Postharvest Technology-Units Operations Notes

T : +250 788 90 30 30, +250
Ntwali Janvier Department of Biotechnologies INES, Email: ntjanvier@hotmail.com

POSTHARVEST
TECHNOLOGY

INSTITUT DENSEIGNEMENT SUPRIEUR DE RUHENGERI
B.P. 155, Ruhengeri, Rwanda
+250 788 90 30 32, W : www.ines.ac.rw, E : inesruhengeri@yahoo.fr

POSTHARVEST
TECHNOLOGY

STITUT DENSEIGNEMENT SUPRIEUR DE RUHENGERI
inesruhengeri@yahoo.fr
POSTHARVEST

1

COURSE OUTLINE
Fundamental concepts
Material balance
Energy balances
Fluid flow theory and viscosity
Heat transfer and its application in food industry
Evaporation
Dehydration
Mechanical separation
Mixing
Size reduction

2

Useful references
1. George D. Saravacos Z B M, Maroulis Z B. Food Process Engineering Operations.
CRC Press INC, 2011.
2. Toledo R T. Fundamentals of Food Process Engineering. Springer, 2010.
3. White F M. Fluid Mechanics . McGraw-Hill, 2008.
4. Heldman D R, Lund D B. Handbook of Food Engineering, Second Edition.
Taylor & Francis Group, 2007.
5. Ibarz A, Barbosa-Cnovas G V. Unit Operations in Food Engineering. Taylor &
Francis Group, 2003.
6. L. R. Earle M D E. Unit Operations in Food Processing . 1983
http://www.nzifst.org.nz/unitoperations/index.htm(English).
Fundamental concept of unit operations in food processing
3

Basic definitions
Food process engineering can also be defined as the science of conceiving, calculating,
designing, building, and running the facilities where the transformation processes of
agricultural products, at the industrial level and as economically as possible, are carried
out. Thus, an engineer in the food industry should know the basic principles of process
engineering and be able to develop new production techniques for agricultural products.
He should also be capable of designing the equipment to be used in a given process. The
main objective of food process engineering is to study the principles and laws governing
the physical, chemical, or biochemical stages of different processes, and the apparatus or
equipment by which such stages are industrially carried out.
The processing of most food products involves raw materials; cleaning; separating;
disintegrating; forming, raw; pumping; mixing; application methods (formulations,
additives, heat, cold, evaporation, drying, fermenting, etc.); combined operations; and
forming, finished product. We discuss some of these as units of operations. Certain items
- heating, cooling, sanitation, quality control, packaging, and similar procedures - are
discussed as separate topics rather than as units of operations.
Unit operation: unit operation is defined as a basic step in a food processing operation.
In food industry unit operations consists of bringing physical change like separation,
evaporation, crystallization, etc.
Unit operation classification: unit operations are classified depending on the nature of
the transformation performed. There are physical, chemical and biochemical processes.
In physical processes we have: grinding, sieving, mixture, fluidization,
sedimentation, flotation, filtration, rectification, absorption, extraction, adsorption,
heat exchange, drying evaporation, etc.
Chemical processes include: refining, chemical peeling, chemical browning
Biochemical processes are fermentation, sterilization, enzymatic peeling,
blanching, pasteurization
Food processes are usually schematized by means of flow charts. These are diagrams of
all processes that indicate different manufacturing steps, as well as the flow of materials
and energy in the process. In these charts each stage of the process is represented by a
block or rectangle connected by arrows to indicate the way in which the materials flow.
The stage represented is written within the rectangle. An example of a process flow chart
is shown in the fig 1.1
4

FIGURE 1.1 Process flow showing the production of fruit concentrated juices.
Material balance
5

Chapter I Material balance
Material balance are calculations employed in tracing the inflow and outflow of material
in a process and thus establish quantities of components or the whole process stream. The
procedures are useful in formulating products to specified compositions from available
raw materials, evaluating final compositions after blending, evaluating processing yields,
and evaluating separation efficiencies in mechanical separation systems.
Material balances are undertaken before a food processing unit is installed to determine
the quantity of raw material and product to be handled. Compositions of raw material,
product, and by-product streams can be evaluated by using material balances
Material balances are statements on the law of conservation of mass. If there is no
accumulation, what goes into a process equals what comes out.
Inflow = outflow + accumulation
1.1 Conservation of mass
Even in the case of a chemical reaction, the composition of mass of a reactant and the
product before and after the reaction may be different, but the mass of the total system
remains unaltered.
In a unit operation, whatever its nature, the mass of material going in, must balance with
the mass of material going out. This is true for batch operation as well as continuous
operation in a certain interval of time
The fig. 1.2 shows flow of a liquid in a tank. If the level of the liquid in the tank remains
constant, then the flow rate at the inlet must be equal to the flow rate at exit. Thus, the
rate at the inlet is 1kg/s and the rate at the exit is also 1kg/s.

Figure 1.2: Liquid flow in and out of a tank

Material balance
6

Although only one inlet and one exit stream is shown in the figure above, there may be
more than one stream entering and exiting a control volume. Therefore, for a general case,
the rate of mass flow entering the system is
m
nIct
= m
n
=1
(1.1)
Where subscript i denotes the inlet, and n is the number of inlets to a system.
The mass accumulation in the system as function of time is
m
cxt
= m
c
p
c=1
(1.2)
Where subscript e denotes the exit and p is the number of exits from a system.
The rate of mass accumulation within the system boundary, expressed as a function of
time, is
m
uccumuIuton
=
dm
sjstcm
dt
(1.3)
The conservation of mass principle can then be expressed in terms of an equation
m
nIct
m
cxt
=
dm
sjstcm
dt
(1.4)
1.2 Useful steps in solving a material balance problem
In order to conduct material balance in an organized manner, one should:
Collect all known data on mass and composition at all inlet and exit streams
Draw a block diagram indicating the process, with inlet and exit streams
identified, show the system boundary
Write all available data on the block diagram
Select a suitable basis (e.g.: mass, time) for calculations
Using Equation (1.4), write material balances in terms of the selected basis for
calculating unknowns
Solve material balances to determine the unknowns

Material balance
7

1.3 Composition and concentration
For a stream that contains more than one component, the mass fraction of a component is
simply the mass of that component expressed as a fraction of the total mass of the
mixture containing that component. For a mixture of components of mass m
A
and m
B
of
components A and B, the mass fraction of the component A is:
X
A
=
m
A
m
A
+m
B
(1.5)
Similarly, a mole fraction is defined as a number of moles a component expressed as a
fraction of the total number of moles in the mixture as illustrated in the equation 1.6
X
A
=
n
A
n
A
+n
B
(1.6)
1.4 Moisture content
Moisture content expresses the amount of water present in a moist sample. Two bases are
widely used to express moisture content; namely, moisture content wet basis and
moisture content dry basis.
Moisture content wet basis (MC
wb
) is the amount of water per unit mass of moist (or wet)
sample.
MC
wb
=mass of water/mass of moist sample
Moisture content dry basis (MC
db
) is the amount of water per unit mass of dry solids
(bone dry) present in the sample.
MC
db
=mass of water/mass of dry solids
Thus, moisture content wet basis is
HC
wb
=
(muss o] wutc)
muss o] wutc+muss o] d soIds
(1.7)
1.5 Component Material Balances
For a system with four streams as shown in the fig. 1.3, suppose that each of the four
streams contains water, at a steady state, the combined mass flow rate of water in all
streams entering the system, must equal the combined mass flow rate of water leaving the
system.
Material balance
8

Figure 1.3: Material balance: a process with four streams, m
1
+m
2
=m
3
+m
4

If x is the mass fraction of water in a stream of total mass flow rate m, the mass flow rate
of water is xm. And according to the low of conservation of mass we get the equation 1.8.
Equation 1.8 is called component material balance, and any material balance problem,
other than the most trivial, will require the simultaneous solution of an overall balance
and at least one component balance equation.
x
1
m
1
+x
2
m
2
= x
3
m
3
+ x
4
m
4
(1.8)
Examples
1. Consider a problem in crystallization. The problem may be stated as: Determine the
amount of sugar (water-free basis) that can be produced from 100 kg of sugar solution
that contains 20% by weight of sugar and 1% of a water-soluble un-crystallizable
impurity. The solution is concentrated to 75% sugar, cooled to 20
C, centrifuged, and
the crystals dried.
From what we know, the process of sugar crystallization can be represented in the fig. 1.4.

Figure 1.4: process flow diagram for crystallization
But that figure alone is not sufficient; we need to add data from the problem statement.
Thats why a more detailed figure is drawn, showing different stages with their inflows
and outflows based on what was given in problem statement. Figure 1.5 is a flow diagram
of the same process, but after taking into consideration how components partition in
various steps in the process, additional streams leaving the system are drawn in the
diagram. To concentrate a 20% solution to 75% requires the removal of water. Thus,
water leaves the system at the evaporator. The process of cooling does not alter the mass;
Material balance
9

therefore, the same process stream enters and leaves the crystallizer. Centrifugation
separates most of the liquid phase from the solid phase, and the crystals, the solid phase
containing a small amount of retained solution, enter the drier. A liquid phase leaves the
system at the centrifuge. Water leaves the system at the drier.

Figure 1.5: Process flow diagram for a crystallization problem showing inflows and outflows and
boundaries enclosing subsystems for analyzing sections of the process.
2. A wet food product contains 70% water. After drying, it is found that 80% of original
water has been removed. Determine (a) mass of water removed per kilogram of wet
food and (b) composition of dried food.
Given
Initial water content = 70%
Water removed = 80% of original water content
Solution
1. Select basis =1 kg wet food product
2. Mass of water in inlet stream = 0.7 kg
3. Water removed in drying = 0.8(0.7) = 0.56 kg/kg of wet food material
4. Write material balance on water,
Water in dried food = 0.7(1) - 0.56 = 0.14 kg
5. Write balance on solids,
0.3(1) = solids in exit stream
Solids = 0.3 kg
6. Thus, the dried food contains 0.14 kg water and 0.3 kg solids.
Material balance
10

3. A membrane separation system is used to concentrate total solids (TS) in a liquid
food from 10% to 30%. The concentration is accomplished in two stages with the first
stage resulting in release of a low-total-solids liquid stream. The second stage
separates the final concentration product from a low-total-solids stream, which is
returned to the first stage. Determine the magnitude of the recycle stream when the
recycle contains 2% TS, the waste stream contains 0.5% TS, and the stream between
stages 1 and 2 contains 25% TS. The process should produce 100 kg/min of 30% TS.
Given:
Concentration of inlet stream= 10%
Concentration of outlet stream = 30%
Concentration of the recycle stream = 2%

Figure 1.6: A schematic arrangement of equipment described in Example 3
Concentration of the waste water stream = 0.5%
Concentration of the stream between the 2 stages= 25%
Mass flow rate of the exit stream= 100kg/min
Solution:
1. Select 1 min as a basis
2. For the total system
F = P +W
Fx
F
=Px
p
+Wx
W

F (0.1) =100(0.3) +W (0.005)
Were x is the solids fraction
3. For the first stage
F+R=W+B
Fx
F
+ RX
R
=Wx
W
+ Bx
B

F90.1) +R90.02) =W (0.005) +B (0.25)
4. From step (2)
(100+W)(0.1)=30+0.005W
Material balance
11

0.1W-0.005W=30-10
0.095W=20
W=210.5Kg/min
F=310.5Kg/min
5. From step (3)
310.5+R=210.5+B
B=100+R
310.5(0.1) +0.02R=210.5(0.005) +0.25B
31.05+0.02=1.0525+0.25B
4.9975=0.23R
R=21.73kg/min
6. The results show that the recycle will be flowing at a rate of 21.73Kg/min
4. In a furnace, 95% of carbon is converted to carbon dioxide and the remainder to
carbon monoxide. By material balance, predict the quantities of gases appearing in
the flue gases leaving the furnace.
Given
Carbon converted to CO
2
= 95%
Carbon converted to CO=5%
Solution
1. Basis is 1 kg of carbon
2. The combustion equations are
C + O
2
CO
2

C + O
2
CO
3. From these equations, 44kg of carbon dioxide is being formed by combustion of
12kg of carbon, and 28kg of carbon monoxide is being produced by combustion
of 12kg carbon
4. The amount of CO
2
produced is
(44kg C0
2
)(0.95kg C buncd)
12kg C buncd
= S.4S kg C0
2

5. Similarly the amount of CO produced
(28kg C0)(u.uSkg C burncJ)
12kg C burncJ
= u.12 kg C0
6. Thus, the flue gasses contain 3.4 kg of CO
2
and 0.12 kg CO for every kg of
carbon burned

5. Potato flakes (moisture content=75% wet basis) are being dried in a concurrent flow
drier. The moisture content of the air entering the drier is 0.08 kg of water per 1 kg
dry air. The moisture content of air leaving the drier is 0.18 kg water per 1 kg of dry
air. The air flow rate in the drier is 100 kg dry air per hour. As shown in Figure below,
Material balance
12

50 kg of wet potato flakes enter the drier per hour. At steady state, calculate the
following
1. What is the mass flow rate of dried potatoes?
2. What is the moisture content, of dried potatoes exiting the drier?

