_-48132E - Separation Process tutorial #1 D1L# We are separating a misture of methanol and water ina flash drum at 1 aum pressure. Equilibrium daa ave listed in Table 2-7. a. Feed is 60 mol% methanol, and 40% ofthe feed is vaporized. What ate the vapor and liquid ‘mole fractions and flow rates? Feed rate is 100 kamol/h. Repeat parta fora fed rte of 1500 kmol/h. (DAE rd wre. wrt eae values) “0 6 Ife feed i 30 01% methanol and we desire a Higuid prodvct thats 20 mol% methanol, what ‘IF mast be used? Fora feed rate of 1000 Ibmo/h find product low rates and compositions 44 We are operating the flash drumso that he liquid mole fractions 45 mol% methana. vol ae V/F = 0.2. What must the flow rate and composiion of te feed be? 3 ¢. Find the dimensions of vertical ash drum for Problem 2.D1c Data: py = 1.00 fem? Py, = 0.7914 gem, MW, = 18.01, MW, dea Womno\ flay, LE AS Nemes }ine ideal gas. Yave yaet ) £.1E2= 04, p= 1 atm, and Tyg) = 77°C find VIF, Xe ad Yn IPF =50 mol/h, = 0.8, p= 1 atm, and yp, 0.892 mole fraction methanol, find V,L, andy ‘Table 2-7. Vapor liquid equilibrium data for methanol water (p= 1 atm) (mol%) Fraction feed vapouriced, Ww bevy soy nw Reval voy YU vee Oe wawange 0:4 Soups yoy eg oan gape mtn net sso LemetiVg ome gate mata etd at? eens fete vay Lue ons “Wr 4 ye sers Cea gop) evel, ©) Fog svt -O Ne yee Ypnuy Nuon Diag aeoa Wenn, 0594 " salen -O toe forvEL ye tha, L= ase WW) X05 eevarsoo -@) EOF 500 oBF = "00 Fs tty Vad saa Re Loating we) [sete Son Angi, 5 EG ean) 15% oy ra ative ae “EA sa tie 1a 37 wa = 1500 m9 a7 a = 22.04 Assure vaporsare ms mi (2) ang ha, saeenar wi, Tad, = anehOlin # MN = 22 00) O ELE OY Speenkic val 8 if, Mtoe vos tment ta 02 gle Was eg satin na( BB Jee (f2) = aside wa fee es BE sets gi : re MN = ay MNay ov Yap rpleewlay WL, " wnedg = Hanya ov Mae © O5RCSE08) FD ARLAT On) = 26 154 xt yey fate « a3h-Fk (Crow taioe) py = (amy (ton) (Fr) GF) Vagey fiw why = Ye May = Gb) Oe Lywa few Nas Lo MNE* (36) 202) v vwapawr deity = B-4pe iy glint AOy Veans-hh toe Se FE, ti, RRC vas wy V7.” Whore wary NT hvvin = ony [A + Fay 9 € (hv Soy)40 (Ba Fes)? eltat)” 3 Beals wane (bap Wye = Kjyyua (ticle = 2 tat nar) we gis = Ln) eat) ay = ot : Term 3400p) CHTENCSGOOEAEND®) tv slaty ate a ae, Ao ale we wos 12 v2 ea lope VEL = tape ong e034 -O Leng a ve it? () rom giagn , Xn 0750 so= tay — © 5008) = Leet) FY Ce am)-© Ve tle Le spn tele e BADCN3132E - Separation Process tutorial #2 D6. We have mixture that is 35 mol% n-butane with unknown amounts of propane and n- hexane. We are able to operate a flash drum at 400 kPa and 70°C the mole fraction of n-hexane in the feed, z,,, and the value of W/E. D9.* We wish to flash distill an ethanol-water mixture that is 30 wt % ethanol and has a feed flow of 1000 kg/h. Feed is at 200°C. The flash drum operates at a pressure of 1 kg/cm’. Find: Tyne WC frac of liquid and vapor products, and liquid and vapor flow rates. Data G, 76 at HOE C: kal (kooC) Muka hme Ch Meme 2788 1 DOM LOT 7 OT N86 OAD WT O4853 « 1T ¢ Both C,,.salues are in healifkinod C), with Tan’ € Bhan = 8789 BML. Py, MW oy, = 4007, MW = ISI16, Fy gy) = 922 Kealmol at 351.7 K, and jy = 97071 keal mol at 373.16 K Enthalpy composition di units p = 1 kplem” isin Figure 2-4 Note: Be careful with that is 25 mol% benzene and 75 mol% toluene is flashed. Feed is 200 he