Concept Recap Test Mains 3 Sol

AITS-CRT(Set-III)-PCM(S)-JEE(Main)/13
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1

ANSWERS, HINTS & SOLUTIONS
CRT (Set-III)

Q. No. PHYSICS CHEMISTRY MATHEMATICS
1.
A C A
2.
A C B
3.
B B A
4.
D C C
5.
A D B
6.
C B A
7.
A A A
8.
B B C
9.
C C D
10.
C C A
11.
C C B
12.
D A A
13.
B B C
14.
B D B
15.
A B B
16.
C C D
17.
A B C
18.
D D A
19.
A C A
20.
C D D
21.
C A D
22.
C D A
23.
C A C
24.
C
B
C
25.
D C C
26.
C A A
27.
D B B
28.
C B D
29.
C C D
30.
A A B

A
L
L

I
N
D
I
A

T
E
S
T

S
E
R
I
E
S

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4
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9

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2


2
P Ph hy ys si ic cs s PART I
1. Use Keplers 3
rd
law :
2 3
2 2
1 1
T R
T R
| | | |
=
| |
\ . \ .

2. At closed end, Maximum pressure = P
0
+ P
0
.

3. Angular momentum of the comet is conserved.

4.
2 2
Z R X = +
where
L C
X X X =
6.
2
2
V
H I Rt t
R
= =

1
H
R
if V = constant
Current along 4, 6, 12 are 6I, 4I, 2I
Total current = 12 I
Also current through
3
2 12I
5
=
Heat through
2
1
4 (6I) 4 t H = =
Heat through
2
2
3
2 12I 2 t H
5
| |
= =
|
\ .

2 1
H H <
7. As the capacitors are uncharged, the initial current
eq
V
;
R
=
R
eq
= (1.5 + 0.5) = 2 .
8. E
Stored
=
2
1
Li
2
; and emf =
di
L
dt

9.
S
V n ,
t
= = number of waves
S
=
=
2000m
2500
0.8 m
= =
10.
S
e t
L
I
= 0.2 H

1 2
LI LI
E
2 2
1 2
E ,
2 2
= =

( )
L
= I I J
2
2 2
2 1
E 7.5 =
11. Since, the pendulum started with no kinetic energy, conservation of energy implies that the
potential energy at Q
max
must be equal to the original potential energy, i.e., the vertical position
will be same.
L cos = A + (L A ) cos

Lcos
cos
L

=
A
A

1
Lcos
cos
L
(
=
(

A
A


3
12. hr = constant for capillarity
h = 6 cm for a vertical tube

o
h
12 cm
cos60
= = A

13. Acceleration =
V(g a)( d)
Vd
+

2
20 m/ s =

14. Least count = 1 MSD 1 VSD
In this question
(M 1) MSD M VSD

M 1
1VSD MSD
M
| |
=
|
\ .

Now, LC = IMSD
( ) M 1
MSD
M

M M 1 1
MSD MSD
M M
+
= =

b
LC
M
= .
15 Use Newtons Law of cooling.

16. For an adiabatic process, TV
1
= const; and U (ideal gas) T.

18. The radius of curvature =
2
N
v
a
,

19. a = g sing - g cos
a = g [ sin - 0.1 x cos ]
acceleration will remain +ve upto
x = 10 tan .
m
g

s
i
n

m
g

c
o
s

20.
2
T
=
AN Rsin
2
=

t
AN Rsin
2
=

t
AB 2Rsin
2
=
A
O
B
N
R
/2

AB
average velocity =
t

2R 2
3 sin
2 2 3

3 3 R
2
.

4

21. B
G
is parallel to v
G
.

23.
e
i
T
=
Now
2 3
T r and
2 3
r n T n

3
1
i
n

the current will increase 8 times.
(C)

25.
1
2
T
T
=
3
1
2
n
n
| |
|
\ .
= 8

1
2
n
n
= 2.

26.
min 1 2
S i i A = + for S
min
i
1
= i
2

30 = 2I
1
60
i
1
= 45

27.
7 2
4
5
D D 6 10 40 10
d 20 10 m 0.2cm
d 12 10

= = = = =

.

28. Let the mass of wood and concrete be M and m respectively. Then

M m
(M m)
0.5 2.5
+ = +
or
1 1
M 1 m 1
0.5 2.5
| | | |
=
| |
\ . \ .

or
1.5 3
M m m
2.5 5
| | | |
= =
| |
\ . \ .

