Boudouard
-2.8

-3.3

-3.8

-4.3
5.0E-04

5.5E-04

6.0E-04

6.5E-04

1/T (K-1)

Cr2O3
Cr2O3
reduo
reduo

log pCO2/pCO
-3.928101287
-3.777598952
-3.638056989
-3.508320174
-3.387390121
-3.274399539
-3.168591398
-3.069301949
-2.975946783
-2.88800932

-2.75

log (pCO2 / pCO)

1/T
7.9E-04
7.6E-04
7.3E-04
7.0E-04
6.8E-04
6.6E-04
6.4E-04
6.2E-04
6.0E-04
5.8E-04

-2.5

Reduo de Cr
-3

-3.25

-3.5

5.6E-04
5.5E-04
5.3E-04

-2.80503125
-2.726604537
-2.652364713

-3.75

y = -5070.6x + 0.0546
-4
5.0E-04

5.5E-04

6.0E-04

6.5E-04

1/T (K-1)

ma para reduo do xido:

1260,6 C

rficos justapostos
Reduo de Cr2O3
Boudouard

6.5E-04

1/T (K-1)

7.0E-04

7.5E-04

8.0E-04

7.0E-04

y = 8817.9x - 9.0008

7.0E-04

7.5E-04

Reduo de Cr2O3

8.0E-04

5070.6x + 0.0546
7.0E-04

7.5E-04

8.0E-04