9 Cng ngh sn xut MTBE

Dng nguyn liu i-Butane c nhit 500 oC, p sut 150kPa, lu lng
mole 100kgmole/h i vo thit b phn ng thc hin phn ng Dehydro ha
vi s c mt ca hi nc, dng hi nc i vo thit b phn ng c nhit
500oC, p sut 150kPa, lu lng mole 300kgmole/h. Phn ng xy ra ti nhit
500oC, 150kPa. Hn hp sau phn ng c a qua Component Splitter tch
i-Butane v H2, p sut nh 150kPa, nhit 500oC. Dng i-Butene tinh khit
c nng p ln 1500kPa, ri lm lnh n 85 oC v i vo a 11 ca thit b
chng-phn ng. Dng Metanol c nhit 85oC, p sut 1500kPa, lu lng
100kgmole/h c a vo a 9. Thp chng-phn ng c p sut nh 1490kPa,
p sut y 1510kPa, gm 25 a, phn ng xy ra t a th 8 ti a th 16.
i-Butene + CH3OH

MTBE

- Thc hin m phng qu trnh trn, yu cu hn hp MTBE thu c c

khng t hn 29% MTBE, i-Butene khng qu 7%, dng nh ca thp
chng khng cn MTBE
- Thc hin tun hon li lng i-Butene thu c ti nh thp chng tng
hiu sut, ng thi thc hin tun hon li i-Butane cha phn ng
- Kho st s nh hng ca dng H2O i vo thit b phn ng Dehydro ha
i vi thnh phn ca MTBE trong hn hp thu c di y thp chng
- Tm lu lng ca dng H2O vo thit b Dehydro ha sao cho thnh phn
i-Butene trong hn hp dng sn phm yca thp chng l 0.017
- Tm lu lng H2O thnh phn mole ca MTBE trong hn hp sn phm
y thp chng ln nht.
S dng FP UNIQUAC