FTIR Spectroscopy Studies of Chapter 7

Chapter 7
FTIR Spectroscopic Studies
CHAPTER - 7
FTIR SPECTROSCOPIC STUDIES
7.1. Introduction
Infrared spectroscopy (IR spectroscopy) is the subset of Spectroscopy that
deals with the infrared region of the electromagnetic spectrum. It covers a range of
techniques, the most common being a form of absorption spectroscopy. As with all
spectroscopic techniques, it can be used to identify compounds and investigate sample
composition. A common laboratory instrument that uses this technique is an infrared
spectro photometer. A molecule is a collection of atoms. The atom in a molecule
executes different types of vibrational motion. The energy of most of these molecular
vibrations is quantized and corresponds to that to the infrared regions of the
electromagnetic spectrum. When infra red radiation of the same frequency is allowed
fall on the molecule, the system absorbs energies, carrying the excitation of the
molecule to higher vibrational levels[123]. The molecules absorbing a quantum of
energy give rise to bands characteristic of the molecule from about 200 to 4000 cm-1.
Functional groups can be identified spectra one of the most reliable methods for
understanding the structure of the molecules [124].
The infrared portion of the electromagnetic spectrum is usually divided into
three regions; the near-, mid- and far- infrared, named for their relation to the visible
spectrum. The far-infrared, approximately 40010 cm-1 (100030 m), lying adjacent
to the microwave region, has low energy and may be used for rotational spectroscopy.
The mid-infrared, approximately 4000 400 cm1 (30 2.5 m) may be used to study
the fundamental vibrations and associated rotational-vibrational structure. The higher
261
energy near-IR, approximately 140004000 cm1 (2.50.8 m) can excite overtone or

harmonic vibrations
[125]
. The names and classifications of these sub regions are
merely conventions. They are neither strict division nor based on exact molecular or
electromagnetic properties.
7.2. Theory
FT-IR stands for Fourier Transform Infra Red, the preferred method of
infrared spectroscopy. It was first developed by astronomers in the early 1950s to
study the infrared spectra of distant stars, has now been developed into a very
powerful technique for the detection of very weak signals from the environment
noise. It is a simple mathematical technique to reverse a complex wave into its
frequency components. The conventional IR spectrometers are not of much use for
the far IR region (20 400 cm-1) as the sources are weak and the detectors are
insensitive. FT-IR has made this energy limited region more accessible. It has made
the middle infrared (400 4000 cm-1) also more useful [124].
Infrared spectroscopy exploits the fact that molecules absorb specific
frequencies that are characteristic of their structure. These absorptions are resonant
frequencies, i.e. the frequency of the absorbed radiation matches the frequency of the
bond or group that vibrates. The energies are determined by the shape of the
molecular potential energy surfaces, the masses of the atoms, and the associated
vibronic coupling.
In order for a vibrational mode in a molecule to be "IR active," it must be
associated with changes in the permanent dipole.
A molecule can vibrate in many ways, and each way is called a vibrational
mode. Linear molecules have 3N5 degrees of vibrational modes whereas nonlinear
262
molecules have 3N6 degrees of vibrational modes (also called vibrational degrees of
freedom). As an example H2O, a non-linear molecule, will have 336 = 3 degrees of
vibrational freedom, or modes [124].
Simple diatomic molecules have only one bond and only one vibrational band.
If the molecule is symmetrical, e.g. N2, the band is not observed in the IR spectrum,
but only in the Raman spectrum
[126]
. Unsymmetrical diatomic molecules, e.g. CO,
absorb in the IR spectrum. More complex molecules have many bonds, and their
vibrational spectra are correspondingly more complex, i.e. big molecules have many
peaks in their IR spectra. The atoms in a CH2 group, commonly found in organic
compounds can vibrate in six different ways: symmetric and antisymmetric stretching,
scissoring, rocking, wagging and twisting.
Using the information of FT-IR, We can determine the amount of components
in a mixture, the quality of consistency of a sample and identify unknown materials
7.3. Practical IR spectroscopy

The infrared spectrum of a sample is recorded by passing a beam of infrared
light through the sample. Heated silicon carbide rods, heated ceramic rods coated with
rare earth oxides, tungsten and carbon are used as sources of infrared radiation.
Examination of the transmitted light reveals how much energy was absorbed at each
wavelength. This can be done with a monochromatic beam, which changes in
wavelength over time, or by using a Fourier Transform instrument to measure all
wavelengths at once. From this, a transmittance or absorbance spectrum can be
produced, showing at which IR wavelengths the sample absorbs. Analysis of these
absorption characteristics reveals details about the molecular structure of the sample.
263
When the frequency of the IR is the same as the vibrational frequency of a bond,
absorption occurs. This technique works almost exclusively on samples with covalent
bonds. Simple spectra are obtained from samples with few IR active bonds and high
levels of purity. More complex molecular structures lead to more absorption bands
and more complex spectra. The technique has been used for the characterization of
very complex mixtures.
7.4. Sample preparation

In the Fourier transform infrared spectrum the samples are prepared by the
pressed pellet technique. In this technique a small amount of the ground solid sample
is mixed with about 100 times its weight of potassium bromide (KBr). The finely
ground mixture is pressed under very high pressure to form small pellet. The pellets
are then exposed to a source of continuous infrared radiation. The spectrometer
dispenses. The radiation into a spectrum and the detector converts the radiant energy
into an electrically signal which is amplified electronically and recoded by a chart
recorder.
Liquid samples can be sandwiched between two plates of a salt (commonly
sodium chloride, or common salt, although a number of other salts such as potasium
bromide or calcium fluoride are also used).[127] The plates are transparent to the
infrared light and do not introduce any lines onto the spectra. A means of decoding
the individual frequencies is required. This can be accomplished via a well known
mathematical technique called the Fourier transformation. This transmissions
performed by the computer which them presents the user with the desired spectral
information for analysis.
264
In addition to "standard" transmission FTIR we they also have the following

sample handling capabilities:
1. Horizontal ATR - attenuated total reflectance. Allows measurement of
aqueous solutions, elastic and viscous samples which are difficult to grind
2. Specular reflectance - allows measurement of thin films on metals
3. KBr Discs - allow suspension of powders in IR transparent KBr so they may
be analysed
4. Gas cells - This may be used for FTIR analysis of a gaseous sample (e.g.
headspace analysis or environmental monitoring)
5. Solution cells - for measuring liquid sample in transmission mode.
7.5. Comparison with a reference
Fig. 7.1: Schematics of a two-beam absorption spectrometer.
A beam of infrared light is produced, passed through an interferometer (not

shown), and then split into two separate beams. One is passed through the sample, the
other passed through a reference. The beams are both reflected back towards a
detector, however first they pass through a splitter, which quickly alternates which of
the two beams enters the detector. The two signals are then compared and a printout is
obtained. This "two-beam" setup gives accurate spectra even if the intensity of the
265
light source drifts over time. To take the infrared spectrum of a sample, it is necessary
to measure both the sample and a "reference" (or "control"). This is because each
measurement is affected by not only the light-absorption properties of the sample, but
also the properties of the instrument (for example, what light source is used, what
detector is used, etc.). The reference measurement makes it possible to eliminate the
instrument influence. Mathematically, the sample transmission spectrum is divided by
the reference transmission spectrum.
The appropriate "reference" depends on the measurement and its goal. The
simplest reference measurement is to simply remove the sample (replacing it by air).
However, sometimes a different reference is more useful. For example, if the sample
is a dilute solute dissolved in water in a beaker, then a good reference measurement
might be to measure pure water in the same beaker. Then the reference measurement
would cancel out not only all the instrumental properties (like what light source is
used), but also the light-absorbing and light-reflecting properties of the water and
beaker, and the final result would just show the properties of the solute (at least
approximately).
A common way to compare to a reference is sequentially: First measure the
reference, then replace the reference by the sample, then measure the sample. This
technique is not perfectly reliable: If the infrared lamp is a bit brighter during the
reference measurement, then a bit dimmer during the sample measurement, the
measurement will be distorted. More elaborate methods, such as a "two-beam" setup,
can correct for these types of effects to give very accurate results.
266
7.6. FTIR Spectroscopy

Fourier Transform infrared (FTIR) spectroscopy is a measurement
technique that allows one to record infrared spectra. Infrared light is guided through
an interferometer and then through the sample (or vice versa). A moving mirror inside
the apparatus alters the distribution of infrared light that passes through the
interferometer. The signal directly recorded, called an "interferogram", represents
light output as a function of mirror position. A data-processing technique called
Fourier Transform turns this raw data into the desired result (the sample's spectrum):
Light output as a function of infrared wavelength (or equivalently,wavenumber). As
described above, the sample's spectrum is always compared to a reference.
There is an alternate method for taking spectra (the "dispersive" or "scanning
monochromator method), where one wavelength at a time passes through the sample.
The dispersive method is more common in UV-Vis spectroscopy, but is less practical
in the infrared than the FTIR method. One reason that FTIR is favored is called
"Fellgetts advantage" or the "multiplex advantage": The information at all
frequencies is collected simultaneously, improving both speed and signal-to-noise
ration. Another is called "Jacquinot's Throughput Advantage": A dispersive
measurement requires
detecting much lower light levels than an FTIR
measurement.[128] There are other advantages, as well as some disadvantages,[128] but

virtually all modern infrared spectrometers are FTIR instruments.
7.7. Analyse of the spectra

Step 1
Look first for carbonyl C=O bend. Look for a strong band at 1820 1660cm-1.
This band usually belongs to the most intense absorption band in a spectrum. It will
267
have medium width. If we see the carbonyl band, look for other ends associated with
functional groups that contain the carbonyl by going to step 2. If no C=O band is
present, check for alcohols and go to the step 3.
Step 2
If a C=O is present we want to determine if it is a part of an acid, an ester, or
an aldehyde or ketone. At this time we may not able to distinguish aldehyde from
ketone and you will not be asked to do so.
ACID
Look for indications that an O-H is also present. It has a broad absorption near
3300 2500 cm-1. This actually will overlap the C-H stretch. There will also be a C-O
single band near 1100 1300 cm-1. Look for the carbonyl and band near
1725 1700 cm-1.
ESTER
Look for C=O absorption of medium intensity near 1300 1000 cm-1. There
will be no O-H band.
ALDEHYDE
Look for aldehyde type C-H absorption bands. There are two weak
absorptions to the right of the C-H stretch near 2850 cm-1 and 2750 cm-1 and are
caused by the C-H band that is a part of the CHO aldehyde functional group. Look for
the carbonyl C-O band around 1725 1705 cm-1.
268
Step 3
If no carbonyl band appears in the spectrum looks for an alcohol O-H band.
ALCOHOL
Look for the broad OH band near 3600 3300 cm-1 and a C-O absorption
band near 1300 1000 cm-1.
Step 4
If no carbonyl band and no O-H bands are in the spectrum check for double
bands, C=C from an aromatic or an alkene.
ALKENE
Look for weak absorption near 1650 cm-1 for a double band. There will be a
C-H stretch band near 3000 cm-1.
AROMATIC
Look for the benzene C=C, double bonds which appear as medium to strong
absorption in the region 1650 1450 cm-1. The CH stretch bond is much weaker than
in alkenes.
Step 5
If none of the previous groups can be divided, we may have an alkane.
ALKANE
The main absorption will be the C-H stretch near 3000 cm-1. The spectrum
will be simple with another band near 1450 cm-1.
269
Step 6
If the spectrum still cannot assigned we may have an alkyl bromide.
ALKYL BROMIDE
Look for the C-H stretch and a relatively simple spectrum with an absorption
to the right of 667 cm-1.
Note: Terminal C-CH2:
Absorption at 1600 1675 cm-1
Strong bands at 900 cm-1.
Aromatic ring breathing motions: Observed between 1450 cm-1 and 1600 cm-1
the interpretation of infrared spectra involves the correlation of absorption bands in
the spectrum of an unknown compound with the known absorption frequencies for
types of bands.
A model table is given below which is helpful for analyzing a FT-IR spectrum.
270
Table - 7.1
Analyzing a FTIR specturm
Bond
Frequency range, cm-1
Compound type
2960 2850(s) stretch

Alkanes
1470 1350 (v) Scissoring and

bending
C H
1380 (m-w) Doublet isopropy 1,tbuty1
CH3 Umbrella Deformation

CH
30803020 (m) stretch
Alkanes
1000675 9s) bend

CH
Aromatic Rings
3100300 (m) stretch
Phenyl Ring Substitution Bonds
870 675 (s) bend
Phenyl ring substitution Overtones
200 1600 (w) fingerprint region

33333267 (s) stretch
CH
Alkynes
C =C
Alkenes
1680 1640 (m,w) stretch
C=C
Alkynes
22602100 (w, sh) stretch
C=C
Aromatic Rings
1600, 1500 (w) stretch
C O
Alcohols, ketones, Carboxylic acids

Esters
1260 100 (s) Stretch
C=O
Aldehydes, ketones, Carboxylic acids

Esters
17601670 (2) stretch
Monomeric Alcohols, phenols
36403160 (s, br) stretch
O=H
700610 (b) bend
Hydrogenbondedalcohols, phenols
Carboxylic acids
36003200 (b) stretch

35003300 (m) bend
NH
Amines
CN
Amines
C=N
Nitriles
22602220 (v) Stretch
Nitro Compounds
16601500 (s) asymmetrical stretch
NO2
V = Variable,
m = Medium s Strong
16501580 (m) bend
W weak
271
sh sharp
272
273
7.8. Advantages of FTIR

Some of the major advantages of FT-IR are:
Speed
Because all of the frequencies are measured simultaneously, most
measurements by FT-IR are made in a matter of seconds rather than several minutes.
Sensitivity
Sensitivity is dramatically improved with FT-IR for many reasons. The
detectors employed are much sensitive, the optical throughput is much higher which
results in much lower noise levels, and the fast scans enable the co addition of several
scans in order to reduce the random measurements noise to any desired level (referred
to as signal averaging)
Mechanical Simplicity
The moving mirror in the interferometer is the only continuously moving part
in the instrument. Thus there is very little possibility of mechanical breakdown. FTIR
can be used to identify the chemical from spills, paints, polymers, coating and drugs.
FTIR is perhaps the most powerful tool for identifying types of chemical bonds.
Organic compounds have very rich detailed spectra; inorganic compounds are usually
much simpler.
7.9. Applications
Infrared spectroscopy is widely used in both research and industry as a simple
and reliable technique for measurement, quality control and dynamic measurement. It
274
is also used in forensic analysis in both criminal and civil cases, enabling
identification of polymer degradation for example.
The instruments are now small, and can be transported, even for use in field
trials. With increasing technology in computer filtering and manipulation of the
results, samples in solution can now be measured accurately (water produces a broad
absorbance across the range of interest, and thus renders the spectra unreadable
without this computer treatment). Some instruments will also automatically tell you
what substance is being measured from a store of thousands of reference spectra held
in storage.
Infrared spectroscopy has been highly successful for applications in both
organic and inorganic chemistry. Infrared spectroscopy has also been successfully
utilized in the field of semiconductor microelectronics:[129] for example, infrared
spectroscopy can be applied to semiconductors like silicon, gallium arsenide, gallium
nitride, zinc selenide, amorphous silicon, silicon nitride, etc.
7.10. Results and Discussion

FTIR analysis of binary liquid systems
In the FTIR spectrum of binary liquid mixtures was revealed at room
temperature in the range of 4004000cm1. The FTIR spectrums for binary and
ternary mixtures are represented in Fig 7.1 to 7.30 and their observations are given in
tables 7.2 to 7.31. Liquid mixtures were added and few mg of the composition was
used for making pellets with KBr. The pellets were then exposed to IR radiation. The
FTIR spectrums were taken using Perkin Elmer FTIR spectrometer. The tentative
frequency assignments were made by comparing it with standard values of frequency.
The FTIR spectrum taken shows drastic changes in the frequency values for binary
275
and ternary mixtures. In the binary systems of Cyclohexanone(X1) + Hexane(X2),

Cyclohexanone(X1)
2-Butanone(X2),
Heptane(X1)
Benzaldehyde(X2),
Heptane(X1) + 2-Butanone(X2), Benzaldehyde(X1) + Benzyl Chloride(X2),

Benzaldehyde(X1) + Ethyl Acetate(X2) mixtures the maximum frequency has been
observed in the region 0.6 mole fraction of X1 and 0.4 mole fraction of X2. In
Cyclohexanone(X1) + Benzyl Chloride(X2),
Heptane(X1) + Ethyl Acetate(X2),
Benzaldehyde(X1) + 2-Butanone(X2), Ethyl Acetate (X1) + 2-Butanone(X2)

combinations shows the maximum frequency has been observed in the region 0.7
mole fraction of X1 and 0.3 mole fraction of X2. In Cyclohexanone(X1) +
Heptane(X2),
Hexane(X1) + Heptane(X2), Hexane(X1) + Ethyl Acetate (X2)
combinations the maximum frequency has been observed in the region 0.8 mole
fraction of X1 and 0.2 mole fraction of X2. In Cyclohexanone(X1) +
Benzaldehyde(X2),
Benzaldehyde(X1) + Hexane(X2), Heptane(X1) + Benzyl
Chloride (X2) mixtures the maximum frequency has been observed in the region 0.4
mole fraction of X1 and 0.6 mole fraction of X2. In Hexane(X1) + 2-Butanone(X2),
Ethyl Acetate(X1) + Benzyl Chloride (X2) mixtures the maximum frequency has
been observed in the region 0.3 mole fraction of X1 and 0.7 mole fraction of X2. In
Cyclohexanone(X1) + Ethyl Acetate (X2), Benzyl Chloride (X1) + 2-Butanone (X2)
mixtures the maximum frequency has been observed in the region 0.5 mole fraction of
X1 and 0.5 mole fraction of X2.
FTIR analysis of ternary liquid systems

In the ternary systems, Cyclohexanone(X1) + Hexane(X2) + Heptane(X3)
mixture the maximum frequency has been observed in 0.5, 0.4 mole fractions of X1,
276
0.3,0.5 mole fractions of X2 and 0.2,0.1 mole fractions of X3. In Cyclohexanone(X1)

+ Hexane(X2) + Benzaldehyde(X3) mixture the maximum frequency has been
observed in 0.4, 0.3 mole fractions of X1, 0.2,0.3 mole fractions of X2 and 0.4,0.4
mole fractions
of X3. In Cyclohexanone(X1) + Hexane(X2) + 2-Butanone(X3)
+ Hexane(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been
observed in 0.4, 0.3 mole fractions of X1, 0.2,0.2 mole fractions of X2 and 0.4,0.5
mole fractions
of X3. In Cyclohexanone(X1) + Heptane(X2) + 2-Butanone(X3)
+ Heptane(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been
observed in 0.4 mole fraction of X1, 0.5 mole fraction of X2 and 0.1 mole fractions
of X3. In Cyclohexanone(X1) + 2-Butanone(X2) + Benzaldehyde(X3) mixture the
maximum frequency has been observed in 0.4, 0.5 mole fractions of X1, 0.2,0.1 mole
fractions of X2 and 0.4,0.4 mole fractions
of X3. In Cyclohexanone(X1) +
Benzaldehyde(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been

observed in 0.4,0.5,0.2 mole fractions of X1, 0.4,0.4,0.4 mole fractions of X2 and
0.2,0.1,0.4 mole fractions of X3. In Cyclohexanone(X1) + Ethyl Acetate(X2) + 2Butanone(X3) mixture the maximum frequency has been observed in 0.3, mole
fraction of X1, 0.4 mole fraction of X2 and 0.3 mole fraction of X3. In Ethyl
Acetate(X1) + 2-Butanone(X2) + Hexane(X3) mixture the maximum frequency has
been observed in 0.7, 0.5 mole fractions of X1, 0.1,0.2 mole fractions of X2 and
0.2,0.3 mole fractions of X3.
277
So, the observation from the VE study has been confirmed by the FTIR
spectrum measurement. The shift in the frequency values of FTIR spectrum
measurement is generally due to following observed factors:
1. Interstitial accommodation.
2. Strong interactions (H-bond type, or dipole-dipole or dipole-induced dipole
interactions).
278
For Binary systems

Fig-7.1 FTIR spectrums for Cyclohexanone + Hexane mixture:
SPECTRUM
SPECTRUM
SPECTRU M
SPECTRUM
0.9 (CYC) + 0.1 (HEXANE)
SPECTRUM
SPECTRUM
0.6 (CYC) + 0.4 (HEXANE)
0.7 (CYC) + 0.3 (HEXANE)
0.5 (CYC) + 0.5 (HEXANE)
0.8(CYC) + 0.2 (HEXANE)
(1)CYC + (0)H EXANE

100.0
100.0
100.0
100.0
95
95
95
100.0
2335.
95
100.0
95
95
413.3
90
90
90
90
2673.
90
3937.
85
85
85
80
991.42
1264.33
75
70
2672.30
65
2063.86
2340. 71
1018.08 864.24
1312.
3949.
105 3. 12 907.55
55
750 .1 6
%T
156 0. 38
45
490 .5 7
55
2063.
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50
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3002.
1872.
55
652.90
50
1018.
40
40
131 1. 99
1119.02
122 2. 35
2940.57
1342.
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40
3412.
35
35
2864.
1416.
1568.
1635.
30
1023.
30
1119.
25
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20
30
1000
400.0
10
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3000
2000
1500
1000
400.0
3000
2000
1500
1000
400.0
15
10
3414.
10
2867.
1712.
4000.0
5
3438.
2942.
0.0
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cm-1
1566.
20
2939.
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904.5
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1424.18
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286 4. 06
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2670.
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60
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187 1. 50
904.6
80
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70
3767.
85
2363.74
80
1713.
3000
0.0
2000
1500
1000
400.0
0.0
4000.0
3000
2000
1500
cm-1
cm-1
1000
400.0
4000.0
3000
2000
cm-1
1500
SJC= Phy-
SJC=phy-
SJC= Phy-
SJC=phy-
SJC= Phy-
CYCLON~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T 5 0.50
SJE497~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T
SJC_PH~1.SP 3601 4000.00 400.00 3.17 99.73 4.00 %T
SJ2057~1.SP 3601 4000.00 400.00 4.26 100.00 4.00 %T
SJC_PH~3.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T
SJ205F~1.SP 3601 4000.00 400.00 10.00 99.99 4.00 %T
RE F 400 0 7 5. 82 2000 7 3. 85 600

344 9.1 4 9 .99 29 40. 57 16. 99 28 64. 06 30. 70 26 72. 30 72. 97 23 63.74 72.06
234 0.7 1 7 2.4 2 206 3.8 6 7 1.9 1 187 1.5 0 74.9 8 180 5.8 6 70.4 2 171 2.0 6 1 0.9 0
163 8.8 2 3 4.6 7 156 0.3 8 5 1.8 5 144 9.8 8 40.4 3 142 4.18 40.5 6 134 2. 46 5 1.1 1
131 1.9 9 4 3.4 5 126 4.3 3 6 8.7 4 122 2.3 5 41.5 1 111 9.0 2 44.1 7 105 3.1 2 6 2.9 7
101 8.0 8 6 4.7 1 991 .42 71. 38 90 7. 55 62.34 864. 24 6 6.33 750 .16 54.80
652 .90 57. 99 49 0. 57 51 .01 414.18 75.32
REF 4000 67.77 2000 66.53

3949.75 64.79 3771.50 63.78 3412.64 9.99 2941.57 12.87
2672.34 54.14 2362.22 56.70 2176.21 61.93 2063.32 61.94
1872.14 63.38 1806.55 50.78 1712.96 11.83 1565.33 31.39
1342.48 31.06 1312.47 28.92 1222.50 28.88 1119.18 29.68
1018.23 45.10 905.55 43.53 864.67 49.49 750.51 40.38 652.67
490.81 38.81 414.20
REF 4000 99.39 2000 86.51

3937.11 94.39 3442.57 3.17 3002.55 45.49 2925.08 46.29
2125.50 77.40 1643.95 25.49 1565.63 50.69 1416.33 38.79
1224.12 84.94 1114.72 80.62 1023.16 35.30 952.89 59.12
703.97 54.58 654.66
REF 4000 96.52 2000 94.52

3946.85 90.09 3767.63 89.85 3414.47 12.99 2942.29 4.26
2670.75 70.86 2424.36 92.42 2335.89 88.13 2176.82 85.87
1969.56 88.72 1870.29 86.76 1804.88 65.07 1713.79 4.26
1425.86 20.60 1314.25 32.48 1223.02 30.59 1119.55 35.78
1019.24 63.08 902.95 56.35 866.88 68.88 750.84 53.98 652.18
491.71 50.03 413.33
REF 4000 85.01 2000 84.30

3412.62 43.20 2939.86 20.75 2864.54 39.42 2670.80 80.23
1805.81 78.08 1712.49 9.96 1565.88 66.48 1425.10 50.33
1312.34 55.04 1222.32 53.27 1118.91 56.43 1054.23 70.92
904.58 70.92 864.55 76.02 750.33 69.99 650.48 75.94 490.12
411.32 79.45
REF 4000 80.81 2000 78.54

3934.56 79.80 3776.88 76.00 3438.20 10.00 2943.43 60.90
2104.26 76.73 1635.55 38.44 1566.96 27.76 1416.20 40.18
1120.65 68.37 1021.85 71.61 928.97 79.75 653.20
ACIC
St.Joseph's College ( Autonomous )
Tric hy-2
ACIC
St. Joseph's College ( Autonomous )
Tric hy-2
ACIC
Tric hy-2
FTIR SPECT RUM

Date: 21-12-2009
FIGURE 5
SPECTRUM
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 21- 12-2009
Spectrum Name: SJC-.6- .4 C.sp
0 (CYC) + 1 (HEXANE)
FT IR SPECT RUM
Date: 21- 12-2009
Spectrum Name: SJC-. 7-. 3 C.sp
FTIR
Date :
FT IR SPECT RUM
Date: 21- 12-2009
400.0
FIGURE 6
FIGURE 4
FIGURE 3
FIGURE 2
FIGURE 1
1000
cm-1
C yclohexa none.pk

100.0
100.0
100.0
100.0
100.0
1020.46
3929.03
1019.56
90
90
392 8.72
1976 .94
1019.04
95
863.28
1020.14
90
90
90
825.20
1171.48
1018.
41 5.01
862.42
206 4.94
3940.59
206 6.37
1114.
85
416.70
1416.
2 671.73
80
80
904.93
80
1975.94
2669.38
825.70
496.55
50
750.11
%T
650.68
1446.30
40
748.60
1447.60
40
713.64
45
40
1225.04
1345.67
1348.47
30
30
30
35
1594.44
2865.7 6
1230 .67
30
2866.5 7
10
0.0
2866.3 3
20
1595.75
20
294 2.30
10
1706.09
2000
1500
1000
400.0
4000.0
3 450.45
10
1595.69
1706.83
10
3 452.56
20
294 0.82
2000
1500
1000
400.0
4000.0
cm-1
17 10.56
0.0
3000
2000
3432.
10
17 09.48
0.0
3000
cm -1
1637.
15
294 1.41
3448.97
0.0
3000
25
20
1594.76
2 942.22
3457.73
4000.0
668.2
50
40
1447.10
712.74
2969.
55
%T
1345.87
1 227.34
1312.18
286 6.81
20
2338.
65
1223.65
%T
65 0.99
1449.01
30
2077.
70
4 93.14
60
111 8.56
50
749.80
2362.
75
65 0.95
1118.69
60
65 0.83 4 94.52
111 8.20
%T
40
80
904.21
750.68
60
1385.60
50
111 8.21
3072.54
1057.8 4
70
1060.65
1313.98
1063.59
60
4 98.36
2742.57
50
1314.29
904.27
70
825.2 5
1314.81
2664.4 2
13 91.70
60
714 .94
13 88.23
903.99
70
106 5.78
26 41.57
80
1 172.14
1172.30
70
%T
1500
1000
400.0
4000.0
5
3000
2000
cm-1
1500
1000
400.0
cm-1
0.0
4000.0
SJ C-. 6-. 4 C. pk
SJC-.7-.3 C.pk
SJC-.8-.2 C.pk
SJC-.9-.1 C.pk
SJ C-6-~1. SP 3601 4000.00 400.00 6. 32 99. 99 4.00 %T 5 1.00
SJC-7-~1. SP 3601 4000.00 400. 00 6.33 100.00 4.00 %T 5 1. 00
SJC-8-~1. SP 3601 4000.00 400. 00 6.94 99. 99 4.00 %T 5 1.00
SJC-9-~1. SP 3601 4000.00 400. 00 8.41 100.00 4.00 %T 5 1. 00
REF 4000 98 .17 2000 9 4.12 600

39 29. 03 96. 31 3457.73 6.32 3072.54 34.70 2942. 22 13.72 2 866.81 27 .40
27 42. 57 64. 87 2641.57 70.96 1976.94 92.78 1706.09 8.85 1 595.75 25 .49
14 49. 01 46. 87 1391.70 54.89 1312.18 43.21 1230.67 36.67 1172.30 60.18
11 18. 21 57. 75 1065.78 74.61 1020.46 81.69 904.93 84.87 8 25. 70 72.12
74 8.60 44.96 712.74 40. 63 650.99 50.6 6 498. 36 61.31
REF 4 000 97.56 2000 95.26 600

3928.72 95.16 3448.97 6 .33 2942.30 17.51 2866.57 30.65 2664.42 74.23
1975.94 93.80 1706.83 1 1.35 1595.69 13.45 1447. 60 45.72 1385.60 47. 60
1348.47 39.04 1314.81 4 5.52 1227.34 42.61 1172. 14 66.61 1118.20 59. 39
1063.59 75.58 1020.14 8 2.05 903. 99 82.04 825.25 75. 63 749.80 49.90
713. 64 48 .66 650.68 54. 43 496.55 59.64
REF 4 000 98.11 2000 96.86 600

3940.59 96.47 3452.56 11.92 2941.41 12.17 2866.33 29. 08 2669.38 86. 88
2064.94 95.65 1709.48 6. 94 1594.76 23.83 1447.10 46.17 1388.23 59.64
1345.67 46.37 1313.98 47.59 1225.04 41.95 1171.48 74. 79 1118.56 59. 00
1060.65 79.52 1019.56 85.60 904.27 81.38 862.42 85.07 825 .20 81.65
750. 11 55 .32 714.94 57.87 650.83 61.6 4 494.52 60.89 416.70 88. 59
REF 4 000 98.82 2000 97.87 600

3450.45 22.38 2940.82 1 6.30 2865.76 38.95 2671. 73 92.85 2066.37 96. 59
1710.56 8. 39 1594. 44 37. 41 1446.30 57.07 1345.87 57.48 1314.29 60.33
1223.65 57.75 1118.69 6 8.75 1057.84 86.19 1019. 04 90.36 904.21 85.71
863. 28 89 .48 750.68 71. 01 650.95 76.54 4 93. 14 71. 85 415.01 93.25
3000
2000
1500
1000
400.0
cm-1
Hexane.p
Hexane.sp 3601 4000.00 400.00 3.24 99.01 4.00 %T
REF 4000 98.71 2000 89.72
3432.69 3.24 2969.84 72.05 2362.02 81.94 2338.24 84.34
1637.62 24.85 1416.40 89.27 1114.27 96.09 1018.58 97.88
FIGURE 7
Table - 7.2
Observations of FTIR spectrums for Cyclohexanone + Hexane mixture:
1 (CH)
Cm-1
3449.14
2940.57
2864.06
2672.30
2363.74
2340.71
2063.86
1871.50
1805.86
1712.06
1638.82
1560.38
1449.88
1424.18
1342.46
1311.99
1264.33
1222.35
1119.02
1053.12
1018.08
991.42
907.55
864.24
750.16
652.90
490.57
414.18
0.9(CH)
+
0.1(HX)
Cm-1
3949.75
3771.50
3412.64
2941.57
2865.04
2672.34
2362.22
2176.21
2063.32
1974.04
1872.14
1806.55
1712.96
1565.33
1423.06
1342.48
1312.47
1222.50
1119.18
1054.06
1018.23
905.55
864.67
750.51
652.67
490.81
414.20
0.8(CH)
+
0.2(HX)
Cm-1
3937.11
3442.57
3002.55
2925.08
2673.82
2125.50
1643.95
1565.63
1416.33
1316.12
1224.12
1114.72
1023.16
952.89
904.60
703.97
654.66
0.7(CH)
+
0.3(HX)
Cm-1
3946.85
3767.63
3414.47
2942.29
2867.14
2670.75
2424.34
2335.89
2176.82
2064026
1969.56
1870.29
1804.88
1713.79
1568.10
1425.86
1314.25
1223.02
1119.55
1056.47
1019.24
902.95
866.88
750.84
652.18
491.71
413.33
*0.6 (CH)
+
0.4(HX)
Cm-1
3412.62
2939.86
2864.54
2670.80
2062.74
1805.81
1712.49
1565.88
1425.10
1341.35
1312.34
1222.32
1118.91
1054.23
1018.06
904.58
864.55
750.33
650.48
490.12
411.32
0.5(CH)
+
0.5(HX)
Cm-1
3934.56
3776.88
3438.20
2943.43
2362.89
2104.26
1635.55
1566.96
1416.20
1347.59
1120.65
1021.85
928.97
653.20
0.4(CH)
+
0.6(HX)
Cm-1
3943.13
2841.84
2865.33
2672.07
2366.07
2174.64
1605.42
1711.74
1638.91
1565.53
1420.73
1342.57
1312.83
1222.37
1119.20
1054.11
1019.45
904.61
863.42
749.84
652.50
491.76
* Maximum shift in the frequency has been observed.

279
0.3(CH)
+
0.7(HX)
Cm-1
3917.10
2942.71
2867.49
2366.67
2085.61
1708.47
1633.93
1565.03
1417.15
1345.31
1221.89
1119.35
1022.23
953.09
619.88
482.36
0.2(CH)
+
0.8(HX)
Cm-1
3912.54
2939.69
2864.30
2671.80
2062.93
1805.79
1712.68
1638.92
1565.12
1449.43
1425.20
1341.99
1312.04
1222.24
1118.98
1053.34
1017.93
906.51
864.38
750.30
652.47
490.44
411.06
0.1(CH)
+
0.9(HX)
Cm-1
3949.77
2968.27
2935.76
2882.46
2363.00
2339.50
2096.41
1638.55
1561.29
1464.64
1415.21
1116.58
1022.17
928.41
652.83
1 (HX)
Cm-1
3432.69
2969.84
2362.02
2338.24
2077.43
1637.62
1416.40
1114.27
1018.58
668.29
Fig-7.2: FTIR spectrums for Cyclohexanone + Heptane mixture:

SPECTRUM 7 : 0.9 (CYC) + 0.1 (HEPTANE)
SPECTRUM 4 :0.6 (CYC) + 0.4 (HEPTANE)
S P E C T R U M 1 : ( 1 )C Y C + ( 0 ) H E P T A N E
90
90
1805.
864.3
75
60
55
1118.
40
40
1 31 1. 99
35
1 11 9 .0 2
14 49 .8 8
50
1565.
1312.
1222.
904.8
750.6
50
40
35
15
15
25
20 00
150 0
1 000
30 00
20 00
1 50 0
10 00
4 00 .0
cm-1
cm -1
R E F 4 00 0 7 5. 8 2 2 0 0 0 7 3. 8 5 6 0 0
3 4 4 9 . 1 4 9 . 9 9 2 9 4 0. 5 7 1 6. 9 9 28 6 4 . 0 6 3 0 . 7 0 2 6 7 2 .3 0 7 2 . 9 7 2 3 6 3 .7 4 7 2 .0 6
2 3 4 0 . 7 1 7 2 . 4 2 2 0 6 3 .8 6 7 1 . 9 1 1 8 7 1 .5 0 7 4 .9 8 1 80 5 . 8 6 70 .4 2 1 7 1 2 .0 6 1 0 . 9 0
1 6 3 8 . 8 2 3 4 . 6 7 1 5 6 0 .3 8 5 1 . 8 5 1 4 4 9 .8 8 4 0 .4 3 1 42 4 . 1 8 40 .5 6 1 3 4 2 .4 6 5 1 . 1 1
1 3 1 1 . 9 9 4 3 . 4 5 1 2 6 4 .3 3 6 8 . 7 4 1 2 2 2 .3 5 4 1 .5 1 1 11 9 . 0 2 44 .1 7 1 0 5 3 .1 2 6 2 . 9 7
1 0 1 8 . 0 8 6 4 . 7 1 9 9 1 .4 2 7 1. 3 8 90 7 . 5 5 6 2 . 34 8 6 4. 2 4 6 6 .3 3 7 5 0 .1 6 5 4 .8 0
6 5 2 . 9 0 5 7 .9 9 4 9 0. 5 7 5 1 . 0 1 4 1 4 .1 8 7 5 . 3 2
REF 4000 97.30 2000 96.56

3412.54 41.25 2939.69 8.78 2864.30 24.31 2671.80 91.01
1805.79 87.03 1712.68 3.67 1638.92 62.60 1565.12 69.26
1425.20 41.46 1341.99 55.83 1312.04 45.61 1222.24 42.10
1053.34 75.65 1017.93 79.48 906.51 73.08 864.38 81.72 750.30
652.47 81.49 490.44 62.00 411.06
ACIC
Tric hy-2
2941.
1000
400.0
SJC_PH~4.SP 3601 4000.00 400.00 3.60 99.05 4.00 %T

REF 4000 98.66 2000 97.05
3947.97 96.20 3413.37 17.48 2940.67 4.98 2865.12 13.52
2364.80 82.89 2176.18 92.86 2063.53 92.59 1972.86 94.98
1805.76 78.03 1712.73 3.60 1565.11 59.37 1425.87 25.04
1312.73 31.34 1222.72 29.20 1119.18 34.28 1054.54 61.71
904.80 59.74 864.87 73.28 750.63 58.25 652.38 72.03 490.89
411.60 90.06
ACIC
Tric hy-2
490 .5
15
1565.
15 00
1000
400. 0
1421 .
15
10
2000
156 6.
20
10
3000
163 7.
286 4.
25
1565.
2 941.
0.0
4 000.0
1500
652. 2
35
3417.
171 2.
342 0.
0.0
4000.0
3000
2000
c m-1
2000
SJC= Phy-
1500
1000
400.0
4000.0
3000
cm-1
20 00
1500
1000
400.0
cm -1
SJC= Phy-
SJC=phy-
SJC= Phy-
SJ105F~1.SP 3601 4000.00 400.00 3.16 99.99 4.00 %T
SJC_PH~2.SP 3601 4000.00 400.00 3.25 99.70 4.00 %T
SJ2053~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T
REF 4000 97.99 2000 94.92

3443.13 3.16 2941.84 20.27 2865.33 37.18 2672.07 92.55
2174.64 90.80 1805.42 88.06 1711.74 18.86 1638.91 26.21
1420.73 23.95 1342.57 56.45 1312.83 55.00 1222.37 56.67
1054.11 72.17 1019.45 73.30 904.61 80.74 863.42 84.57 749.84
652.50 55.49 491.76
REF 4000 99.55 2000 95.24

3417.10 3.25 2942.71 63.39 2867.49 82.73 2366.67 92.47
1708.47 59.45 1633.93 31.67 1565.03 29.28 1417.15 45.43
1221.89 92.00 1119.35 80.63 1022.23 79.15 953.09 97.82
482.36 77.26
REF 4000 77.51 2000 75.64

3420.77 10.00 2941.90 14.59 2864.70 33.43 2672.37 74.95
1712.73 12.85 1637.45 36.29 1566.13 30.42 1421.81 30.86
1312.05 47.82 1221.93 46.61 1118.99 46.80 1053.23 63.26
906.17 66.53 863.71 69.62 750.04 57.50 652.29 55.00 490.59
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 21- 12-2009
FT IR SPECT RUM
Date: 21- 12-2009
1711.
3000
cm-1
ACIC
Tric hy-2
FTIR SPECT RUM

Date: 21-12-2009
15
1712.
2940.
4000.0
750.0
1221.
30
1633.
25
20
0.0
2865.
5
0.0
SJC= PhySJ205B~1.SP 3601 4000.00 400.00 3.67 100.00 4.00 %T
86 3.7
90 6.1
101 8.
1342.
40
1417.
35
1420.
10
3413.
10
4 00 0 .0
400 .0
1425.
15
2939.
0.0
30 00
1222.
20
1712.
1 71 2 .0 6
34 49 .1 4
C yc l oh e x a n o n e .p k
C Y C L O N ~ 1 .S P 3 6 0 1 4 0 0 0. 0 0 4 0 0. 0 0 1 0. 0 0 1 0 0 .0 0 4 .0 0 % T 5 0 . 50
236 3.
50
45
30
3443.
131 2.
10
2 94 0. 57
10
0.0
4 000 .0
%T
40
20
1119.
267 2.
60
55
1708.
50
45
2865.
25
35
30
2864.
70
65
619.8
111 8.
30
40
25
20
%T
1638.
286 4 .0 6
20
491.7
10 53.
482.3
1022.
2942.
55
652.5
1119.
1312 .
75
111 9.
65
60
45
45
1345.
286 7.
70
490.8
1 42 4. 1 8
16 3 8. 82
%T
1222.
1425.
30
12 2 2. 35
30
25
1312.
1449.
3412.
35
80
75
749.8
%T
1054.
85
1221.
80
863.4
904.6
1019.
55
101 8.
50
45
2085.
1342.
1805.
60
652.3
864.8
%T
4 90 .5 7
236 6.
85
2174.
70
65
1805.
1638.
65 2. 90
75 0 .1 6
15 60 .3 8
2672.
80
2063.
2364.
70
65
90
2366.
85
1871.
1972.
90
75
2671.
75
490.4
55
50
45
750.3
60
10 18 .0 8 864 . 24
10 5 3. 12 9 07 .5 5
95
953.0
1054.
1341.
80
906.5
1565.
1 80 5. 86
2176.
3947.
85
1053.
65
206 3 .8 6
2 34 0. 71
652.4
1017.
70
41 4. 18
18 7 1. 50
267 2 .3 0
60
55
411.6
95
2671.
80
9 91 .4 2
1 26 4. 33
1 34 2. 4 6
70
65
100.0
95
90
100.0
2062.
85
2 36 3. 74
80
75
100.0
95
1341.
90
85
100. 0
411.0
95
95
%T
10 0.0
10 0.0
SPECTRUM 2 : (0)CYC +(1)HEPTANE
FT IR SPECT RUM
Date: 21- 12-2009

100.0
100.0
100.0
100.0
100.0
1020.46
3929.03
1019.56
90
90
392 8.72
1976 .94
1019.04
95
863.28
1020.14
90
41 5.01
862.42
206 4.94
3940.59
1171.48
90
90
825.20
206 6.37
85
416.70
2 671.73
80
80
904.93
80
1975.94
2669.38
825.70
496.55
749.80
40
748.60
%T
650.68
1446.30
1447.60
55
1223.65
%T
%T
1345.87
40
713.64
712.74
30
30
2866.3 3
20
1595.75
20
1706.09
2000
1500
1000
400.0
4000.0
3 450.45
10
1595.69
1706.83
10
17 09.48
2000
1500
1000
400.0
4000.0
cm-1
17 10.56
0.0
3000
2000
3449.
20
294 1.41
0.0
3000
cm -1
1638.
15
294 0.82
10
3 452.56
3448.97
0.0
3000
2968.
25
20
1594.76
294 2.30
10
2 942.22
3457.73
4000.0
2935.
30
2866.5 7
10
1561.
35
1594.44
2865.7 6
1230 .67
0.0
652.8
288 2.
40
1225.04
1345.67
1348.47
30
1415.
50
45
40
1447.10
1 227.34
1312.18
286 6.81
20
928.4
1022.
1116.
236 3.
50
750.11
65 0.99
1449.01
30
209 6.
2339.
65
60
111 8.56
50
%T
3072.54
40
1464.
75
70
4 93.14
1118.69
60
65 0.83 4 94.52
111 8.20
50
111 8.21
%T
80
65 0.95
750.68
60
1385.60
904.21
1057.8 4
70
1060.65
1313.98
1063.59
60
4 98.36
2742.57
50
1314.29
904.27
70
825.2 5
1314.81
2664.4 2
13 91.70
60
714 .94
13 88.23
903.99
70
106 5.78
26 41.57
80
1 172.14
1172.30
70
1500
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
400.0
cm-1
0.0
4000.0
SJ C-. 6-. 4 C. pk
SJC-.7-.3 C.pk
SJC-.8-.2 C.pk
SJC-.9-.1 C.pk
SJ C-6-~1. SP 3601 4000.00 400.00 6. 32 99. 99 4.00 %T 5 1.00
SJC-7-~1. SP 3601 4000.00 400. 00 6.33 100.00 4.00 %T 5 1. 00
SJC-8-~1. SP 3601 4000.00 400. 00 6.94 99. 99 4.00 %T 5 1.00
SJC-9-~1. SP 3601 4000.00 400. 00 8.41 100.00 4.00 %T 5 1. 00
REF 4000 98 .17 2000 9 4.12 600

39 29. 03 96. 31 3457.73 6.32 3072.54 34.70 2942. 22 13.72 2 866.81 27 .40
27 42. 57 64. 87 2641.57 70.96 1976.94 92.78 1706.09 8.85 1 595.75 25 .49
14 49. 01 46. 87 1391.70 54.89 1312.18 43.21 1230.67 36.67 1172.30 60.18
11 18. 21 57. 75 1065.78 74.61 1020.46 81.69 904.93 84.87 8 25. 70 72.12
74 8.60 44.96 712.74 40. 63 650.99 50.6 6 498. 36 61.31
REF 4 000 97.56 2000 95.26 600

3928.72 95.16 3448.97 6 .33 2942.30 17.51 2866.57 30.65 2664.42 74.23
1975.94 93.80 1706.83 1 1.35 1595.69 13.45 1447. 60 45.72 1385.60 47. 60
1348.47 39.04 1314.81 4 5.52 1227.34 42.61 1172. 14 66.61 1118.20 59. 39
1063.59 75.58 1020.14 8 2.05 903. 99 82.04 825.25 75. 63 749.80 49.90
713. 64 48 .66 650.68 54. 43 496.55 59.64
REF 4 000 98.11 2000 96.86 600

3940.59 96.47 3452.56 11.92 2941.41 12.17 2866.33 29. 08 2669.38 86. 88
2064.94 95.65 1709.48 6. 94 1594.76 23.83 1447.10 46.17 1388.23 59.64
1345.67 46.37 1313.98 47.59 1225.04 41.95 1171.48 74. 79 1118.56 59. 00
1060.65 79.52 1019.56 85.60 904.27 81.38 862.42 85.07 825 .20 81.65
750. 11 55 .32 714.94 57.87 650.83 61.6 4 494.52 60.89 416.70 88. 59
REF 4 000 98.82 2000 97.87 600

3450.45 22.38 2940.82 1 6.30 2865.76 38.95 2671. 73 92.85 2066.37 96. 59
1710.56 8. 39 1594. 44 37. 41 1446.30 57.07 1345.87 57.48 1314.29 60.33
1223.65 57.75 1118.69 6 8.75 1057.84 86.19 1019. 04 90.36 904.21 85.71
863. 28 89 .48 750.68 71. 01 650.95 76.54 4 93. 14 71. 85 415.01 93.25
3000
2000
1500
1000
400.0
cm-1
Heptane.p
Heptane.sp 3601 4000.00 400.00 3.17 99.99 4.00 %T
REF 4000 83.95 2000 80.08
3449.77 3.17 2968.27 32.42 2935.76 42.98 2882.46 57.01
2339.50 72.71 2096.41 78.11 1638.55 29.09 1561.29 45.85
1415.21 58.44 1116.58 75.81 1022.17 77.56 928.41 83.36
Table - 7.3
Observations of FTIR spectrums for Cyclohexanone + Heptane mixture
1 (CH)
Cm-1
3449.14
2940.57
2864.06
2672.30
2363.74
2340.71
2063.86
1871.50
1805.86
1712.06
1638.82
1560.38
1449.88
1424.18
1342.46
1311.99
1264.33
1222.35
1119.02
1053.12
1018.08
991.42
907.55
864.24
750.16
652.90
490.57
414.18
0.9 (CH)
+
0.1(HP)
Cm-1
3412.54
2939.69
2864.30
2671.80
2062.93
1805.79
1712.68
1638.92
1565.12
1449.43
1425.20
1341.99
1312.04
1222.24
1118.98
1053.34
1017.93
906.51
864.38
750.30
652.47
490.44
411.06
*0.8 CH)
+
0.2 (HP)
Cm-1
3947.97
3413.37
2940.67
2865.12
2671.83
2364.80
2176.18
2063.53
1972.86
1871.69
1805.76
1712.73
1565.11
1425.87
1341.64
1312.73
1222.72
1119.18
1054.54
1018.20
904.80
864.87
750.63
652.38
490.89
411.60
0.7 (CH)
+
0.3(HP)
Cm-1
3443.13
2941.84
2865.33
2672.07
2366.07
2174.64
1805.42
1711.74
1638.91
1565.53
1420.73
1342.57
1312.83
1222.37
1119.20
1054.11
1019.45
904.61
863.42
749.84
652.50
491.76
0.6 (CH)
+
0.4(HP)
Cm-1
3417.10
2942.71
2867.49
2366.67
2085.61
1708.47
1633.93
1565.03
1417.15
1345.31
1221.89
1119.35
1022.23
953.09
619.88
482.36
0.5 (CH)
+
0.5(HP)
Cm-1
3420.77
2941.90
2864.70
2672.37
2363.64
1712.73
1637.45
1566.13
1421.81
1342.75
1312.05
1221.93
1118.99
1053.23
1018.76
906.17
863.71
750.04
652.29
490.59
0.4 (CH)
+
0.6(HP)
Cm-1
3453.13
2951.84
2855.33
2632.07
2346.07
2164.64
1808.42
1716.74
1638.91
1567.53
1428.73
1348.57
1318.83
1225.37
1116.20
1058.11
1012.45
901.61
869.42
743.84
658.50
492.76
280
0.3 (CH)
+
0.7(HP)
Cm-1
3415.53
2936.68
2867.30
2678.80
2061.92
1802.79
1714.68
1636.92
1568.12
1442.43
1424.20
1346.99
1318.04
1223.24
1116.98
1059.34
1012.93
906451
862.38
759.30
656.47
492.44
418.06
0.2 (CH)
+
0.8(HP)
Cm-1
3425.74
2947.96
2869.73
2673.38
2366.64
1718.73
1632.44
1566.13
1424.81
1348.75
1314.02
1226.93
1117.92
1052.23
1018.76
902.17
868.71
755.04
658.29
492.59
0.1 (CH)
+
0.9(HP)
Cm-1
3423.13
2921.84
2825.33
2622.07
2346.07
2184.64
1845.42
1751.74
1688.91
1525.53
1430.73
1342.57
1352.83
1262.37
1169.20
1074.11
1069.45
906.61
867.42
746.84
658.50
499.76
1 (HP)
Cm-1
3449.77
2968.27
2935.76
2882.46
2363.00
2339.50
2096.41
1638.55
1561.29
1464.64
1415.21
1116.58
1022.17
928.41
652.83
Fig-7.3: FTIR spectrums for Cylclohexanone + Benzaldehyde mixture:

ACIC
Tric hy-2
ACIC
Trichy-2
FTIR SPECTRUM
Date: 21-12-2009
90
FT I R SP ECT R UM
D ate: 21 -1 2 - 200 9
21 27 .7 7
80
1071.12
1915.78
2739.45
30
1390.29
826.08
40
30 00
20 00
20
SJ C-1.0 H.pk
748.25
711.65
1234.30
2866.6 1
30
20
20
294 1.90
294 3.23
294 2.44
1596.08
1596.17
10
10
3459.33
17 01.81
10 00
2000
1500
1000
400.0
3000
2000
1500
1000
400.0
1594.85
17 00.39
3450.26
3 455.32
0.0
4000.0
10
1702.34
17 03.62
0.0
3000
cm-1
15 00
1312.30
650.93
70 5.60
1211.11
0.0
4000.0
3000
2000
1500
cm-1
SJC-.2-.8 C.pk
1701.38
4 00 0. 0
3443.28
4000.0
3448.46
0 .0
747.51
708.66
1594.54
0.0
400.0
40
1221.66
2867.49
30
2865.13
746.89
10
746.47
1595.35
1000
30
1648.11
651.13
692.51
1207.81
10
1500
1172.10
1449.77
651.17
40
651.00
1275.09
3072.34
20
15 93 .9 9
cm-1
502.40
1118.21
50
%T
1309.89
20
1308.76
2820.04
30
1 70 9.99
1067.27
1346.06
501.66
747.26
1169.49
10
2000
2644.38
2741.33
60
111 8.46
1449.28
1312.26
651.04
691.30
50
29 41 .0 9
2741.42
50
%T
1450.49
40
1207.55
2944.45
452.34
1452.97
%T
3000
102 0.51
70
1068.11
1390.13
825.64
60
826.41
1391.77
%T
40
2945.26
60
1 35 0.43
34 35 .0 7
2644.03
825.42
526.91
1 117.95
3069.88
50
825.85
1311.25
14 44 .2 8
20
70
1069.62
60
1387.22
2820.26
535.57
%T
30
80
102 0.71
1389.46
70
2739.65
50
%T
1115.63
28 65 .3 7
80
905.45
454.72
116 9.54
921.99
1016.08
1823.61
70
7 52 .3 1
50
1 977.97
2739.06
60
1914.95
1981.63
80
4 94 .0 6
39 29.45
905.98
2360.34
1019.47
1116.75
1350.39
1071.71
90
6 51 .4 9
90
1979.11
454.25
1983.61
70
90 2.94
12 23 .1 3
60
0.0
4000.0
90
908.34
2360.56
80
1 00 .0
10 18 .42
1 05 4.8 0
1 11 9.21
70
100.0
1 978.55
101 6.77
235 6.74
Sp ec tru m Nam e : SJ C- . 1- . 9 C. s p
39 28 .3 5
80
FT IR SPECT RUM
Date: 21- 12-2009
100.0
90
1452.5 3
1915.41
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 21- 12-2009
100.0
Spectrum Name: SJ C-1.0 H.sp
40
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 21- 12-2009
100.0
100.0
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 21- 12-2009
ACI C
St. J os ep h 's C olle g e ( Auton om o u s )
T r ic h y - 2
1000
400.0
4000.0
3000
cm-1
SJC-.3-.7 C.pk
2000
1500
1000
400.0
cm-1
SJC-.4-.6 C.pk
SJC-.5-.5 C.pk
4 00 .0
cm -1
SJC-2-~1. SP 3601 4000.00 400. 00 5.03 99. 90 4.00 %T 5 1.00
SJC-3-~1. SP 3601 4000.00 400. 00 5.71 100.00 4.00 %T 5 1. 00
SJC-4-~1. SP 3601 4000.00 400. 00 5.03 99. 95 4.00 %T 5 1.00
SJC-5-~1. SP 3601 4000.00 400. 00 6.32 100.00 4.00 %T 5 1. 00
REF 4 000 98.71 2000 94.94 600

3443.28 5. 03 2944.45 47 .23 2820.26 56.76 2739.06 69.56 2356.74 87.51
1983.61 94.37 1915.41 95.36 1701.81 9.41 1648.11 21.11 1594.54 11.72
1452.53 64.70 1387.22 55.14 1350.39 57.59 1311.25 55. 35 1207.55 45. 79
1169.54 66.14 1116.75 82.95 1071.12 89.20 1016.77 90. 38 825.85 57.65
746. 89 33 .90 691.30 41.19 651.04 43.6 8 454.72 71.54
REF 4 000 98.88 2000 94.24 600

3459.33 10.05 3069.88 3 6.67 2941.90 22.79 2865. 13 37.71 2739.65 60. 71
2360.56 92.47 1978.55 9 2.73 1915.78 93.66 1703. 62 5.71 1596.08 19.41
1450.49 51.70 1391.77 5 2.45 1309.89 41.12 1211. 11 32.34 1117.95 64. 63
1069.62 76.59 1019.47 8 2.16 908. 34 89.63 826.41 57. 00 747.26 31.04
705. 60 32 .67 651.00 43. 23 526.91 66.18 4 54. 25 72. 51
REF 4 000 98.02 2000 93.62 600

3455.32 5. 03 2943.23 22 .17 2867.49 36.69 2741.42 67.05 2644.03 76.53
2360.34 93.23 1979.11 92.66 1702.34 14.15 1596.17 19. 09 1449.28 52. 52
1390.13 53.94 1312.26 48.08 1221.66 43.56 1118.46 64. 10 1068.11 77. 62
1020.71 83.03 905.98 87 .80 825.64 67.20 747.51 41.19 708.66 38.87
650. 93 46 .69 501.66 60.43
REF 4 000 98.65 2000 94.89 600

3929.45 96.28 3450.26 6 .32 2942.44 22.24 2866.61 37.10 2741.33 68.76
2644.38 76.92 1977.97 9 3.82 1700.39 15.00 1594. 85 19.89 1449.77 54. 05
1389.46 54.41 1346.06 5 2.59 1312.30 48.46 1234. 30 43.99 1172.10 63. 52
1118.21 65.38 1067.27 7 8.84 1020.51 84.56 905.45 89.22 825. 42 69.84
748. 25 43 .95 711.65 40. 63 651.17 49.83 5 02. 40 64. 41
SJ C- . 1- . 9 C. pk
SJ C-10~1.SP 3601 4000.00 400.00 6.34 100.00 4.00 % T 5 1.00

SJ C- 1- ~ 1. SP 36 0 1 4 0 00 .0 0 4 00. 0 0 7. 43
REF 4000 99.03 2000 96.69 600

3928.35 97.64 3435.07 6.34 2941.09 26.56 2865.37 49.20 2127.77 93.90
1709.99 18.80 1593.99 18.45 1444.28 63.06 1350.43 49.90 1223.13 73.49
1119.21 78.97 1054.80 91.51 1018.42 92.75 902.94 88.78 752.31 67.75
651.49 68.80 494.06 68.15
99. 87
4. 00 % T 5 1 . 00
REF 4 000 9 9 .3 9 2 000 9 3. 41 6 00

34 48 . 46 8. 1 2 3 07 2. 34 33 .9 0 2 945 . 26 43 .3 8 2 8 20. 0 4 41 .9 4 2 73 9. 45 5 2 .9 3
19 81 . 63 91 . 86 1 9 14. 9 5 92. 6 3 182 3. 61 9 3. 26 1 70 1. 3 8 7. 43 1 59 5. 35 1 3 .6 2
14 52 . 97 58 . 28 1 3 90. 2 9 51. 7 8 130 8. 76 4 4. 33 1 27 5. 0 9 44 .4 0 12 0 7. 81 33. 34
11 69 . 49 51 . 23 1 1 15. 6 3 76. 9 6 107 1. 71 8 3. 44 1 01 6. 0 8 85 .3 6 92 1 .9 9 9 1 .4 6
82 6. 0 8 49 . 4 3 7 46 . 47 27 . 68 6 92 .5 1 36 .6 2 6 51. 1 3 40. 1 9 53 5 .5 7 7 3. 00
45 2. 3 4 69 . 9 7
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FTIR SPECT RUM

Date: 21-12-2009
1020.46
3929.03
Spectrum Name: SJC-1BD.sp
100.0
100.0
1019.04
863.28
1019.56
90
392 8.72
90
825.20
1171.48
18 24.00
1072.35
41 5.01
862.42
206 4.94
3940.59
FT IR SPECT RUM
Date: 21- 12-2009
100.0
90
1976 .94
FT IR SPECT RUM
Date: 21- 12-2009
100.0
1020.14
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 21- 12-2009
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 21- 12-2009
90
206 6.37
236 3.70
3928.23
924.10
1982.17
416.70
2 671.73
80
80
904.93
80
1975.94
2669.38
70
750.68
60
1385.60
496.55
749.80
50
750.11
%T
650.68
1449.01
40
748.60
1015.97
70
1310.06
452.91
60
1453.8 0
2 738.80
116 9.33
111 8.56
50
%T
1446.30
1447.60
1223.65
50
%T
40
713.64
2819.60
40
1447.10
13 87.26
40
1 227.34
1312.18
545.73
825.54
%T
1345.87
65 0.99
40
4 93.14
1118.69
60
65 0.83 4 94.52
111 8.20
50
111 8.21
3072.54
65 0.95
70
1063.59
60
4 98.36
2742.57
50
1114.11
1913.80
1057.8 4
904.27
1060.65
1313.98
1314.81
2664.4 2
825.70
70
825.2 5
106 5.78
13 91.70
60
%T
80
904.21
1314.29
714 .94
13 88.23
903.99
1172.30
70
26 41.57
80
1 172.14
651 .10
1206.73
712.74
1225.04
1345.67
30
1348.47
30
30
30
69 0.95
1594.44
2865.7 6
30
746.17
1230 .67
2866.5 7
286 6.81
20
2866.3 3
20
1595.75
20
20
1594.76
20
3 450.45
16 97.38
10
0.0
294 2.30
10
2 942.22
1706.09
3457.73
4000.0
10
1595.69
1706.83
2000
10
3 452.56
1500
1000
400.0
4000.0
294 0.82
10
1594.54
17 09.48
17 10.56
0.0
3000
2000
cm -1
1500
1000
400.0
4000.0
cm-1
3446.84
294 1.41
3448.97
0.0
3000
0.0
3000
2000
1500
1000
400.0
4000.0
0.0
3000
2000
cm-1
1500
1000
400.0
4000.0
cm-1
3000
2000
1500
1000
400.0
cm-1
SJ C-. 6-. 4 C. pk
SJC-.7-.3 C.pk
SJC-.8-.2 C.pk
SJC-.9-.1 C.pk
SJC-1BD.pk
SJ C-6-~1. SP 3601 4000.00 400.00 6. 32 99. 99 4.00 %T 5 1.00
SJC-7-~1. SP 3601 4000.00 400. 00 6.33 100.00 4.00 %T 5 1. 00
SJC-8-~1. SP 3601 4000.00 400. 00 6.94 99. 99 4.00 %T 5 1.00
SJC-9-~1. SP 3601 4000.00 400. 00 8.41 100.00 4.00 %T 5 1. 00
SJC-1BD.sp 3601 4000.00 400. 00 6. 32 99. 90 4.00 %T 5 1.00
REF 4000 98 .17 2000 9 4.12 600

39 29. 03 96. 31 3457.73 6.32 3072.54 34.70 2942. 22 13.72 2 866.81 27 .40
27 42. 57 64. 87 2641.57 70.96 1976.94 92.78 1706.09 8.85 1 595.75 25 .49
14 49. 01 46. 87 1391.70 54.89 1312.18 43.21 1230.67 36.67 1172.30 60.18
11 18. 21 57. 75 1065.78 74.61 1020.46 81.69 904.93 84.87 8 25. 70 72.12
74 8.60 44.96 712.74 40. 63 650.99 50.6 6 498. 36 61.31
REF 4 000 97.56 2000 95.26 600

3928.72 95.16 3448.97 6 .33 2942.30 17.51 2866.57 30.65 2664.42 74.23
1975.94 93.80 1706.83 1 1.35 1595.69 13.45 1447. 60 45.72 1385.60 47. 60
1348.47 39.04 1314.81 4 5.52 1227.34 42.61 1172. 14 66.61 1118.20 59. 39
1063.59 75.58 1020.14 8 2.05 903. 99 82.04 825.25 75. 63 749.80 49.90
713. 64 48 .66 650.68 54. 43 496.55 59.64
REF 4 000 98.11 2000 96.86 600

3940.59 96.47 3452.56 11.92 2941.41 12.17 2866.33 29. 08 2669.38 86. 88
2064.94 95.65 1709.48 6. 94 1594.76 23.83 1447.10 46.17 1388.23 59.64
1345.67 46.37 1313.98 47.59 1225.04 41.95 1171.48 74. 79 1118.56 59. 00
1060.65 79.52 1019.56 85.60 904.27 81.38 862.42 85.07 825 .20 81.65
750. 11 55 .32 714.94 57.87 650.83 61.6 4 494.52 60.89 416.70 88. 59
REF 4 000 98.82 2000 97.87 600

3450.45 22.38 2940.82 1 6.30 2865.76 38.95 2671. 73 92.85 2066.37 96. 59
1710.56 8. 39 1594. 44 37. 41 1446.30 57.07 1345.87 57.48 1314.29 60.33
1223.65 57.75 1118.69 6 8.75 1057.84 86.19 1019. 04 90.36 904.21 85.71
863. 28 89 .48 750.68 71. 01 650.95 76.54 4 93. 14 71. 85 415.01 93.25
REF 4 000 99.33 2000 94.67 600

3928.23 97.09 3446.84 6. 32 2819.60 52.37 2738.80 63.28 2363.70 95.08
1982.17 93.61 1913.80 94.42 1824.00 94.71 1697.38 18. 33 1594.54 10. 43
1453.80 66.53 1387.26 52.24 1310.06 55.31 1206.73 48. 10 1169.33 62. 45
1114.11 85.01 1072.35 87.37 1015.97 88.91 924.10 93.62 825.54 55.94
746. 17 35 .49 690.95 41.50 651.10 43.6 5 545.73 67.86 452.91 69. 90
Table - 7.4
Observations of FTIR spectrums for Cyclohexanone + Benzaldehyde mixture:
1(CH)
Cm-1
3930.87
3416.27
2940.92
2864.96
2720.59
2676.41
2063.83
1712.26
1598.04
1445.45
1355.79
1222.93
1119.11
1055.52
1018.37
904.24
864.54
762.30
651.44
491.25
413.81
0.9(CH)
+ 0.1(BD)
Cm-1
0.8(CH)
+ 0.2(BD)
Cm-1
0.7(CH)
+ 0.3(BD)
Cm-1
0.6(CH)
+ 0.4(BD)
Cm-1
0.5(CH)
+ 0.5(BD)
Cm-1
*0.4(CH)
+ 0.6(BD)
Cm-1
0.3(CH)
+ 0.7(BD)
Cm-1
0.2(CH)
+ 0.8(BD)
Cm-1
0.1(CH)
+ 0.9(BD)
Cm-1
3448.46
3072.34
2945.26
2820.04
2739.45
1981.63
1914.95
1823.61
1701.38
1595.35
1452.97
1390.29
1308.76
1275.09
1207.81
1169.49
1115.63
1071.71
1016.08
921.99
826.08
746.47
692.51
651.13
535.57
452.34
3443.28
2944.45
2820.26
2739.06
2356.74
1983.61
1915.41
1701.81
1648.11
1594.54
1452.53
1387.22
1350.39
1311.25
1207.55
1169.54
1116.75
1071.12
1016.77
825.85
746.89
691.30
651.04
454.72
3459.33
3069.88
2941.90
2865.13
2739.65
2360.56
1978.55
1915.78
1703.62
1596.08
1450.49
1391.77
1309.89
1211.11
1117.95
1069.62
1019.47
908.34
826.41
747.26
705.60
651.00
526.91
454.25
3455.32
2943.23
2867.49
2741.42
2644.03
2360.34
1979.11
1702.34
1596.17
1449.28
1390.13
1312.26
1221.66
1118.46
1068.11
1020.71
905.98
825.64
747.51
708.66
650.93
501.66
3929.45
3450.26
2942.44
2866.61
2741.33
2644.38
1977.97
1700.39
1594.85
1449.77
1389.46
1346.06
1312.30
1234.30
1172.10
1118.21
1067.27
1020.51
905.45
825.42
748.25
711.65
651.17
502.40
3929.03
3457.73
3072.54
2942.22
2866.81
2742.57
2641.57
1976.94
1706.09
1595.75
1449.01
1391.70
1312.18
1230.67
1172.30
1118.21
1065.78
1020.46
904.93
825.70
748.60
712.74
650.99
498.36
3928.72
3448.97
2942.30
2866.57
2664.42
1975.94
1706.83
1595.69
1447.60
1385.60
1348.47
1314.81
1227.34
1172.14
1118.20
1063.59
1020.14
903.99
825.25
749.80
713.64
650.68
496.55
3940.59
3452.56
2941.41
2866.33
2669.38
2064.94
1709.48
1594.76
1447.10
1388.23
1345.67
1313.98
1225.04
1171.48
1118.56
1060.65
1019.56
904.27
862.42
825.20
750.11
714.94
650.83
494.52
416.70
3450.45
2940.82
2865.76
2671.73
2066.37
1710.56
1594.44
1446.30
1345.87
1314.29
1223.65
1118.69
1057.84
1019.04
904.21
863.28
750.68
650.95
493.14
415.01
281
1(BD)
Cm-1
3928.23
3446.84
2819.60
2738.80
2363.70
1982.17
1913.80
1824.00
1697.38
1594.54
1453.80
1387.26
1310.06
1206.73
1169.33
1114.11
1072.35
1015.97
924.10
825.54
746.17
690.95
651.10
545.73
452.91
Fig-7.4: FTIR spectrums for Cylclohexanone + Benzyl Chloride mixture:

ACIC
Tric hy-2
ACIC
T ric hy-2
FT IR SPECT RUM
Date: 08- 2-2010
ACIC
T ric hy-2
ACIC
T ric hy-2
ACIC
T ric hy-2
ACIC
T ric hy-2
Spectrum Name: SJC-PH-D-13.sp

100.0
FTIR SPECTRUM
Date: 23-6-2010
1018.37
864 .54
413.81
3930.87
90
2676.41
FTIR SPECTRUM
Date: 23-6-2010
Spectrum Name: T5-0.2+0.8.sp
10 0. 0
80
FTIR SPECTRUM
Date: 23-6-2010
2063.83
FTIR SPECTRUM
Date: 23-6-2010
10 0. 0
10 0. 0
10 0. 0
65 1.44
2720.59
2735.96
90
1055.52 904.24
3938.72
2868.05
70
90
1963.51
2094.44
90
1077.29
4 91.25
3961.87
80
90
1965.52
2341.75
2092.32
70
60
1222.93
2340.84
1118.65
70
2945.41
60
1267.71
2160.51
1266.77
70
70
60
2870.05
50
562.85
%T
20
40
30
1642.59
1439.70
30
1642.92
1705.86
1642.25
294 0.92
495.10
%T
2942.64
40
1443.48
2942.09
30
50
%T
561.19
40
30
1696.36
20
564.90
50
%T
40
30
561.87
50
561.87
%T
40
2864.9 6
1355.79
1259.07
60
1437.36
1266.32
50
1445.45
3416.27
30
1116.77
2869.64
60
1439.41
1446.17
40
2672.64
80
1118.22
1266.68
50
%T
3954.27
3846.65
80
2081.12
3084.07
2953.55
70
111 9.11
90
2340.29
1118.69
2097.92
80
1208.42
60
2672.42
3843.40
2337.88
2346.29
80
762.30
10
FTIR SPECTRUM
Date: 23-6-2010
10 0. 0
20
20
20
1644.06
2940.51
20
695.37
1598.04
694.53
10
1712.26
0.0
4000.0
3000
2000
1500
1000
400.0
10
692.94
10
3 00 0
2 00 0
15 00
10 00
40 0 .0
3 00 0
2 00 0
c m -1
15 00
10 00
40 0 .0
3428.48
3428.60
0. 0
4 00 0. 0
4 00 0. 0
2 00 0
15 00
10 00
40 0 .0
1707.71
3429.92
0. 0
3 00 0
c m -1
693.78
10
694.98
0. 0
4 00 0. 0
SJ666F~1. SP 3601 4000.00 400.00 7.43 100. 00 4.00 %T 5 1. 00

