s p e c t r o g r a p h h a v i n g s o me o f t h e a d v a n t a g e s o f t h e c o n c a v e o p t i c a l g r a t i n g .

T h e l a t t e r me t h o d p e r mi t s t h e s t u d y o f s c a t t e r i n g a t o t h e r a n g l e s t h a n
1 8 0 0 , ma i n t a i n i n g g o o d h o mo g e n e i t y o f s c a t t e r i n g a n g l e .
I
G . W e n t z e l , Z e i t s . P h y s . , 4 3 , 1 - 2 , p p . 1 - 8 , 1 9 2 7 ; I b i d . , 4 3 , 1 1 - 1 2 , p p . 7 7 9 - 7 8 7 ,
1 9 2 7 .
2
J . E . M. J a u n c e y , P h y s . R e v . , 2 5 , p p . 3 1 4 - 3 2 2 , Ma r . , 1 9 2 5 ; I b i d . , 2 5 , p p . 7 2 3 -
7 3 6 , J u n e , 1 9 2 5 .
a S me k a l , N a t u r w i s s . , 1 1 , p p . 8 7 3 , 1 9 2 3 . Z e i t s . P h y s . , 3 2 , p p . 2 4 1 , 1 9 2 5 .
4
J . W . Du Mo n d , N a t u r e , 1 1 6 , p . 9 3 7 , De c . , 1 9 2 5 .
6 B e r g e n Da v i s , P r o c . N a t . . 4 c a d . S c i , , 1 3 , p p . 4 1 9 , J u n e , 1 9 2 7 . P h y s . R e v . , p p .
3 3 1 , S e p t . , 1 9 2 8 .
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B y S T AN LZ Y S MI T H
Du P AR T MI N T Ol t P H YS I C S , UN I V 1 R S I T Y o r ALB g R T A
C o mmu n i c a t e d S e p t e mb e r 1 4 , 1 9 2 8
T h e mo s t c o n s p i c u o u s l i n e s i n t h e s p e c t r u m o f d o u b l y i o n i z e d l e a d
( P b I I I ) w o u l d b e e x p e c t e d t o a r i s e f r o m s i n g l e t a n d t r i p l e t t e r ms a s i n
t h e c a s e o f H g I . I n t h e n o r ma l s t a t e o f t h e P b ++ i o n t h e t w o v a l e n c e
e l e c t r o n s a r e p r e s u ma b l y i n 6 s o r b i t s g i v i n g r i s e t o t h e l o w e s t t e r m ( 6 s 6 s ) ' S o .
Ot h e r i mp o r t a n t t e r ms t o b e e x p e c t e d a r e ( 6 s 6 p ) 3 P O, , , 2 , ( 6 s 6 d ) 3 Db , 2 , 3 ,
( 6 s 6 f ) 3 F2 , 3 , 4 , ( 6 s 7 s ) 3 S l
a n d ( 6 p 6 p ) ' P o , 1 , 2 .
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a s t h i s c o mmu n i c a t i o n d e a l s o n l y w i t h c o mb i n a t i o n s b e t w e e n t r i p l e t
t e r ms .
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1 2 7 9 . 4 4 ( 1 5 )
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8 5 6 9 4 1 4 5 9 9
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9 9 5 . 7 5 ( 1 0 )
1 0 0 4 2 8 1 4 5 9 5
1 0 7 4 . 6 3 ( 1 5 )
9 3 0 5 5 1 4 5 9 7
4 7 7
1 0 6 9 . 1 5 ( 2 0 )
9 3 5 3 2 1 4 5 9 2
1 0 9 8 . 3 9 ( 1 0 )
9 1 0 4 2 1 4 5 9 5
( 6 s 6 p ) 3 P 2
1 4 0 6 . 5 7 ( 1 2 )
7 1 0 9 5
1 4 7 3 8
1 1 6 5 . 0 5 ( 1 5 )
8 5 8 3 3
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( 6 s 7 s ) I S , 1 0 5 2 . 2 3 ( 7 )
9 5 0 3 6 3 9 9 4
8 7 8 P H YS I C S : S . S MI T H P R OC . N . A. S .
A s e a r c h w a s f i r s t ma d e f o r t h e c h a r a c t e r i s t i c g r o u p 3 P - P w h i c h i s
u s u a l l y s t r o n g i n t h e s p e c t r u m o f a n a t o m w i t h t w o v a l e n c e e l e c t r o n s .
On r e f e r r i n g t o t h e w a v e - l e n g t h me a s u r e s o f C a r r o l l ' o f t h e h o t s p a r k i n
t h e S c h u ma n n r e g i o n a n d t o s o me u n p u b l i s h e d me a s u r e s ma d e b y Dr .
