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JOB SHEET KIMIA ANALITIK LEVEL II

ARGENTOMETRI

Disusun Oleh : TEAM TEACHING KIMIA ANALITIK

SMK NEGERI 13 BANDUNG ROGRAM KEAHLIAN ANALISIS KIMIA

=EMERINTAH KOTA BAN)>NG )INAS =EN)I)IKAN SEKOLAH MENENGAH KE5URUAN NEGERI 13 ROGRAM KEAHLIAN ANALISIS KIMIA
La$#rat#rium Kimia Analitik

INSTR>KSI KERJA EMBUATAN LARUTAN A)NO3 ? 4642( N

N# )#kumen
5S!KA!ANA!U!413!A!2!41

1! Al"# : Neraca teknis Gelas ukur 1000 mL Gelas kimia100 mL Batan !en a"uk B#t#l sem!r#t B#t#l rea en c#klat "an la$el

$! %insi& Ke%'" : Se%umla& tertentu A NO' !a"at "ilarutkan lalu "iencerkan "alam a(ua )M $e$as kl#ri"a &in a k#nsentrasi "an *#lum +an "iin inkan,

(! L"n)*"h Ke%'" : Tim$an A NO' !a"at se$an+ak -./0 ram, Larutkan "alam 1000 mL a(ua )M $e$as kl#ri"a, H#m# enkan, Masukkan ke "alam $#t#l rea en c#klat "an $eri la$el,

2! B"h"n : A NO' !a"at A(ua )M $e$as kl#ri"a

+! e%s",""n Re"*si : H/O A NO'1s2 3 A NO'1a(2

3! D"#" M"s" A#-, Rel"#i. /A%0 :

1! e%hi#un)"n :

A 4 105 6 N 4 1- 6 O 4 17

N A NO' 4 ek, A NO'8V Larutan1L2 Berat A NO' + &arus "itim$an 4 BE A NO' 9 ek A NO' Sisa larutan "i$uan !a"a tem!at +an "ise"iakan Hati:&ati "en an A NO'. karena $ersi;at l# am $erat Tutu! kran air. kran as "an %en"ela "en an $enar6 Bersi&kan me%a. lantai "an ruan tim$an se$elum menin alkan la$,

2! Kesel","#"n Ke%'" d"n LH 3! e%h"#i"n

14! L"&-%"n 11! us#"*"

La!#ran "i$uat "alam lem$ar la!#ran +an "ise"iakan V# el. Art&ur I, In#r anic <uantitati*e Anal+sis

1! Al"# : Neraca analitis La$u ukur /00 mL Buret 00 mL =i!et seukuran /0 mL B#t#l tim$an B#t#l sem!r#t @#r#n tan kai !en"ek La$u Erlenme+er /00 mL Batan !en a"uk Klem $uret Stati; Sen"#k8 s!atula Te el !uti&

$! %insi& Ke%'" : Se%umla& tertentu larutan Na@l stan"ar "ititrasi #le& larutan A NO' +an akan "iteta!kan k#nsentrasin+a !a"a suasana netral "en an men unakan in"ikat#r K/@rO- sam!ai "en an ter$entuk en"a!an Aarna mera& $ata, =a"a TE mek A NO ' 4 mek Na@l se&in a k#nsentrasi A NO' "a!at "i&itun , (! L"n)*"h Ke%'" : Tim$an ? 0.'B ram Na@l !,a, $ilasi ke "alam la$u ukur /00 mL. larutkan "an encerkan &in a te!at, =i!et /0.00 mL "an masukkan ke "alam la$u Erlenme+er /00 mL, Tam$a&kan 10 mL a(ua )M "an 0.0 mL larutan K/@rO- 0C Titrasi "en an larutan A NO' +an akan "iteta!kan k#nsentrasin+a sam!ai ter$entuk en"a!an Aarna mera& $ata >lan i titrasi sam!ai "i!er#le& *#lume !eniter k#nstan Hitun n#rmalitas A NO'

2! B"h"n : Na@l !,a kerin A NO' 0.0/0 N Larutan K/@rO- 0C A(ua )M Kertas isa! 3! D"#" M"s" A#-, Rel"#i. /A%0 : Na 4 /'6 @l 4'0.0