REF 4 000 98.06 2000 95.04 600
3930.87 96.55 3416.27 3 9.48 2940.92 13.42 2864. 96 30.69 2720.59 91. 03
2676.41 92.15 2063.83 9 4.22 1712.26 7. 43 1598.04 15.54 1445.45 43.83
1355.79 28.26 1222.93 5 2.54 1119.11 60.60 1055. 52 81.18 1018.37 85. 37
904. 24 79 .06 864.54 86. 10 762.30 71.15 6 51. 44 84. 16 491.25 69.72
413. 81 91 .89
1706.87
10
3430.60
3429.25
0. 0
cm-1
SJC-PH-D- 13. pk
0. 0
4 00 0. 0
3 00 0
2 00 0
15 00
c m -1
10 00
40 0 .0
4 00 0. 0
3 00 0
2 00 0
c m -1
15 00
10 00
40 0 .0
c m -1
T5-0. 1+0.9.pk
T5-0. 2+0.8.pk
T5-0. 3+0.7.pk
T5-0. 4+0.6.pk
T5-0. 5+0.5.pk
T5-01_~1.SP 3601 4000.00 400.00 6.34 99.99 4.00 %T 5 1.00
T5-02_~1.SP 3601 4000.00 400.00 6.36 100. 00 4.00 %T 5 1.00
T5-03_~1.SP 3601 4000.00 400.00 6.43 100. 00 4.00 %T 5 1.00
T5-04_~1.SP 3601 4000.00 400.00 6.41 99.99 4.00 %T 5 1.00
T5-05_~1.SP 3601 4000.00 400.00 10.10 99. 99 4.00 %T 5 1.00
REF 4000 99.26 2000 96. 11 600

3938. 72 94.00 3429.25 6.34 2953.55 78.43 2868.05 93. 06 2735.96 97. 82
2346. 29 89.15 2094.44 93.12 1963.51 94.84 1696.36 35. 98 1642. 59 30.10
1446. 17 62.90 1267.71 65.07 1208.42 84.86 1077.29 88. 60 692.94 14. 18
562.85 53.66
REF 4000 99.53 2000 95. 63 600

3430. 60 6.36 2945.41 74.05 2337.88 94.71 2097.92 92.42 1642.25 32.13
1439. 41 64.03 1266. 68 73.56 1118.69 88.87 694.53 20.25 561.87 56.45
REF 4000 99.59 2000 94. 75 600

3961. 87 93.14 3843. 40 92.88 3428.60 6.43 3084.07 69.34 2942.09 37.11
2870. 05 66.58 2672. 42 97.25 2340.29 92.24 2081.12 91.26 1965.52 93.20
1706. 87 16.91 1644. 06 26.02 1443.48 46.32 1266.32 57.76 1118.65 76.37
694.98 11.31 561. 19 50.20
REF 4000 99.46 2000 95. 91 600

3428. 48 6.41 2942.64 50.23 2869.64 76.18 2341.75 93. 90 2092.32 92. 79
1705. 86 30.17 1642.92 32.93 1437.36 61.09 1266.77 77. 76 1118. 22 85.02
695.37 25.73 561.87 59. 38
REF 4000 99.17 2000 95. 95 600

3954. 27 95.23 3846.65 92.46 3429.92 10.10 2940.51 26. 77 2672. 64 96.70
2340. 84 92.84 2160.51 92.74 1707.71 15.06 1439.70 46. 83 1259. 07 66.40
1116. 77 75.84 693.78 17.89 564.90 59.29 495.10 65.64
ACIC
Tric hy-2
ACIC
T ric hy-2
ACIC
T ric hy-2
ACIC
T ric hy-2
ACIC
T ric hy-2
FT IR SPECT RUM
Date: 2/14/2009
Spectrum Name: EA+BC-11.sp
FTIR SPECTRUM
Date: 23-6-2010
FTIR SPECTRUM
Date: 23-6-2010
FTIR SPECTRUM
Date: 23-6-2010
10 0. 0
FTIR SPECTRUM
Date: 23-6-2010
10 0. 0
100.0
90
10 0. 0
39 06.50
10 0. 0
80
90
90
2670.46
90
2669.55
3944.24
90
2669.51
2080.23
2338.25
2343.15
80
80
2669.81
2084.29
3939.40
2341.31
2095.48
80
3772.29
70
80
2088.84
2344.19
900.83
892.23
1053.16
70
70
561.17
492.06
1118.94
562.06
465.12
270 8.50
60
1223.82
2336.46
1027.31
1956.03
1600.2 2
30
3435.57
1436.22
1493.17
2960.75
810 .55
1207.69
1439.91
30
30
30
1644.85
695.92
697.16
20
30
694.24
2871.56
2941.55
20
20
20
559.3 7
1 074.43
693.96
40
1435.96
9 27.39
1811.47
189 0.06
2868.60
%T
40
%T
40
50
%T
1320.13
40
494.63
1323.73
50
%T
1434.46
50
1117.94
1225.65
60
496.08
1323.52
50
2871.24
%T
40
70
1117.88
1227.12
60
495.22
50
60
1049.11
70
1118.67
1327.85
1223.61
60
7 59.02
1451.17
3034.41
1266.87
20
10
1708.49
10
3427.60
10
10
3424.65
2 00 0
15 00
10 00
40 0 .0
4 00 0. 0
0. 0
3 00 0
c m -1
2 00 0
2939.32
1709.04
0. 0
3 00 0
0.0
3431.16
1711.02
4 00 0. 0
694.99
10
2939.64
2940.78
0. 0
15 00
10 00
40 0 .0
4000.0
1710.49
0. 0
3433.17
4 00 0. 0
c m -1
3 00 0
2 00 0
15 00
10 00
40 0 .0
4 00 0. 0
3000
2000
1500
1000
400.0
cm-1
3 00 0
2 00 0
c m -1
15 00
10 00
40 0 .0
c m -1
T5-0. 6+0.4.pk
T5-0. 7+0.3.pk
T5-0. 8+0.2.pk
T5-0. 9+0.1.pk
T5-06_~1.SP 3601 4000.00 400.00 6.42 100. 00 4.00 %T 5 1.00
T5-07_~1.SP 3601 4000.00 400.00 10.07 100.00 4. 00 %T 5 1.00
T5-08_~1.SP 3601 4000.00 400.00 6.40 100. 00 4.00 %T 5 1.00
T5-09_~1.SP 3601 4000.00 400.00 8.23 99.96 4.00 %T 5 1.00
REF 4000 99.06 2000 95. 57 600

3427. 60 6.42 2941.55 31.72 2871.24 57.77 2670.46 97.02 2338.25 93.74
2095. 48 91.76 1708. 49 19.24 1644.85 28.54 1434.46 49.21 1327.85 71.75
1223. 61 73.43 1118. 67 75.13 695. 92 26.59 562.06 57.81 495.22 63.12
REF 4000 99.33 2000 96. 62 600

3944. 24 96.24 3424. 65 14.14 2940.78 11.85 2871.56 34.85 2669.55 94.90
2343. 15 93.54 2080. 23 93.77 1711.02 10.07 1439.91 39.45 1320.13 56.70
1223. 82 59.01 1118. 94 64.17 1053.16 80.22 900.83 82.99 697.16 28.24
561.17 67.09 492. 06 64.06
REF 4000 99.35 2000 95. 59 600

3433. 17 6.40 2939.64 15.27 2669.51 96.64 2341.31 93.50 2088.84 92.00
1709. 04 10.13 1435. 96 45.29 1323.52 63.44 1227.12 68.32 1117.88 71.81
694.24 36.13 496. 08 60.45
REF 4000 99.80 2000 96. 31 600

3939. 40 93.21 3431.16 11.48 2939.32 12.63 2669.81 95. 45 2344. 19 93.64
2084. 29 92.85 1710.49 8.22 1436.22 42.62 1323.73 57. 95 1225.65 63. 71
1117. 94 67.64 1049.11 82.69 892.23 82.25 693.96 51.89 494.63 65.04
EA+BC-11. pk
EA9C82~1.SP 3601 4000. 00 400.00 7.08 99.91 4.00 %T 5 2. 00
REF 4 000 98.47 2000 59.62 600
3906.50 94.80 3772.29 83.63 3435.57 39.14 3034.41 25. 24 2960.75 35. 21
2868.60 51.22 2708.50 60.11 2336.46 56.86 1956.03 48. 63 1890.06 51. 79
1811.47 53.04 1600.22 42.75 1493.17 41.14 1451.17 26. 63 1266.87 19. 47
1207.69 41.07 1074.43 41.36 1027.31 49.25 927.39 55.87 810.55 38.57
759. 02 31 .11 694.99 7. 08 559.37 42.03 465.12 60. 85
Table - 7.5
Observations of FTIR spectrums for Cyclohexanone + Benzyl Cholride mixture
1(CH)
Cm-1
3930.87
3416.27
2940.92
2864.96
2720.59
2676.41
2063.83
1712.26
1598.04
1445.45
1355.79
1222.93
1119.11
1055.52
1018.37
904.24
864.54
762.30
651.44
491.25
413.81
0.9(CH)
+
0.1(BC)
Cm-1
3938.72
3429.25
2953.55
2868.05
2735.96
2346.29
2094.44
1963.51
1696.36
1642.59
1446.17
1267.71
1208.42
1077.29
692.94
562.85
0.8(CH)
+
0.2(BC)
Cm-1
3430.60
2945.41
2337.88
2097.92
1642.25
1439.41
1266.68
1118.69
694.53
561.87
*0.7(CH)
+
0.3(BC)
Cm-1
3961.87
3843.40
3428.60
3084.07
2942.09
2870.05
2672.42
2340.29
2081.12
1965.52
1706.87
1644.06
1443.48
1266.32
1118.65
694.98
561.19
0.6(CH)
+
0.4(BC)
Cm-1
3428.48
2942.64
2869.64
2341.75
2092.32
1705.86
1642.92
1437.36
1266.77
1118.22
695.37
561.87
0.5(CH)
+
0.5(BC)
Cm-1
3954.27
3846.65
3429.92
2940.51
2672.64
2340.84
2160.51
1707.71
1439.70
1259.07
1116.77
693.78
564.90
495.10
0.4(CH)
+
0.6(BC)
Cm-1
3427.60
2941.55
2871.24
2670.46
2338.25
2095.48
1708.49
1644.85
1434.46
1327.85
1223.61
1118.67
695.92
562.06
495.22
282
0.3(CH)
+ 0.7(BC)
Cm-1
3944.24
3424.65
2940.78
2871.56
2669.55
2343.15
2080.23
1711.02
1439.91
1320.13
1223.82
1118.94
1053.16
900.83
697.16
561.17
492.06
0.2(CH)
+
0.8(BC)
Cm-1
3433.17
2939.64
2669.51
2341.31
2088.84
1709.04
1435.96
1323.52
1227.12
1117.88
694.24
496.08
0.1(CH)
+
0.9(BC)
Cm-1
3939.40
3431.16
2939.32
2669.81
2344.19
2084.29
1710.49
1436.22
1323.73
1225.65
1117.94
1049.11
892.23
693.96
494.63
1(BC)
Cm-1
3906.50
3772.29
3435.57
3034.41
2960.75
2868.60
2708.50
2336.46
1956.03
1890.06
1811.47
1600.22
1493.17
1451.17
1266.87
1207.69
1074.43
1027.31
927.39
810.55
759.02
694.99
559.37
465.12
Fig-7.5: FTIR spectrums for Cyclohexanone + 2-Butanone mixture:

ACIC
Tric hy-2
ACIC
Trichy-2
ACIC
Tric hy-2
100.0
1018.37
864.54
80
2672.01
2671.09
70
1054.56
904.61
50
50
60
1447.94
30
1355.79
20
752.07
50
4 92.34
2940.92
1598.04
3000
2000
1595.67
40
30
1000
400.0
3000
2000
1000
400.0
3000
2000
1594.77
20
2866.21
1351.48
10
1500
1000
400.0
4000.0
3000
2000
cm-1
10
294 0.14
294 1.89
1595.99
1712.13
294 1.69
0.0
4000.0
2864.72
30
3444.29
20
1348.4 4
3456.40
1500
cm-1
1347.75
40
2866.39
10
0.0
4000.0
1448.26 1313.49
%T
1444.92
1444.77
20
17 12.15
294 0.72
17 11.76
0.0
1500
cm-1
50
4 92.55
1222.88
1223.16
30
2865.20
10
294 0.98
1712.26
4000.0
752.83
111 9.41
%T
1222.70
1313.17
1596.25
20
2865.0 6
3458.27
10
10
4 91.53
111 9.16
60
111 9.47
40
1343.92
1448.0 2
30
3486.61
2864.96
20
0.0
65 1.80
%T
40
1313.97
1347.44
1712.54
3 425.95
0.0
1500
1000
400.0
17 11.65
0.0
15 95.59
4000.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
cm-1
2000
1500
1000
SJC-Ph-2. pk
SJC-Ph-3. pk
SJC-Ph-4. pk
SJC-Ph-5. pk
SJC-Ph-6. pk
SJ666F~1.SP 3601 4000.00 400.00 7.43 100.00 4.00 %T 5 1.00
SJC-Ph-2. sp 3601 4000. 00 400. 00 7.58 100.00 4.00 %T 5 1. 00
SJC-Ph-3. sp 3601 4000. 00 400. 00 7.50 100.00 4.00 %T 5 1. 00
SJC-Ph-4. sp 3601 4000. 00 400. 00 7.33 99.99 4.00 %T 5 1.00
SJC-Ph-5. sp 3601 4000. 00 400. 00 6.67 100.00 4.00 %T 5 1. 00
SJC-Ph-6. sp 3601 4000. 00 400. 00 8.87 100.00 4.00 %T 5 1. 00
REF 4000 98.06 2000 95.04 600

3930.87 96.55 3416.27 39.48 2940.92 13.42 2864.96 30.69 2720.59 91.03
2676.41 92.15 2063.83 94.22 1712.26 7.43 1598.04 15.54 1445.45 43.83
1355.79 28.26 1222.93 52.54 1119.11 60.60 1055.52 81.18 1018.37 85.37
904.24 79.06 864.54 86.10 762.30 71.15 651.44 84.16 491.25 69.72
413.81 91.89
REF 4 000 97.34 2000 96.37 600

3941.98 95.03 3458.27 1 7.89 2940.98 11.48 2865. 06 25.66 2672.01 86. 93
2175.67 92.77 2064.23 9 3.26 1971.59 95.17 1870. 28 94.51 1804.50 83. 19
1711.76 7. 57 1595. 67 17. 94 1447.94 40.63 1347.44 33.99 1313.97 43.78
1222.69 46.44 1119.11 5 2.84 1054.51 75.33 1017. 94 81.43 904.48 71.63
864. 14 80 .18 751.38 63. 17 652.02 74.78 4 91. 26 58. 91 412.78 86.93
REF 4 000 97.50 2000 96.56 600

3938.83 95.20 3486.61 3 0.92 2940.72 10.73 2865. 20 24.67 2671.09 85. 69
2334.58 94.42 2175.95 9 3.18 2063.95 93.35 1971. 50 94.86 1870.77 94. 47
1805.13 82.88 1712.15 7 .50 1633.84 42.74 1596.25 41.54 1448.02 39.83
1343.92 44.12 1313.17 4 3.98 1222.70 43.59 1119. 19 49.62 1054.56 72. 08
1018.22 79.19 904.61 70. 08 864.50 80 .10 750.74 66.53 652.39 79.62
491. 14 60 .66 412.30 88. 11
REF 4 000 96.99 2000 95.42 600

3941.66 93.34 3456.40 9. 17 2941.69 7. 88 2866.39 18.17 267 1.60 82.28
2425.67 95.27 2335.42 93.58 2175.98 90.55 2065.44 91. 20 1970.17 93. 73
1870.36 93.18 1712.13 7. 33 1595.99 11.79 1444.77 31.21 1348.44 26.54
1223.16 40.77 1119.47 47.81 1055.54 71.94 1018.62 79. 94 904.01 69.19
864. 59 79 .53 752.07 58.76 652.13 71.0 4 492.34 54.64 413.79 88. 06
REF 4 000 97.76 2000 96.65 600

3930.88 94.72 3785.94 9 2.03 3425.95 7. 89 2941.89 10.71 2866.21 23.76
2672.09 84.35 2335.31 9 4.61 2175.58 91.97 1970. 58 95.29 1870.08 94. 68
1712.54 7. 87 1595. 59 6.67 1444.92 34 .90 1351. 48 21. 97 1222.88 46.69
1173.09 78.85 1119.41 5 3.87 1055.78 76.45 1018. 44 83.85 903.80 73.44
863. 95 82 .11 752.83 57. 71 651.80 68.48 4 92. 55 55. 19 414.81 87.41
REF 4 000 98.52 2000 97.98 600

3939.27 97.31 3444.29 3 0.13 2940.14 16.16 2864. 72 37.42 2672.28 93. 64
2175.05 95.76 1711.65 8 .86 1594.77 29.37 1448.26 55.70 1347.75 50.15
1313.49 58.91 1222.63 6 0.68 1119.16 66.71 1054. 18 86.31 1018.04 89. 90
905. 04 83 .14 863.78 87. 92 751.37 74.26 6 52. 25 81. 35 491.53 70.87
413. 13 92 .72
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 06- 1-2010
180 4.85
903.84
1053.06
100.0
2 721.81
80
904.56
1055.25
65 2.42
70
905.44
1222.39
90
65 1.99
70
752.27
864 .60
2357.45
FTIR SPECTRUM
Spectrum Name: 2-Butanone
2169.05
379 0.77
415.02
1054.5 5
1313.53
70
11 19.54
652.62
80
111 9.39
60
60
1449.8 9
2834.19
50
111 9.36
%T
491.86
1247.00
3778.25
2863.8 1
50
%T
1815.01
70
586.34
1222.98
50
751.08
2087.47
774.12
4 91.75
90 4.02
3921.99
4 94.26
4 92.42
751.15
60
105 5.43
60
1171.44
90
2175.01
3939.5 7
80
864.25
2175.51
2175.74
2670.63
90
2672.58
2672.25
80
4 13.86
90
70
100.0
863.74
3921.39
412.3 2
1871.35
3941.98
101 8.30
1018.56
1173.23
90
100.0
3931.83
Spectrum Name: SJC-Ph- 10. sp
100.0
1018.04
ACIC
St.Joseph 's College ( Autonomous )
Trichy-2
FT IR SPECT RUM
Date: 06- 1-2010
Spectrum Name: SJC-Ph- 9.sp
100.0
FT IR S PECTR UM
Dat e: 06 -1 -2 01 0
Sp ect rum Na m e: SJ C-Ph -7. sp
80
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 06- 1-2010
400.0
cm-1
SJC-PH-D-13.pk
ACIC
St. J os ep h's C olleg e ( Aut ono m o us )
Tric h y-2
65 2.25
751.37
903.80
50
%T
1222.69
1445.45
3416.27
30
863.78
70
1055.78
60
1222.63
111 9.19
40
40
1018.04
1054.18
863 .95
70
904.01
4 91.14
50
111 9.11
%T
1222.93
750.74
1633.84
4 91.26
%T
2175.0 5
80
26 72.09
2175.5 8
864.59
1055.5 4
60
751.38
2 672.28
905.04
2671.60
65 2.13
60
413.13
3939.27
1870.08
80
187 0.36
1018.62
864.50
70
65 2.02
904.48
491.25
1119.11
90
414.8 1
1173.09
3785.94
2065.44
23 35.42
65 2.39
1805.13
864 .14
1054.51
1970.58
233 5.31
413 .79
80
2175.95
1017.94
70
100.0
3930.88
90
1970.17
2425.67
762.30
60
FT IR SPECT RUM
Date: 06- 1-2010
100.0
2175.9 8
90
2063.95
80
1804.50
1055.52 904.24
70
412.30
1870.77
233 4.58
3941.66
187 0.28
206 4.23
80
651.44
3938.83
1 018.44
1018.22
90
21 75.67
3941.98
2720.59
100.0
1971.50
412.7 8
2063.83
FT IR SPECT RUM
Date: 06- 1-2010
100.0
19 71.59
90
2676.41
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 06- 1-2010
413.81
3930.87
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 06- 1-2010

100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 06- 1-2010
FTIR SPECTRUM
Date: 08-2-2010
SpectrumName: Cyclohexanone
2930.86
%T
60
1445.49
1409.75
1011.07
40
1119.2 8
50
40
1222.78
1448.37
1346.95
%T
1223.01
30
40
1445.36
40
1351.35
%T
294 2.07
30
30
1314.79
50
1117.88
563.2
40
2865.71
17 10.70
30
1594.83
1344.36
1593.26
20
20
20
1594.84
2865.35
30
1360.76
1626.89
3448.12
20
2865.95
3475.7 2
10
3458.65
10
20
10
294 0.50
3437.07
294 0.54
10
2940.74
4000.0
1711.79
3000
17 11.57
1711.95
0.0
2000
0.0
1500
1000
400.0
4000.0
cm-1
4000.0
3000
2000
1500
1000
cm-1
SJ C-P h-7 .p k
SJ C-P h-7 .s p 3 60 1 40 0 0. 00 400 .0 0 7 .84 10 0 .0 0 4. 00 %T 5 1 .0 0
R EF 4 00 0 9 8 .2 4 20 00 9 7 .0 2 6 00
3 9 31 .8 3 96 .1 5 347 5 .7 2 2 4. 90 2 9 40 .74 10 .1 5 2 8 65 .9 5 26 .1 3 267 0.6 3 8 9. 56
2 3 57 .4 5 90 .0 8 217 5 .7 4 9 4. 14 1 7 11 .79 7. 84 1 59 4 .8 3 3 5 .8 8 1 44 5. 36 4 3 .7 8
1 3 44 .3 6 46 .7 0 131 4 .7 9 4 9. 12 1 2 23 .01 49 .9 6 1 1 19 .2 8 57 .2 4 105 5.4 3 7 9. 21
1 0 18 .3 0 85 .1 6 904 .0 2 7 5. 98 86 4 .6 0 84 .3 6 7 5 1 .08 6 9 .3 7 65 2.6 2 7 8 .82
4 9 1. 86 6 4 .3 3 41 3 .8 6 9 0. 77
400.0
159 3.38
0.0
10
0.0
3000
2000
1500
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
400.0
cm-1
0.0
3445.42
SJC-Ph-8. pk
SJC-Ph-9. pk
SJC-Ph-10.pk
SJC-Ph-8. sp 3601 4000. 00 400. 00 7.26 100.00 4.00 %T 5 1. 00
SJC-Ph-9. sp 3601 4000. 00 400. 00 9.63 100.00 4.00 %T 5 1. 00
SJC-PH~1. SP 3601 4000. 00 400. 00 6.50 100.00 4.00 %T 5 1.00
Cl-AN-11.pk
REF 4 000 97.86 2000 96.48 600

3941.98 96.27 3458.65 1 6.44 2940.54 9. 09 2865.35 23.40 2672.25 90.32
2175.51 93.62 1871.35 9 6.24 1804.85 87.89 1711. 95 7.26 1593.26 27.47
1448.37 40.88 1346.95 4 0.04 1313.53 46.24 1222. 78 47.11 1173.23 85. 99
1119.36 55.09 1054.55 8 1.06 1018.04 86.59 905.44 76.63 864. 25 85.20
751. 15 67 .93 652.42 78. 65 491.75 61.55 4 12. 32 90. 08
REF 4 000 98.17 2000 97.25 600

3939.57 96.80 3448.12 2 0.74 2940.50 13.18 2865. 71 33.48 2672.58 92. 77
2175.01 95.21 1711.57 9 .62 1594.84 24.68 1445.49 51.33 1351.35 44.73
1222.98 59.86 1119.39 6 6.51 1055.25 86.13 1018. 56 90.22 904.56 83.81
863. 74 89 .50 752.27 74. 25 651.99 80.62 4 92. 42 69. 00 415.02 91.60
REF 4 000 99.10 2000 98.49 600

3921.39 97.01 3790.77 9 4.70 3437.07 12.79 2942. 07 40.75 2863.81 63. 08
2834.19 65.58 2721.81 8 9.94 2169.05 96.21 1710. 70 30.25 1593.38 6.50
1449.89 70.25 1360.76 2 5.90 1222.39 83.52 1171. 44 93.02 1119.54 84. 70
1053.06 94.37 903.84 94. 36 774.12 66 .41 586.34 73.54 494.26 74.79
Cl-AN-11.sp 3601 4000.00 400.00 6.34 99.17 4.0 0 %T 5 1 .00
4000.0
3000
2000
1500
1000
400.0
cm-1
REF 4000 88.37 20 00 83.26 600

3921.99 87.11 3778.25 73.94 3445.42 6.3 4 2930 .86 71.20 2087.47 82.53
1815.01 86.05 1626.89 35.54 1409.75 68.12 1247.00 74.30 1117.88 55.3 5
1011.07 61.13 563.25 53.03
Table - 7.6
Observations of FTIR spectrums for Cyclohexanone + 2-Butanone mixture:
1(CH)
Cm-1
3930.87
3416.27
2940.92
2864.96
2720.59
2676.41
2063.83
1712.26
1598.04
1445.45
1355.79
1222.93
1119.11
1055.52
1018.37
904.24
864.54
762.30
651.44
491.25
413.81
0.9(CH)
+ 0.1(2B)
Cm-1
0.8(CH)
+ 0.2(2B)
Cm-1
0.7(CH)
+ 0.3(2B)
Cm-1
*0.6(CH)
+ 0.4(2B)
Cm-1
0.5(CH)
+ 0.5(2B)
Cm-1
0.4(CH)
+ 0.6(2B)
Cm-1
0.3(CH)
+ 0.7(2B)
Cm-1
0.2(CH)
+ 0.8(2B)
Cm-1
0.1(CH)
+ 0.9(2B)
Cm-1
3941.98
3458.27
2940.98
2865.06
2672.01
2175.67
2064.23
1971.59
1870.28
1804.50
1711.76
1595.67
1447.94
1347.44
1313.97
1222.69
1119.11
1054.51
1017.94
904.48
3938.83
3486.61
2940.72
2865.20
2671.09
2334.58
2175.95
2063.95
1971.50
1870.77
1805.13
1712.15
1633.84
1596.25
1448.02
1343.92
1313.17
1222.70
1119.19
1054.56
1018.22
904.61
864.50
750.74
652.39
3941.66
3456.40
2941.69
2866.39
2671.60
2425.67
2335.42
2175.98
2065.44
1970.17
1870.36
1712.13
1595.99
1444.77
1348.44
1223.16
1119.47
1055.54
1018.62
904.01
864.59
752.07
652.13
492.34
413.79
3930.88
3785.94
3425.95
2941.89
2866.21
2672.09
2335.31
2175.58
1970.58
1870.08
1712.54
1595.59
1444.92
1351.48
1222.88
1173.09
1119.41
1055.78
1018.44
903.80
863.95
752.83
651.80
492.55
414.81
3939.27
3444.29
2940.14
2864.72
2672.28
2175.05
1711.65
1594.77
1448.26
1347.75
1313.49
1222.63
1119.16
1054.18
1018.04
905.04
863.78
751.37
652.25
491.53
413.13
3931.83
3475.72
2940.74
2865.95
2670.63
2357.45
2175.74
1711.79
1594.83
1445.36
1344.36
1314.79
1223.01
1119.28
1055.43
1018.30
904.02
864.60
751.08
652.62
491.86
413.86
3941.98
3458.65
2940.54
2865.35
2672.25
2175.51
1871.35
1804.85
1711.95
1593.26
1448.37
1346.95
1313.53
1222.78
1173.23
1119.36
1054.55
1018.04
905.44
864.25
751.15
652.42
491.75
412.32
3939.57
3448.12
2940.50
2865.71
2672.58
2175.01
1711.57
1594.84
1445.49
1351.35
1222.98
1119.39
1055.25
1018.56
904.56
863.74
752.27
651.99
492.42
415.02
3921.39
3790.77
3437.07
2942.07
2863.81
2834.19
2721.81
2169.05
1710.70
1593.38
1449.89
1360.76
1222.39
1171.44
1119.54
1053.06
903.84
774.12
586.34
494.26
864.14
751.38
652.02
491.26
412.78
491.14
412.30
283
1(2B)
Cm-1
3921.99
3778.25
3445.42
2930.86
2087.47
1815.01
1626.89
1409.75
1247.00
1117.88
1011.07
563.25
Fig-7.6: FTIR spectrums for Cyclohexanone + Ethyl Acetate mixture:

ACIC
St.Joseph's College( Autonomous )
Trichy-2
ACIC
T ric hy-2
FTIR SPECTRUM
Date: 08-2-2010
ACIC
T ric hy-2
ACIC
T ric hy-2
ACIC
T ric hy-2
ACIC
T ric hy-2
Spectrum Name: Cyclohexanone

100.0
1018.37
864.54
FTIR SPECTRUM
Date: 09-3-2010
413.81
3930.87
90
2676.41
FTIR SPECTRUM
Date: 09-3-2010
Spectrum Name: SJ C-Ph-S-4.sp
10 0. 0
80
FTIR SPECTRUM
Date: 09-3-2010
2063.83
FTIR SPECTRUM
Date: 09-3-2010
10 0. 0
412.01
FTIR SPECTRUM
Date: 09-3-2010
10 0. 0
412.60
10 0. 0
413.43
10 0. 0
413.70
651.44
2720.59
90
1055.52 904.24
90
2364.76 2065.06
2672.44
90
2088.47
3780.79
1382.60
80
651.40
2363.51
907.14
1310.99
491.25
70
1119.11
70
1053.64
1340.94
30
40
2867.07
40
1118.67
904.27
40
1378.25
40
905.15
3514.51
%T
1053.72
30
40
490.84
30
1117.99
846.40
1313.15
30
1444.94
30
1118.03
1053.60
1312.07
1445.48
1229.67
20
10
2940.92
2943.02
20
20
20
1758.93
4000.0
3000
2000
1713.81
10
1500
1000
3 00 0
2 00 0
15 00
10 00
40 0 .0
4 00 0. 0
3 00 0
2 00 0
4 00 0. 0
3 00 0
2 00 0
15 00
10 00
10 00
40 0 .0
4 00 0. 0
3 00 0
2 00 0
15 00
10 00
SJ C-PH~3.SP 3601 4000.00 400.00 6. 19 100.00 4.00 %T 5 2.00

REF 4000 78.90 2000 78. 49 600
3781. 77 76.22 3514. 51 52.70 3409.98 53.77 2940.59 10.35 2865.74 20.22
2671. 35 69.49 2066. 97 76.33 1713.00 6.19 1447.87 28.48 1375.48 41.05
1342. 03 38.85 1312. 07 32.46 1237.99 11.62 1118.03 35.97 1051.28 32.43
905.15 52.69 846. 40 40.14 750.72 53.62 649.90 65. 86 557.71 72.65
490.84 48.89 416. 18 76.61
ACIC
T ric hy-2
ACIC
T ric hy-2
ACIC
Trichy-2
FTIR SPECTRUM
Date: 09-3-2010
FTIR SPECTRUM
Date: 09-3-2010
Spectrum Name: Ethyl Acetate
10 0. 0
90
2671.88
3778.66
80
3778.61
557.86
906.23
70
751.06
2489.19
90
2088.87
1383.37
2671.56
928.0
651.75
80
864.52
905.41 750.29
70
2362.08
80
635.35
1311.35
3161.64
70
1340.51
90
1168.92
2088.74
2358.27
100.0
412.20
412.79
3787.98
FTIR SPECTRUM
10 0. 0
40 0 .0
c m -1
SJ C-Ph-S-7.pk
80
863.98
15 00
c m -1
REF 4000 95.96 2000 95. 35 600

3780. 24 88.11 3411. 44 52.61 2941.63 8.45 2866.50 19.81 2670.81 85.20
2356. 77 90.99 2068. 86 92.99 1714.72 7.81 1445.48 30.76 1378.90 49.70
1313. 15 37.56 1236. 88 12.64 1117.99 41.06 1053.60 40.97 904.27 64.32
853.79 60.72 750. 64 65.05 650.16 79.81 556.60 88. 18 490.88 57.85
413.70 85.04
90
70
490.75
750.55
904.56
2 00 0
SJ C-PH~2.SP 3601 4000.00 400.00 7. 81 100.00 4.00 %T 5 2.00
651.00
1380.39
3 00 0
SJ C-Ph-S-6.pk
REF 4000 97.61 2000 97. 06 600

3781. 38 92.07 3497. 27 48.00 2941.24 10.23 2866.49 23.76 2670.51 88.70
2355. 74 94.20 2070. 74 94.54 1714.04 7.54 1444.94 36.02 1377.64 49.61
1312. 68 42.95 1238. 06 12.43 1117.68 47.17 1052.09 41.30 904.82 69.64
850.74 67.76 750. 70 70.73 649.02 82.80 491.04 62. 50 413.43 88.05
FTIR SPECTRUM
Date: 09-3-2010
2068.09
4 00 0. 0
SJ C-PH~4.SP 3601 4000.00 400.00 7. 54 100.00 4.00 %T 5 2.00
REF 4000 99.20 2000 98. 63 600

3779. 32 92.84 3464.57 55.53 2943.02 27.47 2867.07 48. 04 2672. 44 94.89
2363. 51 96.74 2088.47 96.33 1758.93 20.13 1446.45 55. 59 1378. 25 46.79
1310. 99 61.03 1241.51 7.69 1114.95 62.58 1053.72 38. 81 907.14 85.19
849.95 79.54 751.03 86. 32 638.34 88.40 490.73 81. 03 412.60 96.53
ACIC
T ric hy-2
60
40 0 .0
c m -1
SJ C-Ph-S-5.pk
SJ D905~1.SP 3601 4000.00 400.00 7. 70 99.99 4.00 %T 5 2. 00
2360.34
70
40 0 .0
SJ C-Ph-S-4.pk
2671.04
10 00
1237.99
REF 4000 97.24 2000 96. 69 600

3780. 79 90.13 3411. 76 57.34 2941.37 9.65 2865.51 24.46 2671.56 89.81
2364. 76 95.22 2065. 06 95.03 1713.81 7.48 1447.98 38.66 1382.60 62.10
1340. 94 52.75 1312. 48 43.77 1229.67 28.35 1118.67 46.81 1053.64 57.50
905.48 70.40 864. 26 79.01 750.38 71.71 651.40 85. 64 490.42 62.70
412.01 87.97
10 0. 0
80
1051.28
1713.00
0. 0
SJ D901~1.SP 3601 4000.00 400.00 7. 48 100.00 4.00 %T 5 2.00
FTIR SPECTRUM
Date: 09-3-2010
3778.20
15 00
c m -1
2865.74
2940.59
1714.72
0. 0
SJ C-Ph-S-3.pk
ACIC
T ric hy-2
10
1236.88
2941.63
0. 0
c m -1
SJ666F~1.SP 3601 4000.00 400.00 7.43 100.00 4.00 %T 5 1.00

REF 4000 98.06 2000 95.04 600
3930.87 96.55 3416.27 39.48 2940.92 13.42 2864.96 30.69 2720.59 91.03
2676.41 92.15 2063.83 94.22 1712.26 7.43 1598.04 15.54 1445.45 43.83
1355.79 28.26 1222.93 52.54 1119.11 60.60 1055.52 81.18 1018.37 85.37
904.24 79.06 864.54 86.10 762.30 71.15 651.44 84.16 491.25 69.72
413.81 91.89
90
10
1238.06
1241.51
0. 0
4 00 0. 0
SJC-PH-D-13.pk
413.42
1714.04
10
2941.37
0. 0
10 0. 0
2866.50
10
2941.24
400.0
cm-1
1447.87
20
2866.49
2865.51
1598.04
1712.26
0.0
750.72
3409.98
1312.68
1447.98
30
649.90
50
853.79
3411.44
1117.68
1052.09
1355.79
1342.03
1375.48
2671.35
60
490.88
50
%T
3497.27
750.64
491.04
50
%T
1312.48
2864.96
20
2066.97
3781.77
557.71
60
850.74
1446.45
3464.57
%T
70
1378.90
904.82 750.70
60
1114.95
50
3411.76
%T
416.18
70
1377.64
60
490.42
50
1445.45
3416.27
650.16
2670.81
70
849.95
750.38
60
1222.93
40
80
649.02
905.48
50
%T
556.60
80
2355.74
490.73
864.26
60
2068.86
2356.77
3780.24
2670.51
80
751.03
90
2070.74
638.34
2671.56
80
762.30
90
3781.38
3779.32
70
60
651.34
60
1053.54
60
1381.89
2671.91
864.46
490.93
490.53
2991.58
622.0
1378.64
60
3413.80
3501.95
50
50
%T
50
1116.91
%T
40
1118.41
844.94
1118.80
%T
490.48
40
1449.13
%T
1312.44
1447.89
40
3411.21
50
1056.51
40
1225.64
1637.15
1053.70
1313.24
30
50
750.40
905.61
%T
3493.45
1053.93
40
1379.09
30
1444.69
30
1052.40
2866.30
1312.37
1118.64
30
30
20
20
1763.76
2865.29
1447.56
20
20
2866.55
20
1231.49
1233.98
2942.69
1713.85
10
1242.81
1712.83
10
10
10
2865.37
10
2940.58
2941.59
2941.51
1241.32
0. 0
0. 0
4 00 0. 0
3 00 0
2 00 0
15 00
10 00
40 0 .0
4 00 0. 0
1714.06
1713.29
0. 0
3 00 0
c m -1
2 00 0
15 00
10 00
40 0 .0
4 00 0. 0
c m -1
3449.55
0. 0
3 00 0
2 00 0
15 00
10 00
40 0 .0
4 00 0. 0
0.0
3 00 0
2 00 0
c m -1
15 00
10 00
40 0 .0
4000.0
3000
2000
1500
1000
400.0
cm-1
c m -1
SJ C-Ph-S-8.pk
SJ C-Ph-S-9.pk
SJ C-Ph-S-10.pk
SJ C-Ph-S-11.pk
Cl-AN-1.pk
SJ E905~1.SP 3601 4000.00 400.00 7.48 99.99 4. 00 %T 5 2.00
SJ C-PH~1.SP 3601 4000.00 400.00 7. 63 100.00 4.00 %T 5 2.00
SJ AE41~1.SP 3601 4000.00 400.00 6. 69 100.00 4.00 %T 5 2.00
SJ A651~1.SP 3601 4000. 00 400.00 8.26 99. 99 4.00 %T 5 2.00
Cl-AN-1.sp 360 1 4000.00 4 00.00 6.33 100.00 4.00 %T 5 1 .00
REF 4000 97.39 2000 96. 89 600

3778. 20 89.87 3501.95 58.30 2941.59 10.65 2866.55 24. 05 2671. 04 88.36
2360. 34 93.80 2068.09 95.05 1713.85 7. 48 1444.69 34. 89 1380.39 60. 28
1313. 24 40.80 1233.98 20.54 1118.41 45.28 1053.93 51. 32 904.56 67. 70
863.98 77.30 750.55 69. 40 651.00 83.61 490.93 60. 67 413.42 86.66
REF 4000 97.62 2000 97. 10 600

3787. 98 91.94 3493. 45 51.82 3161.64 76.74 2942.69 19.00 2866.30 35.56
2671. 88 92.46 2358. 27 94.30 2088.74 94.47 1712.83 16.05 1449.13 43.67
1379. 09 39.22 1311. 35 50.60 1241.32 7.62 1168.92 76.15 1116.91 53.11
1052. 40 34.81 906.23 77.10 844.94 42.72 751.06 74.33 635. 35 83.92
557.86 79.85 490. 75 71.81 412.79 89.19
REF 4000 75.70 2000 73. 48 600

3778. 61 65.37 3411. 21 42.81 2941.51 6.68 2865.37 17.25 2671.91 68.29
1714. 06 7.41 1447.56 30.86 1381.89 47.86 1312.37 34.07 1231.49 21.24
1118. 64 37.09 1053. 70 43.97 905. 61 54.98 864.46 61.52 750.40 56.19
651.34 65.91 490. 48 50.28
REF 4000 97.49 2000 96. 94 600

3778. 66 90.23 3413.80 60.94 2940.58 14.43 2865.29 32. 89 2671. 56 92.24
1713. 29 8.25 1447.89 47.51 1383.37 73.34 1340.51 60. 75 1312.44 51. 96
1225. 64 42.35 1118.80 55.58 1053.54 70.66 905. 41 76. 75 864.52 84.16
750.29 76.85 651.75 87. 84 490.53 69.11 412.20 89. 01
REF 4000 99.39 2000 97.58 600

3449.55 6.33 2991.58 69.36 2489.19 98.54 2362.08 89.0 0 2088.87 95.42
1763.76 32.63 1637.15 43.78 1378 .64 67.05 1 242.81 18.73 1056.51 55.12
928.00 97.75 622.08 69.8 6
Table - 7.7
Observations of FTIR spectrums for Cyclohexanone + Ethyl Acetate mixture:
1(CH)
Cm-1
3930.87
3416.27
2940.92
2864.96
2720.59
2676.41
2063.83
1712.26
1598.04
1445.45
1355.79
1222.93
1119.11
1055.52
1018.37
904.24
864.54
762.30
651.44
491.25
413.81
0.9(CH)
+
0.1(EA)
Cm-1
0.8(CH)
+
0.2(EA)
Cm-1
0.7(CH)
+
0.3(EA)
Cm-1
0.6(CH)
+
0.4(EA)
Cm-1
*0.5(CH)
+ 0.5(EA)
Cm-1
3780.79
3411.76
2941.37
2865.51
2671.56
2364.76
2065.06
1713.81
1447.98
1382.60
1340.94
1312.48
1229.67
1118.67
1053.64
905.48
864.26
750.38
651.40
490.42
3779.32
3464.57
2943.02
2867.07
2672.44
2363.51
2088.47
1758.93
1446.45
1378.25
1310.99
1241.51
1114.95
1053.72
907.14
849.95
751.03
638.34
490.73
412.60
3781.38
3497.27
2941.24
2866.49
2670.51
2355.74
2070.74
1714.04
1444.94
1377.64
1312.68
1238.06
1117.68
1052.09
904.82
850.74
750.70
649.02
491.04
413.43
3780.24
3411.44
2941.63
2866.50
2670.81
2356.77
2068.86
1714.72
1445.48
1378.90
1313.15
1236.88
1117.99
1053.60
904.27
853.79
750.64
650.16
556.60
490.88
413.70
3781.77
3514.51
3409.98
2940.59
2865.74
2671.35
2066.97
1713.00
1447.87
1375.48
1342.03
1312.07
1237.99
1118.03
1051.28
905.15
846.40
750.72
649.90
557.71
490.84
416.18
412.01
0.4(CH)
+
0.6(EA)
Cm-1
3778.20
3501.95
2941.59
2866.55
2671.04
2360.34
2068.09
1713.85
1444.69
1380.39
1313.24
1233.98
1118.41
1053.93
904.56
863.98
750.55
651.00
490.93
413.42
284
0.3(CH)
+
0.7(EA)
Cm-1
3787.98
3493.45
3161.64
2942.69
2866.30
2671.88
2358.27
2088.74
1712.83
1449.13
1379.09
1311.35
1241.32
1168.92
1116.91
1052.40
906.23
844.94
751.06
635.35
557.86
490.75
412.79
0.2(CH)
+
0.8(EA)
Cm-1
0.1(CH)
+
0.9(EA)
Cm-1
3778.61
3411.21
2941.51
2865.37
2671.91
1714.06
1447.56
1381.89
1312.37
1231.49
1118.64
1053.70
905.61
864.46
750.40
651.34
490.48
3778.66
3413.80
2940.58
2865.29
2671.56
1713.29
1447.89
1383.37
1340.51
1312.44
1225.64
1118.80
1053.54
905.41
864.52
750.29
651.75
490.53
412.20
1(EA)
Cm-1
3449.55
2991.58
2489.19
2362.08
2088.87
1763.76
1637.15
1378.64
1242.81
1056.51
928.00
622.08
Fig-7.7: FTIR spectrums for Hexane + Heptane mixture:

ACIC
St.Joseph's Colleg e ( Autonomous )
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/17/2009
FT IR SPECT RUM
Date: 3/5/2008
Spectrum Name: Sample -4.sp
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 3/5/2008
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 3/5/2008
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 3/5/2008
Spectrum Name: Hex+Bz-11. sp
FT IR SPECT RUM
Date: 3/5/2008
100.0
100.0
2338.30
100.0
2734.6 7
2339.62
2338.64
90
3 915.97
90
90
237 3.48
20 90.58
80
1120.98
2870.02
60
652.75
607.50
2959 .60
240 5.48
1120.44
70
237 3.95
2097.45
1197.33
26 18.71
80
2870.0 1
237 7.31
1121.63
2098.49
655.39
70
1122.86
70
2959 .73
2960.28
60
2339.1 5
90
3762.46
80
1121.90
2869.55
70
2929.60
2727.89
3750.51
80
2868 .43
70
60
11 96.25
2338.41
90
1197.13
2372.302097.43
2372.322100.58
80
3764.62
70
90
3762.32
1196.69
80
3838 .59
60
60
656.61
1392.73
2958 .69
1393.19
60
606.86
1464.50
606.35
607.48
50
50
%T
50
%T
50
1393.87
%T
50
%T
50
1393.57
%T
607.11
%T
2928 .53
40
40
40
7 12.33
1117.52
30
1415.62
40
40
1636.19
615.48
40
13 90.37
1638.32
30
30
20
20
1636.55
30
30
20
20
1637.32
30
1638.05
2880.66
1028.23
20
20
1628.07
10
10
10
3443.99
0.0
4000.0
10
3443.57
0.0
3000
2000
1500
1000
400.0
344 5.52
0.0
4000.0
3000
2000
cm -1
1500
1000
400.0
4000.0
10
2000
1500
1000
400.0
4000.0
10
2963.34
344 3.87
3444.34
0.0
3000
cm -1
0.0
3000
2000
cm -1
1500
1000
400.0
0.0
4000.0
3000
2000
cm -1
1500
1000
400.0
344 4.54
4000.0
3000
cm -1
2000
1500
1000
Sample -2.pk
Sample -3.pk
Sample -4.pk
Sample -5.pk
Sample -6.pk
HEX_BZ~4.SP 3601 4000.00 400.00 6. 33 9 8.66 4. 00 %T 5 1.00
SAMPLE~2.SP 3601 4000.00 400.00 6. 32 99.82 4.00 %T 3 0.50
SAMPLE~3.SP 3601 4000.00 400.00 6. 32 99.37 4.00 %T 3 0.50
SAMPLE~4.SP 3601 4000.00 400.00 6. 32 99.30 4.00 %T 3 0.50
SA0150~1.SP 3601 4 000.00 400.00 6.32 99.49 4. 00 %T 3 0.50
SA0950~1.SP 3601 4 000.00 400.00 5.02 99.23 4. 00 %T 3 0.50
REF 4000 73.80 2000 56.81 600

3838.59 68.32 3750.51 65.74 3443. 99 6.33 2928.53 47.34 2727.89 65.85
2405.48 63.83 1628.07 19.08 1415. 62 34.75 1117. 52 36. 84 1028. 23 37. 71
712.33 39.7 2 615.48 38. 51
REF 4000 97.36 2000 93.26 600

3915.97 95.60 3764.62 85.95 3443. 57 6.32 2959.60 65.39 2929.60 69.91
2870.02 82.87 2373.48 94.57 2338. 64 96.63 2090. 58 91. 24 1636. 19 41. 18
1392.73 60.54 1196.69 92.30 1120. 98 82.82 652.75 65.73 607. 50 65. 28
REF 4000 95.61 2000 91.14 600

3762.32 82.50 3445.52 6. 32 2960. 28 68.75 2868.43 83.93 2372.32 87.48
2338.30 93.95 2100.58 88.88 1636. 55 37.82 1393. 87 54. 99 1196. 25 87. 87
1120.44 78.05 607.48 59.55
REF 4000 99.16 2000 91.99 600

3444.34 6. 32 2958. 69 62.27 2869. 55 81.89 2372.30 89.99 2339.62 94.81
2097.43 89.64 1638.32 39.59 1393. 19 60.76 1197. 13 93. 32 1121. 90 85. 46
656.61 65.3 7 606.86 65. 33
REF 4000 99.14 2000 90.45 600

3762.46 81.13 3443.87 6. 32 2959. 73 70.00 2870.01 86.87 2373.95 91.14
2338.41 94.97 2097.45 88.13 1637. 32 37.05 1393. 57 57. 58 1197. 33 91. 68
1121.63 82.64 655.39 63.09 606.35 62. 47
REF 4000 93.84 2000 85.92 600

3444.54 5. 02 2963. 34 8.87 2880. 66 32. 87 2734.67 92. 98 2618.71 93. 10
2377.31 85.60 2339.15 95.57 2098. 49 83.63 1638. 05 34. 06 1464. 50 62. 58
1390.37 45.95 1122.86 76.73 607.1 1 54.83
ACIC
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 3/5/2008
FT IR SPECT RUM
Date: 3/7/2008
Spectrum Name: Sample-9. sp
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 3/7/2008
Spectrum Name: Sample-8. sp
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 3/7/2008
FT IR SPECT RUM
Date: 3/7/2008
Spectrum Name: Sample-10.sp
100.0
400.0
cm -1
Hex+Bz-11.pk
Spectrum Name: Sample-11.sp
100.0
100.0
2736 .02
3962.13
2338.53
90
90
3764.86
2607.90
2378.82
2098.42
80
90
3918.22
80
90
3960 .16
80
3772.70
1122.81
70
70
80
2382.26
20 86.71
2099.25
1195.14
70
60
1464.69
70
1122.83
1763.36
20 85.72
60
1122.73
2409.78
3777.70
2968.93
60
1122.49
11 95.75
3774.28
2882.23
60
90
2339.42
181 2.30
2424 .51
70
20 92.97
3772.95
3960.15
80
26 23.58
2382.58
60
1283.78
1465.86
60 4.99
606.54
50
50
%T
50
606.53
%T
1120.95
50
605.92
%T
50
%T
608.79
1465.26
%T
2966.7 7
13 89.93
13 90.22
40
40
40
2 881.30
40
13 89.67
1636.90
30
30
40
1392.11
30
1 632.89
1628.27
30
1 634.40
30
1 634.48
1387.28
2881.5 8
20
20
20
20
20
2 882.61
2966.4 4
10
10
3443.50
4000.0
10
10
10
343 8.87
2963.43
0.0
343 9.77
0.0
3000
2000
1500
1000
400.0
4000.0
cm -1
0.0
3000
2000
1500
1000
400.0
3440.74
4000.0
cm -1
0.0
3000
2000
1500
1000
400.0
2965.03
3441.07
4000.0
0.0
3000
2000
cm -1
1500
1000
400.0
4000.0
cm -1
3000
2000
1500
1000
400.0
cm -1
Sample -7.pk
Sample-8.pk
Sample-9.pk
Sample-10.pk
Sample-11.pk
SA0160~1.SP 3601 4 000.00 400.00 6.38 98.84 4. 00 %T 3 0.50
Sample-8.sp 3601 4000.00 400.00 6.33 97.51 4. 00 %T 3 1.00
Sample-9.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 0. 50
SA1D50~1.SP 3601 4000. 00 400.00 6.31 98 .56 4.00 %T 3 1 .00
SA1560~1.SP 3601 4 000.00 400.00 7.17 98.93 4. 00 %T 3 1.00
REF 4000 93.08 2000 86.76 600

3764.86 77.62 3443.50 6. 38 2963. 43 8.28 2881.58 31. 36 2736.02 92. 11
2607.90 92.48 2378.82 88.57 2338. 53 96.16 2098. 42 84. 67 1636. 90 37. 04
1464.69 61.36 1389.93 47.68 1122. 81 76.74 604.99 60.69
REF 4000 84.55 2000 80.75 600

3918.22 83.54 3772.95 76.26 3439. 77 6.33 2966.44 19.88 2881.30 45.02
2382.58 82.21 2092.97 79.30 1632. 89 35.32 1465. 86 64. 53 1389. 67 42. 54
1122.49 64.85 606.53 56.10
REF 4000 86.60 2000 80.34 600

3960.16 84.69 3772.70 76. 04 3440. 74 6.31 2966.7 7 52.44 2882.23 71.42
2623.58 86.22 2424.51 84. 47 2099. 25 78.9 5 1812.30 83.05 1634. 40 35.68
1392.11 44.16 1195.14 76. 80 1122. 73 64.7 1 605. 92 55.45
REF 4000 86.21 2000 81.84 600

3960.15 84.79 3774.28 76.92 3441. 07 6.31 2968.93 71.85 2382.26 84.07
2339.42 94.42 2086.71 80.32 1634. 48 35.73 1390. 22 47. 88 1195. 75 79. 21
1122.83 68.61 606.54 58.61
REF 4000 87.45 2000 71.02 600

3962.13 84.51 3777.70 72.93 3438. 87 11.47 2965. 03 7.17 2882.61 25.46
2409.78 73.71 2085.72 70.14 1763. 36 73.25 1628. 27 42. 24 1465. 26 54. 42
1387.28 35.79 1283.78 65.39 1120. 95 58.93 608.79 57.38
Table - 7.8
Observations of FTIR spectrums for Hexane + Heptane mixture:
*0.8(HX)
+
0.2(HP)
Cm-1
0.7(HX)
+
0.3(HP)
Cm-1
0.6(HX)
+
0.4(HP)
Cm-1
0.5(HX)
+
0.5(HP)
Cm-1
0.4(HX)
+
0.6(HP)
Cm-1
0.3(HX)
+
0.7(HP)
Cm-1
0.2(HX)
+
0.8(HP)
Cm-1
0.1(HX)
+
0.9(HP)
Cm-1
1(HP)
Cm-1
0.9(HX)
+
0.1(HP)
Cm-1
3443.19
2964.61
2376.18
2095.63
1639.14
3915.97
3764.62
3443.57
2959.60
2929.60
3762.32
3445.52
2960.28
2868.43
2372.32
3444.34
2958.69
2869.55
2372.30
2339.62
3762.46
3443.87
2959.73
2870.01
2373.95
3444.54
2963.34
2880.66
2734.67
2618.71
3764.86
3443.50
2963.43
2881.58
2736.02
3918.22
3772.95
3439.77
2966.44
2881.30
3960.16
3772.70
3440.74
2966.77
2882.23
3960.15
3774.28
3441.07
2968.93
2382.26
3962.13
3777.70
3438.87
2965.03
2882.61
1394.63
1237.74
1196.98
1120.23
656.26
2870.02
2373.48
2338.64
2090.58
1636.19
2338.30
2100.58
1636.55
1393.87
1196.25
2097.43
1638.32
1393.19
1197.13
1121.90
2338.41
2097.45
1637.32
1393.57
1197.33
2377.31
2339.15
2098.49
1638.05
1464.50
2607.90
2378.82
2338.53
2098.42
1636.90
2382.58
2092.97
1632.89
1465.86
1389.67
2623.58
2424.51
2099.25
1812.30
1634.40
2339.42
2086.71
1634.48
1390.22
1195.75
2409.78
2085.72
1763.36
1628.27
1465.26
607.16
1392.73
1196.69
1120.98
607.50
1120.44
607.48
656.61
606.86
1121.63
655.39
606.35
1390.37
1122.86
607.11
1464.69
1389.93
1122.81
604.99
1122.49
606.53
1392.11
1195.14
1122.73
605.92
1122.83
606.54
1387.28
1283.78
1120.95
608.79
1(HX)
285
Cm-1
Fig-7.8: FTIR spectrums for Benzaldehyde + Hexane mixture:

ACIC
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/17/2009
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/17/2009
Spectrum Name: Hex+Bz-1.sp
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/17/2009
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/17/2009
100.0
FT IR SPECT RUM
Date: 2/17/2009
100.0
FT IR SPECT RUM
Date: 2/17/2009
100.0
100.0
100.0
1 071.69
1982.16
90
80
543.19
1826.42
1912.16
90
1072.33
1110.9 3
80
19 11.65
40
40
3392.00
273 8.48
1307.67
1168.30
826.40
3067.51
2 818.96
33 93.85
650.20
826.41
650.77
40
650.57
1306.83
33 95.06 3067.92
30
1167.49
545.50
40
449.83
60
1308.92
1166.99
2 817.92
50
1395.18
1453.28
3068.66
825.84
1288.65 1 168.37
2819.24
650.02
649.75
50
826.37
%T
689.26
%T
688.62
689 .51
344 3.70
40
40
1594.93
1594.88
1204.85
74 5.68
1594.67
1204.72
1204.30
74 6.62
30
1205.68
74 6.19
1018.48
2738.18
1454.3 1
27 37.62
3066.35
650.17
826.36
1112.88
70
1391.72
3391.42
60
1308.56
690.83
2 819.03
30
1204.57
1595.80
74 6.58
30
30
74 6.61
74 6.19
1596.17
20
10
2737.99
2 818.28
%T
826.51
1168.75
689.47
2818.41
690.41
1205.49
1596.15
20
80
450.36
70
1392.28
3066.90
50
1394.21
273 8.25
1308.161167 .94
929.03
2 547.97
101 4.44
450.27
1454.06
3391.13
60
1453.8 8
50
%T
2737.93
3067.04
80
1014.96
1071.85
70
450.49
60
13 92.47
1454.2 6
%T
1393.10
1981.77
3754 .69
1915.13
1826.60
1912.00
450.64
60
50
1454.22
30
80
925.83
101 6.32
101 4.06
450.71
50
90
923.07
1910.37
2965.51
924.21
1912.95
70
101 4.39
60
1109.5 9
2370.07 1981.82
90
542.21
1982.01 1826.43
542.80
540.09
924.06
70
1 110.98
1111.87
1981.61 1825.80
80
2139.27
924.07
70
%T
1110.62
90
2236.15
3856.08
2235.20
3856.01
1 981.96
1071.5 3
1072.42
182 6.68
1072.56
90
20
10
20
10
20
10
20
10
10
1702 .27
1702 .69
1702 .22
0.0
1702 .47
0.0
4000.0
3000
2000
1500
1000
400.0
0.0
4000.0
3000
2000
1500
cm -1
1000
400.0
0.0
4000.0
3000
2000
cm -1
Hex+Bz-1. pk
1702 .49
1500
1000
400.0
0.0
4000.0
3000
2000
cm -1
Hex+Bz-2. pk
1500
1000
400.0
0.0
4000.0
3000
2000
cm -1
Hex+Bz-3. pk
1700.71
1500
1000
400.0
4000.0
3000
cm -1
Hex+Bz-4. pk
2000
1500
1000
Hex+Bz-6. pk
HEB9CA~1.SP 3601 4000.00 400.00 8. 27 9 9.09 4. 00 %T 5 1.00
HEB9CE~1.SP 3601 4000. 00 400.00 7.80 99. 22 4.00 %T 5 1.00
HEB9C2~1.SP 3601 4000. 00 400.00 10.63 9 9.11 4. 00 %T 5 1.00
HEB9C6~1.SP 3601 4000. 00 400.00 8.40 99 .99 4.00 %T 5 1 .00
HEX_BZ~3.SP 3601 4000.00 400.00 9. 86 9 9.23 4. 00 %T 5 1.00
REF 4000 92.26 2000 86.34 600

3856.01 90.52 3393.85 46.16 3067. 04 49.51 2818. 41 44. 59 2737. 93 50. 23
2235.20 91.22 2139.27 91.10 1982. 16 84.60 1911. 65 85. 07 1826. 68 84. 36
1702.22 8. 26 1595. 80 30.55 1454. 26 56.32 1392.47 58.03 1308.16 48.46
1204.57 31.81 1167.94 47.43 1110. 93 73.85 1072. 33 73. 48 1014. 06 73. 77
924.06 81.9 8 826.41 46. 91 746.19 30.22 689. 47 42.35 650 .20 46.94
540.09 83.5 0 450.64 67. 08
REF 4000 94.76 2000 89.96 600

3856.08 93.11 3395.06 44.30 3067. 92 44.11 2819. 03 43. 29 2738. 25 50. 73
2236.15 93.76 1981.61 88.27 1912. 95 88.41 1825. 80 88. 41 1702. 47 7.80
1596.17 30.97 1453.88 58.70 1394. 21 59.03 1306. 83 46. 79 1205. 68 32. 37
1168.75 49.53 1111.87 76.53 1072. 42 78.97 1016. 32 80. 69 925.83 86.07
826.51 50.1 7 746.19 32. 07 690.83 43.67 650. 57 48.64 542 .80 87.24
450.49 73.7 4
REF 4000 95.66 2000 92.16 600

3391.13 67.02 3066.90 62.88 2818. 28 57.05 2737. 99 62. 32 1982. 01 90. 90
1912.00 91.23 1826.43 90.84 1702. 27 10.62 1594. 93 43. 47 1454. 06 68. 37
1392.28 70.62 1308.56 60.92 1204. 72 41.50 1167. 49 59. 39 1110. 62 84. 05
1071.85 83.55 1014.96 84.23 924.2 1 89.78 826. 36 57. 54 746.62 38.97
689.26 53.7 8 650.17 58. 34 542.21 92.08 450. 27 78.20
REF 4000 99.84 2000 96.16 600

3391.42 70.09 3066.35 68.63 2965. 51 80.07 2817. 92 59. 84 2737. 62 65. 08
2370.07 96.25 1981.82 94.85 1910. 37 95.27 1826. 60 94. 62 1702. 49 8.38
1594.67 43.21 1454.31 70.14 1391. 72 73.93 1308. 92 63. 85 1204. 30 40. 13
1166.99 60.60 1109.59 88.40 1071. 69 86.51 1014. 44 86. 78 923.07 94.67
826.37 57.0 9 746.61 35. 79 688.62 53.00 650. 02 58.28 450 .36 80.03
REF 4000 98.44 2000 96.33 600

3754.69 96.07 3443.70 51.89 3068. 66 64.84 2819. 24 66. 54 2738. 18 73. 27
2547.97 89.42 1981.77 95.56 1915. 13 95.57 1700. 71 9.86 1594.88 46.93
1453.28 70.88 1395.18 72.06 1288. 65 60.49 1204. 85 45. 69 1168. 37 64. 08
1112.88 81.67 1071.53 83.86 1018. 48 85.38 929.03 87.61 825. 84 63. 89
745.68 44.7 0 689.51 53. 31 649.75 57.20 545. 50 84.16 449 .83 80.18
ACIC
T richy-2
ACIC
T richy-2
FTIR SPECTRUM
Date: 3/11/2009
3753 .95
1110.58
90
100.0
90
1826.65
1981.74
2680.13
1 015.76
70
80
80
40
50
1595.35
30
2727.89
240 5.48
%T
826.12
1 452.54
3069.23
2 820.54
40
745.66
1287.48
744.29
1202.57
3750.51
50
%T
651.38
40
1417.63
2819.86
40
74 6.32
60
545.52
1115.60
50
11 70.12
822.62
3069.14
%T
1204.30
825.44
141 3.91
3069.09
%T
1021.49
930.58
27 37.52
2 819.11
50
543.49
452.01
60
2736.59
1452.10
928.86
2356.41
1594.92
3838 .59
70
2551.46
2933.15
931.57
1116.42
60
1118.74
2735.88
60
6 49.44
688.44
1 071.89
70
451.51
546.23
2684.53
449.71
1022.40
2556.97
1 167.12
826.57
80
1980.10
19 12.43
1021.16
2962 .26
1913.16
70
1309.49
343 8.06
90
2550.96
1070.57
450.32
1454.7 0
2737.96
2 818.22
50
30
100.0
375 4.42
1915.12
90
1071.97
1392.24
3068.23
60
100.0
1071.2 4
1980.04
80
1983.2 2
70
FT IR SPECT RUM
Date: 2/17/2009
3755 .10
90
Spec trum Name: HEx+BZ-8. sp

923.97
80
%T
FT IR SPECT RUM
Date: 2/17/2009
10 0. 0
19 10.32
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/17/2009
100.0
2407.99
ACIC
T richy-2
ACIC
Trichy-2
FT IR SPECT RUM
Date: 2/17/2009
2928 .53
40
1405.56
6 51.10
705.14
1204.80
30
7 12.33
745.46
1288.79
1204.91
1117.52
30
1415.62
703.88
30
1702 .28
10
0.0
4000.0
1597.28
20
1287.45
3000
2000
1500
1000
cm -1
20
10
1698.70
0.0
4000.0
1692.51
20 00
1 50 0
1 0 00
HEx+BZ-8. pk
HE79C2~1.SP 3601 4000. 00 400. 00 7.90 99.24 4.00 %T 5 1.00
REF 4000 99.04 2000 95.92 600
3446. 29 16. 50 3069. 14 55. 81 2819. 86 59.46 2735.88 70.28 2680.13 76.05
2556. 97 78. 16 2356. 41 62. 48 1981. 74 94.70 1913.16 94.10 1826.65 97.63
1692. 51 7.89 1597.28 35. 66 1417.63 57.01 1287.45 35.28 1202.57 46.05
1118. 74 72. 97 1070. 57 74. 88 1022. 40 80.54 928.86 66.02 822. 62 67. 07
744.29 50. 57 699. 67 32.91 543. 49 68.21 449.71 79.49
4 00 .0
3443.99
0.0
3000
2000
1500
1000
400.0
4000.0
0.0
3000
cm -1
3 0 00
c m -1
REF 4000 93.35 2000 89.96 600

3753.95 90.84 3438.06 53.88 3068. 23 65.86 2818. 22 59. 98 2737. 96 64. 77
2407.99 91.88 1983.22 89.05 1910. 32 89.43 1702. 28 8.00 1594.92 40.22
1454.70 66.39 1392.24 69.28 1309. 49 60.83 1204. 30 38. 00 1167. 12 58. 73
1110.58 82.25 1071.97 80.98 1015. 76 81.09 923.97 89.16 826. 57 54. 58
746.32 34.2 5 688.44 49. 13 649.44 53.68 450. 32 74.01
1596.29
10
1698.35
0. 0
4 00 0 .0
HEC9CE~1.SP 3601 4000.00 400.00 8. 01 9 9.65 4. 00 %T 5 1.00
344 0.06
1628.07
10
3446.29
400.0
Hex+Bz-7. pk
20
699.67
20
10
615.48
1028.23
344 3.57
20
400.0
cm -1
Hex+Bz-5. pk
HEA9C6~1.SP 3601 4000. 00 400.00 7.90 99. 06 4.00 %T 5 2.00

REF 4000 95.76 2000 88.36 600
3392.00 42.17 3067.51 40.85 2818. 96 37.18 2738. 48 43. 57 1981. 96 86. 08
1912.16 86.53 1826.42 85.60 1702. 69 7.90 1596.15 26.12 1454.22 53.83
1393.10 54.44 1307.67 43.97 1205. 49 29.19 1168. 30 43. 76 1110. 98 74. 24
1072.56 74.83 1014.39 75.69 924.0 7 85.56 826. 40 44. 04 746.58 27.49
690.41 39.5 8 650.77 44. 09 543.19 87.96 450. 71 67.18
2000
1500
1000
400.0
4000.0
cm -1
3000
2000
1500
1000
400.0
cm -1
Hex+Bz-9. pk
Hex+Bz-10.pk
Hex+Bz-11.pk
HEX_BZ~1.SP 3601 4000.00 400.00 8. 31 9 8.25 4. 00 %T 5 1.00
HEX_BZ~2.SP 3601 4000.00 400.00 7. 88 9 9.67 4. 00 %T 5 1.00
HEX_BZ~4.SP 3601 4000.00 400.00 6. 33 9 8.66 4. 00 %T 5 1.00
REF 4000 90.78 2000 89.01 600

3755.10 88.09 3443.57 30.77 3069. 09 54.78 2962. 26 59. 31 2819. 11 58. 08
2736.59 66.55 2684.53 74.33 2550. 96 76.84 1980. 04 88. 13 1915. 12 87. 81
1698.35 8. 31 1595. 35 36.75 1452. 10 59.56 1413.91 57.65 1287.48 40.01
1204.80 41.72 1170.12 56.39 1116. 42 70.19 1071. 24 72. 84 1021. 16 75. 88
931.57 70.8 2 825.44 60. 24 745.66 44.11 705. 14 42.12 651 .38 52.70
546.23 72.5 2 451.51 76. 03
REF 4000 98.87 2000 87.61 600

3754.42 95.11 3440.06 26.34 3069. 23 47.77 2933. 15 50. 32 2820. 54 51. 75
2737.52 60.98 2551.46 75.65 1980. 10 86.42 1912. 43 85. 77 1698. 70 7.88
1596.29 27.95 1452.54 49.41 1405. 56 47.92 1288. 79 34. 21 1204. 91 33. 58
1115.60 58.28 1071.89 61.92 1021. 49 63.09 930.58 63.50 826. 12 49. 99
745.46 35.2 1 703.88 35. 16 651.10 43.54 545. 52 66.27 452 .01 70.72
REF 4000 73.80 2000 56.81 600

