Escolar Documentos
Profissional Documentos
Cultura Documentos
ST 04
Test of acidity of alkyne-1 is done by using(a) Ammoniacal silver Nitrate (b) Silver Nitrate solution
(c) Fehling solution (d) Barium Nitrate solution
2. Ozonolysis reaction is given by (i) Ethene
(ii) Ethyne
(iii) Benzene; which one is correct?
(a) i + ii
(b) i, ii, iii
(c) ii, iii
(d) iii
3. Which one of the following compound can be prepared from Phenol(i) Benzene
(ii) Picric acid (iii) salicylic acid, which one is correct?
(a) i,ii
(b) i, ii, iii
(c) ii, iii
(d) iii
4. Which one gives nucleophillic reaction with carboyl group(i) HCN
(ii) RMgX
(iii) NH2NH2 ; which one is correct?
(a) i,ii
(b) i, ii, iii
(c) ii, iii
(d) iii
5. Which one is more basic?
(a) Ammonia
(b) Methyl amine (c) Dimethyl amine (d) Aniline
6. Alcohol reacts with carboxylic acid to give(a) Ester
(b) Alcohol
(c) Alkene
(d) Ether
7. Nitration of aniline gives-(a) para (b) meta (c) ortho (d) ortho- para product
8. Ozonolysis of alkene gives- (i) aldehyde
(ii) ketone
(iii) organic acid
which one is correct? (a) i,ii (b) i, ii, iii
(c) ii, iii
(d) iii
9. Reagent that is used in the distinguishing test between alcohol and phenol is(i) Tollens reagent (ii) Ferric Chloride solution (iii) Bromine solution
which one is correct? (a) i,ii (b) i, ii, iii
(c) ii, iii
(d) iii
10. Which one is known as paraffin? (a) Alkyne (b) Alkene (c) Alcohol (d) Alkane
11. Which one is slightly acidic?(a) Butyne-1 (b) Butyne-2 (c) Butene-2 (d) Butane
12. Ozonolysis of propene gives(a) ethanal
(b) Methanal
(c) Ethanal & methanal
(d) propanone
13. Oxidation of methyl benzene with dilute nitric acid gives(a) Toluene
(b) Benzaldehyde
(c) Benzoic acid
(d) Benzene
0
14. 3 amine is -(a)NH(CH3)2(b) ethylamine (c) C6H5N(CH)2 (d) N-methyl aniline
15. Hoffmann degradation reaction of propanamide gives(a) Ethanol
(b) Propanol
(c) Propylamine
(d) Ethyl amine
Methyl amine + Chloroform + Caustic soda = ?(X) + KCl+ water
16. X = ?
(a) Methanol (b) Methyl iso cyanide (c) Methyl cyanide (d) chloromethyl amine
17. If X is reduced by LiAlH4 then it gives(a) dimethyl amine (b) ethyl amine (c) ethanol
(d) methyl amine
*
RCH = CH2 + HX A
18. Formula of A is - (a) RCHXCH2 (b) RCH2CH2X (c) RCHXCH3 (d) RCH2 CHX2
ST 04
ST 04
39| - glycosidic bond is present in- (i) Cellulose (ii) Amylose (iii) Amylo pectene
; which one is correct? K) i
(L) i I ii
(M) ii I iii
N) i, ii I iii
40| Nucleophillic addition reaction is given by
(K) >CO
(L) -OH (M) -COOH (N) -COOR
41| Monomer of PVC is
(K) Propelene (L) Chloroethene
(M) Vinyl acetate
(N) Protein nitrile
42| If nitrobenzene is heated with Sn and Conc. HCl, then the product will be
(i) Heavier than water (ii) Brown coloured oil (iii) Less basic than ammonia
Which one is correct? (K) i
(L) ii I iii
(M) i I iii
N) i, ii I iii
43| Which one is used in bromine water test?
(K) Benzene
(L) Hexane (M) Toluene (N) Carbon tetrachloride
44| What happens if calcium ethanoate is heated?
(K) HCHO
(L) Ethanal (M) Acetone (N) Ethanoic acid
45| Lucas reagent is
(K) SnCl2 + HCl
(L) AlCl3 + HCl (M) PCl3 + HCl(N) ZnCl2 + HCl
+
2+
46. MnO4 + 8H +? = Mn + 4H2O- a) 3e b) 5e c) 6e d) 7e
47. Electrolysis process is applicable-i) Extraction of metals ii) Electroplating iii)
commercial preparation of I2; which one is correct? A) I b) ii,iii c) I,ii d) I,iii
48. Which one of the following apparatus will reduce LJP?a) pH meter b) Galvanometer
c) Voltmeter d) Salt bridge
49. Aldehyde is detected by- i. Fehling solution
C3 H 7COOC2 H5
b)
CH 3COOC8 H17
c)
