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A classic example is given below- (Allogons) PEtPh2 Br CS2,-780 C Ni Br PEtPh2 Heat Ph2EtP Br
PEtPh2
Ni
Br
Tetrahedral(dark green)paramagnetic
FLUXIONALITY OF PF5
PF5 has TBP(trigonal bipyramidal structure) with three F
atoms are in equatorial position and two F atoms are in axial position But in reality these equatorial F atoms are interchanged with two axial F atoms leading to the generation of Fluxionality in the molecule F1 F4
F4
F3 P F5 F2 F5 F3 P
F1
F2
Structure of XeF6
XeF has total 14 electrons in its Xe centre having six bond pairs and one
6
stereochemically active lonepair.So, from VSEPR theory we expect a pentagonal bipyramidal structure with a lonepair.
But in reality it exist as distorted octahedral structure in solid state, which
is illustrated as [XeF5]+F- with five bond pairs and one lone pair.
In the vapour phase it exist in three different structures.They are
1.Capped trigonal prism 2.Pentagonal bipyramid(lone pair is projected along one corner of basal plane) 3.Capped Octahedron(lone pair is projected along the centre of a trigonal face )
Fluxionality Of XeF6
F F .. F F F F F F F F F F F F .. F F F
..
F
Ha Hb M Hb
Ha H Hb Ha
M Hb
3-Allyl Complex
1-Allyl Complex
3- Allyl Complex
NMR Studies.
(At Room Temperature) one peak Two Doublet total three signals (At 1400 C Temperature)
One peak
One doublet
At room temperature two peaks are observed one at 4.4 ppm and another at 5.7 ppm At low temperature a number of signals are obtained between the value of 6.5 to 5.9 ppm
H
M H M H
Fluxionality Of Ti(1-Cp)2(5Cp)2
H
1H-
Ti
on
special kind of fluxional behavior in which CO group is scrambled over a skeleton of two or more metal atoms, such kind of Fluxionality is termed Metal carbonyl Scrambling a Classic example is given below
CO
CO
CO
CO
Fe
CO Cis-Form
Fe
CO CO
Fe
Fe
CO Trans-Form
detected..
At room temperature (280 C)We get one peak At -700 C temperaturewe get two distinct peaks