3838.59 68.32 3750.51 65.74 3443. 99 6.33 2928.53 47.34 2727.89 65.85
2405.48 63.83 1628.07 19.08 1415. 62 34.75 1117. 52 36. 84 1028. 23 37. 71
712.33 39.7 2 615.48 38. 51
Table - 7.9
Observations of FTIR spectrums for Benzaldehyde + Hexane mixture:
1(BD)
Cm-1
3872.55
3752.13
3392.00
3067.51
2818.96
2738.48
1981.96
1912.16
1826.42
1702.69
1596.15
1454.22
1393.10
1307.67
1205.49
1168.30
1110.98
1072.56
1014.39
924.07
826.40
746.58
690.41
650.77
543.19
450.71
0.9(BD)
+
0.1(HX)
Cm-1
0.8(BD)
+
0.2(HX)
Cm-1
0.7(BD)
+
0.3(HX)
Cm-1
0.6(BD)
+
0.4(HX)
Cm-1
0.5(BD)
+
0.5(HX)
Cm-1
*0.4(BD)
+
0.6(HX)
Cm-1
0.3(BD)
+
0.7(HX)
Cm-1
0.2(BD)
+
0.8(HX)
Cm-1
0.1(BD)
+
0.9(HX)
Cm-1
1(HX)
3856.01
3393.85
3067.04
2818.41
2737.93
2235.20
2139.27
1982.16
1911.65
1826.68
1702.22
1595.80
1454.26
1392.47
1308.16
1204.57
1167.94
1110.93
1072.33
1014.06
924.06
826.41
746.19
689.47
650.20
540.09
450.64
3856.08
3395.06
3067.92
2819.03
2738.25
2236.15
1981.61
1912.95
1825.80
1702.47
1596.17
1453.88
1394.21
1306.83
1205.68
1168.75
1111.87
1072.42
1016.32
925.83
826.51
746.19
690.83
650.57
542.80
450.49
3391.13
3066.90
2818.28
2737.99
1982.01
1912.00
1826.43
1702.27
1594.93
1454.06
1392.28
1308.56
1204.72
1167.49
1110.62
1071.85
1014.96
924.21
826.36
746.62
689.26
650.17
542.21
450.27
3391.42
3066.35
2965.51
2817.92
2737.62
2370.07
1981.82
1910.37
1826.60
1702.49
1594.67
1454.31
1391.72
1308.92
1204.30
1166.99
1109.59
1071.69
1014.44
923.07
826.37
746.61
688.62
650.02
450.36
3754.69
3443.70
3068.66
2819.24
2738.18
2547.97
1981.77
1915.13
1700.71
1594.88
1453.28
1395.18
1288.65
1204.85
1168.37
1112.88
1071.53
1018.48
929.03
825.84
745.68
689.51
649.75
545.50
449.83
3753.95
3438.06
3068.23
2818.22
2737.96
2407.99
1983.22
1910.32
1702.28
1594.92
1454.70
1392.24
1309.49
1204.30
1167.12
3446.29
3069.14
2819.86
2735.88
2680.13
2556.97
2356.41
1981.74
1913.16
1826.65
1692.51
1597.28
1417.63
1287.45
1202.57
1118.74
1070.57
1022.40
928.86
822.62
744.29
699.67
543.49
449.71
3755.10
3443.57
3069.09
2962.26
2819.11
2736.59
2684.53
2550.96
1980.04
1915.12
1698.35
1595.35
1452.10
1413.91
1287.48
1204.80
1170.12
1116.42
1071.24
1021.16
931.57
825.44
745.66
705.14
651.38
546.23
451.51
3754.42
3440.06
3069.23
2933.15
2820.54
2737.52
2551.46
1980.10
1912.43
1698.70
1596.29
1452.54
1405.56
1288.79
1204.91
1115.60
1071.89
1021.49
930.58
826.12
745.46
703.88
651.10
545.52
452.01
3838.59
3750.51
3443.99
2928.53
2727.89
2405.48
1628.07
1415.62
1117.52
1028.23
712.33
615.48
1110.58
1071.97
1015.76
923.97
826.57
746.32
688.44
649.44
450.32
286
Cm-1
Fig-7.9: FTIR spectrums for Hexane + 2-Butanone mixture:

ACIC
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 1/24/2009
FT IR SPECT RUM
Date: 1/27/2009
Spectrum Name: RK H 0. 3-0.7.sp
100.0
100.0
90
90
3856.29
FT IR SPECT RUM
Date: 1/27/2009
100.0
100.0
3921.91
90
90
2626.86
442.73
3770.76
80
80
90
2363.97
80
943.46
2112.50
2097.85
3767.49
1110.29
1404.06
866.86
2498.58
2367.63
80
3773.7 9
2366.47
80
1107.70
20 78.06
70
2100.44
70
751.14
3952.3 1
210 4.86
80
1 422.03
1110.60
3771.15
1410.72
20 87.02
1170 .28
70
1171 .54
70
179 0.00
1735.79
2363.47
70
1 366.54
1 368.01
606.37
2382.32
60
90
941.67
1088.5 8
2369.27
2725.15
3755 .04
70
ACIC
T richy-2
FT IR SPECT RUM
Date: 1/27/2009
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 1/27/2009
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 1/27/2009
Spectrum Name: RK H 0- 1.sp
665.02
1425.35
60
2860.10
2982 .89
60
5 89.29
623.44
60
5 89.32
600.71
60
60
2974.55
573.84
50
50
2927 .98
%T
50
%T
50
%T
50
%T
50
1736.49
%T
%T
1 113.20
40
1 636.90
40
1407.50
40
1172 .15
30
20
40
40
1636.89
1 633.52
1637.25
1636.57
30
20
40
1 365.79
2983 .14
30
30
20
1736.88
30
20
30
20
20
1626.68
10
10
10
343 7.82
0.0
4000.0
10
3451.21
0.0
3000
2000
1500
1000
400.0
3000
2000
1500
1000
400.0
4000.0
10
10
3457.44
3442.39
0.0
4000.0
cm -1
3450.96
0.0
3000
2000
cm -1
1500
1000
400.0
344 7.85
0.0
4000.0
3000
2000
cm -1
1500
1000
400.0
0.0
4000.0
3000
2000
cm -1
1500
1000
400.0
4000.0
3000
cm -1
2000
1500
1000
RK H 0.1-0.9 .pk
RK H 0.2-0.8 .pk
RK H 0.3-0.7 .pk
RK H 0.4-0.6 .pk
RK H 0.5-0.5 .pk
RKH0-1~1. SP 3601 4000.00 4 00. 00 6.36 98.75 4.00 %T 5 1.00
RKH01-~1. SP 3601 4000.00 4 00. 00 6.32 100.00 4.00 %T 5 1.00
RKH02-~1. SP 3601 4000.00 4 00. 00 6.32 100.00 4.00 %T 5 1.00
RKH03-~1. SP 3601 4000.00 4 00. 00 6.33 100.00 4.00 %T 5 1.00
RKH04-~1. SP 3601 4000.00 4 00. 00 6.32 99.99 4.00 %T 5 1.00
RKH05-~1. SP 3601 4000.00 4 00. 00 6.32 99.44 4.00 %T 5 1.00
REF 4000 93.53 2000 75.30 600

3856.29 85.07 3755.04 78.56 3437. 82 6.36 2927.98 56.76 2860.10 66.08
2725.15 76.93 2626.86 79.50 2498. 58 78.86 2382. 32 75. 27 2100. 44 74. 69
1790.00 73.57 1626.68 21.69 1407. 50 44.85 1113. 20 52. 09 866.86 83.19
623.44 61.6 3 573.84 61. 51 442.73 79.42
REF 4000 99.09 2000 93.09 600

3770.76 91.69 3451.21 6.32 2983. 14 40.57 2369.2 7 91.86 2112.50 90.25
1736.88 24.28 1636.90 46. 89 1425. 35 66.7 5 1365.79 45.92 1172. 15 46.79
1088.58 90.14 943. 46 84.94 751.14 74.13 589.29 65.55
REF 4000 93.55 2000 90.44 600

3442.39 6. 32 2363.97 87.57 2078. 06 89.30 1636.5 7 41.37 1404.06 84.39
1110.29 89.82 665. 02 69.99
REF 4000 91.30 2000 88.85 600

3921.91 89.99 3773.79 85. 99 3457. 44 6.33 2367.6 3 88.22 2087.02 87.88
1636.89 42.85 1410.72 83. 80 1107. 70 85.9 0 606. 37 72.27
REF 4000 99.23 2000 94.43 600

3767.49 92.66 3450.96 6. 32 2982. 89 70.14 2366.47 91.58 2097.85 92.68
1736.49 56.17 1637.25 43.59 1422. 03 85.54 1366. 54 75. 09 1171. 54 76. 45
941.67 96.6 2 589.32 69. 79
REF 4000 98.33 2000 88.98 600

3952.31 96.07 3771.15 84.78 3447. 85 6.32 2974.55 65.76 2363.47 76.63
2104.86 86.82 1735.79 77.32 1633. 52 46.02 1368. 01 77. 12 1170. 28 81. 14
1110.60 86.26 600.71 70.39
ACIC
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 1/27/2009
FT IR SPECT RUM
Date: 1/27/2009
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 1/27/2009
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 1/27/2009
FT IR SPECT RUM
Date: 1/27/2009
100.0
400.0
cm -1
RK H 0-1.pk
Spectrum Name: RK H 1- 0.sp
100.0
100.0
1259.45
391 9.93
3907.24
90
90
942.63
3769.68
90
3775.65
2368.73
80
2361.63
80
2098.86
1087.65
90
3957 .00
90
3963.75
2100.69
3776.6 1
2364.40
80
211 5.17
80
2363.58
3774.8 9
943.56
1171 .35
70
1167.09
70
1170 .47
1115.82
3775.59
588.55
70
753.72
70
2364.48
70
1 367.97
1 380.34
1736.42
5 91.28
60
60
60
50
1382.96
20 97.24
60
5 93.01
61 4.13
1465.81
50
%T
40
1465.35
1466.16
1 634.05
50
%T
1636.57
13 76.54
60
5 88.95
1422.14
1737.27
50
%T
40
80
2087.18
1461.93
50
%T
40
1636.45
%T
40
40
1 634.47
2965.81
1 633.55
1 365.82
2882.41
1172 .40
30
30
20
30
2981 .15
20
30
2882.43
2882 .80
20
30
20
20
1735.24
2964.12
10
10
10
3452.92
345 5.17
0.0
3000
2000
1500
1000
400.0
4000.0
10
0.0
3000
2000
cm -1
1500
1000
400.0
4000.0
cm -1
10
345 0.00
2965.63
0.0
3451.42
4000.0
2963.80
0.0
3000
2000
1500
1000
400.0
4000.0
0.0
3000
2000
cm -1
1500
1000
400.0
344 9.68
4000.0
cm -1
3000
2000
1500
1000
400.0
cm -1
RK H 0.6-0.4 .pk
RK H 0.7-0.3 .pk
RK H 0.8-0.2 .pk
RK H 0.9-0.1 .pk
RK H 1-0.pk
RKH06-~1. SP 3601 4000.00 4 00. 00 6.33 100.00 4.00 %T 5 1.00
RKH07-~1. SP 3601 4000.00 4 00. 00 6.32 100.00 4.00 %T 5 1.00
RKH08-~1. SP 3601 4000.00 4 00. 00 7.34 99.99 4.00 %T 5 1.00
RKH09-~1. SP 3601 4000.00 4 00. 00 6.32 99.99 4.00 %T 5 1.00
RKH1-0~1. SP 3601 4000.00 4 00. 00 6.32 99.99 4.00 %T 5 1.00
REF 4000 99.10 2000 93.66 600

3907.24 98.01 3769.68 92. 18 3451. 42 6.33 2965.8 1 44.27 2368.73 91.95
2098.86 91.94 1737.27 60. 36 1636. 57 46.8 3 1461.93 83.87 1367. 97 75.33
1171.35 77.58 942. 63 97.16 591.28 68.27
REF 4000 99.29 2000 94.17 600

3775.65 93.36 3455.17 6.32 2981. 15 34.35 2361.6 3 90.81 2115.17 91.16
1735.24 21.06 1636.45 44. 74 1422. 14 60.1 4 1365.82 39.63 1259. 45 91.23
1172.40 41.11 1087.65 89. 22 943.56 80.00 753.72 74.54 588.95 65.65
REF 4000 98.88 2000 94.62 600

3957.00 97.52 3776.61 91.03 3452. 92 15.60 2965. 63 7.34 2882.80 29.34
2364.40 91.63 2100.69 93.43 1736. 42 68.63 1634. 05 59. 54 1466. 16 65. 99
1376.54 70.47 1170.47 80.05 588.5 5 77.06
REF 4000 98.28 2000 89.89 600

3963.75 96.94 3774.89 87.55 3450. 00 6.32 2963.80 8.78 2882.43 30. 01
2363.58 88.32 2087.18 88.17 1634. 47 45.21 1465. 35 65. 82 1380. 34 73. 29
1167.09 87.27 593.01 64.46
REF 4000 92.19 2000 80.27 600

3919.93 90.20 3775.59 79.25 3449. 68 6.32 2964.12 19.48 2882.41 41.18
2364.48 76.31 2097.24 78.71 1633. 55 44.51 1465. 81 70. 76 1382. 96 72. 85
1115.82 81.05 614.13 65.14
Table - 7.10
Observations of FTIR spectrums for Hexane + 2-Butanone mixture:
1(HX)
0.9(HX)
+
0.1(2B)
Cm-1
0.8(HX)
+
0.2(2B)
Cm-1
0.7(HX)
+
0.3(2B)
Cm-1
0.6(HX)
+
0.4(2B)
Cm-1
0.5(HX)
+
0.5(2B)
Cm-1
0.4(HX)
+
0.6(2B)
Cm-1
Cm-1
3856.29
3755.04
3437.82
2927.98
2860.10
2725.15
2626.86
2498.58
2382.32
2100.44
1790.00
1626.68
1407.50
1113.20
866.86
623.44
573.84
442.73
3770.76
3451.21
2983.14
2369.27
2112.50
1736.88
1636.90
1425.35
1365.79
1172.15
1088.58
943.46
751.14
589.29
3442.39
2363.97
2078.06
1636.57
1404.06
1110.29
665.02
3921.91
3773.79
3457.44
2367.63
2087.02
1636.89
1410.72
1107.70
606.37
3767.49
3450.96
2982.89
2366.47
2097.85
1736.49
1637.25
1422.03
1366.54
1171.54
941.67
589.32
3952.31
3771.15
3447.85
2974.55
2363.47
2104.86
1735.79
1633.52
1368.01
1170.28
1110.60
600.71
3907.24
3769.68
3451.42
2965.81
2368.73
2098.86
1737.27
1636.57
1461.93
1367.97
1171.35
942.63
591.28
287
1(2B)
*0.3(HX)
+
0.7(2B)
Cm-1
0.2(HX)
+
0.8(2B)
Cm-1
3775.65
3455.17
2981.15
2361.63
2115.17
1735.24
1636.45
1422.14
1365.82
1259.45
1172.40
1087.65
943.56
753.72
588.95
3957.00
3776.61
3452.92
2965.63
2882.80
2364.40
2100.69
1736.42
1634.05
1466.16
1376.54
1170.47
588.55
0.1(HX)
+
0.9(2B)
Cm-1
Cm-1
3963.75
3774.89
3450.00
2963.80
2882.43
2363.58
2087.18
1634.47
1465.35
1380.34
1167.09
593.01
3919.93
3775.59
3449.68
2964.12
2882.41
2364.48
2097.24
1633.55
1465.81
1382.96
1115.82
614.13
Fig-7.10: FTIR spectrums for Hexane + Ethyl Acetate mixture:

ACIC
T richy-2
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FT IR SPECT RUM
Date: 2/18/2009
Spectrum Name: EA+Hex-6.sp
FTIR SPECTRUM
Date: 2/18/2009
FTIR SPECTRUM
Date: 2/18/2009
Spec trum Name: EA+Hex-1.sp
FTIR SPECTRUM
Date: 2/18/2009
10 0. 0
FTIR SPECTRUM
Date: 2/18/2009
10 0. 0
FTIR SPECTRUM
Date: 2/18/2009
10 0. 0
10 0. 0
100.0
3855.32
90
3768.40
2093.17
80
3917.93
90
90
3964.09
2091.73
2365.35
80
90
90
3905.70
90
2493.14
930.11
2088.86
80
3772.12
80
2384.79
3770.59
80
929.20
70
80
607.99
2379.02
2092.59
70
3772.03
70
70
3769.87
2931.38
1753.54
1379.58
60
1050.10
60
2988.62
2990.04
60
1378.06
1377.68
1055.31
50
2928.11
558.53
50
1243.52
%T
40
50
%T
40
1760.91
1636.38
1628.57
30
20
50
40
40
30
1049 .37
1371.21
1636.66
1634.83
1634.91
30
20
2960.84
557.41
%T
40
1629.98
1762.09
30
1762.57
%T
40
533.17
50
%T
1049.25
2928.17
1054.23
50
1055.03
%T
60
1242.46
1381.22
60
547.94
617.11
1378.55
2859.60
1111.63
2859.61
616.31
2929.67
2990.08
70
1110.54
2087.94
3774.67
2098.42
70
60
931.21
2378.76
10 0. 0
3972.80
1242.66
30
1243.04
20
30
20
1 741.82
20
20
10
1241.77
3448.96
1242.99
10
10
0. 0
4 00 0 .0
10
3 0 00
20 00
1 50 0
1 0 00
4 00 .0
4 00 0 .0
10
10
3450.82
3449.73
0. 0
3449.31
0. 0
3 0 00
20 00
1 50 0
c m -1
1 0 00
4 00 .0
4 00 0 .0
3 0 00
20 00
c m -1
1 50 0
1 0 00
4 00 .0
4 00 0 .0
0.0
4000.0
3448.68
3448.93
0. 0
3 0 00
20 00
1 50 0
c m -1
1 0 00
4 00 .0
3 0 00
20 00
1 50 0
1 0 00
4 00 .0
EA+Hex-3.pk
EA+Hex-4.pk
EA+Hex-5.pk
EA31CE~1. SP 3601 4000.00 400.00 6.32 99. 74 4.00 %T 5 1.00
EA31C2~1.SP 3601 4000. 00 400. 00 6.32 100.00 4. 00 %T 5 1. 00
EA_HEX~4.SP 3601 4000.00 400.00 6. 34 99. 37 4.00 %T 5 1.00
EA_HEX~3.SP 3601 4000.00 400.00 6. 32 99. 58 4.00 %T 5 1.00
EA_HEX~2.SP 3601 4000.00 400.00 6. 33 100.00 4.00 %T 5 1.00
REF 4000 98.67 2000 92.84 600

3964. 09 97. 24 3772. 12 85. 75 3449. 31 6.32 2990.08 60.70 2929.67 61.59
2365. 35 87. 76 2091. 73 90. 07 1762. 09 38.27 1629.98 42.76 1378.55 59.41
1242. 99 19. 75 1055. 03 53. 73 930.11 96.52 616. 31 66. 89
REF 4000 90.10 2000 82.09 600

3917. 93 87. 95 3772.03 75.37 3449.73 6.32 2928. 11 60. 34 2859.61 70.81
2098. 42 80. 11 1753.54 71.73 1628.57 40.24 1379. 58 66.33 1243.52 54.28
1111. 63 69. 40 1050.10 65.81 558.53 59.86
REF 4000 93.46 2000 89.84 600

3770. 59 84. 10 3450. 82 6.34 2988.62 65.19 2493.14 92.57 2384.79 92.61
2088. 86 87. 78 1760. 91 43. 61 1636. 38 42.22 1378.06 64.36 1243.04 26.35
1054. 23 58. 75 929.20 92. 46 617. 11 61.12
REF 4000 93.21 2000 89.78 600

3972. 80 91. 82 3774. 67 85. 42 3448. 93 6.32 2990.04 70.32 2931.38 71.65
2087. 94 87. 89 1762. 57 53. 80 1634. 83 42.26 1377.68 67.09 1242.66 37.01
1055. 31 65. 42 547.94 64. 74
REF 4000 84.37 2000 81.95 600

3905. 70 82. 45 3769.87 73.71 3448.68 6.33 2928. 17 62. 66 2859.60 72.71
2379. 02 81. 84 2092.59 80.92 1634.91 39.67 1381. 22 68.07 1242.46 68.75
1110. 54 69. 20 1049.25 68.98 557.41 62.66
ACIC
Trichy-2
ACIC
St.Joseph' s College ( Autono mous )
Trichy-2
FTIR SPECTRUM
Date: 2/18/2009
100. 0
3906.07

10 0. 0
90
90
90
3964.69
90
80
3964.48
3964.05
80
80
3964.24
80
3770.91
2491.89
70
80
930.32
70
3773.07
70
70
2091.99
70
60
60
60
50
1116.49
%T
2091.46
60
50
608.91
%T
609.33
1410.74
50
2405.75
40
1115.31
50
2110.78
%T
1378.57
1410.61
1757.54
619.94
40
2109.27
3772.97
3772.43
60
50
%T
3772.57
%T
2928.27
40
1245.29
40
615.47
621.67
1627.25
40
2929.40
30
1056.01
30
2932.51
2964.89
20
1763.72
10
30
1117.56
30
1627.09
2119.44
1408.65
30
1377.93
20
FTIR SPECTRUM
Date: 2/18/2009

10 0. 0
Sp ectrum Name: EA+Hex-9.sp
1 00. 0
90
400.0
REF 4000 98.40 2000 91.37 600

3855.32 96.93 3768.40 91.09 3448. 96 6.32 2960.84 53.32 2378.76 92.67
2093.17 89.21 1741.82 27.67 1636. 66 37.95 1371. 21 44. 99 1241. 77 24. 20
1049.37 53.91 931.21 96.86 607.99 71. 80 533.17 68.16
ACIC
Trichy-2
FTIR SPECTRUM
Date: 2/18/2009
FTIR S PECTRUM
Date: 2/18 /2 009
Spectrum Name: EA+Hex-8 .s p
1000
EA_HEX~1. SP 3601 4000.00 400. 00 6.32 99.36 4.00 %T 5 1.00
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECTRUM
Date: 2/18/2009
1500
EA+Hex-6.pk
c m -1
EA+Hex-2.pk
2000
cm -1
4 00 0 .0
c m -1
EA+Hex-1.pk
10 0. 0
3000
0. 0
1055.57
1625.96
1627.46
20
2928.11
1619.21
20
10
1763.23
10
20
10
10
3448.84
1242.87
3446.90
0. 0
4 00 0 .0
3448.43
1242.94
3 0 00
20 00
1 50 0
1 0 00
c m -1
4 00 .0
40 00. 0
3000
20 00
15 00
3437.12
0. 0
0. 0
1 000
4 00. 0
cm-1
0. 0
3447.13
4000.0
4 00 0 .0
3000
2000
1500
1000
cm-1
EA+Hex-7.pk
EA+Hex -8.pk
EA41C6~1.SP 3601 4000. 00 400. 00 7.59 99.33 4.00 %T 5 1.00
EA51CA~1.SP 360 1 40 00. 00 40 0.00 6.93 100.00 4.00 %T 5 1.00
REF 4000 98.10 2000 78.25 600

3906. 07 96. 10 3770. 91 83. 08 3448. 84 7.59 2964.89 26.03 2491.89 78.46
2091. 99 75. 63 1763. 72 21. 24 1627. 25 39.37 1378.57 42.71 1242.87 8.65
1056. 01 36. 36 930.32 79. 15 619. 94 57.13
REF 4 000 97.12 2000 48.79 600

39 64.69 94.69 3773.07 81.25 3446.90 6.93 2932.51 35.60 2405.75 51.64
20 91.46 47.39 1763.23 17.31 1627.46 25.19 1377.93 31.18 1242.94 8.11
10 55.57 28.88 621.67 47 .0 0
0. 0
EA+Hex-9.pk
EA51CE~1.SP 3601 4000.00 400.0 0 6.34 100.00 4.00 %T 5 1.00
REF 4000 84.74 2000 61.21 600
3964.05 83.34 3772.43 70.77 3447.13 6.34 2929.40 43.90 2110.78 59.07
1757.54 65.65 1625.96 32.05 1410.74 56.65 1245.29 58.90 1116.49 59.46
609.33 58.59
3 0 00
20 00
1 50 0
1 0 00
4 00 .0
4 00 0 .0
3 0 00
20 00
c m -1
400.0
1 50 0
1 0 00
4 00 .0
c m -1
EA+Hex-10.pk
EA+Hex-11.pk
EA0607~1. SP 3601 4000.00 400.00 6.33 100.00 4.00 %T 5 1.00
EA0E07~1.SP 3601 4000.00 400.00 6. 35 99.99 4.00 %T 5 1.00
REF 4000 76.42 2000 65.23 600

3964. 48 74. 66 3772.97 63.95 3448.43 6.33 2928. 27 47. 96 2109.27 63.46
1627. 09 35. 23 1410.61 58.11 1115.31 58.29 608.91 53. 13
REF 4000 75.79 2000 35.78 600

3964. 24 73. 75 3772. 57 57. 82 3437. 12 6.35 2928.11 25.90 2119.44 34.17
1619. 21 21. 51 1408. 65 36. 29 1117. 56 37.55 615.47 44.68
Table - 7.11
Observations of FTIR spectrums for Hexane + Ethyl Acetate mixture:
*0.8(EA)
1 (EA)
0.9(EA)
+
Cm-1
0.1(HX)
Cm-1
0.2(HX)
Cm-1
0.3(HX)
Cm-1
0.4(HX)
Cm-1
0.5(HX)
Cm-1
0.6(HX)
Cm-1
3917.93
3772.03
3449.73
2928.11
2859.61
2098.42
1753.54
1628.57
1379.58
1243.52
1111.63
1050.10
558.53
3770.59
3450.82
2988.62
2493.14
2384.79
2088.86
1760.91
1636.38
1378.06
1243.04
1054.23
929.20
617.11
3972.80
3774.67
3448.93
2990.04
2931.38
2087.94
1762.57
1634.83
1377.68
1242.66
1055.31
547.94
3905.70
3769.87
3448.68
2928.17
2859.60
2379.02
2092.59
1634.91
1381.22
1242.46
1110.54
1049.25
557.41
3855.32
3768.40
3448.96
2960.84
2378.76
2093.17
1741.82
1636.66
1371.21
1241.77
1049.37
931.21
607.99
533.17
3906.07
3770.91
3448.84
2964.89
2491.89
2091.99
1763.72
1627.25
1378.57
1242.87
1056.01
930.32
619.94
3964.09
3772.12
3449.31
2990.08
2929.67
2365.35
2091.73
1762.09
1629.98
1378.55
1242.99
1055.03
930.11
616.31
0.7(EA)
0.6(EA)
0.5(EA)
0.4(EA)
288
0.3(EA)
0.1(EA)
0.2(EA)
+
0.7(HX)
Cm-1
0.8(HX)
Cm-1
0.9(HX)
Cm-1
3964.69
3773.07
3446.90
2932.51
2405.75
2091.46
1763.23
1627.46
1377.93
1242.94
1055.57
621.67
3964.05
3772.43
3447.13
2929.40
2110.78
1757.54
1625.96
1410.74
1245.29
1116.49
609.33
3964.48
3772.97
3448.43
2928.27
2109.27
1627.09
1410.61
1115.31
608.91
1(HX)
+
Cm-1
3964.24
3772.57
3437.12
2928.11
2119.44
Fig-7.11: FTIR spectrums for Heptane + Benzaldehyde mixture:

ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 13- 2-2010
Spectrum Name: SJC-J-1.sp

100.0
90
3927.66
1 072.46
2031.43
38 95.66
3914.34
80
80
3781.71
80
454.31
90
3924.16
922.50
80
1909.07
1 072.05
543 .53
1982.09
1014.99
70
1111.62
1826.00
70
70
1013.85
1109.11
101 4.23
450.80
1072.24
60
450.90
651.75
101 3.14
60
60
450.87
774.31
450.65
50
50
708.76
1459.80
%T
922.80
377 9.77
1910.5 2
80
1911.9 4
70
60
1282.06
1467.24
50
%T
233 3.38
1982.26 1823.92
23 29.95
923.73
541 .80
1981.59
549.5 4
824.80
1205.65
60
1072.08
2140.56
37 81.38
1825.07
1981.75
80
1 825.66
1019.2 4
70
608.97
60
2331.49
3781.23
923.64
2738.34
2722.97
70
Spectrum Name: SJC-PH-JO-6. sp

100.0
90
1110.91
1912.36
3781.88
FT IR SPECT RUM
Date: 13- 2-2010

100.0
90
1072.53
930.62
1 116.35
FT IR SPECT RUM
Date: 13- 2-2010

100.0
90
2542.27
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 13- 2-2010

100.0
90
379 4.95
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 13- 2-2010
100.0
50
%T
2737.72
3 069.41
50
%T
1455.10 1309.26
50
%T
%T
11 67.12
2818.14
13 87.80
296 5.22
40
40
2879.83
40
40
1455.72 1307.72
27 38.28
13 84.69
1308.11
826.22
11 68.51
1455.67
2738.20
40
1167.87
3067.63
30
30
30
30
68 9.77
650.63
1387.49
3069.26
30
20
1204.69
20
745.68
1596.03
2874.8 1
296 4.19
20
745.96
650.63
30
3440.24
688.95
3394.87
1596.46
2876.2 3
3 451.06
825.69
1167.30
1388.72
2864.03
2818.61
68 9.26
2819.58
1204.70
2882.2 9
20
2964.92
650.24
2738.01
68 8.57
1387.56
1696.28
3444.07
20
826.26
40
1455.19 1307.95
825.81
650.69
3 068.53
1204.08
1595.40
1203.86
746.35
20
1595.69
1 362.51
746.33
3443.35
1596.87
10
10
10
3446.47
10
10
296 3.39
0.0
4000.0
3000
2000
1500
1000
400.0
3000
2000
1500
1000
400.0
4000.0
3000
2000
1000
400.0
0.0
4000.0
3000
2000
1500
cm-1
SJC-PH-JO-2.pk
17 01.59
0.0
1500
cm-1
SJC-J-1.pk
17 01.53
1701.59
0.0
4000.0
cm-1
10
296 4.49
296 3.39
0.0
1000
400.0
SJC-PH-JO-3.pk
17 02.19
0.0
4000.0
3000
2000
1500
cm-1
1000
400.0
4000.0
3000
cm-1
SJC-PH-JO-4.pk
2000
1500
1000
SJC-PH-JO-5.pk
SJC-PH-JO-6.pk
SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4. 00 %T 5 1.00
SJC-PH~1. SP 3601 4000. 00 400. 00 7.89 99. 69 4.00 %T 5 1. 00
SJC-PH~4. SP 3601 4000. 00 400. 00 6.66 99. 78 4.00 %T 5 2. 00
SJ66F3~1. SP 3601 4000.00 400.00 5.99 99.99 4.00 %T 5 2.0 0
SJ6EF3~1.SP 3601 4000.00 400 .00 7.66 100.00 4. 00 %T 5 2.00
SJ6604~1.SP 3601 4000. 00 400.00 6.53 99.91 4.00 %T 5 2. 00
REF 4 000 87.15 2000 85.48 600

3794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49. 43 2722.97 78. 96
1596.87 6. 70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67
REF 4 000 95.81 2000 94.48 600

3927.66 92.70 3781.71 88.30 3446.47 14.16 2963.39 7.88 2882.29 27.54
2738.34 85.29 2542.27 92.66 2031.43 94.02 1696.28 28. 71 1459.80 54. 91
1384.69 44.14 1282.06 65.12 1205.65 70.99 1116.35 87. 42 1072.46 88. 02
1019.24 88.74 930.62 92 .20 824.80 78.44 708.76 57.49 651.75 65.22
549. 54 78 .72 454.31 85.15
REF 4 000 98.92 2000 91.26 600

3895.66 96.56 3781.88 91.06 3451.06 23.89 3068.53 39. 90 2963.39 12. 54
2876.23 27.95 2738.28 45.53 1981.59 88.94 1912.36 90. 03 1825.66 91. 62
1701.59 6. 65 1596.46 27 .37 1455.72 46.37 1387.56 42.62 1307.72 46.29
1204.70 29.38 1168.51 44.99 1111.62 77.55 1072.53 77. 66 1014.23 78. 65
923. 64 89 .35 826.22 44.29 745.68 25.4 7 689.77 36.06 650.69 40. 26
541. 80 83 .49 450.90 65.50
REF 4 000 98.89 2000 90.36 600

3914.34 96.44 3781.23 91.67 3443.35 18.38 3069.26 37. 08 2964.49 12. 67
2874.81 27.62 2819.58 35.28 2738.20 42.07 2331.49 91. 44 1981.75 87. 57
1911.94 89.04 1825.07 89.52 1701.53 5.98 1596.03 25.01 1455.67 43.91
1387.49 39.39 1308.11 46.00 1204.69 28.52 1167.87 44. 55 1110.91 75. 59
1072.24 75.31 1014.99 76.25 923.73 88.34 825.81 42.13 745 .96 23.78
689. 26 34 .03 650.63 37.30 543.53 78.9 4 450.87 60.93
REF 4 000 98.97 2000 89.20 600

3781.38 93.86 3394.87 3 0.73 3067.63 43.84 2964. 19 26.73 2864.03 39. 01
2818.61 35.71 2738.01 4 0.99 2329.95 92.09 2140. 56 96.58 1982.09 86. 01
1910.52 87.83 1826.00 8 7.49 1701.59 7. 65 1595.69 25.07 1455.19 46.98
1388.72 44.85 1307.95 4 5.65 1204.08 28.15 1167. 30 41.01 1109.11 78. 71
1072.08 73.55 1013.14 7 2.81 922. 50 86.91 825.69 38. 57 746.33 22.63
688. 95 33 .75 650.63 37. 32 450.65 59.52
REF 4 000 98.75 2000 93.82 600

3924.16 96.21 3779.77 90.67 3440.24 33.34 3069.41 60. 40 2965.22 47. 23
2818.14 52.16 2737.72 57.94 2333.38 95.41 1982.26 92. 30 1909.07 93. 65
1823.92 93.85 1702.19 6. 53 1595.40 32.39 1455.10 58.52 1387.80 54.56
1309.26 57.85 1203.86 33.23 1167.12 53.27 1072.05 81. 73 1013.85 81. 71
922. 80 93 .52 826.26 48.04 746.35 27.0 0 688.57 41.50 650.24 46. 69
450. 80 70 .90
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 13- 2-2010
90
90
2140.49
3783.77
80
922.10
80
2332.01
1910.0 5
921.71
2332.65
3779.18
1981.60 1825.07
80
1 071.86
1909.34
80
1982.62
1910.63
1 072.25
1910.16
1 072.24
1011.34
90
922.12
37 80.86
80
2964.71
1911.07
1982.44 1826.49
921.88
1982.50 1826.64
2965.78
70
FT IR SPECT RUM
Date: 13- 2-2010
100.0
90
2329.54
2965.54
3779.85
922.12
Spectrum Name: SJC-PH-JO-11.sp
100.0
90
2328.98
2329.14
1982.75 1827.05
Spectrum Name: SJC-PH-JO-10.sp
100.0
100.0
2140.52
3782.72
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 13- 2-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 13- 2-2010
FT IR SPECT RUM
Date: 13- 2-2010
1 071.87
70
1012.18
70
1 825.75
70
4 50.84
1 072.35
70
1011.51
101 1.85
1012.36
450.91
60
400.0
cm-1
450.67
450.64
60
3067.58
60
60
1454.62
60
451.05
1454.22
2737.69
1389.89
50
3067.16
40
%T
1454.75
1389.65
40
2 738.03
1308.39
1166.93
2818.09
40
650.66
825.89
1309.18
40
1167.33
30
826.54
650.78
1167.84
30
650.56
688.99
30
688.51
1203.73
746.67
1595.88
1204.23
1203.54
20
746.81
1308.82
2818.16
40
826.32
1595.35
1595.47
20
746.69
1389.83
2738.01
3393.17
2817.83
1203.47
30
1203.75
1596.21
20
3067.61
%T
13 88.46
2737.63
68 8.53
3456.88
68 8.77
688.84
50
3068.39
%T
650.36
826.01
2818.27
3395.10
1454.6 2
50
1308.78 116 6.70
2817.82
%T
3393.20
650.87
826.17
13 88.71
50
1308.31
2737.97
116 7.62
30
3067.20
50
1454.70
%T
20
746.72
20
1596.45
746.63
3 449.62
10
10
10
10
10
17 02.07
17 02.23
17 02.05
0.0
4000.0
2000
1500
1000
cm-1
400.0
4000.0
3000
2000
1702.37
0.0
0.0
3000
1500
1000
400.0
4000.0
2000
1500
1000
400.0
0.0
4000.0
3000
2000
cm-1
cm-1
1703.08
0.0
3000
1500
1000
400.0
4000.0
cm-1
3000
2000
1500
1000
400.0
cm-1
SJC-PH-JO-7.pk
SJC-PH-JO-8.pk
SJC-PH-JO-9.pk
SJC-PH-JO-10.pk
SJC-PH-JO-11.pk
SJC-PH~2. SP 3601 4000. 00 400. 00 7.40 99. 79 4.00 %T 5 2. 00
SJC-PH~3. SP 3601 4000. 00 400. 00 8.57 99. 83 4.00 %T 5 2. 00
SJ6E1 4~1. SP 3601 4000.00 400.00 11.02 99. 89 4.00 %T 5 2. 00
SJ57CE~1. SP 3601 4000. 00 400. 00 6.48 99. 82 4.00 %T 5 2. 00
SJ57C2~1.SP 3601 4000.00 400 .00 9.19 100.00 4. 00 %T 5 2.00
REF 4 000 98.91 2000 89.96 600

3782.72 96.20 3395.10 34.31 3067.16 48.96 2965.78 64. 04 2818.27 37. 38
2738.03 43.12 2329.14 94.09 2140.52 96.60 1982.75 87. 51 1911.07 89. 41
1827.05 88.97 1702.23 7. 40 1596.21 26.49 1454.70 55.08 1389.65 54.17
1308.39 49.90 1203.75 30.14 1167.62 44.37 1072.24 77. 99 1011.34 75. 98
922. 10 89 .47 826.17 40.94 746.69 23.8 1 688.84 37.20 650.87 42. 32
450. 91 66 .32
REF 4 000 99.35 2000 91.49 600

3783.77 96.21 3393.20 45.93 3067.20 55.39 2964.71 59. 91 2818.09 42. 61
2737.97 47.49 2328.98 94.71 2140.49 97.19 1982.50 88. 97 1910.16 90. 65
1826.64 89.75 1702.05 8. 57 1595.47 29.97 1454.75 56.91 1389.89 57.76
1308.31 53.17 1203.73 32.80 1166.93 46.95 1071.87 78. 74 1012.36 77. 12
922. 12 89 .92 825.89 43.20 746.81 25.7 7 688.77 40.01 650.66 44. 75
450. 64 66 .89
REF 4 000 99.22 2000 94.14 600

3779.85 96.02 3456.88 43.95 3067.58 67.71 2965.54 73. 41 2817.82 54. 51
2737.69 59.18 2329.54 96.63 1982.44 92.49 1909.34 93. 70 1826.49 93. 50
1702.07 11.02 1595.35 36.89 1454.62 65.15 1388.71 63. 22 1308.78 62. 55
1203.47 40.03 1166.70 56.47 1071.86 84.36 1012.18 83. 31 922.12 93.44
826. 01 51 .01 746.67 31.13 688.53 46.4 9 650.36 51.60 450.84 73. 67
REF 4 000 99.01 2000 92.28 600

3780.86 91.73 3449.62 18.83 3068.39 56.63 2817.83 44. 06 2737.63 50. 03
2332.01 93.90 1982.62 90.54 1910.05 92.43 1825.75 92. 39 1702.37 6.48
1596.45 24.92 1454.62 57.80 1388.46 53.80 1309.18 53. 78 1203.54 30. 54
1167.33 47.93 1072.25 81.04 1011.51 79.80 921.71 92.45 826.32 41.01
746. 63 21 .38 688.51 34.45 650.56 39.6 1 451.05 65.18
REF 4 000 99.17 2000 91.90 600

3779.18 91.96 3393.17 4 9.55 3067.61 56.55 2818. 16 47.88 2738.01 53. 25
2332.65 92.39 1981.60 8 9.76 1910.63 90.99 1825. 07 90.53 1703.08 9.19
1595.88 32.13 1454.22 6 0.71 1389.83 58.76 1308. 82 52.85 1204.23 32. 12
1167.84 49.04 1072.35 7 8.97 1011.85 78.28 921.88 88.49 826. 54 44.82
746. 72 26 .61 688.99 40. 38 650.78 45.75 4 50. 67 68. 49
Table - 7.12
Observations of FTIR spectrums for Heptane + Benzaldehyde mixture:
0.9(HP)
0.8(HP)
0.7(HP)
*0.6(HP)
0.5(HP)
0.4(HP)
0.3(HP)
0.2(HP)
+
0.1(HP)
+
Cm-1
0.1(BD)
Cm-1
0.2(BD)
Cm-1
0.3(BD)
Cm-1
0.4(BD)
Cm-1
0.5(BD)
Cm-1
0.6(BD)
Cm-1
0.7(BD)
Cm-1
0.8(BD)
Cm-1
0.9(BD)
Cm-1
Cm-1
3794.95
3444.07
2964.92
2879.83
2722.97
1596.87
1467.24
1362.51
774.31
608.97
3927.66
3781.71
3446.47
2963.39
2882.29
2738.34
2542.27
2031.43
1696.28
1459.80
1384.69
1282.06
1205.65
1116.35
1072.46
1019.24
930.62
824.80
708.76
651.75
549.54
454.31
3924.16
3779.77
3440.24
3069.41
2965.22
2818.14
2737.72
2333.38
1982.26
1909.07
1823.92
1702.19
1595.40
1455.10
1387.80
1309.26
1203.86
1167.12
1072.05
1013.85
922.80
826.26
746.35
688.57
650.24
450.80
3782.72
3395.10
3067.16
2965.78
2818.27
2738.03
2329.14
2140.52
1982.75
1911.07
1827.05
1702.23
1596.21
1454.70
1389.65
1308.39
1203.75
1167.62
1072.24
1011.34
922.10
826.17
746.69
688.84
650.87
450.91
3783.77
3393.20
3067.20
2964.71
2818.09
2737.97
2328.98
2140.49
1982.50
1910.16
1826.64
1702.05
1595.47
1454.75
1389.89
1308.31
1203.73
1166.93
1071.87
1012.36
922.12
825.89
746.81
688.77
650.66
450.64
3779.85
3456.88
3067.58
2965.54
2817.82
2737.69
2329.54
1982.44
1909.34
1826.49
1702.07
1595.35
1454.62
1388.71
1308.78
1203.47
1166.70
1071.86
1012.18
922.12
826.01
746.67
688.53
650.36
450.84
3780.86
3449.62
3068.39
2817.83
2737.63
2332.01
1982.62
1910.05
1825.75
1702.37
1596.45
1454.62
1388.46
1309.18
1203.54
1167.33
1072.25
1011.51
921.71
826.32
746.63
688.51
650.56
451.05
3779.18
3393.17
3067.61
2818.16
2738.01
2332.65
1981.60
1910.63
1825.07
1703.08
1595.88
1454.22
1389.83
1308.82
1204.23
1167.84
1072.35
1011.85
921.88
826.54
746.72
688.99
650.78
450.67
1 (HP)
3895.66
3781.88
3451.06
3068.53
2963.39
2876.23
2738.28
1981.59
1912.36
1825.66
1701.59
1596.46
1455.72
1387.56
1307.72
1204.70
1168.51
1111.62
1072.53
1014.23
923.64
826.22
745.68
689.77
650.69
541.80
450.90
3914.34
3781.23
3443.35
3069.26
2964.49
2874.81
2819.58
2738.20
2331.49
1981.75
1911.94
1825.07
1701.53
1596.03
1455.67
1387.49
1308.11
1204.69
1167.87
1110.91
1072.24
1014.99
923.73
825.81
745.96
689.26
650.63
543.53
450.87
3781.38
3394.87
3067.63
2964.19
2864.03
2818.61
2738.01
2329.95
2140.56
1982.09
1910.52
1826.00
1701.59
1595.69
1455.19
1388.72
1307.95
1204.08
1167.30
1109.11
1072.08
1013.14
922.50
825.69
746.33
688.95
650.63
450.65
289
1(BD)
Fig-7.12: FTIR spectrums for Heptane + Benzyl Chloride mixture:

ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
3832.74
Spectrum Name: T1-0. 5+0.5.sp
100.0
90
926.22
FT IR SPECT RUM
Date: 18- 6-2010
100.0
90
2673.51
FT IR SPECT RUM
Date: 18- 6-2010
100.0
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010
100.0
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010
Spectrum Name: T1-2--0.1+0.9 .asc
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010
2329.91
100.0
90
1888.85
90
923.13
3928.10
379 4.95
233 6.30
2148.79
80
80
2773.8 9
3941.78
1267.20
70
60
1 075.12
2085.56
80
1 075.12
80
70
70
70
472.08
472.96
1962.21
60
60
2962.30
60
60
1449.54 1266.95
2961.07
1467.24
774.31
13 96.87
50
560.2 2
50
1449.91
50
%T
50
1450.86
%T
40
2879.83
50
564.45
1445.90
%T
1267.15
40
1 074.47
1958.64
1080.95
469.60
70
3821.81
608.97
60
1959.22
80
3916.55
111 9.09
2722.97
70
%T
9 23.81
3939.4 8
3943.95
2158.9 2
80
1886.71
1962.22
50
560.9 3
%T
1266.90
560.5 4
3057.23
%T
1269.43
40
1636.74
2956.52
40
40
40
3049.1 2
1639.96
30
30
20
30
20
30
1640.94
20
20
1 362.51
1596.87
10
10
10
10
3000
2000
1500
1000
400.0
693.65
0.0
4000.0
3000
2000
1500
cm-1
1000
400.0
10
693.78
3000
2000
1500
cm-1
1000
400.0
693.87
691.00
0.0
4000.0
3435.30
10
3425.62
3433.62
3428.44
3421.26
0.0
4000.0
30
3058.42
696 .89
20
2964.92
1641.16
30
1637.70
3444.07
20
0.0
4000.0
3000
2000
cm-1
1500
0.0
1000
400.0
0.0
4000.0
3000
2000
1500
cm-1
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
T1-2--0. 1+0. 9.pk
T1-0.2+0.8 .pk
T1-0.3+0.7 .pk
T1-0.4+0.6 .pk
T1-0.5+0.5 .pk
SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4. 00 %T 5 1.00
T1-2--~1.ASC 3601 4000. 00 400. 00 8.12 99.32 4.00 %T 3 1.00
T1-02_~1.SP 3601 4000. 00 400.00 7.03 99.41 4.00 %T 3 1. 00
T1-03_~1.SP 3601 4000. 00 400.00 7.43 99.83 4.00 %T 3 1. 00
T1-04_~1.SP 3601 4000. 00 400.00 6.36 99.99 4.00 %T 3 1. 00
T1-05_~1.SP 3601 4000. 00 400.00 9.26 99.47 4.00 %T 3 1. 00
REF 4 000 87.15 2000 85.48 600

3794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49. 43 2722.97 78. 96
1596.87 6. 70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67
REF 4 000 98.96 2000 93.72 600

3941.78 89.03 3832.74 92.98 3421.26 8.12 2773.89 97.31 2673.51 97.20
2158.92 89.12 1637.70 29.86 1396.87 59.09 1267.20 81. 71 1119.09 83. 70
696. 89 31 .11
REF 4 000 98.85 2000 72.44 600

3916.55 82.46 3821.81 72.74 3428.44 7.03 3058.42 34.05 1962.21 70.76
1641.16 37.88 1450.86 54.41 1267.15 51.52 1075.12 83. 25 926.22 95.66
693. 65 9. 49 560.22 58.4 8 469.60 76.88
REF 4 000 99.21 2000 98.58 600

3928.10 93.30 3425.62 14.46 3049.12 44.13 2956.52 48. 84 2329.91 96. 67
1959.22 92.20 1888.85 95.69 1636.74 49.47 1445.90 54. 79 1269.43 50. 28
1080.95 83.96 923.13 93 .04 691.00 7. 43 564.45 56.61 472.96 73. 33
REF 4 000 99.76 2000 95.31 600

3943.95 92.18 3435.30 6. 36 2962.30 67.61 2336.30 93.53 2085.56 92.39
1962.22 93.83 1640.94 35.45 1449.54 64.66 1266.95 65. 24 1075.12 88. 92
693. 78 13 .07 560.93 54.40
REF 4 000 97.29 2000 95.11 600

3939.48 92.27 3433.62 12.01 3057.23 56.94 2961.07 64. 74 2148.79 92. 83
1958.64 91.87 1886.71 94.80 1639.96 40.21 1449.91 58. 61 1266.90 55. 24
1074.47 84.91 923.81 93 .18 693.87 9. 26 560.54 56.01 472.08 76. 32
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010
FT IR SPECT RUM
Date: 18- 6-2010
100.0
1888.10
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010
FT IR SPECT RUM
Date: 2/14/2009
100.0
Spectrum Name: EA+BC-11.sp
100.0
1026.35
400.0
cm-1
SJC-J-1.pk
100.0
3937.09
90
90
233 5.39
90
233 5.70
3927.4 6
1887.34
2411.56
80
80
1956.83
80
1076.88
80
2149.02
393 8.15
2154.27
3772.29
70
70
465.92
39 06.50
2410.89
111 9.70
3947.94
1 074.40
1 074.56
70
30 77.27
70
1266.80
467.87
3042.6 0
1208.92
60
90
922.15
1206.80
1394.17
1960.17
925.06
1956.20
70
90
1887.23
924.41
1804.23
80
1208.74
60
1611.02
60
60
60
1445.88
465.12
1267.22
50
50
559.84
%T
50
560.1 6
%T
270 8.50
1397.0 4
50
1449.82
%T
50
563.68
%T
2336.46
561.6 6
40
1451.90
40
9 27.39
189 0.06
2868.60
2959.53
40
1267.13
1811.47
%T
1451.49
1637.31
40
1027.31
1956.03
40
1600.2 2
3423.02
3040.77
1267.39
30
30
20
20
30
2957.59
2959.79
30
3435.57
1493.17
2960.75
810 .55
1207.69
1640.16
1640.46
20
559.3 7
1 074.43
2957.85
30
20
20
7 59.02
1451.17
3034.41
692.66
1266.87
10
10
3 431.07
10
10
10
692.73
692.73
0.0
4000.0
2000
1500
1000
400.0
4000.0
3000
cm-1
2000
1500
1000
694.99
3 427.62
692.85
0.0
3000
0.0
400.0
4000.0
cm-1
0.0
3000
2000
1500
1000
400.0
3430.86
4000.0
0.0
3000
cm-1
2000
1500
1000
400.0
4000.0
cm-1
3000
2000
1500
1000
400.0
cm-1
T1-0.6+0.4 .pk
T1-0.7+0.3 .pk
T1-0.8+0.2 .pk
T1-0.9+0.1 .pk
EA+BC-11. pk
T1-06_~1.SP 3601 4000. 00 400.00 8.43 99.98 4.00 %T 3 1. 00
T1-07_~1.SP 3601 4000. 00 400.00 7.41 99.99 4.00 %T 3 1. 00
T1-08_~1.SP 3601 4000. 00 400.00 8.00 99.80 4.00 %T 3 1. 00
T1-09_~1.SP 3601 4000. 00 400.00 6.33 99.81 4.00 %T 3 1. 00
EA9C82~1.SP 3601 4000. 00 400.00 7.08 99.91 4.00 %T 5 2. 00
REF 4 000 99.90 2000 98.05 600

3937.09 97.08 3423.02 42.74 3040.77 42.44 2957.59 35. 57 2335.39 94. 55
1956.20 86.05 1888.10 90.42 1804.23 89.13 1611.02 63. 35 1451.90 44. 55
1267.39 38.53 1208.92 72.63 1074.56 76.41 925.06 88.87 692.73 8. 43
559. 84 55 .18 465.92 71.56
REF 4 000 99.71 2000 98.83 600

3927.46 94.33 3431.07 16.25 3042.60 46.09 2957.85 41. 34 2335.70 95. 15
1956.83 90.91 1887.34 94.72 1637.31 47.82 1451.49 50. 04 1267.13 45. 20
1208.74 80.78 1074.40 80.61 924.41 92.22 692.85 7. 41 560.16 52.83
467. 87 71 .17
REF 4 000 98.26 2000 95.21 600

3947.94 86.85 3427.62 8. 00 3077.27 57.94 2959.79 32.72 2411.56 96.78
2154.27 91.90 1960.17 92.33 1887.23 95.77 1640.16 33. 61 1449.82 55. 26
1394.17 65.88 1267.22 60.17 1206.80 90.25 1076.88 85. 22 1026.35 89. 49
922. 15 93 .69 692.73 11.15 561.66 49.3 7
REF 4 000 97.38 2000 93.68 600

3938.15 88.50 3430.86 6. 33 2959.53 48.48 2410.89 95.61 2149.02 89.85
1640.46 30.25 1445.88 66.07 1397.04 65.96 1266.80 75. 76 1119.70 88. 79
692. 66 21 .44 563.68 54.16
REF 4 000 98.47 2000 59.62 600

3906.50 94.80 3772.29 83.63 3435.57 39.14 3034.41 25. 24 2960.75 35. 21
2868.60 51.22 2708.50 60.11 2336.46 56.86 1956.03 48. 63 1890.06 51. 79
1811.47 53.04 1600.22 42.75 1493.17 41.14 1451.17 26. 63 1266.87 19. 47
1207.69 41.07 1074.43 41.36 1027.31 49.25 927.39 55.87 810.55 38.57
759. 02 31 .11 694.99 7. 08 559.37 42.03 465.12 60. 85
Table - 7.13
Observations of FTIR spectrums for Heptane + Benzyl Chloride mixture:
1(HP)
0.9(HP)
+
0.1(BC)
Cm-1
0.8(HP)
+
0.2(BC)
Cm-1
0.7(HP)
+
0.3(BC)
Cm-1
0.6(HP)
+
0.4(BC)
Cm-1
0.5(HP)
+
0.5(BC)
Cm-1
Cm-1
3794.95
3444.07
2964.92
2879.83
2722.97
1596.87
1467.24
1362.51
774.31
608.97
3941.78
3832.74
3421.2
2773.89
2673.51
2158.92
1637.70
1396.87
1267.20
1119.09
696.89
3916.55
3821.81
3428.44
3058.42
1962.21
1641.16
1450.86
1267.15
1075.12
926.22
693.65
560.22
469.60
3928.10
3425.62
3049.12
2956.52
2329.91
1959.22
1888.85
1636.74
1445.90
1269.43
1080.95
923.13
691.00
564.45
472.96
3943.95
3435.30
2962.30
2336.30
2085.56
1962.22
1640.94
1449.54
1266.95
1075.12
693.78
560.93
3939.48
3433.62
3057.23
2961.07
2148.79
1958.64
1886.71
1639.96
1449.91
1266.90
1074.47
923.81
693.87
560.54
472.08
*0.4(HP)
+
0.6(BC)
Cm-1
3937.09
3423.02
3040.77
2957.59
2335.39
1956.20
1888.10
1804.23
1611.02
1451.90
1267.39
1208.92
1074.56
925.06
692.73
559.84
465.92
290
1(BC)
0.3(HP)
+
0.7(BC)
Cm-1
0.2(HP)
+
0.8(BC)
Cm-1
0.1(HP)
+
0.9(BC)
Cm-1
Cm-1
3927.46
3431.07
3042.60
2957.85
2335.70
1956.83
1887.34
1637.31
1451.49
1267.13
1208.74
1074.40
924.41
692.85
560.16
467.87
3947.94
3427.62
3077.27
2959.79
2411.56
2154.27
1960.17
1887.23
1640.16
1449.82
1394.17
1267.22
1206.80
1076.88
1026.35
922.15
692.73
561.66
3938.15
3430.86
2959.53
2410.89
2149.02
1640.46
1445.88
1397.04
1266.80
1119.70
692.66
563.68
3906.50
3772.29
3435.57
3034.41
2960.75
2868.60
2708.50
2336.46
1956.03
1890.06
1811.47
1600.22
1493.17
1451.17
1266.87
1207.69
1074.43
1027.31
927.39
810.55
759.02
694.99
559.37
465.12
Fig-7.13: FTIR spectrums for Heptane + 2-Butanone mixture:

ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
90
90
90
379 6.71
100.0
90
3 925.74
100.0
90
37 93.09
90
3919.84
3924.97
2127.72
9 39.52
2152.75
80
80
80
80
1467.00
80
80
1168.73
2724.40
2722.97
2133.9 8
70
70
3924.74
70
70
604.10
1165.83
70
2722.39
1171.32
2723.06
608.97
60
1171.14
60
60
1467.24
60
611.49
60
590.12
1463.6 7
50
774.50
28 33.22
50
%T
%T
2881.0 8
1466.31
40
50
1465.6 4
2834.84
50
774.24
%T
2879.53
%T
40
40
40
30
30
30
40
1735.65
2882.12
1736.29
2880.55
30
773.93
2833.7 8
773.91
773.90
50
%T
2879.83
588.48
60
1466.0 9
607.14
774.31
50
27 22.63
1021.01
937.60
2720.21
70
%T
40
FT IR SPECT RUM
Date: 04- 2-2010
100.0
379 4.95
FT IR SPECT RUM
Date: 04- 2-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
100.0
30
296 4.96
30
3447.26
2967.38
3444.07
20
20
2964.92
2966.74
20
1360.44
20
20
20
1 362.51
3441.28
3437.58
1596.87
10
296 6.33
1 362.14
2967.45
1 362.68
10
10
1 361.93
10
3445.25
10
1 362.50
10
3438.36
1594.90
1597.43
0.0
0.0
4000.0
3000
2000
1500
1000
400.0
3000
2000
1500
1000
400.0
0.0
4000.0
3000
2000
cm-1
SJC-J-1.pk
1599.26
0.0
4000.0
cm-1
1500
1000
400.0
SJC-J-2.pk
1596.16
0.0
4000.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
2000
cm-1
SJC-J-3.pk
1596.73
0.0
1500
1000
400.0
4000.0
3000
cm-1
SJC-J-4.pk
2000
1500
1000
SJC-J-6.pk
SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4. 00 %T 5 1.00
SJC-J-2.sp 3601 4000.00 400.00 5.34 98.50 4. 00 %T 5 1.00
SJC-J-3.sp 3601 4000.00 400.00 6.68 99.29 4. 00 %T 5 1.00
SJC-J-4.sp 3601 4000.00 400.00 6.99 98.71 4. 00 %T 5 1.00
SJC-J-5.sp 3601 4000.00 400.00 6.48 99.27 4. 00 %T 5 1.00
SJC-J-6.sp 3601 4000.00 400.00 6.72 99.69 4. 00 %T 5 1.00
REF 4 000 87.15 2000 85.48 600

3794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49. 43 2722.97 78. 96
1596.87 6. 70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67
REF 4 000 81.24 2000 79.36 600

3924.74 79.66 3796.71 77.77 3437.58 19.83 2966.33 18. 58 2880.55 40. 03
2723.06 72.86 1597.43 5. 34 1466.31 54.01 1362.14 19.05 1165.83 77.23
774. 50 52 .68 607.14 61.13
REF 4 000 94.92 2000 92.95 600

3925.74 92.51 3438.36 10.85 2966.74 28.56 2881.08 52. 92 2724.40 84. 55
2152.75 91.02 1594.90 6. 68 1467.00 66.21 1360.44 27.18 773.90 59.77
611. 49 64 .44
REF 4 000 88.56 2000 85.88 600

3793.09 86.71 3447.26 33.86 2964.96 35.79 2879.53 57. 08 2833.22 56. 60
2720.21 80.32 1599.26 6. 99 1466.09 63.33 1362.68 19.16 1168.73 82.94
773. 91 61 .72 604.10 75.15
REF 4 000 83.27 2000 82.94 600

3919.84 82.16 3441.28 21.00 2967.45 21.89 2882.12 44. 66 2834.84 55. 28
2722.39 74.85 2133.98 81.68 1735.65 49.12 1596.16 6.48 1465.64 56.00
1361.93 19.58 1171.14 69.44 1021.01 81.52 937.60 82.09 774.24 55.71
590. 12 63 .23
REF 4 000 95.97 2000 95.87 600

3924.97 94.42 3445.25 20.72 2967.38 29.99 2833.78 63. 93 2722.63 86. 66
2127.72 94.15 1736.29 41.79 1596.73 6.72 1463.67 64.95 1362.50 19.78
1171.32 71.15 939.52 92 .66 773.93 63.48 588.48 70.02
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010

100.0
90
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
100.0
FT IR SPECT RUM
Date: 04- 2-2010
FT IR SPECT RUM
Date: 04- 2-2010
100.0
100.0
100.0
90
90
90
2134.6 2
80
80
2723.43
80
9 40.23
2120.11
2124.88
2121.16
941.51
80
2124.20
3925.39
2726.13
9 40.16
27 29.15
9 40.87
70
3799.99
3926.98
112 0.91
80
400.0
cm-1
SJC-J-5.pk
70
70
2723.22
70
70
272 6.68
1171.97
60
2831.35
60
2832.12
2830.0 7
60
594.09
1462.4 8
1171.65
7 70.78
50
589.83
7 72.60
1171.40
60
590.76
50
%T
%T
1736.42
40
40
588.52
50
2986.89
%T
7 70.71
7 72.42
2832.1 8
50
2988.35
%T
60
590.67
1461.6 8
773.73
2832.85
50
%T
1171.83
40
40
40
1736.34
2987.82
30
30
30
30
1357.24
30
1736.61
2968.63
20
1359.60
20
20
20
20
1 361.50
1359.86
10
10
1737.56
3438.91
1596.53
10
10
3441.96
4000.0
3000
2000
1500
0.0
1000
400.0
4000.0
2000
1500
1000
400.0
4000.0
cm-1
3445.81
0.0
3000
2000
1500
1000
400.0
4000.0
2000
1500
1000
400.0
4000.0
cm-1
SJC-J-9.pk
1595.49
0.0
3000
cm-1
SJC-J-8.pk
1 362.59
10
1596.16
0.0
3000
cm-1
SJC-J-7.pk
3438.81
1592.41
3438.28
1595.85
0.0
3000
2000
1500
1000
400.0
cm-1
SJC-J-10.pk
SJC-J-11.pk
SJC-J-7.sp 3601 4000.00 400.00 6.46 99.24 4. 00 %T 5 1.00
SJC-J-8.sp 3601 4000.00 400.00 6.48 99.56 4. 00 %T 5 1.00
SJC-J-9.sp 3601 4000.00 400.00 6.32 99.38 4. 00 %T 5 1.00
SJC-J-10.sp 3601 4000.00 400. 00 6. 48 99. 84 4.00 %T 5 1.00
SJC-J-11.sp 3601 4000.00 400. 00 7. 03 99. 99 4.00 %T 5 1.00
REF 4 000 82.55 2000 82.12 600

3441.96 12.97 2968.63 27.75 2832.85 59.07 2726.68 74. 50 2124.88 79. 88
1736.61 31.12 1595.85 6. 46 1462.48 55.47 1359.86 20.07 1171.65 55.99
940. 87 78 .64 772.60 54.04 589.83 56.5 1
REF 4 000 92.98 2000 91.83 600

3438.91 17.36 2831.35 68.26 2723.43 84.71 2134.62 90. 16 1596.53 6.48
1359.60 28.00 1120.91 87.96 773.73 59.63 594.09 63.59
REF 4 000 87.32 2000 85.60 600

3438.28 6. 32 2988.35 54 .28 2830.07 70.35 2729.15 81.21 2120.11 82.93
1736.42 49.70 1592.41 12.55 1461.68 68.81 1357.24 36. 54 1171.97 70. 24
940. 23 85 .60 770.78 60.36 590.76 58.5 5
REF 4 000 85.01 2000 84.80 600

3925.39 83.44 3438.81 15.62 2986.89 53.90 2832.18 59. 94 2723.22 77. 05
2124.20 83.21 1736.34 44.75 1596.16 6.48 1361.50 21.09 1171.40 68.10
940. 16 83 .14 772.42 58.51 590.67 63.4 7
REF 4 000 99.04 2000 98.74 600

3926.98 96.87 3799.99 95.07 3445.81 12.13 2987.82 40. 47 2832.12 69. 24
2726.13 89.36 2121.16 95.77 1737.56 19.80 1595.49 7.03 1362.59 17.87
1171.83 49.73 941.51 89 .22 770.71 65.15 588.52 63.33
Table - 7.14
Observations of FTIR spectrums for Heptane + 2-Butanone mixture:
1(HP)
Cm-1
3794.95
3444.07
2964.92
2879.83
2722.97
1596.87
1467.24
1362.51
774.31
608.97
0.9(HP)
+
0.1(2B)
Cm-1
0.8(HP)
+
0.2(2B)
Cm-1
0.7(HP)
+
0.3(2B)
Cm-1
3924.74
3796.71
3437.58
2966.33
2880.55
2723.06
1597.43
1466.31
1362.14
1165.83
774.50
607.14
3925.74
3438.36
2966.74
2881.08
2724.40
2152.75
1594.90
1467.00
1360.44
773.90
611.49
3793.09
3447.26
2964.96
2879.53
2833.22
2720.21
1599.26
1466.09
1362.68
1168.73
773.91
604.10
*0.6(HP)
+ 0.4(2B)
Cm-1
3919.84
3441.28
2967.45
2882.12
2834.84
2722.39
2133.98
1735.65
1596.16
1465.64
1361.93
1171.14
1021.01
937.60
774.24
590.12
0.5(HP)
+
0.5(2B)
Cm-1
0.4(HP)
+
0.6(2B)
Cm-1
0.3(HP)
+
0.7(2B)
Cm-1
0.2(HP)
+
0.8(2B)
Cm-1
0.1(HP)
+
0.9(2B)
Cm-1
3924.97
3445.25
2967.38
2833.78
2722.63
2127.72
1736.29
1596.73
1463.67
1362.50
1171.32
939.52
773.93
588.48
3441.96
2968.63
2832.85
2726.68
2124.88
1736.61
1595.85
1462.48
1359.86
1171.65
940.87
772.60
589.83
3438.91
2831.35
2723.43
2134.62
1596.53
1359.60
1120.91
773.73
594.09
3438.28
2988.35
2830.07
2729.15
2120.11
1736.42
1592.41
1461.68
1357.24
1171.97
940.23
770.78
590.76
3925.39
3438.81
2986.89
2832.18
2723.22
2124.20
1736.34
1596.16
1361.50
1171.40
940.16
772.42
590.67
291
1(2B)
Cm-1
3926.98
3799.99
3445.81
2987.82
2832.12
2726.13
2121.16
1737.56
1595.49
1362.59
1171.83
941.51
770.71
588.52
Fig-7.14: FTIR spectrums for Heptane + Ethyl Acetate mixture:

ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 04- 2-2010
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010

100.0
80
100.0
90
90
2341.82
2091.63
3926.2 4
80
100.0
90
3937.42
FT IR SPECT RUM
Date: 18- 6-2010
100.0
90
2092.63
80
FT IR SPECT RUM
Date: 18- 6-2010
100.0
3944.42
90
379 4.95
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010
100.0
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 18- 6-2010
2087.64
2089.68
2341.88
3933.76
80
80
80
1056.26
208 9.59
2722.97
70
70
70
70
70
1057.10
70
378 1.90
1760.48
608.97
60
2985.63
60
60
1467.24
1058.39
774.31
60
1057.12
2977.21
633.00
1390.89
60
1056.86
13 85.70
50
50
%T
50
630.89
%T
2969.03
13 84.93
60
6 40.28
12 42.86
2964.89
13 84.35
50
%T
13 86.94
6 38.77
50
633.59
%T
50
%T
1761.14
%T
12 42.98
40
40
2879.83
40
40
40
40
296 1.06
1762.28
30
1642.62
1762.43
30
3444.07
20
30
20
2964.92
1596.87
10
10
12 42.98
20
10
30
12 43.00
3444.00
30
1641.33
20
10
3440.75
0.0
0.0
4000.0
1761.82
1641.73
30
1641.77
20
12 42.99
1641.59
20
3435.67
1 362.51
3000
2000
1500
1000
400.0
3000
2000
1500
1000
400.0
4000.0
10
10
3420.70
3432.96
0.0
4000.0
cm-1
0.0
3000
2000
cm-1
1500
1000
400.0
0.0
4000.0
3000
2000
cm-1
1500
1000
400.0
0.0
4000.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
cm-1
2000
1500
1000
400.0
cm-1
SJC-J-1.pk
T2-0.1+0.9 .pk
T2-0.2+0.8 .pk
T2-0.3+0.7 .pk
T2-0.4+0.6 .pk
T2-0.5+0.5 .pk
SJC-J-1.sp 3601 4000.00 400.00 6.70 99.64 4. 00 %T 5 1.00
T2-01_~1.SP 3601 4000. 00 400.00 7.99 99.74 4.00 %T 3 1. 00
T2-02_~1.SP 3601 4000. 00 400.00 6.40 100.00 4.00 %T 3 1 .00
T2-03_~1.SP 3601 4000. 00 400.00 6.34 99.90 4.00 %T 3 1. 00
T2-04_~1.SP 3601 4000. 00 400.00 8.02 99.97 4.00 %T 3 1. 00
T2-05_~1.SP 3601 4000. 00 400.00 6.39 100.00 4.00 %T 3 1 .00
REF 4 000 87.15 2000 85.48 600

3794.95 84.60 3444.07 27.79 2964.92 27.22 2879.83 49. 43 2722.97 78. 96
1596.87 6. 70 1467.24 60 .42 1362.51 21.79 774.31 59.01 608 .97 67.67
REF 4 000 99.37 2000 95.61 600

3944.42 97.72 3440.75 7. 99 2985.63 68.54 2092.63 91.01 1762.43 35.79
1642.62 38.32 1385.70 58.71 1242.99 24.28 1058.39 60. 42 633.00 61.40
REF 4 000 99.54 2000 95.78 600

3937.42 93.52 3432.96 6 .40 2977.21 65.61 2091.63 91.40 1762.28 39.26
1641.77 36.66 1384.35 5 9.71 1242.98 27.08 1057. 12 63.32 630.89 57.49
REF 4 000 99.84 2000 95.76 600

3926.24 89.73 3444.00 6. 34 2969.03 57.57 2341.82 94.54 2089.68 91.20
1761.82 38.81 1641.73 34.08 1384.93 57.71 1243.00 27. 85 1056.86 62. 63
633. 59 57 .56
REF 4 000 99.85 2000 96.00 600

3933.76 90.71 3781.90 75.14 3420.70 8.02 2964.89 61.04 2087.64 92.44
1760.48 70.22 1641.33 34.60 1390.89 68.26 1242.86 64. 48 1056.26 84. 99
640. 28 60 .49
REF 4 000 99.52 2000 95.82 600

3435.67 6. 39 2961. 06 44. 06 2341.88 94.46 2089.59 91.67 1761.14 56.23
1641.59 34.28 1386.94 6 1.59 1242.98 47.57 1057. 10 76.47 638.77 58.31
ACIC
St.Joseph's Colleg e ( Autono mous )
Trichy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FTIR SPECTRUM
Date: 3/11/2009
Spectrum Name: Cl-AN-1.sp
1 0 0. 0
FT IR SPECT RUM
Date: 18- 6-2010
FT IR SPECT RUM
Date: 18- 6-2010
FT IR SPECT RUM
Date: 18- 6-2010
100.0
FT IR SPECT RUM
Date: 18- 6-2010
100.0
2489.19
90
100.0
2088.87
928.00
100.0
2362.08
80
90
90
39 54.90
90
2088.75
1462.72
2084.93
3946.3 1
90
1249.22
1115.43
3940.85
2087.25
1114.81
70
2095.36
80
80
80
80
2991.58
1056.29
1057.23
70
70
70
622.08
1378.64
60
1390.99
12 43.15
13 88.10
60
13 94.47
70
1760.17
13 85.53
60
60
1056.51
50
60
656.34
%T
657.87
2 960.80
633.82
1762.00
6 36.95
50
50
%T
50
%T
%T
50
40
40
30
1637.15
%T
2962.58
40
40
12 43.01
40
1641.34
1641.21
30
30
20
20
10
30
20
2957.17
10
0.0
1763.76
1640.75
2958.68
30
1640.58
3437.11
10
0.0
20
1242.81
20
10
3449.55
10
0. 0
3437.23
3441.69
0.0
4000.0
3000
2000
1500
1000
400.0
4000.0
3000
cm-1
2000
1500
1000
400.0
4000.0
cm-1
4 00 0. 0
3443.85
0.0
3000
2000
1500
1000
400.0
4000.0
3 0 00
20 00
15 00
10 0 0
4 00 .0
cm -1
3000
2000
cm-1
1500
1000
400.0
cm-1
T2-0.6+0.4 .pk
T2-0.7+0.3 .pk
T2-0.8+0.2 .pk
T2-0.9+0.1 .pk
T2-06_~1.SP 3601 4000. 00 400.00 7.97 99.99 4.00 %T 3 1. 00
T2-07_~1.SP 3601 4000. 00 400.00 6.34 99.99 4.00 %T 3 1. 00
T2-08_~1.SP 3601 4000. 00 400.00 7.97 100.00 4.00 %T 3 1 .00
T2-09_~1.SP 3601 4000. 00 400.00 7.95 99.99 4.00 %T 3 1. 00
REF 4 000 99.63 2000 95.68 600

