1)

= 10lb

= 10lb
P = 50

T =60F o T =519.65R
a)

= 0.31251171mol.lb

= 0.53545803

=0.84796974mol.lb

Ahora calculando la fraccin molar

Ahora calculando la fraccin molar

b)

= 0.3685411109(31.9988

) + (28.0134

=29.48218374

c)

R = 1545.33

=52.4157238

d)
R = 10.7315

T = 520R
P = 50 psia

= 94.63986755

e)

(V)

Ahora tenemos la presin parcial

= 0.3685411109 (50 psia)

=18.42705555 psia
Ahora tenemos la presin parcial

=0.6314588891psia

=31.57294446 psia

2)

= 26 lb T = 60 F <> 519.65R

=? R =

= 100

P = 75 psia

=1.343994495mol.lb

= 0.4158672416 mol.lb

=0.3094262984

=0.6905737016

= (

= 0.6905737061 (75) psia

= 51.79302762 psia

= 0.6905737016 (28.0134

) + 0.3094262904 (31.9988

= 29.24658757

3)









Q =100 000

(24hr) =24 00 000 BTU

Entonces se tiene

= 2

P = 3000 psia
T =70 F <> 529.65R

P = 3000 psia (

a)

1.054908887 mol.lb

13.71428571 mol.lb

= 13 cilindros

b) ecuacin de van der Waals:
(P +

) (V - nb) = nRT

(

) (V - nb) =nRT

P

nb + a

V -a

nRT

) (

) -

) (2

) + (n)

( ) (2

) +

n (

) (529.67R)

Lo cual se transforma en:

-2.9175

n
1 -0.7296
1.01 -0.7051
1.02 -0.681
1.04 -0.6313
1.06 -0.58197
1.10 -0.48
1.20 -0.228
1.40 -0.32836

Se tiene

Entonces



=


= 10.79865017



11

C ) ecuacin de BEATIE BRIDGEMAN

P =

P = 0

Ahora como
=

En lo cual obtenemos
n
1 -124.6633
1.01 -82.438798
1.03 2.07226916
1.04 44.35884784

Del grafico:

= 13.3148405

= 13.3148405


d) ecuacin de estado correspondiente :
n =

Como

= 11.18078

Cantidad de energa en el cilindro

=17500

= 1830 750

4) m = 1000

P = 50 atm (

) psia = 734.8 psia
T = 300 F <>422.038889k <> 760 R

Componente n (mol)

P (atm)

0.5 0.5 45.8 190.3 25 0.54585 2.2131 0.99

0.5 0.5 48.2 305.43 25 0.51867 1.38178 0.93

Del grafico
n =

+0.5 (30.07012

Ahora para una hora:
n =

= 43.37157622 mol.lb

V =

V =
(

)



V = 462.1482504

5)
m = 300

T = 515F <> 975R <>541.48333K

20 mol

100 mol


P = 600 psia <> 40.8276 atm <> 50 atm
D =2 in

44.09562

58.1222

72.24876

COMPUESTO

0.1 10 42.01 369.9 4.08276 0.0971854 1.4638641 0.99

0.2 20 37.47 425.2 8.16552 0.2179215 1.2734791 0.98

0.7 70 33.31 469.8 28.57932 0.8579215 1.152582605 0.74

V =

+0.7 (72.24878

66.538148

n =

=4.508691766mol.lb

V =

V = 63.92266706

6)



P = 600 atm
T = 77F = 537R
V = 200

% =15 %
n =

= 3
n = 3 mol.lb + 1 mol.lb + 4 mol.lb

Componente n (mol)

P (atm)

3 0.75 12.8 33.3 25 46.875 8.95345 1.47

1 0.25 33.5 126.2 25 17.91044 2.36251 1.34

600
600

n =

n =
(

)
(

)

n = 214.8822422 mol.lb
Salida tomando disociacin del 13 % con respecto al

t = 0 s 1 3 O
t = T 1 0.15 3 0.15(3) 2(0.15)

Componente n

2.55 0.689 550 12.8 449.8166 33.3 13.5080 1.34

0.85 0.229 550 33.5 449.8166 126.2 3.5643 1.24

0.3 0.081 550 111.3 449.8166 405.5 1.10928 0.67

Ley de amagat modificada:
V =

n =

n =

n =

n = 196.916074 mol.lb

0.689 (1.34) + 0.229(1.24) + 0.081(0.67)

Reemplazando en la ley de amagat modificado:
V =

V = 267.1449575

A =

)
A = 0.02181647

En 1 hora:
Velocidad =

Velocidad =

Velocidad = 12245.10124

(


)
Velocidad = 3.40141701

7)

= 85 % mol P = 600 psia =40.82743604 atm

5% mol T = 60 F = 288.56 K

10 % mol

V =

Componente n

(P)

85 0.85 34.7033 45.8 190.7

0.75772 1.51316 0.75 0.8075

5 0.05 2.04137 48.2 305.43 0.6773 0.944716 0.94 0.044

10 0.10 4.08274 33.5 120.2 0.121017 0.24652 0.72 0.372

P = 1 atm
V =

T = 60 F < > 520 R
n =



n =

n = 2633.52221

V =

V =

V = 23183.02624

(


)
V = 6.439729

Entonces hallando la velocidad
Velocidad =

A = 1 ft
R = 0.5 ft
Velocidad =

Velocidad = 8.1993182