+! e%s",""n Re"*si :
A NO' 1a(2 ? Na@l 1a(2 3 A @l 1s2 ? NaNO' 1a(2 1t$2 1t$2 1!uti&2 1t$2 / A NO' 1a(2 ? K/@rO- 1a(2 3 A /@rO- 1s2 ? / KNO' 1a(2 1t$2 1kunin 2 1mera& $ata2 1t$2

1! e%hi#un)"n : K#nsentrasi Na@l 4 Berat Na@l8 BE 9 10008/00 Eki*alen Na@l 4 DNa@lE 9 V +an "i!i!et K#nsentrasi A NO' 4 eki*alen Na@l 8 V !eniter Sisa larutan "i$uan !a"a tem!at +an "ise"iakan Hati:&ati "en an A NO'. karena $ersi;at l# am $erat Tutu! kran air. kran as "an %en"ela "en an $enar6 Bersi&kan me%a. lantai "an ruan tim$an se$elum menin alkan la$,

2! Kesel","#"n Ke%'" d"n LH 3! e%h"#i"n

14! L"&-%"n 11! us#"*" 1! Al"# :

La!#ran "i$uat "alam lem$ar la!#ran +an "ise"iakan V# el. Art&ur I, In#r anic <uantitati*e Anal+sis $! %insi& Ke%'" :

Neraca analitis La$u ukur /00 mL Buret 00 mL =i!et seukuran /0 mL B#t#l tim$an B#t#l sem!r#t @#r#n tan kai !en"ek La$u Erlenme+er /00 mL Batan !en a"uk Klem $uret Stati; Sen"#k8 s!atula Te el !uti&

Se%umla& tertentu larutan sam!el aram @l : +an akan "itentukan ka"arn+a. "ititrasi #le& larutan A NO ' stan"ar !a"a suasana netral "en an men unakan in"ikat#r ;lu#rescein sam!ai "en an ter$entuk en"a!an Aarna mera& mu"a, =a"a TE mek A NO ' 4 mek @l: se&in a ka"ar @l: "a!at "i&itun , (! L"n)*"h Ke%'" : Tim$an ? 0.'B ram sam!el aram @l: $ilasi ke "alam la$u ukur /00 mL. larutkan "an encerkan &in a te!at, =i!et /0.00 mL "an masukkan ke "alam la$u Erlenme+er /00 mL, Tam$a&kan 10 mL a(ua )M "an 1 tetes larutan in"ikat#r ;lu#rescein, Titrasi "en an larutan A NO' stan"ar sam!ai ter$entuk en"a!an mera& mu"a 1!ink2, >lan i titrasi sam!ai "i!er#le& *#lume !eniter k#nstan Hitun ka"ar @l: "alam sam!el,

2! B"h"n : Sam!el aram Na@l A NO' st" 0.0/0 N Larutan K/@rO- 0C A(ua )M Kertas isa!

+! e%s",""n Re"*si :
A NO' 1a(2 ? @l: 1a(2 3 A @l 1s2 ? NO': 1a(2 1t$2 1t$2 1!uti&2 1t$2 A @l 1s2 ? nA ? 1a(2 3 1A @l2nA ? 1s2 1!uti&2 1t$2 1!uti&2 1A @l2nA ? 1s2 ? HFl 1a(2 3 1A @l2nA ?Fl: 1s2 ? H? 1a(2

1!uti&2 1kunin &i%au2 1mera& mu"a2 3! D"#" M"s" A#-, Rel"#i. /A%0 : @l 4'0.0 1! e%hi#un)"n : mek @l: Berat @l: Ka"ar @l: 4 V#lume !eniter 9 D A NO' E 4 mek @l: 9 BE 9 V La$u8V =i!et 4 $erat @l: 8 $erat sam!el 9 100 C

1t$2

2! Kesel","#"n Ke%'" d"n LH 3! e%h"#i"n

Sisa larutan "i$uan !a"a tem!at +an "ise"iakan Hati:&ati "en an A NO'. karena $ersi;at l# am $erat Tutu! kran air. kran as "an %en"ela "en an $enar6 Bersi&kan me%a. lantai "an ruan tim$an se$elum menin alkan la$,