3954.90 97.26 3437.23 7. 97 2962.58 51.23 2088.75 92.18 1762.00 57.81
1641.34 41.22 1385.53 66.49 1243.01 46.85 1057.23 76. 92 633.82 62.32
REF 4 000 99.57 2000 95.58 600

3437.11 6. 34 2957.17 25 .06 2095.36 91.88 1760.17 72.99 1640.58 35.98
1388.10 63.96 1243.15 67.11 1056.29 83.60 636.95 58.13
REF 4 000 99.86 2000 95.70 600

3946.31 94.12 3441.69 7 .97 2958.68 37.05 2084.93 92.67 1641.21 39.33
1462.72 79.27 1390.99 7 2.83 1249.22 96.70 1115. 43 92.09 656.34 64.27
REF 4 000 99.28 2000 95.68 600

3940.85 95.93 3443.85 7. 95 2960.80 63.70 2087.25 92.87 1640.75 41.14
1394.47 77.50 1114.81 93.56 657.87 64.42
Cl-AN-1.p k
Cl-AN-1.s p 3 601 4000.00 400.00 6.33 10 0.00 4.00 %T 5 1.00
REF 4000 99.39 2000 9 7.58 600
3449.55 6.33 2 991.58 69.36 2489.19 98.54 2362.08 89.00 2088.87 9 5.42
1763.76 32.63 163 7.15 43.78 1378.6 4 6 7.05 1242.81 18.7 3 1056.51 55. 12
928.00 97.75 6 22.08 6 9.86
Table - 7.15
Observations of FTIR spectrums for Heptane + Ethyl Acetate mixture:
1(EA)
1(HP)
0.9(HP)
+
0.1(EA)
Cm-1
0.8(HP)
+
0.2(EA)
Cm-1
*0.7(HP)
+ 0.3(EA)
Cm-1
0.6(HP)
+
0.4(EA)
Cm-1
0.5(HP)
+
0.5(EA)
Cm-1
0.4(HP)
+
0.6(EA)
Cm-1
0.3(HP)
+
0.7(EA)
Cm-1
0.2(HP) +
0.8(EA)
Cm-1
0.1(HP)
+
0.9(EA)
Cm-1
Cm-1
Cm-1
3933.91
3435.81
2954.98
2665.98
2348.12
2135.82
1640.00
1459.35
1392.35
1225.90
1120.63
657.99
3944.42
3440.75
2985.63
2092.63
1762.43
1642.62
1385.70
1242.99
1058.39
633.00
3937.42
3432.96
2977.21
2091.63
1762.28
1641.77
1384.35
1242.98
1057.12
630.89
3926.24
3444.00
2969.03
2341.82
2089.68
1761.82
1641.73
1384.93
1243.00
1056.86
633.59
3933.76
3781.90
3420.70
2964.89
2087.64
1760.48
1641.33
1390.89
1242.86
1056.26
640.28
3435.67
2961.06
2341.88
2089.59
1761.14
1641.59
1386.94
1242.98
1057.10
638.77
57.56
3954.90
3437.23
2962.58
2088.75
1762.00
1641.34
1385.53
1243.01
1057.23
633.82
292
3437.11
2957.17
2095.36
1760.17
1640.58
1388.10
1243.15
1056.29
636.95
3946.31
3441.69
2958.68
2084.93
1641.21
1462.72
1390.99
1249.22
1115.43
656.34
3940.85
3443.85
2960.80
2087.25
1640.75
1394.47
1114.81
657.87
3449.55
2991.58
2489.19
2362.08
2088.87
1763.76
1637.15
1378.64
1242.81
1056.51
928.00
622.08
Fig-7.15: FTIR spectrums for Benzaldehyde + Benzyl Chloride mixture:

ACIC
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/15/2008
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/15/2008
Spectrum Name: Sam =0+19.67. sp
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/15/2008
Spectrum Name: Sam =4.82+15. 73.sp
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/15/2008
100.0
FT IR SPECT RUM
Date: 2/15/2008
100.0
FT IR SPECT RUM
Date: 2/15/2008
100.0
100.0
100.0
1495.51
90
2540.68
1887.33
1954 .65
2866.83
80
2 817.92
80
1027.37
1495.36
90
1495.1 2
1958 .06
2736.78
925.88
1807.15
80
1020.97
2359.43
80
80
1023.51
2361.84
458.71
453.48
453.69
557.83
456.26
70
1073.45
1074.02
1072.78
1074.55
2359.20
70
2736.97
70
2 819.75
2737.87
559.12
559.14
2817.20
1168.03
60
2737.26
1166.43
60
60
1393.77
1393.06
2 817.73
1397.50
2 818.57
60
11 66.79
1168.03
1452.75
813.02
50
1452.03
3034.51
823.92
815.57
559.03
50
559.46
%T
1310.13
50
557.54
1400.26 1204.8 3
%T
1452.57
40
1648.19
40
126 8.72
40
1597.63
50
824.59
3033.97
3 066.36
%T
1453.2 8
1205.39
40
1204.22
40
1596.78
343 7.67
3073.15
30
127 1.31
30
747.40
30
127 7.16
1597.14
1204.36
126 6.53
30
3069.79
%T
126 9.20
1268.98
1452.09
3065.58
50
821.29
3067.86
%T
3070.48
760.56
1452.48
40
2963.51
928.75
2737.67
70
2362.73
927.05
1022.76
1398.17
1204.97
1970.64
1965.8 4
925.94
80
462.79
1167.05
2 962.70
60
8 10.75
1637.89
90
925.20
1960.10
1024.51
2358.99
70
464.81
1699.23 149 5.29
2960.77
50
%T
303 3.08
90
1962.6 0
2545.69
1074.60
1073.70
1 394.35 1207.06
60
90
926.73
1025.73
2361.42
70
14 95.11
1494.80
1160 .38
90
746.94
343 9.86
747.14
343 9.42
30
30
746.84
344 4.32
20
20
10
20
1699.03
10
20
10
344 7.49
20
10
20
10
1698.89
0.0
4000.0
3000
2000
1500
1000
400.0
3000
2000
1500
1000
400.0
1700.91
0.0
4000.0
3000
2000
1500
cm -1
1000
400.0
0.0
4000.0
3000
2000
1500
cm -1
Sam =2.41+17.70.pk
694.86
1701.17
0.0
4000.0
cm -1
Sam =0+19. 67.pk
1701.42
695.95
695.77
0.0
696.10
10
696.19
344 3.18
696.69
1000
400.0
0.0
4000.0
3000
2000
1500
cm -1
Sam =4.82+15.73.pk
1000
400.0
4000.0
3000
cm -1
Sam =7.24+13.76.pk
2000
1500
1000
Sam =12. 07+9.835.pk
SAM_0_~1.SP 3601 4000.00 400.00 8. 19 1 00. 00 4.00 %T 3 2. 00
SAM_24~2.SP 3601 4000.00 400.00 9. 09 9 9.99 4. 00 %T 3 2.00
SAM_48~1.SP 3601 4000.00 400.00 7. 05 9 9.84 4. 00 %T 3 2.00
SAM_72~1.SP 3601 4000.00 400.00 10.80 100.00 4.00 %T 3 2.00
SAM_96~1.SP 3601 4000.00 400.00 9. 03 9 9.53 4. 00 %T 3 2.00
SAM_12~1.SP 3601 4000.00 400.00 10.98 99. 92 4.00 %T 3 2. 00
REF 4000 99.61 2000 99.02 600

3444.32 31.42 3065.58 52. 84 3033. 08 49.6 3 2960.77 67.54 2866. 83 88.38
2361.42 79.78 1954.65 88. 69 1887. 33 92.5 0 1807.15 90.79 1699. 23 68.22
1637.89 63.83 1495.29 64. 98 1452. 48 48.8 1 1394.35 74.16 1266. 53 41.05
1207.06 75.43 1160.38 83. 44 1073. 70 76.1 4 1027.37 86.66 925.88 91.32
810.75 61.0 7 760. 56 50.09 696. 69 8.19 559.46 56.01 464.81 74.80
REF 4000 99.73 2000 97.37 600

3447.49 15.67 3070.48 53.89 3034. 51 54.06 2962. 70 74. 19 2817. 92 87. 66
2736.78 92.46 2540.68 96.74 2358. 99 85.24 1958. 06 93. 14 1699. 03 26. 02
1648.19 48.37 1495.12 74.20 1452. 03 55.76 1398. 17 68. 40 1268. 72 46. 30
1204.97 67.30 1167.05 80.32 1074. 60 83.18 1025. 73 91. 89 926.73 92.71
813.02 62.7 8 695.77 9.09 5 59. 03 60.03 462.79 78.76
REF 4000 99.51 2000 96.55 600

3443.18 13.70 3073.15 41.73 2819. 75 72.10 2737. 67 80. 92 2545. 69 90. 36
2359.20 75.50 1960.10 91.90 1698. 89 10.57 1495. 36 71. 10 1452. 09 48. 98
1400.26 54.69 1271.31 38.58 1204. 83 52.91 1168. 03 68. 46 1074. 55 79. 23
1024.51 89.32 928.75 88.11 815.57 57. 97 747.40 38.25 695.95 7.05
557.54 55.9 8 458.71 76. 87
REF 4000 99.69 2000 97.42 600

3439.42 35.10 3067.86 54. 14 2963. 51 74.4 0 2817.20 70.15 2736. 97 75.71
2359.43 82.44 1962.60 93. 52 1701. 42 11.7 4 1597.63 47.02 1494. 80 75.98
1452.57 54.02 1393.77 66. 01 1268. 98 48.7 6 1204.22 47.37 1166. 43 67.52
1074.02 81.80 1022.76 89. 54 925.20 92.24 821.29 57.31 747.14 35.39
694.86 10.8 0 559. 14 68.49 456. 26 78. 41
REF 4000 99.49 2000 97.40 600

3439.86 38.48 3066.36 53.18 3033. 97 54.15 2817. 73 64. 78 2737. 26 70. 80
2361.84 84.33 1965.84 94.10 1701. 17 9.03 1596.78 45.36 1495.51 77.77
1453.28 53.72 1393.06 65.17 1310. 13 61.95 1269. 20 49. 82 1204. 36 42. 21
1166.79 63.53 1072.78 81.35 1023. 51 88.83 925.94 90.76 824. 59 56. 31
746.84 34.2 8 696.19 13. 99 559.12 71.66 453. 69 79.39
REF 4000 99.76 2000 97.59 600

3437.67 41.99 3069.79 55.88 2818. 57 66.69 2737. 87 73. 89 2362. 73 92. 48
1970.64 95.50 1700.91 10.98 1597. 14 50.47 1495. 11 85. 31 1452. 75 64. 32
1397.50 68.22 1277.16 55.15 1205. 39 49.42 1168. 03 68. 01 1073. 45 86. 32
1020.97 91.54 927.05 91.33 823.92 62. 41 746.94 41.79 696.10 23.64
557.83 79.5 8 453.48 83. 27
ACIC
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/15/2008
1 976.28 1821.6 9
19 11.15
80
1978.74
100.0
1908.74
80
925.48
80
555.32
2365.30
2738.17
50
33 92.16
40
1072.68
652 .64
1392.52
%T
27 37.93
3390.58
40
1452.81
1167.95
40
1205.67
2738.60
30
693.96
20
746 .76
20
1167.04
65 0.77
2 818.39
1285.60
1169.01
3392.11
824.81
689.23
30
2 819.15
652.82
1204.67
3390.83
1205.95
3071.24
1596.07
20
694.76
1596.65
695.80
74 7.24
74 6.45
695.33
10
10
10
0.0
400.0
4000.0
1700.22
0.0
3000
2000
cm -1
10
1701.95
1700.74
1700.47
1000
2738.32
826.10
1396.15
74 6.88
30
1205.18
20
3068.94
40
1595.96
825.21
128 1.16
1596.0 5
10
1500
1454.14
50
%T
1308.46
2 818.69
20
2000
450.84
450.72
50
825.54
3066.47
0.0
3000
101 2.18
60
1112.44
11 67.92
1306.81
2 818.59
1452.23
30
1205.43
746 .52
4000.0
1910.62
70
926.88
60
1394.45
3069.01
%T
548.34
2550.16
1453.08
60
452.04
1394.61
128 1.88
1595.83
80
922.30
101 5.51
556.59
50
824.10
2 818.64
3068.18
30
10 72.61
70
927.04
1072.00
40
1980.3 3
1982.52 1826.09
19 13.14
70
10 22.32
2549.23
60
%T
139 7.26
1 168.71
1823 .61
451.12
70
553.80
451.58
1451.93
2737.89
3390.66
1108 .93
2332.07
1072.84
1072.39 927.95
60
50
2139.72
90
1492 .91
202 7.14
10 16.10
80
11 11.33
2363.98
2140.47
90
1822 .87
1910.83
10 18.08
2550.12
70
%T
Spectrum Name: Sam =24.14+0. sp
100.0
1110.72
90
1494.75
1973.32 1820.52
FT IR SPECT RUM
Date: 2/15/2008
100.0
90
1112.48
2361.64
FT IR SPECT RUM
Date: 2/15/2008
100.0
1494 .04
90
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/15/2008
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/15/2008
400.0
cm -1
Sam =9.65+11.80.pk
1500
1000
400.0
4000.0
1702 .46
0.0
3000
cm -1
2000
1500
1000
400.0
4000.0
0.0
3000
cm -1
2000
1500
1000
400.0
4000.0
3000
cm -1
2000
1500
1000
400.0
cm -1
Sam =14. 48+7.86.pk
Sam =16. 89+5.90.pk
Sam =19. 32+3.93.pk
Sam =21. 72+1.967.pk
Sam =24. 14+0.pk
SAM_14~1.SP 3601 4000.00 400.00 7. 75 1 00. 00 4.00 %T 3 2. 00
SAM_16~1.SP 3601 4000.00 400.00 7. 53 9 9.99 4. 00 %T 3 2.00
SAM_19~1.SP 3601 4000.00 400.00 10.42 99. 85 4.00 %T 3 1. 00
SAM_21~1.SP 3601 4000.00 400.00 7. 14 9 9.99 4. 00 %T 3 1.00
SAM_24~1.SP 3601 4000.00 400.00 7. 78 9 9.80 4. 00 %T 3 2.00
REF 4000 99.55 2000 95.47 600

3390.66 50.09 3068.18 41. 88 2818. 64 45.5 2 2737.89 53.38 2550. 12 77.80
2361.64 89.14 1976.28 92. 30 1911. 15 92.3 8 1821.69 92.83 1700. 47 7.74
1595.83 35.79 1494.04 84. 79 1451. 93 56.2 4 1397.26 56.41 1281. 88 40.72
1205.43 34.78 1168.71 49. 49 1112. 48 76.0 8 1072.39 76.63 1018. 08 81.55
927.95 74.7 8 824. 10 48.14 746. 52 31. 25 695.80 22. 89 553.80 74.39
451.58 72.7 8
REF 4000 99.34 2000 94.39 600

3390.58 45.03 3066.47 33.83 2818. 69 38.42 2737. 93 45. 81 2549. 23 73. 48
2363.98 85.77 1973.32 89.72 1908. 74 89.98 1820. 52 89. 71 1700. 74 7.53
1596.05 29.28 1494.75 76.42 1452. 81 45.15 1394. 61 50. 67 1281. 16 34. 04
1205.18 27.26 1167.95 41.83 1111. 33 71.55 1072. 00 68. 93 1022. 32 75. 99
927.04 71.2 7 825.21 40. 05 746.76 24.05 695. 33 16.20 556 .59 66.92
452.04 66.6 8
REF 4000 99.56 2000 95.70 600

3392.16 56.03 3069.01 55.70 2818. 59 57.23 2738. 17 63. 97 1978. 74 93. 87
1910.83 94.16 1822.87 93.44 1701. 95 10.42 1595. 96 44. 54 1453. 08 67. 52
1394.45 66.72 1306.81 58.70 1205. 67 43.04 1167. 92 59. 89 1110. 72 84. 70
1072.84 85.51 1016.10 88.45 925.4 8 89.27 825. 54 56. 98 746.88 37.69
693.96 38.1 6 652.64 53. 20 555.32 86.77 451. 12 79.20
REF 4000 99.23 2000 90.91 600

3390.83 28.65 3071.24 29.60 2819. 15 32.65 2738. 60 39. 18 2550. 16 68. 32
2365.30 84.93 2140.47 98.07 2027. 14 91.35 1980. 33 86. 94 1913. 14 86. 83
1823.61 87.25 1700.22 7. 14 1596. 65 25.06 1492.91 85.87 1452.23 49.48
1396.15 41.91 1285.60 34.66 1205. 95 26.63 1169. 01 38. 12 1112. 44 65. 44
1072.61 70.52 1015.51 74.79 926.8 8 67.28 824. 81 37. 12 746.45 23.20
694.76 24.2 1 652.82 31. 36 548.34 68.70 450. 72 60.11
REF 4000 98.63 2000 89.64 600

3392.11 38.45 3068.94 49.16 2818. 39 41.61 2738. 32 47. 07 2332. 07 92. 72
2139.72 96.16 1982.52 87.01 1910. 62 88.53 1826. 09 87. 47 1702. 46 7.77
1596.07 28.46 1454.14 58.66 1392. 52 56.44 1308. 46 50. 72 1204. 67 31. 12
1167.04 45.91 1108.93 82.45 1072. 68 79.76 1012. 18 79. 42 922.30 88.15
826.10 41.8 9 747.24 23. 95 689.23 38.08 650. 77 42.43 450 .84 67.18
Table - 7.16
Observations of FTIR spectrums for Benzaldehyde + Benzyl Chloride mixture:
1 (BD)
Cm-1
3392.11
3068.94
2818.39
2738.32
2332.07
2139.72
1982.52
1910.62
1826.09
1702.46
1596.07
1454.14
1392.52
1308.46
1204.67
1167.04
1108.93
1072.68
1012.18
922.30
826.10
747.24
689.23
650.77
450.84
0.9(BD)
+
0.1(BC)
Cm-1
0.8(BD)
+
0.2(BC)
Cm-1
0.7(BD)
+
0.3(BC)
Cm-1
*0.6(BD)
+
0.4(BC)
Cm-1
0.5(BD)
+
0.5(BC)
Cm-1
0.4(BD)
+
0.6(BC)
Cm-1
0.3(BD)
+
0.7(BC)
Cm-1
0.2(BD)
+
0.8(BC)
Cm-1
0.1(BD)
+
0.9(BC)
Cm-1
1(BC)
3390.83
3071.24
2819.15
2738.60
2550.16
2365.30
2140.47
2027.14
1980.33
1913.14
1823.61
1700.22
1596.65
1492.91
1454.23
1396.15
1285.60
1205.95
1169.01
1112.44
1072.61
1015.51
926.88
824.81
746.45
694.76
3392.16
3069.01
2818.59
2738.17
1978.74
1910.83
1822.87
1701.95
1595.96
1453.08
1394.45
130681
1205.67
1167.92
1110.72
1072.84
1016.10
925.48
825.54
746.88
693.96
65264
555.32
451.12
3390.58
3066.47
2818.69
2737.93
2549.23
2363.98
1973.32
1908.74
1820.52
1700.74
1596.05
1492.75
1452.81
1394.61
1281.16
1205.18
1167.95
1111.33
1072.00
1022.32
927.04
825.21
746.76
695.33
556.59
452.04
3390.66
3068.18
2818.64
2737.89
2550.12
2361.64
1976.28
1911.15
1821.69
1700.47
1595.83
1494.04
1451.93
1397.26
1281.88
1205.43
1168.71
1112.48
1072.39
1018.08
927.95
824.10
746.52
695.80
553.80
451.58
3437.67
3069.79
2818.57
2737.87
2362.73
1970.64
1700.91
1597.14
1495.11
1452.75
1397.50
1277.16
1205.39
1168.03
1073.45
1020.97
927.05
823.92
746.94
696.10
557.83
453.48
3439.86
3066.36
3033.97
2817.73
2737.26
2361.84
1965.84
1701.17
1596.78
1495.51
1453.28
1393.06
1310.13
1269.20
1204.36
1166.79
1072.78
1023.51
925.94
824.59
746.84
696.19
559.12
453.69
3439.42
3067.86
2963.51
2817.20
2736.97
2359.43
1962.60
1701.42
1597.63
1494.80
1452.57
1393.77
1268.98
1204.22
1166.43
1074.02
1022.76
925.20
821.29
747.14
694.86
559.14
456.26
3443.18
3073.15
2819.75
2737.67
2545.69
2359.20
1960.10
1698.89
1495.36
1452.09
1400.26
1271.31
1204.83
1168.03
1074.55
1024.51
928075
815.57
747.40
695.95
557.54
458.71
3447.49
3073.48
2962.70
2817.92
2736.78
2540.68
2358.99
1958.06
1699.03
1648.19
1495.12
1452.03
1398.17
1268.72
1204.97
1167.05
1074.60
1025.73
926.73
813.02
695.77
559.03
462.79
3444.32
3065.58
3033.08
2960.77
2866.83
2361.42
1954.65
1887.33
1807.15
1699.23
1637.89
1495.29
1452.48
1394.35
1266.53
1207.06
1160.38
1073.70
1027.37
925.88
810.75
760.56
696.69
559.46
464.81

293
Cm-1
Fig-7.16: FTIR spectrums for Benzaldehyde + 2-Butanone mixture:

ACIC
Tric hy-2
ACIC
T richy-2
ACIC
Tric hy-2
3956.28
90
930.50
3942.73
90
2027.76
2736.34
202 2.06
1311.05
80
1017.84
2819.42
70
464.81
1310.27
2815.56
273 7.53
2989.41
70
1168.90
2820.53
456.26
70
70
2819.78
824.59
60
1014.90
80
2734.92
2818.25
1450.89
460.27
822 .24
60
1303.20
60
13 86.52
8 10.75
2032.44
3941.05
80
454.91
70
2984.73
2332.11
1016.00
1013.78
2736.48
1027.37
1073.70
1637.89
90
932.87
2130.63
80
938.97
1 394.35 1207.06
1699.23 149 5.29
2960.77

100.0
2033.45
2737.35
80
2361.42
60
FT IR SPECT RUM
Date: 29- 6-2010

100.0
2333.28
90
1014.68
925.88
1807.15
70
FT IR SPECT RUM
Date: 29- 6-2010

100.0
2991.86
90
1887.33
1954 .65
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 29- 6-2010

100.0
1160 .38
90
2866.83
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 29- 6-2010

100.0
80
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 29- 6-2010
FT IR SPECT RUM
Date: 2/15/2008
Spectrum Name: Sam =0+19.67. sp
100.0
60
1202.77
1304.85
60
823.73
458.13
81 9.82
1393.13
50
50
559.46
50
%T
%T
303 3.08
50
%T
50
13 85.07
%T
50
%T
1376.29
1189.37
1193.13
69 2.77
40
3065.58
40
1204.58
40
689.05
745.04
40
688.57
682.82
30
30
821.96
40
745.92
126 6.53
13 96.80
%T
1197.28
650.09
760.56
1452.48
40
30
744.12
30
344 4.32
30
30
741.06
1649.4 6
20
20
691.81
20
10
10
20
17 01.44
10
20
10
3000
2000
1500
1000
400.0
3 451.99
0.0
4000.0
3000
2000
1500
1000
400.0
4000.0
2000
1500
1000
400.0
T3-0.1+0.9 .pk
17 00.34
0.0
4000.0
3000
2000
cm-1
1500
1000
400.0
0.0
4000.0
3000
2000
cm-1
T3-0.2+0.8 .pk
743.76
10
17 00.15
3433.85
0.0
3000
cm-1
cm -1
Sam =0+19. 67.pk
20
1704.63
17 07.96
0.0
4000.0
10
3 426.16
3 431.30
696.69
0.0
1500
1000
400.0
3424.31
4000.0
cm-1
T3-0.3+0.7 .pk
3000
2000
1500
1000
T3-0.4+0.6 .pk
T3-0.5+0.5 .pk
SAM_0_~1.SP 3601 4000.00 400.00 8. 19 1 00. 00 4.00 %T 3 2. 00
T3-01_~1.SP 3601 4000. 00 400.00 7.88 99.99 4.00 %T 5 1. 00
T3-02_~1.SP 3601 4000. 00 400.00 6.36 99.92 4.00 %T 5 1. 00
T3-03_~1.SP 3601 4000. 00 400.00 10.53 100.00 4. 00 %T 5 1.00
T3-04_~1.SP 3601 4000. 00 400.00 10.79 99.99 4.00 %T 5 1 .00
T3-05_~1.SP 3601 4000. 00 400.00 5.12 99.99 4.00 %T 5 1. 00
REF 4000 99.61 2000 99.02 600

3444.32 31.42 3065.58 52. 84 3033. 08 49.6 3 2960.77 67.54 2866. 83 88.38
2361.42 79.78 1954.65 88. 69 1887. 33 92.5 0 1807.15 90.79 1699. 23 68.22
1637.89 63.83 1495.29 64. 98 1452. 48 48.8 1 1394.35 74.16 1266. 53 41.05
1207.06 75.43 1160.38 83. 44 1073. 70 76.1 4 1027.37 86.66 925.88 91.32
810.75 61.0 7 760. 56 50.09 696. 69 8.19 559.46 56.01 464.81 74.80
REF 4 000 99.54 2000 90.39 600

3431.30 12.40 2984.73 74.96 2819.42 86.55 2737.35 88. 66 2033.45 89. 50
1707.96 7. 88 1376.29 47 .35 1189.37 49.02 1014.68 94.68 938.97 93.55
822. 24 65 .70 745.92 40.94 692.77 47.8 5 460.27 78.59
REF 4 000 99.92 2000 95.70 600

3942.73 95.56 3451.99 6. 36 2991.86 90.02 2815.56 87.29 2736.34 88.63
2130.63 94.26 1701.44 15.76 1649.46 31.63 1450.89 74. 48 1386.52 64. 68
1310.27 80.27 1202.77 61.59 1168.90 70.44 1017.84 94. 39 930.50 96.86
824. 59 66 .51 745.04 43.68 689.05 48.4 5 650.09 51.20 454.91 80. 57
REF 4 000 99.66 2000 94.32 600

3956.28 96.54 3426.16 1 3.62 2989.41 77.28 2819. 78 79.49 2736.48 83. 48
2027.76 93.89 1704.63 1 0.53 1385.07 55.15 1311. 05 70.83 1193.13 48. 06
1013.78 93.69 932.87 94. 88 823.73 61 .84 744.12 37.63 688.57 44.28
456. 26 76 .40
REF 4 000 99.38 2000 94.17 600

3433.85 10.79 2820.53 82.08 2734.92 86.05 2333.28 97. 87 2022.06 93. 94
1700.15 10.96 1393.13 59.38 1303.20 68.69 1197.28 50. 47 1016.00 92. 70
819. 82 60 .62 741.06 36.28 682.82 40.5 2
REF 4 000 99.58 2000 92.60 600

3941.05 90.22 3424.31 5. 12 2818.25 74.51 2737.53 79.41 2332.11 95.86
2032.44 91.25 1700.34 6. 90 1396.80 55.71 1304.85 67.90 1204.58 49.54
1014.90 90.68 821.96 48 .66 743.76 25.53 691.81 31.26 458.13 66.62
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 29- 6-2010
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 29- 6-2010
FT IR SPECT RUM
Date: 29- 6-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 29- 6-2010
100.0
FT IR SPECT RUM
Date: 04- 2-2010
100.0
400.0
cm-1
100.0
100.0
2 407.88
90
90
233 6.90
3841.76
90
233 4.08
9 28.06
925.46
80
90
23 25.60
1913.87
2027.07
80
1012.19
1988.46
3936.33
70
70
2738.44
80
1013.52
70
3799.99
2121.16
3926.98
941.51
80
70
2726.13
70
27 37.84
454.79
2737.73
1309.49
60
3946.81
1995.68
1015.20
1011.91
80
90
233 8.82
1914.74
2025.07
2818.47
453.48
60
2 824.30
60
456.62
27 36.26
2832.12
456.05
60
60
1304.90
7 70.71
588.52
2821.00
50
50
822.84
1389.71
%T
2821.85
50
1308.25
%T
1391.30
40
50
1302.34
13 95.57
%T
3084.59
1196.87
3079.94
823.89
40
50
13 96.30
%T
%T
1204.59
40
822.26
1171.83
40
820.61
40
6 88.01
30
2987.82
1200.38
30
743.49
1197.95
30
30
20
20
30
691.69
688.83
682.04
20
743.74
744.02
20
741.93
20
3431.33
1737.56
10
10
17 01.96
10
10
1 362.59
10
3445.81
3421.01
0.0
17 01.67
3423.22
0.0
4000.0
3000
2000
1500
1000
400.0
16 98.41
16 99.95
0.0
4000.0
3000
2000
cm-1
1500
1000
400.0
4000.0
cm-1
T3-0.6+0.4 .pk
0.0
3000
2000
1500
1000
400.0
1595.49
0.0
3 421.90
4000.0
3000
cm-1
T3-0.7+0.3 .pk
2000
1500
1000
400.0
4000.0
3000
2000
cm-1
T3-0.8+0.2 .pk
1500
1000
400.0
cm-1
T3-0.9+0.1 .pk
SJC-J-11.pk
T3-06_~1.SP 3601 4000. 00 400.00 6.36 100.00 4.00 %T 5 1 .00
T3-07_~1.SP 3601 4000. 00 400.00 7.87 99.64 4.00 %T 5 1. 00
T3-08_~1.SP 3601 4000. 00 400.00 8.04 99.49 4.00 %T 5 1. 00
T3-09_~1.SP 3601 4000. 00 400.00 6.34 100.00 4.00 %T 5 1 .00
SJC-J-11.sp 3601 4000.00 400. 00 7. 03 99. 99 4.00 %T 5 1.00
REF 4 000 100.00 2000 92.51 600

3431.33 6. 36 2824. 30 64. 14 2738.44 71.59 2336.90 95.13 2025.07 92.19
1701.96 14.14 1389.71 5 3.40 1309.49 69.27 1196. 87 50.48 1011.91 90. 25
928. 06 94 .26 822.84 56. 75 743.49 34.88 6 88. 01 39. 51 454.79 71.62
REF 4 000 98.82 2000 90.97 600

3936.33 93.51 3841.76 94.15 3421.01 7.87 3084.59 57.89 2821.00 63.73
2737.73 70.31 2334.08 96.40 1988.46 90.77 1914.74 93. 22 1701.67 8.08
1391.30 47.90 1308.25 57.53 1200.38 38.82 1012.19 86. 53 925.46 91.72
823. 89 47 .79 743.74 25.97 688.83 31.7 4 453.48 67.80
REF 4 000 98.56 2000 90.34 600

3423.22 8. 70 3079.94 53 .85 2821.85 58.55 2736.26 66.54 2338.82 95.68
1995.68 90.29 1698.41 8. 04 1395.57 50.35 1302.34 54.78 1197.95 37.70
1013.52 85.45 820.61 45 .97 741.93 25.02 682.04 28.94 456.62 66.17
REF 4 000 99.21 2000 91.71 600

3946.81 94.63 3421.90 6 .34 2818.47 70.21 2737.84 74.90 2407.88 98.27
2325.60 97.66 2027.07 9 0.96 1913.87 94.69 1699. 95 10.11 1396.30 54. 87
1304.90 64.35 1204.59 4 8.62 1015.20 87.01 822.26 48.87 744. 02 27.55
691. 69 32 .76 456.05 66. 00
REF 4 000 99.04 2000 98.74 600

3926.98 96.87 3799.99 95.07 3445.81 12.13 2987.82 40. 47 2832.12 69. 24
2726.13 89.36 2121.16 95.77 1737.56 19.80 1595.49 7.03 1362.59 17.87
1171.83 49.73 941.51 89 .22 770.71 65.15 588.52 63.33
Table - 7.17
Observations of FTIR spectrums for Benzaldehyde + 2-Butanone mixture:
0.9(BD)
0.8(BD)
*0.7(BD)
0.6(BD)
0.5(BD)
0.4(BD)
0.3(BD)
0.2(BD)
0.1(BD)
Cm-1
0.1(2B)
Cm-1
0.2(2B)
Cm-1
0.3(2B)
Cm-1
0.4(2B)
Cm-1
0.5(2B)
Cm-1
0.6(2B)
Cm-1
0.7(2B)
Cm-1
0.8(2B)
Cm-1
0.9(2B)
Cm-1
Cm-1
3928.23
3446.84
2819.60
2738.80
2363.70
1982.17
1913.80
1824.00
1697.38
1594.54
1453.80
1387.26
1310.06
1206.73
1169.33
1114.11
1072.35
1015.97
924.10
825.54
746.17
690.95
651.10
545.73
452.91
3946.81
3421.90
2818.47
2737.84
2407.88
3423.22
3079.94
2821.85
2736.26
2338.82
2325.60
2027.07
1913.87
1699.95
1396.30
1995.68
1698.41
1395.57
1302.34
1197.95
1013.52
820.61
741.93
682.04
456.62
3936.33
3841.76
3421.01
3084.59
2821.00
2737.73
2334.08
1988.46
1914.74
1701.67
1391.30
1308.25
1200.38
1012.19
925.46
823.89
743.74
688.83
453.48
3431.33
2824.30
2738.44
2336.90
2025.07
1701.96
1389.71
1309.49
1196.87
1011.91
928.06
822.84
743.49
688.01
454.79
3941.05
3424.31
2818.25
2737.53
2332.11
2032.44
1700.34
1396.80
1304.85
1204.58
1014.90
821.96
743.76
691.81
458.13
3433.85
2820.53
2734.92
2333.28
2022.06
1700.15
1393.13
1303.20
1197.28
1016.00
819.82
741.06
682.82
3956.28
3426.16
2989.41
2819.78
2736.48
2027.76
1704.63
1385.07
1311.05
1193.13
1013.78
932.87
823.73
744.12
688.57
456.26
3942.73
3451.99
2991.86
2815.56
2736.34
2130.63
1701.44
1649.46
1450.89
1386.52
1310.27
1202.77
1168.90
1017.84
930.50
824.59
745.04
689.05
650.09
454.91
3431.30
2984.73
2819.42
2737.35
2033.45
1707.96
1376.29
1189.37
1014.68
938.97
822.24
745.92
692.77
460.27
3921.99
3778.25
3445.42
2930.86
2087.47
1815.01
1626.89
1409.75
1247.00
1117.88
1011.07
563.25
1 (BD)
1304.90
1204.59
1015.20
822.26
744.02
691.69
456.05
294
1(2B)
Fig-7.17: FTIR spectrums for Benzaldehyde + Ethyl Acetate mixture:

ACIC
St.Jos eph's College ( Autonomous )
Trichy-2
ACIC
St.Jos eph's College ( Autonomous )
Trichy-2
FTIR S PECT RUM

Date: 23-6-2010
ACIC
St.J os ep h's Colle g e ( Auto nomo us )
Trich y-2
FTIR S PECTR UM
Date: 21-1 2-200 9
90
23 42 .0 5
9 24 .5 5
90
3 824.49
5 44 .0 4
9 25 .0 1
70
80
27 38 .8 1
1 39 7.28
80
825.54
50
927.36
60
50
%T
1 28 9.65
40
2819.60
10
0.0
1594.54
30 00
2 000
1 500
100 0
400 .0
400 0.0
30 00
2 000
cm-1
30 00
20 00
1 50 0
1 00 0
40 0. 0
cm-1
1 500
100 0
R EF 4 000 99 .3 3 2000 9 4.6 7 600

3 92 8.23 97.09 34 46.8 4 6.3 2 2 819.60 52 .37 2 738 .80 6 3.2 8 2 363.70 95 .0 8
1 98 2.17 93.61 19 13.8 0 94. 42 1 824 .00 94.71 169 7.38 18. 33 15 94 .54 10.43
1 45 3.80 66.53 13 87.2 6 52. 24 1 310 .06 55.31 120 6.73 48. 10 11 69 .33 62.45
1 11 4.11 85.01 10 72.3 5 87. 37 1 015 .97 88.91 924 .10 9 3.6 2 8 25.54 55. 94
7 46 .17 35 .49 6 90. 95 41.50 651 .10 43.6 5 5 45.73 67. 86 45 2.9 1 69.9 0
T4-08_~1.S P 3601 4000.00 400.00 7.67 100.00 4.00 %T 5 1.00
REF 4000 98.47 2000 94.83 600

3426.97 28.43 3074.62 56.80 2822.34 64.77 2738.81 74.71 2543.76 90.90
2342.05 95.64 1982.50 94.39 1915.68 94.66 1700.87 9.07 1600.13 35.70
1397.28 59.71 1289.65 48.64 1207.65 43.35 1022.33 89.37 924.55 89.05
824.79 59.18 741.17 36.73 544.04 78.22 452.99 78.43
REF 4000 99.49 2000 93.14 600

3946.88 96.74 3402.54 26.54 3069.09 33.63 2825.68 38.79 2739.72 49.44
1983.45 92.59 1916.65 92.30 1698.37 7.67 1605.97 28.26 1400.35 47.52
1228.31 30.02 925.01 77.31 819.31 50.75 719.78 28.16 540.81 74.24
452.23 73.20
2669.71
70
80
1119.87
70
40
1637.15
1394.82
30
703.05
30
1763.76
20
1286.37
3425.57
20
690.23
1260.52
1248.47
10
10
1242.81
10
10
3430.96
4 00 .0
4 00 0. 0
1056.51
40
543.80
1403.64
4 00 0.0
3 0 00
20 00
cm -1
1685.89
3434.47
0 .0
1690.47
10 0 0
622.08
1378.64
50
%T
926.22
30
0. 0
15 00
2991.58
60
544.56
2996.97
20
20
692.06
20 00
70
930.37
1052.99
808.71
805.02
40
1248.62
1686.44
3 0 00
2362.08
80
2556.94
2833.61
50
%T
1056.78
701.69
1405.99
3442.32
4 00 0. 0
2088.87
2663.95
60
2552.21
1599.10
2999.42
2489.19
90
928.00
70
2352.41
2661.10
2992.63
3067.72
10
2089.94
1119.52
30
20
0. 0
FTIR SPECTRUM
Date: 3/11/2009
Spectrum Name: Cl-AN-1.sp
3944.19
1914.06
2828.90
40
543.85
928.09
400.0
1 0 0. 0
545.98
931.36
1416.36
811.86
2826.21
2997.04
1000
ACIC
Trichy-2
FTIR SPECTRUM
Date: 23-6 -2010
50
30
1500
cm -1
80
%T
40
2000
REF 4000 98.93 2000 95.20 600

3937.36 90.52 3824.09 86.52 3427.15 5.11 2996.89 48.88 2824.44 62.89
2738.24 73.70 2670.77 73.47 2557.58 73.29 2353.71 88.24 2087.20 94.54
1982.95 94.39 1914.00 92.78 1686.42 6.82 1402.21 36.22 1246.93 14.71
1056.49 54.95 927.51 56.11 811.14 49.50 690.96 21.84 544.62 48.94
90
60
816.01
3000
400.0
T4-05_~1.SP 3601 4000.00 400.00 5.11 99.54 4.00 %T 5 1.00
ACIC
Trichy-2
1062.06
2556.93
%T
1000
T4-0.5+0.5.pk
1 00 .0
70
2740.53
50
1056.82
1500
cm-1
1916.25
3814.90
60
2558.07
2000
452.08
2669.85
454.80
2355.10
50
3000
REF 4000 98 .6 0 2000 92.52 600

3404.26 25. 71 30 69.00 52. 52 2821. 75 51.64 2738. 30 60.23 2338.90 94.09
1986.61 92. 20 19 12.24 93. 37 1704. 01 9. 00 1600.11 31.32 1451.57 61. 63
1389.34 51. 76 12 34.43 26. 85 1053. 37 65.10 921.84 89.99 825.35 51.00
744. 45 31. 91 689. 00 40. 61 45 2. 32 7 3. 64
3940.58
80
342 7.1 5
4000.0
4000.0
T 4-0.6+0. 4. pk
1 00 .0
1119.47
2739.54
60
400.0
T 4-06_~1. SP 3 601 4000.00 400 .0 0 9 .0 0 9 9.80 4.00 %T 5 1.00
1915.24
1914.54
80
1000
REF 4000 99.54 2000 92.98 600

3940.27 95.72 3824.49 93.52 3408.17 21.31 3073.65 37.37 2823.61 43.92
2740.09 52.20 2554.09 67.40 1981.36 91.95 1915.75 91.37 1700.85 8.28
1601.44 31.42 1397.86 49.12 1234.35 31.64 1069.95 75.17 927.36 74.68
822.83 52.79 737.91 32.79 543.34 72.29 451.45 74.20
90
90
2089.29
%T
1500
T4-07_~1.SP 3601 4000.00 400.00 8.28 99.84 4.00 %T 5 1.00
FTIR SPECTRUM
Date: 23-6 -2010
1 0 0. 0
1983.47
2000
T4-0.7+0.3.pk
ACIC
Trichy-2
FTIR SPECTRUM
Date: 23 -6-2010
90
16 86.42
0.0
3000
cm -1
ACIC
Trichy-2
FTIR SPECTRUM
Date: 23 -6-2010
3928.98
1246 .9 3
0.0
1704.01
0.0
4000.0
T4-0.8+0.2.pk
T4-09_~1.S P 3601 4000.00 400.00 9.07 99.84 4.00 %T 5 1.00
ACIC
Trichy-2
1 0 0. 0
690.96
10
10
170 0.8 5
400 .0
cm-1
T4-0.9+0.1.pk
SJ C-1BD.sp 36 01 4 000 .0 0 4 00.00 6.3 2 99. 90 4 .00 %T 5 1.00
544 .62
140 2.2 1
20
12 34.43
3404.26
0.0
400 0.0
0. 0
SJ C-1BD.pk
8 11.14
299 6.8 9
30
744.45
1600.11
20
10
16 98 .3 7
92 7.5 1
1 056 .49
40
30
737.91
3408.17
17 00 .8 7
82 5.35
68 9.00
1 234.35
1601.44
10
1697.38
3446.84
13 89.34
282 1.75
40
3 073.65
30
71 9.78
1 60 5.97
50
%T
306 9.00
%T
2823 .61
34 02 .5 4
20
20
20
282 4.4 4
1397.86
40
1 22 8.31
34 26 .9 7
20
60
2738.30
50
8 22.8 3
%T
28 25 .6 8
30
1 60 0.13
30 69 .0 9
690.95
746.17
198 2.9 5
25 57.58
452.32
1053.37
1451 .57
2740.09
7 41 .1 7
30
651.10
1206.73
30
70
60
50
12 07 .6 5
1387.26
40
45 1.45
543.34
1069 .95
2 554.09
8 19 .3 1
1 40 0.35
27 39 .7 2
40
%T
40 00 . 0
382 4.0 9
1 912.2 4
70
82 4.79
30 74 .6 2
%T
545.73
2 353.71
80
92 1.84
1 915.75
70
60
28 22 .3 4
50
452.91
1169.33
208 7.2 0191 4.0 0

273 8.2 4
233 8.90 19 86.61
198 1.3 6
39 40.2 7
45 2.23
45 2.99
60
1015.97
1310.06
1453.80
26 70.77
393 7.3 6
90
2738.80
10
100.0
Spec trum Name: T4-0.6+0.4.sp

100.0
5 40 .8 1
1 91 6.65
1114.11
1913.80
70
60
Spectrum Name: T4-0.5+0.5.s p
90
80
70
924.10
1982.17
80
FTIR S PECTRUM
Date: 23-6-2010
FT IR SPECT RUM
Date: 23 -6-2010
100.0
19 83 .4 5
1 02 2.33
1 91 5.68
2363.70
3928.23
3 94 6.88
19 82 .5 0
2 54 3.76
80
1072.35
90
FTIR SPECTRUM
Date: 23-6-2010
90
1824.00
ACIC
Trichy-2
ACIC
Tric hy-2
Spectrum Name: T 4-0.8+0.2.s p

100.0
Sp ectrum Name: SJC-1BD.sp

10 0. 0
ACIC
Trichy-2
FTIR S PECT RUM

Date: 23-6-2010
Spectrum Name: T 4-0.9+0.1.s p

100.0
15 00
10 0 0
cm -1
T4-0.4+0.6.pk
T4-0.3+0.7.pk
T4-04_ ~1.SP 3601 4000.00 400 .00 5.75 99.86 4.00 %T 5 1.0 0
T4-03_ ~1.SP 3601 4000.00 400 .00 7.89 99.82 4.00 %T 5 1.0 0
REF 4000 99.20 2000 9 4.56 600

3928.98 90.25 3442.32 5.75 2997.04 36.93 2826.21 48.37 2739.5 4 60.28
2669.71 59.20 2558.07 59.58 2355.10 82.30 2089.29 92.87 19 83.47 93.67
1914.54 90.96 1686.44 6.12 1405.99 33.11 1248.62 12.39 1119.8 7 65.48
1056.82 54.72 928.09 45.31 811.86 45.36 692.06 1 7.95 543.85 44.55
454.80 67.65
REF 4000 99.42 2000 9 5.74 600

3425.57 24.94 3067.72 44.25 2999.42 44.20 2828.90 48.65 27 40.53 61.46
2669.85 58.80 2556.93 59.51 1915.24 93.73 1690.47 7.89 1599.1 0 42.03
1416.36 50.30 1286.37 27.15 1119.47 80.61 1062.06 75.59 93 1.36 55.80
816.01 68.31 701.69 36.35 54 5.98 69.45 452.08 85.58
1698.70
0 .0
3 00 0
2 00 0
1 50 0
1 00 0
4 00 .0
4 00 0.0
3449.55
3 00 0
2 00 0
cm-1
4 00 .0
1 50 0
1 00 0
4 00 .0
cm-1
0. 0
4 00 0. 0
3 0 00
20 00
15 00
10 0 0
4 00 .0
cm -1
T4-0.2+0.8.pk
T4-0.1+0.9.pk
T4-02_~1.SP 3601 4000.00 400.00 6.38 99.99 4.00 %T 5 1.00
T4-01_~1.SP 3601 4000.00 400.00 7.67 100.00 4.00 %T 5 1.00
REF 4000 99.26 2000 88.24 600

3940.58 92.24 3814.90 88.53 3430.96 6.38 2992.63 51 .91 2661.10 69.15
2552.21 66.66 2352.41 74.98 1916.25 88.91 168 5.89 10.13 1403.64 31.61
1248.47 16.32 1119.52 55.26 1056.78 49.95 926 .22 40 .29 805.02 50.50
690.23 20.43 543.80 37.44
REF 4000 99.63 2000 96.95 600

3944.19 96.64 3434.47 9.28 2996.97 51.18 2833 .61 64.69 2663.95 74.61
2556.94 74.70 2089.94 95.37 1 914.06 96.4 9 1698.70 7.67 1394.82 39.57
1260.52 19.75 1052.99 65.44 9 30.37 69.32 808.71 67.28 703.05 35.76
544.56 62.42
Cl-AN-1.p k
Cl-AN-1.s p 3 601 4000.00 400.00 6.33 10 0.00 4.00 %T 5 1.00
REF 4000 99.39 2000 9 7.58 600
3449.55 6.33 2 991.58 69.36 2489.19 98.54 2362.08 89.00 2088.87 9 5.42
1763.76 32.63 163 7.15 43.78 1378.6 4 6 7.05 1242.81 18.7 3 1056.51 55. 12
928.00 97.75 6 22.08 6 9.86
Table - 7.18
Observations of FTIR spectrums for Benzaldehyde + Ethyl Acetate mixture:
1 (BD)
Cm-1
3928.23
3446.84
2819.60
2738.80
2363.70
1982.17
1913.80
1824.00
1697.38
1594.54
1453.80
1387.26
1310.06
1206.73
1169.33
1114.11
1072.35
1015.97
924.10
825.54
746.17
690.95
651.10
545.73
452.91
0.9(BD)
0.8(BD)
0.7(BD)
*0.6(BD)
0.5(BD)
0.4(BD)
0.3(BD)
0.2(BD)
0.1(BD)
0.1(EA)
Cm-1
0.2(EA)
Cm-1
0.3(EA)
Cm-1
0.4(EA)
Cm-1
0.5(EA)
Cm-1
0.6(EA)
Cm-1
0.7(EA)
Cm-1
0.8(EA)
Cm-1
0.9(EA)
Cm-1
3944.19
3434.47
2996.97
2833.61
2663.95
2556.94
2089.94
1914.06
1698.70
1394.82
1260.52
1052.99
930.37
808.71
703.05
544.56
3940.58
3814.90
3430.96
2992.63
2661.10
2552.21
2352.41
1916.25
1685.89
1403.64
1248.47
1119.52
1056.78
926.22
805.02
690.23
543.80
3425.57
3067.72
2999.42
2828.90
2740.53
2669.85
2556.93
1915.24
1690.47
1599.10
1416.36
1286.37
1119.47
1062.06
931.36
816.01
701.69
545.98
452.08
3928.98
3442.32
2997.04
2826.21
2739.54
2669.71
2558.07
2355.10
2089.29
1983.47
1914.54
1686.44
1405.99
1248.62
1119.87
1056.82
928.09
811.86
692.06
543.85
454.80
3937.36
3824.09
3427.15
2996.89
2824.44
2738.24
2670.77
2557.58
2353.71
2087.20
1982.95
1914.00
1686.42
1402.21
1246.93
1056.49
927.51
811.14
690.96
544.62
3404.26
3069.00
2821.75
2738.30
2338.90
1986.61
1912.24
1704.01
1600.11
1451.57
1389.34
1234.43
1053.37
921.84
825.35
744.45
689.00
452.32
295
3940.27
3824.49
3408.17
3073.65
2823.61
2740.09
2554.09
1981.36
1915.75
1700.85
1601.44
1397.86
1234.35
1069.95
927.36
822.83
737.91
543.34
451.45
3946.88
3402.54
3069.09
2825.68
2739.72
1983.45
1916.65
1698.37
1605.97
1400.35
1228.31
925.01
819.31
719.78
540.81
452.23
3426.97
3074.62
2822.34
2738.81
2543.76
2342.05
1982.50
1915.68
1700.87
1600.13
1397.28
1289.65
1207.65
1022.33
924.55
824.79
741.17
544.04
452.99
1(EA)
Cm-1
3449.55
2991.58
2489.19
2362.08
2088.87
1763.76
1637.15
1378.64
1242.81
1056.51
928.00
622.08
Fig-7.18: FTIR spectrums for Benzyl Chloride + 2-Butanone mixture:

ACIC
Trichy-2
ACIC
Trichy-2
100.0
FTIR SPECT RUM

Date: 2/23/2008
22 35.79
Spectrum Name: Sam =3.s p
100.0
213 9.83
20 27 .0 8
9 23 .4 3
2 13 9.0 3
1 01 2.1 8
1 072 .2 8
19 10 .17
65 0.60
6 50.23
82 6.70
6 88.70
30
20
1 454 .6 1 1 310 .20
306 6.7 2
27 38.47
40
13 91.15
28 18.73
7 47 .3 9
30
689 .19
11 68 .19
3 393 .99
20
1204.32
159 6.1 8
20
1597.13
120 3.8 3
747 .7 8
747.33
10
10
17 02 .00
3000
2000
15 00
100 0
400.0
10
0 .0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
40 00.0
cm-1
10
3 000
2000
1500
1000
SAM_1~1.SP 3601 4000.00 400.00 8.04 99.86 4.00 %T 3 1.00
SAM_2~1.SP 3601 4000.00 400.00 9.18 99.98 4.00 %T 3 1.00
SAM_3~2.SP 3601 4000.00 400.00 9.36 99.92 4.00 %T 3 1.00
REF 4000 99.14 2000 89.33 600

3394.11 31.28 3072.11 51.40 2818.42 48.88 2738.34 53.57 2372.89 93.94
2330.26 93.64 2235.79 97.53 2139.83 96.21 2026.52 89.18 1982.86 86.85
1911.14 88.44 1826.50 87.25 1701.69 8.03 1596.72 33.01 1454.12 61.66
1392.85 56.13 1308.72 56.19 1204.25 35.78 1166.91 52.28 1109.92 80.91
1073.38 80.67 1012.73 81.15 922.40 89.82 826.07 47.98 746.86 29.08
688.87 42.31 650.60 46.50 450.67 70.58
REF 4000 99.84 2000 93.13 600

3392.13 50.39 3067.40 62.67 2818.44 55.53 2738.20 59.65 2367.01 92.64
2332.27 92.66 2236.38 98.68 2139.34 97.78 2027.08 92.62 1983.03 91.02
1910.17 92.08 1826.27 90.69 1702.00 9.18 1655.24 45.74 1595.90 39.27
1454.70 65.13 1392.10 63.91 1310.13 60.34 1204.12 38.07 1166.83 55.09
1108.54 86.82 1072.28 83.86 1012.18 85.07 923.43 91.83 826.70 50.84
747.06 31.09 688.70 46.57 650.23 51.30 450.89 74.49
REF 4000 99.12 2000 92.30 600

3396.11 35.96 3070.63 61.26 2818.50 59.99 2738.21 64.26 2373.11 95.85
2330.79 96.13 2235.76 98.05 2139.03 96.82 2027.29 91.74 1983.09 90.43
1911.42 91.70 1825.70 90.59 1701.38 9.35 1654.81 41.64 1596.48 40.79
1454.41 67.49 1392.53 62.65 1310.26 62.41 1204.34 41.37 1166.82 58.69
1109.80 84.41 1072.43 84.63 1012.95 86.94 923.24 91.48 826.64 53.85
746.91 33.76 688.63 47.68 650.17 51.53 450.96 74.90
REF 40 00 99 .3 4 20 00 9 2 .99 600

33 9 6.05 3 9.35 3 0 69.4 1 54.0 6 281 8. 69 48. 05 27 38 .46 54 .69 2 32 9.9 1 9 6.2 6
21 3 8.94 9 7.57 1 9 83.0 9 91.3 5 191 1. 55 92. 50 18 26 .24 91 .44 1 70 3.5 3 8 .98
15 9 7.13 3 4.18 1 4 53.9 9 62.7 4 139 1. 81 57. 85 13 08 .28 56 .99 1 20 4.3 2 3 8.1 6
11 6 8.77 4 8.45 1 1 09.3 3 84.9 0 107 3. 80 83. 60 10 11 .83 84 .65 9 25 .2 8 91 .7 7
82 5 .98 50 .4 5 7 47. 33 31 .29 69 0 .0 5 46 .11 6 51.0 3 50 .52 45 1.1 9 73.8 7
1500
1000
REF 4000 99.20 2000 90.29 600

3393.99 32.63 3066.72 49.01 2981.95 58.79 2818.73 40.37 2738.47 45.18
2405.59 95.68 2329.51 94.80 2138.99 96.05 2027.34 89.59 1984.22 87.57
1911.03 89.28 1826.92 87.47 1703.87 7.35 1596.18 27.64 1454.61 48.79
1391.15 47.10 1310.20 49.05 1203.83 28.43 1168.19 36.29 1106.93 83.07
1073.17 76.76 1011.61 79.05 928.64 87.21 826.38 40.72 747.78 22.49
689.19 37.55 650.30 41.85 451.17 66.64
FTIR SPECTRUM
Date: 2/21/2008
Spectrum Name: Sam = 1 0.sp
Spectrum Name: Sam = 1 1.sp
1 00 .0
1 00 .0
2339.69
1024.29
50
3399.05
2983.47
2819.42
1387.82
1169.24
1596.94
40
%T
%T
938.37
2984.67
548.46
752.00
1289.16
%T
934.40
40
1597.56
3446.56
50
50
933.60
2823.30
40
747.32
30
746.48 654.22
1451.42
1204.29
30
2370.90
60
593.27
2558.19
50
1596.96
747.69
2098.22
70
3069.90
689.04
40
1204.37
80
547.41
2668.13
50
%T
1170.93
2552.77
594.50
805.24
2558.32
60
826.81
650.21
691.22
%T
750.45
1073.49
547.54
821.56
60
1126.20
1324.68
70
1124.97
2736.41
1454.30
1311.01
1391.35
80
1072.21
2670.86
70
2819.21
2984.11
60
650.64
1024.90
90
1916.64
450.85
80
451.46
1073.33
826.54
1025.96
90
1917.31
80
451.50
2738.64
1309.35
400.0
ACIC
Trichy-2
FTIR SPECTRUM
Date: 2/21/2008
Spectrum Name: Sam = 9 .sp
70
1453.55
3069.09
1000
SAM_6~1.SP 3601 4000.00 400.00 7.36 99.92 4.00 %T 3 2.00
4 00 . 0
ACIC
Trichy-2
90
1016.45
933.56
935.87
2738.97
60
1500
c m -1
REF 4000 99.81 2000 96.51 600

3393.76 58.42 3067.49 63.29 2818.81 62.12 2738.32 68.14 2331.93 97.79
1982.81 95.37 1912.98 95.82 1825.18 95.14 1703.44 8.94 1595.99 47.21
1454.20 67.73 1391.37 65.94 1310.66 63.92 1204.91 43.62 1168.61 55.98
1109.98 86.79 1072.58 87.48 1015.10 90.79 930.45 92.50 826.77 60.21
747.39 38.72 689.11 55.98 650.24 59.36 451.16 82.34
1 00 .0
1109.88
70
2000
SAM_5~2.SP 3601 4000.00 400.00 8.95 99.98 4.00 %T 3 1.00
1 0 00
FTIR SPECTRUM
Date: 2/21/2008
1984.33
1012.35
80
3000
SAM _4 ~1.S P 3 601 40 0 0.0 0 4 00 .0 0 8 .9 9 9 9 .8 7 4.0 0 % T 3 1 .0 0
1 50 0
ACIC
Trichy-2
90
1983.33
4000 .0
Sam =4. pk
2 0 00
1110.76
90
400.0
Sam = 6.pk
30 00
cm -1
FTIR SPECTRUM
Date: 2/21/2008
1 00 .0
2000
Sam = 5.pk
4 0 00 . 0
ACIC
Trichy-2
3 000
cm-1
Sam = 3.pk
1 00 .0
0.0
40 00.0
1703.53
0 .0
Sam = 2.pk
FTIR SPECTRUM
Date: 2/21/2008
1 703 .87
0 .0
400.0
c m -1
Sam =1.pk
ACIC
Trichy-2
10
17 03.44
170 1.38
0.0
4000.0
20
10
17 01 .69
0.0
6 50.30
8 26.38
30
690.05
30
451 .17
50
1 204 .9 1
651.03
825.98
1168.77
3396.05
20
101 1.6 1
107 3.1 7
65 0.24
826 .7 7
116 8.61
6 89 .11
40
1391.81
2818.69
40
7 46 .9 1
20
1 911 .0 3
2 981 .95
60
1 310 .6 6
15 95.99
2738.46
3069.41
15 96.48
3 396 .1 1
74 7.06
9 28.64
%T
1308.28
50
%T
1 204 .3 4
12 04.12
74 6.86
1 826 .9 2
70
1 39 1.37
3 393 .7 6
50
%T
1453.99
40
15 95 .9 0
30
12 04 .2 5
15 96 .7 2
3 394 .1 1
2 027 .3 4
198 4.2 2
14 54 .20
3 067 .4 9
281 8.81
451.19
60
6 88 .6 3
688 .8 7
30
232 9.51
80
45 1.16
273 8.32
60
1109.33
1011.83
65 0.1 7
1 106 .93
90
925.28
1826.24
70
826 .6 4
%T
24 05.59
9 30 .45
1 072 .5 8
70
1911.55
1983.09
13 92 .53
1 310 .2 6 1 16 6.8 2
50
11 66.83
40
19 12 .98
1073.80
2138.94
2329.91
90
16 54 .81 1 45 4.41
273 8.21
3 070 .6 3
281 8.50
13 10 .1 3
33 92 .1 3
82 6.07
45 0.96
60
1 39 2.10
2 73 8.2 0
2 818 .4 4
%T
116 6.91
80
1 45 4.70
3 067 .4 0
50
13 08 .7 2
70
16 55.24
60
1 39 2.85
19 82 .81 18 25 .18
80
101 5.10
1 00 .0
1 072 .4 3
450 .8 9
45 0.67
14 54 .1 2
27 38 .3 4
3 072 .1 1
28 18 .4 2
40
FTIR SPECTRUM
Date: 2/21/2008
2 138 .99
11 09.98
2 331 .9 3
90
Spectrum Nam e: Sam = 4.s p
9 23 .24
10 12 .95
1 825 .7 0
19 83 .09
70
1 01 2.7 3
60
50
19 11 .42
202 7.29
80
11 09 .9 2
70
%T
FT IR SPECT RUM
Date: 2/23/ 2008
1 10 9.80
23 30.79
90
23 32.27 19 83.03 1 82 6.27
80
Spectrum Name: Sam = 6.sp

10 0.0
22 35 .7 6
23 67 .0 1
9 22 .4 0
1 82 6.50
19 82.86
19 11 .14
2 373 .1 1
213 9.34
90
20 26 .5 2
2 33 0.2 6
Spectrum Name: Sam =5.s p

10 0.0
10 0.0
1 10 8.5 4
22 36.38
107 3.38
2 37 2.89
80
ACIC
Trichy-2
FTIR SPECTRUM
Date: 2/23/2008
ACIC
St.J os ep h 's C olleg e ( Aut onom o us )
T richy-2
FTIR SPECTRUM
Date: 2/23/2008
Spectrum Name: Sam = 2.sp
90
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 2/23/2008
Spectrum Name: Sam =1.sp
1453.62
40
1174.81
708.66
1176.11
1418.90
2985.42
30
1419.42
30
30
2987.29
706.48
707.39
20
20
1288.32
20
1289.26
20
1172.99
20
1374.94
3446.41
3450.46
10
10
10
1705.87
4 00 0.0
0 .0
3 00 0
2 00 0
10
1 50 0
1 00 0
4 00 .0
4 00 0.0
cm-1
2 00 0
1 50 0
1 00 0
4 00 .0
3449.47
1690.02
0 .0
3 00 0
10
1698.20
1703.56
0 .0
0 .0
4 00 0.0
3 00 0
cm-1
2 00 0
1 50 0
1 00 0
4 00 .0
1724.52
0 .0
4 00 0.0
3 00 0
2 00 0
cm-1
1 50 0
1 00 0
4 00 .0
4 00 0.0
3 00 0
2 00 0
cm-1
1 50 0
1 00 0
4 00 .0
cm-1
Sam = 7.pk
Sam = 8.pk
Sam = 9.pk
Sam = 10.pk
Sam = 11.pk
SAM_7~1.SP 3601 4000.00 400.00 9.19 99.85 4 .00 %T 3 2.0 0
SAM_8~1.SP 3601 4000.00 400.00 8.38 99.85 4 .00 %T 3 2.0 0
SAM_9~1.SP 3601 4000.00 400.00 6.87 99.57 4 .00 %T 3 2.0 0
SAM_10~1.SP 3601 4000.00 400.00 6.95 99.68 4.00 %T 3 2.00
SAM_11~1.SP 3601 4000.00 400.00 6.34 99.25 4.00 %T 3 1.00
REF 4000 99.75 2000 96.32 600

3399.05 57.33 3069.09 63.15 2983.47 64.86 281 9.42 62.71 2738.97 69.66
1983.33 95.46 1705.87 9.19 1596.94 49.46 1453.55 66 .53 1387.82 62.11
1309.35 64.96 1204.37 45.42 1170.93 52.92 110 9.88 86.60 1012.35 90.83
935.87 90.76 826.54 64.55 747 .69 44 .24 691.22 60.37 650.64 64.96
451.50 86.71
REF 4000 99.10 2000 95.75 600

3446.56 36.47 2984.11 68.93 2819.21 67.88 273 8.64 73.35 1984.33 94.86
1703.56 8.37 1596.96 48.66 1454.30 65.93 1391.35 61 .11 1311.01 65.22
1204.29 44.16 1169.24 54.53 1110.76 84.92 107 3.33 86.65 1016.45 91.12
933.56 91.56 826.81 61.89 747 .32 41 .10 689.04 54.92 650.21 58.33
451.46 83.18
REF 4000 99.46 2000 90.97 600

3446.41 23.54 3069.90 45.63 2984.67 40.80 282 3.30 51.11 2736.41 61.18
2670.86 59.71 2558.19 59.51 1917.31 89.76 169 8.20 6.87 1597.56 43.17
1451.42 54.01 1418.90 40.44 1288.32 28.23 117 4.81 42.16 1124.97 74.46
1072.21 80.23 1024.29 90.34 933.60 51.24 821.56 67.89 746 .48 51.87
706.48 31.65 654.22 52.72 547 .54 68 .63 450.85 87.84
REF 4000 99.53 2000 95.68 600

3450.46 19.61 2985.42 39.89 2668.13 69.66 255 8.32 67.90 1916.64 94.53
1690.02 6.95 1419.42 38.35 1324.68 46.40 1289.26 27 .86 1176.11 42.53
1126.20 77.73 1073.49 84.46 1025.96 94.37 934 .40 50 .29 805.24 77.29
750.45 79.91 707.39 30.60 594 .50 76 .48 547.41 69.65
REF 4000 99.25 2000 84.80 600

3449.47 6.34 2987.29 35.70 2552.77 91.18 2370.90 75 .22 2339.69 84.29
2098.22 82.03 1724.52 7.85 1453.62 48.10 1374.94 24 .73 1289.16 60.26
1172.99 28.20 1024.90 96.34 938.37 70.56 752.00 64.59 708 .66 45.53
593.27 58.47 548.46 67.08
Table - 7.19
Observations of FTIR spectrums for 2-Butanone + Ethyl Acetate
0.9(BC)
0.8(BC)
0.7(BC)
0.6(BC)
*0.5(BC)
0.4(BC)
0.3(BC)
0.2(BC)
0.1(BC)
Cm-1
0.1(2B)
Cm-1
0.2(2B)
Cm-1
0.3(2B)
Cm-1
0.4(2B)
Cm-1
0.5(2B)
Cm-1
0.6(2B)
Cm-1
0.7(2B)
Cm-1
0.8(2B)
Cm-1
0.9(2B)
Cm-1
Cm-1
3394.11
3072.11
2818.42
2738.34
2372.89
3392.13
3067.40
2818.44
2738.20
2367.01
3396.11
3070.63
2818.50
2738.21
2373.11
3396.05
3069.41
2818.69
2738.46
2329.91
3393.76
3067.49
2818.81
2738.32
2331.93
2330.26
2235.79
2139.83
2026.52
1982.86
2332.27
2236.38
2139.34
2027.08
1983.03
2330.79
2235.76
2139.03
2027.29
1983.09
2138.94
1983.09
1911.55
1826.24
1703.53
1982.81
1912.98
1825.18
1703.44
1595.99
1911.14
1826.50
1701.69
1596.72
1454.12
1910.17
1826.27
1702.00
1655.24
1595.90
1911.42
1825.70
1701.38
1654.81
1596.48
1597.13
1453.99
1391.81
1308.28
1204.32
1454.20
1391.37
1310.66
1204.91
1168.61
1392.85
1308.72
1204.25
1166.91
1109.92
1454.70
1392.10
1310.13
1204.12
1166.83
1168.77
1109.33
1073.80
1011.83
925.28
1109.98
1072.58
1015.10
930.45
826.77
3446.56
2984.11
2819.21
2738.64
1984.33
1703.56
1596.96
1454.30
1391.35
1311.01
1204.29
1169.24
1110.76
1073.33
1016.45
933.56
826.81
747.32
689.04
650.21
451.46
3449.47
2987.29
2552.77
2370.90
2339.69
2098.22
1724.52
1453.62
1374.94
1289.16
1172.99
1024.90
938.37
752.00
708.66
593.27
548.46
1108.54
1072.28
1012.18
923.43
747.39
689.11
650.24
451.16
688.87
650.60
450.67
747.06
688.70
450.89
825.98
747.33
690.05
651.03
451.19
3446.41
3069.90
2984.67
2823.30
2736.41
2670.86
2558.19
1917.31
1698.20
1597.56
1451.42
1418.90
1288.32
1174.81
1124.97
1072.21
1024.29
933.60
821.56
746.48
706.48
654.22
547.54
450.85
3450.46
2985.42
2668.13
2558.32
1916.64
1690.02
1419.42
1324.68
1289.26
1176.11
1126.20
1073.49
1025.96
934.40
805.24
750.45
707.39
594.50
547.41
1073.38
1012.73
922.40
746.86
1454.41
1392.53
1310.26
1204.34
1166.82
1109.80
1072.43
1012.95
923.24
746.91
688.63
450.96
3399.05
3069.09
2983.47
2819.42
2738.97
1983.33
1705.87
1596.94
1453.55
1387.82
1309.35
1204.37
1170.93
1109.88
1012.35
935.87
826.54
747.69
691.22
650.64
451.50
1 (BC)
3393.99
3066.72
2981.95
2818.73
2738.47
2405.59
2329.51
2138.99
2027.34
1984.22
1911.03
1826.92
1703.87
1596.18
1454.61
1391.15
1310.20
1203.83
1168.19
1106.93
1073.17
1011.61
928.64
747.78
689.19
650.30
451.17

296
1(2B)
Fig-7.19: FTIR spectrums for Ethyl Acetate + Benzyl Chloride mixture:

ACIC
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/14/2009
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/14/2009
Spectrum Name: EA+BC- 1.sp
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/14/2009
100.0
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/14/2009
100.0
FT IR SPECT RUM
Date: 2/14/2009
100.0
FT IR SPECT RUM
Date: 2/14/2009
100.0
100.0
100.0
3 964.11
90
90
90
80
80
3918.91
90
2084.37
90
90
3921.12
2340.59
80
3957.8 7
70
70
3775.26
3775.5 3
80
1 889.30
70
70
3067.61
60
60
1817.37
3776.47
1381.27
2965.86
50
1723.04
620.59
30
13 89.69
1610.33
1451.41
30
1956 .79
1000
400.0
3000
2000
1500
1000
400.0
1761.67
3000
2000
1500
20
30
1451.06
400.0
1265.27
10
694.94
3000
2000
1500
1000
400.0
0.0
4000.0
3000
2000
1500
cm -1
EA+BC-3.pk
695.62
0.0
4000.0
1000
400.0
4000.0
3000
cm -1
EA+BC-4.pk
2000
1500
1000
EA+BC-5.pk
EA+BC-6.pk
EA_BC-~4. SP 3601 4000.00 4 00. 00 6.33 99.84 4.00 %T 5 1.00
EA_BC-~1. SP 3601 4000.00 4 00. 00 6.35 99.94 4.00 %T 5 1.00
EA_BC-~2. SP 3601 4000.00 4 00. 00 8.83 100.00 4.00 %T 5 1.00
EAE083~1. SP 3601 4000.00 4 00. 00 7.15 100.00 4.00 %T 5 2.00
EAE883~1. SP 3601 4000.00 4 00. 00 6.95 100.00 4.00 %T 5 2.00
EAE093~1. SP 3601 4000.00 4 00. 00 8.67 99.99 4.00 %T 5 2.00
REF 4000 98.26 2000 61.61 600