C3 H 7COOC4 H9
ST 04
CH 3COOC5 H11
58. Which one is more basic? A) Ammonia b) Methyl amine c) Phenyl amine d)
dimethylamine
59. CH3CH(OH)CH2CH3 and CH3CH2CH2CH2OH are- isomer of each other.
A)Chain b)Position c) Optical d) Geometric
60. Carbanion is i. Electron deficient ii. Formed by heterolytic fission iii.stabilizes
with increase in alkyl group; which one is correct? a) I b) ii c) ii and I d ) I,ii and iii
61.Which one gives immediate white ppt with lucas reagent - i) Primary alcohol ii)
Ethanol iii) tertiary butylalcohol;which one is correct? a) I b) ii c) I,ii d) I,iii
62. Which one is used in refrigerator? A) CFC b) Methanol
c) Rectified spirit d)
Picric acid
63. Dimethyl benzene is known as- A) TNT b) Xylene c) Westracol d) Picric acid
64.Griegnard reagent react with methanol to give- i. 10alcohol ii. 20 alcohol iii. 30
alcohol; which one is correct?
(a) i
(b) ii
(c) i and ii
(b) HCOOH
(c) CH4
66| What number of mole present in 100mL 0.1M? (K) 0.1 (L) 0.01(M) 0.001(N) 0.001
67| What amount of Cu will be deposited if 5mA electricity is passed through copper
sulphate solution for about 10 minutes?
(K) 4.910-4gm
(L) 9.810-4gm (M) 9.810-7gm
(N) 4.910-12gm
68| If a cell is constructed by using
0
Zn / Zn 2 ( EOx
0.76V ) and Ag / Ag E o OX 0.80v then
i.At anode: Zn = Zn2+ + 2e
ii. At cathode: 2Ag = 2Ag+ + 2e
iii. Zn2+ can be kept in Ag container; which one is correct?
(K) i (L) ii (M) i I iii (N) i, ii I iii
69| Standard electrode potential for hydrogen electrode is
(K) 0.0v (L) 1.1 v(M) 1.5 v(N) 6-10 v
70| Vander waals equation for 1 mole of gas is
(K) P
a
v b RT
v2
(L) P
0.12 a
v 0.2b 2 RT
v2
(M) P
0.01
v 0.016 RT
v2
ST 04
0.01
v 0.1b 0.0 RT
v2
(N) P
71| Absolute temperature is (K) 250C (L) 00C (M) -2730C (N) -2980C
72| Primary standard substance is (K) H2SO4 (L) HCl (M) Na2CO3 (N) NaOH
73| 1F = ?
(K) 9650C
(L) 96500C
(M) 965000C (N) 9650000C
74| Oxidation number of the central element of sodium tetrathionate is
(K) 2.0 (L) 2.5
(M) 3.0 (N) 3.5
75| pH of 0.05M is (K) 0 (L) 1 (M) 2 (N) 4
76. Tendency of metal to enter into solution is known as
K. Solution pressure
L. Osmotic pressure
M. Diffusion
N. Effusion
L. CH3COOH
M. NH4OH
N. HCOOH
L. 2F M. 3F
N. 4F
79. What will be the emf of the cell composed of Zn and Ag? [ Zn/Zn2+=+0.76v and Ag /
Ag+ = -0.799v]- K. 1.955 L. 1.595 M. 1.559
N. 1.506
80. The electrode where oxidation takes place is known asa) Anode b) Cathode c) Ameter d) Salt bridge
81. Electrolysis of brine gives..... at cathode? a) Na b) H c) Cl d) O
82. Which one is known as calomel? K. NaCl
L. KCl
M. Hg2Cl2 N. ZnCl2
83.Electrochemical equivalent of Cu is
a) 0.000329 b) 0.000218 c) 0.000118 d) 0.000108
84. The amount of current required to give 4g Ni coating over the iron spoon is
K. 12152C
L. 13152C
M. 13552C N.13652C
85.Represent the cell where the following reaction takes place: Zn + H2SO4 = ZnSO4 + H2K. Pt,H2/H2SO4 | | ZnSO4/ Zn
M. H2/H2SO4 | | ZnSO4/ Zn
86.Unit of current is K. Volt
ST 04
88.If E0Cu2+/Cu=0.34V and E0Mg2+/Mg=-2.3V then- i) emf is 0.57V , ii) MgSO4 can be kept
in Cu container iii) MgSO4 cannot be kept in Cu container ; which one is correct ?
K. i
L. ii
M. iii
N. i,iii
89.Standard electrode potential for hydrogen electrode is - K. 0.0v
L.