Given
Weight of potato flakes entering the drier F = 50 kg
Time = 1 h
Solution
1. Basis = 1 h
2. M ass of air entering the drier + mass of dry air + mass of water
I=1uu+1uuxu.8
I=1u8
3. Mass of the air leaving the drier = mass of air + mass of water
E=1uu+1uuxu.18
E=118
4. Total balance of the drier
I+F=E+P
P=I+F E
P=1u8+1uu 118
P=4ukg
5. Solid balance on the drier
We know that X
A
=
m
A
m
A
+m
B
X
B
= 1 X
A

In our case, X
A
is the mass fraction of water in the moist product; X
B
is the mass
fraction of solid in the product. Thus, mass of solids is
mA + mB (1 XA)
mA + mB = F, XA = 7S%=u.7S
Mass of solid content in the feed = F (1-0.75)
If y is the solid fraction in the product stream P, then solid balance on the drier
gives:
0.25 F = y P
Material balance
13

y =
0.2550
40

y = 0.3125
Thus moisture content in the product feed is
1 y=u.S12S=u.687S oi 68.7S%
In 40kg of the product there is 400.6875= 27.5 kg of water.
6. An experimental engineered food is being manufactured using five
stages, as shown in Figures below. The feed is 1000 kg/h; various
streams have been labeled along with the known composition values
on the diagram. Note that the composition of each stream is in terms
of solids and water only (TS=total solids). Stream C is divided equally
into streams E and G. Product P, with 80% solids, is the desired final
product. Stream K produces a by-product at the rate of 450 kg/h with
20% solids. Calculate the following:
1. The mass flow rate of P
2. The mass flow rate of the recycle stream A
3. The mass flow rate of the recycle stream R

F
D
W
P
K
System total
Material balance
14

System boundary
Feed F
1000 kg/h
15% TS
85% water
D
150 kg/h
0% TS
A 5% TS
II
V
III
IV
Product
p
80% TS
W
water
K
450 kg/h
20% TS
G
C
B
R
L
E 10% TS
I
Flow chart of the experimental food manufacturing
Energy balances
15

Chapter II Energy balances
2.1 General principles
Increasing energy costs have forced people to recognize and appreciate the value of
energy more than ever before. Energy conservation is being stressed not only in
industrial operations but also in almost all aspects of an individuals daily activities.
Energy balance calculations can be used to account for the various forms of energy
involved in a system. Energy audits are essential in identifying effectiveness of energy
conservation measures and in identifying areas where energy conservation can be done,
or in designing systems involving heating and cooling
2.2 Laws of thermodynamics
The first law of thermodynamics is a statement of the conservation of energy. The law
states:
The energy of an isolated system remains constant.
Stated in other words,
Energy can be neither created nor destroyed but can be transformed from one form to
another.
Energy can be either stored within an object or transferred to another one, such as in the
form of thermal or mechanical energy. If we increase the elevation of an object, its
potential energy will increase. The increased potential energy will remain stored in the
object until we move it again. Similarly, we can increase the thermal energy of an object
by transferring heat into it and observing an increase in temperature.
Energy can also be transformed from one form to another. For example, in a
hydroelectric plant, as water falls from a high elevation onto the blades of a turbine, the
potential energy of water is converted into mechanical energy in the turbine, and the
generator then converts the mechanical energy into electrical energy. The electrical
energy is transmitted to homes or factories where it is further converted to other useful
forms such as thermal energy in electric heaters.
The second law of thermodynamics is useful in examining the direction of energy
transfer or conversion. The following two statements of the second law are by Rudolf
Clausius and Lord Kelvin, respectively.
No process is possible whose sole result is the removal of heat from a reservoir (system)
at one temperature and the absorption of an equal quantity of heat by a reservoir at a
higher temperature.
Energy balances
16

No process is possible whose sole result is the abstraction of heat from a single reservoir
and the performance of an equivalent amount of work.
The second law of thermodynamics helps explain why heat always flows from a hot
object to a cold object; why two gases placed in a chamber will mix throughout the
chamber, but will not spontaneously separate once mixed; and why it is impossible to
construct a machine that will operate continuously while receiving heat from a single
reservoir and producing an equivalent amount of work.
The second law of thermodynamics assigns both quantity and quality to energy. The
importance of this law is evident in any processthe path of a process is always toward
that of decreasing quality. For example, a hot bowl of soup left to itself on a table cools
down. In this case, the quality of energy degrades. Energy of a higher quality (at a higher
temperature) transfers from the soup to the surroundings and converts into less useful
forms of energy.
2.3 Energy
Energy is a scalar quantity. It was first hypothesized by Newton to express kinetic and
potential energies. We cannot observe energy directly, but we can measure it using
indirect methods and analyze its value. Energy may be in different forms, such as
potential, kinetic, chemical, magnetic, or electrical.
Potential energy of a system is by virtue of its location with respect to the gravitational
field. If an object has a mass m, located at elevation h, and acceleration due to gravity is g,
then the potential energy is
E
PE
=mgh (2.1)
Kinetic energy of an object is due to its velocity. If an object is moving with a velocity u,
and it has mass m, then its kinetic energy is:
E
KL
=
1
2
mu
2
(2.2)
Both kinetic and potential energies are macroscopic; that is, they represent energy of a
system due to its entire being. This is in contrast to internal energy, which is due to the
microscopic nature of a system. At the molecular scale, the atoms of a substance are
continuously in motion. They move in random direction, collide with each other, vibrate,
and rotate. Energies related to all these movements, including energy of attraction
between the atoms is combined into one lump sum and is called the internal energy.
Energy balances
17

Internal energy is an extensive property, and it is independent of the path of a process.
Although we cannot measure an absolute value of internal energy, we can relate changes
in internal energy to other properties such as temperature and pressure.
In many engineering systems, one or two forms of energy may dominate whereas others
can be neglected. For example, when a sugar beet is dropped from a conveyor into a bin,
the potential and kinetic energy of the sugar beet changes, but other energy forms such as
chemical, magnetic, and electrical do not change and may be neglected in the analysis.
Similarly, when tomato juice is heated in a hot-break heater, the potential or kinetic
energy of the juice does not change, but the internal energy will change as temperature
increases.
The total energy of a system can be written in the form of an equation as
E
totuI
= E
KL
+E
PL
+E
cIcctcuI
+E
Mugnctc
+E
ChcmcuI
+E
(2.3)
Where E i is the internal energy, kJ.
If the magnitudes of all other energy forms are small in comparison with the kinetic,
potential, and internal energies, then
E
totuI
= E
KL
+E
PL
+E
(2.4)
2.4 Enthalpy
Enthalpy (H) is an extensive property, expressed as the sum of internal energy (E
i
) and
the product of pressure and volume (PV).
H = E
i
+ PV (2.5)
In some special cases, enthalpy can be an energy quantity. These are cases where there is
fluid entering and leaving an open system. In this case the product of volume and
pressure represents the flow energy. In this case, enthalpy of the system is the sum of
internal energy and flow energy
2.5 Equation of state and perfect gas law
The thermodynamic properties of a simple system are established by any two
independent properties. A functional relationship between the properties of a system is
called an equation of state. Values of two properties of a system help establish the value
of the third property.

Energy balances
18

For a perfect gas, an equation of state is a relationship between pressure, volume, and
temperature. The equation may be written as
PV = RTA or P = RTA (2.6)
Where P is absolute pressure (Pa), v is specific volume (m
3
/kg), R is the gas constant
(m
3
Pa/[kg
o
K]), TA is absolute temperature (
o
K) and is density.
2.6 Heat
Heat transfer between a system and its surroundings is probably the most prevalent form
of energy that we observe in many food engineering systems. Heat plays a major role in
cooking, preservation, and creating new food products with unique properties. Heat is an
energy form that is easy to sense because of its association with temperature. Heat
transferred to a product can be defined into two types:
Sensible heat is defined as the energy transferred between two bodies at different
temperatures, or the energy present in a body by virtue of its temperature.
Latent heat is the energy associated with phase transitions, heat of fusion, from solid to
liquid, and heat of vaporization, from liquid to vapor.
Unit of heat in SI is Joule (J). If we consider heat transfer per unit of time, then we
express it in terms of rate of heat transfer q, with the units J/s or Watt (W)
Thermal energy for a specific compound can be determined if the heat capacity c is
known. Thus:
= m] cJI
t
2
t
1
(2.7)
t
1
is the initial temperature, while t
2
is the final temperature
If the path of energy transfer is under constant pressure, the heat capacity constant is the
one under constant pressure c
p
:
= m] c
p
JI
t
2
t
1
(2.8)
For constant volume energy transfer, the heat capacity is the one for constant volume c
v
:
= m] c
JI
t
2
t
1
(2.9)
The numeric values of c p and c v are similar for solids and liquids; however, they may
be considerably different for gases.
Energy balances
19

2.7 Work
Work includes all interactions between a system and its surroundings that are not a result
of temperature difference. There are many such interactions. Examples include the
movement of a piston in an engine, an electric wire conducting electric current across a
system boundary, and a shaft transmitting energy from a motor to another piece of
equipment that is enclosed in the system boundary.
Examples of such interactions include a piston moving in a cylinder, a shaft transmitting
energy from a motor to equipment in the system
The sign for work is W and the SI unit is joules (J). Work can be expressed in
mathematical terms as follows: consider a system where an object moves a short distance
ds due to the force F. the work done by the system is then
dW = -Fds (2.10)
For an object moving from position 1 to position 2 the work is:
w
1-2
= ] FJs
2
1
= F(s
1
s
2
) (2.11)
The sign convention used for work (W) is that any time work is done by a system, W is
positive; when work is done on a system, W is negative. This is opposite to that of heat
transfer where Q is positive when heat is applied to a system from the surroundings and is
negative when heat flows from the system to the surroundings. This is why in the formula
of work above the sign was negative because the force is applied to the system. The
work interaction between a system and its surroundings can be attributed to several
mechanisms, such as a moving boundary, gravitational forces, acceleration, and shaft
rotation.
2.7.1 Work Due to a Moving Boundary
Consider the case of a piston and a cylinder as shown in the figure 2.1.

