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Aim
Observe the enthalpy of reaction between NaOH
solid and HCl solution with two ways.
APPRATUS /CHEMICALS
Apparatus:
Materials:
NaOH solid
Hydrochloric acid 1 M
NaOH Solution 1 M
Hydrochloric acid 0.5 M
Experiment 1
NaOH(s) + H2O(l)
NaOH
2g
50 cm3
Twater
T end
= 26
= 33
oC
oC
(aq)
NaOH(aq) +
50 cm31M
TNaOH
T HCl
T initial
T end
T end
=
=
=
=
=
27 oC
27oC
27oC
29oC
30oC
NaOH(S) +
2g
T HCl
Tend
HCl
(aq)
NaCl(aq) + H2O(l)
= 27 oC
= 38 oC
Experiment 1
Q = m . c . t
= 50 g . 4,2 j.g-1.oC-1 . 7oC
= 1442 joule
Mole NaOH = 2/ 40 = 0,05
H1 per mole
= -28840 j
= -28,84 kJ
Experiment 2
Q = m . c . t
= 100 g . 4,2 j.g-1.oC-1 . 2oC
= 840 joule
Mole NaOH = 2/ 40 = 0,05
Mole HCl = 50 ml . 0,5 M = 0,025
H2 per mole
= -33600 j
= -33,600 kJ
Experiment 3
Q = m . c . t
= 100 g . 4,2 j.g-1.oC-1 . 9oC
= 3780 joule
Mole NaOH = 2/ 40 = 0,05
Mole HCl = 100 ml . 0,5 M = 0,0 5
H3 per mole
= -75600 j
= -75,600 kJ
1.
NaOH(aq) + 1/2HCl
(aq)
(aq)
NaCl(aq) + H2O(l)
Observation
Measure ( cylinder , balance)
Use balance
Inteprating
Reading thermometer
Accuraty
Honesty
Responsibility
Basic Competence :
2.2. Determining H of reaction based on
experiment, Hess law, standard enthalpy
change of formation and bond energies
data