Cu 1/Cho 40,5 gam Al tc dng vi dung dch HNO3 thu c 10,08 lt (ktc) kh X (khng c sn phm kh no khc).

Kh X l : ( cho Al = 27) A. NO2 B. NO C. N2O D. N2 Cu 2/ Cho m gam hn hp gm Cu;Zn;Fe tc dng ht vi dung dch HNO3 1M long thu c dung dch X.C cn dung dch X thu c (m+62)gam mui nitrat.Th tch dung dch HCl dng l a.1 lt b.4 lt c.2 lt d.3 lt Cu 3/ Cho 19,2 gam mt kim loi M tan hon ton trong HNO3 hu c 4,48 lt kh NO(ktc).M l a. Fe b. Cu c. Zn d. Mg Cu 4/ Ha tan 4,59gam Al bng dung dch HNO3 thu c hn hp kh NO; N2O.Hn kh ny c t khi so vi H2 l 16,75.Tnh th tch(ktc) mi kh c trong hn hp l a 3 lt ;0,3 lt b2,42 lt;0,14 lt c 3,2 lt;0,1 lt d3,4272 lt; 0,14336 lt Cu 5/ Cho 29gam hn hp gm Al;Fe;Cu tc dng ht vi HNO3 thu c 0,672 lt kh NO(ktc).Tnh khi lng hn hp mui khan thu c sau phn ng a 29,00g b 36,00g c 29,44g d 36,44g Cu 6/ Cho 26 gam Zn tc dng va vi dung dch HNO3 thu c 8,96 lt hn hp kh NO;NO (ktc) s mol HNO3 trong dung dch l a 1,2mol b 0,6mol c 0,4mol d 0,8mol Cu 7/ Ha tan 10,8gam Al bng dung dch HNO3 thu c hn hp kh NO;NO .Hn kh ny c t khi so vi H2 l 19.Tnh th tch(ktc) mi kh trong hn hp kh l a cng 5,72 lt b 7 lt v 4 lt c 4 lt v 7 lt d cng 6,72 lt Cu 8/ Cho 6,4 gam Cu tan hon ton vo 200ml dung dch HNO3 th gii phng hn hp kh gm NO;NO2 c t khi so vi H2 bng 18.Tnh C ca dung dch HNO3
M 2 2