M 3
m 5
=

29. Longitudinal stress = Y longitudinal strain.
Here, longitudinal stress = 0
Then, longitudinal strain = 0.


5
C Ch he em mi is st tr ry y PART II

4. H
3
BO
3
+ Na
2
CO
3
Na
2
B
4
O
7
+ H
2
O + CO
2

H
3
BO
3
+ NaCl Na
2
B
4
O
7
+ HCl ( remains in solution) + H
2
O
HCl does not escape from the system as gas like CO
2
because of higher magnitude of enthalpy
of solution (it is ve and hence, released) otherwise, like CO
2
, it too would have escaped the
system as gas, thereby driving the reaction forward.
5. OH
NH
2
acetylation
OH
NHCOCH
3
Paracetamol
6. Being a linear polymer of, natural rubber becomes soft at high temperature (62C) and brittle at
low temperature (< 10C). It is, therefore, not used in making footwear for polar region.
9. +3 and +4 states are shown by Ce in aqueous solution
10. Dolomite (MgCO
3
.CaCO
3
) produces slag, which can be further used in building materials.
11. 2KMnO
4
+ 3H
2
SO
4
+ 5H
2
O
2
K
2
SO
4
+ 2MnSO
4
+ 8H
2
O + 5O
2

a b c 2 3 5
5
2 2
+ + + +
= =
12.
( )
( )
( )
2
2
oxalic acid dihydrate
2 mL
2
Meq of COOH .2H O
N
V of COO 2H O solution
=

3
6.3
10
126/ 2
0.4
250
| |
|
\ .
= =
for neutralisation
N
oxalic
V
oxalic
= N
NaOH
V
NaOH

0.4 10 N
NaOH
40
N
NaOH
= 0.1 N
13. C would be sp
3
hybridisation
O would be sp
3
hybridised
14. If the molar volume is very large, the effect of attractive forces as well as molecular size is almost
nil, both the pressure correction and volume correction can be neglected. Therefore the gas
behaves ideally i.e. PV = nRT
The gas in Van der Waals equation is characterised by Van der Waals coefficient that are
dependent on the identity of gas but are independent of temperature or the effect of temperature
or the effect of temperature on these constants is neglected.

In case of a real gas, the molecules strike the walls of the containers with less force because they
are attracted by other molecules, therefore pressure is always less than pressure in an ideal gas,
where molecules collide with a larger impact.
15.
NH
2
2
NaNO HCl +
N
2
Cl
4
HBF
F

6
16. SN2 reaction takes place.
inversion of configuration
17.
OH
CH
2
OH
2 3
K CO +
O
CH
2
OH
3
CH I +
OCH
3
18. Lack of H-bonding in ether decreases boiling point.
19. In the depresin of freezing point experiment
(i) it is found that vapour pressure of solution is less than that of pure solvent.
(ii) Only solvent molecules solidify as freezing point. Not applicable for solute particles.
SUM = (2) + (3) + (4) = 9
20.
C
O
is meta directing group.
21.
( ) ( )
n
s aq
M M ne
+
+
for electrodes oxidation potential

n n
0 n
10
M / M M / M
2.303RT
E E log M
nF
+ +
+
(
=

(1) and (3) correct
SUM = 1 + 3 = 4
22.
C O
CH
3
CH
O
A
B
+
2
NaOH/ I
C O
CH
3
O
( )
3
CHI yellow +
23.
C
OH
H
C CH
H
+
C
H
C CH

C
H
C CH
O
H
H
C
H
C C
OH
H
Tautomerise
ZZZZZZZZX
YZZZZZZZZ
CH CH CH
O
Tollen' s Test
24.
( )
2 2
3 3
PbCO Pb CO
x x y
+
+
+
ZZZX
YZZZ

( )
2 2
3 3
MgCO Mg CO
y x y
+
+
+
ZZZX
YZZZ


7

sp 3
sp 3
K PbCO
x
K MgCO y
=

15
15
x 1.5 10
y 1 10

x = 1.5 y
x(x + y) = 1.5 10
-15

1.5y (1.5y + y) = 1.5 10
-15

1
15 2
8
1.5 10
y 2 10
3.75
| |
= =
|
\ .