14! L"&-%"n 11! us#"*" 1! Al"# :

La!#ran "i$uat "alam lem$ar la!#ran +an "ise"iakan V# el. Art&ur I, In#r anic <uantitati*e Anal+sis $! %insi& Ke%'" :

Neraca teknis Gelas ukur 1000 mL Gelas kimia100 mL Batan !en a"uk B#t#l sem!r#t B#t#l rea en "an la$el

Se%umla& tertentu KS@N !a"at "ilarutkan lalu "iencerkan "alam a(ua )M &in a k#nsentrasi "an *#lum +an "iin inkan,

(! L"n)*"h Ke%'" : Tim$an KS@N !a"at se$an+ak /.- ram, Larutkan "alam 1000 mL a(ua )M, Masukkan ke "alam $#t#l rea en "an "i$eri la$el H#m# enkan,

2! B"h"n : KS@N !a"at A(ua )M

+! e%s",""n Re"*si : H/O KS@N1s2 3 KS@N1a(2

3! D"#" M"s" A#-, Rel"#i. /A%0 : K 4 'G 6 S 4 '/ 6 @ 4 1/ 6 N 4 1-

1! e%hi#un)"n :

N, KS@N 4 ek KS@N8V Larutan1L2 Berat NaOH + &arus "itim$an 4 BE KS@N 9 ek KS@N Sisa larutan "i$uan !a"a tem!at +an "ise"iakan Tutu! kran air. kran as "an %en"ela "en an $enar6 Bersi&kan me%a. lantai "an ruan tim$an se$elum menin alkan la$, La!#ran "i$uat "alam lem$ar la!#ran +an "ise"iakan V# el. Art&ur I, In#r anic <uantitati*e Anal+sis

2! Kesel","#"n Ke%'" d"n LH 3! e%h"#i"n

14! L"&-%"n 11! us#"*"

1! Al"# :

$! %insi& Ke%'" :

La$u Erlenme+er /00 mL Buret c#klat 00 mL Gelas kimia /0 mL Gelas kimia 0 mL =i!et seukuran /0 mL B#t#l sem!r#t

Se%umla& tertentu larutan A NO ' stan"ar "ititrasi #le& larutan KS@N +an akan "iteta!kan k#nsentrasin+a !a"a suasana asam "en an men unakan in"ikat#r Fe1III2 sam!ai "en an ter$entuk Aarna %in a mera& +an teta!, =a"a TE mek A NO ' 4 mek KS@N se&in a k#nsentrasi KS@N "a!at "i&itun , (! L"n)*"h Ke%'" : =i!et /0.00 mL larutan A NO' stan"ar. masukkan ke "alam la$u Erlenme+er /00 mL, Tam$a&kan /:' mL HNO' - N "an 0.0 mL larutan in"ikat#r Fe1III2 %enu&, Titrasi "en an larutan KS@N +an akan "iteta!kan k#nsentrasin+a sam!ai "en an ter$entuk Aarna %in a mera& +an teta!, >lan i titrasi sam!ai "i!er#le& *#lume !eniter k#nstan, Hitun n#rmalitas KS@N,

2! B"h"n : KS@N ? 0.0/0 N A NO' st" 0.0/0 N Larutan HNO' - N Larutan Fe1III2 %enu& A(ua )M Kertas isa! 3! D"#" M"s" A#-, Rel"#i. /A%0 : A 4 105 6 N 4 1- 6 O 4 17 K 4 'G 6 S 4 '/ 6 @ 4 1/ 2! Kesel","#"n Ke%'" d"n LH 3! e%h"#i"n

+! e%s",""n Re"*si :
A NO'1a(2 ? KS@N1a(2 3 A S@N1s2 ? KNO'1a(2 1t$2 1t$2 1!uti&2 1t$2 '? /? KS@N1a(2 ? Fe 1a(2 3 DFeS@NE 1a(2 ? K?1a(2 1t$2 1kunin 2 1%in a mera&2 1t$2

