The redox pair around 0.

2V refers to the redox process Fe3 + / Fe2 + and is related to conversion of the "insoluble" form of FeHCF to "soluble", as described in reactionsXX and XXX below XX Fe3+4[Fe2+(CN)6]3 +4K+ + 4eInsoluble state K4Fe42+[Fe2+(CN)6]3 XX everitts salt

KFe [Fe2+(CN)6] + K+ + eSoluble state

K2Fe2+ [Fe2+(CN)6] everitts salt

XXX

The redox pair near 0,8V is possibly realted to the following process Fe43+[Fe2+(CN)6]3 3e- + 3AKFe3+Fe2+(CN)6 e- K+ Fe43+ [Fe2+(CN)6A-]3 Fe3+Fe3+(CN)6

Referencia das equaes e tambm dos picos SETTI, G. D. O. Estudo Estrutural e das Mudanas Configuracionais em Compostos Moleculares tipo Hexacianometlicos por meio de Tcnicas Eletroqumicas e Eletrogravimtricas. 2009. -Instituto de Qumica, UNESP, Araraquara, SP, 2009.