8 8
x 1.5 2 10 3 10 M

= =
25. CsCl has body centered cubic unit cell. Each ion in this structure has a coordination no. of 8.
26. Products

Cl
Br
CHO
H C C C C H
O O O O
+

3 chiral C atoms
Total number of stereoisomer = 2
n
= 2
3
= 8
27.
N
H
H
H
sp
3
P
Cl
Cl
Cl
Cl
Cl
sp
3
d
B
Cl
Cl Cl
sp
2
(a)

N
+
O O
sp
N
O
O
O
sp
2
N
+
H H
H
H
sp
3
(b)

S
O
O
sp
2
(c)

S
H H
sp
2
angular
(d)

8
28.
C H
3
C CH
2
CH
3
O
H
C C CH
2
CH
3
OH
CN
above and below
C H
3
C CH
2
CH
3
OH
CN
(R as well as S) racemic mixture
4
LiAlH
C C
2
H
5
OH
C H
3
CH
2
NH
2

29.
C NH
O
CH
3
OH
C
O
OH CH
3
HN
COO CH
3
N H
2
(C)
18
3
1. H
2. CH O H
+
C
O
O CH
3
18
+
+
30. meq. Of NaOH = 10 0.1 = 1
meq. Of H
2
SO
4
= 10 0.05 = 0.5
meq. Of NaOH > meq of H
2
SO
4

[OH
] > [H
+
]
pOH < 7

9
M Ma at th he em ma at ti ic cs s PART III

1. D = (2x
2
+ 4) 2(4x 20) = 2x
2
+ 8x 42 = 0 + = 4.

2. Total into = 2
3
2 = 6]

3.
( ) ( )

V 2i 3j k i 2j 5k = + +
G

4. f(x) = x(9 x
2
) ; 3 x 3

5. Use L Hospitals Rule twice

7. Number of rectangles =
n+1
C
2
.
n+1
C
2
=
( )
2
2
n n 1
4
+

8. ( )
( )
4
3
f x 3 cosx 0
x 1
= + <
+

Hence f(x) is always decreasing, also as x , f(x) and as x , f(x) +
Hence one positive and one negative root

9. p(x) = ax
2
+ bx + c
p(x) = Q
1
x + 4
= Q
2
(x + 1) + 3
= Q
3
(x 1) + 1
p(0) = c = 4 (1)
p(1) = a b + 4 = 3 b a = 1
p(1) = a + b + 4 = 1 b + a = 3
b = 1 ; a = 2
p(x) = 2x
2
x + 4
p(2) = 8 2 + 4 = 6.

10. As f(x) has continuous derivative x [a, b] f(x) is continuous and as f(a) and f(b) have
opposite signs at least one value a < x = c < b such that f(c) = 0 also since f(x) 0
f(x) > 0 or f(x) < 0 throughout function is increasing or decreasing will have only one
possible root.

11. x
2
+ y
2
= 1
let x = cos and y = sin so (x + y)
2
can be written in the form of
(cos + sin)
2
= 2sin
2
4
| |
+
|
\ .

maximum value = 2.

12. Put x = tan
I =
( )
( )
( ) ( )
a
/ 2 / 2
a a a
0 0
cos
d
d
1 tan sin cos

=
+ +

I =
4

13. Let
1
x
r
= so that as r 0

10

2
x 0 x 0
2
cosax cosbx.coscx 1 cosax cosbx coscx
lim lim
sinbx sincx
bc x
bc x
bx cx

=

use Lhospitals to get (C).

14. f*(x) = 2x
2
+ c
f(2) = 1 = 8 + c c = 7
now f(x) = 2x
2
7
f(x) =
3
2
x 7x d
3
+
f(2) = 0 d =
26
3

f(x) =
1
3
[2x
2
21x 26]
f(1) =
45
3
= 15.

15. If x 1
st
quadrant they y = 4
If x 2
nd
quadrant they y = 2
If x 3
rd
quadrant they y = 0 y min = 2
If x 4
th
quadrant they y = 2

16. Degree of f(x) = n ; degree of f(x) = n 1
degree of f(x) = (n 2)
hence n = (n 1) + (n 2) = 2n 3
n = 3
hence f(x) s = ax
3
+ bx
2
+ cx + d, (a 0)
f(x) = 3ax
2
+ 2bx + c
f(x) = 6ax + 2b
ax
3
+ bx
2
+ cx + d = (3ax2 + 2bx + c) (6ax + 2b)
18a
2
= a a =
1
18
.