Figure 2.1: Work due to moving boundary
Energy balances
20

As the gas heats it expands and causes the piston to move from position 1 to position 2 as
the system boundary is flexible, it expands and the piston moves outward. In this case,
work is being done by the expending gas. When the piston moves by a small distance, ds,
then the differential amount of work done by the system is force, F, times the distance, ds:
W=Fds (2.12)
But we know that force/area=pressure, if the cross-section of the cylinder is A, then:
W=PAds=PdV (2.13)
The work done to move the piston from position 1 to position 2 is:
w
1-2
= ] PJI
2
1
(2.14)
2.7.2 Work Due to Gravitational Forces
Force of gravity F=mg. If the mass m is lifted a small distance dh then the corresponding
small work is
dW=Fdh dW=mgdh
To lift an object from location 1 to 2, we have
] Jw
2
1
= ] mgJ
2
1
W= mg(h
2
h
1
) (2.1S)
2.7.3 Work Due to Change in Velocity
For an object moving at velocity u
1
to move at velocity u
2
, there is need to apply force.
Force is
F=ma
Where F is force, m is mass and a is acceleration.
o =
du
dt
and u =
ds
dt

Work is W=Fds
Substituting in this equation of work
w = m
du
dt
uJt (2.16)
After simplifying and integrating, we obtain:
Energy balances
21

w = m] uJu
2
1
thus w =
m
2
(u
2
2
u
1
2
) (2.17)
Thus, the work done in changing velocity is equal to the change in kinetic energy of the
system

2.7.4 Work Due to Shaft Rotation
A typical example is in an electric motor a rotating shaft provides a source of mechanical
energy to the connected equipment

Figure 2.2: work due to rotating shaft
As shown in Figure 2.2, the torque (rotating force) applied to a shaft is determined if
the force F and radius r are known,
= Fr
If the movement along the circumference is distance s, and the number of revolutions is n,
then the distance traveled along the circumference during n revolutions is
s=(2r)n
Since the product of force and distance is work, we get
w =
U
(2nr)n = 0(2n)n (2.18)

2.7.5 Work Due to Frictional Forces
If there is friction in the system, work must be done to overcome it. If we denote friction
energy by E
f
then work due to friction force is: W=-Ef

(2.19)

Energy balances
22

2.8 Energy Balance
The first law of thermodynamics states that energy can be neither created nor destroyed.
Therefore, when a process is undergoing in a system, energy entering the system minus
energy leaving the system must equal the energy variation in the system:
E
n
E
out
= E
sstcm
(2.20)
This energy balance per unit of time can be written as a rate expression:
E
n
E
out
= E
sstcm
(2.21)
The dot added on top of the E is to show that the units are per unit of time
2.8.1 Energy balance in a closed system
In a closed system there is no mass transfer between the system and the surrounding.
Energy can be transferred between the system and the surrounding only through heat and
different forms of work. According to the first law of thermodynamics, the total change
in energy of a closed system is equal to the heat added to the system minus the work done
by the system
E = w (2.22)
The total change of energy in the system E is composed of internal energy E
i
, Kinetic
energy E
KE
and potential energy E
PE
, assuming that other forms of energy are too small to
be considered which is the case in many systems we get:
E
+ E
KL
+ E
PL
= w (2.23)
Based on the explanations on expansion of gas in a cylinder, the complete equation for
work may be written as:
w = ]PJI E
KL
E
PL
E
]
(2.24)
Substituting W in the equation (2.22), and eliminating E
KE
and E
PE
, we obtain:
E
= + E
]
]PJI (2.24)
From an elementary theorem of calculus, we know that
u(Pv)=uPv+Puv Pv=]Puv+]vuP
Thus
Energy balances
23

]Puv= Pv- ]vuP
Substituting in the energy balance equation:
E
+PI = +E
]
]IJP = + E
]
]IJP (2.25)

H being variation in enthalpy; for heating processes at constant pressure, friction is
absent and we remain with
H=Q
Constant pressure processes are encountered most commonly in food processing
applications. The change in enthalpy shown in the equation above is simply called heat
content.
2.8.2 Energy balance for an open system
For an open system, in addition to heat transfer and work, mass is transferred across the
boundaries of the system. Mass entering or leaving the system carries a certain amount of
energy therefore; change in energy due to the mass flow has to be considered. The work
associated to mass flow is referred to as flow work

Figure 2.3: movement of a liquid volume
We can calculate flow work by determining the work involved in pushing a certain mass
through the system boundary. Consider a differential element of fluid of uniform
properties entering an open system (Fig. 2.3). If the cross-sectional area of the element is
A and the pressure of the fluid is P, the force required to push this element through the
system boundaries is
F = PA
Energy balances
24

If the element is pushed to a distance L then the work done on the fluid is
w
muss ]Iow
= F = P = PI (2.26)

As we have seen before, the total energy of the fluid element in the fig. 2.3 includes the
kinetic energy, potential energy and internal energy. In addition we have to account for
the energy associated with the flowing of the fluid or flow work.
E
totuI
= E
KL
+ E
PL
+E
+ PI (2.26)
By substituting each term by its value we get
E
totuI
=
1
2
mu
2
+mg + E
+PI (2.27)
Energy Balance for Steady Flow Systems: When a system is in a steady state, its
properties do not change with time, there is no change in the energy of the system with
time. We have:
E
n
= E
out
= E
sstcm
= u E
n
= E
out
(2.28)
2.8.3 Total energy balance
Substituting all terms presented in previous sections into the equation (2.28) of
conservation of energy
E
n
= E
out

We get:
n
+ w
n
+ m
p
=1
E
,
+
u
2
2
+ g
+ P
=
out
+
w
out
+ m
c
c=1
E
,c
+
u
c
2
2
+ g
c
+ P
c
I
c
(2.29)
In the above equation Ei is internal energy per unit mass and v is specific volume. p and
q are numbers of inlet and exit streams respectively. For a system where there is only one
inlet (position 1) and one exit (position 2) streams,
m
=
u
2
2
2
+g
2
+
P
2
2

u
1
2
2
+g
1
+
P
1
1
+E
1,2
E
,1
+w
m
(2.30)
Energy balances
25

Where Qm and Wm are the transfer of heat and work per unit mass, respectively. The
specific volume v is replaced with 1 where (rho) is the density
Examples
1. A tubular water blancher is being used to process beans (Fig. 2.4 ). The product mass
flow rate is 860 kg/h. It is found that the theoretical energy consumed for the
blanching process amounts to 1.19 GJ/h. The energy lost due to lack of insulation
around the blancher is estimated to be 0.24 GJ/h. If the total energy input to the
blancher is 2.71 GJ/h,

Figure 2.4 schematic of the water blancher
a. Calculate the energy required to reheat water.
b. Determine the percent energy associated with each stream.
Given
Product mass flow rate 860 kg/h
Theoretical energy required by product 1.19 GJ/h
Energy lost due to lack of insulation 0.24 GJ/h
Energy input to the blancher 2.71 GJ/h
Approach
We will first write an energy balance and then solve for the unknowns
Solution
1. Select 1 hour as basis
2. Energy balance can be written as follows:
Energy input to the blancher = energy output with the product + energy loss due
to lack of insulation + energy out with water
Energy balances
26

3. Substituting appropriate values in the energy balance,
2.71 = 1.19 + 0.24+Ew
We get:
EW = 1.28Gj/h
Thus, the blancher requires 2.71 -1.28 = 1.43 GJ/h to both reheat water
and maintain it at conditions necessary to accomplish the blanching
process.
4. These values can be converted to percentage of total thermal input as follows:
Energy out with product =
(1.19)
2.1
(1uu) = 4S.91%
Energy loss due to lack of insulation =
(0.24)(100)
2.1
= 8.86%
Energy out with water =
(1.2)(100)
2.1
= 47.2S%
5. The results indicate that this water blancher operates at about 44% thermal
energy efficiency
2. Five kilograms of ice at 10
o
C is heated to melt it into water at 0
o
C; then additional
heat is added to vaporize the water in the stream. The saturated vapors exit at 100
o
C.
Calculate the different enthalpy values involved in the process. Specific heat of ice is
C
i
=2.05kj/kg
o
K, specific heat of water is C
w
=4.182kj/kg
o
k, latent heat of fusion is
333.2 kj/kg, latent heat of vaporization at 100
o
C is 2257.06kj/kg.
Given:
The fig 2.5 shows a plot of temperature versus enthalpy. Note that temperature
remains constant in regions that involve latent heat.

Figure 2.5: A plot of temperature versus enthalpy for melting of ice and vaporization of water
Energy balances
27

Solution:
The enthalpy calculations are made separately for each zone in the fig. 2.5
1. Zone A-B
= 5(kg)2.05(kj/kg
o
C)(0+10)
o
C
= 102.5kj/kg
2. Zone B-C
H
BC
=mH
latent

= 5kg333.2kj/kg
=1666kj
3. Zone C-D
=5kg4.1822.05(kj/kg
o
C)(100-0)
o
C
=2091kj
3. Steam is used for peeling potatoes in a semicontinuous operation. Steam is supplied at
the rate of 4 kg per 100 kg of unpeeled potatoes. The unpeeled potatoes enter the
system with a temperature of 17
o
C, and the peeled potatoes leave at 35
o
C. A waste
stream from the system leaves at 60
o
C. The specific heats of unpeeled potatoes, waste
stream, and peeled potatoes are 3.7, 4.2, and 3.5 kJ/(kg
o
K), respectively. If the heat
content (assuming 0
o
C reference temperature) of the steam is 2750 kJ/kg, determine
the quantities of the waste stream and the peeled potatoes from the process.

Figure 2.6: A block diagram showing various streams described in Example above
Fluid flow theory and Viscosity
28

Chapter III Fluid flow theory and viscosity
Fluids are substances that flow without disintegration when pressure is applied. This
definition of a fluid includes gases, liquids, and certain solids. A number of foods are
fluids. In addition, gases such as compressed air and steam are also used in food
processing and they exhibit resistance to flow just like liquids. The resistance of fluids to
flow and its implications in the design of a fluid handling system will be discussed here.
3.1 Liquid transport system
Fluids are substances that flow without disintegration when pressure is applied. This
definition of a fluid includes gases, liquids, and certain solids. In any commercial food
processing plant, the movement of liquid foods from one location to another is an
essential operation. Various types of systems are used for moving raw liquid foods as
well as processed liquid products before packaging. In food industry, transport systems
are of particular design because of the important need of sanitation in order to maintain
the product clean.
From our daily experience with handling different kinds of fluids, we know that if
pressure at one location within a fluid system is higher than another, the fluid moves
toward the region of lower pressure. Gravity causes the flow of fluid from higher to lower
elevations. A fluid moving to a lower elevation undergoes a decrease in its potential
energy, while its kinetic energy increases. With the presence of thermal gradients, heated
fluids experience a decrease in density, causing lighter fluid to rise while denser fluid
takes its place.

Figure 3.1: A typical liquid food processing system, illustrating pipelines and pipeline components
29

A typical transport system consists of four basic components: tanks, pipelines, pumps and
fittings. Tanks serve in keeping the liquid products prior to or after processing. Pipelines
are used to transport the product from one processing station to another. Fittings consist
of elbows and tee that serve in changing direction of the product; and valves that serve in
control of the flow rate. Apart from regions where liquids are transported by gravitational
force, pumps are the ones that produce mechanical energy for transport
3.2 Pipelines for processing plants
Fluids (liquids and gases) in food processing plants are transported mostly in closed
conduitscommonly called pipes if they are round, or ducts if they are not round.
Although sometimes used in processing plants, open drains generally are avoided, for
sanitation reasons. The pipelines used for liquid foods and their components have
numerous unique features. Probably the most evident feature is the use of stainless steel
for construction. This metal provides smoothness, cleanability, and corrosion resistance.
Typical pipeline system for liquid food transport contains several essential components.
In addition to the straight lengths of the pipe, which may vary in diameter from 2 to 10
cm, elbows and tees are essential for changing the direction of product movement. These
components are welded into the pipeline system and may be used in several different
configurations. Another component is the valve used to control the flow rate; an air-
actuated valve is illustrated in Figure 3.2. This valve may be operated remotely, often
based on some type of preset signal.

Figure 3.2: An air-actuated valve for liquid foods.