0.334V
M. 0.76V
N. 0.798V
d) Ni/Ni++
92.Salt bridge is used- i) to complete the circuit connection ii) to reduce LJP iii) to make
the circuit electrically neutral ; which one is correct? a) i b) ii c) iii d) i,ii,iii
L. 1.1 M. 1.5
N. 2.0v
94. Which one of the following gas will diffuse fast? a. Cl2
b. N2
c. CO2 d. SO2
95. How many atoms are in 4.0 grams of Al? a) 8.9 x 1017 b)8.9 x 1022 c) 9.9 x 1023
d) 11.9 x 1023
96. RMS velocity of O2 at 00C is a) 356.4 b)461.3
97. A sealed vessel contains 0.200 mol of oxygen gas, 0.100 mol of nitrogen gas, and
0.200 mol of argon gas. The total pressure of the gas mixture is 5.00 atm. The partial
pressure of the argon is
(a) 0.200 atm (b) 0.500 atm (c) 1.00 atm (d) 2.00 atm
98. Secondary standard substance is- a) Oxalic acid b) Potassium dichromate
c)
Potassium paramagnetic d) Sodium carbonate
99. What is the mass of one hydrogen atom? a) 1.67 x 10-24g b) 1.67 x 10-27g c) 3.67 x 1024
g d) 4.67 x 10-27g
100. Conjugate base of HSO4- is- a) H2SO4 b) SO42- c) H3O+ d) SO4101. What amount of 0.3M NaOH will be required to neutralize 30mL0.3M H2SO4
solution? A) 15 b) 30 c) 60 d) 90
102. pH of 0.01M NaOH is- a) 2 b)8
c) 12 d) 14
103. What amount of lime will be produced if 10g CaCO3 is heated? A) 4.0 b) 5.6 c) 10
d) 15
104. Which one is oxidant? A) H2S b) KMnO4 c) Na d) C
105. What will be deposited at cathode is brine is electrolysed? A)Na b) Cl c) H d) K
ST 04
106. Which one of the following metal cannot displace hydrogen of HCl? A) Zn b) Ca c)
Au d) K
107. Iodometry is the process of determination of the concentration of a) Cl b) Br c) I
d) S
108. What amount of electricity is required to get 500mL hydrogen gas at STP if H2SO4
is electrolysed ? a) 4308c b) 9650c c) 96500c d) 2x96500c
109. Which one is known as primary reference electrode? A)Hydrogen b) Calomel c)
Glass d) Metal-metal ion electrode
110. What amount of KMNO4 is required to oxide 152 gm FeSO4? A) 106 b) 144 c) 158
d) 162
111.If the EMF of a cell is positive then i) the process is spontaneous ii) cathode will
decay iii) cell reaction is possible; which one is correct? A) I b) ii c) iii and I d) ii and i
112. Reduction is-i) Removal of hydrogen ii) Removal of oxygen iii) addition of
electropositive species; which one is correct? a) I b) ii c) ii and iii d) I and ii
113. During the electrorefining of blister copper, anode compartment is a) Blister copper
b) pure copper c) spelter d) Iron
114. Anode of a dry cell is made of a)C b) Zn c) Cu d) Sn
115. MnO4- + 8H+ +? = Mn2+ + 4H2O- a) 3e b) 5e c) 6e d) 7e
116.Electrolysis process is applicable-i) Extraction of metals ii) Electroplating iii)
commercial preparation of I2; which one is correct? A) I b) ii,iii c) I,ii d) I,iii
117. Which one of the following apparatus will reduce LJP?a) pH meter b) Galvanometer
c) Voltmeter d) Salt bridge
118. If the standard oxidation potential of Fe and Ag are +0.44V and -0.79V respectively
then the emf of this cell will be-a) 0.35 b) 1.1 c) 1.23 d) 1.50v
119.Hydrolysis of ester in acid medium is order reaction? A) First b) Second
c) Zero d) Pseaudo order
120. Which one of the following compound has the oxidation number of S as +2?
a) S b)H2S c)SO2 d) Na2S2O3
121. In electrolytic cell, anode is a)Positive b) Negative c) Neutral
d) reducing chamber
122. Oxidation number of Fe in K4 [Fe(CN)6] is- a) 0 b) 2 c) +2 d) +3
123. NH2-CO-NH2 is- a) aldehyde b) Amine c) Amide d) Acid
124. Chemical constituent present in vinegar isa) HCOOH
b) Ethanol
c) Benzoic acid d) Ethanoic acid
125. CH3CON(CH3)2 is known asa) 2.2 dimethylethanamide
b) N,N dimethylethanamide
b) Methylketone
d) Methylethanamide
126. HCOOH reacts withi) NaHCO3
ii) Fehling solution
iii) Tollens reagent
Which one is correct?
a) ii
b) i+iii c) ii+iii d) i, ii, iii
ST 04
ST 04
ST 04
d) Acid Halide
c) Methyl amine
d) Sodium amide
b) ii
c) iii
d) I,ii
d)Surf
c) H2O d) SO3
171.
ST 04
d) Nucleophillic substitution
b) CH3CH2CH2CH2OH
c) CH3CH2CH=CH2
d) CH3CH=CHCH3
180. Benzene has- i. m.p. 5.40C ii. acidic iii. can be synthesized from medium oil ;
which one is correct ? a) I
b) ii
c) iii
d) I, iii
d) Methylethanamide
b) C6H5CH = CH CO2H
c) (CH3)2 C = C (CH3)2
d) CH3 C C CH3