3964.11 93.33 3776.47 67.73 3437. 83 6.35 2928.87 40.87 2115.59 58.76
1817.37 68.83 1723.04 57.79 1610. 33 34.28 1379. 47 44. 37 1242. 98 36. 73
1118.19 31.32 697.37 35.99 620.03 43. 80 559.44 49.88
REF 4000 98.23 2000 95.06 600

3918.91 96.12 3775.26 84. 22 3451. 07 10.0 9 3067.61 48.72 3034. 19 45.50
2965.86 58.33 2340.59 92. 81 2084. 37 94.0 0 1957.48 89.45 1889. 30 92.01
1763.12 55.78 1625.53 52. 11 1492. 95 67.4 8 1451.41 45.74 1381. 27 62.42
1253.88 23.09 1107.37 60. 80 1067. 81 55.7 3 927. 99 89.85 809. 62 64. 19
760.92 51.5 2 695. 67 8.82 559.29 50.52 467.04 68.36
REF 4000 97.79 2000 53.46 600

3921.12 94.46 3774.33 75. 22 3436. 06 23.0 1 3033.29 24.66 1956. 79 47.84
1891.42 50.22 1761.67 27. 52 1599. 84 37.4 7 1450.39 27.33 1377. 21 36.99
1249.46 8. 69 1061.68 28.92 928.36 51.66 810.08 38.59 759. 95 31.90
695.28 7.15 559.59 40.30 466.15 57.44
REF 4000 98.98 2000 73.22 600

3775.53 88.58 3433.62 55. 25 3033. 16 39.2 5 2961.40 51.44 1955. 96 67.24
1889.21 69.55 1764.05 65. 42 1598. 56 60.0 1 1493.24 56.73 1451. 21 38.77
1381.19 66.13 1264.45 25. 83 1071. 85 55.6 1 927. 66 71.26 810. 37 53. 78
761.09 45.5 0 694. 94 6.95 559.24 54.20 465.43 72.70
REF 4000 98.18 2000 71.48 600

3916.71 95.98 3776.62 84.25 3435. 76 43.35 3033. 47 37. 84 2961. 25 48. 64
1956.21 65.29 1889.50 67.83 1811. 99 69.25 1765. 78 67. 67 1598. 42 55. 26
1492.95 56.29 1451.06 39.15 1265. 27 27.62 1072. 82 53. 03 1031. 02 59. 53
927.48 67.8 8 810.22 50. 27 760.92 42.27 695. 62 8.67 559.42 51.00
465.89 68.1 8
ACIC
T richy-2
ACIC
T richy-2
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/14/2009
ACIC
T richy-2
FT IR SPECT RUM
Date: 2/14/2009
90
90
ACIC
Trichy-2
FT IR SPECT RUM
Date: 2/14/2009

100.0
FT IR SPECT RUM
Date: 2/14/2009
100.0
FTIR SPECTRUM
Date: 2/14/2009
90
3908.14
400.0
cm -1
REF 4000 75.33 2000 41.99 600

3957.87 72.68 3776.13 59.06 3443. 70 6.33 2990.70 33.10 2375.94 39.21
2106.73 40.14 1766.66 38.80 1607. 16 27.22 1389. 69 38. 26 1243. 16 26. 83
1114.03 32.93 620.59 45.10
100.0
559.42
760.92
3033.47
20
1264.45
10
695.28
1249.46
1000
cm -1
EA+BC-2.pk
1450.39
695.67
0.0
4000.0
cm -1
EA+BC-1.pk
761.09
3436.06
10
3451.07
0.0
4000.0
810.22
1492.95
40
1451.21
30
1377.21
465.89
1072.82
%T
1061.68
3033.29
20
1253.88
10
3437.83
1500
cm -1
559.24
3033.16
8 10.08
1599.84
30
20
10
2000
810.37
759.95
20
0.0
3000
927.48
1031.02
1598.42
50
1071.85
1493.24
2961.40
29 61.25
1118.19
1243.16
344 3.70
4000.0
1 889.50
1956 .21 17 65.78
1381.19
3433.62
40
3435.76
697.37
1 114.03
1607.16
10
465.43
60
17 64.05
50
%T
928.36
1891.42
40
559.59
1242.98
30
237 5.94
2990.70
20
0.0
181 1.99
70
927.66
1889.21
1955 .96
60
466.15
%T
559.29
2928 .87
1766.66
3776.62
1598.56
760.92
3034.19
620.03
13 79.47
210 6.73
70
3774.33
50
1067.8 1
1625.53
40
80
1107.37
1763.12
%T
559.44
40
60
8 09.62
1492.95
50
%T
40
80
467.04
60
2115.59
3776.13
50
%T
3916 .71
927.99
1957 .48
100.0
90
Spec trum Name: EA+BC-10.sp
1810.23
3906.50
10 0. 0
80
80
3773.20
80
3773.85
80
90
2524.74
3774.7 0
3772.2 9
70
70
70
2709.24
1889.76
2 338.23
1891.62
50
80
927.24
40
2869.48
811.07
40
2961.58
60
40
60
1208.69
758.79
344 6.99
30
1451.38
20
50
3432.65
1500
1000
3000
2000
1500
30
400.0
4000.0
3000
2000
1500
1000
1027.31
1 600.22
20
3034.41
126 6.87
694.99
0.0
4000.0
695.01
3000
2000
20 00
1 50 0
1 0 00
4 00 .0
EA+BC-10.pk
EA_BC-~3. SP 3601 4000.00 4 00. 00 7.32 99.99 4.00 %T 5 1.00
EAE8A3~1.SP 3601 4000. 00 400.00 7.31 10 0.00 4. 00 %T 5 2.00
REF 4000 98.72 2000 81.52 600

3908.14 96.36 3773.20 87.62 3446. 99 35.66 3034. 34 33. 30 2961. 58 45. 87
2869.48 66.48 2709.24 78.12 2524. 74 80.31 2338. 23 75. 23 1956. 02 69. 47
1889.76 73.30 1810.23 74.35 1761. 76 74.92 1601. 62 56. 57 1493. 38 55. 11
1451.38 36.25 1265.76 25.95 1209. 60 54.50 1161. 44 58. 88 1073. 99 51. 88
1029.68 60.99 927.24 70.66 809.95 48. 15 758.79 38.23 695.21 7.31
559.57 47.3 1 465.40 64. 47
REF 4000 98.97 2000 71.06 600

3773.85 87.59 3435.20 49. 88 3033. 88 34.3 2 2960.87 47.62 2868. 79 63.95
2336.49 69.32 1956.00 63. 59 1890. 40 66.4 6 1811.93 67.89 1600. 27 57.82
1493.61 53.47 1451.51 36. 27 1266. 47 26.2 2 1208.69 55.80 1073. 76 54.70
1028.04 62.74 927. 51 69.32 810.70 49.54 759.61 40.26 694. 82 7.31
559.42 51.0 3 465. 61 70.35
1500
1000
400.0
cm -1
3 0 00
c m -1
EAE893~1. SP 3601 4000.00 4 00. 00 7.45 99.99 4.00 %T 5 2.00
759.02
1451.17
10
10
400.0
4 00 0 .0
REF 4000 98.09 2000 60.09 600

3774.70 84.76 3435.13 41.14 3034. 24 36.80 2961. 08 46. 92 1956. 43 55. 84
1891.62 57.84 1814.22 59.48 1600. 19 48.94 1493. 15 50. 68 1451. 65 35. 85
1266.03 26.31 1073.74 48.88 928.4 7 60.94 811. 07 48. 01 760.48 41.33
694.87 7.45 558.97 47.51 4 66. 13 65.92
1207 .69
1493 .17
2960.75
0. 0
cm -1
EA+BC-9.pk
559.37
810.55
3435.57
1265.93
1000
cm -1
EA+BC-8.pk
927.39
181 1.47
1890.06
1956.03
1074.43
760.18
20
694.82
0.0
4000.0
cm -1
40
810.96
1451.82
30
10
695.21
0.0
400.0
1493.40
40
126 6.47
20
126 5.76
10
694.87
2000
EA+BC-7.pk
2960.91
559.62
%T
1451.51
3033.50
20
10
0.0
2336.46
2868.60
1073.25
3033.88
465.12
2708.50
50
%T
1599.21
3034.34
126 6.03
927.60
1955.94
559.42
810.70
2960.87
466.26
1812.72
1890.82
1073.76
149 3.61
3435.20
559.57
3773.89
70
1028.04
1600.27
%T
8 09.95
759.61
30
1451.65
3034.24
3000
465.61
1956 .00
181 1.93
1073.9 9
1209.60
760.48
30
4000.0
2868.79
50
1601.62
1493.38
558.97
2961 .08
3435.13
927.51
1 890.40
60
465.40
1029.68
50
%T
181 4.22
1073.74
2336.49
1761.76
60
928.47
1956.4 3
1600.19
70
1161.44
1956 .02
466.13
1493 .15
60
%T
EA+BC-11. pk
EA9C82~1.SP 3601 4000.00 400.00 7. 08 99. 91 4.00 %T 5 2. 00
EA9C8E~1. SP 3601 4000.00 400.00 7.68 100.00 4.00 %T 5 2.00

REF 4000 99.10 2000 73.01 600
3773. 89 89. 40 3432.65 57.28 3033.50 43.83 2960. 91 56.07 1955.94 68.06
1890. 82 70. 10 1812.72 71.44 1599.21 61.13 1493. 40 59.52 1451.82 42.89
1265. 93 31. 38 1073.25 59.33 927.60 71.78 810.96 56.08 760.18 47.55
695.01 7.68 559.62 58. 26 466.26 75.75
REF 4000 98.47 2000 59.62 600

3906.50 94.80 3772.29 83.63 3435. 57 39.14 3034. 41 25. 24 2960. 75 35. 21
2868.60 51.22 2708.50 60.11 2336. 46 56.86 1956. 03 48. 63 1890. 06 51. 79
1811.47 53.04 1600.22 42.75 1493. 17 41.14 1451. 17 26. 63 1266. 87 19. 47
1207.69 41.07 1074.43 41.36 1027. 31 49.25 927.39 55.87 810. 55 38. 57
759.02 31.1 1 694.99 7.08 5 59. 37 42.03 465.12 60.85
Table - 7.20
Observations of FTIR spectrums for Ethyl Acetate + Benzyl Chloride mixture:
0.9(EA)
0.8(EA)
0.7(EA)
0.6(EA)
0.5(EA)
0.4(EA)
*0.3(EA)
0.2(EA)
0.1(EA)
Cm-1
0.1(BC)
Cm-1
0.2(BC)
Cm-1
0.3(BC)
Cm-1
0.4(BC)
Cm-1
0.5(BC)
Cm-1
0.6(BC)
Cm-1
0.7(BC)
Cm-1
0.8(BC)
Cm-1
0.9(BC)
Cm-1
Cm-1
3957.87
3776.13
3443.70
2990.70
2375.94
3964.11
3776.47
3437.83
2928.87
2115.59
1817.37
1723.04
1610.33
1379.47
1242.98
1118.19
697.37
620.03
559.44
3918.91
3775.26
3451.07
3067.61
3034.19
2965.86
2340.59
2084.37
1957.48
1889.30
3921.12
3774.33
3436.06
3033.29
1956.79
1891.42
1761.67
1599.84
1450.39
1377.21
1249.46
1061.68
928.36
810.08
759.95
695.28
559.59
466.15
3775.53
3433.62
3033.16
2961.40
1955.96
1889.21
1764.05
1598.56
1493.24
1451.21
1381.19
1264.45
1071.85
927.66
810.37
761.09
694.94
559.24
465.43
3916.71
3776.62
3435.76
3033.47
2961.25
1956.21
1889.50
1811.99
1765.78
1598.42
1492.95
1451.06
1265.27
1072.82
1031.02
927.48
810.22
760.92
695.62
559.42
465.89
3774.70
3435.13
3034.24
2961.08
1956.43
1891.62
1814.22
1600.19
1493.15
1451.65
1266.03
1073.74
928.47
811.07
760.48
694.87
558.97
466.13
3908.14
3773.20
3446.99
3034.34
2961.58
2869.48
2709.24
2524.74
2338.23
1956.02
1889.76
1810.23
1761.76
1601.62
1493.38
1451.38
1265.76
1209.60
1161.44
1073.99
1029.68
927.24
809.95
758.79
695.21
559.57
465.40
3773.85
3435.20
3033.88
2960.87
2868.79
2336.49
1956.00
1890.40
1811.93
1600.27
1493.61
1451.51
1266.47
1208.69
1073.76
1028.04
927.51
810.70
759.61
694.82
559.42
465.61
3773.89
3432.65
3033.50
2960.91
1955.94
1890.82
1812.72
1599.21
1493.40
1451.82
1265.93
1073.25
927.60
810.96
760.18
695.01
559.62
466.26
3906.50
3772.29
3435.57
3034.41
2960.75
2868.60
2708.50
2336.46
1956.03
1890.06
1811.47
1600.22
1493.17
1451.17
1266.87
1207.69
1074.43
1027.31
927.39
810.55
759.02
694.99
559.37
465.12
1 (EA)
2106.73
1766.66
1607.16
1389.69
1243.16
1114.03
620.59
1763.12
1625.53
1492.95
1451.41
1381.27
1253.88
1107.37
1067.81
927.99
809.62
760.92
695.67
559.29
467.04
297
1(BC)
Fig-7.20: FTIR spectrums for Ethyl Acetate + 2-Butanone mixture:

ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECTRUM
Date: 3/11/2009
2489.19
2488.21
90
2089.05
1164.40
90
2489.94
3755.77
931.02
80
1409.82
Spec trum Name: Cl-AN-6.sp
1165.69
10 0. 0
90
90
2090.50
2093.87
3778.13
1245.49
2378.86
3768.93
80
80
2376.34
2928.83
1110.28
935.24
2091.95
932.09
2375.18
80
FTIR SPECTRUM
Date: 3/11/2009

10 0. 0
2089.01
2365.16
2369.39
80
FTIR SPECTRUM
Date: 3/11/2009

10 0. 0
928.00
ACIC
Trichy-2
FTIR SPECTRUM
Date: 3/11/2009

10 0. 0
90
2088.87
2362.08
80
ACIC
Trichy-2
FTIR SPECTRUM
Date: 3/11/2009

10 0. 0
90
ACIC
Trichy-2
FTIR SPECTRUM
Date: 3/11/2009

10 0. 0
1418.32
1739.40
70
1168.70
1244.60
70
70
70
1113.89
70
1049.78
2991.58
70
1021.27
622.08
1378.64
60
60
60
622.77
60
623.89
60
1373.67
60
577.76
1056.34
595.26
2990.28
574.78
50
50
1056.51
%T
50
%T
40
50
2990.51
1376.73
%T
40
50
2990.49
%T
40
%T
40
1056.63
1637.33
50
%T
1375.96
40
1056.35
1637.15
1637.35
40
1637.41
1757.15
1637.90
30
1636.17
30
30
30
30
30
20
20
20
20
20
1242.87
1763.76
20
1762.32
1242.81
1761.48
10
10
10
10
10
1242.82
3449.55
3449.85
0. 0
3 0 00
20 00
1 50 0
1 0 00
4 00 .0
3450.69
0. 0
4 00 0 .0
3 0 00
20 00
c m -1
1 50 0
1 0 00
4 00 .0
3450.23
0. 0
4 00 0 .0
10
1242.79
3450.45
0. 0
4 00 0 .0
3 0 00
20 00
c m -1
1 50 0
1 0 00
4 00 .0
0. 0
4 00 0 .0
3 0 00
20 00
c m -1
1 50 0
1 0 00
4 00 .0
0. 0
3447.05
4 00 0 .0
3 0 00
20 00
c m -1
1 50 0
1 0 00
4 00 .0
4 00 0 .0
c m -1
3 0 00
20 00
1 50 0
1 0 00
Cl-AN-2.pk
Cl-AN-3.pk
Cl-AN-4.pk
Cl-AN-5.pk
Cl-AN-6.pk
Cl-AN-1.sp 3601 4000.00 400. 00 6.33 100.00 4. 00 %T 5 1.00
Cl-AN-2.sp 3601 4000.00 400. 00 6.33 100.00 4. 00 %T 5 1.00
Cl-AN-3.sp 3601 4000.00 400. 00 6.33 100.00 4. 00 %T 5 1.00
Cl-AN-4.sp 3601 4000.00 400. 00 6.34 99.75 4.00 %T 5 1.00
Cl-AN-5.sp 3601 4000.00 400. 00 6.34 99.61 4.00 %T 5 1.00
Cl-AN-6.sp 3601 4000.00 400. 00 6.34 99.58 4.00 %T 5 1.00
REF 4000 99.39 2000 97.58 600

3449. 55 6.33 2991.58 69.36 2489. 19 98.54 2362. 08 89. 00 2088.87 95.42
1763. 76 32. 63 1637.15 43.78 1378.64 67.05 1242. 81 18.73 1056.51 55.12
928.00 97. 75 622.08 69.86
REF 4000 98.71 2000 96.65 600

3449. 85 6.33 2369.39 92.94 2089. 05 94.90 1739. 40 79. 26 1637.90 39.82
1409. 82 86. 69 1244.60 78.23 1110.28 81.86 1049. 78 78.70 574. 78 61.81
REF 4000 98.69 2000 96.73 600

3450. 45 6.33 2990.51 56.61 2488. 21 97.59 2365. 16 92. 03 2089.01 94.12
1762. 32 21. 07 1637.33 43.39 1376.73 53.59 1242. 82 11.07 1164.40 84.67
1056. 35 45. 12 931.02 94.74 623.89 63.96
REF 4000 97.57 2000 95.86 600

3755. 77 94. 19 3450. 69 6.34 2990.49 54.27 2489.94 96.40 2375.18 94.86
2090. 50 93. 31 1761. 48 19. 31 1637. 41 42.15 1375.96 51.98 1242.79 10.20
1165. 69 79. 36 1056. 63 45. 21 932.09 93.90 622. 77 66. 13
REF 4000 95.93 2000 94.61 600

3778. 13 93. 82 3447. 05 6.34 2928.83 84.16 2376.34 93.57 2093.87 93.59
1636. 17 39. 47 1418. 32 81. 88 1245. 49 93.11 1113.89 76.66 1021.27 78.67
577.76 63. 78
REF 4000 95.44 2000 93.34 600

3768. 93 89. 15 3450. 23 6.34 2990.28 63.10 2378.86 93.82 2091.95 91.68
1757. 15 41. 96 1637. 35 45. 43 1373. 67 65.02 1242.87 35.39 1168.70 78.44
1056. 34 65. 29 935.24 93. 23 595. 26 64.81
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECTRUM
Date: 3/11/2009
90
FTIR SPECTRUM
Date: 3/11/2009
FTIR SPECTRUM
Date: 3/11/2009
10 0. 0
90
2370.49
3775.07
ACIC
Trichy-2
FTIR SPECTRUM
Date: 3/11/2009

10 0. 0
10 0. 0
90
10 0. 0
90
90
3921.99
3920.45
3765.76
938.26
2092.69
80
ACIC
Trichy-2
FTIR SPECTRUM
Date: 3/11/2009

10 0. 0
1109.66
80
80
80
80
70
2094.28
2368.72
70
1005.30
70
70
2087.47
70
2104.31
60
594.26
2089.51
60
1247.00
3778.25
3772.35
1164.26
60
1815.01
2380.41
3906.73
2930.86
60
1409.75
60
1011.07
3769.93
2989.86
1373.15
50
1114.23
50
1056.57
%T
2988.64
595.48
1746.98
40
1635.10
1008.88
2375.62
50
1370.94
%T
40
50
1405.90
%T
1242.92
1635.26
30
1757.83
1008.25
30
50
1243.00
%T
1243.50
40
586.32
563.25
40
2988.97
1167.31
1367.68
1628.07
30
1636.11
1117.88
%T
40
670.17
1116.30
30
4 00 .0
c m -1
Cl-AN-1.pk
30
1626.89
1740.66
1242.82
20
10
20
20
20
20
10
10
10
10
3448.38
3448.32
0. 0
4 00 0 .0
3449.47
0. 0
3 0 00
20 00
1 50 0
1 0 00
4 00 .0
4 00 0 .0
c m -1
0. 0
3 0 00
20 00
1 50 0
1 0 00
4 00 .0
0. 0
3449.06
4 00 0 .0
3 0 00
c m -1
20 00
1 50 0
1 0 00
4 00 .0
4 00 0 .0
0. 0
3 0 00
20 00
c m -1
1 50 0
1 0 00
4 00 .0
3445.42
4 00 0 .0
3 0 00
c m -1
20 00
1 50 0
1 0 00
4 00 .0
c m -1
Cl-AN-7.pk
Cl-AN-8.pk
Cl-AN-9.pk
Cl-AN-10. pk
Cl-AN-11. pk
Cl-AN-7.sp 3601 4000.00 400. 00 6.32 99.45 4.00 %T 5 1.00
Cl-AN-8.sp 3601 4000.00 400. 00 6.34 100.00 4. 00 %T 5 1.00
Cl-AN-9.sp 3601 4000.00 400. 00 6.33 100.00 4. 00 %T 5 1.00
Cl-AN-10. sp 3601 4000. 00 400.00 6.33 100.00 4.00 %T 5 1. 00
Cl-AN-11. sp 3601 4000. 00 400.00 6.34 99.17 4. 00 %T 5 1.00
REF 4000 97.51 2000 95.13 600

3775. 07 92. 31 3448. 38 6.32 2989.86 58.27 2370.49 92.46 2092.69 93.04
1757. 83 34. 82 1635. 10 45. 07 1373. 15 58.91 1242.82 26.44 1164.26 68.31
1109. 66 66. 78 1056. 57 56. 70 1005. 30 75.18 938.26 92.74 594. 26 65. 12
REF 4000 80.85 2000 77.99 600

3765. 76 75. 87 3448.32 6. 34 2988. 64 56.76 2368. 72 74. 98 2094.28 76.58
1746. 98 48. 38 1635.26 38.45 1370.94 57.05 1242. 92 49.25 1114.23 57.80
595.48 52. 73
REF 4000 71.37 2000 68.30 600

3906. 73 69. 57 3769.93 61.87 3449.06 6.33 2375. 62 65. 34 2089.51 67.56
1636. 11 34. 39 1405.90 57.02 1243.50 56.03 1116. 30 44.72 1008.25 47.96
670.17 42. 17
REF 4000 84.49 2000 80.62 600

3920. 45 83. 10 3772.35 71.56 3449.47 6.33 2988. 97 43. 60 2380.41 82.93
2104. 31 79. 26 1740.66 29.75 1628.07 38.07 1367. 68 44.01 1243.00 53.09
1167. 31 42. 59 1008.88 58.20 586.32 53.29
REF 4000 88.37 2000 83.26 600

3921. 99 87. 11 3778. 25 73. 94 3445. 42 6.34 2930.86 71.20 2087.47 82.53
1815. 01 86. 05 1626. 89 35. 54 1409. 75 68.12 1247.00 74.30 1117.88 55.35
1011. 07 61. 13 563.25 53. 03
Table - 7.21
Observations of FTIR spectrums for Ethyl Acetate + 2-Butanone mixture:
1 (EA)
Cm-1
3449.55
2991.58
2489.19
2362.08
2088.87
1763.76
1637.15
1378.64
1242.81
1056.51
928.00
622.08
0.9(EA)
+
0.1(2B)
Cm-1
3449.85
2369.39
2089.05
1739.40
1637.90
1409.82
1244.60
1110.28
1049.78
574.78
0.8(EA)
+
0.2(2B)
Cm-1
3450.45
2990.51
2488.21
2365.16
2089.01
1762.32
1637.33
1376.73
1242.82
1164.40
1056.35
931.02
623.89
*0.7(EA)
+
0.3(2B)
Cm-1
3755.77
3450.69
2990.49
2489.94
2375.18
2090.50
1761.48
1637.41
1375.96
1242.79
1165.69
1056.63
932.09
622.77
0.6(EA)
+
0.4(2B)
Cm-1
3778.13
3447.05
2928.83
2376.34
2093.87
1636.17
1418.32
1245.49
1113.89
1021.27
577.76
0.5(EA)
+
0.5(2B)
Cm-1
3768.93
3450.23
2990.28
2378.86
2091.95
1757.15
1637.35
1373.67
1242.87
1168.70
1056.34
935.24
595.26
0.4(EA)
+
0.6(2B)
Cm-1
3775.07
3448.38
2989.86
2370.49
2092.69
1757.83
1635.10
1373.15
1242.82
1164.26
1109.66
1056.57
1005.30
938.26
594.26
298
0.3(EA)
+
0.7(2B)
Cm-1
3765.76
3448.32
2988.64
2368.72
2094.28
1746.98
1635.26
1370.94
1242.92
1114.23
595.48
0.2(EA)
+
0.8(2B)
Cm-1
3906.73
3769.93
3449.06
2375.62
2089.51
1636.11
1405.90
1243.50
1116.30
1008.25
670.17
0.1(EA)
+
0.9(2B)
Cm-1
3920.45
3772.35
3449.47
2988.97
2380.41
2104.31
1740.66
1628.07
1367.68
1243.00
1167.31
1008.88
586.32
1(2B)
Cm-1
3921.99
3778.25
3445.42
2930.86
2087.47
1815.01
1626.89
1409.75
1247.00
1117.88
1011.07
563.25
For Ternary mixtures:

Fig-7.21: FTIR spectrums for Cyclohexanone + Hexane + Heptane mixture:
ACI C
Trichy- 2
ACI C
Trichy- 2
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/22/2008
413.75
2 176.94
3 948.52
415.92
1019 .51
90
1 342.88
1970 .70 180 5.14
865 .83
267 1.60
236 1.71
80
65 2.99
1342 .76
8 64.5 2
1056 .75905.36
65 3.03
10 54.19
267 2.73
90
65 3.46
90
267 3.01
9 04.9 9
60
1 312 .31
60
%T
50
341 2.01
%T
11 19.24
131 4.03
122 3.01
40
50
34 50.5 9
11 20.90
1 312 .96
122 2.31
492 .92
60
6 53.8 1
%T
50
122 3.74
40
3442 .33
%T
50
%T
11 19.43
14 52.3 4
40
2865 .82
60
293 9.48
23 67.3 6
267 0.73
65 2.59
41 3.69
1969 .33
21 77.1 8
65 2.49
80
7 50.1 7
18 05.0 0
4 90.57
865.9 5
105 5.68
70
50
605.2 9
%T
50
%T
6 71.08
50
11 19.03
3 504.58
341 0.73
122 2.36
341 4.02
491 .15
60
%T
50
11 19.22
1 314.10
2868 .13
40
1391 .42
40
40
40
122 3.00
13 92.30
144 4.68
2865 .13
1395 .51
30
30
30
20
20
20
30
1640 .67
30
30
30
20
20
1 641.05
235 8.57
20
164 0.01
20
286 6.70
2 940 .26
10
2 940 .88
171 1.12
10
2 941 .82
10
10
171 2.69
2 940 .30
10
2 940 .39
10
10
10
171 2.17
171 2.63
3000
2000
171 1.15
1500
1000
0.0
4000.0
400.0
3000
2000
c m-1
1500
1000
0.0
4000.0
400.0
3000
2000
1500
c m-1
1000
0.0
4000.0
400.0
344 1.89
2 940 .43
2 939 .73
3000
2000
c m-1
1500
1000
0.0
4000.0
400.0
3442 .72
3000
2000
1500
c m-1
1000
0.0
4000.0
400.0
171 2.58
3442 .93
3000
2000
1500
c m-1
1000
0.0
4000.0
400.0
3000
2000
171 2.76
1500
c m-1
1000
0.0
4000.0
400.0
3000
2000
c m-1
1500
400.0
Sample-5.pk
Sample-6.pk
Sample-7.pk
Sample-8.pk
Sample-9.pk
Sampe- 10.pk
Sampe- 11.pk
Sample-4.sp 3601 4000.00 400.00 8.43 99.99 4.00 %T 3 1.00
Sample-5.sp 3601 4000.00 400.00 7.51 99.99 4.00 %T 3 1.00
Sample-6.sp 3601 4000.00 400.00 8.16 100.00 4.00 %T 3 1.00
Sample-7.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 1.00
Sample-8.sp 3601 4000.00 400.00 6.33 100.00 4.00 %T 3 1.00
Sample-9.sp 3601 4000.00 400.00 6.32 99.99 4.00 %T 3 0.75
Sampe- 10.sp 3601 4000.00 400.00 9.14 100.00 4.00 %T 3 1.00
Sampe- 11.sp 3601 4000.00 400.00 8.37 100.00 4.00 %T 3 1.00
REF 4000 97.81 2000 97.05 600

3948.52 96.28 3412.01 53.26 2940.39 10.75 2866.33 25.76 2670.59 90.98
2358.73 89.51 2176.94 95.31 2064.94 95.22 1970.70 96.02 1805.14 87.08
1712.63 8.42 1444.01 44.13 1314.03 50.51 1223.01 48.26 1119.24 54.46
1055.45 76.87 1018.64 82.56 904.24 73.85 865.83 83.54 750.64 73.63
652.99 85.58 491.29 65.88 413.75 88.37
REF 4000 89.33 2000 89.05 600

3450.59 50.34 2940.26 18.84 2865.14 40.07 2671.90 83.52 2361.71 84.49
1711.12 7.51 1448.81 57.57 1424.79 58.06 1342.88 65.22 1312.32 59.70
1223.71 51.56 1120.51 62.07 1055.88 78.51 1019.51 83.30 905.11 78.16
864.80 81.87 750.96 77.67 653.03 81.80 492.28 73.35 415.92 88.32
REF 4000 98.34 2000 97.70 600

3442.33 45.68 2940.88 20.63 2865.82 45.24 2671.60 91.76 2361.63 88.89
2065.75 96.95 1711.15 8.16 1447.85 62.93 1423.73 62.87 1342.76 71.44
1312.31 65.86 1223.74 56.24 1120.90 68.06 1056.75 85.28 905.36 86.07
864.52 89.04 750.64 83.29 653.46 85.64 492.38 78.87 413.67 91.62
REF 4000 98.57 2000 96.09 600

3441.89 6.31 2939.73 9.03 2869.57 29.76 2672.73 96.06 2365.72 75.70
2066.40 93.81 1712.17 11.88 1640.67 34.38 1452.34 52.22 1391.42 45.20
1343.39 69.50 1312.96 64.65 1222.31 62.45 1119.43 54.53 1054.19 81.73
1019.48 83.58 904.99 84.68 863.28 85.64 749.44 64.07 653.81 64.34
491.58 68.63 415.62 90.49
REF 4000 98.44 2000 95.39 600

3442.72 6.33 2941.82 18.80 2868.13 47.92 2673.01 97.10 2364.26 90.05
2090.47 93.00 1712.69 20.22 1641.05 32.36 1451.04 59.40 1392.30 43.59
1343.77 73.70 1313.47 71.61 1221.45 69.57 1119.64 58.89 1020.47 83.48
903.21 88.46 748.07 62.12 653.88 59.49 605.29 60.18 492.92 67.40
REF 4000 98.59 2000 90.95 600

3863.90 83.44 3747.72 73.42 3442.93 6.32 2939.48 65.43 2868.94 83.44
2523.97 97.04 2358.57 30.87 2032.01 90.24 1640.01 28.38 1395.51 41.16
1117.96 63.95 1031.16 80.53 671.08 54.50 434.46 85.53
REF 4000 98.76 2000 98.22 600

3414.02 55.34 2940.30 18.24 2865.13 41.11 2671.13 95.49 2372.20 96.52
2064.24 97.11 1804.81 92.90 1712.58 9.13 1448.16 60.75 1340.50 72.24
1312.45 64.60 1222.36 61.11 1119.03 65.78 1054.35 85.44 1018.20 89.60
905.32 84.05 864.51 89.53 750.17 81.53 652.59 89.35 490.57 77.45
411.88 94.22
REF 4000 97.87 2000 97.50 600

3948.18 96.47 3504.58 61.49 3410.73 59.93 2940.43 10.32 2866.70 24.62
2670.73 89.76 2367.36 95.65 2177.18 95.74 2064.69 95.68 1969.33 96.15
1805.00 86.01 1712.76 8.37 1444.68 42.73 1314.10 49.22 1223.00 47.13
1119.22 53.82 1055.68 75.35 1018.52 82.15 904.12 72.30 865.95 82.42
750.67 73.30 652.49 87.11 491.15 65.74 413.69 88.21
ACI C
Trichy- 2
ACI C
Trichy- 2
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/23/2008
90
206 5.52
2 670.3 8
865.6 4
90
19 67.86
394 8.09
65 2.53
10 18.6 9
23 72.1 9 2 063 .26
39 49.58
26 72.12
490 .97
60
11 19.19
90
134 0.74
180 5.50
90 3.80
60
491 .16
26 71.5 8
237 0.23
206 4.97
864.5 1
50
341 2.46
%T
1119 .25
7 50.1 0
7 50.1 9
491 .05
%T
1395 .95
60
1 119.2 2
122 2.54
1640 .21
50
50
20
20
10
20
2 940 .32
2 864 .65
2 939 .12
171 2.75
3000
2000
1500
1000
20
20
10
10
3000
2000
1500
1000
0.0
4000.0
400.0
3000
2000
c m-1
1 312 .93
11 19.27
1000
0.0
4000.0
400.0
3446 .62
2 942 .83
1 713.4 3
2000
1500
1000
0.0
4000.0
400.0
20
20
10
10
20
29 40.96
171 2.81
2000
1500
1000
0.0
4000.0
400.0
3000
2 867.0 3
10
2 940 .75
3000
2000
c m-1
Sampe- 15.pk
1500
1000
0.0
4000.0
400.0
171 2.82
3000
2000
c m-1
Sampe- 16.pk
1 637.6 2
30
2865 .85
171 2.77
3000
c m-1
Sampe- 14.pk
60 6.71
50
40
30
34 48.4 4
3446 .36
1500
c m-1
Sampe- 13.pk
655 .37
13 93.69
%T
164 0.37
40
30
2 940 .72
17 12.02
171 3.21
294 1.43
0.0
4000.0
400.0
c m-1
Sampe- 12.pk
2866 .55
60
50
122 2.64
30
3 419.7 5
0.0
4000.0
65 2.80
7 50.2 4
491 .14
%T
1 449.22
163 8.31
30
10
286 8.71
11 19.83
1 448.87
40
294 4.18
142 6.32
30
286 6.24
10
10 54.66
60
131 2.81 1119 .23
122 2.55
16 40.6 5
%T
1 448.99
40
1729 .51
122 2.64
122 1.54
70
491 .06
60
50
40
145 0.02
209 2.08
233 8.38
80
864 .70
6 07.17
%T
11 19.21
131 2.57
40
122 2.95
144 5.60
30
2368 .87
134 0.61
18 05.7 1
70
905.36
655.54
60
490 .97
50
131 5.50
40
286 6.06
FTIR S PECTRUM
Date: 2/25/2008
131 3.92
90
18 72.0 2
23 67.4 8
217 5.74
80
65 2.84
11 19.83
2 869.3 7
750 .88
340 9.40
13 12.77
%T
144 4.79
40
267 1.50
8 64.5 9
1054 .60
905.39
70
41 2.60
1 018.2 7
90
134 0.61
80
65 3.11
100.0
2064 .36
41 2.47
1805 .42
23 71.71
10 18.3 5
1054 .59
905.53
70
122 2.75
50
30
206 4.97
26 71.7 6
80
122 0.65
70
16 40.0 5
1 313.65
341 3.01
90
209 1.08
2374 .64
80
10 18.1 6 865.3 7
105 4.78
904.74 7 50.4 4
60
90
4 14.9 3
65 2.44
18 06.01
70
105 5.31
Spectrum Na me: Sampe-19.sp
100.0
101 8.35
13 42.36
19 73.10
80
65 2.48
866.04
70
100.0
41 2.58
2 176.2 2
21 77.2 6
80
1055 .53
7 50.5 1
904.49
70
FTIR S PECTRUM
Date: 2/25/2008
100.0
233 9.07
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/25/2008
100.0
993.17
187 1.50
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/25/2008
100.0
101 8.34
23 73.36
90
2374 .29 206 4.95

267 0.70
80
4 14.46
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/25/2008
100.0
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/23/2008

413.5 9
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/23/2008
1500
1000
0.0
4000.0
400.0
34 46.2 4
3000
2000
c m-1
Sampe- 17.pk
1500
1000
400.0
c m-1
Sampe- 18.pk
Sampe- 19.pk
Sampe- 12.sp 3601 4000.00 400.00 9.52 100.00 4.00 %T 3 1.00
Sampe- 13.sp 3601 4000.00 400.00 6.69 100.00 4.00 %T 3 1.00
Sampe- 14.sp 3601 4000.00 400.00 7.36 122.21 4.00 %T 3 1.00
Sampe- 15.sp 3601 4000.00 400.00 6.32 98.54 4.00 %T 3 1.00
Sampe- 16.sp 3601 4000.00 400.00 8.23 99.99 4.00 %T 3 1.00
Sampe- 17.sp 3601 4000.00 400.00 8.36 99.99 4.00 %T 3 1.00
Sampe- 18.sp 3601 4000.00 400.00 7.09 99.99 4.00 %T 3 1.00
Sampe- 19.sp 3601 4000.00 400.00 6.31 100.00 4.00 %T 3 1.00
REF 4000 98.57 2000 98.17 600

3413.01 60.31 2940.32 13.51 2866.06 34.75 2670.70 94.38 2374.29 97.23
2064.95 97.04 1712.75 9.51 1444.79 54.55 1313.65 60.42 1222.75 57.80
1119.19 63.29 1055.53 83.40 1018.69 88.13 904.49 81.31 865.64 88.62
750.51 80.45 652.53 89.76 490.97 74.44 413.59 92.15
REF 4000 97.77 2000 97.28 600

3948.09 96.54 3412.46 53.01 2941.43 6.69 2868.71 18.07 2670.38 89.88
2373.36 96.19 2177.26 95.57 2065.52 95.54 1967.86 96.11 1713.21 9.16
1445.60 37.56 1315.50 47.19 1222.95 45.81 1119.25 52.62 1055.31 75.42
1018.34 81.83 904.74 72.45 866.04 82.66 750.44 72.47 652.48 86.55
491.16 64.59 414.46 89.22
REF 4000 99.77 2000 99.52 600

3949.58 98.65 3409.40 64.26 2939.12 11.66 2864.65 25.52 2672.12 92.47
2372.19 98.36 2176.22 97.75 2063.26 97.62 1973.10 98.24 1871.50 97.62
1806.01 88.79 1712.02 7.36 1640.05 73.02 1450.02 45.33 1426.32 47.61
1342.36 56.84 1312.57 47.97 1222.64 44.62 1119.21 50.78 1054.78 77.58
1018.16 83.48 993.17 91.83 903.80 72.93 865.37 83.49 750.88 73.12
652.44 88.31 490.97 65.00 414.93 95.54
REF 4000 96.58 2000 93.48 600

3446.36 6.32 2944.18 43.11 2869.37 70.48 2374.64 89.18 2339.07 96.15
2091.08 91.47 1729.51 46.84 1638.31 38.77 1395.95 53.30 1220.65 83.91
1119.83 72.02 655.54 68.70 607.17 68.84
REF 4000 98.14 2000 96.53 600

3446.62 25.03 2940.72 11.02 2866.24 30.81 2671.76 94.24 2370.23 93.79
2064.97 94.76 1805.50 91.51 1712.77 8.23 1640.21 56.95 1448.99 53.16
1340.74 67.49 1312.77 59.26 1222.54 56.10 1119.22 59.55 1054.59 83.12
1018.35 87.30 905.53 80.81 864.51 86.78 750.10 73.72 653.11 80.94
491.05 70.52 412.58 91.48
REF 4000 98.05 2000 96.57 600

3448.44 30.41 2940.75 11.92 2865.85 30.47 2671.58 93.57 2371.71 94.61
2064.97 94.70 1805.42 90.22 1712.81 8.36 1640.65 58.52 1448.87 51.86
1340.61 65.88 1312.81 58.10 1222.55 55.22 1119.23 58.70 1054.60 81.98
1018.35 86.35 905.39 79.69 864.59 86.16 750.19 73.89 652.84 82.13
491.06 70.37 412.47 91.06
REF 4000 97.14 2000 95.36 600

3419.75 19.72 2940.96 7.09 2867.03 19.94 2671.50 91.03 2367.48 92.87
2175.74 93.52 2064.36 92.94 1872.02 95.53 1805.71 86.63 1712.82 7.60
1640.37 49.06 1449.22 40.00 1340.61 55.36 1312.93 47.27 1222.64 44.46
1119.27 48.31 1054.66 75.30 1018.27 81.08 905.36 71.88 864.70 80.70
750.24 64.94 652.80 75.90 491.14 60.74 412.60 86.69
REF 4000 99.44 2000 95.37 600

3446.24 6.31 2942.83 46.68 2866.55 72.01 2368.87 92.69 2338.38 94.69
2092.08 93.00 1713.43 41.53 1637.62 39.94 1393.69 62.24 1313.92 87.78
1221.54 86.97 1119.83 78.32 655.37 66.55 606.71 67.27
ACI C
Trichy- 2
ACI C
Trichy- 2
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/26/2008
267 1.62
217 6.602
064.1 3
267 1.24
236 6.84
1018 .18
864.8 4
865 .59
80
65 2.96
267 2.32
206 5.06
90
134 1.00
6 53.2 1
1018 .43
236 4.43
80
1 055.3 3 904.65
267 0.86
8 64.45
90
4 90.25
70
70
80
20 96.3 8
80
1 458.9 6
28 72.16
70
80
121 9.78
1 026.1 8
23 71.9 1
11 20.39
252 2.83
3821 .18
2098 .52
865.50
10 18.48
65 2.96
1 055.5 4
904.44
7 50.1 0
80
7 49.7 4
4 90.70
70
7 50.2 7
100.0
90
1 204.4 4
2098 .33
236 1.85
653.48
1 054.4 5 905.50
7 50.2 2
905.33
Spectrum Na me: Sample-27.sp
100.0
90
26 77.47
90
206 5.34
1 054.5 5
70
FTIR S PECTRUM
Date: 3/7/2008
100.0
413 .74
90
206 5.56
2 365.1 0
180 5.04
80
FTIR S PECTRUM
Date: 3/7/2008
Spectrum Na me: Sample - 25.sp
100.0
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/26/2008
100.0
4 12.55
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/26/2008
100.0
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/26/2008

41 4.08
1 018.9 4
90
1 340 .50
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/26/2008

100.0
412 .37
90
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/26/2008

100.0
20 95.7 6
80
2872 .26
23 71.0 3
236 3.45
70
70
656 .97
70
490 .97
4 90.61
60
60
131 3.60
11 19.14
50
1 312 .82
11 19.14
%T
50
164 1.75
122 0.73
11 20.41
1 312 .69
60
11 19.03
122 2.22
60
659 .33
60
%T
50
%T
60
659 .07
60
%T
745 .19
37 41.4 3
603.8 2
29 45.05
13 94.13
122 2.69
50
1 458.3 3
236 3.45
1 313.77
1 450.06
3 415.7 9
11 20.49
60
1119 .23
122 2.53
144 6.46
%T
1000
c m-1
Sample-4.pk
100.0
%T
1 312 .45
1 448.16
11 19.64
286 9.57
0.0
4000.0
60
11 17.96
7 48.0 7
1 451 .04
122 3.71
40
2 866.3 3
8 64.5 1
905.32
904.12 7 50.6 7
286 5.14
20
10 18.2 0
10 54.35
70
374 7.72
122 1.45
7 49.4 4
60
1018 .52
180 4.81
237 2.20
80
43 4.46
1 031.1 6
70
65 3.88
1313 .47
142 3.73
144 4.01
30
2 064 .69
90 394 8.18
206 4.24
267 1.13
286 8.94
70
236 5.72
144 7.85
11 20.51
14 24.7 9
1 448.81
1 312 .32
3863 .90
80
102 0.47
1 019.4 8
70
491 .58
491 .29
100.0
41 1.88
90
2032 .01
903.21
1343 .77
80
86 3.28
492 .38
70
492 .28
60
FTIR S PECTRUM
Date: 2/23/2008
100.0
2 523.9 7
209 0.47
236 4.26
415 .62
13 43.3 9
80
7 50.6 4
1 055.8 8 905.11 7 50.9 6
70
904.24 7 50.6 4
236 1.63
80
864 .80
267 1.90
1 055.4 5
70
100.0
1 340 .50
90
206 5.75
206 6.40
267 0.59
235 8.73
80
FTIR S PECTRUM
Date: 2/23/2008
100.0
41 3.67
90
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 3/7/2008
100.0
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 3/7/2008
100.0
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 3/7/2008
100.0
101 8.64
90
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/22/2008

206 4.94
ACI C
Trichy- 2
FTIR S PECTRUM
Date: 2/22/2008

100.0
606 .22
50
%T
2 957.50
50
2869 .35
%T
50
%T
11 20.06
50
145 6.34
122 2.47
40
1 448.98
40
341 3.73
40
40
40
1 450.30
40
40
13 93.87
40
1716 .72
13 93.90
3 417.6 5
30
2866 .57
30
2 867.4 8
3440 .92
30
30
164 0.38
30
30
30
13 93.11
30
163 9.62
295 3.79
2 866.6 4
20
20
20
20
20
287 7.21
164 0.64
20
20
163 8.29
20
286 8.82
10
10
10
173 3.70
10
10
10
10
10
2 941 .10
171 3.15
2 941 .40
0.0
4000.0
3000
2 941 .24
171 2.84
2000
29 42.07
171 2.94
1500
1000
400.0
0.0
4000.0
3000
c m-1
2000
1500
1000
400.0
0.0
4000.0
c m-1
3000
2000
1500
1000
400.0
0.0
4000.0
3000
c m-1
3445 .53
1 713 .40
2000
1500
1000
400.0
0.0
4000.0
c m-1
3444 .92
3444 .36
3000
2000
1500
1000
400.0
0.0
4000.0
c m-1
3000
2000
1500
1000
400.0
0.0
4000.0
3441 .76
c m-1
3000
2000
1500
1000
400.0
0.0
4000.0
c m-1
294 8.94
3000
2000
1500
1000
c m-1
Sample - 20.pk
Sample - 21.pk
Sample - 22.pk
Sample - 23.pk
Sample - 24.pk
Sample - 25.pk
Sample-26.pk
Sample-27.pk
SAMP LE~1.SP 3601 4000.00 400.00 8.14 100.00 4.00 %T 3 1.00
SAMP LE~2.SP 3601 4000.00 400.00 10.45 100.00 4.00 %T 3 1.00
SAMP LE~3.SP 3601 4000.00 400.00 8.75 99.99 4.00 %T 3 1.00
SAMP LE~4.SP 3601 4000.00 400.00 6.54 99.99 4.00 %T 3 1.00
SA811D~1.SP 3601 4000.00 400.00 6.32 99.19 4.00 %T 3 1.00
SA891D~1.SP 3601 4000.00 400.00 6.33 97.92 4.00 %T 3 1.00
SA2D8C~1.SP 3601 4000.00 400.00 6.35 100.00 4.00 %T 3 0.75
SA259C~1.SP 3601 4000.00 400.00 6.34 97.60 4.00 %T 3 0.75
REF 4000 98.31 2000 97.63 600

3413.73 45.12 2941.40 9.61 2866.64 26.54 2671.62 92.71 2366.84 91.32
2176.60 96.16 2064.13 95.95 1805.04 89.03 1712.84 8.14 1448.98 47.80
1340.50 62.59 1312.82 54.79 1222.47 51.64 1119.14 55.97 1054.55 79.09
1018.18 83.77 905.33 77.80 864.84 85.98 750.27 75.45 652.96 85.92
490.61 70.35 412.37 91.63
REF 4000 98.37 2000 97.82 600

3415.79 56.60 2941.10 15.37 2866.57 38.37 2671.24 94.81 2365.10 90.64
2065.56 96.84 1713.15 10.45 1446.46 57.79 1313.60 64.76 1222.53 61.98
1119.14 65.87 1055.33 84.60 1018.94 88.03 904.65 84.59 865.59 90.60
750.22 83.08 653.21 89.81 490.70 78.81 414.08 93.47
REF 4000 98.88 2000 97.75 600

3440.92 37.68 2941.24 12.54 2867.48 37.03 2672.32 96.11 2364.43 87.69
2065.06 96.52 1712.94 8.75 1641.75 65.66 1450.06 59.71 1341.00 74.64
1312.69 67.93 1222.22 64.77 1119.03 66.45 1054.45 86.20 1018.43 88.88
905.50 86.73 864.45 91.49 749.74 81.51 653.48 86.39 490.25 78.54
412.55 94.72
REF 4000 98.57 2000 97.54 600

3417.65 41.11 2942.07 6.54 2868.82 21.84 2670.86 93.30 2361.85 91.55
2065.34 95.79 1713.40 9.59 1450.30 46.71 1313.77 58.65 1222.69 56.52
1119.23 61.18 1055.54 81.95 1018.48 86.45 904.44 79.76 865.50 87.34
750.10 76.50 652.96 85.87 490.97 72.99 413.74 92.27
REF 4000 99.08 2000 95.08 600

3445.53 6.32 2957.50 54.14 2872.16 76.64 2363.45 78.10 2098.33 92.54
1640.38 38.12 1458.96 81.51 1394.13 60.12 1204.44 95.36 1120.39 83.84
659.33 66.76
REF 4000 97.77 2000 89.50 600

3444.36 6.33 2953.79 30.89 2869.35 57.50 2363.45 60.82 2096.38 87.52
1716.72 41.97 1640.64 30.08 1458.33 62.18 1393.87 44.66 1219.78 85.18
1120.41 70.91 659.07 63.85
REF 4000 99.42 2000 93.97 600

3441.76 6.35 2945.05 61.75 2872.26 83.30 2371.91 84.56 2098.52 91.84
1639.62 31.53 1393.90 44.28 1120.49 70.26 1026.18 86.89 606.22 59.70
REF 4000 97.44 2000 94.76 600

3821.18 80.17 3741.43 68.94 3444.92 6.34 2948.94 7.74 2877.21 33.66
2677.47 96.56 2522.83 96.67 2371.03 81.33 2095.76 92.35 1733.70 21.41
1638.29 26.84 1456.34 50.65 1393.11 37.05 1220.73 72.88 1120.06 55.45
745.19 70.36 656.97 66.47 603.82 65.82
Table - 7.22
Observations of FTIR spectrums for
Cyclohexanone + Hexane + Heptane mixture
S1
(Cm-1)
3948.52
3412.01
2940.39
2866.33
2670.59
2358.73
2176.94
2064.94
1970.70
1805.14
1712.63
1444.01
1314.03
1223.01
1119.24
1055.45
1018.64
904.24
865.83
750.64
652.99
491.29
413.75
S2
(Cm-1)
3450.59
2940.26
2865.14
2671.90
2361.71
1711.12
1448.81
1424.79
1342.88
1312.32
1223.71
1120.51
1055.88
1019.51
905.11
864.80
750.96
653.03
492.28
415.92
S3
(Cm-1)
3442.33
2940.88
2865.82
2671.60
2361.63
2065.75
1711.15
1447.85
1423.73
1342.76
1312.31
1223.74
1120.90
1056.75
905.36
864.52
750.64
653.46
492.38
413.67
S4
(Cm-1)
S5
(Cm-1)
3442.72
2941.82
2868.13
2673.01
2364.26
2090.47
1712.69
1641.05
1451.04
1392.30
1343.77
1313.47
1221.45
1119.64
1020.47
903.21
748.07
653.88
605.29
492.92
3441.89
2939.73
2869.57
2672.73
2365.72
2066.40
1712.17
1640.67
1452.34
1391.42
1343.39
1312.96
1222.31
1119.43
1054.19
1019.48
904.99
863.28
749.44
653.81
491.58
415.62

299
S6
(Cm-1)
S7
(Cm-1)
*S8
(Cm-1)
3863.90
3747.72
3442.93
2939.48
2868.94
2523.97
2358.57
2032.01
1640.01
1395.51
1117.96
1031.16
671.08
434.46
3414.02
2940.30
2865.13
2671.13
2372.20
3948.18
3504.58
3410.73
2940.43
2866.70
2670.73
2367.36
2177.18
2064.69
1969.33
1805.00
1712.76
1444.68
1314.10
1223.00
1119.22
1055.68
2064.24
1804.81
1712.58
1448.16
1340.50
1312.45
1222.36
1119.03
1054.35
1018.20
905.32
864.51
750.17
652.59
490.57
411.88
1018.52
904.12
865.95
750.67
652.49
491.15
413.69
400.0
S9
(Cm-1)
3413.01
2940.32
2866.06
2670.70
2374.29
2064.95
1712.75
1444.79
1313.65
1222.75
1119.19
1055.53
1018.69
904.49
865.64
750.51
652.53
490.97
413.59
S17
(Cm-1)
3413.73
2941.40
2866.64
2671.62
2366.84
2176.60
2064.13
1805.04
1712.84
1448.98
1340.50
1312.82
1222.47
1119.14
1054.55
1018.18
905.33
864.84
750.27
652.96
490.61
412.37
S10
(Cm-1)
3948.09
3412.46
2941.43
2868.71
2670.38
2373.36
2177.26
2065.52
1967.86
1713.21
1445.60
1315.50
1222.95
1119.25
1055.31
1018.34
904.74
866.04
750.44
652.48
491.16
414.46
S18
(Cm-1)
3415.79
2941.10
2866.57
2671.24
2365.10
2065.56
1713.15
1446.46
1313.60
1222.53
1119.14
1055.33
1018.94
904.65
865.59
750.22
653.21
490.70
414.08
*S11
(Cm-1)
3949.58
2939.12
2864.65
2672.12
2372.19
2176.22
2063.26
1973.10
1871.50
1806.01
1712.02
1640.05
1450.02
1426.32
1342.36
1312.57
1119.21
1054.78
1018.16
993.17
903.80
865.37
750.88
652.44
490.97
414.93
S19
(Cm-1)
3440.92
2941.24
2867.48
2672.32
2364.43
2065.06
1712.94
1641.75
1450.06
1341.00
1312.69
1222.22
1119.03
1054.45
1018.43
905.50
864.45
749.74
653.48
490.25
412.55
S12
(Cm-1)
S13
(Cm-1)
3446.36
2944.18
2869.37
2374.64
2339.07
2091.08
1729.51
1638.31
1395.95
1220.65
1119.83
655.54
607.17
3446.62
2940.72
2866.24
2671.76
2370.23
2064.97
1805.50
1712.77
1640.21
1448.99
1340.74
1312.77
1222.54
1119.22
1054.59
1018.35
905.53
864.51
750.10
653.11
491.05
412.58
S20
(Cm-1)
3417.65
2942.07
2868.82
2670.86
2361.85
2065.34
1713.40
1450.30
1313.77
1222.69
1119.23
1055.54
1018.48
904.44
865.50
750.10
652.96
490.97
413.74
3448.44
2940.75
2865.85
2671.58
2371.71
2064.97
1805.42
1712.81
1640.65
1448.87
1340.61
1312.81
1222.55
1119.23
1054.60
1018.35
905.39
864.59
750.19
652.84
491.06
412.47
S15
(Cm-1)
3419.75
2940.96
2867.03
2671.50
2367.48
2175.74
2064.36
1872.02
1805.71
1712.82
1640.37
1449.22
1340.61
1312.93
1222.64
1119.27
1054.66
1018.27
905.36
864.70
750.24
652.80
491.14
412.60
S21
(Cm-1)
S22
(Cm-1)
S23
(Cm-1)
3445.53
2957.50
2872.16
2363.45
2098.33
1640.38
1458.96
1394.13
1204.44
1120.39
659.33
3444.36
2953.79
2869.35
2363.45
2096.38
1716.72
1640.64
1458.33
1393.87
1219.78
1120.41
659.07
3441.76
2945.05
2872.26
2371.91
2098.52
1639.62
1393.90
1120.49
1026.18
606.22

300
S14
(Cm-1)
S16
(Cm-1)
3446.24
2942.83
2866.55
2368.87
2338.38
2092.08
1713.43
1637.62
1393.69
1313.92
1221.54
1119.83
655.37
606.71
S24
(Cm-1)
3821.18
3741.43
3444.92
2948.94
2877.21
2677.47
2522.83
2371.03
2095.76
1733.70
1638.29
1456.34
1393.11
1220.73
1120.06
745.19
656.97
603.82
Fig-7.22: FTIR Spectrums for Cyclohexanone+Hexane+Benzaldehyde mixture:

ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08- 2-2010
4 12.11
1018.31
90
2673.85
3938.94
100.0
FT IR SPECT RUM
Date: 15- 2-2010
Spectrum Name: SJC-PH-R-4.s p
100.0
100.0
100.0
90
90
80
80
Spectrum Name: SJC-Ph- Ram-6. sp

100.0
45 2.53
233 3.47
90
2177.10
394 1.40
90
1980.80
3780.00
3942.53
1020.84
2332.62
3879.66
1911.94
904.98
20 62.83
65 1.39
80
80
3778.63
80
1017.83
2719.87
1 981.01
905.90
492.81
1055.22
1065.69
863 .92
905.31
70
FT IR SPECT RUM
Date: 15- 2-2010
412.8 5
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08- 2-2010
864.4 1
2062.95
80
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08- 2-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08- 2-2010
70
753.33
70
905.35
70
418.93
39 44.01
2737.45
70
6 50.00
1173.10
1919.88
4 93.86
60
1022.50
771.73
60
1067.51
650.1 7
1168.60
60
1450.30
751.20
50
111 9.02
3411.73
50
716.0 0
1314.39
%T
50
%T
40
1448.45
1 117.51
3068.38
20
294 2.05
1000
400.0
4000.0
1449.82
1351.29
2867.10
3000
2000
20
1000
400.0
1600.92
1207.97
748.09
3000
2000
cm-1
1500
1000
400.0
4000.0
20
712.49
294 1.61
10
1067.87
2660.71
1358.41
10
1115.74
1680.71
3431.03
0.0
4000.0
159 6.62
652.81
2944.18
10
0.0
1500
1310.74
2864.0 4
30
294 0.98
20
908.16
1 117.20
1 231.91
2942.12
1709.72
0.0
1500
cm-1
17 12.22
1599.12
3415.15
10
1610.93
2000
715.5 0
1173.76
1355.77
2865.8 6
10
1712.31
3000
30
17 07.78
0.0
3000
2000
1500
cm-1
1000
400.0
1708.08
0.0
4000.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
SJC-PH-R-2. pk
SJC-PH-R-3. pk
SJC-PH-R-4. pk
SJC-Ph-Ram-5.pk
SJC-Ph-Ram-6.pk
SJC-PH~1. SP 3601 4000. 00 400. 00 6.26 99. 99 4.00 %T 5 1. 00
SJC-PH~2. SP 3601 4000. 00 400. 00 6.50 100.00 4.00 %T 5 1.00
SJC-PH~3. SP 3601 4000. 00 400. 00 6.49 100.00 4.00 %T 5 1.00
SJC-PH~4. SP 3601 4000. 00 400. 00 6.32 99. 99 4.00 %T 5 1. 00
SJ0CDA~1.SP 3601 4000.00 400.00 7.94 100.00 4. 00 %T 5 1.00
SJ0CDE~1.SP 3601 4000. 00 400. 00 6.39 99.99 4.00 %T 5 1.00
REF 4 000 98.25 2000 96.06 600

3938.94 97.04 3411.73 52.70 2940.35 9.74 2864.51 26.53 2719.87 91.57
2673.85 92.26 2062.95 95.42 1712.31 6.25 1595.53 21.53 1448.45 43.12
1356.25 31.74 1313.77 46.95 1222.96 48.18 1119.02 57. 28 1055.22 80. 45
1018.31 84.36 905.31 78 .16 864.41 85.62 753.33 74.15 651.39 85.70
490. 92 70 .17 412.11 91.67
REF 4 000 97.37 2000 95.11 600

3941.40 95.43 3447.65 2 5.12 3068.38 36.53 2942. 05 8.93 2865.86 18.47
2677.62 67.45 2177.10 9 5.51 2062.83 94.36 1709. 72 6.50 1610.93 14.98
1449.22 34.37 1355.77 2 1.05 1314.39 34.71 1228. 24 27.77 1173.10 52. 26
1118.35 47.06 1061.64 6 6.75 1020.84 78.21 905.35 74.45 863. 92 79.36
771. 73 62 .88 716.00 57. 27 650.00 69.13 4 93. 86 65. 76 412.85 87.29
REF 4 000 77.21 2000 72.09 600

3942.53 75.80 3415.15 1 7.93 3068.64 16.61 2942. 12 6.49 2867.10 11.75
2652.26 36.82 1919.88 6 8.40 1712.22 7. 33 1599.12 18.08 1449.82 23.07
1420.51 23.96 1351.29 2 1.79 1313.28 20.81 1231. 91 15.33 1173.76 26. 82
1117.20 27.85 1066.08 3 9.55 1022.50 47.21 905.78 45.87 863. 94 49.16
778. 24 42 .28 751.20 41. 13 715.50 28.18 6 50. 71 41. 57 496.88 49.73
418. 93 76 .12
REF 4 000 63.78 2000 54.03 600

3944.01 62.08 3431.03 6. 32 2944.18 6. 49 2660.71 11.93 192 0.32 47.18
1680.71 8. 45 1600.92 8. 82 1358.41 11.43 1115.74 16.17 106 7.87 20.30
908. 16 23 .42 712.49 18.25 652.81 23.7 9 502.47 29.97
REF 4 000 98.65 2000 96.86 600

3780.00 93.97 3443.67 5 2.90 3067.21 71.46 2940. 98 34.80 2864.31 56. 07
2737.45 79.95 2333.47 9 7.95 1980.80 96.21 1707. 78 7.94 1596.20 55.95
1450.30 62.85 1389.44 7 1.18 1310.84 62.49 1209. 02 48.87 1168.60 68. 58
1116.50 74.37 1065.69 8 3.89 1017.83 86.77 904.98 90.09 826. 63 71.00
748. 17 49 .99 691.79 65. 27 650.17 67.50 4 92. 81 83. 60 452.53 86.34
REF 4 000 98.20 2000 93.19 600

3879.66 96.56 3778.63 90.32 3401.34 43.48 3065.75 54. 75 2941.61 20. 26
2864.04 37.16 2737.66 59.25 2332.62 94.93 1981.01 91. 57 1911.94 93. 23
1815.10 88.88 1708.08 6. 39 1596.62 36.27 1449.79 46.04 1390.87 56.08
1310.74 46.16 1207.97 32.12 1168.39 52.68 1117.51 62. 37 1067.51 73. 46
1016.38 76.52 905.90 82 .22 826.80 53.97 748.09 32.86 690.97 49.34
650. 41 53 .04 491.84 75.33 452.10 75.5 6
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 15- 2-2010
4 13.92
FT IR SPECT RUM
Date: 08- 2-2010
Spectrum Name: SJC-PH-R-10. sp
100.0
ACIC
St.Joseph's College( Autonomous )
Trichy-2
FT IR SPECT RUM
Date: 08- 2-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08- 2-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08- 2-2010
400.0
cm-1
SJC-PH-R-1. pk
ACIC
Tric hy-2
650.41
690.97
1449.79
502.47
20
3447.65
1595.53
294 0.35
4000.0
30
6 50.71
3068.64
1 228.24
20
2864.51
10
0.0
40
3 401.34
1066.08
826.80
116 8.39
1209.02
40
7 78.24
265 2.26
30
1449.22
1390.87
3065.75
%T
748.17
1420.51
30
1356.25
50
1310.8 4
2864.3 1
1920.3 2
40
905.78
131 3.77
30
1596.20
3443.67
%T
496.88
40
111 8.35
50
%T
1313.28
1222.96
40
452.10
60
691.79
2737.66
50
491.84
1016.38
826.63
3067.21
863 .94
60
1061.64
26 77.62
1815.10
70
1116.50
1389.44
4 90.92
60
%T
FTIR SPECTRUM
Date: 09-2-2010
Spectrum Name: SJC-PH-R-12.sp
100.0
859.50
413.82
100.0
100.0
1018.69
864.13
3879.79
90
90
1912.46
233 3.39
3778.22
90
1 020.26
3938.95
90
3 940.62
906.21
13 91.08
80
10 16.80
70
1068.29
1171.4 2
2677.10
1424.28
650.48
904.32
1066.39
3064.87
650.23
1173.34
756.09
1061.04
%T
1207.69
747.84
3415.96
30
1312.62
826 .55
60
650.67
2738.03
1451.19
3067.46
%T
748.94
120 8.42
2864.30
30
542.68
1 115.66
117 0.05
3396.20
714.03
50
1452.05
1355.60
40
1596.55
1452.44
50
30
1226.45
748.74
650.77
2821.39
40
1207.97
1 227.20
694.68
1385.06
1212.54
30
825.94
1169.75
%T
1310.83
2864.67
40
1118.31
1446.64
453.57
70
1359.62
60
715.87
2824.68
%T
3069.74
40
649.91
1169.23
3 401.83
50
4 94.41
716.2 1
111 8.42
40
27 37.74
1117.22
60
904.82
2668.26
50
%T
6 91.45
70
2737.03
826.57
60
50
1168.65
2863.59
1070.67
1115.27
1313.51
70
4 92.90
759.83
1315.48
650.41
1450.10
1310.35
3 403.81
40
1018.94
80
451.56
1068.16
70
716.42
1059.36
60
826.78
3066.66
50
1913.50
497.40
906.16
1914.26
80
4 93.29
10 19.45
1979.60
90
1 977.33
451.75
903.77
80
2178.50
70
451.85
1116.70
2737.81
60
%T
90
690 .06
1916.9 9
864.11
80
492.69
1 975.38
420 .36
1816.49
1 981.38
80
30
1354.33
30
747.88
2943.84
1593.14
294 1.47
1445.59
1354.11
20
20
20
294 2.14
3420.68
20
1229.02
3075.36
1597.23
20
294 0.63
20
1616.13
2866.27
1601.98
10
10
1352.97
2867.97
10
10
10
3435.76
10
1700.99
1707.39
294 1.32
0.0
17 12.23
0.0
4000.0
3000
2000
1500
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
400.0
0.0
171 3.05
4000.0
1705.98
1706.69
294 2.12
0.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
2000
1500
cm-1
1000
400.0
1595.99
0.0
0.0
4000.0
3000
2000
cm-1
1500
1000
4000.0
400.0
3000
2000
1500
1000
SJC-PH-R-8. pk
SJC-PH-R-9. pk
SJC-PH-R-10.pk
SJC-PH-R-11.pk
SJC-PH-R-13.pk
SJ0CD2~1.SP 3601 4000. 00 400.00 7.07 100.0 0 4.00 %T 5 1 .00
SJC90F~1. SP 3601 4000. 00 400. 00 6.72 100.00 4.00 %T 5 1.00
SJD9 0B~1. SP 3601 4000.0 0 400.00 6. 60 100.00 4.00 %T 5 1. 00
SJ8E4 3~1. SP 3601 4000.00 400.00 6.60 100. 00 4.00 %T 5 1. 00
SJ8653~1.SP 3601 4000. 00 400.00 7.33 100.00 4.00 %T 5 1 .00
SJ8663~1.SP 3601 4000.00 400.00 7.19 99.98 4.00 %T 5 1.00
REF 4 000 98.78 2000 95.10 600

3879.79 97.45 3778.22 9 2.66 3403.81 48.02 3066. 66 58.45 2941.47 30. 36
2863.59 47.86 2737.81 6 5.84 2333.39 96.15 1981. 38 93.87 1912.46 95. 06
1816.49 92.48 1707.39 7 .06 1596.55 43.54 1450.10 55.80 1391.08 63.45
1310.35 54.27 1207.69 3 9.29 1168.65 58.96 1116. 70 69.43 1068.29 78. 37
1016.80 81.64 906.21 87. 39 826.78 61 .10 747.84 40.07 691.45 55.73
650. 41 59 .56 492.69 81. 92 451.85 80.70
REF 4 000 98.01 2000 96.65 600

3938.95 96.66 3415.96 3 8.82 2941.32 8. 41 2866.27 21.88 2677.10 81.58
1712.23 6. 72 1616. 13 20. 97 1446.64 38.43 1354.11 28.73 1315.48 41.59
1226.45 35.90 1171.42 6 5.07 1118.42 51.90 1059. 36 71.62 1020.26 81. 56
904. 32 77 .41 864.13 83. 43 759.83 68.24 7 16. 42 73. 39 650.48 78.37
492. 90 68 .36 413.92 89. 65
REF 4 000 83.43 2000 82.79 600

3940.62 82.36 3420.68 2 4.49 3069.74 34.00 2942. 12 6.79 2867.97 16.04
2668.26 61.89 2178.50 8 2.36 1713.05 6. 60 1601.98 19.48 1445.59 30.54
1352.97 25.76 1229.02 2 5.16 1173.34 45.96 1118. 31 41.51 1061.04 56. 95
904. 82 64 .57 864.11 68. 72 756.09 57.48 7 16. 21 53. 11 650.23 62.03
494. 41 56 .07 420.36 81. 47
REF 4 000 99.08 2000 96.37 600

3401.83 59.27 3064.87 6 0.72 2940.63 23.94 2864. 30 43.46 2824.68 58. 96
2737.03 74.58 1975.38 9 5.17 1916.99 94.64 1706. 69 6.59 1593.14 32.35
1452.05 54.68 1424.28 6 5.03 1355.60 53.21 1313. 51 52.05 1227.20 49. 41
1208.42 46.25 1169.23 6 5.09 1117.22 67.68 1066. 39 82.99 1019.45 85. 56
903. 77 87 .82 859.50 89. 47 826.57 71.01 7 48. 94 49. 22 715.87 63.15
690. 06 66 .77 649.91 66. 40 493.29 84.48 4 51. 75 89. 78 413.82 95.01
REF 4 000 99.34 2000 95.98 600

