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Group 1 (Insoluble Chlorides)
- Ag+, Pb2+ and Hg22+
Precipitating Reagent: HCl
Ag+:
Remarks:
1. Forms an insoluble precipitate AgCl upon the addition
of HCl
2. Insoluble in hot water
Confirmatory Test:
Ag+ + 2NH3 Ag(NH3)2+
Note: AgCl forms again upon the addition of HNO3
Pb2+:
Remarks:
1. Soluble in hot water
Confirmatory Test:
Pb2+ + CrO42- PbCrO4 (yellow precipitate)
Pb2+ + SO42- PbSO4
Confirmatory Test:
*same with that in Group I
Chem18.1
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Cd2+:
Remarks:
1. Cd2+forms a sulfide which is the only yellow sulfide,
CdS
OR
Al3+:
Remarks:
1. It forms an insoluble hydroxide, Al(OH)3 which is a
white precipitate
Confirmatory Test:
Dissolve CdS in acid then add thioacetamide OR H2S
Cd2+ + S2- CdS (yellow precipitate)
Cu2+:
Remarks:
1. Cu2+ can be identified by its distinctly BLUE colored
solutions
Confirmatory Test:
Al(OH)3 + HNO3 + Aluminon (dye) Red Lake
Confirmatory Test:
Cu2+ + 4NH3 Cu(NH3)42+ (blue complex in expt 3)
Cr3+:
Remarks:
1. Forms an insoluble hydroxide, Cr(OH)3 which is green
in color
Confirmatory Test:
Cr(OH)3 + H2O2 + NaOH CrO42- (yellow)
Chem18.1
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Confirmatory Test:
Fe3+ + SCN- Fe(SCN)2+ (blood red solution)
Zn2+:
Remarks:
1. Forms the only white colored sulfide, ZnS
Confirmatory Test:
3Zn2+ + 2K+ + 2[Fe(CN)6]4- K2Zn3[Fe(CN)6]2(white
precipitate)
Mn2+:
Remarks:
1. Solutions of this ion are pinkish in color
2. Forms a peach colored precipitate, MnS
Confirmatory Test:
Mn2+ + NaBiO3 (crystals) MnO4- (purple)
Note: The formation of purple
permanganate is quickly disappears
Chem18.1
solution
due
to
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Co2+:
Remarks:
1. Solutions of this ion are rose colored/dark pink
Ba2+:
Remarks:
1. Forms a white precipitate BaCO3
Confirmatory Test:
Co2+ + KNO2 (crystals) K3Co(NO2)6 (yellow precipitate)
Confirmatory Test:
Ni2+:
Remarks:
1. Solutions of this ion are green in color.
2. Forms a black sulfide, NiS
Confirmatory Test:
C4H8N2O2 (Dimethylglyoxime) + Ni2+ Ni(C4H8N2O2)2
(red precipitate)
Ba2+ + SO42- BaSO4 (white precipitate)
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Mg2+:
Confirmatory Test:
Mg2+ + HPO42- + NH3 MgNH4PO4 (white precipitate)
Flame Test: White-colored flame
Ca2+:
Remarks:
1. Forms a white precipitate, CaCO3
Confirmatory Test:
Ca2++ C2O42- (oxalate) CaC2O4 (white precipitate)
Group V (Alkali Metal Ions)
- Na+, K+, NH4+
Precipitating Reagent: NONE
Na+:
Flame Test: Yellow-colored flame
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K+:
Flame Test: Lilac/Purple-colored flame
NH4+:
Remarks:
1. Turns red litmus paper into blue due to the presence
of NH3
Confirmatory Test:
NH4+ + OH- NH3 (gas) + H2O
Solubility in H2O:
Nitrates and Acetates all are soluble
Sulfates all are soluble except Pb2+, Ba2+, Sr2+, Ca2+
Carbonates, Oxalates, Phosphates all insoluble except
Na+, K+ and NH4+
Sulfides, Oxides, and Hydroxides all insoluble except
Na+, K+, NH4+, Ba2+, Ca2+, Sr2+
Metal ions that dissolve in excess NaOH due to
complex formation:
Al(OH)3 Al(OH)4Cr(OH)3 Cr(OH)4Pb(OH)2 Pb(OH)4Zn(OH)2 Zn(OH)4Sn(OH)4 Sn(OH)62Metal ions that dissolve in excess NH3 due to complex
formation:
Ni(NH3)62+ (violet)
Cu(NH3)42+ (blue)
Zn(NH3)62+ (colorless)
Ag(NH3)2+ (colorless)
Cd(NH3)42+ (colorless)
Anions
Anions that react with H2SO4 or HNO3:
Anion
Product
Visible Result
2S
H2S (g)
Rotten egg smell
S2O32Sulfur (s)
Colloidal sulfur
SO32SO2 (g)
Respiratory irritant
CO32CO2 (g)
Effervescence
NO3NO2 (g)
Brown gas
CH3COOCH3COOH
Acetic acid smell
CrO42Cr2O72Orange solution
Flame Test:
Na: yellow
K: purple
Ca: brick red
Sr: crimson red
Ba: green
Cu: bluish-green
Chem18.1
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2. CrO42Reagent: HNO3/H2SO4
CrO42- (yellow) + 2H+ Cr2O72- (orange) + H2O
6. S2Reagent: HNO3/H2SO4
S2- + 2H+ H2S (g) (rotten egg smell)
3. SO42-
Reagent: Pb(OAc)2
Pb2+ + S2- PbS (black ppt)
Reagent: BaCl2
Ba2+ + SO42- BaSO4 (white precipitate)
4. SO32-
7. S2O32-
Reagent: HNO3/H2SO4
5. CO32Reagent: HNO3/H2SO4
CO32- + 2H+ CO2 (g) (effervescence) + 2H2O
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9. NO3-
12. Br-
Reagent: Ethanol
CH3CH2OH + CH3COOH CH3COOCH2CH3 + H2O
Reagent: AgNO3
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Chem18.1
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