EQUAO DE ANTOINE

de vapor, mmHg
B pT == presso
temperatura, C
log p = A C + T A, B, C = constantes
Substncia

Frmula
C3H6O

A
7.02447

B
1161.00

C2H4O2

7.18807

1416.70

H2O

7.96681

1668.21

C6H7N

7.24179

1675.30

5 Benzeno

C8H6

6.90565

1211.03

6 i-Butano

C4H10

6.74808

882.80

7 n-Butano

C4H10

6.83029

945.90

8 Estireno

C8H8

6.92409

1420.00

C2H6O

8.04494

1554.30

10 ter dietlico

C4H10O

6.78574

994.20

11 Etilbenzeno
12 Etilenoglicol
13 n-Heptano

C8H10
C7H16

6.95719
7.88080
6.90240

1424.26
1957.00
1268.12

14 n-Hexano

C6H14

6.87776

1171.53

15 n-Octano

C8H18

6.92370

1355.13

16 i-Pentano

C5H12

6.78967

1020.01

17 n-Pentano

C5H12

6.85221

1064.63

18 Tolueno

C7H8

6.95464

1344.80

19 o-Xileno

C8H10

6.99891

1474.68

20 m-Xileno

C8H10

7.00908

1462.27

21 p-Xileno

C8H10

6.99052

1453.43

1 Acetona
2 cido actico
3 gua
4 Anilina

9 Etanol

OINE

vapor, mmHg

C
224.00
211.00
228.00
200.00
220.79
240.00
240.00
206.00
222.65
220.00
213.21
193.80
216.90
222.37
209.52
233.10
232.00
219.48
213.69
215.11
215.31

Presso = 1500

SUBST. A =
CTE. A =
CTE. B =
CTE. C =
Teb =

Temp. (C)
55.4271
57.4849
59.5427
61.6006
63.6584
65.7162
67.7740
69.8319
71.8897
73.9475
76.0053
78.0632
80.1210
82.1788
84.2366
86.2945
88.3523
90.4101
94.5258
96.5836

ter dietlico

10

6.7857
994.1950
220.0000
55.4

pA
1500.00
1595.37
1695.26
1799.80
1909.14
2023.40
2142.71
2267.21
2397.04
2532.33
2673.21
2819.82
2972.30
3130.77
3295.38
3466.25
3643.53
3827.33
4215.09
4419.29

Curva de equilbrio:
ter dietlico

(mmHg)

pB
285.42
313.72
344.35
377.47
413.22
451.77
493.30
537.98
585.99
637.54
692.81
752.02
815.37
883.11
955.44
1032.62
1114.88
1202.48
1394.77
1500.00
/

x
1.0000
0.9256
0.8555
0.7892
0.7265
0.6670
0.6103
0.5563
0.5047
0.4552
0.4076
0.3617
0.3174
0.2745
0.2327
0.1921
0.1523
0.1133
0.0373
0.0000
Etanol

SUBST. B =
CTE. A =
CTE. B =
CTE. C =
Teb =

y
1.0000
0.9844
0.9668
0.9470
0.9247
0.8997
0.8719
0.8409
0.8065
0.7684
0.7264
0.6800
0.6290
0.5728
0.5113
0.4438
0.3699
0.2892
0.1048
0.0000

Etanol

8.0449
1554.3000
222.6500
96.6

a
5.0853
4.9230
4.7681
4.6202
4.4788
4.3436
4.2143
4.0906
3.9721
3.8585
3.7497
3.6453
3.5452
3.4491
3.3568
3.2681
3.1829
3.0221
2.9462

Curva de equilbrio: ter dietlico-Etanol (1500 mmHg)

1.0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

Diagrama das temperaturas de ebulio

100
96
92
88
84

80
76
72
68
64
60
56
52
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0