3396.20 61.37 3067.46 5 3.46 2942.14 30.61 2864. 67 47.56 2737.74 69. 99
1977.33 94.66 1914.26 9 3.78 1705.98 7. 33 1597.23 30.17 1451.19 58.73
1359.62 53.12 1310.83 5 2.74 1212.54 43.33 1170. 05 61.83 1115.66 71. 49
1068.16 82.84 1018.69 8 6.70 906. 16 87.88 826.55 68. 26 748.74 49.65
714. 03 59 .23 650.67 65. 29 497.40 88.23 4 51. 56 88. 84
REF 4000 99.41 2000 97.82 600

3435.76 16.46 3075.36 36.79 2943.84 39.15 2821.39 47.32 2738.03 61.49
1979.60 96.58 1913.50 96.31 1700.99 12.81 1595.99 7.19 1452.44 59.85
1385.06 44.86 1354.33 43.00 1312.62 51.91 1207.97 45.16 1169.75 62.34
1115.27 80.03 1070.67 85.60 1018.94 89.20 825.94 59.29 747.88 38.21
694.68 46.63 650.77 49.53 542.68 72.65 453.57 76.93
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 15- 2-2010
Spectrum Name: SJC-Ph- Ram-13.sp
100.0
90
2544.31
924.23
416.91
2944.94
100.0
544.35
1169.05
100.0
30
746.04
749.24
10
2866.56
20
1000
400.0
4000.0
1313.21
294 1.98
10
1597.06
32 04.98
3439.15
2000
1000
400.0
4000.0
1453.58
2738.07
651.06
826.14
30
690.87
745.60
3068.32
20
29 39.93
116 8.70
13 87.96
1206.19
3395.62
20
2822.60
651.09
1284.43
688.77
3393.43
1205.73
2939.60
746.54
2865.74
10
1597.63
1705.04
0.0
1500
cm-1
713.73
1169.43
2821.81
1233.66
2867.0 0
294 2.50
17 07.38
3000
13 87.84
1283.71
30
1232.55
10
3000
2000
0.0
1500
1000
400.0
4000.0
2000
1500
1000
400.0
4000.0
cm-1
16 99.87
1595.44
17 00.04
0.0
1704.78
3000
cm-1
10
1595.24
1596.58
294 2.04
1500
cm-1
450.78
6 50.63
32 06.39
3437.50
713.83
40
3069.60
714.23
543.54
1114.31
824.51
2 737.70
11 71.23
748.64
1311.21
50
%T
40
1451.25
1312.84
0.0
2000
1823.64
2550.33
60
449.42
%T
3068.4 7
30
1349.30
20
17 02.36
3000
70
542 .09
50
827.30
1116.64
1 117.27
1173.58
1450.6 8
1232.20
3438.23
10
0.0
9 27.79
1070.83
1114.41
1068.13
1351.48
1452.1 2
3069.5 2
30
1312.33
20
1979.33
1016.43
2551.07
60
13 88.27
2739.08
40
650.83
3071.40
20
1071.31
1494.04
2660.12
50
%T
139 0.10
2654.89
40
1449.07
1205.51
2028.28
23 31.96
1914.27
70
499.13
1021.77
60
499.66
827.56
1068.55
749.53
713.17
1596.60
3914.04
80
236 3.84
1416.62
50
%T
650.43
11 72.62
40
3443.99
30
1019.30
90
2026.94
1979.12
907.07
70
906.79
60
1116.46
%T
650.82
690.37
1914.88
2140.59
3792.24
1 823.31
3 795.21
392 5.94
80
1917.85
498.23
1386.35
50
826.54
1306.91
23 68.76
9 28.44
826.33
1350.22
2 740.59
1390.11
70
102 1.40
1066.51
60
1453.37
2819.26
3069.37
40
3922.57
1023.35
904.94
70
2658.54
2738.06
50
1 975.95
4 52.91
80
862.84
1920.05
450.97
60
90
3 780.75
415.38
80
1 111.47
70
%T
90
1972.99
80
FT IR SPECT RUM
Date: 09- 2-2010
100.0
3938.64
191 7.73
1017.16
1913.01
90
197 5.62
1981.03 1 821.90
3 778.62
80
4000.0
FT IR SPECT RUM
Date: 09- 2-2010
1072.42
3880.0 0
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 09- 2-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 09- 2-2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 09- 2-2010
400.0
cm-1
cm-1
SJC-Ph-Ram-7.pk
3000
2000
0.0
1500
1000
400.0
4000.0
cm-1
3000
2000
1500
1000
cm-1
SJC-Ph-Ram-13.pk
SJC-PH-R-14.pk
SJC-PH-R-15.pk
SJC-PH-R-16.pk
SJC-PH-R-17.pk
SJC-PH-R-18.pk
SJC833~1.SP 3601 4000.00 400 .00 7.30 99.94 4.00 %T 5 1. 00
SJ8E6 3~1. SP 3601 4000.00 400.00 6.68 100. 00 4.00 %T 5 1. 00
SJ8673~1.SP 3601 4000. 00 400.00 6.46 99.99 4.00 %T 5 1. 00
SJ8E7 3~1. SP 3601 4000.00 400.00 6.50 99.99 4.00 %T 5 1.0 0
SJ8683~1.SP 3601 4000. 00 400.00 7.11 100.00 4.00 %T 5 1 .00
SJ8E8 3~1. SP 3601 4000.00 400.00 5.97 99.99 4.00 %T 5 1.0 0
REF 4 000 98.94 2000 95.23 600

3880.00 97.52 3778.62 91.98 3443.99 39.30 3069.37 56. 01 2944.94 60. 40
2819.26 57.97 2738.06 65.71 2544.31 90.10 1981.03 94. 00 1913.01 94. 35
1821.90 94.34 1702.36 7. 30 1596.60 37.53 1453.37 64.88 1390.11 59.98
1306.91 54.95 1205.51 38.59 1169.05 58.47 1111.47 82. 24 1072.42 85. 10
1017.16 87.43 924.23 90 .74 826.54 55.59 746.04 35.00 690.37 45.92
650. 82 50 .68 544.35 83.49 450.97 74.7 0
REF 4 000 98.27 2000 97.28 600

3438.23 22.03 3071.40 3 1.13 2941.98 12.86 2866. 56 25.99 2740.59 63. 84
2658.54 69.83 1975.62 9 5.96 1917.73 95.96 1707. 38 6.67 1597.06 15.45
1449.07 43.07 1386.35 4 3.09 1350.22 37.79 1312. 33 37.44 1232.20 27. 42
1172.62 50.12 1116.46 5 2.66 1066.51 69.17 1021. 40 78.49 904.94 80.66
826. 33 70 .30 749.53 47. 29 713.17 39.72 6 50. 43 55. 01 498.23 69.56
416. 91 91 .23
REF 4 000 97.69 2000 93.33 600

3938.64 96.09 3439.15 17.67 3204.98 20.38 3069.52 19. 75 2942.50 8.60
2867.00 17.05 2654.89 50.10 1972.99 90.61 1920.05 89. 66 1705.04 6.46
1597.63 16.40 1450.68 33.65 1416.62 34.65 1390.10 34. 69 1349.30 32. 89
1313.21 27.17 1233.66 19.40 1173.58 37.72 1117.27 40. 43 1068.55 55. 77
1023.35 65.10 906.79 66 .72 862.84 69.76 827.56 62.70 749.24 43.31
714. 23 28 .64 650.83 46.11 499.66 63.6 8 415.38 86.82
REF 4 000 98.22 2000 95.44 600

3922.57 97.21 3780.75 94.64 3437.50 23.47 3206.39 27. 10 3068.47 25. 41
2942.04 11.42 2865.74 23.02 2739.08 52.99 2660.12 63. 17 2368.76 89. 94
1975.95 93.32 1917.85 92.81 1704.78 6.50 1596.58 11.01 1451.25 38.78
1388.27 36.99 1351.48 35.53 1312.84 31.71 1232.55 25. 70 1171.23 40. 49
1116.64 49.61 1068.13 63.34 1021.77 70.81 907.07 76.89 827.30 55.57
748. 64 34 .17 713.73 31.12 650.63 44.1 5 499.13 69.05 452.91 78. 41
REF 4 000 99.39 2000 92.88 600

3925.94 97.82 3795.21 9 7.45 3395.62 28.99 3069. 60 33.11 2939.93 29. 94
2821.81 35.56 2737.70 4 5.22 2551.07 68.33 2363. 84 85.55 2026.94 93. 29
1979.12 89.42 1914.27 8 8.85 1823.31 90.27 1700. 04 7.11 1595.24 11.65
1452.12 50.18 1387.84 4 1.29 1283.71 36.69 1206. 19 31.67 1169.43 43. 78
1114.41 66.70 1070.83 7 4.27 1016.43 78.20 927.79 76.94 824. 51 48.12
745. 60 31 .11 690.87 36. 23 651.06 39.50 5 42. 09 74. 76 449.42 69.53
REF 4 000 99.18 2000 91.35 600

3914.04 97.96 3792.24 97.20 3393.43 27.17 3068.32 30. 72 2939.60 28. 94
2822.60 32.14 2738.07 41.52 2550.33 67.71 2331.96 87. 73 2140.59 98. 16
2028.28 91.40 1979.33 87.44 1914.88 86.06 1823.64 85. 97 1699.87 5.97
1595.44 8. 81 1494.04 73 .72 1453.58 44.36 1387.96 36.00 1311.21 33.37
1284.43 32.58 1205.73 26.12 1168.70 38.59 1114.31 65. 30 1071.31 70. 10
1019.30 74.33 928.44 71 .32 826.14 39.26 746.54 24.33 713.83 32.95
688. 77 31 .17 651.09 33.64 543.54 70.9 9 450.78 61.25
301
400.0
Table - 7.23
Observations of FTIR Spectrums for
Cyclohexanone + Hexane + Benzaldehyde mixture
S1 (Cm-1)
S2 (Cm-1)
S3 (Cm-1)
S4 (Cm-1)
*S5(Cm-1)
S6 (Cm-1)
S7 (Cm-1)
S8 (Cm-1)
3938.94
3411.73
2940.35
2864.51
2719.87
2673.85
2062.95
1712.31
1595.53
1448.45
1356.25
1313.77
1222.96
1119.02
1055.22
1018.31
905.31
864.41
753.33
651.39
490.92
412.11
3941.40
3447.65
3068.38
2942.05
2865.86
2677.62
2177.10
2062.83
1709.72
1610.93
1449.22
1355.77
1314.39
1228.24
1173.10
1118.35
1061.64
1020.84
905.35
863.92
771.73
716.00
650.00
493.86
412.85
3942.53
3415.15
3068.64
2942.12
2867.10
2652.26
1919.88
1712.22
1599.12
1449.82
1420.51
1351.29
1313.28
1231.91
1173.76
1117.20
1066.08
1022.50
905.78
863.94
778.24
751.20
715.50
650.71
496.88
3944.01
3431.03
2944.18
2660.71
1920.32
1680.71
1600.92
1358.41
1115.74
1067.87
908.16
712.49
652.81
502.47
3780.00
3443.67
3067.21
2940.98
2864.31
2737.45
2333.47
1980.80
1707.78
1596.20
1450.30
1389.44
1310.84
1209.02
1168.60
1116.50
1065.69
1017.83
904.98
826.63
748.17
691.79
650.17
492.81
452.53
3879.66
3778.63
3401.34
3065.75
2941.61
2864.04
2737.66
2332.62
1981.01
1911.94
1815.10
1708.08
1596.62
1449.79
1390.87
1310.74
1207.97
1168.39
1117.51
1067.51
1016.38
905.90
826.80
748.09
690.97
3879.79
3778.22
3403.81
3066.66
2941.47
2863.59
2737.81
2333.39
1981.38
1912.46
1816.49
1707.39
1596.55
1450.10
1391.08
1310.35
1207.69
1168.65
1116.70
1068.29
1016.80
906.21
826.78
747.84
691.45
3938.95
3415.96
2941.32
2866.27
2677.10
1712.23
1616.13
1446.64
1354.11
1315.48
1226.45
1171.42
1118.42
1059.36
1020.26
904.32
864.13
759.83
716.42
650.48
492.90
413.92
S11 (Cm-1)
3396.20
3067.46
2942.14
2864.67
2737.74
1977.33
1914.26
1705.98
1597.23
1451.19
1359.62
1310.83
1212.54
1170.05
1115.66
1068.16
1018.69
906.16
826.55
748.74
714.03
650.67
497.40
451.56
S12 (Cm-1)
3435.76
3075.36
2943.84
2821.39
2738.03
1979.60
1913.50
1700.99
1595.99
1452.44
1385.06
1354.33
1312.62
1207.97
1169.75
1115.27
1070.67
1018.94
825.94
747.88
694.68
650.77
542.68
453.57
S14 (Cm-1)
3438.23
3071.40
2941.98
2866.56
2740.59
2658.54
1975.62
1917.73
1707.38
1597.06
1449.07
1386.35
1350.22
1312.33
1232.20
1172.62
1116.46
1066.51
1021.40
904.94
826.33
749.53
713.17
650.43
498.23
416.91
S15 (Cm-1)
3938.64
3439.15
3204.98
3069.52
2942.50
2867.00
2654.89
1972.99
1920.05
1705.04
1597.63
1450.68
1416.62
1390.10
1349.30
1313.21
1233.66
1173.58
1117.27
1068.55
1023.35
906.79
862.84
827.56
749.24
714.23
650.83
499.66
415.38
*S16 (Cm-1)
3922.57
3780.75
3437.50
3206.39
3068.47
2942.04
2865.74
2739.08
2660.12
2368.76
1975.95
1917.85
1704.78
1596.58
1451.25
1388.27
1351.48
1312.84
1232.55
1171.23
1116.64
1068.13
1021.77
907.07
827.30
748.64
713.73
650.63
499.13
452.91
S10 (Cm-1)
3401.83
3064.87
2940.63
2864.30
2824.68
2737.03
1975.38
1916.99
1706.69
1593.14
1452.05
1424.28
1355.60
1313.51
1227.20
1208.42
1169.23
1117.22
1066.39
1019.45
903.77
859.50
826.57
748.94
715.87
690.06
649.91
493.29
451.75
413.82
S13 (Cm-1)
3880.00
3778.62
3443.99
3069.37
2944.94
2819.26
2738.06
2544.31
1981.03
1913.01
1821.90
1702.36
1596.60
1453.37
1390.11
1306.91
1205.51
1169.05
1111.47
1072.42
1017.16
924.23
826.54
746.04
690.37
650.82
544.35
450.97

302
S17 (Cm-1)
3925.94
3795.21
3395.62
3069.60
2939.93
2821.81
2737.70
2551.07
2363.84
2026.94
1979.12
1914.27
1823.31
1700.04
1595.24
1452.12
1387.84
1283.71
1206.19
1169.43
1114.41
1070.83
1016.43
927.79
824.51
745.60
690.87
651.06
542.09
449.42
S9 (Cm-1)
3940.62
3420.68
3069.74
2942.12
2867.97
2668.26
2178.50
1713.05
1601.98
1445.59
1352.97
1229.02
1173.34
1118.31
1061.04
904.82
864.11
756.09
716.21
650.23
494.41
420.36
S18 (Cm-1)
3914.04
3792.24
3393.43
3068.32
2939.60
2822.60
2738.07
2550.33
2331.96
2140.59
2028.28
1979.33
1914.88
1823.64
1699.87
1595.44
1494.04
1453.58
1387.96
1311.21
1284.43
1205.73
1168.70
1114.31
1071.31
1019.30
928.44
826.14
746.54
713.83
688.77
651.09
543.54
450.78
Fig-7.23: FTIR Spectrums for Cyclohexanone+Hexane+2-Butanone mixture:

ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECTRUM
Date: 11-5-2010
ACIC
Trichy-2
FTIR SPECTRUM
Date: 11-5-2010
Spectrum Name: SJC-0.5+ 0.4+0.1.sp
100.0
ACIC
Trichy-2
FTIR SPECTRUM
Date: 11-5-2010
Spectrum Name: SJC-0.5+0.2+0.3.sp
FTIR SPECTRUM
Date: 11-5-2010
10 0.0
10 0.0
10 0.0
10 0.0
4 19.47
90
3 92 7.77
90
393 2.10
4 14 .9 9
2 17 7.5 2
90
37 85.81
4 21 .74
2 67 1.1 1
80
393 4.64
80
1 018 .9 0 86 4.78
6 51.22
74 9.00
2 17 7.20
26 69.96
37 83 .01
217 7.76
2 67 0.99
80
1 054 .3 7
90 4.99
65 2.5 9
70
4 91.24
4 91.22
60
4 91.27
60
1 56 3.2 9
1 11 8.9 7
1 11 9.0 0
1 11 8.9 7
50
1 56 4.9 5
50
131 4.03
%T
1 22 2.9 0
1 22 3.0 3
1 565 .6 0
50
%T
1 11 9.1 0
131 4.76
1 22 2.6 8
%T
131 5.28
1 32 3.2 2
1 22 2.4 6
40
50
%T
1 56 3.3 7
40
65 2.2 6
7 49 .8 5
7 50 .0 6
4 92.23
1 11 9.4 9
50
40
1 222 .6 6
40
40
143 2.69
1 326 .1 9
30
14 27 .0 9
30
14 35.37
30
143 2.95
30
30
2 86 7.00
3 451 .0 1
28 66.78
14 33 .02
20
8 65 .1 7
26 70 .57
80
8 65.27
10 54.47 90 5.07
70
9 03 .0 3
60
4 93 .54
2 177 .8 1
65 1.9 3
7 49 .6 7
70
65 2.4 9
7 49 .8 0
60
%T
15 64 .39
4 15 .32
39 28.61
90
10 55.01
10 54.65 90 4.34
70
105 7.20
60
4 14 .2 3
23 42.34
3 792 .1 7
90 2.2 9
70
101 8.93
3 92 8.52
90
23 45.32
3 79 1.1 3
21 75.90
26 70 .15
3 785 .7 5
80
FTIR SPECTRUM
Date: 11-5-2010
3 45 5.1 7
20
20
2 87 1.0 0
3 43 1.3 2
2 867 .4 7
20
20
28 71.39
34 46.59
10
10
10
29 41.96
10
10
29 41.36
34 47.99
29 42.53
171 3.47
171 6.75
0.0
29 41.39
0 .0
4000.0
300 0
2000
15 00
1000
400.0
171 4.66
29 41.90
0 .0
40 00.0
3 000
2000
1500
c m -1
1000
400.0
171 4.55
171 3.50
0 .0
40 00.0
3 000
2000
1500
c m -1
1000
400.0
0 .0
40 00.0
3 000
2000
1500
c m -1
1000
400.0
40 00.0
3 000
2000
1500
c m -1
1000
400.0
c m -1
SJ C-0.5+ 0.2+0.3.pk
SJ C-0.5+0.4+0.1.pk
SJ C-0.5+0.3+0.2.pk
SJ C-0.5+0.1+0.4.pk
SJ C-0.4+0.5+0.1.pk
SJ C-05~3.SP 3601 4000.00 400.00 7.01 99.99 4.00 %T 3 1.00
SJ C-05~1.SP 3601 4000.00 400.00 8.63 100.00 4.00 %T 3 1.00
SJ C-05~2.SP 3601 4000.00 400.00 9.53 99.99 4.00 %T 3 1.00
SJ C-05~4.SP 3601 4000.00 400.00 8.40 100.00 4.00 %T 3 1.00
SJ C-04~1.SP 3601 4000.00 400.00 9.42 100.00 4.00 %T 3 1.00
REF 4000 99.14 2000 97.22 600

3932.10 95.11 3785.75 88.95 3447.99 11.09 2942.53 7.04 2871.39 22.58
2670.15 90.51 2177.52 94.13 1716.75 7.01 1564.39 42.74 1433.02 28.34
1326.19 47.76 1222.90 51.67 1119.49 60.38 1057.20 79.81 902.29 79.69
749.00 67.39 651.22 69.55 493.54 58.54 421.74 87.07
REF 4000 97.38 2000 95.95 600

3927.77 94.92 3785.81 91.13 3446.59 20.08 2941.96 13.16 2866.78 31.31
2671.11 91.09 2175.90 93.59 1713.47 8.62 1563.37 52.20 1427.09 37.56
1314.03 53.58 1222.46 51.74 1118.97 58.70 1054.65 78.80 1018.90 82.94
904.34 77.78 864.78 85.54 749.80 70.63 652.49 74.55 491.27 61.74
414.99 88.90
REF 4000 98.50 2000 97.10 600

3934.64 95.56 3791.13 92.36 3431.32 25.85 2941.39 9.87 2871.00 27.68
2669.96 91.54 2345.32 95.97 2177.20 95.09 1714.66 9.53 1564.95 61.02
1435.37 37.28 1323.22 52.57 1223.03 55.18 1119.00 62.60 1055.01 79.88
903.03 81.11 749.67 76.41 651.93 81.89 492.23 68.75 419.47 94.89
REF 4000 98.21 2000 97.04 600

3928.52 95.87 3783.01 90.94 3455.17 29.09 2941.90 9.59 2867.47 27.08
2670.99 91.04 2342.34 95.38 2177.76 94.99 1714.55 8.39 1565.60 60.85
1432.95 37.92 1315.28 51.52 1222.66 49.88 1119.10 57.18 1054.47 78.24
1018.93 82.27 905.07 77.78 865.27 86.14 750.06 73.20 652.59 79.97
491.22 66.00 414.23 92.44
REF 4000 98.41 2000 97.41 600

3928.61 96.81 3792.17 93.24 3451.01 32.96 2941.36 13.64 2867.00 34.31
2670.57 93.30 2177.81 95.75 1713.50 9.41 1563.29 64.11 1432.69 45.05
1314.76 58.31 1222.68 56.08 1118.97 63.21 1054.37 82.27 904.99 81.26
865.17 87.97 749.85 76.69 652.26 81.48 491.24 69.21 415.32 92.23
ACIC
Trichy-2
ACIC
Trichy-2
10 0.0
100.0
90
3 87 9.9 9
26 71.61
37 80 .5 0
8 64 .75
80
1 96 5.1 3
26 69.71
100.0
10 18.18
5 86 .5 1
1 87 3.58
11 72 .7 8
20 71.33
3 78 7.1 2
100.0
865 .1 6
23 38 .0 2
23 45.83
80
Spectrum Name: SJ C-0.3+0.5+0.2.sp
10 18 .5 9
391 5.77
90
21 78 .12
80
2 670 .3 7
3 78 1.01
38 79 .9 8
90
2 33 8.9 6
2 17 6.60
21 77.85
37 78 .8 5
80
86 5.33
9 03.90
80
586 .8 3
26 69 .97
10 55 .3 9
6 52 .3 3
74 9.87
9 05.19
70
10 55 .0 0
37 12 .6 0
9 05.48
70
6 52 .5 1
24 52 .7 1
2 16 8.1 4
3 94 2.4 1
13 45.44
9 05 .1 9
70
90
26 70 .9 1
6 52 .4 3
10 38 .2 8
70
7 50 .4 3
10 51 .94
75 0.22
49 1.33
60
8 97.71
60
38 22 .3 8
41 5.4 8
1 87 4.69
11 72 .6 7
41 4.48
10 54 .3 8
65 2.1 0
70
FTIR SPECT RUM

Date: 14-5-2010
4 16 .8 0
42 1.0 8
ACIC
Trichy-2
FTIR SPECT RUM

Date: 11-5-2010
100.0
2 178 .9 8
ACIC
Trichy-2
FTIR SPECT RUM

Date: 11-5-2010
393 8.94
90
ACIC
Trichy-2
FTIR SPECT RUM

Date: 11-5-2010
FTIR SPECTRUM
Date: 11-5-2010
15 65 .5 3
4 92.19
1 11 9.34
75 0.41
60
1 11 9.05
60
12 22 .5 2
60
49 1.72
4 96.64
74 6.93
49 1.95
1 31 5.13
50
%T
1 431 .8 6
50
%T
6 50 .4 9
13 37 .2 8
%T
131 6.69
12 22 .4 7
15 64.86
40
1 11 9.30
50
%T
1 22 2.43
%T
1 22 3.7 5
15 66 .0 9
1 11 9.22
50
1 11 9.1 4
50
40
40
30
30
131 6.80
12 22 .2 6
40
40
13 24 .15
30
34 18 .7 9
30
2 87 6.47
14 29 .99
28 67 .2 7
14 36.06
3 453 .9 8
2 86 8.11
20
20
30
1 432 .5 7
20
20
20
2 868 .0 7
3 459 .5 5
1 42 2.18
10
10
40 00.0
10
17 27 .8 5
10
2 94 6.3 1
29 41 .7 8
1 569 .4 1
17 13 .96
17 14 .49
0.0
3 000
3 456 .5 2
10
29 41 .4 4
171 3.81
29 39.87
0 .0
2000
1500
1000
29 41 .7 5
0.0
4000.0
400.0
3000
2000
15 00
100 0
400.0
c m -1
17 15 .54
0.0
4000.0
3000
2000
15 00
cm-1
100 0
400.0
34 21 .5 3
0.0
4000.0
3000
2000
15 00
cm-1
100 0
400.0
4000.0
3000
2000
15 00
cm-1
100 0
SJ C-0.4+0.3+0.3.pk
SJ C-0.4+0.2+0.4.pk
SJ C-0.4+0.1+0.5.pk
SJ C-0.3+0.5+0.2.pk
SJ C-04~2.SP 3601 4000.00 400.00 7.82 100.00 4.00 %T 3 1.00
SJ C-04~3.SP 3601 4000.00 400.00 9.31 99.99 4.00 %T 3 1.00
SJ C-04~4.SP 3601 4000.00 400.00 8.41 100.00 4.00 %T 3 1.00
SJ 67A7~1.SP 3601 4000.00 400.00 8.30 99.99 4.00 %T 3 1.00
SJ C-03~1.SP 3601 4000.00 400.00 6.34 99.52 4.00 %T 3 1.00
REF 4000 99.42 2000 98.11 600

3938.94 97.29 3787.12 94.60 3418.79 36.62 2939.87 7.82 2669.71 86.12
2345.83 95.88 2178.98 95.63 2071.33 95.81 1965.13 96.70 1713.81 12.52
1436.06 33.84 1324.15 44.97 1223.75 49.71 1119.14 58.98 1051.94 75.25
897.71 74.41 750.43 73.95 652.10 85.17 492.19 66.77 421.08 93.59
REF 4000 97.99 2000 96.97 600

3879.99 96.44 3780.50 89.78 3453.98 29.07 2941.44 13.17 2867.27 33.97
2671.61 92.60 2178.12 95.35 1713.96 9.31 1565.53 63.91 1431.86 45.00
1315.13 59.59 1222.43 57.89 1119.05 64.97 1054.38 83.43 905.19 82.44
864.75 88.35 749.87 74.93 652.33 78.69 491.33 67.36 416.80 89.65
REF 4000 97.80 2000 96.23 600

3915.77 95.10 3781.01 87.36 3456.52 16.57 2941.78 12.31 2868.11 28.83
2670.37 90.09 2338.02 95.17 2176.60 93.50 1873.58 96.45 1714.49 8.40
1564.86 54.39 1429.99 33.80 1316.69 51.41 1222.47 50.84 1172.78 76.93
1119.22 58.60 1055.00 78.43 1018.59 82.67 905.19 77.64 865.16 86.37
750.22 68.56 652.51 74.78 586.51 83.06 491.95 61.85 414.48 90.10
REF 4000 97.44 2000 96.43 600

3879.98 95.57 3778.85 87.88 3459.55 23.37 2941.75 9.92 2868.07 25.52
2670.91 89.55 2338.96 95.84 2177.85 94.44 1874.69 96.28 1715.54 8.29
1566.09 66.74 1432.57 36.59 1345.44 51.23 1316.80 51.49 1222.26 50.68
1172.67 72.06 1119.30 59.24 1055.39 80.07 1018.18 84.62 905.48 77.81
865.33 86.59 750.41 70.54 652.43 78.85 586.83 85.12 491.72 63.49
415.48 87.79
REF 4000 98.62 2000 95.71 600

3942.41 87.88 3822.38 88.96 3712.60 81.90 3421.53 6.34 2946.31 14.78
2876.47 36.88 2669.97 89.12 2452.71 94.26 2168.14 89.76 1727.85 16.71
1569.41 11.99 1422.18 19.55 1337.28 57.99 1222.52 66.59 1119.34 70.60
1038.28 77.83 903.90 87.27 746.93 66.93 650.49 56.70 496.64 65.81
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 14-5-2010
2 67 0.27
80
395 1.27
100.0
100.0
1 966 .0 2
3 948 .4 4
80
6 52 .5 4
2 17 8.62
1 01 8.35 8 65 .7 5
1 57 2.05
583 .5 5
21 76.88
26 69 .94
1 17 5.15
80
6 51 .8 0
2 34 2.1 0
3 77 7.76
1 87 1.9 3
24 55 .7 7
3 943 .0 7
267 0.93
80 3 950 .9 2
6 51 .7 3
9 04.02
70
75 0.92
21 74 .2 7
80
1 018 .4 6
65 2.24
86 5.76
70
105 4.85
74 9.97
9 04.66
49 2.53
60
19 67 .6 5
2 17 6.6 7
26 70 .38
6 52 .5 7
70
75 1.18
10 57 .84
10 56 .70
49 1.12
60
90
1 87 3.57
1 01 8.7 8
9 05.30
9 03.19
70
9 04.80 75 0.48
41 5.06
4 14 .3 6
3 77 6.76
3 830 .3 0
26 69 .4 7
10 54 .9 2
100.0
864 .8 5
10 54 .3 6
90
2 34 7.1 7
2 34 6.9 9
3 94 1.39
70
4 18.26
1 96 4.66
383 3.01
90
1 96 4.53
38 32 .8 2
FTIR SPECT RUM

Date: 14-5-2010
4 19.41
90
21 76 .78
38 53.71
FTIR SPECT RUM

Date: 14-5-2010
100.0
4 14 .3 2
90
ACIC
Trichy-2
FTIR SPECT RUM

Date: 14-5-2010
100.0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 14-5-2010
400.0
cm-1
SJ C-0.4+0.4+0.2.pk
49 3.13
60
1 569 .5 1
60
1 57 0.65
60
49 1.42
75 0.25
341 0.86
1 11 9.50
50
1 11 9.68
50
1 11 9.13
%T
1 11 9.05
15 69.15
50
%T
40
50
%T
15 66 .8 5
12 22 .4 7
1 33 0.60
40
13 26 .0 7
1 22 2.8 1
49 1.05
50
%T
12 23 .0 0
1 31 5.23
40
1 31 5.52
12 22 .3 4
%T
1 11 9.05
40
40
30
30
341 4.30
1 31 5.24
12 22 .7 5
34 17 .9 6
1 43 6.33
30
30
30
14 29 .82
341 1.57
1 43 5.96
1 43 4.11
1 43 4.89
20
20
2 86 7.2 9
2 87 3.3 2
20
20
20
28 67.80
34 19 .9 4
2 867 .2 5
28 72.00
10
10
10
10
29 41 .2 4
10
29 42 .3 9
29 41 .4 0
17 13 .99
17 15 .29
0.0
0.0
4000.0
3000
2000
15 00
100 0
400.0
3000
2000
2 94 1.72
17 15 .34
17 14 .98
0.0
2 94 1.1 9
4000.0
15 00
cm-1
100 0
400.0
17 14 .15
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
4000.0
0.0
3000
cm-1
2000
15 00
100 0
400.0
4000.0
3000
cm-1
2000
15 00
100 0
cm-1
SJ C-0.3+0.4+0.3.pk
SJ C-0.3+0.3+0.4.pk
SJ C-0.3+0.2+0.5.pk
SJ C-0.2+0.5+0.3.pk
SJ C-0.2+0.3+0.5.pk
SJ C-03~2.SP 3601 4000.00 400.00 8.61 100.00 4.00 %T 3 1.00
SJ C-03~3.SP 3601 4000.00 400.00 6.44 100.00 4.00 %T 3 1.00
SJ C-03~4.SP 3601 4000.00 400.00 8.23 100.00 4.00 %T 3 1.00
SJ C-02~3.SP 3601 4000.00 400.00 8.43 99.99 4.00 %T 3 1.00
SJ C-02~1.SP 3601 4000.00 400.00 7.36 100.00 4.00 %T 3 1.00
REF 4000 97.90 2000 97.40 600

3951.27 95.73 3853.71 96.78 3410.86 60.84 2941.40 9.53 2867.29 24.43
2670.27 89.76 2176.78 95.54 1966.02 96.26 1713.99 8.61 1572.05 77.82
1436.33 38.17 1315.23 48.03 1222.81 46.34 1119.13 54.51 1054.92 76.65
1018.35 82.20 904.80 73.84 865.75 83.46 750.48 74.41 652.54 86.76
491.12 65.68 414.32 90.21
REF 4000 97.75 2000 96.86 600

3941.39 94.67 3832.82 96.29 3414.30 43.93 2941.19 6.44 2872.00 19.59
2669.47 87.60 2346.99 94.64 2178.62 94.45 1964.53 95.83 1715.29 9.95
1569.51 65.51 1435.96 32.09 1326.07 46.46 1223.00 50.57 1119.50 60.11
1056.70 78.21 903.19 76.24 750.92 75.18 651.80 84.95 492.53 66.99
419.41 92.10
REF 4000 99.73 2000 98.75 600

3948.44 95.86 3833.01 98.35 3417.96 41.79 2941.24 13.01 2873.32 28.04
2669.94 91.40 2347.17 96.17 2176.88 96.16 1964.66 97.58 1715.34 8.22
1569.15 61.37 1434.89 29.68 1330.60 44.83 1222.47 49.46 1175.15 67.80
1119.68 59.71 1057.84 78.62 904.02 77.02 751.18 74.53 651.73 85.37
583.55 91.19 493.13 67.20 418.26 93.49
REF 4000 98.07 2000 96.37 600

3950.92 92.90 3830.30 95.48 3776.76 94.24 3419.94 23.91 2942.39 10.92
2867.80 28.53 2670.93 91.36 2342.10 94.72 2174.27 93.72 1873.57 96.91
1714.98 8.43 1566.85 51.73 1429.82 35.93 1315.52 53.91 1222.34 52.63
1119.05 60.25 1054.36 80.66 1018.78 83.99 905.30 79.98 864.85 87.45
749.97 72.20 652.57 76.22 491.42 65.36 414.36 91.40
REF 4000 96.78 2000 95.18 600

3943.07 92.03 3777.76 94.63 3411.57 38.88 2941.72 7.36 2867.25 18.69
2670.38 82.41 2455.77 91.88 2176.67 91.37 1967.65 93.91 1871.93 94.73
1714.15 8.10 1570.65 66.73 1434.11 31.88 1315.24 42.58 1222.75 41.23
1119.05 48.96 1054.85 71.38 1018.46 77.46 904.66 69.53 865.76 80.08
750.25 68.00 652.24 79.36 491.05 58.63 415.06 85.13
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM
FTIR SPECT RUM
Date: 14-5-2010
FTIR SPECT RUM
Date: 14-5-2010
Date: 14-5-2010
100.0
4 14 .2 9
100.0
100.0
2 34 3.73
41 4.72
41 4.20
58 6.41
3 829 .3 9
90
10 17 .8 2
1 96 7.01
90
245 7.50
3 94 4.73
15 68 .5 7
21 75.94
80
37 78.36
1 87 2.91
3 828 .9 4
2 458 .0 4
1 87 2.4 0
80
8 65 .8 8
2 670 .4 4
80
21 76 .2 9
6 52 .4 1
86 5.57
10 55 .8 0
70
90
11 72 .86
1 17 2.68
18 71.91
2 670 .3 3
101 8.54
101 8.14
19 68.99
2 34 3.0 0
3 94 4.45
217 5.42
394 8.44
267 0.38
6 52 .4 1
86 5.35
10 55 .4 7
70
9 05.23
1 96 8.75
6 52 .2 2
70
9 04.93
10 55 .3 3
9 04.46
75 0.79
60
75 0.49
15 67 .7 1
60
49 1.68
75 0.12
60
49 1.45
1 11 9.34
50
49 1.29
50
%T
50
1 11 9.25
%T
1 56 2.00
%T
1 317 .3 5
40
40
1 34 6.81
12 22 .1 8
1 11 9.12
131 6.09
12 22 .4 9
40
131 6.46
12 22 .4 7
341 2.78
30
30
1 433 .4 6
30
341 4.11
1 43 4.23
1 433 .3 2
34 15 .7 2
20
20
28 68.98
28 68.71
20
28 68.76
10
10
10
29 42 .4 5
29 41 .6 9
17 15 .39
29 41 .7 8
0.0
4000.0
17 15 .00
17 15 .29
0.0
3000
2000
15 00
100 0
400.0
4000.0
0.0
3000
cm-1
2000
15 00
100 0
400.0
4000.0
3000
cm-1
2000
15 00
100 0
400.0
cm-1
SJ C-0.2+0.4+0.4.pk
SJ C-0.1+0.5+0.4.pk
SJ C-0.1+0.4+0.5.pk
SJ C-02~2.SP 3601 4000.00 400.00 8.37 100.00 4.00 %T 3 1.00
SJ C-01~1.SP 3601 4000.00 400.00 7.97 99.99 4.00 %T 3 1.00
SJ C-01~2.SP 3601 4000.00 400.00 7.99 100.00 4.00 %T 3 1.00
REF 4000 97.73 2000 96.70 600

3944.73 92.92 3829.39 95.14 3412.78 40.63 2941.69 10.02 2868.98 24.39
2670.33 85.88 2457.50 94.72 2175.94 93.51 1967.01 95.36 1871.91 95.62
1715.39 8.36 1568.57 70.95 1433.46 34.43 1346.81 47.11 1317.35 48.48
1222.18 48.02 1172.68 66.02 1119.34 56.72 1055.80 76.86 1017.82 82.55
905.23 73.74 865.88 83.76 750.79 70.37 652.41 83.03 586.41 89.54
491.68 64.38 414.29 89.37
REF 4000 97.35 2000 95.87 600

3944.45 93.13 3778.36 95.78 3414.11 35.99 2941.78 7.97 2868.76 21.04
2670.44 85.92 2343.00 92.83 2176.29 92.63 1968.99 94.78 1872.40 95.52
1715.00 8.14 1567.71 71.39 1434.23 33.44 1316.46 46.64 1222.47 46.05
1172.86 74.42 1119.25 54.73 1055.47 76.65 1018.14 82.63 904.93 73.67
865.57 83.59 750.49 69.36 652.41 81.03 491.45 61.88 414.72 87.52
REF 4000 97.46 2000 95.35 600

3948.44 88.43 3828.94 93.56 3415.72 29.30 2942.45 12.01 2868.71 27.61
2670.38 85.39 2458.04 93.31 2343.73 92.34 2175.42 91.36 1968.75 94.07
1872.91 95.54 1715.29 7.99 1562.00 59.09 1433.32 33.35 1316.09 47.37
1222.49 46.07 1119.12 53.77 1055.33 73.98 1018.54 80.27 904.46 73.25
865.35 82.71 750.12 67.53 652.22 77.64 491.29 60.94 414.20 88.92
303
400.0
Table - 7.24
Cyclohexanone + Hexane + 2-Butanone mixture
S1
(Cm-1)
3927.77
3785.81
3446.59
2941.96
2866.78
2671.11
2175.90
1713.47
1563.37
1427.09
1314.03
1222.46
1118.97
1054.65
1018.90
904.34
864.78
749.80
652.49
491.27
414.99
S10 (Cm-1)
3942.41
3822.38
3712.60
3421.53
2946.31
2876.47
2669.97
2452.71
2168.14
1727.85
1569.41
1422.18
1337.28
1222.52
1119.34
1038.28
903.90
746.93
650.49
496.64
(Cm-
S2
1
3934.64
3791.13
3431.32
2941.39
2871.00
2669.96
2345.32
2177.20
1714.66
1564.95
1435.37
1323.22
1223.03
1119.00
1055.01
903.03
749.67
651.93
492.23
419.47
S3 (Cm1
)
S4
3932.10
3785.75
3447.99
2942.53
2871.39
2670.15
2177.52
1716.75
1564.39
1433.02
1326.19
1222.90
1119.49
1057.20
902.29
749.00
651.22
493.54
421.74
3928.52
3783.01
3455.17
2941.90
2867.47
2670.99
2342.34
2177.76
1714.55
1565.60
1432.95
1315.28
1222.66
1119.10
1054.47
1018.93
905.07
865.27
750.06
652.59
491.22
414.23
S11 (Cm1
)
S12 (Cm1
)
3951.27
3853.71
3410.86
2941.40
2867.29
2670.27
2176.78
1966.02
1713.99
1572.05
1436.33
1315.23
1222.81
1119.13
1054.92
1018.35
904.80
865.75
750.48
652.54
491.12
414.32
3941.39
3832.82
3414.30
2941.19
2872.00
2669.47
2346.99
2178.62
1964.53
1715.29
1569.51
1435.96
1326.07
1223.00
1119.50
1056.70
903.19
750.92
651.80
492.53
419.41
(Cm)
S13 (Cm-1)
3948.44
3833.01
3417.96
2941.24
2873.32
2669.94
2347.17
2176.88
1964.66
1715.34
1569.15
1434.89
1330.60
1222.47
1175.15
1119.68
1057.84
904.02
751.18
651.73
583.55
493.13
418.26
S5 (Cm-1)
3928.61
3792.17
3451.01
2941.36
2867.00
2670.57
2177.81
1713.50
1563.29
1432.69
1314.76
1222.68
1118.97
1054.37
904.99
865.17
87.97
749.85
652.26
491.24
415.32
(Cm-
S6
1
3938.94
3787.12
3418.79
2939.87
2669.71
2345.83
2178.98
2071.33
1965.13
1713.81
1436.06
1324.15
1223.75
1119.14
1051.94
897.71
750.43
652.10
492.19
421.08
(Cm-
S14 (Cm1
)
*S15
3950.92
3830.30
3776.76
3419.94
2942.39
2867.80
2670.93
2342.10
2174.27
1873.57
1714.98
1566.85
1429.82
1315.52
1222.34
1119.05
1054.36
1018.78
905.30
864.85
749.97
652.57
491.42
414.36
3944.73
3829.39
3412.78
2941.69
2868.98
2670.33
2457.50*
2175.94
1967.01*
1871.91
1715.39
1568.57
1433.46
1346.81*
1317.35
1222.18
1172.68*
1119.34
1055.80
1017.82
905.23
865.88
750.79
652.41
586.41
491.68
414.29

304
S7
(Cm-1)
3879.99
3780.50
3453.98
2941.44
2867.27
2671.61
2178.12
1713.96
1565.53
1431.86
1315.13
1222.43
1119.05
1054.38
905.19
864.75
749.87
652.33
491.33
416.80
S8
(Cm)
3915.77
3781.01
3456.52
2941.78
2868.11
2670.37
2338.02
2176.60
1873.58
1714.49
1564.86
1429.99
1316.69
1222.47
1172.78
1119.22
1055.00
1018.59
905.19
865.16
750.22
652.51
586.51
491.95
414.48
*S9
(Cm-
3879.98
3778.85
3459.55
2941.75
2868.07
2670.91
2338.96
2177.85
1874.69
1715.54
1566.09
1432.57
1345.44*
1316.80
1222.26
1172.67
1119.30
1055.39
1018.18
905.48
865.33
750.41
652.43
586.83
491.72
415.48
S16 (Cm1
)
S17 (Cm1
)
S18 (Cm1
)
3943.07
3777.76
3411.57
2941.72
2867.25
2670.38
2455.77
2176.67
1967.65
1871.93
1714.15
1570.65
1434.11
1315.24
1222.75
1119.05
1054.85
1018.46
904.66
865.76
750.25
652.24
491.05
415.06
3944.45
3778.36
3414.11
2941.78
2868.76
2670.44
2343.00
2176.29
1968.99
1872.40
1715.00
1567.71
1434.23
1316.46
1222.47
1172.86
1119.25
1055.47
1018.14
904.93
865.57
750.49
652.41
491.45
414.72
3948.44
3828.94
3415.72
2942.45
2868.71
2670.38
2458.04
2343.73
2175.42
1968.75
1872.91
1715.29
1562.00
1433.32
1316.09
1222.49
1119.12
1055.33
1018.54
904.46
865.35
750.12
652.22
491.29
414.20
Fig-7.24: FTIR Spectrums for Cyclohexanone+Hexane+Ethyl Acetate mixture:

ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 17-6-2010
Spectrum Name: II-0.5+0.4+0.1.s p
FTIR SPECT RUM

Date: 17-6-2010
100.0
4 18 .7 1
ACIC
Trichy-2
FTIR SPECT RUM

Date: 17-6-2010
100.0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 17-6-2010
FTIR SPECT RUM

Date: 17-6-2010
100.0
100.0
100.0
425 .6 3
90
3 89 2.1 1
90
26 69 .5 3
90
2 074 .4 1
39 03 .7 3
90
2 08 0.52
42 1.72
20 81.80
80
26 68 .6 3
2 66 9.7 5
2 669 .5 9
80
80
6 51 .7 3
89 7.0 0
90 0.30
90
2 07 7.60
2 07 7.36
266 5.99
3 77 9.91
80
80
89 8.1 7
10 51 .4 3
6 47 .7 2
70
74 9.72
10 51 .7 6
70
70
9 02.72
70
49 1.83
6 51 .2 6
74 8.28
49 3.18
1 11 8.53
60
8 91 .0 7
70
6 49 .3 6
74 7.44
6 48 .8 4
60
10 53 .0 2
60
1 11 8.72
74 8.69
60
49 2.57
10 57 .58
74 9.35
1 05 4.9 8
13 21 .92
132 1.25
1 22 5.20
50
%T
11 16 .6 3
132 0.60
50
49 4.14
60
49 2.25
1 11 7.62
122 6.98
50
%T
1 11 7.81
50
%T
50
%T
%T
132 1.54
40
40
1 433 .3 4
40
1 43 7.33
40
1 43 5.88
40
13 25 .7 5
1 43 8.50
30
30
28 72 .4 9
30
3 429 .4 3
20
171 2.60
30
1 43 7.55
12 33 .88
20
10
29 40 .2 0
17 14 .02
294 0.97
20
28 70 .9 5
3 428 .3 2
3 458 .6 5
10
34 47.47
34 41.46
30
20
10
29 40 .4 7
12 36 .0 8
2 87 3.48
20
10
12 32 .42
17 14 .55
10
29 41 .8 5
17 15 .62
0.0
0.0
4000.0
3000
2000
15 00
100 0
400.0
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
29 41 .6 2
0.0
4000.0
3000
2000
15 00
cm-1
100 0
400.0
17 15 .20
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
4000.0
3000
2000
cm-1
15 00
100 0
II-0.5+0.3+0.2.pk
II-0.5+0.2+0.3.pk
II-0.5+0.1+0.4.pk
II-0.4+0.5+0.1.pk
II-05_~1.SP 3601 4000.00 400.00 10.54 100.00 4.00 %T 3 1.00
II-05_~2.SP 3601 4000.00 400.00 12.73 100.00 4.00 %T 3 1.00
II-05_~3.SP 3601 4000.00 400.00 11.41 99.99 4.00 %T 3 1.00
II-05_~4.SP 3601 4000.00 400.00 9.43 100.00 4.00 %T 3 1.00
II-04_~2.SP 3601 4000.00 400.00 8.48 99.92 4.00 %T 3 1.00
REF 4000 99.54 2000 97.02 600

3892.11 95.99 3441.46 11.77 2940.47 14.06 2872.49 36.90 2669.53 96.35
2080.52 94.02 1712.60 10.53 1433.34 46.19 1321.92 60.84 1226.98 56.68
1118.53 67.72 1051.43 81.27 897.00 83.43 748.28 67.32 651.26 69.65
493.18 67.58
REF 4000 99.66 2000 98.24 600

3429.43 33.01 2940.20 12.74 2873.48 31.79 2669.59 95.07 2074.41 96.46
1714.02 12.73 1437.33 46.04 1321.25 55.65 1225.20 55.07 1118.72 64.52
1051.76 79.75 900.30 81.53 749.72 77.47 651.73 85.14 491.83 72.65
418.71 96.08
REF 4000 99.21 2000 96.75 600

3447.47 13.80 2940.97 14.63 2669.75 95.13 2081.80 93.88 1714.55 11.40
1435.88 45.22 1320.60 56.75 1236.08 34.46 1117.62 64.06 1053.02 67.33
898.17 81.84 748.69 68.01 648.84 69.85 492.57 65.37
REF 4000 99.19 2000 97.31 600

3903.73 97.71 3779.91 87.12 3458.65 15.67 2941.85 10.19 2870.95 27.16
2668.63 93.92 2077.36 94.59 1715.62 9.43 1438.50 40.02 1321.54 50.81
1233.88 30.79 1117.81 57.71 1054.98 64.19 902.72 77.72 749.35 67.98
649.36 73.31 492.25 62.35 421.72 88.37
REF 4000 99.82 2000 97.90 600

3428.32 22.80 2941.62 8.58 2665.99 94.01 2077.60 95.25 1715.20 8.48
1437.55 35.96 1325.75 45.68 1232.42 41.60 1116.63 60.07 1057.58 71.24
891.07 76.98 747.44 72.60 647.72 79.84 494.14 66.25 425.63 92.22
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 17-6-2010
100.0
90
2 669 .5 7
2 458 .3 4
2 66 8.75
2 341 .0 8
4 13.61
26 68.67
1 05 2.49
80
13 24 .2 5
8 64 .45
70
74 9.13
6 50 .9 2
88 8.3 0
70
70
49 2.04
1 11 7.57
396 2.41
49 2.27
60
9 04.50 75 0.44
60
1 11 8.37
60
123 0.42
1 43 7.02
13 26 .2 2
4 99 .3 0
28 70.58
50
%T
50
%T
7 41 .87
1 43 5.70
122 9.04
40
40
40
1 11 8.48
142 5.06
40
6 48 .9 9
1 31 3.64
30
30
30
28 77.47
30
14 42 .8 6
30
2 873 .1 3
20
4 98.79
64 9.82
49 1.29
50
%T
10 53 .2 3
1 43 6.00
7 40 .76
12 26 .9 4
11 16 .0 0
60
1 05 5.52
132 0.55
50
%T
40
2 08 0.46
10 39 .5 1
2 34 7.4 12 08 0.88
1 87 2.4 6
6 51 .0 7
74 8.53
1 11 8.11
132 0.95
50
90
2 676 .7 2
38 80 .7 4
80
90 1.76
70
6 51 .0 4
1 05 2.38
60
100.0
38 25 .2 2
90
2 670 .4 4
3 77 6.04
80
89 8.1 6
70
100.0
19 70.29
21 76 .51
3 78 2.7 4
80
%T
FTIR SPECT RUM

Date: 17-6-2010
2 33 5.0 7 20 66.83
39 28 .0 7
90
2 07 8.29
2 081 .3 4
80
FTIR SPECT RUM

Date: 17-6-2010
100.0
90
ACIC
Trichy-2
FTIR SPECT RUM

Date: 17-6-2010
100.0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 17-6-2010
400.0
cm-1
II-0.5+0.4+0.1.pk
1 23 8.95
20
341 3.97
20
29 42 .3 7
20
20
12 33 .61
34 45.73
10
2 86 6.83
10
34 49 .9 7
10
29 41 .2 9
29 40 .7 6
3000
2000
15 00
100 0
400.0
4000.0
3000
2000
15 00
100 0
400.0
0.0
4000.0
17 13 .35
17 14 .01
0.0
cm-1
29 41 .0 0
10
17 13 .37
29 41 .6 5
0.0
4000.0
1 64 2.9 2
10
17 14 .49
17 14 .47
0.0
3000
2000
cm-1
15 00
100 0
400.0
4000.0
34 40.05
0.0
341 5.84
3000
2000
cm-1
15 00
100 0
400.0
4000.0
3000
2000
cm-1
15 00
100 0
II-0.4+0.3+0.3.pk
II-0.4+0.2+0.4.pk
II-0.4+0.1+0.5.pk
II-0.3+0.5+0.2.pk
II-04_~1.SP 3601 4000.00 400.00 9.60 100.00 4.00 %T 3 1.00
II-04_~3.SP 3601 4000.00 400.00 10.33 99.81 4.00 %T 3 1.00
II-04_~4.SP 3601 4000.00 400.00 8.31 99.99 4.00 %T 3 1.00
II5C66~1.SP 3601 4000.00 400.00 6.35 99.20 4.00 %T 3 1.00
II-03_~1.SP 3601 4000.00 400.00 7.96 99.96 4.00 %T 3 1.00
REF 4000 99.86 2000 97.10 600

3449.97 12.99 2941.29 11.14 2669.57 95.67 2341.08 96.65 2081.34 94.27
1714.47 9.59 1436.00 45.77 1320.95 57.65 1230.42 47.28 1118.11 64.73
1052.38 75.20 898.16 82.88 748.53 69.99 651.04 73.87 492.27 70.29
REF 4000 99.49 2000 97.98 600

3782.74 90.20 3445.73 20.44 2940.76 12.12 2873.13 32.93 2668.75 95.94
2078.29 96.16 1714.49 10.33 1437.02 47.47 1320.55 57.98 1229.04 49.32
1118.37 65.05 1052.49 76.98 901.76 83.41 749.13 74.82 651.07 79.66
492.04 71.98
REF 4000 97.42 2000 96.27 600

3928.07 96.14 3776.04 89.59 3413.97 27.54 2941.65 8.31 2866.83 19.50
2670.44 88.41 2458.34 96.38 2335.07 95.60 2176.51 93.66 2066.83 93.08
1970.29 94.93 1872.46 94.87 1714.01 8.95 1442.86 34.27 1313.64 41.61
1233.61 21.46 1118.48 46.22 1053.23 51.64 904.50 67.82 864.45 79.02
750.44 66.04 650.92 78.34 491.29 59.01 413.61 86.68
REF 4000 99.20 2000 93.16 600

3962.41 72.69 3880.74 96.45 3825.22 95.65 3415.84 6.35 2942.37 26.62
2870.58 56.63 2676.72 95.78 2347.41 88.49 2080.88 87.23 1713.37 12.25
1642.92 17.62 1425.06 44.56 1324.25 68.36 1238.95 30.16 1116.00 66.99
1055.52 64.88 741.87 49.84 648.99 45.25 499.30 59.20
REF 4000 99.89 2000 96.26 600

3440.05 7.96 2941.00 15.90 2877.47 41.24 2668.67 97.07 2080.46 93.04
1713.35 11.50 1435.70 51.04 1326.22 64.14 1226.94 70.52 1117.57 73.41
1039.51 87.11 888.30 86.69 740.76 68.35 649.82 68.86 498.79 70.63
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM
FTIR SPECT RUM
FTIR SPECT RUM
FTIR SPECT RUM
Date: 17-6-2010
Date: 17-6-2010
Date: 17-6-2010
Date: 17-6-2010
100.0
100.0
FTIR SPECT RUM

Date: 17-6-2010
100.0
400.0
cm-1
II-0.4+0.4+0.2.pk
100.0
100.0
4 24 .02
90
90
3 93 3.85
90
2 07 8.83
39 37.63
20 81.34
90
26 69 .3 4
26 69 .3 0
90
39 27 .8 5
2 08 0.05
26 70 .0 5
2 67 1.22
20 81.78
2 66 9.7 1
2 08 0.63
3 92 9.90
80
80
2 34 9.9 0
80
37 83 .5 1
80
2 342 .9 0
9 02.41
9 02.76
90 0.94
70
80
70
89 7.1 2
70
70
49 1.88
60
49 2.70
89 5.0 3
6 49 .8 5
74 9.99
6 49 .9 3
74 7.80
49 3.82
1 05 5.13
60
10 52 .1 0
1 11 8.07
60
1 11 7.61
10 52.81
70
10 52 .0 7
6 49 .3 9
74 9.61
60
6 50 .4 1
74 8.41
49 3.13
1 11 8.47
60
13 22 .22
1 11 7.55
1 11 7.82
50
132 1.52
50
%T
74 7.25
49 4.00
132 1.15
50
%T
10 50 .8 0
50
%T
50
%T
6 50 .7 6
122 9.92
%T
132 0.89
132 1.64
1 43 4.87
40
40
40
40
1 43 7.18
40
1 43 4.67
12 34 .06
1 43 7.60
30
30
1 43 6.71
12 34 .73
30
2 87 0.49
30
1 64 7.0 8
30
28 73 .4 5
12 35 .7 6
20
34 23 .0 1
20
12 36 .8 6
10
20
10
29 40 .6 7
29 40 .2 9
3000
2000
15 00
100 0
400.0
17 14 .43
3000
2000
cm-1
15 00
100 0
400.0
4000.0
20
29 40 .7 3
2000
15 00
100 0
400.0
4000.0
cm-1
17 14 .75
17 13 .78
0.0
3000
cm-1
29 41 .9 1
10
3 43 6.37
3 454 .2 8
0.0
4000.0
10
29 41 .5 1
17 16 .2 2
17 16 .2 0
0.0
4000.0
20
10
3 43 3.03
0.0
0.0
3000
2000
15 00
100 0
400.0
34 38 .3 3
4000.0
cm-1
3000
2000
15 00
100 0
cm-1
II-0.3+0.4+0.3.pk
II-0.3+0.3+0.4.pk
II-0.3+0.2+0.5.pk
II-0.2+0.5+0.3.pk
II-0.2+0.4+0.4.pk
II-03_~2.SP 3601 4000.00 400.00 9.04 100.00 4.00 %T 3 1.00
II-03_~3.SP 3601 4000.00 400.00 10.22 100.00 4.00 %T 3 1.00
II-03_~4.SP 3601 4000.00 400.00 7.99 99.95 4.00 %T 3 1.00
II-02_~3.SP 3601 4000.00 400.00 11.44 100.00 4.00 %T 3 1.00
II-02_~2.SP 3601 4000.00 400.00 6.35 99.99 4.00 %T 3 1.00
REF 4000 99.01 2000 96.54 600

3933.85 93.10 3783.51 84.94 3433.03 11.69 2940.29 9.27 2669.71 93.22
2081.34 92.81 1716.20 9.04 1436.71 35.96 1321.64 48.39 1236.86 25.98
1117.55 58.50 1050.80 59.00 900.94 77.65 749.61 66.42 649.39 71.54
492.70 63.10
REF 4000 99.48 2000 97.92 600

3937.63 95.10 3423.01 28.17 2940.67 10.22 2669.30 93.58 2342.90 96.75
2078.83 95.36 1716.22 11.15 1437.60 39.91 1320.89 50.40 1235.76 30.04
1117.82 59.69 1052.10 63.20 902.76 79.41 749.99 74.40 649.85 80.86
491.88 68.84 424.02 93.79
REF 4000 99.78 2000 96.45 600

3454.28 7.99 2941.51 14.43 2870.49 35.29 2669.34 95.75 2349.90 96.16
2080.05 92.87 1714.43 11.76 1647.08 37.48 1437.18 47.02 1321.52 59.69
1234.73 37.89 1117.61 64.96 1055.13 70.62 902.41 83.62 747.80 66.40
649.93 68.45 493.82 67.96
REF 4000 99.55 2000 96.55 600

3927.85 96.56 3436.37 11.44 2940.73 15.92 2873.45 37.07 2670.05 95.79
2081.78 93.32 1713.78 11.76 1434.67 46.45 1321.15 59.50 1234.06 43.40
1118.07 66.45 1052.07 73.76 897.12 83.08 748.41 66.72 650.41 68.99
493.13 67.13
REF 4000 99.29 2000 95.23 600

3929.90 89.76 3438.33 6.35 2941.91 16.94 2671.22 95.45 2080.63 91.51
1714.75 13.36 1434.87 48.11 1322.22 61.05 1229.92 52.70 1118.47 66.67
1052.81 78.27 895.03 82.96 747.25 61.49 650.76 61.51 494.00 61.43
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 17-6-2010
FTIR SPECT RUM

Date: 17-6-2010
90
100.0
90
2 34 4.5 1
2 07 6.52
80
100.0
42 1.94
3 94 0.58
FTIR SPECT RUM

Date: 17-6-2010
100.0
90
26 72 .03
3 92 8.6 1
20 85.27
80
26 69 .43
2 670 .7 4
20 87.90
80
3 93 3.26
2 34 9.2 6
10 53 .4 2
6 50 .0 3
70
70
9 02.61
70
1 11 7.82
13 23 .47
75 0.12
49 4.42
60
4 96.62
60
49 2.03
12 34 .44
10 51 .5 0
11 17 .3 0
60
1 32 1.16
742 .8 9
10 54 .27
74 7.54
6 48 .7 8
14 30 .48
50
50
1 11 8.02
%T
50
6 49 .8 0
%T
%T
1 433 .5 1
40
40
40
132 1.29
30
30
30
1 43 8.31
20
1 644 .4 5
20
17 13 .58
10
2 94 0.2 5
4000.0
1 23 8.01
29 42 .2 2
20
12 35 .1 9
34 70.79
10
17 16 .7 2
0.0
0.0
3000
2000
15 00
100 0
400.0
10
4000.0
cm-1
II-0.2+0.3+0.5.pk
29 43 .0 1
17 16 .3 7
34 45.13
3 441 .7 8
0.0
3000
2000
15 00
100 0
400.0
4000.0
cm-1
II-0.1+0.5+0.4.pk
3000
2000
15 00
100 0
400.0
cm-1
II-0.1+0.4+0.5.pk
II-02_~1.SP 3601 4000.00 400.00 7.51 100.00 4.00 %T 3 1.00
II-01_~2.SP 3601 4000.00 400.00 6.33 99.99 4.00 %T 3 1.00
II-01_~1.SP 3601 4000.00 400.00 7.98 100.00 4.00 %T 3 1.00
REF 4000 99.01 2000 97.21 600

3940.58 96.76 3470.79 18.71 2940.25 7.51 2669.43 91.92 2344.51 95.91
2076.52 94.43 1716.72 8.73 1438.31 31.69 1321.29 41.67 1235.19 23.71
1118.02 53.22 1051.50 57.90 902.61 74.18 750.12 69.96 650.03 78.86
492.03 62.46 421.94 92.09
REF 4000 99.19 2000 95.33 600

3928.61 94.91 3441.78 6.33 2942.22 27.15 2672.03 97.64 2087.90 91.53
1713.58 19.06 1644.45 33.74 1430.48 59.26 1323.47 74.31 1234.44 60.72
1117.82 75.41 1053.42 81.51 742.89 62.74 649.80 59.88 496.62 67.04
REF 4000 100.00 2000 96.38 600

3933.26 87.64 3445.13 7.98 2943.01 13.62 2670.74 96.22 2349.26 93.97
2085.27 92.19 1716.37 13.14 1433.51 49.31 1321.16 64.71 1238.01 32.96
1117.30 68.09 1054.27 67.52 747.54 65.20 648.78 64.29 494.42 69.10
305
400.0
Table - 7.25
Cyclohexanone + Hexane + Ethyl Acetate mixture
*S8
(Cm-1)
S1
(Cm-1)
S2
(Cm-1)
S3
(Cm-1)
S4
(Cm-1)
S5
(Cm-1)
S6
(Cm-1)
3892.11
3441.46
2940.47
2872.49
2669.53
2080.52
1712.60
1433.34
1321.92
1226.98
1118.53
1051.43
897.00
748.28
651.26
493.18
3429.43
2940.20
2873.48
2669.59
2074.41
1714.02
1437.33
1321.25
1225.20
1118.72
1051.76
900.30
749.72
651.73
491.83
418.71
3447.47
2940.97
2669.75
2081.80
1714.55
1435.88
1320.60
1236.08
1117.62
1053.02
898.17
748.69
648.84
492.57
3903.73
3779.91
3458.65
2941.85
2870.95
2668.63
2077.36
1715.62
1438.50
1321.54
1233.88
1117.81
1054.98
902.72
749.35
649.36
492.25
421.72
3428.32
2941.62
2665.99
2077.60
1715.20
1437.55
1325.75
1232.42
1116.63
1057.58
891.07
747.44
647.72
494.14
425.63
3449.97
12.99
941.29
2669.57
2341.08
2081.34
1714.47
1436.00
1320.95
1230.42
1118.11
1052.38
898.16
748.53
651.04
492.27
S10
(Cm-1)
S11
(Cm-1)
S12
(Cm-1)
* S13
(Cm-1)
S14
(Cm-1)
S15
(Cm-1)
S16
(Cm-1)
S17
(Cm-1)
S18
(Cm-1)
3440.05
2941.00
2877.47
2668.67
2080.46
1713.35
1435.70
1326.22
1226.94
1117.57
1039.51
888.30
740.76
649.82
498.79
3933.85
3783.51
3433.03
2940.29
2669.71
2081.34
1716.20
1436.71
1321.64
1236.86
1117.55
1050.80
900.94
749.61
649.39
492.70
3937.63
3423.01
2940.67
2669.30
2342.90
2078.83
1716.22
1437.60
1320.89
1235.76
1117.82
1052.10
902.76
749.99
649.85
491.88
424.02
3454.28
2941.51
2870.49
2669.34
2349.90
2080.05
1714.43
1647.08
1437.18
1321.52
1234.73
1117.61
1055.13
902.41
747.80
649.93
493.82
3927.85
3436.37
2940.73
2873.45
2670.05
2081.78
1713.78
1434.67
1321.15
1234.06
1118.07
1052.07
897.12
748.41
650.41
493.13
3929.90
3438.33
2941.91
2671.22
2080.63
1714.75
1434.87
1322.22
1229.92
1118.47
1052.81
895.03
747.25
650.76
494.00
3940.58
3470.79
2940.25
2669.43
2344.51
2076.52
1716.72
1438.31
1321.29
1235.19
1118.02
1051.50
902.61
750.12
650.03
492.03
421.94
3928.61
3441.78
2942.22
2672.03
2087.90
1713.58
1644.45
1430.48
1323.47
1234.44
1117.82
1053.42
742.89
649.80
496.62
3933.26
3445.13
2943.01
2670.74
2349.26
2085.27
1716.37
1433.51
1321.16
1238.01
1117.30
1054.27
747.54
648.78
494.42

306
S7
(Cm-1)
3782.74
3445.73
2940.76
2873.13
2668.75
2078.29
1714.49
1437.02
1320.55
1229.04
1118.37
1052.49
901.76
749.13
651.07
492.04
3928.07
3776.04
3413.97
2941.65
2866.83
2670.44
2458.34*
2335.07*
2176.51*
2066.83
1970.29*
1872.46*
1714.01
1442.86
1313.64
1233.61
1118.48
1053.23
904.50
864.45*
750.44
650.92
S9
(Cm-1)
3962.41
3880.74
3825.22
3415.84
2942.37
2870.58
2676.72
2347.41
2080.88
1713.37
1642.92
1425.06
1324.25
1238.95
1116.00
1055.52
741.87
648.99
499.30
Fig-7.25: FTIR Spectrum for Cyclohexanone + Heptane + 2-Butanone mixture:

ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
Spectrum Name: K-0.5+0.4+0.1.sp
100.0
90
21 77 .81
37 90 .16
2 670 .3 7
37 89 .6 9
80
89 6.3 5
1 05 0.6 6
6 51 .5 7
74 7.97
6 49 .1 0
90 0.51
70
75 0.13
6 51 .9 8
2 66 9.8 7
6 48 .8 2
89 4.6 4
70
70
74 9.25
1 042 .0 9
89 7.8 0 75 0.46
15 78.58
49 2.68
60
49 1.60
60
49 1.53
1 22 4.49
1 57 2.28
60
1 11 9.21
1 05 1.2 5
49 1.83
15 78.02
1 12 0.34
50
12 22 .7 5
13 24 .6 0
50
12 23 .1 3
%T
60
49 4.07
1 11 9.07
13 24 .44
%T
%T
50
1 11 9.07
50
1 57 3.60
%T
%T
12 24.33
13 23 .23
1 574 .7 1
40
39 40.31
80
1 05 0.7 9
1 11 8.41
60
50
4 19 .2 2
21 79 .43
1 96 3.83
37 89.34
196 2.54
26 69 .4 4
6 51 .2 3
90 3.28 74 9.93
70
90
20 79 .9 5
37 85 .5 4
80
2 67 0.55
1 04 5.71
70

100.0
4 27.00
3 90 8.21
90
21 79 .10
42 5.55
196 6.64
80
FTIR SPECT RUM

Date: 16-6-2010

100.0
4 26 .9 6
392 1.77
90
2 07 6.42
3 786 .9 3
2 67 1.46
80
FTIR SPECT RUM

Date: 16-6-2010

100.0
39 10.00
3 927 .8 6
90
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
100.0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
1 22 4.00
40
40
40
40
13 27 .5 8
341 4.34
34 24 .9 9
1 432 .5 2
30
13 24 .42
1 43 5.16
30
1 43 4.25
30
30
30
34 23 .9 3
1 43 4.92
20
20
3 43 1.92
10
20
10
20
10
171 3.01
29 41 .1 9
3000
2000
15 00
100 0
400.0
10
3000
2000
15 00
100 0
400.0
2 94 0.68
0.0
4000.0
17 13 .60
17 16 .1 6
29 41 .2 1
0.0
4000.0
cm-1
20
17 15 .03
29 40 .9 7
0.0
4000.0
3 429 .8 5
10
17 14 .75
29 39 .6 0
0.0
1 43 5.79
3000
2000
cm-1
15 00
100 0
400.0
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
cm-1
K-0.5+0.4+0.1.pk
K-0.5+0.3+0.2.pk
K-0.5+0.2+0.3.pk
K-0.5+0.1+0.4.pk
K-0.4+0.5+0.1.pk
K-05_0~2.SP 3601 4000.00 400.00 9.82 99.90 4.00 %T 3 1.00
K-05_0~4.SP 3601 4000.00 400.00 10.23 99.76 4.00 %T 3 1.00
K-05_0~1.SP 3601 4000.00 400.00 8.75 100.00 4.00 %T 3 1.00
K-05_0~3.SP 3601 4000.00 400.00 8.54 99.97 4.00 %T 3 1.00
K-04_0~4.SP 3601 4000.00 400.00 7.28 100.00 4.00 %T 3 1.00
REF 4000 99.17 2000 98.33 600

3927.86 97.62 3790.16 93.89 3431.92 25.82 2939.60 9.82 2671.46 93.03
2177.81 96.75 1713.01 12.78 1574.71 51.30 1432.52 38.27 1324.44 56.65
1224.49 62.53 1118.41 68.52 1045.71 80.98 896.35 83.59 747.97 77.57
649.10 77.48 492.68 66.69
REF 4000 97.55 2000 96.74 600

3910.00 95.60 3786.93 91.42 3424.99 40.85 2941.19 10.60 2670.37 90.02
2076.42 95.29 1966.64 95.90 1714.75 10.23 1578.58 69.76 1435.16 37.39
1323.23 49.60 1223.13 53.11 1119.07 60.85 1050.79 77.48 900.51 77.23
750.13 75.49 651.57 83.89 491.53 65.50 425.55 89.97
REF 4000 99.23 2000 98.37 600

3921.77 96.69 3789.69 91.84 3423.93 32.60 2940.97 8.75 2670.55 89.90
2179.10 96.60 1715.03 10.38 1572.28 64.52 1434.25 37.82 1324.60 52.74
1222.75 56.65 1119.21 64.61 1050.66 81.78 903.28 81.96 749.93 78.31
651.23 84.13 491.60 68.24 426.96 91.12
REF 4000 98.04 2000 97.28 600