30

3.3 Types of pumps
Except for situations where gravity can be used to move liquid products, some type of
mechanical energy must be introduced to overcome the forces opposing transport of the
liquid. This mechanical energy is supplied by pumps. There are numerous types of pumps
used in the industry. As shown in Figure 3.3, pumps may be classified as centrifugal or
positive displacement. There are variations within each of these types, as shown in the
figure.

Figure 3.3 Classification of pumps
3.3.1 Centrifugal pumps
The basic principle of these pumps is the use centrifugal force to increase pressure of the
fluid. The pump consists of a motor-driven impeller enclosed in a case. The product
enters the pump at the center of impeller rotation and, due to centrifugal force, moves to
the impeller periphery. At this point, the liquid experiences maximum pressure and
moves through the exit to the pipeline. These pumps are most efficient in high viscosity
foods like milk and juices.
31

Figure 3.4: Exterior view of a centrifugal pump

Figure 3.4: A centrifugal pump with components

Figure 3.5: Principle of operation of a centrifugal pump

32

3.3.2 Positive displacement pumps
By application of direct force to a confined liquid, a positive displacement pump
produces the pressure required to move the liquid product. Product movement is related
directly to the speed of the moving parts within the pump. Thus, flow rates are accurately
controlled by the drive speed to the pump. The mechanism of operation also allows a
positive displacement pump to transport liquids with high viscosities.

Figure 3.6: examples of positive displacement pumps. Above left is reciprocating piston pump, above left
is Peristaltic (flexible membrane rotary) pump and below is Lobe pump
3.4 Properties of liquids
The transport of a liquid food by one of the systems described above is directly related to
liquid properties, primarily viscosity and density. These properties will influence the
power requirements for liquid transport as well as the flow characteristics within the
pipeline. An understanding of the physical meaning associated with these properties is
necessary in order to design an optimal transport system.
33

Fluid flow takes place when force is applied on a fluid. Force per unit area is defined as
stress. When force acting on a surface is perpendicular to it, the stress is called normal
stress. More commonly, normal stress is referred to as pressure. When the force acts
parallel to the surface, the stress is called shear stress, . When shear stress is applied to
a fluid, the fluid cannot support the shear stress; instead the fluid deforms, or simply
stated, it flows.
The influence of shear stress on solids and liquids leads to a broad classification of such
materials as plastic, elastic, and fluid.
In the case of an elastic solid, when shear stress is applied, there is a proportional finite
deformation, and there is no flow of the material. On removal of the applied stress, the
solid returns to its original shape.
A plastic material, on the other hand, deforms continuously on application of shear stress;
the rate of deformation is proportional to the shear stress. When the shear stress is
removed, the object shows some recovery. Examples include some types of cheese,
gelatin deserts
A fluid deforms continuously on application of shear stress. The rate of deformation is
proportional to the applied shear stress. There is no recovery; that is, the fluid does not
retain or attempt to retain its original shape when the stress is withdrawn.
When normal stress or pressure is applied on a liquid, there is no observed appreciable
effect. Thus, liquids are called incompressible fluids, whereas gases are compressible
fluids, since increased pressure results in considerable reduction in volume occupied by a
gas.
3.4.1 Density
The density of a liquid is defined as its mass per unit volume and is expressed as kg/m
3
in
the SI unit system. In a physical sense, the magnitude of the density is the mass of a
quantity of a given liquid occupying a defined unit volume. The most evident factor is
that the magnitude of density is influenced by temperature. For example, the density of
water is at maximum at 4
o
C and decreases consistently with increasing temperature.
Densities of liquids are most often measured by a hand hydrometer. This instrument
measures specific gravity, which is the ratio of the density of the given liquid to the
density of water at the same temperature. The measuring instrument is a weighted fl oat
attached to a small-diameter stem containing a scale of specific-gravity values. The fl oat
will sink into the unknown liquid by an amount proportional to the specific gravity, and
the resulting liquid level is read on the stem scale.
34

Figure 3.7: Density of water as a function of temperature
3.4.2 Viscosity
A fluid may be visualized as composed of different layers. The fluid begins to move as
soon as a force acts on it. The relative movement of one layer of fluid over another is due
to the force, commonly called shearing force, which is applied in a direction parallel to
the surface over which it acts. From Newtons second law of motion, a resistance force
is offered by the fluid to movement, in the opposite direction to the shearing force, and it
must also act in a direction parallel to the surface between the layers. This resistance
force is a measure of an important property of fluids called viscosity.
With different types of fluids, we commonly observe a wide range of resistance to
movement. For example, honey is much more difficult to pour out of a jar or to stir than
water or milk. Honey is considerably more viscous than milk. With this conceptual
framework, we will consider a hypothetical experiment.
Consider a fluid element sheared in one plane by a single shear stress (tau) as shown in
fig. 3.8. The shear strain angle will continuously grow with time as long as the stress
is maintained, the upper surface moving at speed of u larger than the lower. When the
shearing stress increases, the rate of shear will increase in direct proportion:

du
d
(3.1)
and
tan o0 =
6u6t
6
(3.2)
35

Figure 3.8: illustration of a fluid element straining at a rate of /t
For a small angular deflection
tan (3.3)
Therefore
o0 =
6u6t
6

60
6t
=
6u
6
(3.4)
Replacing /t by its value in the equation (3.1) and introducing a constant in order to
remove the proportionality we get:
= p
6u
6
= p
du
d
(3.5)
is the coefficient of viscosity, or simply viscosity, of the fluid. It is also called absolute
or dynamic viscosity and is expressed in Pa s of poise (1 poise=0.1 Pa s). Liquids that
follow Equation (3.5), exhibiting a direct proportionality between shear rate and shear
stress, are called Newtonian liquids. When shear stress is plotted against shear rate, a
straight line is obtained passing through the origin.

Figure 3.9: Shear stress vs. shear rate behavior for a Newtonian fluid
36

Figure 3.10: Rheological behavior of various fluids
The slope of the line gives the value for viscosity, . Water is a Newtonian liquid; other
foods that exhibit Newtonian characteristics include honey, fluid milk, and fruit juices.
Table 3.1 gives some examples of coefficients of viscosity. Viscosity is a physical
property of the fluid and it describes the resistance of the material to shear-induced flow.
Furthermore, it depends on the physicochemical nature of the material and the
temperature.
Fluid Approximate viscosity in Pa s
Air
10
-5

Water
10
-3

Olive oil
10
-1

Glycerol 1
Liquid honey 10
Golden syrup
10
2

Glass
10
4

Table 3.1: The Viscosity of Some Common Materials at Room Temperature
37

In some books the symbol is used to symbolize shear stress but the Society of Rheology
recommends the use of symbol .
3.4.2.1 Methods of measuring viscosity
Instruments used for measuring flow properties of fluids are called viscometers. The most
common viscometers are the capillary tube and the rotational viscometer shown in the
figure below.

Figure 3.11: Diagram of a glass capillary viscometer and a rotary viscometer.
3.5 Liquid transport in food industry
In food industry, transport of liquid food from one processing equipment to another is
usually achieved by using pumps. Depending on velocity, internal viscous and inertial
forces, different types of flow characteristics are observed.
Flow patterns of liquids can be viewed in different ways, will consider flow of fluid along
a streamline which is a line everywhere tangent to the velocity vector at a given instant.
When bunched together into a stream tube, stream lines provide a good indication of the
instantaneous flow of a fluid as shown in fig. 3.12
38

Figure 3.12: a stream tube formed by a closed collection of streamlines
3.5.1 The Continuity Equation
Consider a fluid flowing in a pipeline as shown in the fig. 3.13. Suppose that in time
space t the fluid occupying the space XX has moved to the space YY.

Figure 3.13: Fluid flow through a pipe of varying cross-section. Cross-section areas of the two and are
different in order to prove that calculations to follow are applicable to these variations
Note that the amount of fluid in space YX is the same in the initial and final stage of the
experiment thus mass of fluid in space XY must equal mass fluid in space XY.
Therefore:
1
A
1
x
1
=
2
A
2
x
2
(3.6)
Dividing by time step t:
1
6x
1
6t
=
2
2
6x
2
6t

1
1
u
1
=
2
2
u
2
(3.7)
Where is the average velocity
39

The equation 3.7 is called equation of continuity. It can also be expressed in terms of
mass flow since:
A = (3.8)
For incompressible fluids the density remains constant thus 1

=
2
and we remain with
1
u
1
=
2
u
2
onJ u = I
(3.9)
Where is the volumetric rate
The volumetric rate is a product of the cross-section area A of the pipe and the fluid
velocity .
Example
The volumetric flow rate of beer flowing in a pipe is 1.8 l/s. the inside diameter of the
pipe is 3 cm. the density of beer is 1100 kg/m
3
. Calculate the average velocity of beer and
its mass flow rate in kg/s. what is the mass flow rate if another pipe with 1.5 cm is used,
and what is the velocity for the same volumetric flow rate?
Given:
Pipe diameter: 3 cm = 0.03 m
Volumetric flow rate: 1.8 l/s = 0.0018 m
3
/s
Density: 1100 kg/l
Solution:
Velocity is
=
u.uu18|m
3
s]
n u.uS
2
4
|m
2
]
= 2.SSms
Mass flow rate :
m = 11uu|kgm
3
]
n u.uS
2
4
|m
2
] 2.SS|ms]
= 1.98 kg/s
New velocity if the diameter is halved and the volumetric flow rate is kept
constant:
=
u.uu18|m
3
s]
n u.u1S
2
4
|m
2
]
= 1u.19 ms
Note that by halving the diameter of the pipe, the average velocity is increased
four times
40

3.5.2 Reynolds Number
In order to visualize the flow characteristics of a liquid in a pipe suppose that a dye is
injected in a liquid flowing in a pipe as shown in fig. 3.14

Figure 3.14: Laminar, transitional, and turbulent flow in a pipe
At low flow rates, the dye moves in a straight-line manner in the axial direction. As the
flow rate increases to some intermediate level, the dye begins to blur at some distance
away from the injection point. The blurring is caused by movement of some of the dye in
radial direction. At high flow rate, the dye becomes blurred immediately after injection.
The straight-line flow observed at low flow rates is called laminar flow; at intermediate
flow rates, the flow is called transitional flow; and the erratic flow obtained at higher
flow rates is called turbulent flow.
The flow characteristics for laminar flow are influenced by liquid properties, flow rate
and the dimensions of liquid solid interfaces. As the mass flow rate increases, the force of
momentum or inertia increase; but these forces are resisted by friction of viscous forces
within the flowing liquid. The opposing forces reach a certain balance, changes in the
flow characteristics occur. It has been proved that the inertial forces are a function of
liquid density , pipe diameter D and average fluid velocity . The viscous forces on the
other hand are a function of liquid viscosity.
A dimension less number called Reynolds number (N
RE
) is defined as the ratio of the
inertial to the viscous forces:
N
RL
=
nctuI ]occs
scous ]occs
N
RL
=
(3.10)
If instead of average velocity , mass flow rate is given, then:
N
RL
=
4
n
(3.11)
A Reynolds number is most useful in quantitatively describing the flow characteristics of
a fluid
For a N
RE
2100: the flow is laminar
For a 2100 N
RE
4000: the flow is transitional
41

For a N
RE
4000: the flow is turbulent.