KIM LOI TC DNG VI HNO3

a 1,44M b 1M c 0,44M d 2,44M Cu 9/ Ha tan ht 4,431gam hn hp Al;Mg trong HNO3 long thu c dung dch A v 1,568 lt hn hp 2 kh NO; N2O c khi lng 2,59gam.Phn trm v khi lng ca mi kim loi trong hn hp l a20%;80% b13%;87% c12,8%;87,2% d 12%;88% Cu 10/ Ha tan ht 16,2 gam Fe;Cu bng dung dch HNO3 c nng thu c 11,2 lt NO2(ktc).Hm lng Fe trong mu hp kim l a 46,6% b 52,6%/ c 28,8% d 71,3% Cu 11/ Ha tan 62,1gam kim loi M trong dung dch HNO3 long c 16,8 lt hn hp kh X gm N2O;N2 .T khi X so vi H2 bng 17,2.Xc nh CTPT ca mui v V ca dung dch HNO3 2M dng bit ly d 25% so vi lng cn thit? a Cu(NO3)2; 5 lt b Zn((NO3)2; 5,35 lt c Fe(NO3)2; 6 lt d Al(NO3)3 5,25 lt Cu 12/ Ho tan 12,8gam kim loi X bng dung dch HNO3 c thu 8,96 lt (ktc) kh NO2. Tn ca X ho tr II l: a Mg b Fe c Zn d Cu Cu 13/Cho 5,6 g Fe phn ng vi lng HNO 3 long, d gii phng ra mt kh (khng mu, ho nu trong khng kh) c th tch iu kin chun l (Fe=56) A. 1,12 (l) B. 2,24 (l) C. 6,72(l) D. 4,48(l) Cu 14/ Cho m (g) Cu tc dng ht vi dung dch HNO3 thu c 1,12 lt ( ktc) NO v 2,24 lt (ktc) NO 2. Gi tr ca m l (Cu=64) A. 8,00g B. 2.08g C. 0,16g D. 2,38g Cu 15/ Ha tan ht 1,84 gam hn hp Fe v Mg trong dung dch HNO3 d thy thot ra 0,04 mol kh NO (sn phm kh duy nht). S mol Fe, Mg trong hn hp ln lt l A. 0,02 mol v 0,03 mol. B. 0,03 mol v 0,02 mol. C. 0,03 mol v 0,03 mol. D. 0,01 mol v 0,01 mol. Cu 16/Cho m (g) hn hp Fe v Cu tc dng ht vi 100 ml dung dch HNO 3 2,4M c nung nng thu c dung dch A v mt kh mu nu . C cn dung dch A thu c 10,48 g hn hp 2 mui khan. a, Tnh m (g) ? b, Cho 2 mui trong dng dch A tc dng vi 200 ml dung dch NaOH. Tnh nng mol/l ca dung dch NaOH thu c kt ta ln nht, nh nht ? Cu 17/ Ha tan hon ton 13 g mt kim loi R c ha tr khng i vo mt dung dch axit HNO 3 long d. Cho thm dung dch NaOH nng d vo dung dch sau phn ng th thy thot ra 1,12 lt mt cht kh (ktc). Xc nh tn kim loi R ? Cu 18/ Ha tan hon ton 50,8 gam hn hp Fe3O4 v FeO, Fe v Fe2O3 vo dugn dch HNO3 long d thot ra c 2,24 lt kh NO (sp kh duy nht). Xc nh khi lng mui thu c sau khi kt thc phn ng. Cu 19. Cho hn hpX gm 0,2 mol Al v 0,2 mol Fe vo dung dch HNO 3 thy thot ra 6,72 lt kh duy nht ha nu trong khng kh v cn li 0,28 gam cht rn khng tan. Lc b cht rn v c cn dung dch thu c a gam mui khan. Nung mui khan ti khi lng khng i thu c b gam cht rn. Xc nh a, b. Cu 20/ Ha tan hon ton 0,1 mol Fe, 0,1 mol FeS2, 0,1 mol Cu vo dung dch HNO3 long d thy thot ra kh NO duy nht. C cn dung dch sn phm thy thu c60 gam mui khan. Xc nh th tch NO. Cu 21/ Cho hn hp Al, Fe c t l mol 1: 1 vo dung dch HNO3 long thy cn li 5,6 gam cht rn khng tan v thot ra 11,2 lt kh NO (sn phm kh duy nht). Xc nh khi lng ca hn hp ban u. Bit rng dung dch sn phm tc dng vi dung dch NaOH khng c kh thot ra.

III.TRC NGHIM 1/ nhit thng,nito phn ng c vi:

2/ Cc mui nitrat no sau khi nhit phn to ra sn phm:M(NO ) + O ?

2 n 2

Pb

Li

Cl

a NaNO ;AuNO ;Hg(NO ) bCa(NO ) ;Ba(NO ) ;Ni(NO ) cLiNO ;NaNO ;KNO 3/ Nguyn t nguyn t no c bn knh nh nhtaGe(Z=32) bSi(Z=14) 4/ Ngi ta sn xut N trong cng nghip bng cch no sau? a Dng photpho t chy ht oxi khng kh c Cho khng kh i qua bt ng nung nng 5/ Phn ng no sau chng minh NH c tnh bazo?
3 2 3 3 3 2 3 2 3 2 3 2 3 3

dKNO ;Cu(NO ) ;Ni(NO )

3 3 2

3 2

c As(Z=33)

d.P(Z=15)

b Chng ct phn on khng kh lng d Nhit phn dung dch NH NO bo ha

4 2

a NH +Cl->N +HCl
3 2

b NH +O ->N +H O
3 2 2 2

c NH +HCl->NH Cl
3 4

d NH ->N +H
3 2 3

6/ Thuc n en l hn hp cc cht no sau?