17.
1 1 2 2 3 3
z z 1; z z 1; z z 1 = = =
given z
1
+ z
2
+ z
3
= 0
1 2 3
z z z 0 + + =
hence (z
1
+ z
2
+ z
3
)
2
= 0

2
1 1 2 3
1 2 3
1 1 1
z 2z z z 0
z z z
(
+ + + =
(

hence | |
2
1 1 2 3 1 2 3
z 2z z z z z z 0 + + + =

2
1
z 0 =

18. ( )
2 13
x 2 3 y
3
| |
+ = +
|
\ .
latus rectum = 3
The other conic is,
( ) ( )
( )
2 2
2 2
x 3 x 2
1
7
7 / 2
+
+ = which is an ellipse
Latus rectum =
2
2b 2.49 7
a 4.7 2
= =
positive difference
7 1
3
2 2
=

11

19. Given
1 2
V V V + =
G G G
; also
1
V V 2 =
G G

( ) ( )
2 2
1 2
V V V =
G G G
and
2
V V 2 =
G G

also s
1 2
V V V = = =
G G G
say
hence,
2
= 2
2
2
2
cosa cos
1
2

= 2n
3

20.
( )
( )
2
2
2
sin a / 2
1 cosa
cos a / 2
2cosa
a 1 cosa
sin
2

=
+ | |
|
\ .

k = 2 ; w = 1 ; p = 1 k
2
+ w
2
+ p
2
= 4 + 1 + 1 = 6

21. Let x =2 2 cos, y =2 2 sin
x y =2 2 (cos sin)
(x y)
max
= 4.

22. u(x) = 7v(x) u(x) = 7v(x) p = 7(given)
again
( )
( )
u x
7
v x
=
( )
( )
u x
0
v x
| |
=
|
|
\ .
q = 0 ; now
p q 7 0
1
p q 7 0
+ +
= =

23. f(x) = ax
3
+ bx
2
+ cx + d

b
x
3a
= is possible point inflexion also since
2
2
d y
dx
changes sign as we move from left to right of
b
x
3a
= it is a point of inflexion.

24. y
2
= 4ax, 4a = 2p > 0
and t
1
t
2
= 1
ratio =
2
1 2
2 2 2
1 2
4a t t
4
a t t
=

25.
( )
n
n
n
1
lim
x 2
1
3
n 3

+
(dividing N
r
and D
r
by 3
n
)
for
n
lim
to be equal to
1
3
;
n
1
lim
n
0 (which is true) and

n
n
x 2
lim
3
| |
|
\ .
0.


12
26. For f to be one-one f(x) > 0 and f(x) < 0 for all x
clearly f is continuous at x = 0 and f(0) = 1
for x 0, f(x) = 2(x + m) if m > 0 then nothing definite can be said
about f(x)
hence m < 0
but m 0 as for x > 0, f is constant and m < 0, f(x) < 0, x > 0

P Q

27.
2
3
1 i 3
2 3
2
| |
| | | |
+
|
| |
| | |
\ . \ .
\ .
= 8 3()
3
= 24.

28. Let
n
C
151
= q.
n
C
150
where q 1

( ) ( ) ( ) ( )
n! q.n!
151 ! n 151 ! 150 ! n 150 !
=

1 q
151 n 150
=
n 150 = q.151 or n = 151q + 150

smallest n will be when q = 2
n = 302 + 150
n = 452 sum of the digit = 11.

29. Coefficient of A in n
th
term = 8 + (n 1) (2)
Coefficient of B in n
th
term = 2 + (n 1) (1)
10 2n = 2(3 n) 10 = 6
which is absurd

30. ( )
3x 2
F x dx
x 9
+
=
; let x 9 = t
2
dx = 2t dt
( )
( )
( )
2
2 3
3 t 9 2
F x .2t dt 2 29 3t dt 2 29t t
t
| |
+ +
|
(
= = + = +

|
\ .

( ) ( )
3/ 2
F x 2 29 x 9 x 9 C
(
= + +

Given F(10) = 60 = 2[29 + 1] + C C = 0
( ) ( )
3/ 2
F x 2 29 x 9 x 9
(
= +

F(13) = 2[29 2 + 4 2] = 4 33 = 132.

Concept Recap Test Mains 3 Sol

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AITS-CRT(Set-III)-PCM(S)-JEE(Main)/13

0 (which is true) and

n 150 = q.151 or n = 151q + 150

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