R . J . La n g i n t h e s a me r e g i o n t h e 3 P - T a n d 3 P - 3 D c o mb i n a t i o n s
w e r e f o u n d t o a p p e a r w i t h c o n s i d e r a b l e i n t e n s i t y . T h e s e c o mb i n a t i o n s
t o g e t h e r w i t h
( 6 s 6 p ) 3 P - ( 6 s 7 ; ) 3 S
a r e g i v e n i n t a b l e 1 , La n g ' s me a s u r e s b e i n g
q u o t e d .
A s e a r c h w a s t h e n ma d e f o r t h e f u n d a me n t a l c o mb i n a t i o n 3 D- 3 F,
u s i n g me a s u r e s ma d e b y t h e a u t h o r 2 i n t h e h o t v a c u u m s p a r k f o r t h e
r e g i o n 2 3 0 0 A t o 5 0 0 0 A. An o u t s t a n d i n g t r i p l e t o f l i n e s X X 3 0 4 3 . 9 2 ,
3 1 3 7 . 9 2 , 3 1 7 6 . 6 1 b e l o n g s t o t h i s c o mb i n a t i o n . T h e s e l i n e s w e r e a t t r i b u t e d
t o P b I I I b y K i mu r a a n d N a k a mu r a 3 a n d h a v e b e e n me n t i o n e d b y R a o
a n d N a r a y a n 4 a s p r o b a b l y f o r mi n g p a r t o f a 3 D- 3 F c o mb i n a t i o n . T h e
c o mp l e t e g r o u p i s a s f o l l o w s , t h e w a v e - l e n g t h s b e i n g g i v e n a s X I A a i r .
T AB LE 2
FUN DAMI N T AL T R I P I Z r OP P B I I I
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( 6 s 6 f ) 3 F8 3 1 3 7 . 9 2 ( 1 0 ) 3 2 4 2 . 8 6 ( 5 )
3 1 8 5 9 . 0 1 0 3 0 . 9 3 0 8 2 8 . 1
5 0 2 . 9 5 0 2 . 1
( 6 s 6 f ) 3 F2 3 0 4 3 . 9 2 ( 1 0 ) 3 0 8 9 . 1 6 ( 6 ) 3 1 9 0 . 8 9 ( 0 )
3 2 8 4 2 . 8 4 8 0 . 9 3 2 3 6 1 . 9 1 0 3 1 . 7 3 1 3 3 0 . 2
1 4 0 . 8
( 6 s 6 f ) 3 F4 3 1 7 6 . 6 1 ( 1 0 )
3 1 4 7 1 . 0
I t w i l l b e n o t i c e d t h a t t h e 3 F t e r ms a r e a b n o r ma l , 3 Fs b e i n g l o w e r t h a n
3 F2 . I t i s a l s o i n t e r e s t i n g t o o b s e r v e t h a t C a r r o l l ' g a v e t w o a l t e r n a t i v e
c h o i c e s f o r t h e d i f f u s e t r i p l e t o f P b I V a n d t h a t i n t h e f i r s t o f t h e s e o c c u r s
t h e l i n e X 1 0 6 9 . 1 5 w h i c h h a s h e r e b e e n i d e n t i f i e d a s ( 6 s 6 p ) ' P , - ( 6 s 6 d ) 3 D2
o f P b I I I . N o t mu c h p r o g r e s s h a s b e e n ma d e i n t h e i d e n t i f i c a t i o n o f t h e
s i n g l e t s p e c t r u m. H o w e v e r , i t i s p r o b a b l e t h a t X 1 0 4 8 . 8 6 i s ( 6 s 6 s ) ' S o
- ( 6 s 6 p ) ' P , .
An a t t e mp t i s b e i n g ma d e t o i d e n t i f y f u r t h e r mu l t i p l e t s w h i c h w i l l
e n a b l e t h e t e r m v a l u e s t o b e d e d u c e d .
T h e a u t h o r w i s h e s t o e x p r e s s h i s t h a n k s t o Dr . R . J . La n g f o r t h e u s e o f
h i s w a v e - l e n g t h me a s u r e s i n t h e S c h u ma n n r e g i o n a n d t o a c k n o w l e d g e a
g r a n t f r o m t h e R e s e a r c h C o u n c i l o f C a n a d a w h i c h w a s o f a s s i s t a n c e i n
t h i s w o r k .
1
C a r r o l , J . A. , P h i l . T r a n s . R o y . S o c . , A2 2 5 , 3 5 7 - 4 2 0 , 1 9 2 5 .
2
S mi t h , S . , P r o c . R o y . S o c . C a n a d a , 1 9 2 8 ( i n p r e s s ) .
' K i mu r a , M. , a n d N a k a mu r a , G . , J a p . J . P h y s . , 3 , 1 9 7 - 2 1 5 , 1 9 2 4 .
4 R a o , K . R . , a n d N a r a y a n , A. L. , P r o c . R o y . S o c . , A1 9 , 6 0 7 - 6 2 7 , 1 9 2 8 .
P H YS I C S : S . S MI T H V OL, . 1 4 , 1 9 2 8 8 7 9