aKNO ;S
3

KClO ;C;S c
3

KNO ;S;C d

KClO ;C
3

7/ Bit tnh phi kim gim dn theo th t F;O;N;Cl.Cho bit phn t hp cht no sau y c lin kt phn cc mnh nht NF b ClF c NCl d Cl O 9/ P v P trng l 2 dng th hnh ca P nn ging nhau ch a T bc chy trong khng kh iu kin thng b Kh nng chay,kh bay hi c u c cu trc mng v cu trc polime d Tc dng vi kim loi hot ng to thnh photphua 10/ Cc mui nitrat no sau khi nhit phn to ra sn phm:M O +NO +O ?
2 n 2 2 3 3 2

a Ca(NO ) ;Fe(NO ) ;Ni(NO )

3 2 3 2 3

bAl(NO ) ;Zn(NO ) ;Ni(NO )

3 3 3 2 3 2 3 2

3 2 3 2

c KNO ;Cu(NO ) ;Ni(NO )

3 3 2

11/ Trong hp cht ha hc s oxi ha ca nito thng c l a -3;+1;+2;+3;+4;+5 b +1;+2;+3;+4;+5 c +2;+3;+4;+5;+6 d +1;+2;+3;+4;+5;+6 12/ Phn ng sau ang trng thi cn bng:N (k)+3H (k)-><-2NH (k) H=-92kJ.Tc ng khng lm thay i hng s cn bng l a cho cht xc tc
2 2 3

3 2

dHg(NO ) ;Zn(NO ) ;Mn(NO )

Cho thm H

13/ Cc tp hp ion no sau c th ng thi tn ti trong 1 dung dch? a Cu2+;Cl-;Na+;OH-;NO -bNa+;Ca2+;Fe2+;NO -;Cl-cFe2+;Cl-;K+;OH-;NO -dNH +;CO 2-;HCO -;OH-;Al3+ 14/ NH phn ng c vi nhm cht no sau(cc iu kin coi nh c )?
3 3 3 3 4 3 3

thay i p sut

thay i nhit

a FeO;PbO;NaOH;H SO bO ;Cl ;CuO;HCl;AlCl cCuO;KOH;HNO ;CuCl

2 4 2 2 3 3 2

15/ Cho hn hp kh X gm N ;NO;NH hi nc i qua bnh cha P O th cn li hn hp kh Y gm 2 kh l a N ;NO

2

d Cl ;FeCl ;KOH;HCl
2 3

b NH ;hi H O
3 2

c NO;NH

16/ Trong hp cht ha hc sau, hp cht no Nito c s oxi ha ca tiu? aNO b(NH ) SO cN 17/ CTHH ca supephotphat kp l aCaHPO
2 4 2 4 4

d N ;NH
2 2 3

dHNO
4 2

bCa(H PO ) v CaSO cCa(H PO )

2 4 2 4 2

18/ Axit nitric c nng phn ng c vi tt cc cc cht ca nhm no sau y? a Mg(OH) ;NH ;CO ;AubMg(OH) ;CuO;NH ;PtcCaO;NH ;Au;FeCl dMg(OH) ;CuO;NH ;Ag
2 3 2 2 3 3 2 2 3 2 2 3

4 2

dCa (PO )

19/ Phn ng sau ang trng thi cn bng:N (k)+3H (k)-><-2NH (k) H=-92kJ. thu c nhiu NH nn chn iu kin no?aNhit thp ;p sut caobNhit cao;p sut thpcNhit cao;p sut cao dNhit thp;p sut thp 20/ Phn ng no sau NO va l cht kh va l cht oxi haaNO +NaOH->NaNO +NaNO +H O b2NO ->N O
2 2 2 3 2 2 2 3

c Cu+HNO ->Cu(NO ) +NO +H O

3 3 2 2 2

d NO+O ->NO
2

21/ Nito phn ng c vi nhm cc nguyn t no sau y to ra hp cht kh? aLi;H ;Al bO ;Ca;Mg cLi;Mg;Al dO ;H
2 2 2 2 3