Example
A 3 cm inside diameter pipe is being used to pump liquid food into a buffer tank. The
tank is 1.5 m diameter and 3 m high. The density of the liquid is 1040 kg/m
3
and
viscosity is 1600 10
-6
Pa s.
a. What is the minimum time to fill the tank with this liquid food if it is fl owing
under laminar conditions in the pipe?
b. What will be the maximum time to fill the tank if the flow in the pipe is turbulent
Given
Pipe diameter: 3 cm = 0.03 m
Tank height: 3 m
Tank diameter: 1.5 m
Density of liquid: 1040 kg/m3
Viscosity of liquid: 1600 10
-6
Pa s =1600 10
-6
kg/m s
Solution
Part a:
1. The maximum velocity under laminar flow is:
=
21uup
p
=
21uu 16uu 1u
-6
|kgm s]
1u4u |kgm
3
]
= u.1u8ms
Volumetric flow rate is:
I
=
n u.uS
2
|m
2
]
4
u.1u8|ms] = 7.6S 1u
-5
|m
3
s]
2. The volume of the tank is:
I =
n(Jiomctcr)
2
(cigt)
4
=
n 1.S
2
|m
2
] S|m]
4
= S.Sm
3

3. The minimum time to fill the tank:
Volume/volumetric flow rate = 5.3 [m
3
]/7.6310
-5
[m
3
/s]=6.9510
4
s= 19.29h
Part b:
4. Minimum velocity under turbulent flow conditions is:
=
4uuup
p
=
4uuu 16uu 1u
-6
|kgm s]
1u4u |kgm
3
]
= u.2uSms
The volumetric flow rate:
42

I
=
n u.uS
2
|m
2
]
4
u.2uS|ms] = 1.449 1u
-4
|m
3
s]
5. The maximum time to fill the tank: volume of tank/volumetric flow rate:
= 5.3 [m
3
]/1.44910
-4
[m
3
/s]=3.6610
4
s= 10.16h
3.5.3 Entrance region and fully developed flow
When a liquid enters a pipe, there is a certain initial length of the pipe, called the
entrance region, where the flow characteristics of the liquid are quite different from
those in the following length of pipe. As shown in Figure 3.15, immediately at the
entrance to the pipe, the liquid has a uniform velocity profile, identified by the same
length of arrows in the diagram. As it begins to move into the pipe, the liquid next to the
inside wall of the pipe is held back by friction between the liquid and the wall surface.
The velocity of the liquid is zero at the wall and increases toward the central axis of the
pipe. Therefore, the boundary (or the wall surface) begins to influence the velocity profile.

Figure 3.15: V elocity profi le in a fl uid fl owing in a pipe.
As shown in Figure 3.15, in the entrance region, the boundary layer develops from
location X to Y. At location Y, the effect of the boundary layer on the velocity profile
extends all the way to the central axis. The cross-sectional velocity profile at Y is
parabolic in shape (as we will mathematically derive in the following section). From X to
Y, the region is called the entrance region, and the liquid flow in the region beyond Y is
commonly referred to as fully developed flow.
Using dimensional analysis, it has been shown that the dimensionless entrance length,
L
e
/D, is a function of the Reynolds number.
Thus for laminar flow:
L
e
/D=0.06N
RE
(3.12)
43

And for turbulent flow:
L
e
/D=4.4(N
RE
)
1/6
(3.13)
3.5.4 Velocity profile in a liquid flowing under fully developed flow
conditions
Consider fluid flow taking place under steady and fully developed conditions in a
constant-diameter pipe. Forces due to pressure and gravity cause the fluid flow in the
fully developed region. In the case of a horizontal pipe, gravitational effects are
negligible. Therefore, for the purpose of this analysis, we will consider only forces due to
pressure. When a viscous liquid (a liquid with viscosity greater than zero) flows in a pipe,
the viscous forces within the liquid oppose the pressure forces. Application of pressure is
therefore necessary for flow to occur, as it overcomes the viscous forces opposing the
flow.
Furthermore, the flow takes place without accelerating; the velocity profile within the
fully developed flow region does not change with location along the x-axis. For the flow
to be steady, a balance must exist between the pressure and viscous forces in the liquid.
We will conduct a force balance to analyze this case.

Figure 3.16: Force balance for a liquid flowing in a pipe
Using Newtons second law of motion, we can describe forces acting on the small
cylindrical element of liquid of radius r and length L as shown in fig. 3.16. The pipes
diameter is D. From the location A-B at time t, the element has moved to A-B after a
small lapse of time t. The ends of AB are shown distorted, indicating that under fully
developed flow conditions, velocity at the central axis is maximum and deceases with
increasing r.
44

Since the pipe is horizontal, we neglect the gravitational forces. The pressure varies from
one axial location to another, but remains constant along any vertical cross-section of the
pipe. Lets assume that pressure forces at the faces A and B are respectively P
A
and P
B

and the decrease in pressure is P
P= P
A
- P
B

The pressure forces acting on the element are
at location A: =PA i
2

at location B: (PA-P) i
2

On the circumferential area, 2rL viscous forces opposing pressure forces = 2 iL
Where is the shear stress
According to Newtons second law, Fx = max, but under fully developed flow conditions,
ax=u, thus Fx=u. Thus, all forces acting on the element must balance.
PA i
2
- (PA-P) i
2
- 2iL=u
Or simplifying,
AP
L
=
2c
(3.14)
For Newtonian liquids, the shear stress is related to viscosity. For pipe flow, we rewrite
this equation in cylindrical coordinates as
= p
du
d
(3.15)
Note that uuui is negative in case of a pipe flow, the velocity decreasing with increasing
radial distance, r, as seen in Figure 3.16. Therefore, we have introduced a negative sign in
Equation (3.15) so that we obtain a positive value for shear stress, . Substituting
Equation (3.14) in Equation (3.15),
du
d
=
AP
2L
r (3.16)
integrating,
]Ju =
AP
2L
]rJr (3.17)
45

Or
u(r) =
AP
4L
r
2
+ C
1
(3.18)
Where C
1
is a constant
For a viscous fluid flowing in a pipe, u=u at i=R; therefore
C
1
=
AP
4L
R
2
(3.19)
Therefore, the velocity profile for a laminar, fully developed flow, in a horizontal pipe, is:
u(r) =
AP
4L
(R
2
r
2
) (3.20)
This is equal to
u(r) =
APR
2
4L
_1
2
_ (3.21)
The equation (3.21) is an equation of a parabola. Therefore, for a fully developed flow,
we obtain a parabolic velocity profile. Furthermore, substituting r=0, the maximum
velocity umax is obtained at the pipe center. It is equal to
u
mux
=
APR
2
4L
(3.22)
Next, let us determine the volumetric flow rate by integrating the velocity profile across
the cross-section of the pipe. First, we will examine a small ring of thickness dr with an
area dA, where uA=2iui, as shown in Figure 3.17. The velocity, u, in this thin annular
ring is assumed to be constant.
46

Figure 3.17: small ring of thickness dr
Then the volumetric flow rate through the annular ring,
ring
is:
I
ng
= u(r)J = u(r)2nrJr (3.23)
The volumetric flow rate for the entire pipe cross-section is obtained by integration as
follows:
I
= ] u(r)J = ] u(r)2nrJr
=R
=0
(3.24)
or, substituting Equation (3.21) in (3.4),
I
=
2nAPR
2
4L
] _1
2
_
R
0
rJr (3.25)
This is equal to:
I
=
nR
4
AP
L
(3.26)
The equation above is called Poiseuilles Law. The mean velocity, , is defined as the
volumetric flow rate divided by the cross-sectional area of the pipe, R
2
, or
=
v
nR
2
=
APR
2
L
(3.27)
If we divide the equation of maximum velocity by the equation of average velocity we
obtain:
47

u
mcx
= u.S (3.28)
From Equation (3.28), we observe that the average velocity is half the maximum velocity
for fully developed laminar flow conditions. Furthermore, the radius (or diameter) of the
pipe has a dramatic influence on the flow rate, as seen in Equation (3.26). Doubling the
diameter increases the volumetric flow rate 16-fold.
For turbulent flow in the fully developed region, the mathematical analysis necessary to
obtain a velocity profile is complex. Therefore, the following empirical expression is
generally used.
()
u
mcx
= 1
1
(3.29)
Where j is a function of the Reynolds number; for most applications j=7 is recommended.
Under turbulent conditions, the velocity profile may be obtained from
(r) = u
mux
1
1
(3.30)
Equation (3.30) is also called the Blassius 1/7
th
power law.
A volumetric flow rate under turbulent conditions may be obtained in a similar manner as
for laminar conditions. Substituting Equation (3.29) in Equation (3.24)
I
= ] u
mux
1
1
2nrJr
=R
=0
(3.31)
Integrating the equation (3.31)
I
= 2nu
mux
2
(+1)(2+1)
(3.32)
A relationship between average and maximum velocity may be obtained by substituting
Equation (3.27) in Equation (3.32) and we get,
u
mcx
=
2
2
(+1)(2+1)
(3.33)
Substituting the value 7 for j in Equation (3.33),
u
mcx
= u.82 (3.34)
48

Thus, in the case of turbulent flow, the average velocity is 82% of the maximum velocity.
The maximum velocity occurs at the central axis of the pipe.
3.5.5 Forces Due to Friction
The forces that must be overcome in order to pump a liquid through a pipe derive from
several sources. As seen previously, viscous forces are important in liquid flow; these
forces occur due to the movement of one layer over another. The other important forces
are due to friction between the liquid and the surface of the wall of a pipe. When a fluid
flows through a pipe, some of its mechanical energy is dissipated due to friction. It is
common to refer to this dissipated energy as a frictional energy loss.
The friction forces vary with conditions such as flow rates, as described with a Reynolds
number, and surface roughness. The influence of the friction forces is expressed in the
form of a friction factor f. The following mathematical development is for laminar flow
conditions.
The friction factor is the ratio between the shear stress at the wall,
w
, to the kinetic
energy of the fluid per unit volume.
=
c
w
2
2
(3.35)
As seen earlier, the shear stress at the wall is
w
=
AP
4L
(3.36)
Substituting the equation (3.36) into equation (3.35)
=
AP
2L
2
(3.37)
By rearranging terms in Equation (3.27), the pressure drop in fully developed laminar
flow conditions is determined as
=
APR
2
L
P =
32L
2
(3.38)
Substituting P value in the friction factor equation, we get:
=
32L
2L
2
2
=
16
(3.39)
Where f is called the Fanning friction factor; Note that many civil and mechanical
engineering textbooks refer to a different friction factor, called Darcy 3 friction factor,
49

with the same symbol, f. The Darcy friction factor is four times the Fanning friction
factor. In chemical engineering literature, the Fanning friction factor is used more
commonly, thats why I preferred it over the Darcy friction factor.
The previous calculations leading to Fanning friction factor are for laminar flow
conditions only. In cases of transitional and turbulent flow conditions, the mathematical
derivations become highly complex. For situations involving flow conditions other than
laminar flow, we will use a graphical chart that presents friction factor as a function of
the Reynolds number. This chart, called a Moody chart, is shown in Figure 3.18. The
Moody chart presents the friction factor as a function of the Reynolds number for various
magnitudes of relative roughness of the pipes. At low N
RE
(<2100) the curve is described
by the equation (3.39) and is not influenced by surface roughness . In the transition from
laminar to turbulent flow or critical region, either set of curve can be used. Most often the
friction factor is selected for turbulent flow since it ensures that the pressure loss due to
friction will not be underestimated. From the Moody chart there is always a certain
friction loss when a fluid flows in a pipe. The following equation is recommended for
calculating the Fanning friction factor for a turbulent region:
1
]
S.6 log _
6.9
N
RE
+
s
3.
1.11
_ (3.40)

Figure 3.18: The Moody diagram for the Fanning friction factor. Equivalent roughness for new pipes ( in
meters)
Cast iron: = 259x10
-6
, Drawn tubing: =1.5235x10
-6
, Galvanized iron: =152x10
-6
, Steel or wrought iron:
=45.7x10
-6

