edita o arquivo hosts que se localiza em Windows/system32/drivers/etc e coloca isso:

127.0.0.1 www.orkut.com
agora se quer bloquear msn tbm veja isso:
127.0.0.1 gtwy.messenger.hotmail.com
127.0.0.1 gateway.messenger.hotmail.com
127.0.0.1 messenger.hotmail.com
127.0.0.1 loginnet.passport.com
127.0.0.1 login.passport.com
127.0.0.1 www.msn2go.com.br
127.0.0.1 www.e-messenger.com
127.0.0.1 www.emessenger.com
127.0.0.1 www.e-messenger.net
127.0.0.1 atlanta.e-messenger.net/servlet/light/messenger
127.0.0.1 phonefox.com
127.0.0.1 www.centova.net
127.0.0.1 www.chat-sigilo.kit.net
127.0.0.1 www.iloveim.com
127.0.0.1 www.rabbitandpork.com/webmsn/webmsn?started=
127.0.0.1 www.kproxy.com
127.0.0.1 www.filterxp.com
127.0.0.1 webmessenger.com
127.0.0.1 onlinemessenger.nl
127.0.0.1 85.184.4.4
127.0.0.1 zimage.dk/m/index.php
127.0.0.1 www.antion.co.uk
127.0.0.1 www.poloicq.cjb.net
127.0.0.1 www.msn2go.com
127.0.0.1 216.32.84.237
127.0.0.1 www.ILoveIM.com

ainda consta mais servidores proxy virtuais, precisa procurar.

Para bloquear o Orkut e aqueles Webmessengers:
Clique no Menu Iniciar, v em Executar... e digite:

Se estiver em Windows 95, 98 ou ME:

"%WINDIR%\hosts" (sem aspas), ou ento "%WINDIR%\hosts.sam";
Se estiver em Windows NT, 2000, XP ou 2003:
"%WINDIR%\system32\drivers\etc\hosts" (sem aspas), ou ento "%WINDIR%\system32\drivers\etc\hosts.sam.
Aps digitar, d Ok. O Windows perguntar com qual programa abrir, selecione Bloco de notas e abra.

Abaixo de 127.0.0.1 Localhost escreva:

0.0.0.0 www.orkut.com
0.0.0.0 webmessenger.msn.com
0.0.0.0 www.e-messenger.net