22/ sn xut HNO trong cng nghip cn qua cc giai on:1.Oxi ha NO;2.Cho NO tc dng vi H O;3.Oxi ha NH ;4.Chun b hn hp NH v khng kh:5.Tng hp amoniac.Trong thc t th t thc hin cc giai on nh sau
3 3 2 2

a 4-5-3-2-1 b 5-4-3-1-2 c 3-4-5-2-1 23/ NH c ln hi nc,lm th no thu c NH khan dng cht no ht nc?
3 3

d 1-2-3-4-5 d H SO c v CaO
4

a KOH v CaO

b P O v KOH
2 5 3

c Kt qu khc CaO b
3 2

24/ Cht no c th dng lm kh kh NH ?

4 2 4 4

a
3 3

PO c
2 5 3 2

CuSO

H SO c
2 4

25/ Cho cc dung dch :(NH ) SO ;NH Cl;Al(NO ) ;Fe(NO ) ;Cu(NO ) . phn bit cc dung dch trn ch dng 1 ha cht no sau? a Dung dch NH b
3 3

Dung dch Ba(OH)

26/ iu ch HNO trong phng th nghim cc ha cht cn dng l a Dung dch NaNO ;dung dch HCl c c NaNO tinh th;dung dch H SO c
3 2 4 3 3 3

Dung dch KOH d

Dung dch NaCl

b Dung dch NaNO ;dung dch H SO c d NaNO tinh th;dung dch HCl c b b,c ng
3 3 2 4

27/ Cht no sau dy tan c trong dung dch NH ?a Al(OH) 28/ Hy ch ra mnh khng ng trong cc cu sau

cZn(OH)

dCO

a P trng hot ng hn P c C th bo qun P trng trong nc 29/ Dung dch (NH ) SO lm qu tm chuyn sang mu
4 2 4 3

b P to c nhiu oxit hn nito d H PO khng c tnh oxi ha a kt qu khc cMg(NO ) ;N ;H O

3 2 2 2 2 2 3 4

tm c.xanh d

30/ Cho s phn ng:Mg+HNO rt long->X+Y+Z.Bit Y+NaOH->Kh c mi khai.Vy X,Y,Z ln lt l a Mg(NO ) ;NO;H O
3 2 2

bMg(NO ) ;NO ;H O
3 2 2 2

d Mg(NO ) ;NH NO ;H O
3 2 4 3 2

31/ Cc mui nitrat no sau khi nhit phn to ra sn phm:M+NO +O ? 32/ Mun xc nh s c mt ca ion Ag;Cu b Cu c
3 3 2 3

a AgNO ;Hg(NO ) ;NaNO bLiNO ;Fe(NO ; ;Hg(NO ) cKNO ;AuNO ;Hg(NO ) NO 3

2 4 3 3 2 3 2 3 3

trong dung dch mui nitrat ta cho dung dch mui ny tc dng vi NH
3

3 2

dAgNO ;AuNO ;Hg(NO )

3 3

3 2

Cu; H SO long d

33/ C 4 dung dch trong 4 l mt nhn sau:amonisunfat;amoniclorua;natrisunfat;natrihidroxit.Ch dng 1 ha cht no sau c th nhn bit c cc dung dch mt nhn trn? aDung dch AgNO bDung dch Ba(OH) cDung dch KOHdDung dch BaCl 34/ to xp cho cc loi bnh,c th dng mui na sau y? a(NH ) PO bNH HCO cNaCl
4 3 4 4 3 2 3 3 2 2

dCaCO

35/ Cho hn hp gm FeS;Cu S phn ng vi dung dch HNO thu c dung dch A chc chn c cha cc ion sau a Cu2+;Fe3+;S2b Cu2+;Fe3+;SO
24

c Cu+;Fe3+;SO

24

d Cu2+;Fe2+;SO

24

36/ Amophot (mt loi phn phc hp) c thnh phn ho hc l: A. NH4H2PO4 v (NH4)3PO4.B. Ca(H2PO4)2.C. NH4H2PO4 v Ca(H2PO4)2. 37/Sn phm phn ng nhit phn no sau y khng ng? A. NH4NO2