3908.21 96.15 3785.54 90.33 3429.85 23.73 2941.21 8.54 2669.44 89.09
2079.95 95.38 1962.54 96.49 1716.16 10.22 1573.60 53.11 1434.92 28.75
1327.58 44.24 1224.33 53.20 1120.34 61.64 1042.09 77.27 894.64 78.25
749.25 74.91 648.82 80.41 494.07 64.16 427.00 89.24
REF 4000 99.33 2000 98.32 600

3940.31 96.10 3789.34 95.35 3414.34 42.10 2940.68 7.28 2669.87 84.64
2179.43 95.50 1963.83 96.77 1713.60 12.96 1578.02 66.37 1435.79 28.76
1324.42 41.48 1224.00 47.47 1119.07 56.32 1051.25 72.17 897.80 71.50
750.46 72.61 651.98 85.08 491.83 63.74 419.22 93.12
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
FTIR SPECT RUM

Date: 16-6-2010
100.0
100.0
100.0
4 20.72
42 0.48
39 32.99
90
217 9.02
37 89 .4 1
1 96 5.25
21 82 .1 2
37 87 .9 5
90
21 78 .76
90
37 82.97
2 34 5.2 1
90
1 96 3.79
2 34 5.4 2
1 96 5.21
3 94 0.88
37 93 .3 4
3 928 .2 8
80
FTIR SPECT RUM

Date: 16-6-2010
100.0
4 23 .6 1
1 96 4.93
90
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
100.0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
39 35 .5 2
26 70 .4 6
2 67 0.15
80
2 17 8.74
6 51 .6 5
80
2 66 9.9 8
21 78 .2 3
39 39 .3 5
80
6 51 .5 0
70
70
75 0.07
1 05 0.6 4
10 46.46
60
1 11 9.31
70
70
75 0.88
70
9 04.43
89 8.8 5
75 0.89
104 9.50
60
49 2.56
75 0.38
1 05 1.31
10 52 .4 4
60
49 2.57
49 1.91
60
49 2.57
1 11 9.06
15 74 .3 6
50
6 49 .3 6
74 8.74
89 6.5 3
49 1.72
60
6 52 .0 2
2 66 9.8 6
2 66 9.78
89 7.4 2
90 0.45
80
6 52 .1 5
1 11 9.13
12 23 .4 1
50
%T
1 11 9.13
50
%T
1 11 9.70
50
%T
50
%T
15 71.88
%T
12 23 .1 7
1 57 3.96
40
13 27 .8 4
1 22 5.12
40
13 24 .45
12 22 .4 3
40
12 23 .6 2
40
40
34 20 .3 8
13 25 .9 1
13 26 .4 8
30
30
34 20 .1 8
30
30
30
34 22 .5 2
1 43 4.77
34 17 .9 5
1 432 .9 7
20
20
10
1 43 6.94
20
3 429 .4 5
10
2000
1 43 4.72
20
10
10
17 14 .08
29 40 .4 1
15 00
100 0
400.0
17 13 .52
2 93 8.54
17 14 .52
0.0
3000
1 43 5.12
20
10
17 13 .81
29 40 .9 9
0.0
4000.0
133 5.01
29 40 .5 7
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
17 15 .76
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
2 94 1.00
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
cm-1
K-0.4+0.4+0.2.pk
K-0.4+0.3+0.3.pk
K-0.4+0.2+0.4.pk
K-0.4+0.1+0.5.pk
K-0.3+0.5+0.2.pk
K-04_0~3.SP 3601 4000.00 400.00 8.00 100.00 4.00 %T 3 1.00
K-04_0~2.SP 3601 4000.00 400.00 7.64 99.90 4.00 %T 3 1.00
K-3DF8~1.SP 3601 4000.00 400.00 7.49 99.92 4.00 %T 3 1.00
K-04_0~1.SP 3601 4000.00 400.00 7.71 100.00 4.00 %T 3 1.00
K-03_0~1.SP 3601 4000.00 400.00 7.38 100.00 4.00 %T 3 1.00
REF 4000 99.23 2000 98.31 600

3928.28 97.12 3789.41 94.26 3420.18 32.19 2940.99 8.00 2670.15 88.97
2179.02 96.30 1964.93 97.41 1713.81 10.65 1574.36 61.29 1434.77 32.15
1324.45 47.04 1223.17 52.20 1119.06 60.14 1050.64 76.91 900.45 77.75
750.07 75.44 651.50 83.69 491.72 66.40 423.61 92.14
REF 4000 98.11 2000 97.27 600

3932.99 97.00 3793.34 93.61 3429.45 23.44 2940.41 7.64 2670.46 90.96
2178.76 95.19 1714.52 8.80 1573.96 48.63 1432.97 31.01 1327.84 49.24
1223.41 56.27 1119.31 63.99 1046.46 78.38 897.42 80.35 748.74 75.72
649.36 78.36 492.56 64.76
REF 4000 99.78 2000 98.87 600

3935.52 97.82 3787.95 95.14 3420.38 44.36 2938.54 7.49 2669.98 87.49
2182.12 97.01 1965.25 97.69 1714.08 10.56 1436.94 30.32 1326.48 40.34
1225.12 47.69 1119.13 57.37 1049.50 72.60 896.53 71.96 750.88 75.38
651.65 88.20 492.57 65.54
REF 4000 99.37 2000 98.60 600

3939.35 98.30 3782.97 95.53 3422.52 34.32 2940.57 7.71 2669.78 89.42
2345.21 96.10 2178.23 96.51 1963.79 97.33 1715.76 8.45 1435.12 28.42
1335.01 40.96 1222.43 47.63 1119.70 57.17 1052.44 75.66 904.43 74.39
750.89 72.98 652.15 85.39 492.57 64.82 420.48 93.12
REF 4000 99.31 2000 98.39 600

3940.88 97.51 3417.95 33.69 2941.00 7.38 2669.86 87.62 2345.42 96.99
2178.74 95.74 1965.21 97.00 1713.52 10.84 1571.88 58.34 1434.72 28.05
1325.91 43.04 1223.62 48.99 1119.13 57.91 1051.31 74.24 898.85 74.30
750.38 73.48 652.02 84.58 491.91 65.77 420.72 93.08
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM
FTIR SPECT RUM
Date: 16-6-2010
Date: 16-6-2010
100.0
90
2 180 .1 3
6 51 .4 0
234 8.64
FTIR SPECT RUM
100.0
42 8.14
90
21 78 .21
3 78 9.03
21 79 .8 4
2 34 3.2 6
37 82.24
90
1 96 5.92
2 10 4.10
2 67 1.13
2 17 8.69
6 51 .0 6
2 67 0.0 6
80
100.0
1 050 .8 7
39 37.80
90
39 43.56
2 66 9.64
Date: 16-6-2010
100.0
1 96 4.98
3 94 7.7 2
80
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
100.0
90
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
80
80
90 4.72
80
3 94 3.9 2
2 67 1.36
37 86.76
9 04.89
26 70.35
6 51 .0 5
89 7.4 8
74 9.82
70
89 7.7 2 75 0.66
70
1 04 8.33
60
1 11 9.68
74 9.81
70
90 2.02
70
6 51 .3 1
1 04 8.26
70
10 50 .5 9
74 9.97
10 49.65
49 2.57
60
49 3.15
49 2.07
1 11 9.82
1 11 9.54
60
1 12 0.29
60
1 57 2.30
60
74 8.22
6 50 .7 1
12 21 .6 4
49 3.63
12 21 .9 7
12 23 .5 7
50
50
%T
1 11 9.32
50
12 23 .4 2
%T
49 2.18
50
133 3.54
%T
13 38 .7 2
50
%T
%T
12 23 .2 4
13 28 .8 2
1 57 1.43
40
40
40
1 33 1.72
40
40
13 28 .5 8
1 568 .4 8
30
3 430 .9 3
34 25 .2 8
30
1 43 6.36
1 433 .5 1
30
1 43 5.72
20
20
10
20
10
3000
2000
15 00
100 0
400.0
1 433 .0 3
3000
2000
cm-1
15 00
100 0
400.0
20
10
17 15 .95
17 13 .95
29 41 .4 8
0.0
4000.0
34 23 .5 7
10
17 14 .55
29 39 .8 1
0.0
4000.0
30
14 29 .48
20
10
17 15 .30
29 41.02
0.0
30
3 430 .7 2
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
4000.0
cm-1
17 17 .8 2
34 45.99
29 41 .7 7
3000
29 44.90
0.0
2000
15 00
100 0
400.0
4000.0
cm-1
3000
2000
15 00
100 0
cm-1
K-0.3+0.4+0.3.pk
K-0.3+0.3+0.4.pk
K-0.3+0.2+0.5.pk
K-0.2+0.5+0.3.pk
K-0.1+0.5+0.4.pk
K-03_0~2.SP 3601 4000.00 400.00 7.51 100.00 4.00 %T 3 1.00
K-03_0~3.SP 3601 4000.00 400.00 7.65 99.93 4.00 %T 3 1.00
K-03_0~4.SP 3601 4000.00 400.00 9.73 100.00 4.00 %T 3 1.00
K-02_0~3.SP 3601 4000.00 400.00 7.30 100.00 4.00 %T 3 1.00
K-01_0~1.SP 3601 4000.00 400.00 7.26 99.83 4.00 %T 3 1.00
REF 4000 99.73 2000 98.89 600

3947.72 98.61 3430.93 33.97 2941.02 7.51 2669.64 92.03 2348.64 94.44
2180.13 97.06 1715.30 10.34 1436.36 33.99 1328.82 48.36 1223.57 55.35
1119.68 64.00 1048.33 79.43 897.48 79.89 749.82 77.84 651.40 84.62
492.57 67.46
REF 4000 99.83 2000 99.04 600

3943.56 98.35 3425.28 37.78 2939.81 7.65 2670.06 89.88 2179.84 97.17
1964.98 98.03 1714.55 10.79 1435.72 31.90 1331.72 44.84 1223.42 53.48
1120.29 63.14 1049.65 78.05 897.72 77.50 750.66 77.54 651.06 87.20
493.15 69.19
REF 4000 99.35 2000 98.42 600

3937.80 97.43 3789.03 93.55 3430.72 31.63 2941.48 9.72 2671.13 92.68
2178.21 96.79 1715.95 10.37 1572.30 63.99 1433.51 38.82 1333.54 54.93
1221.97 60.15 1119.54 68.23 1050.87 84.74 904.72 84.64 749.81 78.61
651.05 83.22 492.07 69.32
REF 4000 98.92 2000 97.87 600

3943.92 97.27 3782.24 95.36 3423.57 23.43 2941.77 7.30 2670.35 89.35
2343.26 96.51 2178.69 95.36 1965.92 96.87 1713.95 12.16 1571.43 48.29
1433.03 27.28 1328.58 44.75 1223.24 51.41 1119.32 59.60 1050.59 76.06
902.02 76.81 749.97 71.82 651.31 77.25 492.18 59.82 428.14 86.56
REF 4000 99.12 2000 97.67 600

3786.76 91.53 3445.99 9.56 2944.90 7.26 2671.36 94.64 2104.10 95.20
1717.82 12.62 1568.48 39.46 1429.48 33.03 1338.72 56.45 1221.64 64.05
1119.82 70.14 1048.26 84.62 904.89 86.55 748.22 69.83 650.71 67.40
493.63 61.30
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 16-6-2010
FTIR SPECT RUM

Date: 16-6-2010
90
80
100.0
3 794 .2 5
2 34 4.6 9
1 96 5.12
100.0
90
90
20 97 .0 7
80
1 04 5.98
39 75 .4 3
89 9.2 1
10 48 .5 1
70
89 7.5 1 75 0.87
9 07.65
3 78 1.74
2 67 0.71
80
6 51 .6 2
2 67 0.1 8
70
3 88 6.01
2 10 7.05
3 78 3.94
20 79 .9 3
3 94 4.50
FTIR SPECT RUM

Date: 16-6-2010
100.0
6 49 .8 1
70
11 21 .09
74 9.44
1 05 0.7 5
74 7.82
49 3.53
60
60
1 12 2.09
60
49 4.34
11 73.29
12 19 .57
1 12 0.98
50
50
%T
6 49 .5 1
49 5.14
16 41 .7 2
50
12 21 .1 2
%T
%T
12 23 .0 1
40
40
40
1 570 .2 6
13 38 .9 3
133 4.74
30
30
30
1 570 .0 5
142 7.04
1 43 6.37
20
3 427 .7 3
20
10
0.0
4000.0
10
20
1 432 .4 4
10
34 37.78
0.0
2000
15 00
100 0
400.0
4000.0
cm-1
K-0.2+0.4+0.4.pk
0.0
3000
17 21 .4 8
17 16 .7 8
2 94 1.84
17 15 .21
29 41.41
3000
2000
15 00
100 0
400.0
34 44.68
4000.0
cm-1
K-0.2+0.3+0.5.pk
2 94 5.9 2
3000
2000
15 00
100 0
400.0
cm-1
K-0.1+0.4+0.5.pk
K-02_0~1.SP 3601 4000.00 400.00 7.34 99.80 4.00 %T 3 1.00
K-02_0~2.SP 3601 4000.00 400.00 7.19 99.97 4.00 %T 3 1.00
K-01_0~2.SP 3601 4000.00 400.00 6.39 99.86 4.00 %T 3 1.00
REF 4000 99.71 2000 98.70 600

3944.50 97.61 3794.25 96.99 3427.73 27.70 2941.41 7.34 2670.18 87.97
2344.69 97.32 2079.93 96.27 1965.12 97.41 1715.21 9.63 1436.37 29.10
1334.74 41.04 1223.01 50.79 1120.98 60.60 1050.75 76.07 897.51 74.68
750.87 73.60 651.62 86.35 493.53 67.62
REF 4000 99.64 2000 98.71 600

3783.94 94.21 3437.78 14.35 2941.84 7.19 2670.71 91.00 2097.07 96.08
1716.78 10.28 1570.26 41.98 1432.44 24.87 1338.93 42.62 1221.12 54.71
1122.09 64.10 1048.51 80.76 899.21 81.68 749.44 73.14 649.81 76.63
494.34 63.76
REF 4000 98.58 2000 96.89 600

3975.43 97.27 3886.01 96.99 3781.74 91.07 3444.68 6.39 2945.92 9.08
2107.05 94.09 1721.48 13.74 1641.72 41.92 1570.05 32.40 1427.04 30.79
1219.57 67.56 1173.29 68.82 1121.09 71.98 1045.98 84.96 907.65 89.57
747.82 68.49 649.51 63.03 495.14 59.83
307
400.0
Table - 7.26
Observations of FTIR Spectrum for
Cyclohexanone + Heptane + 2-Butanone mixture
S1
(Cm-1)
3927.86
3790.16
3431.92
2939.60
2671.46
2177.81
1713.01
1574.71
1432.52
1324.44
1224.49
1118.41
1045.71
896.35
747.97
649.10
492.68
*S2
(Cm-1)
S3
(Cm-1)
S4
(Cm-1)
S5
(Cm-1)
S6
(Cm-1)
S7
(Cm-1)
S8
(Cm-1)
S9
(Cm-1)
3910.00
3786.93
3424.99
2941.19
2670.37
2076.42*
1966.64*
1714.75
1578.58
1435.16
1323.23
1223.13
1119.07
1050.79
900.51
750.13
651.57
491.53
425.55
3921.77
3789.69
3423.93
2940.97
2670.55
2179.10
1715.03
1572.28
1434.25
1324.60
1222.75
1119.21
1050.66
903.28
749.93
651.23
491.60
426.96
3908.21
3785.54
3429.85
2941.21
2669.44
2079.95
1962.54
1716.16
1573.60
1434.92
1327.58
1224.33
1120.34
1042.09
894.64
749.25
648.82
494.07
427.00
3940.31
3789.34
3414.34
2940.68
2669.87
2179.43
1963.83
1713.60
1578.02
1435.79
1324.42
1224.00
1119.07
1051.25
897.80
750.46
651.98
491.83
419.22
3928.28
3789.41
3420.18
2940.99
2670.15
2179.02
1964.93
1713.81
1574.36
1434.77
1324.45
1223.17
1119.06
1050.64
900.45
750.07
651.50
491.72
423.61
3932.99
3793.34
3429.45
2940.41
2670.46
2178.76
1714.52
1573.96
1432.97
1327.84
1223.41
1119.31
1046.46
897.42
748.74
649.36
492.56
3935.52
3787.95
3420.38
2938.54
2669.98
2182.12
1965.25
1714.08
1436.94
1326.48
1225.12
1119.13
1049.50
896.53
750.88
651.65
492.57
3939.35
3782.97
3422.52
2940.57
2669.78
2345.21
2178.23
1963.79
1715.76
1435.12
1335.01
1222.43
1119.70
1052.44
904.43
750.89
652.15
492.57
420.48

S10
(Cm-1)
S11
(Cm-1)
S12
(Cm-1)
S13
(Cm-1)
*S14
(Cm-1)
S15
(Cm-1)
S16
(Cm-1)
S17
(Cm-1)
S18
(Cm-1)
3940.88
3417.95
2941.00
2669.86
2345.42
2178.74
1965.21
1713.52
1571.88
1434.72
1325.91
1223.62
1119.13
1051.31
898.85
750.38
652.02
491.91
420.72
3947.72
3430.93
2941.02
2669.64
2348.64
2180.13
1715.30
1436.36
1328.82
1223.57
1119.68
1048.33
897.48
749.82
651.40
492.57
3943.56
3425.28
2939.81
2670.06
2179.84
1964.98
1714.55
1435.72
1331.72
1223.42
1120.29
1049.65
897.72
750.66
651.06
493.15
3937.80
3789.03
3430.72
2941.48
2671.13
2178.21
1715.95
1572.30
1433.51
1333.54
1221.97
1119.54
1050.87
904.72
749.81
651.05
492.07
3943.92
3782.24
3423.57
2941.77
2670.35
2343.26
2178.69
1965.92
1713.95
1571.43
1433.03
1328.58
1223.24
1119.32
1050.59
902.02
749.97
651.31
492.18
428.14
3944.50
3794.25
3427.73
2941.41
2670.18
2344.69
2079.93
1965.12
1715.21
1436.37
1334.74
1223.01
1120.98
1050.75
897.51
750.87
651.62
493.53
3783.94
3437.78
2941.84
2670.71
2097.07
1716.78
1570.26
1432.44
1338.93
1221.12
1122.09
1048.51
899.21
749.44
649.81
494.34
3786.76
3445.99
2944.90
2671.36
2104.10
1717.82
1568.48
1429.48
1338.72
1221.64
1119.82
1048.26
904.89
748.22
650.71
493.63
3975.43
3886.01
3781.74
3444.68
2945.92
2107.05
1721.48
1641.72
1570.05
1427.04
1219.57
1173.29
1121.09
1045.98
907.65
747.82
649.51
495.14

308
Fig-7.26: FTIR Spectrum for Cyclohexanone + Heptane + Ethyl Acetate

mixture:
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
FTIR SPECT RUM

Date: 24-6-2010
100.0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
100.0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
FTIR SPECT RUM

Date: 24-6-2010
100.0
100.0
100.0
20 70 .8 7
2 34 5.1 6
3 94 4.06
90
207 1.77
90
26 73 .75
39 36.07
42 1.36
39 38 .05
90
2 34 3.7 9
90
2 34 0.8 4
1 96 5.04
3 93 5.1 9
26 69 .0 8
2 07 7.54
26 68 .92
21 76 .6 7
80
80
41 9.41
3 83 3.35
4 19 .0 6
90
2 34 8.2 4
2 07 4.5 7
26 69 .69
80
3 94 5.35
2 07 8.34
80
80
26 69 .0 3
2 17 7.3 5
1 05 2.79
6 51 .6 7
6 51 .7 5
6 50 .0 0
70
70
89 7.9 1
10 51 .0 8
70
74 9.92
90 1.86
70
9 02.70
70
1 22 5.09
9 02.15 75 0.20
75 0.04
60
1 11 8.90
60
49 1.80
287 0.92
50
60
4 96.89
1 32 8.29
1 11 8.72
50
%T
60
49 2.25
10 53.78
742 .9 5
1 11 8.22
50
%T
30
40
49 1.90
1 118 .8 8
40
13 23 .41
35 01 .5 0
1 22 6.25
34 13 .8 5
30
1 43 7.88
30
30
1 43 7.91
34 17 .5 9
30
1 43 5.14
1 43 8.81
12 32 .44
29 42 .6 1
20
34 17 .2 3
20
10
20
16 41 .0 0
10
10
28 72 .5 1
10
17 13 .82
17 15 .16
2000
20
29 41 .6 2
29 41 .2 6
0.0
3000
12 34 .32
2 87 1.43
20
28 71.55
10
17 13 .80
17 13 .39
29 39 .9 5
0.0
4000.0
1 05 5.6 1
50
%T
13 22 .6 8
40
142 4.92
6 49 .9 4 49 3.57
74 8.13
%T
13 22 .66
40
13 23 .22
122 7.06
60
10 54.45
1 11 7.70
50
%T
65 0.23
40
15 00
100 0
400.0
0.0
3 42 8.39
4000.0
3000
2000
cm-1
15 00
100 0
400.0
3000
2000
15 00
100 0
400.0
17 13 .68
3 428 .1 1
0.0
4000.0
cm-1
4000.0
29 41 .0 7
0.0
3000
2000
cm-1
15 00
100 0
400.0
4000.0
3000
2000
cm-1
15 00
100 0
K-0.5+0.3+0.2.pk
K-0.5+0.2+0.3.pk
K-0.5+0.1+0.4.pk
K-0.4+0.5+0.1.pk
K-05_0~4.SP 3601 4000.00 400.00 7.72 100.00 4.00 %T 5 1.00
K-05_0~2.SP 3601 4000.00 400.00 5.05 99.67 4.00 %T 5 1.00
K-05_0~3.SP 3601 4000.00 400.00 9.59 100.00 4.00 %T 5 1.00
K-05_0~1.SP 3601 4000.00 400.00 6.34 100.00 4.00 %T 5 1.00
K-04_0~2.SP 3601 4000.00 400.00 7.79 99.99 4.00 %T 5 1.00
REF 4000 99.01 2000 97.72 600

3944.06 95.52 3417.59 31.96 2939.95 7.72 2669.08 91.33 2345.16 95.30
2176.67 95.39 2071.77 95.23 1713.39 10.73 1437.88 33.99 1323.22 45.30
1227.06 45.74 1118.72 57.87 1051.08 71.72 897.91 74.03 749.92 71.31
651.67 81.65 491.80 64.54 421.36 92.63
REF 4000 98.59 2000 95.34 600

3936.07 95.48 3428.39 5.05 2942.61 30.93 2870.92 59.30 2673.75 96.25
2077.54 91.12 1713.80 15.21 1641.00 23.84 1424.92 45.14 1328.29 70.06
1225.09 72.97 1118.90 67.80 1052.79 84.31 742.95 57.43 650.23 54.04
496.89 63.92
REF 4000 99.32 2000 98.07 600

3938.05 96.77 3417.23 29.49 2941.26 12.04 2871.55 26.38 2668.92 92.97
2343.79 96.42 2074.57 95.36 1715.16 9.59 1437.91 34.75 1322.66 47.31
1232.44 33.70 1118.22 56.05 1053.78 64.96 902.70 76.07 750.04 70.82
650.00 78.91 492.25 65.04 419.06 91.88
REF 4000 99.11 2000 95.70 600

3935.19 94.03 3428.11 6.34 2941.62 13.91 2871.43 31.14 2669.69 94.04
2340.84 95.23 2078.34 91.31 1713.68 8.16 1435.14 34.49 1322.68 50.15
1234.32 30.26 1117.70 56.93 1054.45 63.96 901.86 76.88 748.13 56.85
649.94 59.34 493.57 58.08
REF 4000 97.58 2000 96.34 600

3945.35 92.87 3833.35 94.76 3501.50 45.15 3413.85 43.26 2941.07 7.79
2872.51 20.19 2669.03 88.55 2348.24 93.11 2177.35 93.90 2070.87 93.92
1965.04 95.19 1713.82 11.00 1438.81 34.08 1323.41 44.64 1226.25 44.50
1118.88 55.61 1055.61 71.13 902.15 72.43 750.20 71.84 651.75 82.91
491.90 64.24 419.41 91.14
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
FTIR SPECT RUM

Date: 24-6-2010
100.0
41 9.26
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
100.0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
FTIR SPECT RUM

Date: 24-6-2010
100.0
400.0
cm-1
K-0.5+0.4+0.1.pk
100.0
100.0
42 4.67
90
90
39 40 .61
2 075 .3 8
3 94 4.64
90
207 4.65
42 2.41
90
26 69 .0 2
26 69 .2 7
80
80
2 670 .3 9
3 94 6.8 7
26 69 .3 0
80
6 50 .6 1
90
2 075 .5 6
394 3.67
2 344 .7 0
2 34 5.73
2 07 9.66
26 69 .0 6
20 83.01
80
80
23 46 .4 7
2 344 .9 9
2 34 5.81
104 9.38
89 8.5 9
70
6 51 .2 5
90 0.40
70
70
75 0.32
89 8.4 2
90 0.92
70
6 50 .8 8
10 52 .0 7
70
8 91 .6 6
6 49 .2 2
74 9.66
74 9.75
60
49 1.77
60
49 2.05
60
10 50 .3 4
1 11 8.38
74 9.76
1 05 1.6 2
60
49 2.31
60
49 2.30
1 11 8.15
50
1 11 8.24
6 51 .7 5
74 6.08
49 5.09
11 17 .4 7
50
%T
1 11 8.37
50
%T
50
%T
1 22 6.18
50
1 05 2.0 8
%T
%T
132 5.52
132 1.67
13 22 .80
40
40
30
40
13 22 .61
123 1.33
40
13 22 .71
40
34 17 .0 1
30
1 43 8.09
1 43 8.07
30
12 33 .34
1 43 5.57
30
12 32 .34
1 43 5.17
30
1 43 6.17
34 19 .7 2
20
20
20
12 37 .1 5
20
34 20 .1 8
10
10
17 14 .31
10
10
29 41 .0 4
17 15 .56
29 39 .5 1
29 40 .4 7
0.0
4000.0
3000
2000
15 00
100 0
400.0
17 14 .42
0.0
4000.0
3000
2000
cm-1
20
34 24 .2 3
10
17 15 .94
29 42 .2 6
0.0
15 00
100 0
400.0
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
3 43 1.37
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
4000.0
29 40 .0 7
171 2.57
3000
2000
cm-1
15 00
100 0
400.0
cm-1
K-0.4+0.4+0.2.pk
K-0.4+0.3+0.3.pk
K-0.4+0.2+0.4.pk
K-0.4+0.1+0.5.pk
K-0.3+0.5+0.2.pk
K-04_0~4.SP 3601 4000.00 400.00 8.61 100.00 4.00 %T 5 1.00
K-04_0~3.SP 3601 4000.00 400.00 7.82 100.00 4.00 %T 5 1.00
K-04_0~1.SP 3601 4000.00 400.00 7.77 100.00 4.00 %T 5 1.00
K-3309~1.SP 3601 4000.00 400.00 10.75 100.00 4.00 %T 5 1.00
K-03_0~4.SP 3601 4000.00 400.00 8.03 100.00 4.00 %T 5 1.00
REF 4000 99.25 2000 97.20 600

3940.61 95.40 3419.72 26.55 2942.26 8.61 2669.27 92.07 2345.81 92.90
2075.38 94.24 1714.31 9.40 1438.09 36.51 1322.80 48.27 1231.33 39.79
1118.38 57.89 1052.07 67.95 898.59 76.31 749.75 70.11 651.25 77.79
492.05 65.16 422.41 93.28
REF 4000 99.37 2000 98.30 600

3944.64 96.25 3417.01 40.21 2939.51 7.82 2669.02 92.20 2344.70 96.38
2074.65 95.96 1715.94 11.30 1438.07 35.30 1322.61 46.61 1233.34 35.75
1118.15 59.17 1050.34 65.49 900.40 76.71 750.32 75.62 650.61 85.23
491.77 68.07 419.26 94.32
REF 4000 99.21 2000 96.92 600

3943.67 93.28 3420.18 19.86 2940.47 7.77 2669.30 91.57 2345.73 93.85
2075.56 93.65 1714.42 9.43 1436.17 33.41 1322.71 46.02 1232.34 35.86
1118.37 56.41 1051.62 65.84 898.42 75.36 749.76 67.25 650.88 74.13
492.31 63.19 424.67 92.31
REF 4000 99.34 2000 97.42 600

3946.87 94.31 3424.23 19.82 2941.04 15.40 2670.39 93.77 2346.47 93.22
2079.66 94.18 1715.56 10.74 1435.57 38.71 1321.67 51.82 1237.15 27.01
1117.47 59.41 1052.08 59.90 900.92 78.67 749.66 68.52 649.22 72.71
492.30 65.32
REF 4000 99.56 2000 95.83 600

3431.37 8.24 2940.07 8.25 2669.06 94.48 2344.99 91.44 2083.01 91.93
1712.57 8.03 1435.17 37.18 1325.52 52.74 1226.18 57.63 1118.24 64.30
1049.38 80.57 891.66 78.32 746.08 60.24 651.75 62.19 495.09 60.19
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM
FTIR SPECT RUM
Date: 24-6-2010
Date: 24-6-2010
100.0
90
70
89 6.8 1
2 07 8.36
20 85.22
23 47.95
26 67 .76
80
23 45 .2 2
2 34 5.14
89 8.3 0
70
89 5.8 8
39 36 .14
80
6 49 .2 2
70
90
2 669 .6 3
2 08 0.56
80
2 667 .0 6
2 34 5.27
26 70 .3 8
FTIR SPECT RUM

Date: 24-6-2010
100.0
90
39 44 .7 6
2 079 .2 0
80
100.0
90
2 34 5.2 4
39 29 .4 0
2 07 8.20
80
100.0
90
266 9.06
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
100.0
3 932 .4 0
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
8 91 .4 2
70
70
6 48 .6 8
105 1.18
75 0.06
89 5.8 0
6 50 .6 7
10 52 .11
60
49 2.99
60
60
105 3.25
6 51 .6 4
74 9.08
60
49 2.34
74 9.96
60
1 11 7.67
49 2.77
10 51 .1 0
1 11 7.82
74 8.97
50
49 3.00
1 11 8.51
%T
50
50
1 11 6.43
%T
6 51 .2 4
74 5.95
49 5.53
50
13 22 .07
%T
%T
50
1 05 0.83
%T
13 25 .9 9
40
40
13 23 .24
40
40
11 16 .8 2
40
12 30 .5 5
13 25 .6 6
13 25 .9 8
123 0.51
30
30
1 43 4.78
30
30
30
1 43 5.85
1 43 7.52
1 43 5.39
12 35 .5 9
20
12 35 .8 4
20
20
20
10
17 14 .23
15 00
100 0
400.0
17 14 .99
0.0
4000.0
3000
2000
cm-1
10
29 41 .8 8
29 40 .3 0
0.0
2000
10
34 25 .7 3
17 15 .77
29 42 .2 7
3000
12 35 .3 7
34 22 .0 5
10
34 28.81
4000.0
1 43 7.48
20
34 23 .6 7
10
0.0
15 00
100 0
400.0
0.0
4000.0
3000
2000
cm-1
15 00
100 0
400.0
3 43 3.41
4000.0
cm-1
29 40 .7 1
171 1.52
29 40 .7 4
17 15 .16
0.0
3000
2000
15 00
100 0
400.0
4000.0
cm-1
3000
2000
15 00
100 0
cm-1
K-0.3+0.4+0.3.pk
K-0.3+0.3+0.4.pk
K-0.3+0.2+0.5.pk
K-0.2+0.5+0.3.pk
K-0.2+0.4+0.4.pk
K-03_0~2.SP 3601 4000.00 400.00 7.32 100.00 4.00 %T 5 1.00
K-03_0~3.SP 3601 4000.00 400.00 8.96 99.99 4.00 %T 5 1.00
K-03_0~1.SP 3601 4000.00 400.00 8.95 100.00 4.00 %T 5 1.00
K-02_0~3.SP 3601 4000.00 400.00 6.36 100.00 4.00 %T 5 1.00
K-02_0~1.SP 3601 4000.00 400.00 7.77 99.99 4.00 %T 5 1.00
REF 4000 99.19 2000 95.61 600

3932.40 91.73 3428.81 7.32 2942.27 8.60 2669.06 92.32 2345.27 89.07
2078.20 91.38 1714.23 8.63 1435.39 30.82 1323.24 45.18 1230.51 38.02
1118.51 54.93 1052.11 68.08 896.81 73.72 748.97 57.31 651.64 61.67
493.00 56.67
REF 4000 99.24 2000 97.14 600

3929.40 92.91 3423.67 19.72 2940.30 8.96 2667.06 90.27 2345.24 92.36
2079.20 93.85 1715.77 10.62 1437.52 33.55 1325.66 44.16 1235.59 30.93
1116.43 58.00 1051.10 60.53 895.88 73.70 750.06 71.39 649.22 79.20
492.99 66.81
REF 4000 99.50 2000 96.86 600

3944.76 93.92 3425.73 14.73 2941.88 10.45 2670.38 93.64 2347.95 86.76
2080.56 93.37 1714.99 8.95 1434.78 38.33 1322.07 53.22 1235.84 30.07
1117.82 60.16 1053.25 64.44 898.30 79.35 749.08 66.20 650.67 69.09
492.34 64.57
REF 4000 99.64 2000 95.36 600

3433.41 6.36 2940.71 8.57 2669.63 94.75 2345.14 90.42 2085.22 91.14
1711.52 8.75 1435.85 35.89 1325.99 51.63 1230.55 48.18 1117.67 63.40
1051.18 75.48 891.42 77.55 745.95 57.59 651.24 58.82 495.53 57.69
REF 4000 99.78 2000 97.79 600

3936.14 92.82 3422.05 19.31 2940.74 7.77 2667.76 90.61 2345.22 93.07
2078.36 94.23 1715.16 7.91 1437.48 27.77 1325.98 39.34 1235.37 27.07
1116.82 53.20 1050.83 56.99 895.80 70.96 749.96 67.67 648.68 75.98
492.77 61.40
ACIC
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECT RUM

Date: 24-6-2010
FTIR SPECT RUM

Date: 24-6-2010
100.0
90
100.0
90
26 69 .13
3 93 7.80
FTIR SPECT RUM

Date: 24-6-2010
100.0
80
90
267 0.47
2 670 .5 5
3 94 8.8 6
3 94 3.60
20 86.15
20 87.49
80
20 83.81
80
2 34 5.9 6
23 46 .0 5
2 34 5.12
70
10 52 .8 9
70
10 52 .7 6
89 4.8 5
70
11 16 .8 2
11 16 .2 6
60
60
4 96.68
60
4 99 .3 0
1 33 0.69
744 .8 8
6 50 .3 6
13 27 .0 1
50
74 7.80
7 42 .59
6 50 .2 5
50
%T
49 4.61
11 15 .4 7
50
12 34 .50
%T
%T
6 46 .7 7
1 05 3.57
40
40
1 43 4.25
40
1 432 .9 9
13 28 .8 8
12 35 .3 3
30
30
30
1 43 6.18
20
20
20
1 23 7.89
10
0.0
29 40 .5 2
29 42 .2 0
10
171 2.32
171 1.83
10
3 429 .0 4
34 32 .3 7
34 30 .3 1
4000.0
0.0
3000
2000
15 00
100 0
400.0
4000.0
cm-1
K-0.2+0.3+0.5.pk
29 43 .1 5
17 16 .5 8
0.0
3000
2000
15 00
100 0
400.0
4000.0
cm-1
K-0.1+0.5+0.4.pk
3000
2000
15 00
100 0
400.0
cm-1
K-0.1+0.4+0.5.pk
K-02_0~2.SP 3601 4000.00 400.00 6.47 100.00 4.00 %T 5 1.00
K-01_0~2.SP 3601 4000.00 400.00 6.37 99.99 4.00 %T 5 1.00
K-01_0~1.SP 3601 4000.00 400.00 7.60 99.95 4.00 %T 5 1.00
REF 4000 99.40 2000 95.31 600

3937.80 93.56 3430.31 6.47 2940.52 12.96 2669.13 95.06 2345.12 90.47
2086.15 91.25 1712.32 13.75 1434.25 44.34 1327.01 59.93 1235.33 44.09
1116.26 69.62 1052.76 74.12 744.88 61.21 650.36 60.87 496.68 64.50
REF 4000 99.64 2000 95.09 600

3943.60 92.37 3432.37 6.37 2942.20 15.49 2670.47 96.19 2345.96 89.23
2087.49 90.63 1711.83 17.53 1432.99 46.53 1330.69 64.45 1234.50 53.87
1116.82 71.73 1052.89 78.45 742.59 59.47 650.25 57.11 499.30 63.38
REF 4000 99.58 2000 96.45 600

3948.86 95.05 3429.04 8.74 2943.15 7.89 2670.55 94.64 2346.05 90.32
2083.81 91.98 1716.58 7.60 1436.18 30.09 1328.88 46.11 1237.89 19.22
1115.47 55.72 1053.57 54.30 894.85 77.04 747.80 60.40 646.77 61.44
494.61 59.17
309
400.0
Table - 7.27
Observations of FTIR Spectrum for
Cyclohexanone + Heptane + Ethyl Acetate mixture
S1
(Cm-1)
S2
(Cm-1)
S3
(Cm-1)
S4
(Cm-1)
*S5
(Cm-1)
3944.06
3417.59
2939.95
2669.08
2345.16
2176.67
2071.77
1713.39
1437.88
1323.22
1227.06
1118.72
1051.08
897.91
749.92
651.67
491.80
421.36
3936.07
3428.39
2942.61
2870.92
2673.75
2077.54
1713.80
1641.00
1424.92
1328.29
1225.09
1118.90
1052.79
742.95
650.23
496.89
3938.05
3417.23
2941.26
2871.55
2668.92
2343.79
2074.57
1715.16
1437.91
1322.66
1232.44
1118.22
1053.78
902.70
750.04
650.00
492.25
419.06
3935.19
3428.11
2941.62
2871.43
2669.69
2340.84
2078.34
1713.68
1435.14
1322.68
1234.32
1117.70
1054.45
901.86
748.13
649.94
493.57
3945.35
3833.35*
3501.50*
3413.85
2941.07
2872.51
2669.03
2348.24
2177.35*
2070.87
1965.04
1713.82
1438.81
1323.41
1226.25
1118.88
1055.61
902.15
750.20
651.75
491.90
419.41
S6
(Cm-1)
S7
(Cm-1)
S8
(Cm-1)
S9
(Cm-1)
3940.61
3419.72
2942.26
2669.27
2345.81
2075.38
1714.31
1438.09
1322.80
1231.33
1118.38
1052.07
898.59
749.75
651.25
492.05
422.41
3944.64
3417.01
2939.51
2669.02
2344.70
2074.65
1715.94
1438.07
1322.61
1233.34
1118.15
1050.34
900.40
750.32
650.61
491.77
419.26
3943.67
3420.18
2940.47
2669.30
2345.73
2075.56
1714.42
1436.17
1322.71
1232.34
1118.37
1051.62
898.42
749.76
650.88
492.31
424.67
3946.87
3424.23
2941.04
2670.39
2346.47
2079.66
1715.56
1435.57
1321.67
1237.15
1117.47
1052.08
900.92
749.66
649.22
492.30

S10
(Cm-1)
S11
(Cm-1)
S12
(Cm-1)
S13
(Cm-1)
S14
(Cm-1)
S15
(Cm-1)
S16
(Cm-1)
S17
(Cm-1)
S18
(Cm-1)
3431.37
2940.07
2669.06
2344.99
2083.01
1712.57
1435.17
1325.52
1226.18
1118.24
1049.38
891.66
746.08
651.75
495.09
3932.40
3428.81
2942.27
2669.06
2345.27
2078.20
1714.23
1435.39
1323.24
1230.51
1118.51
1052.11
896.81
748.97
651.64
493.00
3929.40
3423.67
2940.30
2667.06
2345.24
2079.20
1715.77
1437.52
1325.66
1235.59
1116.43
1051.10
895.88
750.06
649.22
492.99
3944.76
3425.73
2941.88
2670.38
2347.95
2080.56
1714.99
1434.78
1322.07
1235.84
1117.82
1053.25
898.30
749.08
650.67
492.34
3433.41
2940.71
2669.63
2345.14
2085.22
1711.52
1435.85
1325.99
1230.55
1117.67
1051.18
891.42
745.95
651.24
495.53
3936.14
3422.05
2940.74
2667.76
2345.22
2078.36
1715.16
1437.48
1325.98
1235.37
1116.82
1050.83
895.80
749.96
648.68
492.77
3937.80
3430.31
2940.52
2669.13
2345.12
2086.15
1712.32
1434.25
1327.01
1235.33
1116.26
1052.76
744.88
650.36
496.68
3943.60
3432.37
2942.20
2670.47
2345.96
2087.49
1711.83
1432.99
1330.69
1234.50
1116.82
1052.89
742.59
650.25
499.30
63.38
3948.86
3429.04
2943.15
2670.55
2346.05
2083.81
1716.58
1436.18
1328.88
1237.89
1115.47
1053.57
894.85
747.80
646.77
494.61
310
Fig-7.27:
mixture:
FTIR
Spectrums
for
Cyclohexanone+2-Butanone+Benzaldehyde
ACIC
Trichy-2
FTIR SPECTRUM
Date: 03-1 2-2009
ACIC
Tric hy-2
Spectrum Name: SJC-Ph-D-1.sp

1 00 .0
ACIC
Tric hy-2
1018.13
3927.97
90
2176.04
3788.49
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 03- 12-2009
Spectrum Name: SJC-Ph- D-2.sp
80
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 03- 12-2009
413.27
1172.66
100.0
100.0
90
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 03- 12-2009
FT IR SPECT RUM
Date: 03- 12-2009
FT IR SPECT RUM
Date: 03- 12-2009
100.0
100.0
100.0
1804.84
70
863.72
2673.39
1054.67
3927.93
1020.15
3931.53
90
90
861 .26
1018.47
651.14
60
861.50
80
80
2175.76
80
416.20
3788.52
1018.91
2673.92
3790.58
70
1172.47
392 7.50
2173.53
70
904.11
1054.63
60
903.20
60
752.07
754.07
1054.15
3793.60
64 9.91
60
650.90
1314.07
2672.60
6 49.90
1055.56
904.99
60
559.8 8
70
903.29
863 .56
2672.36
1055.20 903.33
80
2 673.57
70
3931.42
60
2175.71
3928.10
2175.61
3 784.96
70
491.59
1119.36
1222.68
40
1448.22
862.8 0
413 .32
80
2175.84
751.78
50
%T
90
414.55
905.15
1055.28
4 91.94
111 9.05
1314.28
50
64 9.71
753.18
4 92.38
111 9.18
%T
30
50
50
751.69
4 91.47
%T
50
4 92.04
1119.36
%T
50
%T
11 19.18
%T
587.69
111 9.18
1223.19
1222.8 9
40
1350.61
20
40
1 227.85
40
40
1445.16
755.49
4 93.59
40
1225.70
1444.00
1223.85
2865.29
1444.52
30
1348.36
1448.21
30
30
1444.42
30
30
2866.09
1350.34
3420.47
10
1595.46
1351.08
2865.46
20
1351.62
20
2865.6 0
2864.88
20
2940.99
20
20
2864.86
1353.25
3 431.36
1712.31
0 .0
4 00 0.0
3 00 0
3439.70
10
2 00 0
1 50 0
1 00 0
10
4 00 .0
294 1.24
cm-1
17 11.17
3000
2000
1500
1000
400.0
4000.0
3431.58
17 12.05
0.0
4000.0
3000
294 0.55
1500
1000
400.0
10
294 0.81
1595.65
17 11.36
17 11.82
3436.14
0.0
4000.0
3000
2000
1500
cm-1
294 2.42
17 12.65
0.0
2000
cm-1
1595.38
10
1595.16
294 0.97
0.0
SJC-Ph-D-1.pk
10
3420.01
1595.42
1000
400.0
1594.99
0.0
4000.0
3000
2000
1500
cm-1
1000
400.0
4000.0
3000
2000
1500
cm-1
1000
cm-1
SJB907~1.SP 3601 4000.00 400.00 7.45 99.05 4 .00 %T 5 1.0 0
SJC-Ph-D- 2.pk
SJC-Ph-D- 3.pk
SJC-Ph-D- 4.pk
SJC-Ph-D- 5.pk
SJC-Ph-D- 6.pk
REF 4000 88.78 2000 87.99 600

3927.97 85.91 3788.49 84.61 3420.47 16.33 294 0.99 11.72 2865.29 26.25
2673.39 80.60 2176.04 84.99 1804.84 79.55 171 2.31 7.45 1595.46 15.29
1448.22 39.98 1350.61 30.91 1314.28 45.22 122 2.68 48.05 1172.66 77.18
1119.36 54.46 1054.67 75.08 1018.13 79.40 905 .15 71 .81 863.72 76.49
751.78 60.58 651.14 69.69 491 .59 56 .71 413.27 80.34
SJB90 3~1. SP 3601 4000.00 400.00 6.31 99.58 4.00 %T 5 1.0 0
SJB90 F~1.SP 3601 4000.00 400 .00 7.42 98.98 4.00 %T 5 1. 00
SJC90B~1. SP 3601 4000. 00 400. 00 7.08 99. 87 4.00 %T 5 1. 00
SJC907~1.SP 3601 4000.00 400 .00 8.04 99.68 4.00 %T 5 1. 00
SJC903~1.SP 3601 4000.00 400 .00 5.30 99.43 4.00 %T 5 1. 00
REF 4 000 87.29 2000 85.89 600

3931.42 82.79 3784.96 81.45 3439.70 6.31 2941.24 11.45 2865.46 27.10
2673.92 79.58 2175.84 82.26 1711.17 8.85 1595.42 7. 48 144 4.52 40.17
1351.08 26.73 1223.19 49.72 1119.18 55.77 1055.20 73. 03 1018.91 77. 60
903. 33 70 .43 861.50 72.39 753.18 53.4 9 649.71 59.94 559.88 61. 46
492. 38 52 .58
REF 4 000 86.78 2000 86.01 600

3927.93 83.62 3790.58 81.90 3420.01 13.77 2940.97 9.61 2864.86 23.69
2672.36 78.90 2175.61 82.90 1712.05 7.42 1595.16 12.54 1448.21 38.64
1350.34 29.32 1314.07 42.85 1223.85 43.49 1119.18 50. 95 1054.15 67. 92
1018.47 74.60 904.99 68 .67 863.56 73.12 751.69 57.26 650.90 65.91
491. 47 53 .39 413.32 78.61
REF 4 000 88.63 2000 87.88 600

3931.53 85.79 3788.52 83.89 3431.58 11.94 2940.55 11. 10 2864.88 27. 74
2673.57 82.37 2175.76 84.89 1711.36 7.08 1595.65 10.34 1444.00 44.44
1351.62 31.26 1222.89 52.77 1119.36 56.47 1055.56 73. 99 1020.15 78. 02
903. 29 73 .90 861.26 78.65 754.07 61.1 6 649.91 68.43 492.04 56. 65
416. 20 81 .52
REF 4 000 89.65 2000 88.80 600

3928.10 87.41 3431.36 18.95 2940.81 13.01 2865.60 30. 40 2672.60 83. 27
2175.71 86.26 1711.82 8. 04 1595.38 20.53 1445.16 44.62 1348.36 39.86
1225.70 46.88 1119.05 58.07 1054.63 72.76 904.11 73.92 862.80 78.05
752. 07 64 .08 649.90 71.91 491.94 60.4 2 414.55 83.95
REF 4 000 81.31 2000 80.29 600

3927.50 76.71 3793.60 72.92 3436.14 5.61 2942.42 14.95 2866.09 32.34
2173.53 76.45 1712.65 11.57 1594.99 5.30 1444.42 42.25 1353.25 22.81
1227.85 48.63 1172.47 71.60 1119.18 59.91 1055.28 69. 28 903.20 70.74
755. 49 49 .41 587.69 54.57 493.59 52.0 1
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 03- 12-2009
FT IR SPECT RUM
Date: 02- 12-2009
100.0
100.0
1017.87
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 02- 12-2009
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 02- 12-2009
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 03- 12-2009
FT IR SPECT RUM
Date: 02- 12-2009
100.0
2174.34
100.0
1 018.97
3940.76
1871.42
90
862.48
3940.98
2175.11
80
2672.80
2175.91
2 671.50
80
415 .26
2103.19
70
863.45
80
861.80
2671.94
1054.2 9
1384.23
2069.77
13 14.41
1054.03
862.20
70
70
111 9.06
64 9.90
1052.88
60
651.79
80
904.81
2095.64
904.39
70
1055.82
904.66
60
65 0.73
90
2 672.91
416.46
903.09
863.95
60
90
233 7.75
1803.58
70
206 6.87
1173.62
1873.36
3940.75
2175.21
1805.01
70
90
1056.16
2672.24
80
1971.82
90
2457.61
3936.68
414.83
2459.49
80
412.58
90
60
65 1.89
111 8.83
750.76
1748.05
60
4 92.78
4 93.52
904.08
602.01
2948.6 8
651.46
60
751.67
1344.49
12 42.49
1354.17
2990.98
751.24
50
50
%T
50
4 91.59
111 9.25
%T
1053.35
50
751.76
%T
50
%T
1448.37
50
1 230.04
%T
%T
751.20
111 9.55
40
40
111 9.18
30
1443.97
1346.8 9
1444.61
20
20
1500
1000
400.0
17 10.37
1711.36
4000.0
30
294 3.19
20
20
20
159 0.14
1591.09
1594.55
1634.58
10
1593.54
10
10
294 0.25
0.0
2000
10
1593.12
3441.28
1712.00
2941.52
3000
40
30
1713.95
2865.7 0
10
2866.52
3461.11
0.0
4000.0
2946.53
1315.05
1346.39
20
2864.48
1227.37
1594.24
10
1236.96
1352.19
2868.75
1313.22
30
1348.45
2866.1 3
40
1223.68
1426.65
30
1314.96
1444.50
40
1449.04
30
4 92.68
40
1222.77
4 92.02
3000
2000
cm-1
3447.81
0.0
1500
1000
400.0
4000.0
294 1.12
3 446.44
1711.08
0.0
3000
2000
1500
cm-1
1000
400.0
3000
2000
1500
1000
400.0
3444.09
3 450.91
0.0
4000.0
cm-1
4000.0
0.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
400.0
cm-1
SJC-Ph-D- 7.pk
SJC-Ph-D- 8.pk
SJC-Ph-D- 9.pk
SJC-Ph-D- 10.pk
SJC-Ph-D- 11.pk
SJC-Ph-D- 12.pk
SJC90F~1. SP 3601 4000. 00 400. 00 6.74 99. 65 4.00 %T 5 1. 00
SJD9 0B~1. SP 3601 4000.0 0 400.00 6. 88 99.65 4. 00 %T 5 1.00
SJD9 07~1. SP 3601 4000. 00 400. 00 5.01 100.00 4.00 %T 5 1.00
SJ8E4 F~1.SP 3601 4000.00 400 .00 6.32 100.00 4. 00 %T 5 1.00
SJ865F~1. SP 3601 4000.00 400.00 5.02 100. 00 4.00 %T 5 1. 00
SJ8E5 F~1.SP 3601 4000.00 400 .00 6.31 100.00 4. 00 %T 5 1.00
REF 4 000 88.66 2000 86.67 600

3940.76 84.43 3461.11 9. 68 2941.52 6. 87 2866.52 14.79 267 1.50 75.85
2459.49 86.83 2175.91 82.44 2066.87 82.78 1971.82 85. 56 1871.42 85. 70
1712.00 6. 74 1594.24 19 .62 1444.61 26.34 1344.49 28.76 1314.96 31.37
1227.37 26.28 1119.18 39.57 1053.35 54.35 904.08 59.03 863.95 68.44
751. 20 51 .31 650.73 63.15 492.02 43.9 6 414.83 75.36
REF 4 000 92.71 2000 91.14 600

3936.68 89.41 3441.28 11.71 2940.25 10.45 2864.48 25. 11 2672.80 84. 75
2457.61 91.64 2175.21 87.54 1805.01 83.36 1711.36 6.88 1593.12 17.15
1449.04 42.43 1426.65 44.77 1384.23 56.55 1346.89 36. 08 1313.22 45. 75
1222.77 47.09 1119.25 54.07 1054.29 77.26 1017.87 81. 61 904.66 71.89
863. 45 76 .54 751.24 59.09 651.79 67.9 4 491.59 56.32 412.58 85. 22
REF 4 000 97.62 2000 95.06 600

3940.98 94.82 3447.81 5 .01 2941.12 7. 74 2865. 70 18. 58 2672.24 87.45
2175.11 90.96 1803.58 8 4.06 1711.08 6. 06 1593.54 14.08 1443.97 32.69
1346.39 30.30 1315.05 3 8.41 1223.68 39.70 1119. 55 48.73 1055.82 74. 96
1018.97 82.81 903.09 69. 63 862.48 77 .91 751.76 55.62 651.89 64.69
492. 68 49 .14 415.26 84. 96
REF 4 000 98.52 2000 95.78 600

3940.75 96.28 3446.44 6 .32 2946.53 31.95 2868.75 41.80 2671.94 88.38
2337.75 95.09 2174.34 9 2.24 2069.77 91.69 1873. 36 96.44 1713.95 31. 60
1594.55 22.28 1444.50 4 7.28 1352.19 38.91 1236. 96 40.46 1173.62 77. 18
1118.83 64.78 1052.88 6 7.20 904. 39 81.12 861.80 86. 51 751.67 65.42
649. 90 70 .63 493.52 62. 98 416.46 89.84
REF 4 000 98.40 2000 95.00 600

3450.91 5. 02 2943. 19 31. 91 2866.13 47.66 2672.91 93.78 2095.64 91.51
1710.37 30.25 1634.58 2 7.40 1591.09 24.35 1448. 37 57.43 1348.45 49. 48
1314.41 62.31 1230.04 5 5.60 1119.06 71.11 1054. 03 79.63 904.81 84.57
862. 20 85 .71 750.76 65. 02 651.46 67.44 4 92. 78 64. 31
REF 4 000 99.52 2000 96.68 600

3444.09 6. 31 2990. 98 70. 97 2948.68 70.81 2103.19 93.89 1748.05 70.07
1590.14 25.54 1354.17 6 2.45 1242.49 67.03 1056. 16 89.49 602.01 68.68
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 02- 12-2009
FT IR SPECT RUM
Date: 02- 12-2009
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 02- 12-2009
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 02- 12-2009
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 02- 12-2009
FT IR SPECT RUM
Date: 02- 12-2009
100.0
100.0
100.0
3917.86
90
90
2099.44
1114.15
3941.98
414 .96
1872.84
2175.32
90
90
1871.57
39 39.33
90
1871.85
2866.79
2174.86
2735.12
1450.41
80
206 9.64
2 671.91
2988.54
70
70
30
30
2866.4 4
40
30
30
1358.98
1350.91
1 234.39
20
20
20
158 8.95
1594.37
1000
400.0
4000.0
cm-1
10
1592.46
10
17 11.30
0.0
3000
1593.35
10
294 1.88
294 0.86
1711.61
1500
12 42.90
1755.07
%T
40
1236.30
10
3457.36
0.0
2000
50
1350.38
%T
2945.90
30
1349.24
20
1594.23
10
3437.27
3000
596.99
2 992.52
50
1236.83
1447.80
2866.69
40
1445.54
2865.7 9
20
770.19
60
650.96
50
%T
30
1348.34
751.68
1383.31
4 92.81
1591.87
10
0.0
4000.0
1056.50
70
2946.69
60
65 0.92
751.82
4 93.75
751.75
111 8.87
40
1444.32
20
70
1053.46
1119.14
60
1053.66
50
%T
1052.50
40
2827.64
861.9 7
70
904.03
60
4 92.49
111 8.49
%T
1355.56
40
1172.18
80
2821.88
904.25
65 0.42
751.92
60
12 42.52
50
2067.03
64 9.01
1314.02
605.78
2949.03
50
2104.59
27 30.73
1223.48
80
26 72.75
862.19
70
903.61
766.39
60
%T
936.37
90
10 53.58
80
206 8.05
2671.32
860.41
1018.19
112 0.17
2130.01
415.97
80
1055.20
1753.55
3927.75
2174.91
2732.05
80
2000
1500
1000
400.0
0.0
3451.61
4000.0
cm-1
3000
2000
1500
1000
400.0
3 438.84
3437.20
4000.0
0.0
3000
cm-1
2000
1500
1000
400.0
0.0
3437.82
4000.0
cm-1
3000
2000
1500
1000
400.0
4000.0
cm-1
3000
2000
1500
1000
cm-1
SJC-Ph-D- 13.pk
SJC-Ph-D- 14.pk
SJC-Ph-D- 15.pk
SJC-Ph-D- 16.pk
SJC-Ph-D- 17.pk
SJC-Ph-D- 18.pk
SJ866F~1. SP 3601 4000.00 400.00 6.35 100. 00 4.00 %T 5 1. 00
SJ8E6 F~1.SP 3601 4000.00 400 .00 7.03 100.00 4. 00 %T 5 1.00
SJC-PH~4. SP 3601 4000. 00 400. 00 5.02 100.00 4.00 %T 5 1.00
SJC-PH~3. SP 3601 4000. 00 400. 00 5.05 99. 99 4.00 %T 5 1. 00
SJC-PH~2. SP 3601 4000. 00 400. 00 5.02 100.00 4.00 %T 5 0.50
SJC-PH~1. SP 3601 4000. 00 400. 00 6.34 99. 99 4.00 %T 5 0. 50
REF 4 000 99.50 2000 97.14 600

3437.27 6. 35 2988. 54 66. 60 2949.03 66.48 2732.05 93.58 2099.44 94.18
1753.55 64.20 1591.87 1 8.50 1355.56 51.26 1242. 52 58.89 1114.15 93. 28
1055.20 85.21 766.39 71. 35 605.78 68 .51
REF 4 000 98.07 2000 96.53 600

3941.98 96.46 3457.36 1 1.15 2940.86 12.17 2865. 79 27.97 2671.91 88. 97
2175.32 93.29 2069.64 9 3.13 1872.84 95.73 1711. 61 7.02 1594.23 23.26
1444.32 40.53 1348.34 3 8.57 1314.02 46.06 1236. 30 22.58 1118.49 55. 20
1052.50 54.96 903.61 75. 36 860.41 82 .10 751.92 65.83 649.01 73.55
492. 49 59 .49 414.96 87. 56
REF 4 000 98.24 2000 95.83 600

3939.33 95.78 3451.61 5 .01 2941.88 14.53 2866.44 28.76 2671.32 87.17
2174.91 91.81 2068.05 9 1.54 1871.57 95.36 1711. 30 11.36 1594.37 17. 35
1445.54 40.25 1349.24 3 5.70 1234.39 31.53 1118. 87 56.63 1053.66 62. 64
904. 03 75 .11 862.19 80. 83 751.75 61.66 6 50. 42 68. 51 492.81 58.47
415. 97 88 .65
REF 4 000 98.20 2000 95.47 600

3927.75 96.13 3437.20 5. 05 2945.90 37.35 2866.69 49.33 2672.75 89.39
2174.86 91.54 2067.03 91.49 1871.85 96.30 1593.35 15. 56 1447.80 56. 37
1350.91 40.01 1236.83 52.68 1119.14 72.14 1053.46 75. 80 904.25 82.97
861. 97 83 .61 751.82 62.22 650.92 64.6 7 493.75 62.42
REF 4 000 99.44 2000 96.21 600

3917.86 95.35 3437.82 5 .02 2946.69 72.57 2866.79 84.56 2821.88 86.71
2735.12 95.38 2130.01 9 2.80 1588.95 18.90 1450. 41 84.84 1383.31 65. 71
1350.38 56.67 1223.48 9 3.51 1120.17 94.90 1053. 58 98.38 1018.19 98. 43
751. 68 67 .32 650.96 63. 96
REF 4 000 99.87 2000 97.91 600

3438.84 6. 34 2992.52 63 .22 2827.64 82.12 2730.73 93.41 2104.59 94.91
1755.07 58.37 1592.46 15.78 1358.98 44.91 1242.90 56. 74 1172.18 88. 73
1056.50 85.87 936.37 98 .32 770.19 70.19 596.99 68.39
311
400.0
400.0
Table - 7.28
Cyclohexanone + 2-Butanone + Benzaldehyde
S1
(Cm-1)
3448.51
2941.93
2866.51
2175.91
1711.69
1595.65
1446.74
1354.51
1223.18
1172.10
1118.85
1059.52
1019.13
904.76
863.73
752.08
716.03
650.23
493.63
413.44
S2
(Cm-1)
3944.67
3457.73
2942.35
2871.12
2663.62
1972.83
1711.36
1598.16
1439.93
1353.82
1226.74
1117.94
1063.44
901.77
739.67
650.62
497.50
420.09
S3 (Cm1
)
3447.86
3069.30
2942.16
2866.54
2642.71
1974.42
1708.85
1596.96
1449.87
1420.52
1352.56
1313.87
1231.92
1173.12
1117.78
1065.99
1021.08
905.75
863.20
826.87
750.48
715.61
650.48
497.45
S4
(Cm-1)
3442.82
3073.87
2943.17
2867.99
2644.84
1975.34
1920.96
1704.93
1597.19
1448.74
1351.97
1312.56
1236.81
1173.78
1117.09
1066.46
1021.27
904.97
749.43
714.94
651.02
501.89
*S5
(Cm-1)
3446.96
3069.41
2942.51
2867.15
2742.55
2645.24
1975.55
1919.41
1705.87
1596.64
1449.33
1386.36
1351.77
1311.62
1235.59
1173.04
1117.10
1067.45
1021.03
905.62
826.00
748.84
713.93
651.02
501.47
S6
(Cm-1)
3442.44
3069.80
2942.72
2865.86
2739.70
2649.95
1975.26
1918.67
1703.09
1595.96
1494.87
1450.94
1354.83
1313.83
1234.88
1172.07
1117.71
1068.72
1022.21
906.73
827.00
748.77
713.83
650.53
503.14
S7
(Cm-1)
3926.06
3450.48
3069.57
2941.99
2862.37
2822.41
2737.39
2408.08
2329.79
2139.06
1981.34
1911.16
1705.45
1595.25
1450.76
1351.60
1312.23
1207.33
1167.56
1118.28
1066.74
1015.13
905.56
826.01
748.67
S8
(Cm-1)
3455.33
2941.26
2866.19
2671.91
2176.28
1711.42
1595.73
1446.34
1348.65
1315.11
1222.86
1171.71
1118.75
1058.44
1018.73
904.55
863.84
825.63
751.01
650.44
492.78
413.29
S9
(Cm-1)
3451.98
2941.65
2865.60
2671.02
2064.06
1710.16
1595.59
1449.08
1348.01
1313.51
1224.95
1170.56
1118.54
1059.18
1018.87
905.16
863.45
826.85
750.34
716.30
650.35
493.24
413.79

S10 (Cm1
)
3445.37
2943.73
2869.15
2646.87
2235.09
1921.41
1708.77
1596.65
1448.97
1355.35
1314.25
1238.22
1173.78
1117.06
1067.28
1021.49
905.83
748.96
715.07
651.03
505.60
S11
(Cm-1)
3450.00
3067.15
2941.91
2861.95
2820.02
2737.46
2330.72
1980.71
1911.34
1704.46
1595.94
1452.14
1353.16
1312.09
1205.81
1167.90
1117.60
1068.66
1016.37
906.76
826.78
748.60
689.61
650.23
494.02
451.80
S12
(Cm-1)
3443.87
3069.86
2943.11
2821.83
2737.74
2332.31
1981.13
1910.46
1702.89
1595.42
1452.76
1359.16
1311.86
1206.24
1168.08
1116.39
1070.05
1015.42
910.00
826.14
748.19
689.91
650.58
451.78
S13
(Cm-1)
3442.14
3070.49
2820.81
2738.04
2328.80
2138.82
1981.46
1910.80
1702.64
1595.07
1453.62
1362.57
1311.78
1204.63
1169.08
1112.48
1072.36
1014.09
928.19
826.07
747.66
689.62
650.62
451.70
S14
(Cm-1)
3444.08
3068.00
2942.19
2865.91
2739.88
2646.16
1975.45
1707.49
1596.27
1450.50
1420.82
1350.68
1313.25
1230.72
1171.85
1117.81
1067.22
1021.42
905.97
862.67
827.38
749.38
714.07
650.24
496.48
414.26
312
*S15
(Cm-1)
3445.39
3067.32
2941.79
2865.71
2740.90
2646.23
1974.43
1919.94
1705.31
1596.41
1493.86
1451.15
1419.53
1388.43
1348.91
1313.75
1231.60
1172.15
1117.93
1067.89
1021.76
905.78
862.33
827.51
749.24
714.42
S16
(Cm-1)
3926.44
3440.64
3073.46
2943.27
2867.00
2658.64
2282.60
1975.83
1918.10
1701.63
1595.85
1448.59
1356.49
1278.98
1174.82
1117.70
1068.12
1022.47
928.17
748.77
710.69
651.80
537.31
S17
(Cm-1)
3445.86
3071.96
2943.13
2820.87
2737.69
1982.04
1912.45
1704.02
1594.93
1452.71
1358.08
1312.34
1205.19
1169.06
1116.58
1070.56
1015.70
917.22
826.11
747.67
689.74
650.24
452.51
S18
(Cm-1)
3924.88
3443.26
3073.51
2821.42
2738.01
2330.10
1980.78
1912.52
1701.43
1594.83
1453.44
1361.19
1312.78
1204.68
1169.21
1114.77
1072.11
1015.31
928.42
825.71
747.00
689.37
650.48
451.87
Fig-7.28: FTIR Spectrums for Cyclohexanone+Benzaldehyde+Ethyl Acetate

mixture:
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08- 2-2010
FT IR SPECT RUM
Date: 08-2- 2010
Spec trum Na me: SJC-PH-D-4. sp
100.0
90
3935.83
197 5.66
100.0
100.0
90
90
80
1915.94
80
80
70
70
70
501.24
907.01
60
774.86
2989.93
1056.32
2666.94
60
1067.46
50
1712.80
3178.88
40
40
111 5.60
1450.63
2866.06
3000
2000
1500
1000
400.0
0.0
4000.0
cm-1
3000
2000
1500
1000
400.0
3000
2000
1500
286 5.95
1000
400.0
20
1 358.40
2867.87
3195.28
3428.99
10
3000
2000
1238.76
2943.12
1 708.55
1 711.18
0.0
4000.0
1500
1000
400.0
2940.78
10
1597.79
cm-1
30
715.19
1173.38
1447.95
1238.90
0.0
4000.0
cm-1
3452.4 5
40
751.09
3071.18
20
15 99.84
1706.27
1 706.59
0.0
4000.0
650 .50
1060.59
1115.66
30
1 359.49
2868.59
10
2942.14
2942.85
1594.61
0.0
1239.34
10
16 00.09
40
713 .93
1447.53
3424.79
20
1597.31
3069.24
2942.63
1224.50
1115.80
30
20
1226.12
10
1365.19
12 41.76
%T
2651.3 2
1311.82
306 7.26
2866.34
750.05
40
714 .05
1171.52
30
1 360.06
3067 .20
749.31
3403.71
710.15
3447.33
20
1762.14
10
1312.17
1446.82
50
%T
650.85
1064.33
749.22
60
498.41
826.84
50
2651.44
%T
65 0.30
750.21
1 448.92
30
3437.28
20
50
1060.10
650.80
40
30
0.0
1707.3 2
4000.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
400.0
cm-1
SJC-PH-D- 1.pk
SJC-PH-D-2. pk
SJC-PH-D-3. pk
SJC-PH-D-4. pk
SJC-PH-D-5. pk
SJC-Ph-D-6.pk
SJ9907~1.SP 3601 4000. 00 400.00 6.67 99.82 4.00 %T 5 1. 00
SJ9903~1. SP 3601 4000.00 400. 00 6.60 99.99 4.00 %T 5 1.00
SJC-PH~4.SP 3601 4000. 00 400.00 6.65 99. 99 4.00 %T 5 1.00
SJA90B~1.SP 3601 4000. 00 400.00 6.72 100.00 4. 00 %T 5 1.00
SJA907~1.SP 360 1 4000. 00 400.00 5.26 99.99 4. 00 %T 5 1.00
SJC-PH~4.SP 3601 4000. 00 400.00 8.54 100.00 4. 00 %T 5 1.00
REF 4 000 99.80 2000 94.10 600

3927.26 97.78 3437.28 27.46 2989.93 57.65 2832.68 65. 93 2721.34 89. 47
1762.14 23.17 1712.80 37.69 1594.61 6.67 1365.19 14.03 1241.76 15.08
1056.32 56.66 924.76 95 .95 774.86 64.59 627.14 77.93 535.01 80.78
REF 4000 98.88 2000 94. 18 600

3447. 33 33.58 31 78. 88 36. 03 3067.20 31.40 2942.63 15.20 2866. 34 27.04
2739. 08 56.28 19 75. 66 92. 30 1913.90 91.01 1706.59 6. 59 1600. 09 15.79
1448. 92 41.97 13 60. 06 31. 08 1310.35 34.76 1226.12 24.69 1116. 46 53.70
1067. 46 66.03 10 22. 88 75. 13 906.96 79.37 826.90 61.52 750.21 40.02
710.15 40.51 650. 80 54.73 501.24 76.6 5 453.53 85. 20
REF 4000 98.52 2000 94. 34 600

3935. 83 97.39 34 03. 71 42. 61 3067.26 33.29 2942.14 14.47 2866. 06 27.17
2739. 71 60.22 26 66. 94 66. 34 1974.48 92.45 1915.94 91.14 1706. 27 6.65
1597. 31 25.72 14 50. 63 39. 90 1364.00 38.32 1311.82 34.08 1239. 34 17.13
1171. 52 42.12 11 15. 60 48. 34 1060.10 55.51 907.01 73.9 1 827.76 62. 78
749.31 44.42 714. 05 40.35 650.30 54.9 9 496.78 75. 59 453.18 86.01
414.64 91.40
REF 4000 98.33 2000 93. 03 600

3424. 79 26.30 3069.24 22.97 2942.85 10.22 28 68. 59 19. 53 2651.44 53.19
1918. 05 89.27 1708.55 6.72 1599.84 19.11 1447.53 36. 01 1359. 49 29.34
1238. 90 16.85 1115.80 44.49 1064.33 54.69 90 6.53 68. 52 826.82 64. 21
750.05 47.31 713.93 37.44 650.85 54.00 501.40 69.71
REF 4000 97.91 2000 94. 89 600