liquid product is 15 mol% benzene. ‘The constant relative volatility is = ‘and L. Do this problem analytically, not graphically. D14. We are feeding 100 kmol/h of a mixture that is 30 mol% n-butane and 70 mol% n-hexane to a flash drum. We operate with V/F = 0.4 and Tyjyym = 100°C. Use Raoult’s law to estimate K values from vapor pressures. Use Antoine’s equation to calculate vapor pressure, B log, (VP) = A= To where VP is in mm Hgand Tis in °C, n-butane: A = 6.809, B = 935.86, C = 238.73 n-hexane: A = 6.876, B= 1171.17, C = 224.41 Find Perum» Xi and yj 122. A flash drum is separating a feed that is 50 wt % n-propanol and 50 wt % isopropanol with F=100 kmol/h. Typum = 90°C and Pgrum = 101.3 kPa. Use the Rachford-Rice equation to find V/F. Note: This does not have to be tial and error. Then find y and x. Determine K values from Raoult’s law using Antoine equation for vapor pressure. Watch your units. The Antoine constants are (Dean, 1985): n-propanol: A = 7.84767, B = 1499.2, C = 204.64 isopropanol: A = 8.11778, B = 1580.9, C = 219.61 where the form of the Antoine equation is VP ins nomn Hand Tin °C log, (Vph= A= J Om 4.14ON BIHTE tut 2 ktpdvation vroress, ou. v Trot WPrinety cmavy COAGES2), 500 We gowe Avis wy Mal hevvoy - boy Keine 25 LO aes MOT nptagany = Oe eps HT who $ Kuemopant © 023 Baws 055 ha Cyt é sho qs: oer Ey ce feo ne a? ay eH oss a ve torsni) 055 Wet Wonayir > Pe oag oud aa peat Tome ” Trop eo = gt) > 095 oq . Ve¥5(9) movaie) tito) {8 20> go)>0 canimMe Ve won dew Poo 435. ge) Hosen , winsare we aiove Wtf wang Nemiows mad, a ona Quis of Fert hans o3tb) it o-noyet (aap Trews Cerny x 2 3 4 Sahat watt Te towne ae fae) 9 Vero obaN es ak WFO) Kernan = 21 save * 25 (0 ObbL ve eae(P5-1) te a a ) = 0-0bW7 + Yorperrat = So Ynqentane = Pb (0-3534) ca (oauet ) ~ 63094 = 03534 Peeper Oe Y nom prone © 0-25(0-5804) Ve OPN (on = O2b > obEOY Teteo ¥ Buje toe ¥n0 te Lostowa veutvt votaniny K=2 tt ager Wt, easier to zepavate ) droop Se) Heea wate ope ano kml XyeDy, 085 ye os t e obs yo BY Yo ousas(efy) Serna, py eton wor trv —O aop(ors) = Lcois)+ Viesae) — @) Le ow. 2lz qmorfe, VE 135 ones) ore wy ating, ek nays WAGE PED “#2? om e goo”) “Ao Gat sre WwelMee vet TEs Migs Tavs 100%, WA)e = iat wh woh Walt), bere = OE _ Hesse = [va 2 1BYY.3 62 yam kes MEL fy e MbRbD eee eee oe ° CURR ayy "ann Xye ee eit Te CEE a tre oak wp ny PeR KHAO ATT TERT ISTP OR COR AFR F) y OAR LOREM AT, peawyes 1a3-W - eeTsA #0 vy Yeon ut) Pe arwl dwt 2 Ny = 013) Kye OHt kX : " Yer keke t WeMHIE2 (ota) i lee = 044 20-521 Kanne law evades Ka = OVPDa/P oat Tape Le oy ttt oe stung tf) (O-GP +4 3F. +)Ndvava = 40% on Taos = 101-3 eta & AO mth 7 1 wepropano| a 21> ito propawal 1 (y 2s 944.2 ~~" tage WP.) «saver - “Go + 208.64 er or VO, = bg wend logs (VPL) = Barna ~ Bos 1 Mae Ve = 1003 summit a Kit 4% SANE nase me Fko es ONE asp Coe Hea a SOEETIS 8 rereys °s 4“ Tone wits het aaa *! Oa OINg a OF carag s )voabep-eaUNhe coryag? SPBBA EP cosy Pad fe ouag wy 0 tue) Sys OG4) | X= oO Ko a 2% 95b (0-541) > 1-352 (404) Soar 055%18 PRESSURE , Keo Figure 2-12. Modified DePriester char at high temperatures (D. B. Dadyburjor, Chem. Eng, Prog {85, April 1978: copyright 1978, AICHE; reproduced by permission ofthe American Insite of Chemical Engineers) ‘compared to the charts i that it can be programmed into a computer or ealeulator. Equat= (2-30) can be simplified for all components except n-octane and n-decane (see Eq. (5352 ‘The K values are used along with the stoichiometric equations which state the mole f=: | tions in liquid and vapor phases must sum to 1.0. Y=10,F n=10 an ‘where C is the number of components. Bubble-point and dew-point calculations are = ‘cussed in detail in Section 5.4. 