D. NH4H2PO4 v (NH4)2HPO4.

t0 t
0

N2 + 2H2O

B. NH4NO3

t0 t
0

NH3 + HNO3

C. NH4Cl NH3 + HCl D. NH4HCO3 NH3 + H2O + CO2 38/ Cho P2O5 tc dng vi dung dch NaOH, ngi ta thu c mt dung dch gm 2 cht.Hai cht c th l: A. Na3PO4 v H3PO4.B. NaH2PO4 v Na3PO4.C. NaH2PO4 v NaOH. D. Na2HPO4 v Na3PO4. 39: Nhit phn hon ton cng s mol mi mui nitrat di y, mui sinh ra th tch O 2 nh nht (trong cng iu kin) lA. AgNO3. B. Fe(NO3)3. C. Fe(NO3)2. D. KNO3. 40: Nhn xt no sau y l sai: A. Mui amoni tc dng vi dung dch kim nng gii phng kh NH3. B. Trong nc, mui amoni in li hon ton to ra mi trng axit. C. Tt c mui amoni u d tan trong nc.D. Mui amoni km bn nhit. 41: phn bit cc dung dch ring bit ng trong cc l mt nhn: NH 4NO3, (NH4)2CO3, ZnCl2, BaCl2, FeCl2. Thuc th duy nht c th dng lA. dung dch NaOH. B. dung dch HCl. C. dung dch CaCl2. D. qu tm. 42: Thi t t cho n d kh NH3 vo dung dch X th c hin tng: ban u xut hin kt ta, sau kt ta tan ht . Vy dung dch X cha hn hp :A. Al(NO3)3 v AgNO3.B. Al2(SO4)3 v ZnSO4.C. Cu(NO3)2 v AgNO3.D. CuCl2 v AlCl3. 43: Cho s phn ng: Al + HNO3 Al(NO3)3 + N2O + H2O. Tng h s cn bng (l cc s nguyn ti gin) ca cc cht tham gia phn ng l:A. 13. B. 38. C. 46. D. 64. 44/ Hm lng nit trong loi phn m no sau y l nhiu nht .a (NH ) SO b (NH ) CO c NH NO d Ca(NO ) 45/ Axit phtphoric v axit nitric cng c phn ng vi nhm cht no sau : a KOH, K O, NaHSO , NH b Na SO , NaOH, K O, NH
2 4 3 2 4 2 4 2 4 2 2 4 3 3 2

c NaOH, Na CO , NaCl, MgO

2 3

NaOH, NH , Na CO , MgO
3 2 3

46: Trn ln dung dch mui (NH4)2SO4 vi dung dch Ca(NO2)2 ri un nng th thu c kh X (sau khi loi b hi nc). X l A. NO B. N2 C. N2O D. NO2 47/.Cho 4 dung dch trong sut, mi dung dch ch cha mt loi cation v mt loi anion trong s cc ion sau: Ba2+, Al3+, Na+, Ag+, CO32-, NO3-, Cl-, SO42- . 4 dung dch l : a AgNO3, BaCl2, Al2(SO4)3, Na2CO3 b AgCl, Ba(NO3)2, Al2(SO4)3, Na2CO3 c AgNO3, BaCl2,Al2(CO3)3, Na2SO4 d Ag2CO3, Ba(NO3)2, Al2(SO4)3, NaNO3 48/. Nh t t dung dch n d dung dch NH3 vo dung dch ZnCl2 .Hin tng xy ra l : A. C kt ta xanh , sau kt ta tan to thnh dung dch xanh thm B.C kt ta trng , sau kt ta tan to thnh dung dch trong sut C.C kt ta xanh , sau kt ta tan to thnh dung dch trong sut D.Dung dch t xanh da tri chuyn qua xanh thm 49/: Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng gia Cu vi dung dch HNO3 c, nng lA. 11. B. 10. C. 8. D. 9. 50: nhn bit ba axit c, ngui: HCl, H2SO4, HNO3 ng ring bit trong ba l b mt nhn, ta dng thuc th l A. CuO. B. Al. C. Cu. D. Fe.