questo 1.

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24/05/2014 07:53:26

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!
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*****************************************************************
Graficao da converso, das relaes de presso (y) e presses
parciais do tolueno, hidrognio e benzeno em funo da massa de
catalisador (w)
*****************************************************************
Dados do Problema: Fluxo de 50 mol/min sendo 30% tolueno,
45% hidrognio e 25% inertes.
Alfa(parmetro de queda de presso)= 9.8x(10^(-5))/kg
T=640C ; Densidade Volumtrica = 400kg/m^3
******************************************************************
program primeira questao
implicit double precision (a-h,o-z)
double precision x(1000),w(1000),ph2(1000),pt(1000),pb(1000)
double precision z1(1000),z2(1000),z3(1000),z4(1000),y(1000)
******************************************************************
Declarao de variveis referentes a questo
m= quantidade de dados gerados em funo do delta
x= converso ; w= massa de catalisador
fto= fluxo de tolueno ; ak= constante de velocidade
akt= contante de equilbrio de adsoro de tolueno
akb= contante de equilbrio de adsoro de benzeno
******************************************************************
m=26
x(1)=0.0d+0
w(1)=0.0d+0
fto=50.0d+0
ak=0.00087d+0
akt=1.038d+0
akb=1.39d+0
alpha=0.000098d+0
pto=12.0d+0
do 10 i=1,m

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******************************************************************
OBS:Intervalos dos passos de 400 em 400 implicando um menor nmero
de pontos para gerao do grfico comparativo com a questo 10-3
Valores de W compreendidos entre 0 - 10000 para peso.
******************************************************************
delta=400.0d+0

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10

******************************************************************
Mtodo Numrico Runge-kutta 4 ordem
******************************************************************
w(i+1)=w(i)+delta
z1(i)=delta*fun(w(i),x(i))
z2(i)=delta*fun(w(i)+delta/2.0d+0,x(i)+z1(i)/2.0d+0)
z3(i)=delta*fun(w(i)+delta/2.0d+0,x(i)+z2(i)/2.0d+0)
z4(i)=delta*fun(w(i)+delta,x(i)+z3(i))
x(i+1)=x(i)+((z1(i)+(2.0d+0*z2(i))+(2.0d+0*z3(i))+z4(i))/5.999d+0)
******************************************************************
Descrio de equaes para a funo principal
******************************************************************
y(i)=(1.0d+0-alpha*w(i))**(0.5d+0)
ph2(i)=pto*(1.5d+0-x(i))*y(i)
pb(i)=pto*x(i)*y(i)
pt(i)=pto*(1.0d+0-x(i))*y(i)
continue
open(50,File='Resultados.txt')
write(50,*)' ---------------------------------------------'
Resultados
|'
write(50,*)' |
write(50,*)' ---------------------------------------------'

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questo 1.f

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24/05/2014 07:53:26

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do i=1,m
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write(50,*)'|Resultados para primeira questo|'
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write(50,*)'-----------------------------'
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=',w(i)
write(50,*)'|massa de catalisador
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=',x(i)
write(50,*)'|converso
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=',y(i)
write(50,*)'|relao de presso
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=',ph2(i)
write(50,*)'|presso de h2
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=',pt(i)
write(50,*)'|presso de tolueno
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=',pb(i)
write(50,*)'|presso de benzeno
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write(50,*)'-----------------------------'
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end do
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close (50)
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stop
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end program
82: !
******************************************************************
83: !
Clculo da funo principal
84: !
******************************************************************
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double precision function fun(w,x)
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implicit double precision (a-h,o-z)
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double precision x(1000),w(1000)
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do i=1,m
!Funes inseridas na funo principal --> d(x)/d(w) = -(-k*pt*ph2/(1 +akb*pb+akt*pt))/fto
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fun = -(-0.00087d+0*(12.0d+0*(1.0d+0-x(i))*((1.0d+0-0.000098d+0* &
!y(i)=(1.0d+0-alpha*w(i))**(0.5d+0)
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&w(i))**(0.5d+0)))*(12.0d+0*(1.5d+0-x(i))*((1.0d+0-0.000098d+0*w(i)&
!ph2(i)=pto*(1.5d+0-x(i))*y(i)
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&)**(0.5d+0)))/(1.0d+0+1.39d+0*(12.0d+0*x(i)*((1.0d+0-0.000098d+0* &
!pb(i)=pto*x(i)*y(i
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&w(i))**(0.5d+0)))+1.038d+0*(12.0d+0*(1.0d+0-x(i))*((1.0d+0&
!pt(i)=pto*(1.0d+0-x(i))*y(i)
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&0.000098d+0*w(i))**(0.5d+0)))))/50.0d+0
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return
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end do
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end

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