50

Examples:
1. A fluid is flowing under laminar conditions in a cylindrical pipe of 2 cm diameter.
The pressure drop P is 330 Pa, the viscosity of the fluid is 5 Pa s, and the pipe is 300
cm long. Calculate the mean velocity and velocity of fluid at different radial locations
in the pipe.
Given:
Diameter of the pipe D = 2 cm
Length of the pipe L = 300 cm
Pressure drop P = 330 Pa
Viscosity = 5 Pa s
Solution:
u(r) =
AP
4L
(R
2
r
2
)
The velocity is calculated at r = 0, 0.25, 0.5, 0.75, and 1 cm
r=0 cm u= 0.055 cm/s
r=0.25 cm u= 0.0516 cm/s
r=0.5 cm u= 0.413 cm/s
r=0.75 cm u= 0.0241 cm/s
r=1 cm u= 0 cm
The mean velocity is calculated as 0.0275 cm/s; this value is half of the
maximum velocity.
2. Water at 30
o
C is being pumped through a 30 m section of 2.5 cm diameter steel pipe
at a mass flow rate of 2 kg/s. Compute the pressure loss due to friction in the pipe
section.
Given:
Density = 995.7 kg/m3
Viscosity = 792.377x10-6 Pa s
Length of the pipe L= 30 m
Diameter of the pipe D= 2.5 cm = 0.025 m
Mass flow rate = 2kg/s
Solution:
1. Compute the Mean velocity:
=
2|kgs]
(995. kgm
3
)|n(0.025 m)
2
4]
= 4.u92 ms
2. Compute the Reynolds number:
51

N
RL
=
(995. kgm
3
)(0.025 m)(4.092 ms)
(92.310
-6
Pu s)
= 28,SSu
3. Using the given information and the fig. 3.13, relative roughness is:
e =
45.10
-6
m
0.025 m
= 1.8281u
-3

4. The friction factor f is obtained from the fig. 3.18:
f= 0.006
5. =
AP
2L
2

AP
= 2()
L
2
= 2(u.uu6)
(4.092 ms)
2
(30 m)
0.025 m
= 241.12 m
2
s
2

Note that 1 J = 1 kg m
2
/s
2

Thus:
AP
= 241.12 m
2
s
2
= 241.12 [kg
P/ represents the energy consumed due to friction on a per-unit-mass basis
6. The pressure loss is calculated as
P=(241.12 }kg)(99S.7 kgm
S
)= 24u.u8 kg(ms
2
)
P= 24u.u8 kPa
Heat transfer in food processing
52

Chapter IV Heat Transfer in Food Processing
4.1 Introduction
The most common processes found in a food processing plant involve heating and
cooling of foods. In the modern industrialized food industry, we commonly find unit
operations such as refrigeration, freezing, thermal sterilization, drying, and evaporation.
The study of heat transfer is important because it provides a basis for understanding how
these food processes operate.
4.2 Systems for heating and cooling food products
In a food processing plant, heating and cooling of foods is conducted in equipment called
heat exchangers. The fig. 4.1 shows the classification of different heat exchangers. There
are contact heat exchanger and non contact heat exchangers. As the name implies, in
noncontact-type heat exchangers, the product and heating or cooling medium are kept
physically separated, usually by a thin wall. On the other hand, in contact-type heat
exchangers, there is direct physical contact between the product and the heating or
cooling streams. We will analyze them, see the mechanisms of heat transfer and then see
the application of heat transfer in food industry

Figure 4.1: Classification of commonly used heat exchangers
4.2.1 Plate Heat Exchanger
The plate heat exchanger invented more than 70 years ago has found wide application in
the dairy and food beverage industry. A schematic of a plate heat exchanger is shown in
Figure 4.2. This heat exchanger consists of a series of parallel, closely spaced stainless-
steel plates pressed in a frame. Gaskets, made of natural or synthetic rubber, seal the plate
edges and ports to prevent intermixing of liquids. These gaskets help to direct the heating
or cooling and the product streams into the respective alternate gaps. The direction of the
product stream versus the heating/cooling stream can be either parallel flow (same
direction) or counter flow (opposite direction) to each other. The plates used in the plate
53

heat exchanger are constructed from stainless steel: Special patterns are pressed on the
plates to cause increased turbulence in the product stream, thus achieving better heat
transfer. Plate heat exchangers are suitable for low-viscosity (< 5 Pa s) liquid foods. If
suspended solids are present, the equivalent diameter of the particulates should be less
than 0.3 cm.

Figure 4.2: Plate heat exchanger: the first picture shows the outer view; the second one shows the fluid
flow between the plates and the third one shows individual plates
Plate heat exchangers offer the following advantages:
The maintenance of these heat exchangers is simple, and they can be easily and
quickly dismantled for product surface inspection.
The plate heat exchangers have a sanitary design for food applications.
Their capacity can easily be increased by adding more plates to the frame.
With plate heat exchangers, we can heat or cool product to within 1
o
C of the adjacent
media temperature, with less capital investment than other noncontact-type heat
exchangers.
Plate heat exchangers offer opportunities for energy conservation by regeneration.
4.2.2 Tubular Heat Exchanger
The simplest noncontact-type heat exchanger is a double-pipe heat exchanger, consisting
of a pipe located concentrically inside another pipe. The two fluid streams flow in the
annular space and in the inner pipe, respectively. The streams may flow in the same
direction (parallel flow) or in the opposite direction (counter flow). Figure 4.3 is a
schematic diagram of a counter flow double-pipe heat exchanger. A slight variation of a
double-pipe heat exchanger is a triple-tube heat exchanger. In this type of heat exchanger,
product flows in the inner annular space, whereas the heating/cooling medium flows in
the inner tube and outer annular space. The innermost tube may contain specially
designed obstructions to create turbulence and better heat transfer.
54

Figure 4.3: Schematic illustration of a tubular heat exchanger showing a double and a triple tube heat
exchanges
Another common type of heat exchanger used in the food industry is a shell-and-tube
heat exchanger for such applications as heating liquid foods in evaporation systems. As
shown in Figure 4.4, one of the fluid streams flows inside the tube while the other fluid
stream is pumped over the tubes through the shell. By maintaining the fluid stream in the
shell side to flow over the tubes, rather than parallel to the tubes, we can achieve higher
rates of heat transfer.

Figure 4.4: A shell-and-tube heat exchanger
55

4.2.3 Scraped-Surface Heat Exchanger
In conventional types of tubular heat exchangers, heat transfer to a fluid stream is
affected by hydraulic drag and heat resistance due to film buildup or fouling on the tube
wall. This heat resistance can be minimized if the inside surface of the tube wall is
scraped continuously by some mechanical means. The scraping action allows rapid heat
transfer to a relatively small product volume. A scraped-surface heat exchanger, used in
food processing, is shown schematically in Figure 4.5. The inside rotor contains blades
that are covered with plastic laminate or molded plastic. The cylinder containing the
product and the rotor is enclosed in an outside jacket. The heating/cooling medium is
supplied to this outside jacket.

Figure 4.5: A scraped-surface heat exchanger with a cutaway section illustrating various components.
4.2.4 Steam-Infusion Heat Exchanger
A steam-infusion heat exchanger provides a direct contact between steam and the product.
Product in liquid state is pumped to the top of the heat exchanger and then allowed to
flow in thin sheets in the heating chamber. The viscosity of the liquid determines the size
of the spreaders. High rates of heat transfer are achieved when steam contacts tiny
droplets of the food. The temperature of the product rises very rapidly due to steam
condensation. The heated products with condensed steam are released from the chamber
at the bottom. A specific amount of liquid is retained in the bottom of the chamber to
achieve desired cooking.
The water added to the product due to steam condensation is sometimes desirable,
particularly if the overall process requires addition of water. Otherwise, the added water
56

of condensation can beflashed off by pumping the heated liquid into a vacuum
cooling system. The amount of water added due to condensation can be computed by
measuring the temperature of the product fed to the heat exchanger and the temperature
of the product discharged from the vacuum cooler.
This type of heat exchanger has applications in cooking and/or sterilizing a wide variety
of products, such as concentrated soups, chocolate, processed cheese, ice cream mixes,
puddings, fruit pie fillings, and milk.

57

Figure 4.6: A steam-infusion heat exchanger
4.3 Thermal properties of foods
4.3.1 Specific heat
It is the quantity of heat that is gained or lost by a unit mass of product to accomplish a
unit change in temperature without change of state.
C
p
=
m(A1)
(4.1)
Where Q is heat gained or lost (kJ), m is mass (kg), T is temperature change in the
material (C or K), and C
p
is specific heat (kJ/[kg C]).
Specific heat is an essential part of the thermal analysis of food processing or of the
equipment used in heating or cooling of foods. For processes that involve change of state
like freezing or thawing, apparent specific heat is used which is the specific heat of the
product plus the heat necessary for change of state.
4.3.2 Thermal Conductivity
In quantitative terms, this property gives the amount of heat that will be conducted per
unit time through a thickness of the material if a unit temperature gradient exists across
that thickness.
In SI units, thermal conductivity k is W/ (m
o
C)
In commonly found materials thermal conductivity varies a lot. For example:
Metals: 50-400 W/ (m
o
C)
Alloys: 10-120 W/ (m
o
C)
Water: 0.597 W/ (m
o
C)
Air: 0.0521 W/ (m
o
C)
Insulating materials: 0.035-0.173 W/ (m
o
C)
Most high-moisture foods have thermal conductivity values closer to that of water. On
the other hand, the thermal conductivity of dried, porous foods is influenced by the
presence of air with its low value.
4.3.3 Thermal diffusivity
Thermal diffusivity, a ratio involving thermal conductivity, density, and specific heat, is
given as,
58

o =
k
Cp
(4.2)
The units of thermal diffusivity are m
2
/s
Thermal diffusivity may be calculated by substituting values of thermal conductivity,
density, and specific heat in Equation (4.2)
The above properties play an important role in heat transfer.
4.4 Modes of heat transfer
Heat energy is simply the sensible and latent forms of internal energy. Heat content of an
object is determined by its mass, specific heat and temperature.
= mCpI (4.3)
Although determining heat content is an important calculation, the knowledge of how
heat may transfer from one object to another or within an object is of even greater
practical value.
The common heat transfer modes are conduction, convection and radiation
4.4.1 Conductive Heat Transfer
Conduction is the mode of heat transfer in which the transfer of energy takes place at a
molecular level. There are two commonly accepted theories:
According to one theory, as molecules of a solid material attain additional thermal
energy, they become more energetic and vibrate with increased amplitude of
vibration while confined in their lattice. These vibrations are transmitted from one
molecule to another without actual translatory motion of the molecules.
The second theory states that conduction occurs at molecular level due to the drift
of free electrons. These free electrons are prevalent in metals, and they carry
thermal and electric energy.
From everyday experience, we know that heat transfer from outside to inside through
wall of a chamber depends on:
The surface area of the wall
The thermal properties of the construction materials
Wall thickness
Temperature difference
59

Figure 4.7: Conductive heat flow in a wall
The rate of heat transfer through the wall may be expressed as
q
(wuII su]ucc)(tcmpcutuc d]]ccncc)
wuII thckncss
(4.4)
Or
q
x
Adt
dx
(4.5)
By introducing a constant of proportionality:
q
x
= k
Adt
dx
(4.6)
Where q
x
is the rate of heat flow in the direction of heat transfer by conduction (W); k is
thermal conductivity
(W/[mC]); A is area through which heat flows (m
2
); T is temperature (C); and x is
length (m). The equation above is called Fouriers law. As heat flows from high
temperature to low temperature, the gradient dT/dx is negative, because temperature
decreases with increasing values of x.
4.4.2 Convective Heat Transfer
When a fluid comes into contact with a solid body such as the surface of a wall, heat
exchange will occur between the solid and the fluid whenever there is a temperature
difference between the two. During heating or cooling of gases and liquids, the fluid
60

stream exchanges heat with solid surfaces by convection. The magnitude of the fluid
motion plays an important role in convection heat transfer.