2 Chapter2. Flash Ditilsso=8 toi, Kei. "Boar $ =_ a aR 3 st i ! “rao fo ail ve Fioure 2-4. Enthalpy-compastion diagram for ethanol-water at a pressure of 1 kg/em? (Bosnjakovie, Technische Thermodynamk, I Steinkopff. Lelie, 1995) oso —a7 —aa —a5 once ion oP coe, wih Penton a ano ‘the same in all figures. In Figure 2-6a we can start at point A and draw a vertical line to point A’ (constant x value). At constant temperature, we can find the equilibrium vapor composi- tion (Point B’). Following the vertical line (constant y), we proceed to point B. The isotherm conneets points A and B. A similar procedure is used in Figure 2-6b, except now the y-x line ‘Saturated FIGURE 2-5. Use of auxiliary line » Chapter 2 Flash Distittion(CN3132E - Separation Process tutorial #3 4 continuous, steady-state distillation column with a total condenser and a partial reboiler is separating methanol from water at one atmosphere (see Table 2-7 for data). ‘The feed rate is 100 kmol/h. The feed is $5 mol% methanol and 45 mol% water. We Sesire a distillate product that is 9%) mol% methanol and a bottoms product that js 5 ol% methanol. Assume CMO. a If the external reflux ratio L/D = 1.25 plot the top operating line. . If the boilup ratio V’B = 2.0 plot the bottom operating © Step off stages starting at the bottom with the partial reboiler. Use the optimum feed stage. Report the optimum feed stage and the total number of stages. 4. Plot the feed line. Calculate its slope. Calculate q. What type of feed is this? We are separating methanol and water. Find the value of q and plot the feed line for the following. Data are in Table 2-7 and Problem 3.D8 a. Feed is 70 % methanol and flashes in the column with V/F = 0.27. b. Feed is 30% methanol and consists of liquid and vapor in equilibrium at a temper ature of 81.7°C. ¢. Feed is 40% methanol and is a liquid at -5°C, 4. Feed is 36.5% methanol and is # vapor at 110°C. €. Feed is 60% methanol and is a subcooled liquid. One mole of vapor must he ¢on- densed to heat 10 moles of feed to their boiling point. £. Peed iy 50% methanol and 60% is vaporized in a flush distillation system. ‘The products of the flash system are fed to a distillation column, Calculate the two q val- tucs and plot the 1wo feed fines. * a. We have a superheated vapor feed of 60 mol% more volatile component at 850°C. Feed flow rate is 1000 kmol/h, On the feed plate the temperature is 50°C. For this i mixture the average heat capacities are Cy, = 50 eal mol- °C), Cpa = 25 eal(mol- °C) while the latent heat of vaporization is % ~ $000 cal/mol. Plot the feed line for this feed. b. If. feed to a column is a two-phase feed that is 40 mol% vapor, find the vale of q and the slope of the feed line. ©. Ifthe feed to a column is a superheated vapor and | mole of liquid is vaporized co the feed plate to cool 5 moles of feed to a saturated vi is * \ 3 rapor, what What is the slope of the feed line? e es is separating a 20 