1! e%hi#un)"n : N, KS@N 4 1V,N2A NO' 8 V !eniter

Sisa larutan "i$uan !a"a tem!at +an "ise"iakan Hati:&ati "en an A NO'. karena $ersi;at l# am $erat Tutu! kran air. kran as "an %en"ela "en an $enar6 Bersi&kan me%a. lantai "an ruan tim$an se$elum menin alkan la$,

14! L"&-%"n 11! us#"*" 1! Al"# : Neraca analitis La$u ukur /00 mL Buret 00 mL =i!et seukuran /0 mL =i!et seukuran 00 mL Ta$un reaksi

La!#ran "i$uat "alam lem$ar la!#ran +an "ise"iakan V# el. Art&ur I, In#r anic <uantitati*e Anal+sis $! %insi& Ke%'" : Se%umla& tertentu larutan sam!el aram @l : "ireaksikan "en an larutan A NO' stan"ar terukur "an $erle$i& lalu "i!anaskan &in a en"a!an A @l men um!al, Sisa A NO ' "ititrasi "en an KS@N stan"ar !a"a suasana asam "en an men unakan in"ikat#r Fe1III2 sam!ai ter$entuk Aarna %in a mera& +an teta!, =a"a saat TE mek A NO' sisa 4 mek KS@N. se&in a

B#t#l tim$an B#t#l sem!r#t @#r#n tan kai !en"ek La$u Erleme+er /00 mL Batan !en a"uk Klem Buret Stati; Sen"#k8s!atula Te el !uti& =em$akar Kassa as$es Kaki ti a Kaca arl#%i

ka"ar @l: "a!at "i&itun ,

(! L"n)*"h Ke%'" : Tim$an 0.- ram sam!el aram @l: $ilasi ke "alam la$u ukur /00 mL "en an a(ua )M. larutkan lalu encerkan &in a tan"a $atas, =i!et /0.00 mL larutan sam!el aram. masukkan ke "alam la$u Erlenme+er /00 mL, Tam$a&kan 00.00 mL larutan A NO' stan"ar, Tam$a&kan / mL KNO' 1 M. lalu "i"i&kan selama ' menit, Tam$a&kan /:' mL HNO' - N "an 0.0 mL larutan in"ikat#r Fe1III2 %enu&, Titrasi "en an larutan KS@N stan"ar sam!ai "en an ter$entuk Aarna %in a mera& +an teta!, >lan i titrasi sam!ai "i!er#le& *#lume !eniter k#nstan, Hitun ka"ar @l: "alam sam!el, +! e%s",""n Re"*si :
A NO' 1a(2 $erle$i& ? @l: 1a(2 3 A @l 1s2 ? NO': 1a(2 1t$2 1t$2 1!uti&2 1t$2 A NO'1a(2 sisa ? KS@N1a(2 3 A S@N1s2 ? KNO'1a(2 1t$2 1t$2 1!uti&2 1t$2 KS@N1a(2 ? Fe'?1a(2 3 DFeS@NE/?1a(2 ? K?1a(2 1t$2 1kunin 2 1%in a mera&2 1t$2

2! B"h"n : Sam!el aram @l: KS@N stan"ar ? 0.0/0 N A NO' stan"ar 0.0/0 N Larutan HNO' - N Larutan Fe1III2 %enu& A(ua )M Kertas isa! 3! D"#" M"s" A#-, Rel"#i. /A%0 : @l 4'0.0

1! e%hi#un)"n : mek @l: m @l: C @l: 4 1V9N2 A NO' H 1V9N2 KS@N 4 mek @l: 9 BE 9 V La$u8V =i!et 4 1m @l: t#tal8 m sam!el 2 9 100 C

2! Kesel","#"n Ke%'" d"n LH 3! e%h"#i"n

Sisa larutan "i$uan !a"a tem!at +an "ise"iakan Hati:&ati "en an A NO'. karena $ersi;at l# am $erat Tutu! kran air. kran as "an %en"ela "en an $enar6 Bersi&kan me%a. lantai "an ruan tim$an se$elum menin alkan la$,

14! L"&-%"n 11! us#"*"

La!#ran "i$uat "alam lem$ar la!#ran +an "ise"iakan V# el. Art&ur I, In#r anic <uantitati*e Anal+sis