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Compressor K-100:
26.74 m3/sec
poly tropic efficiency 76%
Outlet temperature for poly-tropic flow:
then m 0.38
T2 393.2 K 120.05 C
Power Requirement
Reactor PFR-100:
Chemical Reactions:
Air 3816
Moisture 107.5 72.94 75
Benzene 59 133 53
Nitrogen 3014
Oxygen 512
Water 225 72.94 75
CO2 122
MAN 43 158 177
CO 26
Benzene 5 133 53
Quinone 0.94 182 155
Nitrogen 3014
Oxygen 512
Water 225 73.56 24
CO2 122
MAN 43 163 126
CO 26
Benzene 5
Quinone 0.94 189.2 104
Stream(11) is cooled from 76.5C to 50C before it enters Gas Scrubber. For energy ba
assuming 50C as reference temperature.
Nitrogen 3014
Oxygen 512
Water 225 72.94 26.5
CO2 122
MAN 25.35 148 26.5
CO 26
Benzene 4.71 137 26.5
Quinone 0.71 171.2 26.5
Mixer MIX-101:
Pure water stream (16) is added to scrubbed liquid (13) to keep the concentration of
solution up to 40%. Assuming water enters at 30C and 101Kpa while scrubbed liquid
entering at 45C.
stream (15) and (17) are leaving at same temperature. So T15 = T17 = T
Scrubber T-100:
MAN is absorbed in 40% solution of MAC entering at 44.2C while the gases leaves fro
of scubber in vent stream (14).
Feed is heated from 44.2C to 95C in vapor phase befor it enters the dehydrator
Dehydrator T-101:
Operating conditions:
Top plate temperature = 55C
Re-boiler temperature = 120 C
Operating pressure = 15.2 kpa
Assuming 100C as reference temperature
Reactions involved
Overhead condenser:
component m Cpℓ
Total Enthalpy
component m Cpℓ
Total Enthalpy
heat duty of overhead condenser
component m Cpℓ
Total Enthalpy
component m Cpℓ
Total Enthalpy
component m
Water 13.07
MAN 24.77
O-Xylene 3.79
Fumaric Acid 0.12
Quinone 0.71
component m
Water 14.75
MAN 42.51
O-Xylene 3.79
Fumaric Acid 0.12
Quinone 0.94
Total Enthalpy
component m
water 17.74
MAN 1.68
quinon 0.23
###
Operating conditions:
Top plate temperature = 160oC
Re-boiler temperature = 200oC
Ope
component m
Water 14.75
MAN 42.51
O-Xylene 3.79
Fumaric Acid 0.12
Quinone 0.94
component m
Water 54.15
MAN 1.03
O-Xylene 13.27
Quinone 3.06
component m
Water 36.9
MAN 0.73
O-Xylene 9.5
Quinone 2.2
component m
Water 14.75
MAN 0.29
O-Xylene 3.79
Quinone 0.87
component m
MAN 42.21
Fumaric Acid 0.12
Quinone 0.17
Heat duty of condenser
2
1.3
0.38 1.3 0.3 231.47
R 0.08 m3atm/kgmolK
8.31 KJ/kgmolK
Zi 1
202 Kpa
202 Kpa
m Cp
###
###
KJ/hr
KJ/hr
KJ/hr
KJ/hr
KJ/hr
KJ/hr
KJ/hr
.5C at 152Kpa. For energy
e temperature.
### KJ/hr
### KJ/hr
5 = T17 = T
CpℓΔTℓ ∆H
1092 ###
3097.5 ###
2464.5 1749.8
∆H
### (T-30)
### (T-30)
∆H
### (T-30)
### (T-30)
116.65 (T-30)
C
C
CpℓΔTℓ ∆H
199.44 ###
200.67 ###
494.9 ###
266.9 ###
981.92 ###
203.39 ###
906.44 ###
1135.6 806.28
KJ/hr
CpℓΔTℓ ∆H
58.24 ###
165.2 ###
131.44 93.32
KJ/hr
∆H
### (T-44.2)
### (T-44.2)
### (T-44.2)
### (T-44.2)
62.09 (T-44.2)
759.72 (T-44.2)
617.95 (T-44.2)
(T-44.2) KJ/hr
CpℓΔTℓ ∆H
3728.1 ###
### ###
8853.6 ###
### KJ/hr
e = 120 C
= 15.2 kpa
∆H ### KJ/kgmol
∆H ### KJ/kgmol
45C at 15.2Kpa.
water at 15.2Kpa = 53.6C
O-xylene at 15.2Kpa = 85.05C
### KJ/hr
ΔTℓ CpℓΔTℓ ∆H
20 1455.4 ###
20 3846 276912
### KJ/hr
KJ/hr
ΔTℓ CpℓΔTℓ ∆H
70 5103 ###
70 14868 ###
70 11928 ###
### KJ/hr
### KJ/hr
= ### + ### T
T = 95.42 C
condenser
re-boiler
###
###
###
∆H
###
###
###
###
###
###
406289
###
∆H
###
###
###
###
###
###
375722
###
∆H
###
###
###
###
###
###
###
###
λ ∆H
### ###
419688
λ ∆H
### ###
###
### ###
2861.4
###
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
Cpg∆Tg λ ∆H
###
5388.6
3044 46000 ###