3930. 26 96.69 34 28. 99 17. 89 3195.28 19.68 3071.18 19.06 2943. 12 7.07
2867. 87 14.53 26 51. 32 52. 80 1918.54 91.92 1707.32 5. 26 1597. 79 11.02
1447. 95 29.20 13 58. 40 20. 99 1238.76 11.17 1173.38 32.94 1115. 66 38.70
1060. 59 47.99 90 5.04 67.53 860.86 69.43 826.8 4 67.07 751. 09 46.45
715.19 32.75 650. 50 49.97 498.41 62.7 6 415.07 89. 00
REF 4000 98.89 2000 98. 30 600

3778. 90 95.20 3452.45 49.34 3066.93 81.09 29 40. 78 23. 02 2865.95 48.57
2738. 58 91.14 2340.54 97.27 1711.18 8. 54 1599.26 70. 56 1446. 82 60.33
1386. 63 73.36 1312.17 64.45 1224.50 51.50 11 68. 91 79. 21 1117.48 71.07
1057. 09 79.78 905.22 88.08 827.42 85 .19 749. 22 67.00 694. 44 80. 11
650.12 78.86 492.00 80.79 415.28 94.86
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
862.82
100.0
100.0
FT IR SPECT RUM
Date: 08-2- 2010
Spec trum Na me: SJC-PH-D-12.sp
100.0
90
862.51
1917.02

100.0
416.14
3816.59
90
39 28.06
2673.49 217 4.97
FT IR SPECT RUM
Date: 08-2- 2010
413.66
412.03
90
3935.90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
100.0
11 67.38 1019.71
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
90
3797.75
90
3929.21
197 4.15
20 84.05
3929.67
197 6.88
197 6.81
3934.40
80
80
80
80
1916.67
2724.45
80
1917.72
649.91
142 6.56
773.32
60
70
70
905.93
60
80
50
1313.52
3 068.39
40
1233.74
30
40
714 .19
40
1116.42
1311 .56
750.32
3069.18
2865.74
1 357.28
20
3194.15
3440.62
1231.99
4000.0
3000
2000
2942.46
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
2000
3069.99
105 3.28
2823.57
3442.84
2864.82
2948.27
20
1367.83
2943.54
10
1597.80
1000
400.0
1242.13
0.0
1704.70
4000.0
1368.51
10
15 99.47
1241.38
1603.28
1703.36
1 703.01
0.0
1500
708.91
1448.37
30
749.71
2821.56
3000
2000
cm-1
1500
1000
400.0
0.0
4000.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
2000
cm-1
1243.62
1500
1000
SJC-PH-D-8. pk
SJC-PH-D-9. pk
SJC-PH-D-10.pk
SJC-PH-D-11.pk
SJC-PH-D-12.pk
SJA90F~1.SP 3601 4000. 00 400.00 7.01 99. 90 4.00 %T 5 1.00
SJC-PH~2.SP 3601 4000. 00 400.00 6.59 100.00 4. 00 %T 5 1.00
SJB907~1.SP 3601 4000.00 400.0 0 6.76 100. 00 4.00 %T 5 1.00
SJC-PH~3.SP 3601 4000. 00 400.00 6.66 99. 99 4.00 %T 5 1.00
SJ665F~1.SP 3601 4000.00 400.0 0 6.72 100. 00 4.00 %T 5 1.00
SJC-PH~1.SP 3601 4000. 00 400.00 7.00 99. 99 4.00 %T 5 1.00
REF 4000 97.12 2000 95. 74 600

3935. 90 94.23 34 16. 02 29. 31 2940.85 15.27 2864.32 33.49 2724. 45 87.95
2673. 49 91.24 21 74. 97 94. 27 1711.54 7.00 1595. 10 11.1 6 1449. 91 46.35
1426. 56 49.36 13 59. 72 26. 89 1313.35 48.99 1233.74 35.74 1167. 38 89.22
1118. 57 58.85 10 53. 72 65. 92 1019.71 83.14 905.36 79.6 5 862.82 84. 18
773.32 69.53 751. 54 66.92 649.91 76.3 7 491.24 69. 08 412.03 91.28
REF 4000 98.36 2000 94. 68 600

3928. 06 96.66 3438.02 30.93 3196.65 35.32 30 68. 39 33. 72 2942.46 13.74
2865. 74 25.26 2738.45 61.86 2670.32 67.27 19 17. 02 91. 58 1706.97 6. 59
1597. 14 14.57 1450.48 37.99 1419.95 42.80 13 58. 49 26. 98 1313.52 34.24
1231. 99 26.68 1171.87 46.42 1117.11 49.17 10 66. 22 63. 85 1021.67 73.00
905.93 76.08 862.51 78.05 827.65 68.45 750.06 48.08 714. 19 41.95
650.20 56.70 496.07 72.72 413.66 91.21
REF 4000 98.19 2000 92. 90 600

3934. 40 95.47 3816.59 95.94 3440.62 22.51 31 94. 15 25. 99 3069.18 24.16
2942. 93 9.12 2867.50 18.52 2662.74 57.47 1974.15 90. 54 1916. 67 89.55
1709. 41 6.76 1598.55 12.90 1447.83 34.34 1357.28 26. 76 1311. 56 30.58
1235. 60 22.08 1116.42 45.46 1065.06 57.79 10 23. 04 68. 32 905.76 73.38
827.08 64.26 750.32 43.97 712.21 39.92 650.50 54.94 497. 98 68.82
416.14 91.22
REF 4000 98.36 2000 90. 92 600

3929. 21 96.02 34 16. 52 16. 99 3188.26 16.24 3071.26 14.90 2944. 02 8.45
2868. 81 15.67 26 59. 07 41. 92 1917.72 85.04 1704.70 6. 66 1597. 80 10.62
1448. 65 31.41 13 67. 66 21. 59 1241.38 11.52 1115.06 40.96 1062. 51 47.02
909.11 63.63 826. 49 53.34 748.53 37.6 6 712.88 29. 87 651.22 44.33
507.28 66.86
REF 4000 98.68 2000 92. 61 600

3445. 88 33.77 3193.80 35.41 3066.83 31.33 29 43. 54 18. 84 2864.82 30.56
2821. 56 33.50 2738.25 52.79 1976.88 90.35 19 13. 21 88. 20 1703.01 6. 72
1599. 47 12.08 1451.63 39.01 1367.83 23.47 13 11. 74 32. 89 1242.13 10.73
1170. 47 43.20 1114.34 52.86 1056.95 48.71 90 9.35 77. 79 827.47 54. 24
749.71 36.27 714.39 40.46 650.27 47.96 498.57 77.55 452. 23 77.67
REF 4000 99.05 2000 92. 64 600

3929. 67 97.69 37 97. 75 96. 16 3442.84 30.86 3069.99 34.54 2948. 27 28.71
2823. 57 35.06 27 36. 40 54. 08 2551.39 64.57 2084.05 95.45 1976. 81 89.90
1913. 35 85.36 17 03. 36 6.99 1603.28 9. 10 1448. 37 41.29 1368. 51 16. 16
1243. 62 9.21 1110.35 54.21 1053.28 38.49 930.41 63.61 825.56 55.92
753.42 43.10 708. 91 40.20 650.92 48.7 1 541.90 69. 78 451.92 76.52
ACIC
Tric hy-2
ACIC
Tric hy-2
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 15-2- 2010
100.0
100.0
1823.01
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
3884.7 3
11 09.72
2331.80
3779.20
2027.35
80
100.0
2177.01
100.0
90
1914.63
29 93.21
70
829.46
2 671.87
904.70
862.99
60
649.23
1167.76
3067.11
2818.59
716.25
30 67.13
491.68
826.90
1055.68
%T
753.32
40
649.91
1385.51
3454.09
1052.85
20
1171.5 0
40
3069.44
3433.10
2861.08
1170.48
%T
273 8.71
1596.95
1169.05
3068.08
746.34
826.73
650 .61
691.66
40
1595.91
1208.16
30
1 452.81
2819.25
1383.83
708.49
1288.12
2942.94
50
650.96
30
747.07
1353.97
20
20
1596.54
2866 .44
3412.50
1445.87
10
0.0
1500
1000
400.0
4000.0
cm-1
1 236.66
2000
2942.13
1 238.76
1 713.33
1500
1000
400.0
4000.0
1242.74
2000
10
1703.82
0.0
3000
20
10
1 708.06
1 712.07
0.0
cm-1
20
1239.30
2942.18
10
1599.22
2943.33
3000
1596.97
10
1 357.96
2866.44
1702.57
2000
105 5.76
826.71
139 2.64
28 21.03
1117.94
746.76
12 06.48
1242.56
10
3000
1 451.55
3391 .68
1362.89
2865.95
30
1446.90
451.07
3197.19
60
27 38.87
50
%T
714 .21
1449.5 5
40
30
70
60
650.45
7 49.24
3407.23
1 117.11
30
1595.96
20
0.0
4000.0
538.82
927.44
450.97
1112.33
70
10 60.47
3171.11
50
%T
40
1315.23
1107.9 6
1911.07
2546.91
827.09
273 8.92
60
493.24
751.20
3068.01
688.90
30
3442.43
1981.01
1114.61
1313.30
50
%T
649.77
60
904.77
50
1453.62
2333.53
80
542.49
1070.56
70
1170.70
2674.13
451.42
1060.30
2737.88
2946.73
37 79.66
923.83
1018.88
80
498.17
2545.57
70
1310.0 2
60
40
90
2362.24
1915 .23
80
198 1.84
70
50
100.0
1980.26
3778.76
2065.90
905.95
%T
FT IR SPECT RUM
Date: 15-2- 2010
Spec trum Na me: SJC-Ph-D-18. sp
453.4 2
90
861.93
3934.63
80
1969.42
3940.45
413.81
90
2465.19
2176.60
80
5 44.25
FT IR SPECT RUM
Date: 15-2- 2010
100.0
2068.14
90
924.24
1907.88
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
413.97
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
400.0
cm-1
SJC-PH-D-7. pk
650.92
75 3.42
3193.80
2868 .81
3188.26
2944.02
1709.41
cm-1
3445.88
40
71 4.39
1451.63
30
712 .88
20
10
1598.55
2942.93
0.0
2 736.40
1367.66
3416.52
10
1597.14
1 706.97
0.0
1500
1 448.65
20
1 235.60
2867.50
10
1595.10
1711.54
650.27
1170.4 7
748.53
30
1447.8 3
30 71.26
1 358.49
20
2940.85
93 0.41
825.56
%T
1056.95
30 66.83
40
2551 .39
50
827.47
1311.74
651.22
1115.06
712.21
30
3196.65
3438.02
1 359.72
10
0.0
451.92
1110.35
60
2 738.25
%T
1062.5 1
265 9.07
541.90
60
50
826.49
%T
750.06
1450.48
30
1313.35
2864.32
3416.02
20
1117.11
1171.87
1 449.91
70
452.23
507.28
9 09.11
50
650.50
2662.7 4
%T
650.20
60
1065.06
50
%T
40
1913.35
4 98.57
9 09.35
497.98
1066.22
1 419.95
2738.45
70
905.76
1023.0 4
827.08
60
2670.32
1118.57
50
70
496.07
1021.6 7 827.65
491.24
751.54
10 53.72
1 114.34
1913.21
905.36
70
%T
492.00
650.12
15 99.26
905.04
60
826.82
2739.71
50
%T
1116.46
501.40
60
827.76
1364.00
1310 .35
2739.08
%T
1057.09
70
1 117.48
826.90
50
905.22
2738.58
80
827.42
496.78
906.53
2832.68
60
694.44
1 386.63
860.86
453.18
1168.91
2 340.54
3066.93
3 778.90
4 15.07
1918.54
906.96
70
1022.88
%T
415.28
90
3930.26
1918.05
1913.90
80
535.01
6 27.14
70
Spec trum Na me: SJC-Ph-D-6.sp

100.0
197 4.48
2721.34
80
FT IR SPECT RUM
Date: 15-2- 2010
414.64
4 53.53
90
924.76
3927.26
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
100.0
90
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
100.0
ACIC
Tric hy-2
FT IR SPECT RUM
Date: 08-2- 2010
Spectrum Name: SJC-PH-D-1. sp
1500
1000
400.0
4000.0
1 704.11
0.0
3000
cm-1
2000
1500
1000
400.0
4000.0
cm-1
0.0
3000
2000
1500
1000
400.0
4000.0
cm-1
3000
2000
1500
1000
cm-1
SJC-Ph-D-13. pk
SJC-PH-D-14.pk
SJC-PH-D-15.pk
SJC-PH-D-16.pk
SJC-Ph-D-17. pk
SJC-Ph-D-18. pk
SJ866F~1.SP 3601 4000.00 400.0 0 7.88 99.95 4.00 %T 5 1.00
SJ6E6F~1.SP 360 1 4000. 00 400.00 5.60 100. 00 4.00 %T 5 1. 00
SJ667F~1.SP 3601 4000.00 400.0 0 6.84 100. 00 4.00 %T 5 1.00
SJ6E7F~1.SP 360 1 4000. 00 400.00 6.79 99.99 4. 00 %T 5 1.00
SJC-PH~1.SP 3601 4000. 00 400.00 6.32 99. 99 4.00 %T 5 1.00
SJC-PH~3.SP 3601 4000. 00 400.00 6.30 99. 99 4.00 %T 5 1.00
REF 4000 98.78 2000 93. 48 600

3884. 73 96.71 37 79. 20 90. 85 3442.43 33.06 3067.11 49.33 2993. 21 54.39
2946. 73 54.50 28 18. 59 49. 34 2737.88 55.46 2331.80 95.04 2027. 35 92.99
1981. 84 91.54 19 07. 88 92. 24 1823.01 91.21 1702.57 7. 87 1595. 96 32.04
1453. 62 53.56 13 85. 51 44. 19 1310.02 47.75 1242.56 18.94 1206. 48 29.38
1167. 76 50.22 11 09. 72 71. 68 1060.30 61.42 924.24 87.5 5 826.90 47. 35
746.76 29.35 688. 90 41.27 649.91 43.7 6 544.25 84. 22 451.42 68.07
REF 4000 95.76 2000 92. 11 600

3940. 45 90.69 3412.50 20.46 2943.33 5. 60 2866.44 11. 86 2674. 13 74.22
2465. 19 92.32 2176.60 90.18 2068.14 89.17 19 69. 42 89. 19 1713.33 5. 89
1599. 22 8.72 1445.87 19.67 1357.96 13.48 1315.23 23. 88 1238. 76 6.32
1117. 94 33.47 1052.85 30.09 904. 77 57.20 862. 99 68.86 753.32 48. 20
649.23 67.08 491.68 50.24 413.97 82.34
REF 4000 97.48 2000 96. 08 600

3934. 63 95.06 3454.09 30.08 3067.13 47.02 29 42. 13 9.45 2866. 44 20.94
2671. 87 77.84 2177.01 96.13 2065.90 95.73 17 12. 07 6.84 1596. 97 20.21
1446. 90 34.19 1353.97 30.71 1313.30 36.38 12 36. 66 18. 81 1170.70 56.77
1117. 11 47.39 1055.68 52.97 904. 70 74.96 861. 93 79.83 829.46 80. 66
751.20 56.67 716.25 64.15 649.77 68.55 493.24 64.63 413. 81 89.58
REF 4000 99.15 2000 95. 92 600

3407. 23 48.76 31 71. 11 47. 11 3068.01 42.29 2942.18 20.11 2865. 95 36.75
2738. 92 68.40 19 14. 63 93. 27 1708.06 6.79 1596. 54 25.3 8 1449. 55 49.25
1362. 89 39.45 12 39. 30 25. 13 1171.50 50.71 1114.61 60.44 1060. 47 65.20
905.95 83.06 827. 09 70.65 749.24 53.3 4 714.21 50. 63 650.45 64.07
498.17 82.88 453. 42 90.63
REF 4000 99.41 2000 96. 36 600

3778. 76 96.94 34 33. 10 41. 18 3069.44 44.99 2942.94 46.08 2861. 08 54.21
2821. 03 53.27 27 38. 87 63. 96 2545.57 82.67 2362.24 94.43 1980. 26 95.18
1915. 23 94.97 17 03. 82 6.32 1596.95 40.89 1451. 55 62.1 7 1392. 64 58.21
1288. 12 46.77 12 08. 16 38. 14 1170.48 55.69 1112.33 76.61 1070. 56 82.82
1018. 88 87.96 92 3.83 90.31 826.71 60.74 746.3 4 40.16 708. 49 47.60
650.96 54.86 542. 49 86.50 450.97 82.1 1
REF 4000 99.71 2000 95. 23 600

3779. 66 96.64 33 91. 68 58. 61 3197.19 62.05 3068.08 52.44 2819. 25 53.08
2738. 71 60.45 25 46. 91 86. 11 2333.53 94.76 1981.01 93.68 1911. 07 93.09
1704. 11 6.30 1595.91 40.01 1452.81 58.55 1383. 83 47.6 6 1242. 74 21.71
1169. 05 53.97 11 07. 96 73. 56 1055.76 63.69 927.44 83.9 5 826.73 53. 16
747.07 35.26 691. 66 48.70 650.61 52.0 6 538.82 87. 72 451.07 77.09
313
400.0
Table - 7.29
Cyclohexanone + Benzaldehyde + Ethyl Acetate:
S1
(Cm-1)
3927.26
3437.28
2989.93
2832.68
2721.34
1762.14
1712.80
1594.61
1365.19
1241.76
1056.32
924.76
774.86
627.14
535.01
S2
(Cm-1)
3447.33
3178.88
3067.20
2942.63
2866.34
2739.08
1975.66
1913.90
1706.59
1600.09
1448.92
1360.06
1310.35
1226.12
1116.46
1067.46
1022.88
906.96
826.90
750.21
710.15
650.80
501.24
453.53
*S3 (Cm1
)
3935.83
3403.71
3067.26
2942.14
2866.06
2739.71
2666.94
1974.48
1915.94
1706.27
1597.31
1450.63
1364.00
1311.82
1239.34
1171.52
1115.60
1060.10
907.01
827.76
749.31
714.05
650.30
496.78
453.18
414.64
S4
(Cm-1)
3424.79
3069.24
2942.85
2868.59
2651.44
1918.05
1708.55
1599.84
1447.53
1359.49
1238.90
1115.80
1064.33
906.53
826.82
750.05
713.93
650.85
501.40
S5
(Cm-1)
3930.26
3428.99
3195.28
3071.18
2943.12
2867.87
2651.32
1918.54
1707.32
1597.79
1447.95
1358.40
1238.76
1173.38
1115.66
1060.59
905.04
860.86
826.84
751.09
715.19
650.50
498.41
415.07
S6
(Cm-1)
3778.90
3452.45
3066.93
2940.78
2865.95
2738.58
2340.54
1711.18
1599.26
1446.82
1386.63
1312.17
1224.50
1168.91
1117.48
1057.09
905.22
827.42
749.22
694.44
650.12
492.00
415.28
S7
(Cm-1)
3935.90
3416.02
2940.85
2864.32
2724.45
2673.49
2174.97
1711.54
1595.10
1449.91
1426.56
1359.72
1313.35
1233.74
1167.38
1118.57
1053.72
1019.71
905.36
862.82
773.32
751.54
649.91
491.24
412.03
S8
(Cm-1)
3928.06
3438.02
3196.65
3068.39
2942.46
2865.74
2738.45
2670.32
1917.02
1706.97
1597.14
1450.48
1419.95
1358.49
1313.52
1231.99
1171.87
1117.11
1066.22
1021.67
905.93
862.51
827.65
750.06
650.20
496.07
*S9
(Cm-1)
3934.40
3816.59
3440.62
3194.15
3069.18
2942.93
2867.50
2662.74
1974.15
1916.67
1709.41
1598.55
1447.83
1357.28
1311.56
1235.60
1116.42
1065.06
1023.04
905.76
827.08
750.32
712.21
650.50
497.98
416.14
S16
(Cm-1)
3407.23
3171.11
3068.01
2942.18
2865.95
2738.92
1914.63
1708.06
1596.54
1449.55
1362.89
1239.30
1171.50
1114.61
1060.47
905.95
827.09
749.24
714.21
650.45
498.17
453.42
S17
(Cm-1)
3778.76
3433.10
3069.44
2942.94
2861.08
2821.03
2738.87
2545.57
2362.24
1980.26
1915.23
1703.82
1596.95
1451.55
1392.64
1288.12
1208.16
1170.48
1112.33
1070.56
1018.88
923.83
826.71
746.34
708.49
650.96
450.97
S18
(Cm-1)
3779.66
3391.68
3197.19
3068.08
2819.25
2738.71
2546.91
2333.53
1981.01
1911.07
1704.11
1595.91
1452.81
1383.83
1242.74
1169.05
1107.96
1055.76
927.44
826.73
747.07
691.66
650.61
538.82
451.07

S10 (Cm-1)
3929.21
3416.52
3188.26
3071.26
2944.02
2868.81
2659.07
1917.72
1704.70
1597.80
1448.65
1367.66
1241.38
1115.06
1062.51
909.11
826.49
748.53
712.88
651.22
507.28
S11
(Cm-1)
3445.88
3193.80
3066.83
2943.54
2864.82
2821.56
2738.25
1976.88
1913.21
1703.01
1599.47
1451.63
1367.83
1311.74
1242.13
1170.47
1114.34
1056.95
909.35
827.47
749.71
714.39
650.27
498.57
452.23
S12
(Cm-1)
3929.67
3797.75
3442.84
3069.99
2948.27
2823.57
2736.40
2551.39
2084.05
1976.81
1913.35
1703.36
1603.28
1448.37
1368.51
1243.62
1110.35
1053.28
930.41
825.56
753.42
708.91
650.92
541.90
451.92
*S13
(Cm-1)
3884.73
3779.20
3442.43
3067.11
2993.21
2946.73
2818.59
2737.88
2331.80
2027.35
1981.84
1907.88
1823.01
1702.57
1595.96
1453.62
1385.51
1310.02
1242.56
1206.48
1167.76
1109.72
1060.30
924.24
826.90
746.76
451.42
S14
(Cm-1)
3940.45
3412.50
2943.33
2866.44
2674.13
2465.19
2176.60
2068.14
1969.42
1713.33
1599.22
1445.87
1357.96
1315.23
1238.76
1117.94
1052.85
904.77
862.99
753.32
649.23
491.68
413.97
S15
(Cm-1)
3934.63
3454.09
3067.13
2942.13
2866.44
2671.87
2177.01
2065.90
1712.07
1596.97
1446.90
1353.97
1313.30
1236.66
1170.70
1117.11
1055.68
904.70
861.93
829.46
751.20
716.25
649.77
493.24
413.81

314
Fig-7.29: FTIR spectrums for Cyclhexanone + Ethyl Acetate + 2-Butanone

mixture:
ACIC
St.Joseph's College ( Autonomo us )
Trichy-2
FTIR SPECTRUM
Date: 03-12-2009
ACI C
St. Joseph's Colleg e ( Autonomous )
T richy-2
Spectrum Name: SJC-Ph -D-1.sp

10 0. 0
90
ACIC
Tric hy-2
ACIC
Tric hy-2
80
FTIR SPECTRUM
Date: 03-1 2-200 9
413.27
1172.66
FT IR SPECT RUM
Date: 03- 12-2009
Spectrum Na me: SJC-Ph-D-2.sp
2176.04
3788.49
ACIC
Tric hy-2
100.0
100.0
90
90
FT IR SPECT RUM
Date: 03- 12-2009
FT IR SPECT RUM
Date: 03- 12-2009
100.0
100.0
100.0
863.72
2673.39
1054.67
905.15
3927.93
1018.47
861 .50
80
751.78
80
80
416.20
70
903.29
80
6 49.90
60
650.90
1172.47
392 7.50
3793.60
1054.63
60
903.20
60
752.07
754.07
1054.15
2173.53
70
904.11
2672.60
64 9.91
1055.56
904.99
1314.07
2175.71
3928.10
2 673.57
70
863 .56
2672.36
60
559.88
1055.28
4 91.94
111 9.05
649 .71
753 .18
492.3 8
11 19.18
50
%T
50
50
751.69
4 91.47
%T
50
4 92.04
1119.36
%T
50
%T
11 19.18
%T
587.69
111 9.18
1 223.19
1222.8 9
40
1350.61
2175.76
3788.52
3790.58
70
105 5.2090 3.33
60
1314.28
1448.22
30
90
414.55
862.8 0
2175.61
1 018.91
2673.92
3931.42
1119.36
1222.68
40
90
861 .26
413 .32
80
2175 .84
3784.96
70
491.59
50
%T
1020.15
3931.53
90
651.14
60
20
FT IR SPECT RUM
Date: 03- 12-2009
1804.84
70
40
1 227.85
40
40
1445.16
755.49
1223.85
1 444.52
1348.36
1448.21
30
30
1444.42
30
30
2866.09
3420.47
1595.46
1351.62
20
2865.6 0
2864.88
20
20
20
2864.86
1712.31
0. 0
4 00 0. 0
1350.34
1351.08
2865.46
20
2940.99
30 00
1 50 0
1 00 0
1353.25
3 431.36
3 439.70
10
2 00 0
10
40 0 .0
2941.2 4
cm -1
171 1.17
10
3420.01
294 0.97
3000
2000
1500
1000
400.0
4000.0
cm-1
3431.58
17 12.05
0.0
4000.0
10
1595.16
15 95.42
0.0
SJC-Ph-D-1.pk
3000
294 0.55
1500
1000
400.0
10
294 0.81
1595.65
17 11.36
3436.14
0.0
4000.0
3000
2000
1500
cm-1
294 2.42
17 12.65
17 11.82
0.0
2000
1595.38
1000
400.0
1594.99
0.0
4000.0
3000
2000
1500
cm-1
1000
400.0
4000.0
3000
2000
1500
cm-1
1000
SJ C-Ph-D-2.pk
SJC-Ph-D- 3.pk
SJC-Ph-D- 4.pk
SJC-Ph-D- 5.pk
SJC-Ph-D- 6.pk
REF 4000 88.78 2000 87.99 600

3927.97 85.91 37 88.49 84.61 342 0.47 16.33 2940.99 11.72 2865.29 26.25
2673.39 80.60 21 76.04 84.99 180 4.84 79.55 1712.31 7.45 1595.46 15.2 9
1448.22 39.98 13 50.61 30.91 131 4.28 45.22 1222.68 48.05 1172.66 77.18
1119.36 54.46 10 54.67 75.08 101 8.13 79.40 905.1 5 71.81 863.72 76.49
751.78 60.58 651.14 69.69 491.59 56 .71 4 13.27 80.34
SJ B90 3~1.SP 3601 4000.00 400 .00 6.31 99.58 4 .0 0 % T 5 1.00
SJB90 F~1.SP 3601 4000.00 400 .00 7.42 98.98 4.00 %T 5 1. 00
SJC90B~1. SP 3601 4000. 00 400. 00 7.08 99. 87 4.00 %T 5 1. 00
SJC907~1.SP 3601 4000.00 400 .00 8.04 99.68 4.00 %T 5 1. 00
SJC903~1.SP 3601 4000.00 400 .00 5.30 99.43 4.00 %T 5 1. 00
REF 4 000 87.29 2000 85. 89 600

39 31.42 82.79 3784. 96 81.45 3439.70 6.31 2941. 24 11 .45 2865.46 27.10
26 73.92 79.58 2175. 84 82.26 1711.17 8.85 1595. 42 7. 48 1444.52 40. 17
13 51.08 26.73 1223. 19 49.72 1119.18 55. 77 105 5. 20 73.03 1018.91 77. 60
90 3. 33 70.43 861.50 72.39 753.18 53.49 649. 71 59.94 559 .8 8 61.46
49 2. 38 52.58
REF 4 000 86.78 2000 86.01 600

3927.93 83.62 3790.58 81.90 3420.01 13.77 2940.97 9.61 2864.86 23.69
2672.36 78.90 2175.61 82.90 1712.05 7.42 1595.16 12.54 1448.21 38.64
1350.34 29.32 1314.07 42.85 1223.85 43.49 1119.18 50. 95 1054.15 67. 92
1018.47 74.60 904.99 68 .67 863.56 73.12 751.69 57.26 650.90 65.91
491. 47 53 .39 413.32 78.61
REF 4 000 88.63 2000 87.88 600

3931.53 85.79 3788.52 83.89 3431.58 11.94 2940.55 11. 10 2864.88 27. 74
2673.57 82.37 2175.76 84.89 1711.36 7.08 1595.65 10.34 1444.00 44.44
1351.62 31.26 1222.89 52.77 1119.36 56.47 1055.56 73. 99 1020.15 78. 02
903. 29 73 .90 861.26 78.65 754.07 61.1 6 649.91 68.43 492.04 56. 65
416. 20 81 .52
REF 4 000 89.65 2000 88.80 600

3928.10 87.41 3431.36 18.95 2940.81 13.01 2865.60 30. 40 2672.60 83. 27
2175.71 86.26 1711.82 8. 04 1595.38 20.53 1445.16 44.62 1348.36 39.86
1225.70 46.88 1119.05 58.07 1054.63 72.76 904.11 73.92 862.80 78.05
752. 07 64 .08 649.90 71.91 491.94 60.4 2 414.55 83.95
REF 4 000 81.31 2000 80.29 600

3927.50 76.71 3793.60 72.92 3436.14 5.61 2942.42 14.95 2866.09 32.34
2173.53 76.45 1712.65 11.57 1594.99 5.30 1444.42 42.25 1353.25 22.81
1227.85 48.63 1172.47 71.60 1119.18 59.91 1055.28 69. 28 903.20 70.74
755. 49 49 .41 587.69 54.57 493.59 52.0 1
ACI C
T richy-2
ACIC
Tric hy-2
ACI C
T richy-2
100.0
100.0
100.0
80
90
217 5.11
863.95
80
4 15.26
70
651.79
751 .76
50
11 19.25
111 9.18
1426.6 5
30
30
1313.2 2
20
30
144 3.97
2946.53
1 315.05
30
30
1713.9 5
2943.1 9
20
20
20
159 1.09
1594.55
2 865.7 0
1590.14
1634.58
10
1593.12
3 441.28
10
1593.54
10
10
2940.2 5
1711.36
3 447.8 1
0.0
4000.0
40
171 0.37
1346.39
20
2864.48
10
0.0
400.0
1242 .49
1354 .17
13 48.45
28 66.13
40
1236.96
1352.19
1227.37
1712.00
1000
602 .01
1748.05
299 0.98
50
%T
144 4.50
286 8.75
30
134 6.89
1314.96
1444.61
492.6 8
1 223.6 8
1594.24
2866.52
1500
2 948.68
60
492.7 8
1230 .04
%T
40
1449.04
0.0
2000
750.76
1 448.37
50
%T
40
1222.7 7
4 92.02
2941.52
70
6 51.46
60
751 .67
50
%T
11 19.55
40
40
3000
1054.0 3 862.20
11 19.06
649 .90
11 18.83
493.5 2
491.5 9
50
%T
751.20
3461.11
1 314.4 1
70
60
651 .89
751 .24
904.08
1053.35
4000.0
80
90 4.81
2095.64
90 4.39
1052.88
60
65 0.73
1344.49
50
20
80
861.80
2069.77
21 03.19
10 56.16
70
1055.8 2
90 3.09
904.6 6
90
26 72.91
41 6.46
180 3.58
105 4.29 863.45
1384 .23
60
100.0
90
2337.75
2671.94
180 5.01
206 6.87
60
%T
FTIR SPECTRUM
Date: 02-1 2-200 9
100.0
1 173.6 2
18 73.36
3940.75
217 5.21
70
2 671.50
2672 .24
80
2672.8 0
1971.82
2175.91
70
862 .48
394 0.98
2457.6 1
393 6.68
414.83
2459.49
80
90
21 74.34
1018.97
412 .58
FTIR SPECTRUM
Date: 02-1 2-200 9
1017.87
90
1871.42
ACI C
T richy-2
FTIR SPECTRUM
Date: 02-1 2-200 9
3940.76
90
ACI C
T richy-2
FTIR SPECTRUM
Date: 02-1 2-200 9
100.0
ACI C
T richy-2
FTIR SPECTRUM
Date: 03-1 2-200 9
FT IR SPECT RUM
Date: 03- 12-2009
3000
2000
1500
1000
400.0
4000.0
2941.1 2
0.0
2000
1500
cm-1
cm-1
3446.44
1711.0 8
3000
1000
400.0
3000
2000
1500
cm-1
1000
400.0
3444 .09
3450.91
0.0
4000.0
4000.0
0.0
3000
2000
cm-1
1500
1000
400.0
4000.0
3000
2000
cm-1
1500
1000
400.0
cm-1
SJC-Ph-D- 7.pk
SJ C-Ph-D-8.pk
SJ C-Ph-D-9.pk
SJ C-Ph-D-10.pk
SJ C-Ph-D-11.pk
SJ C-Ph-D-12.pk
SJC90F~1. SP 3601 4000. 00 400. 00 6.74 99. 65 4.00 %T 5 1. 00
SJ D90B~1.SP 3601 4000 .0 0 4 00.00 6. 88 99.65 4.00 %T 5 1. 00
SJ D907~1.SP 3601 4000. 00 400.00 5.01 100.00 4.00 %T 5 1. 00
SJ 8E4 F~1.SP 3601 40 00.00 400.00 6.32 100.00 4.00 %T 5 1.00
SJ 865F~1.SP 3601 4000.00 400 .00 5.02 100. 00 4. 00 %T 5 1.00
SJ 8E5 F~1.SP 3601 40 00.00 400.00 6.31 100.00 4.00 %T 5 1.00
REF 4 000 88.66 2000 86.67 600

3940.76 84.43 3461.11 9. 68 2941.52 6. 87 2866.52 14.79 267 1.50 75.85
2459.49 86.83 2175.91 82.44 2066.87 82.78 1971.82 85. 56 1871.42 85. 70
1712.00 6. 74 1594.24 19 .62 1444.61 26.34 1344.49 28.76 1314.96 31.37
1227.37 26.28 1119.18 39.57 1053.35 54.35 904.08 59.03 863.95 68.44
751. 20 51 .31 650.73 63.15 492.02 43.9 6 414.83 75.36
REF 4 000 92.71 2000 91. 14 600

39 36.68 89.41 3441. 28 11.71 2940.25 10. 45 286 4. 48 25.11 2672.80 84. 75
24 57.61 91.64 2175. 21 87.54 1805.01 83. 36 171 1. 36 6. 88 1593.12 17.15
14 49.04 42.43 1426. 65 44.77 1384.23 56. 55 134 6. 89 36.08 1313.22 45. 75
12 22.77 47.09 1119. 25 54.07 1054.29 77. 26 101 7. 87 81.61 904.66 71.89
86 3. 45 76.54 751.24 59.09 651.79 67.94 491. 59 56.32 412 .5 8 85.22
REF 4 000 97.62 2000 95. 06 600

39 40.98 94.82 3447 .8 1 5.01 2941.12 7.74 2865.70 18. 58 2672.24 87. 45
21 75.11 90.96 1803 .5 8 84.06 1711.08 6.06 1593.54 1 4. 08 1 443.97 32.69
13 46.39 30.30 1315 .0 5 38.41 1223.68 39.70 1119.55 48. 73 1055.82 74. 96
10 18.97 82.81 903. 09 69. 63 862.48 77.91 751.76 55.62 651.89 64.69
49 2. 68 49.14 415. 26 8 4. 96
REF 4 000 98.52 2000 95. 78 600

39 40.75 96.28 3446 .4 4 6.32 2946.53 31. 95 2868.75 4 1. 80 2 671.94 88.38
23 37.75 95.09 2174 .3 4 92.24 2069.77 91.69 1873.36 96. 44 1713.95 31. 60
15 94.55 22.28 1444 .5 0 47.28 1352.19 38.91 1236.96 40. 46 1173.62 77. 18
11 18.83 64.78 1052 .8 8 67.20 904. 39 81. 12 861.80 86. 51 751.67 65.42
64 9. 90 70.63 493. 52 6 2. 98 4 16.46 89. 84
REF 4 000 98.40 2000 95. 00 600

34 50.91 5.02 2943.19 31. 91 2866.13 47. 66 2672.91 9 3. 78 2 095.64 91.51
17 10.37 30.25 1634 .5 8 27.40 1591.09 24.35 1448.37 57. 43 1348.45 49. 48
13 14.41 62.31 1230 .0 4 55.60 1119.06 71.11 1054.03 79. 63 904.81 84.57
86 2. 20 85.71 750. 76 6 5. 02 6 51.46 67. 44 492.78 64.31
REF 4 000 99.52 2000 96. 68 600

34 44.09 6.31 2990.98 70. 97 2948.68 70. 81 2103.19 9 3. 89 1 748.05 70.07
15 90.14 25.54 1354 .1 7 62.45 1242.49 67.03 1056.16 89. 49 602.01 68.68
ACI C
T richy-2
ACI C
T richy-2
FTIR SPECTRUM
Date: 02-1 2-200 9
FTIR SPECTRUM
Date: 02-1 2-200 9
100.0
100.0
ACI C
T richy-2
FTIR SPECTRUM
Date: 02-1 2-200 9
100.0
ACI C
T richy-2
FTIR SPECTRUM
Date: 02-1 2-200 9
FT IR SPECT RUM
Date: 02- 12-2009
100.0
ACI C
T richy-2
ACIC
Tric hy-2
FTIR SPECTRUM
Date: 02-1 2-200 9
400.0
cm-1
SJB907~1.SP 3601 4000.00 400.00 7 .45 99.05 4.0 0 %T 5 1.00
10
100.0
100.0
3917 .86
90
90
20 99.44
111 4.15
2 732.05
394 1.98
217 5.32
4 14.96
18 72.84
90
90
1871.57
39 39.33
3 927.75
90
1871 .85
2866.79
2 174.86
2174.91
2 735.1 2
1450.41
80
1055 .20
2 671.91
206 9.64
90
2104.59
273 0.73
1 223.48
80
2067.03
206 8.05
860.4 1
936.37
1 018.19
1053 .58
267 2.75
80
80
2988.5 4
2671.32
1172.18
80
2821.88
9 04.25
2827.64
862.19
70
70
65 0.42
751 .92
60
1242 .52
1053.66
50
30
30
40
30
30
13 58.98
1 234.39
20
20
20
1236.30
1588.95
10
2940.8 6
400.0
4000.0
cm-1
2000
1593.35
10
10
1500
1000
cm-1
SJ C-Ph-D-13.pk
SJ C-Ph-D-14.pk
SJ 866F~1.SP 3601 4000.00 400 .00 6.35 100. 00 4. 00 %T 5 1.00
SJ 8E6 F~1.SP 3601 40 00.00 400.00 7.03 100.00 4.00 %T 5 1.00
REF 4 000 99.50 2000 97. 14 600

34 37.27 6.35 2988.54 66. 60 2949.03 66. 48 2732.05 9 3. 58 2 099.44 94.18
17 53.55 64.20 1591 .8 7 18.50 1355.56 51.26 1242.52 58. 89 1114.15 93. 28
10 55.20 85.21 766. 39 71. 35 605.78 68.51
REF 4 000 98.07 2000 96. 53 600

39 41.98 96.46 3457 .3 6 11.15 2940.86 12.17 2865.79 27. 97 2671.91 88. 97
21 75.32 93.29 2069 .6 4 93.13 1872.84 95.73 1711.61 7.02 1 594.23 23.26
14 44.32 40.53 1348 .3 4 38.57 1314.02 46.06 1236.30 22. 58 1118.49 55. 20
10 52.50 54.96 903. 61 75. 36 860.41 82.10 751.92 65.83 649.01 73.55
49 2. 49 59.49 414. 96 8 7. 56
400.0
1592.46
10
17 11.30
0.0
3000
294 1.88
1711.61
0.0
1000
1594.37
10
3457 .36
3 437.27
1500
1242 .90
1 755.0 7
1350.91
20
1594.23
2992.52
50
%T
40
1591.87
10
0.0
2000
596.99
60
1350.38
%T
2945.90
30
1349.24
2866.4 4
2 865.79
20
7 70.19
751 .68
1 383.3 1
650.96
1445.54
30
1 056.50
70
2946.6 9
60
50
1236.83
1 447.80
2866.69
40
144 4.32
20
70
650 .92
751 .82
493.7 5
50
%T
40
13 48.34
861.97
751.75
111 8.87
%T
1 052.5 0
40
4 92.81
11 18.49
50
%T
13 55.56
40
1119 .14
60
60
492.4 9
50
1053 .46
904.03
649 .01
131 4.02
605.7 8
294 9.03
17 53.55
70
70
90 3.61
7 66.39
60
%T
3000
11 20.17
213 0.01
415.97
80
4000.0
4 93.59
40
1225.70
1444.00
2865.29
30
10
ACIC
Tric hy-2
1018.13
3927.97
0.0
3451.61
4000.0
3000
2000
1500
1000
400.0
3438.84
3 437.2 0
4000.0
0.0
3000
2000
1500
1000
400.0
3 437.82
4000.0
cm-1
cm-1
0.0
3000
2000
1500
1000
400.0
4000.0
cm-1
3000
2000
1500
1000
cm-1
SJC-Ph-D- 15.pk
SJ C-Ph-D-16.pk
SJ C-Ph-D-17.pk
SJ C-Ph-D-18.pk
SJC-PH~4. SP 3601 4000. 00 400. 00 5.02 100.00 4.00 %T 5 1.00
SJ C-PH~3.SP 3601 4000. 00 400.00 5.05 99. 99 4. 00 %T 5 1.00
SJ C-PH~2.SP 3601 4000. 00 400.00 5.02 100.00 4.00 %T 5 0. 50
SJ C-PH~1.SP 3601 4000. 00 400.00 6.34 99. 99 4. 00 %T 5 0.50
REF 4 000 98.24 2000 95.83 600

3939.33 95.78 3451.61 5 .01 2941.88 14.53 2866.44 28.76 2671.32 87.17
2174.91 91.81 2068.05 9 1.54 1871.57 95.36 1711. 30 11.36 1594.37 17. 35
1445.54 40.25 1349.24 3 5.70 1234.39 31.53 1118. 87 56.63 1053.66 62. 64
904. 03 75 .11 862.19 80. 83 751.75 61.66 6 50. 42 68. 51 492.81 58.47
415. 97 88 .65
REF 4 000 98.20 2000 95. 47 600

39 27.75 96.13 3437. 20 5.05 2945.90 37.35 2866. 69 49 .33 2672.75 89.39
21 74.86 91.54 2067. 03 91.49 1871.85 96. 30 159 3. 35 15.56 1447.80 56. 37
13 50.91 40.01 1236. 83 52.68 1119.14 72. 14 105 3. 46 75.80 904.25 82.97
86 1. 97 83.61 751.82 62.22 650.92 64.67 493. 75 62.42
REF 4 000 99.44 2000 96. 21 600

39 17.86 95.35 3437 .8 2 5.02 2946.69 72. 57 2866.79 8 4. 56 2 821.88 86.71
27 35.12 95.38 2130 .0 1 92.80 1588.95 18.90 1450.41 84. 84 1383.31 65. 71
13 50.38 56.67 1223 .4 8 93.51 1120.17 94.90 1053.58 98. 38 1018.19 98. 43
75 1. 68 67.32 650. 96 6 3. 96
REF 4 000 99.87 2000 97. 91 600

34 38.84 6.34 2992. 52 63.22 2827.64 82.12 2730. 73 93 .41 2104.59 94.91
17 55.07 58.37 1592. 46 15.78 1358.98 44. 91 124 2. 90 56.74 1172.18 88. 73
10 56.50 85.87 936.3 7 98.32 770. 19 70. 19 596.99 68 .3 9
315
400.0
Table - 7.30
Cyclohexanone + Ethyl Acetate + 2-Butanone mixture
S1
(Cm-1)
3927.97
3788.49
3420.47
2940.99
2865.29
2673.39
2176.04
1804.84
1712.31
1595.46
1448.22
1350.61
1314.28
1222.68
1172.66
1119.36
1054.67
1018.13
863.72
651.14
491.59
413.27
S2
(Cm-1)
3931.42
3784.96
3439.70
2941.24
2865.46
2673.92
2175.84
1711.17
1595.42
1444.52
1351.08
1223.19
1119.18
1055.20
1018.91
861.50
649.71
559.88
492.38
S3
(Cm-1)
3927.93
3790.58
3420.01
2940.97
2864.86
2672.36
2175.61
1712.05
1595.16
1448.21
1350.34
1314.07
1223.85
1119.18
1054.15
1018.47
863.56
650.90
491.47
413.32
S4
(Cm-1)
3931.53
3788.52
3431.58
2940.55
2864.88
2673.57
2175.76
1711.36
1595.65
1444.00
1351.62
1222.89
1119.36
1055.56
1020.15
861.26
649.91
492.04
416.20
S5
(Cm-1)
3928.10
3431.36
2940.81
2865.60
2672.60
2175.71
1711.82
1595.38
1445.16
1348.36
1225.70
1119.05
1054.63
862.80
649.90
491.94
414.55
S6
(Cm-1)
3927.50
3793.60
3436.14
2942.42
2866.09
2173.53
1712.65
1594.99
1444.42
1353.25
1227.85
1172.47
1119.18
1055.28
587.69
493.59
S7
(Cm-1)
3940.76
3461.11
2941.52
2866.52
2671.50
2459.49
2175.91
2066.87
1971.82
1871.42
1712.00
1594.24
1444.61
1344.49
1314.96
1227.37
1119.18
1053.35
863.95
650.73
492.02
414.83
S8
(Cm-1)
3936.68
3441.28
2940.25
2864.48
2672.80
2457.61
2175.21
1805.01
1711.36
1593.12
1449.04
1426.65
1384.23
1346.89
1313.22
1222.77
1119.25
1054.29
1017.87
863.45
651.79
491.59
412.58
S9
(Cm-1)
3940.98
3447.81
2941.12
2865.70
2672.24
2175.11
1803.58
1711.08
1593.54
1443.97
1346.39
1315.05
1223.68
1119.55
1055.82
1018.97
862.48
651.89
492.68
415.26

*S10
(Cm-1)
3940.75
3446.44
2946.53
2868.75
2671.94
2337.75
2174.34
2069.77
1873.36
1713.95
1594.55
1444.50
1352.19
1236.96
1173.62
1118.83
1052.88
861.80
649.90
416.46
S11
(Cm-1)
3450.91
2943.19
2866.13
2672.91
2095.64
1710.37
1634.58
1591.09
1448.37
1348.45
1314.41
1230.04
1119.06
1054.03
862.20
651.46
492.78
S12
(Cm-1)
3444.09
2990.98
2948.68
2103.19
1748.05
1590.14
1354.17
1242.49
1056.16
602.01
S13
(Cm-1)
3437.27
2988.54
2949.03
2732.05
2099.44
1753.55
1591.87
1355.56
1242.52
1114.15
1055.20
605.78
S14
(Cm-1)
3941.98
3457.36
2940.86
2865.79
2671.91
2175.32
2069.64
1872.84
1711.61
1594.23
1444.32
1348.34
1314.02
1236.30
1118.49
1052.50
860.41
649.01
492.49
414.96
S15
(Cm-1)
3939.33
3451.61
2941.88
2866.44
2671.32
2174.91
2068.05
1871.57
1711.30
1594.37
1445.54
1349.24
1234.39
1118.87
1053.66
862.19
650.42
492.81
415.97

316
S16
(Cm-1)
3927.75
3437.20
2945.90
2866.69
2672.75
2174.86
2067.03
1871.85
1593.35
1447.80
1350.91
1236.83
1119.14
1053.46
861.97
650.92
493.75
S17
(Cm-1)
3917.86
3437.82
2946.69
2866.79
2821.88
2735.12
2130.01
1588.95
1450.41
1383.31
1350.38
1223.48
1120.17
1053.58
1018.19
650.96
S18
(Cm-1)
3438.84
2992.52
2827.64
2730.73
2104.59
1755.07
1592.46
1358.98
1242.90
1172.18
1056.50
936.37
770.19
596.99
Fig-7.30: FTIR spectrums for Ethyl Acetate + 2-Butanone + Hexane mixture:

ACIC
Trichy-2
ACI C
St. Joseph's College ( Autonomo us )
Tr ich y-2
FTIR SPECT RUM

Date: 26-6-2009
ACIC
Trichy-2
ACI C
St.Josep h's Colleg e ( Autonomous )
Tr ichy-2
ACI C
T richy-2
ACIC
T richy-2
Spectrum Name: H-E-2B-1.sp

FTIR SPECT RUM
Date: 26-6-2009
100.0
FTIR SPECTRUM
Date: 26-6-2009
Spectrum Name: H-E-2B-2 .sp
392 5.08
90
100.0
39 22.32
90
23 59.43
90
61 4.51
2 721.6 4
23 64.66
106 1.83
1 228.66
27 19.74
1461.09
2718.6 5
80
80
80
1241.28
2720 .26
612.29
2719.35
612 .42
70
6 10.23
2978.74
3921.92
2375.56
80
70
774 .6 3
90
90
90
1065.56
80
2 83 2.19
23 76.47
29 61.99
3794 .87
2 966.24
70
60
FT IR SPECT RUM
Date: 26-6- 2009
100.0
100.0
100.0
39 20.42
Spec trum Name: H-E-2B-6.sp
Sp ec trum Name: H-E- 2B-5 .sp
100.0
2 72 0.35
80
FT IR SPECTRUM
Date: 26-6-2009
FTIR SPECTRUM
Date: 26-6-2009
10 22 .04
29 66.78
1463.43
613 .93
70
70
614 .72
70
12 42.25
296 1.38
1241.4 7
50
283 1.80
60
2963.90
60
%T
774.51
40
30
34 45.96
40
40
40
30
30
34 57.13
30
30
3459.19
3441.22
3443.38
1 36 1.93
20
20
10
774.45
50
%T
%T
2832.28
%T
40
30
20
77 4.69
50
50
%T
2832.19
2831.7 1
774.90
2832 .02
50
%T
60
60
60
773 .57
50
40
20
20
20
13 60.15
3440.28
1362.03
10
15 99 .6 5
10
4000.0
3000
2000
15 00
100 0
1362.84
159 8.26
400.0
0.0
cm-1
1 599.22
0.0
4000.0
H-E-2B-1.pk
3000
2000
1500
1000
400.0
3000
2000
1500
1000
400.0
4000.0
cm -1
2000
1000
4000.0
400.0
3000
2000
1500
1000
cm -1
H-E-2B-3.sp 3601 4000.00 400.00 5.15 99.79 4.00 %T 10 1.00
H-E-2B-4.sp 3601 4000.00 400.00 5.16 99. 63 4.00 %T 10 1.00
H-E-2B-5 .s p 3601 4000.00 400. 00 6. 37 99.82 4. 00 %T 10 1.00
H-E-2B-6.s p 3 601 400 0. 00 400. 00 6. 46 99.62 4.00 %T 10 1.00
REF 4 000 98 .6 7 2000 96. 56 600

39 20.42 95. 34 3440.28 19.68 2966. 24 71. 79 2831.80 66. 13 272 1. 64 87.67
15 98.26 6.38 1360. 15 22 .8 6 773.57 62. 99 610.23 73 .6 1
REF 4000 99.57 2000 93.81 600

3922.32 96.63 3794.87 95.25 3457.13 31.32 2961.99 74.01 2832.02 59.03
2719.74 86.77 2376.47 97.70 1599.22 5.15 1362.02 14.88 1228.66 87.25
774.51 61.60 612.42 79.54
REF 4000 99.40 2000 88.87 600

3459. 19 34.84 2963.90 71. 25 2832. 28 54.17 2719.35 84.52 2375.56 93.29
1601. 38 5.16 1463. 43 66.85 1362.84 11.79 1241. 47 76 .30 1065.56 91.01
774.90 60.53 612.29 82.33
REF 4000 99.73 2000 97.06 600

3443. 38 30.10 29 61.38 78.46 2831.71 62.58 271 8.65 88. 80 1599. 10 6.37
1461. 09 74.73 13 62.27 16.98 1241.28 86.94 774 .69 59.02 613.93 77.85
REF 4000 99.5 0 2000 9 4. 66 600

3921.92 96.19 34 41.22 29. 63 2978.74 74. 79 2832. 19 63.55 272 0. 26 88.64
2364.66 93.95 15 99.06 6.46 1362.03 18.23 1242.25 75.38 1061. 83 91 .1 4
774. 45 63.15 614. 72 78. 20
ACIC
T richy-2
FTIR SPECTRUM
Date: 26-6-2009
90
146 5.7 5
FTIR SPECTRUM
Date: 2 7-6 -2009
FTIR SPECTRUM
Date: 26-6 -2009
1 241 .5 8
3922.83
1 094.5 4
1057.11
2 831 .8 0
60
3800.40
773 .4 5
2 722.24
1463 .92
80
70
2721.11
70
610.79
1244.51
2369.69
613.73
70
70
2720.66
609.81
2832.01
60
609.92
60
773.88
50
2832.46
40
1427.18
60
60
50
50
30
30
30
13 61.26
20
4000 .0
1000
3000
2000
1500
1000
400.0
H-E-2B-7.pk
400 0.0
3438.16
10
1596.57
3 000
200 0
REF 4000 99.61 2000 96.21 600

3820.17 93.89 3441.43 29.92 2831.80 67.16 2720.98 89.50 2367.12 96.20
1598.86 7.96 1465.75 75.68 1361.26 22.32 1241.58 87.34 773.45 65.76
604.21 79.31
0.0
4000.0
0 .0
15 00
10 00
400 0. 0
4 00. 0
3 00 0
2 000
15 00
1 000
3000
2000
1500
1000
400.0
4 00. 0
H-E-2B-10.pk
H-E-2B-9 .s p 3601 400 0.00 400.00 6.46 100.00 4.00 %T 10 1.00
H-E-2B~1.SP 3 601 400 0.00 400.00 6.62 99 .5 2 4.0 0 %T 10 1 .0 0
REF 4 000 99.84 2000 8 6.03 600

39 22. 83 94.26 3815.17 91.04 3439.58 27 .8 6 2963.05 66.25 283 1.80 58.67
27 20. 66 77.55 2369.69 82.16 1598.12 6. 46 1360.81 21.70 1122.61 88 .7 4
77 3. 98 64 .4 5 61 3.73 7 6.51
REF 4 000 99 .3 1 2000 92.98 600

39 25.24 95.14 380 0.40 92.20 3444.85 24.69 296 6.09 73.26 283 2.26 64. 45
27 21.11 88.79 159 8.52 6.62 1 361.11 20 .3 4 12 44.51 86 .4 9 774.3 4 61.06
60 9.92 75.0 6
3000
2000
1500
1000
400.0
cm -1
H-E-2B-11. pk
H-E-2B-9 .p k
1597.41
4000.0
cm -1
cm-1
cm-1
H-E-2B-8.s p 3601 4000.00 400.00 7.96 99.90 4.00 %T 10 1.00
REF 4000 99.5 7 2000 7 9. 94 600

3451.66 27.72 29 99.34 60. 07 2832.46 56. 03 2719. 92 77.81 237 3. 04 83.10
1714.61 12.32 15 98.94 6.45 1427.18 51.15 1362.70 8.15 1226. 38 36.29
1094.54 80.43 10 57.11 80. 17 905.57 92.15 774. 95 61. 01 611.99 77.29
532. 24 68.40
20
1359.28
343 9.12
0.0
1598.52
1598.12
0.0
H-E-2B-8.pk
H-E-2B-7.s p 3 601 400 0. 00 400. 00 6. 45 99.74 4.00 %T 10 1.00
10
1361.11
10
10
cm-1
400.0
3444.85
1360.81
0.0
1362.70
1500
1360.37
20
3439.58
20
15 98.86
1598.94
cm -1
30
30
30
10
1714.61
40
40
40
20
345 1.66
10
774.04
1759.91
%T
40
%T
%T
34 41.43
122 6.38
1243.11
2831.96
50
%T
774.34
2831.80
29 89.65
50
2832.26
773.98
40
1056.50
2722 .18
1243.14
1122.61
2963.05
80
50
%T
1116.38
80
2966.09
3815.17
532.2 4
3921.81
90
1119.90
80
90
90
61 1.99
774.95
3919.64
3925.24
60
29 99.34
FTIR SPECTRUM
Date: 27-6-2009
100.0
237 5.34
90
100 .0
10 0.0
100.0
Sp ec trum Name: H-E-2B-1 0.sp
Sp ectrum Name: H-E-2B-9 .sp

604 .21
70
2719.92
FT IR SPECT RUM
Date: 27-6 -2009
Spectrum Name: H-E-2B- 11.sp
2 720 .98
80
2373 .04
2000
400.0
ACIC
T richy-2
ACIC
St.Jo sep h's Colleg e ( Autonomo us )
Trichy-2
ACIC
St.Jos ep h's Colleg e ( Autonomo us )
Trichy-2
23 67.12
3 820 .17
905 .57
80
3000
1000
H- E-2B-2.s p 3 601 4000. 00 400.00 6.38 99.88 4.00 %T 10 1 .0 0
10 0.0
90
4000.0
1500
cm -1
H-E-2B-6.pk
FT IR SPECT RUM
Date: 26-6- 2009
20
2000
H-E-2B-5 .p k
0.0
3000
H-E-2B-4.pk
ACIC
Trichy-2
100.0
%T
4000.0
400.0
cm-1
H-E-2B-3.pk
ACI C
St.Josep h's Colleg e ( Autonomous )
Tr ichy-2
70
0.0
0.0
1500
H- E-2B-2.pk
H-E-2B-1.s p 3601 4000.00 400.00 6.64 99.62 4.00 %T 10 1.00

REF 4000 99.55 2000 95.26 600
3925.08 96.42 3445.96 30.18 2966.78 77.08 2832.19 64.45 2720.35 89.14
2359.43 82.43 1599.65 6.64 1361.93 20.02 1022.04 96.01 774.63 65.20
614.51 79.17
3000
15 99.06
15 99.10
1601.38
0.0
4000.0
cm -1
10
13 62.27
10
10
1 362.02
0.0
H-E-2B-12.pk
H-E-2B~2.SP 3601 4000.00 400.00 6. 64 99.19 4.00 %T 10 1.00
H-E-2B~3. SP 3601 4000. 00 400. 00 6. 46 99.99 4.00 %T 10 1.00
REF 4000 98.52 2000 95.57 600

3919.64 95.75 3439.12 15.68 2832. 01 66.97 2722. 24 87. 11 2375. 34 97. 37
1596.57 6. 64 1359. 28 24.88 1243. 14 81.79 1119.90 92.09 773. 88 62. 18
610.79 71.7 5
REF 4000 99.67 2000 89.66 600

3921. 81 94.37 3438.16 19. 83 2989. 65 62.20 2831.96 63.00 2722.18 81.97
1759. 91 55.75 1597.41 6.45 1463.92 69.83 1360. 37 22 .77 1243.11 58.06
1116. 38 88.61 1056.50 82. 60 774.04 62.64 609.81 72.17
ACIC
St.Joseph's College ( Autonomo us )
Trichy-2
ACIC
Trichy-2
ACIC
Trichy-2
FTIR SPECTRUM
Date: 27-6-2009
ACI C
T richy-2

FTIR S PECTRUM
10 0. 0
ACIC
T richy-2
Date: 27-6-2009
ACI C
T richy-2
FTIR S PECTRUM
Date: 27-6-2009

90
100 .0
392 2.83
90
2366.92
3931.86
FT IR SPECTRUM
Date: 27-6-2009
1026.21
2721.68
80
236 8.82
100 .0
FT IR SPECT RUM
Date: 27-6 -2009
Sp ec trum Name: H-E- 2B-1 5. sp
1121.18
80
70
2 72 1.10
90
607.79
2831.82
70
90
90
2104.88
392 4.15
9 34 .2 6
2 72 1.76
80
2725.86
2093 .13
378 7.28
1 464.87
80
2365.51
80
1117.08
21 63.66
1464.73
2723.85
1760.57
607.34
2830.51
60
1 05 6.4 5
773 .34
50
40
1056.50
%T
40
20
29 87 .45
2 981.69
30
30
10
13 61 .1 4
20 00
1500
4 00 0. 0
100 0
cm-1
2 00 0
1 50 0
1 00 0
H-E-2B-1 4.pk
H-E-2B-13.pk
40 0 .0
20
1358.40
10
34 51.48
2000
1500
1000
400.0
cm-1
4000.0
40 00.0
0.0
3000
2000
1500
1000
400.0
4000.0
cm -1
3000
20 00
1500
100 0
cm-1
3000
2000
1500
1000
cm-1
H-FAD3~1.SP 3601 4000.00 400.00 6.65 100.00 4.00 %T 10 1.00
H-E-2B-1 5. pk
H-E-2B-16. pk
H-E-2B-1 7. pk
REF 4000 99.65 2000 95.11 600

3931.86 96.66 3440.19 1 9.73 2831.82 69.47 2721.68 89.44 2366.92 96.14
1596.80 6.65 1359.07 24.96 1121.18 90.89 1026.21 93.74 773.90 61.60
607.79 70.82
H-F2E3~1.SP 360 1 4000.00 400.00 6.66 100.00 4.00 %T 10 1.00
H-FAE3~1. SP 3601 4000.00 4 00. 00 6.58 99.73 4.00 %T 10 1.00
H-F2F3~1.SP 360 1 4000.00 400.00 6.91 99. 93 4. 00 %T 10 1. 00
REF 4000 99.53 2000 97.65 600

3920. 48 95.73 3788.96 90. 14 3438.89 14.76 29 91.14 62.36 2832. 10 68.26
2725. 86 86.66 2365.04 96. 71 2104.88 96.22 17 60.57 60.47 1596. 95 6. 66
1464. 87 73.16 1359.05 27. 91 1243.08 57.73 10 56.19 81.32 773.60 64 .63
610.28 69 .65
REF 4000 99.45 2000 91.85 600

3924.15 96.89 3434.53 21.99 2978. 96 65.46 2830. 51 65. 84 2723. 85 83. 18
2365.51 87.53 2163.66 90.23 1596. 72 6.58 1464.73 71.07 1358.40 24.16
1244.05 76.72 1117.08 91.18 1048. 04 89.29 773.34 59.27 607. 34 65. 87
REF 4000 99.38 2000 97.09 600

3923. 33 97.13 37 87.28 93.60 3451.48 15.57 298 1.69 41. 89 2833. 58 66.26
2724. 87 87.93 20 93.13 95.18 1760.87 21.42 159 6.84 6.91 1463.96 62.72
1364. 08 17.80 12 42.70 15.11 1172.52 77.26 105 6.50 57. 29 933.98 94.64
773.09 62 .44 615. 80 67.42
317
1 242 .7 8
0 .0
1596.84
1596.72
0.0
3000
17 59 .6 7
1 59 7.19
1364.0 8
1242.7 0
1596 .95
4000.0
1 36 6.24
10
176 0.87
10
3438.89
0.0
H-E-2B~4.SP 3601 4000.00 400.00 6.65 100.00 4.00 %T 10 1.00

REF 4000 99.63 2000 95.17 600
3922.83 95.68 3445.58 24.72 2832.13 63.65 2721.10 87.72 2368.82 97.28
1598.01 6.65 1361.14 20.95 774.38 62.04 611.94 75.37
20
34 52 .5 5
20
3434.53
10
30 00
cm -1
400.0
30
1359.05
20
1596.80
0. 0
1 59 8.01
3000
30
40
1359.07
3440.19
3 44 5.58
40 00.0
77 4.40
%T
773.09
2978 .96
50
%T
10
0 .0
60 3.88
11 72 .34
50
615.80
2833.58
60
1243.0 8
40
30
283 3.02
1172 .52
70
1244.05
1 46 1.30
77 3.60
2991.14
50
%T
30
60
1 463.96
70
610 .28
2832.10
60
70
933.98
2724 .87
80
104 8.04
1056.19
70
40
2 09 0.6 7
8 43 .8 4
%T
77 4.38
40
20
100.0
2365.04
773.90
50
28 32.13
50
2 48 0.0 9
90
Sp ec trum Name: H-E- 2B-1 7. sp
100.0
3923.3 3
3920.4 8
3788.96
60
6 11 .9 4
60
%T
FT IR SPECTRUM
Date: 27-6-2009
Spectrum Name: H-E-2B- 16.sp
100.0
400.0
H-E-2B-18.pk
H-FAF3~1.SP 3601 4000.00 400.00 8.06 100.00 4.00 %T 10 1.00
REF 4000 99.58 2000 97.97 600
3452.55 20.96 2987.45 40.50 2833.02 69.66 2721.76 90.87 2480.09 98.55
2090.67 95.86 1759.67 12.88 1597.19 9.71 1461.30 60.62 1366.24 15.68
1242.78 8.06 1172.34 69.01 1056.45 47.87 934.26 91.78 843.84 86.86
774.40 64.13 603.88 70.44
400.0
Table - 7.31
Ethyl Acetate + 2-Butanone + Hexane mixture:
S1
(Cm-1)
S2
(Cm-1)
S3
(Cm-1)
S4
(Cm-1)
S5
(Cm-1)
S6
(Cm-1)
*S7
(Cm-1)
S8
(Cm-1)
S9
(Cm-1)
3925.08
3445.96
2966.78
2832.19
2720.35
2359.43
1599.65
1361.93
1022.04
774.63
614.51
3920.42
3440.28
2966.24
2831.80
2721.64
1598.26
1360.15
773.57
610.23
3922.32
3794.87
3457.13
2961.99
2832.02
2719.74
2376.47
1599.22
1362.02
1228.66
774.51
612.42
3459.19
2963.90
2832.28
2719.35
2375.56
1601.38
1463.43
1362.84
1241.47
1065.56
774.90
612.29
3443.38
2961.38
2831.71
2718.65
1599.10
1461.09
1362.27
1241.28
774.69
613.93
3921.92
3441.22
2978.74
2832.19
2720.26
2364.66
1599.06
1362.03
1242.25
1061.83
774.45
614.72
3451.66
2999.34
2832.46
2719.92
2373.04
1714.61
1598.94
1427.18
1362.70
1226.38
1094.54
1057.11
905.57
774.95
611.99
532.24
3820.17
3441.43
2831.80
2720.98
2367.12
1598.86
1465.75
1361.26
1241.58
773.45
604.21
3922.83
3815.17
3439.58
2963.05
2831.80
2720.66
2369.69
1598.12
1360.81
1122.61
773.98
613.73

S10
(Cm-1)
S11
(Cm-1)
S12
(Cm-1)
S13
(Cm-1)
S14
(Cm-1)
S15
(Cm-1)
S16
(Cm-1)
*S17
(Cm-1)
S18
(Cm-1)
3925.24
3800.40
3444.85
2966.09
2832.26
2721.11
1598.52
1361.11
1244.51
774.34
609.92
3919.64
3439.12
2832.01
2722.24
2375.34
1596.57
1359.28
1243.14
1119.90
773.88
610.79
3921.81
3438.16
2989.65
2831.96
2722.18
1759.91
1597.41
1463.92
1360.37
1243.11
1116.38
1056.50
774.04
609.81
3922.83
3445.58
2832.13
2721.10
2368.82
1598.01
1361.14
774.38
611.94
3931.86
3440.19
2831.82
2721.68
2366.92
1596.80
1359.07
1121.18
1026.21
773.90
607.79
3920.48
3788.96
3438.89
2991.14
2832.10
2725.86
2365.04
2104.88
1760.57
1596.95
1464.87
1359.05
1243.08
1056.19
773.60
610.28
3924.15
3434.53
2978.96
2830.51
2723.85
2365.51
2163.66
1596.72
1464.73
1358.40
1244.05
1117.08
1048.04
773.34
607.34
3923.33
3787.28
3451.48
2981.69
2833.58
2724.87
2093.13
1760.87
1596.84
1463.96
1364.08
1242.70
1172.52
1056.50
933.98
773.09
615.80
3452.55
2987.45
2833.02
2721.76
2480.09
2090.67
1759.67
1597.19
1461.30
1366.24
1242.78
1172.34
1056.45
934.26
843.84
774.40
603.88

318

FTIR Spectroscopy Studies of Chapter 7

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Chapter 7

FTIR Spectroscopic Studies

energy near-IR, approximately 140004000 cm1 (2.50.8 m) can excite overtone or

. The names and classifications of these sub regions are

. Unsymmetrical diatomic molecules, e.g. CO,

7.3. Practical IR spectroscopy

7.4. Sample preparation

In addition to "standard" transmission FTIR we they also have the following

7.5. Comparison with a reference

Fig. 7.1: Schematics of a two-beam absorption spectrometer.

A beam of infrared light is produced, passed through an interferometer (not

7.6. FTIR Spectroscopy

detecting much lower light levels than an FTIR

measurement.[128] There are other advantages, as well as some disadvantages,[128] but

7.7. Analyse of the spectra

Frequency range, cm-1

2960 2850(s) stretch

1470 1350 (v) Scissoring and

1380 (m-w) Doublet isopropy 1,tbuty1

CH3 Umbrella Deformation

30803020 (m) stretch

1000675 9s) bend

3100300 (m) stretch

Phenyl Ring Substitution Bonds

870 675 (s) bend

Phenyl ring substitution Overtones

200 1600 (w) fingerprint region

1680 1640 (m,w) stretch

22602100 (w, sh) stretch

1600, 1500 (w) stretch

Alcohols, ketones, Carboxylic acids

1260 100 (s) Stretch

Aldehydes, ketones, Carboxylic acids

17601670 (2) stretch

Monomeric Alcohols, phenols

36403160 (s, br) stretch

700610 (b) bend

36003200 (b) stretch

13401020 (m) stretch

22602220 (v) Stretch

16601500 (s) asymmetrical stretch

16501580 (m) bend

7.8. Advantages of FTIR

7.10. Results and Discussion

and ternary mixtures. In the binary systems of Cyclohexanone(X1) + Hexane(X2),

Heptane(X1) + 2-Butanone(X2), Benzaldehyde(X1) + Benzyl Chloride(X2),

Heptane(X1) + Ethyl Acetate(X2),

Benzaldehyde(X1) + 2-Butanone(X2), Ethyl Acetate (X1) + 2-Butanone(X2)

Hexane(X1) + Heptane(X2), Hexane(X1) + Ethyl Acetate (X2)

Benzaldehyde(X1) + Hexane(X2), Heptane(X1) + Benzyl

FTIR analysis of ternary liquid systems

0.3,0.5 mole fractions of X2 and 0.2,0.1 mole fractions of X3. In Cyclohexanone(X1)

of X3. In Cyclohexanone(X1) + Hexane(X2) + 2-Butanone(X3)

of X3. In Cyclohexanone(X1) + Heptane(X2) + 2-Butanone(X3)

Benzaldehyde(X2) + Ethyl Acetate(X3) mixture the maximum frequency has been

For Binary systems

0.9 (CYC) + 0.1 (HEXANE)

0.7 (CYC) + 0.3 (HEXANE)

0.5 (CYC) + 0.5 (HEXANE)

0.8(CYC) + 0.2 (HEXANE)

(1)CYC + (0)H EXANE

CYCLON~1.SP 3601 4000.00 400.00 10.00 100.00 4.00 %T 5 0.50