Figure 4.7: Convective heat flow from the surface of a fl at plate
Depending on whether the flow of the fluid is artificially induced or natural, there are two
types of convective heat transfer: forced convection and free (also called natural)
convection
Consider heat transfer from a heated flat plate, PQRS, exposed to a flowing fluid, as
shown in Figure 4.8. The temperature of the surface is T
s
and temperature of the fluid is
t
. Because of the viscous properties of the fluid, a velocity profile is set up within the fl
owing fluid, with the fluid velocity decreasing to zero at the solid surface. The rate of
heat transfer from the solid to the fluid is proportional to the surface area A and the
difference in temperature between the t
s
and t
or
q (Is I) q = (Is I) (4.7)
Where h is the convective heat transfer coefficient sometimes called surface heat-transfer
coefficient.
4.4.3 Radiation Heat Transfer
Radiation heat transfer occurs between two surfaces by the emission and later absorption
of electromagnetic waves (or photons). In contrast to conduction and convection,
radiation requires no physical medium for its propagationit can even occur in a perfect
vacuum, moving at the speed of light, as we experience everyday solar radiation. Liquids
are strong absorbers of radiation. Gases are transparent to radiation, except that some
gases absorb radiation of a particular wavelength (for example, ozone absorbs ultraviolet
radiation). Solids are opaque to thermal radiation. The exception to this is for microwaves
and radio frequency radiation

61

4.5 Applications of heat transfer in food industry
The principles of heat transfer are widely used in food processing in many items of
equipment. As we saw before heat transfer in food industry is done using heat exchangers.
Deferent processes need heat transfer:
4.5.1 Sterilization
The object of sterilization is to destroy all microorganisms, that is, bacteria, yeasts and
moulds, in the food material to prevent decomposition of the food, which makes it
unattractive or inedible. Also, sterilization prevents any pathogenic (disease-producing)
organisms from surviving and being eaten with the food. Some microorganisms are heat
resistant than others, thus the heat required to kill them varies. Generally foodstuff are
treated at 121
o
C for efficiently sterilize them.
Studies of the microorganisms that occur in foods, have led to the selection of certain
types of bacteria as indicator organisms. A frequently used indicator organism is
Clostridium botulinum. This particular organism is a very important food poisoning
organism as it produces a deadly toxin and also its spores are amongst the most heat
resistant. Thus, a heat process that cant kill this microorganism is considered as
inefficient. A combination of heat and time is used to inactivate the microorganisms
efficiently
4.5.2 Pasteurization
Pasteurization is a heat treatment applied to foods, which is less drastic than sterilization,
but which is sufficient to inactivate particular disease-producing organisms of importance
in a specific foodstuff. The most common application is pasteurization of liquid milk.
4.5.3 Refrigeration: chilling and freezing
Rates of decay and of deterioration in foodstuffs depend on temperature. At suitable low
temperatures, changes in the food can be reduced to economically acceptable levels. The
growth and metabolism of micro-organisms is slowed down and if the temperature is low
enough, growth of all microorganisms virtually ceases. To reach temperatures low
enough for deterioration virtually to cease, most of the water in the food must be frozen.
The effect of chilling is only to slow down deterioration changes.
Chilling of foods is a process by which their temperature is reduced to the desired
holding temperature just above the freezing point of food, usually in the region of
-2 to 2C. Many commercial chillers operate at higher temperatures, up to 10-
12C. The effect of chilling is only to slow down deterioration changes and the
reactions are temperature dependent. So the time and temperature of holding the
chilled food determine the storage life of the food. Rates of chilling are governed
62

by the laws of heat transfer which have been described in previous sections. It is
an example of unsteady-state heat transfer by convection to the surface of the
food and by conduction within the food itself. The medium of heat exchange is
generally air, which extracts heat from the food and then gives it up to refrigerant.
The rate of heat transfer gets bigger with increase of air velocity.
Any process below that is freezing. Water makes up a substantial proportion of
almost all foodstuffs and so freezing has a marked physical effect on the food. In
the freezing process, added to chilling is the removal of the latent heat of freezing.
This latent heat has to be removed from any water that is present. Since the latent
heat of freezing of water is 335 kJ/kg, this represents the most substantial thermal
quantity entering into the process. There may be other latent heats, for example
the heats of solidification of fats which may be present, and heats of solution of
salts, but these are of smaller magnitude than the latent heat of freezing of water.

Evaporation
63

Chapter V Evaporation
5. 1 Introduction
Historically, the most important unit operation in concentrating liquid foods has been
evaporation. Solvent (usually water) is removed from the liquid food by boiling to
concentrate the food solids to desired concentration. The requirements for an optimal
evaporation include:
Adequate heat transfer
Efficiency vapor liquid separation
Efficient energy use
Proper product treatment
Pressure at which the evaporation take place
Some examples of use of evaporation include:
concentration of fruit juices,
evaporation of fluid milk products,
refining sugar from beets or canes, etc.
5.2 Evaporation in food processes
5.2.1 Boiling point elevation:
The presence of solute alters the vapor pressure of the solution and thus affects the
equilibrium boiling point. Salts and, to a lesser extent, sugars are mainly responsible for
increasing the boiling point of foods. Boiling point elevation is determined in several
ways one of which is the use of Dhring rule. This rule states that the boiling point of a
solution is a linear function of the boiling point of pure water at the same pressure. The
linear relationship does not hold over a wide range of temperatures, but over moderate
temperature ranges, it is quite acceptable. Fig. 5.1 shows Dhring lines for a sodium
chloridewater system
Evaporation
64

Figure 5.1: Dhring lines illustrating the influence of solute concentrations on boiling point elevation of
NaCl
5.2.2 Loss of volatiles
Most of foods contain flavor and aroma compounds that will be lost from the product as
the water is evaporated. This is extremely important for the quality of final product. The
volatiles must be put back in the product.
5.2.3 Thermal sensitivity of foods:
Some food components undergo thermally induced modifications during processing.
Some negative effects include: denaturation of proteins, production of off colors and off
flavors, vitamin degradation, etc. During evaporation, this modifications have to be
minimized and design techniques have been developed for minimization of these effects
during evaporation:
Use of low pressure, low temperature evaporation
Minimization of the time under high temperature
5.2.4 Physical and chemical properties of foods
Several properties of foods must be accounted for designing an efficient evaporation
system
Evaporation
65

Viscosity: sugars, starches, proteins at high concentration
Changes in density, thermal conductivity and heat capacity limit the heat transfer
5.2.4 Fouling during heat transfer:
Heat induced reactions in the food can cause formation of compounds that deposit on the
heat transfer surface. These fouling layers limit the rate of heat transfer and reduce the
capacity of the evaporator. Examples of foods that can cause fouling include milk.
5.2.5 Cleaning and sanitation:
Periodically, the evaporator must be shutdown and cleaned. The cleaning cycle depends
on the rate of fouling.
5.3 Evaporator components
5.3.1 Heat exchange device (calandria):
Consists of a tube bundle inside which the product to be concentrated is evenly
distributed as a thin film. Steam is condensed outside the tubes causing vaporization of
the film of products inside the tubes.
5.3.2 Distribution device:
The wetting rate of an evaporator is the proportion of product feed to the heat transfer
surface area. The distribution device must deliver the product to the tube bundle in an
appropriate manner. The feed must be distributed evenly in different tubes.
5.3.3 Vapor liquid separator:
There are different types like gravity separator, baffle separator, centrifugal separator.
5.3.4 Condenser:
Residual vapors that will not be further utilized in the evaporation must be removed and
condensed. A cooling medium is required and usually water is used but sometimes air or
another refrigerant may be used. Condensation may be done in heat exchangers or by
direct contact between the vapor and the cooling medium.
5.3.5 Vacuum production:
Vacuum is needed to lower the boiling point. This is partially accomplished by removal
of condenser fluid, but usually a mechanical pump is used.
5.3.6 Pre heaters:
Evaporation
66

To ensure maximal efficiency in the evaporator, the feed needs to be preheated so that it
enters the evaporator at or near the boiling point.
5.4 Single effect evaporator
The typical evaporator is made up of three functional sections: the heat exchanger, the
evaporating section, where the liquid boils and evaporates, and the separator in which the
vapor leaves the liquid and passes off to the condenser or to other equipment. In many
evaporators, all three sections are contained in a single vertical cylinder. In the centre of
the cylinder there is a steam heating section, with pipes passing through it in which the
evaporating liquors rise. At the top of the cylinder, there are baffles, which allow the
vapors to escape but check liquid droplets that may accompany the vapors from the liquid
surface. Fig 5.2 shows a typical diagram of single effect evaporator

Figure 5.2: Schematic diagram of a single-effect evaporator.
5.5 Multiple effect evaporation
This design is used in order to reduce steam consumption. Vapors are used as primary
steam in a subsequent evaporation.
Evaporation
67

For these vapors to provide a temperature difference, the operation pressure of
subsequent evaporator is reduced resulting in a continually decreasing pressure and
subsequent boiling temperature through this type of design. The great the number of
effects, the greater steam economy but also higher the expenses of installation.

Figure 5.3: A two-effect evaporator with feed preheating, below is a tree effects evaporator
5.6 Thermal vapor recompression evaporator
In this process, high pressure steam passing through a nozzle draws vapors from the
evaporator chamber. The resulting steam has higher energy content than the evaporator
vapors and is then fed back into the steam chest to supply the energy for evaporation
Evaporation
68

Dehydration
69

Chapter VI Dehydration
6.1 Introduction
Drying is one of the oldest methods of preserving food. Dried foods can be stored for
long periods without deterioration occurring. The principal reasons for this are that the
microorganisms which cause food spoilage and decay are unable to grow and multiply in
the absence of sufficient water and many of the enzymes which promote undesired
changes in the chemical composition of the food cannot function without water.
Preservation is the main purpose of drying, but in some cases drying is done in
conjunction with other processes.
For example in the baking of bread, application of heat expands gases, changes the
structure of the protein and starch and dries the loaf.
6.2 Heat and Mass Transfer
The removal of moisture from a food product involves simultaneous heat and mass
transfer. Heat transfer occurs. Within the product structure and is related to the
temperature gradient between the product surface and the water surface at some location
within the product. As temperature rises, vapor is transported from the water inside the
product to the surface of the product.
The heat and the mass transfer within the product structure occurs at the molecular level,
with heat transfer being limited by thermal conductivity of the product structure, whereas
mass transfer is proportional to the molecular diffusion of water vapor in air. At the
product surface, simultaneous heat and mass transfer occurs but is controlled by
convective processes.
6.3 Psychrometry
The psycrometrics are the study of the properties of gas-vapor mixtures. The mixture
most commonly encountered in food processing is air-water vapor.
Absolute humidity or specific humidity H, is the weight of water present in the water
air mixture per unit weight of dry air.
=
M
W
P
v
M
A
(P-P
v
)
(6.1)
Where: M
a
is molecular weight of air
M
w
is molar weight of water
P
v
is partial pressure of water vapor in the system
P is total pressure of the system
Dehydration
70

Saturation humidity, H
s
, is the absolute humidity of saturated air. In saturated air, the
water vapor pressure equals the vapor pressure of water at air temperature.
s
=
M
W
P
W
M
A
(P-P
W
)
(6.2)
Where P
w
is vapor pressure of water at air temperature
Percentage absolute humidity H
p
is the ratio of the absolute humidity to the saturation
humidity at a given temperature.
P
= 1uu
P
v
(P-P
v
)
P
W
(P-P
W
)
(6.3)
It is expressed in terms of percentage.
Percentage relative humidity H
R
is the ratio of the partial pressure of water vapor to
vapor pressure of water at a given temperature.
R
= 1uu
P
v
P
W
(6.4)
Dew point or saturation temperature is the temperature at which a give air water vapor
mixture becomes saturated, if cooled at constant humidity.
The humid heat C
H
the amount of heat needed to increase by 1C the temperature of 1
kg of dry air plus the quantity of water it contains.
C
H
= C
A
+ C
v
(6.5)
Where C
A
= specific heat of dry air
C
v
= specific heat of water vapor
Temperature volume V
H
is the volume of a mass of mixture containing a unit of mass
of dry air at one atmosphere pressure and at a given temperature.
I
H
=
22.4
23
(0 + 27S)
1
M
A
+
H
M
W
(6.6)
Where is the temperature of the mixture
When H=0, V
H
= specific volume of dry air, H=H
s
V
H
= specific volume of saturated air.
Adiabatic saturation temperature: if a stream of moist air passes concurrently through
water sprays at temperature
s
under adiabatic conditions, so that air leave the system in
equilibrium with the water and at temperature
s
, the temperature
s
is said to be the
Dehydration
71

adiabatic saturation temperature. The line relating the temperature and humidity of the
air during the adiabatic cooling is known as adiabatic cooling (or saturation) line. The
equation of this line is
s
= (C
H
s
)(00
s
) (6.7)
Wet bulb temperature,
w
, is the steady state (dynamic equilibrium) temperature
attained by a small quantity of water evaporating under adiabatic condition in an air
stream. Wet bulb temperature is measured by means of temperature sensing element
covered by a wick which is maintained saturated with water.
6.4 Psycrometric chart
The properties of air water vapor mixtures may be displayed on a chart at one atmosphere
pressure. This chart shows the humidity as a function of temperature at varying degrees
of saturation. This chart is very useful in determining the change in temperature and
humidity. From the psychrometric charts different properties that we have seen earlier
can be determined.

