Curva de titulacion inversa para acidos di prtidos

Nombre
Acido maleico
Hidroxido de sodio

Formula Masa molar

H2C4H2O4
116
NaOH
39

Volumen equivalente para 1er pto. eq.

pH

1
1.5
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5
10
10.5
11
11.5
12
12.5
13
13.5
14

[H3O]
0.1
0.031623
0.01
0.003162
0.001
0.000316
0.0001
3.16E-05
0.00001
3.16E-06
0.000001
3.16E-07
1E-07
3.16E-08
1E-08
3.16E-09
1E-09
3.16E-10
1E-10
3.16E-11
1E-11
3.16E-12
1E-12
3.16E-13
1E-13
3.16E-14
1E-14

Grafico V = f(pH)
Vol
6.087753944
13.94364506
17.82662936
19.31363383
19.88486489
20.29231319
21.09071568
23.13728732
27.41911819
33.02042703
37.10140791
38.98290434
39.66784758
39.89716002
39.97815348
40.02725034

pH
2
2.5
3
3.5
4
4.5
5
5.5
6
6.5
7
7.5
8
8.5
9
9.5

[OH]
1E-13
3.1623E-13
1E-12
3.1623E-12
1E-11
3.1623E-11
1E-10
3.1623E-10
1E-09
3.1623E-09
0.00000001
3.1623E-08
0.0000001
3.1623E-07
0.000001
3.1623E-06
0.00001
3.1623E-05
0.0001
0.00031623
0.001
0.00316228
0.01
0.03162278
0.1
0.31622777
1

ka1
0.013
-

ka2
Conc. Formal
0.00000059
0.05
0.05

Volumen
20
-

20

0.1
0.03162278
0.01
0.00316228
0.001
0.00031623
1E-04
3.1622E-05
9.999E-06
3.1591E-06
0.00000099
2.846E-07
0
-2.846E-07
-0.00000099
-3.1591E-06
-9.999E-06
-3.1622E-05
-1E-04
-0.00031623
-0.001
-0.00316228
-0.01
-0.03162278
-0.1
-0.31622777
-1

TABLA PARA LA CURVA V = f(pH)

D
0
1
0.01130001 0.884955152 0.11504417
0.0014111 0.708665106 0.29132946
0.00023001 0.43476811 0.56519854
5.1117E-05 0.195628564 0.80422139
1.4008E-05 0.07138946 0.92806298
4.2186E-06 0.023704373
0.9744775
1.3177E-06 0.007589154 0.98658997
4.1977E-07 0.002382279 0.97934564
1.3777E-07 0.000725847 0.94360165
4.879E-08 0.000204962 0.84258944
2.0671E-08 4.8377E-05
0.62890039
1.1781E-08 8.4882E-06
0.34894658
8.97E-09
1.11483E-06 0.14492737
8.0811E-09 1.23746E-07 0.05087132
7.8E-09
1.28205E-08 0.01666667
7.7111E-09 1.29683E-09 0.00533122
7.683E-09 1.30157E-10 0.00169205
7.6741E-09 1.30308E-11 0.00053569
7.6713E-09 1.30356E-12 0.00016946
7.6704E-09 1.30371E-13
5.3595E-05
7.6701E-09 1.30376E-14
1.6949E-05
7.67E-09
1.30377E-15
5.3598E-06
7.67E-09
1.30378E-16
1.6949E-06
7.67E-09
1.30378E-17
5.3598E-07
7.67E-09
1.30378E-18
1.6949E-07
7.67E-09
1.30378E-19
5.3598E-08
1.6949E-08
7.67E-09
1.30378E-20

pH
14
12
10
8
6
4
2
0
0

10

20

30

40

50

60

40.11684431
40.38080983
41.22414389
44.0508225
54.99995763

10
10.5
11
11.5
12

kw
1E-14

(pH)
2
6.78761E-07
5.43546E-06
3.33467E-05
0.000150047
0.000547557
0.001818125
0.005820881
0.018272081
0.055672498
0.157205603
0.371051231
0.651044929
0.855071511
0.949128554
0.983333321
0.99466878
0.998307952
0.999464308
0.999830537
0.999946405
0.999983051
0.99999464
0.999998305
0.999999464
0.999999831
0.999999946
0.999999983

pH

60

0.115045527
0.291340329
0.565265237
0.804521483
0.929158097
0.978113753
0.998231727
1.015889802
1.05494665
1.157000641
1.371002854
1.651036441
1.855070396
1.94912843
1.983333308
1.994668779
1.998307952
1.999464308
1.999830537
1.999946405
1.999983051
1.99999464
1.999998305
1.999999464
1.999999831
1.999999946
1.999999983

-0.62831816
-0.20895834
0.3043877
0.69718225
0.89133147
0.96568169
0.99424324
1.01461566
1.05453578
1.15686437
1.37095591
1.65102135
1.8550704
1.94914522
1.98339238
1.994858
1.99890767
2.00136252
2.00584222
2.01904049
2.06120719
2.20254113
2.74999788
7.1622762
-3.99999983
-1.56342732
-1.15789474

VT
-12.5663632
-4.17916686
6.08775394
13.9436451
17.8266294
19.3136338
19.8848649
20.2923132
21.0907157
23.1372873
27.4191182
33.020427
37.1014079
38.9829043
39.6678476
39.89716
39.9781535
40.0272503
40.1168443
40.3808098
41.2241439
44.0508225
54.9999576
143.245524
-79.9999966
-31.2685464
-23.1578947