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Take two sealed glass bulbs A and B filled with the same
sample of NO vapours. At room temperature both the
bulbs have a light reddish-brown colour. Place the bulb A
in ice(0oC) and B in boiling water(100oC).
The bulb A (which is placed in ice) is colorless due to the
formation of N2O4, while the bulb B (which is placed in
boiling water) has become deep reddish brown due to
the formation of NO2.
Now shift both the bulbs to a trough containing ordinary
water at the room temperature. After sometime, the gas
in both A and B becomes equally brown , i.e. ,deeper
than that at 0o C, and lighter than that at 100oC.This
shows that , the chemical equilibrium,
can be attained from either end of the chemical reaction.
DISTURBANCE IN EQUILIBRIUM