Figure 6.1: Diagram showing the use of a psychometric chart for determining properties of air-water
mixtures
Dehydration
72

The fig. 6.1 shows the way psychrometric chart is used. The figure A shows humidity,
the figure B is for wet bulb temperature, C is for percentage relative humidity and the
figure D shows how humidity and dew point are determined from wet and dry bulb
temperature.
The psycrometric chart is useful when heating or cooling air, mixing of air, drying.
6.5 Stages of drying
During drying of wet solid in heated air, the air supplies the necessary sensible heat
which is converted to latent heat for vaporization of the moisture and also acts as carrier
gas for removal of the vapor from the vicinity of the evaporating surface. A number of
stages are to be considered during drying process:
1. The first stage is called the settling down period during which the solid conditions
come into equilibrium with the drying air. It is often a negligible fraction
2. Constant rate period of drying is a period during which the solid surface remains
saturated with water. This is due to the fact that the movement of water within the
solid to the surface takes place at the same rate as the evaporation from the
surface.
3. Then comes the stage when the surface starts to dry out as the drying process
proceeds. This stage is called the falling rate period. During this stage the
temperature at the surface increases
6.6 Types of driers
Cabinet dryers:
These types of drying systems use trays or similar product holders to expose the product
to heated air in an enclosed space. Air movement over the product surface is at relatively
high velocities to ensure that heat and mass transfer will proceed in an efficient manner.
Tunnel Dryers:
In this type of design, products move on trays that circulate in a tunnel in which air is
blown at high velocity either in the same direction as the product or in opposite direction.
Fluidized-Bed Drying:
In this system, the product pieces are suspended in the heated air throughout the time
required for drying.
Spray drying:
Dehydration
73

Spray drying is a process where a liquid droplet is rapidly dried as it comes in contact
with a stream of hot air. The small size of the liquid droplets allows very rapid drying and
the residence time of the material inside the spray drier is in the order of seconds. The
dried material is separated from air in a cyclone separator. The dried material is
continuously withdrawn and cooled.

Figure 6.2: Schematic illustration of a spray-drying system and a pressure nozzle
Freeze-Drying:
Freeze-drying is accomplished by reducing the product temperature so that most of the
product moisture is in a solid state, and by decreasing the pressure around the product,
sublimation of ice can be achieved. When product quality is an important factor for
consumer acceptance, freeze-drying provides an alternative approach for moisture
removal.
Sublimation is the direct transition from solid state to gaseous state without melting.
Sublimation occurs at a definite range of temperatures and pressures, depending on the
substance in question. The phase diagram of pure water (Figure 6.3) indicates that
sublimation of water ice can occur only if the vapor pressure and temperature are below
those of the triple point of water, i.e. below 611.73 Pa and 0.01C respectively.
Theoretically, freeze drying should be possible at atmospheric pressure, provided that the
partial pressure of water vapor is very low, i.e. the air is very dry. Atmospheric freeze-
drying occurs in nature, for example when snow disappears without melting in cold, dry
weather. In practice, however, freeze drying is carried out at very low total pressure
(typically 10 to 50 Pa).
Dehydration
74

The advantages of the freeze-drying process are superior product quality resulting from
low temperature during sublimation and the maintenance of product structure. These
advantages are balanced against the energy-intensive aspects of the product freezing and
vacuum requirements.

Figure 6.3: Phase diagram of water showing conditions for sublimation

75

Chapter VII Mechanical separation
7.1 Filtration
Filtration is defined as the unit operation in which the insoluble solid component of a
solid liquid suspension is separated from the liquid component by passing the latter
through a porous membrane or septum which retains the solid particles in the upstream
surface. The solid liquid suspension is called feed slurry, the liquid component that
passes through the membrane is called the filtrate and the membrane is called the filtering
medium. The separated solids are known as the filter cake.
Filter media
Filter media may be rigid or flexible. Rigid filter media may be loose such as sand or
gravel, diatomaceous earths or charcoal. There are also rigid fixed media like porous
carbon, porcelain, fused alumina, perforated metal prate,
Flexible media may consist of woven fabrics of cotton, silk, wool and jute. Many
synthetic materials are finding application, including nylon, polypropylene, polythene,
polyvinylchloride
Different filtration equipments are known. These include:
Pressure filters where a pressure high than atmospheric pressure is maintained upstream
of the medium to induce the flow of the filtrate. There may be vertical plate pressure
filter and horizontal plate filters.
Vacuum filters where low pressure is maintained downstream of the medium. There are:
continuous rotary drum vacuum filter, rotary vacuum disc filter.
7.2 Ultrafiltration
Ultrafiltration is widely employed in the increasingly important biotechnological industry
for separation of fermentation products, particularly enzymes. Its largest commercial use
is in the dairy industry for recovery of proteins from cheese whey and for pre-
concentration of milk for cheese making. This process used membranes with a very small
pore size but a bit larger than for reverse osmosis.
7.3 Reverse osmosis
It is well known that when a plant or an animal membrane separates two solutions of
different concentrations, pure water passes through the membrane. The movement of
water occurs from a solution with high concentration of water to a solution with low
concentration of water. This process is called osmosis and it is driven by osmotic
pressure. If a pressure higher than the osmotic pressure is applied to the side where the
76

concentration of water is higher, the process of osmosis is reversed. This process is called
reverse osmosis.
7.4 Centrifugation
Centrifugation is a unit operation involving the separation of materials by the application
of centrifugal force.
7.4.1 Separation of immiscible liquids:
The centrifugal force F
c
acting on an object of mass m, rotating in a circular path of
radius R at an angular velocity of is:
F
c
= mR
2

If two liquids with different densities are placed in a cylinder rotating about a central axis,
the more dense liquid will tend to move towards the wall thus separating from the other
liquid.

Figure 7.1: Liquid separation in a centrifuge
7.4.2 Separation of insoluble solids from liquids:
This process is usually called centrifugal clarification where small quantities of insoluble
solids are removed from a liquid by centrifugation.
7.4.3 Centrifugal filtration:
This tem describes another method of separating insoluble solids from liquids involving
centrifugal force. However, in this case the mechanism of separation is filtration and the
flow of the filtrate is induced by centrifugal force. In this case, the centrifugal bowl is
leaned with filtration medium.
77

7.5 Sieving:
This is a mode of mechanical separation where particles are separated base on their size.
The separating medium is called a sieve. The material is shaken or agitated above a mesh
or cloth screen; particles of smaller size than the mesh openings can pass through under
the force of gravity.
The volume of material handled by the sieve depends on:
nature and the shape of the particles,
frequency and the amplitude of the shaking,
methods used to prevent sticking or bridging of particles in the apertures of the
sieve and
tension and physical nature of the sieve material.
Industrial sieves include rotary screens which are horizontal cylinders either perforated or
covered with a screen, into which the material is fed. Other sieves are vibrating screen
generally vibrated by eccentric weights.
7.6 Sedimentation
Sedimentation uses gravitational forces to separate particulate material from fluid
streams.
The particles are usually solid, but they can be small liquid droplets, and the fluid
can be either a liquid or a gas.
Sedimentation is very often used in the food industry for separating dirt and
debris from incoming raw material, crystals from their mother liquor and dust or
product particles from air streams. In sedimentation, particles are falling from rest
under the force of gravity.

Mixing
78

Chapter VIII Mixing
Mixing is the dispersing of components, one throughout the other. It occurs in
innumerable instances in the food industry and is probably the most commonly
encountered of all process operations.
Mixing can be, particles mixing where small particles are mixed to make an
homogeneous mixture, it can also be particle mixing in liquids it can also be about
mixing of different liquids.
8.1 Mixing equipments:
Liquid Mixers:
The propeller mixer is probably the most common and the most used in liquid mixing.
Powder and Particle Mixers
The essential feature in these mixers is to displace parts of the mixture with respect to
other parts.
Figure 8.1: Mixers (a) ribbon blender, (b) double-cone mixer
Dough and Paste Mixers
Dough and pastes are mixed in machines that have, of necessity, to be heavy and
powerful. Because of the large power requirements, it is particularly desirable that these
machines mix with reasonable efficiency, as the power is dissipated in the form of heat,
which may cause substantial heating of the product.
Mixing
79

Figure 8.2: Example of a Kneader

Size reduction
80

Chapter IX Size reduction
Raw materials often occur in sizes that are too large to be used and, therefore, they must
be reduced in size. This size-reduction operation can be divided into two major categories
depending on whether the material is a solid or a liquid. If it is solid, the operations are
called grinding and cutting, if it is liquid, emulsification or atomization.
9.1 Grinding and cutting
These processes reduce the size of solid materials by mechanical action, dividing them
into smaller particles. Perhaps the most extensive application of grinding in the food
industry is in the milling of grains to make flour, but it is used in many other processes,
such as in the grinding of corn for manufacture of corn starch, the grinding of sugar and
the milling of dried foods, such as vegetables.
9.1.1 Grinding Equipments
Crushers:
In crusher, the material is fed in between two heavy jaws, one fixed and the other
reciprocating, so as to work the material down into a narrower and narrower space,
crushing it as it goes.

Figure 9.1: Crushers
Hammer mills:
In a hammer mill, swinging hammerheads are attached to a rotor that rotates at high
speed inside a hardened casing
Size reduction
81

Figure 9.2: Hammer mills
Roller mills:
Roller mills have smooth or finely fluted rolls, and rotate at differential speeds. They are
used very widely to grind flour.

Figure 9.3: roller mills
Cutters
Cutting machinery is generally simple, consisting of rotating knives in various
arrangements. A major problem often is to keep the knives sharp so that they cut rather
than tear.
9.2 Emulsification
Emulsions are stable suspensions of one liquid in another, the liquids being immiscible.
Stability of the emulsion is obtained by dispersion of very fine droplets of one liquid,
called the disperse phase, through the other liquid, which is called the continuous
phase.
Size reduction
82

The stability of an emulsion is controlled by
interfacial surface forces,
size of the disperse phase droplets,
viscous properties of the continuous phase and
density difference between the two phases.
The terms emulsification and homogenizers are often used interchangeably for equipment
used to produce emulsions. Emulsification is the formation of a stable emulsion by the
intimate mixing of 2 or more immiscible liquids. Homogenization is the reduction in size
and increase in number of solid or liquid particles of the dispersed phase, by the
application of intense shearing forces, to increase the intimacy and stability of the tow
substances. Homogenization is therefore a more severe operation than emulsification.
Both operations are used to change the functional properties or eating quality of liquid
foods. They have little or no effect on nutritional value or shelf life.
Equipments used in homogenization include high pressure homogenizers, high speed
mixers, colloid mills, ultrasonic homogenizers

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(2nr)n = 0(2n)n (2.18)

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