mol% ethanol ~ 80% water feed. The feed rate ced is a saturated liquid. The column has a partial reboiler and a ‘a distillate mole fraction of x, , = 0.70 and a bottoms mole Assume CMO is valid. "ia the optimum feed plate location and the total number ofawrovial AS CN BBE eyo) V ye MEAMAMOY 7 2: Wattr Aoe*% a) Ipweeray koe Hs & = 055K T oF F= 100 xa) . MeDIAW Xp = 0.4 K intteycept = 04 tie sh WW) Ve=2-0 gs y Weert as 1g soqe: Es Vor Te" We ”* aa : Ls aside rss iL ar (Fe] V aque 0.05 : = HX - 85(005) ce) opmienann feud ae ie M0025 2 Brags avert he » ; ~ aw Xys005 LG yarns C6rd ; td) Feed Jin 100-55 Jarrad vewsiler tage t sees 4 Abe P| 4 = 0-55 4 Om wow 4, ie swe fracton ‘a Jiquid for fed =a youre. 3 figuid, vayer « ud ‘= K=2 = ta) Yip 024 action feed wtpoursed, #) fo ET het er oY Ta y aReoy ge oh. oe. = {rte dope = & 250 CW) Wacom ef trae . few ave 2g row" & x=020 saree 05 egy = DrAALOS 10h 2-294 Le 2-14 Sy ye ee sina, ce) Foe Ho), mernawol, fom we z, Wy He! FH. 3°C Stadia a sub cooled figuid « Jeweravel > ANTS 35:25 kg]ar @ bf - ge vy Se Cee-te) = 35270 J]m0) ant Jwuater = 4o-b56 Ka}me) = HooHL a} a3) 2 35.15°C Dyed = OHLELAE) GU ) = 1445 a] Wor °C « Z Yfead 2 otk (asnte 4 (4065) = 3760-4 ao} pwerwawol , = FB. Bo 1683 T 1.45 (453-65) “saya re weasGhy) ge tt il G38) = 1.125 = BVAB afuoire Coewattr = aw 4 J) woe henge owt = 4 aioyes « Wy:64 49 21000 xwor) : 4 « WA) age we yy AT = HT 25 (350-40) ce vapewneed) -Ce) F = Hy 3500 qe Eee nlp qe Ache . M3500 | -700 po pet rar a Beco * F ropes 7 ponte w) 4 a\eyes 4 yA 4o7. Vapor, bo) bg Lpagk = OOF slope = 4 Gad Xe Nain = wo of eiages @ tora) poh. Yefinn Xoe ay 00) Po)rn = Rin Cedrennd vifier aie Frint 1 ‘ OF ep (Sh) ain Gnteena vefiag 02) oo eee 13h Wie = OF u& VO Bp Woe = 034 = 1 Rw Ra 10} Ce) # Ye 2 Cl) win GR . rine toes we gleanwayed fig) & ° a pi Roe . it sow Rou waevcept 2 » Mh a e ~ Draw ROL A LOL suen find ay Vorty ea eqMiliorinm ay 4 gee ed 2 eye 4 0-388 INES pp Pprmuw ZA ioemt® => aleove PR Xe & en eg () A Ystt:toyara\td Jiqyid fred tad der ok . Vest <4) F = 10 waa We Kegs 0-05 _ Vesa 10> it Yox1 a ie \ Ax 001g 5 Whew cr xe 0th} ~ draw tL W coordinates, xg L (0-943,1) > i @ amevecetion of gor K Feed LineHowse find 22 7 Renna) Ais /0 fame vehwein Koon due red ne LOT) Uxfewaed se Yiteneers pons will Fal) Man” all ‘ha on aut cane ‘ ord eye Nop FS a > latCN3132E - Separation Process tutorial #44 - chapter 9 Di. D3.* We wish to use a distillation system with a still Hac uy ene YUU, A simple batch still (one equilibrium stage) is used to separate ethanol from water, ‘The feed to the still Potis 1.0 kmol of a mixture that is 30 mol% ethanol. The final con- centration in the still pot should be 10 mol% ethanol. The ethanol-water equilibrium data is in Table 2-1. Find: a. The final charge of material in the still pot, Wp, b. The amount of distillate collected, D,, © The average mole fraction of the distillate, Xo Hint: Use Simpson's rule. 3 —How +0 get values ” for 01, 0-2,0-37, ay rei aun en), Pot plus a column with one equilibrium Stage to batch distill a mixture of methanol and water. A total condenser is used. The {eed is $7 mol% methanol. We desire a final bottoms concentration of 15 mol% methanol. Pressure is 101.3 kPa. Reflux is a saturated liquid, and LYD is constant at 185. Find Wena Digi 84 Xp ar Methanol-water equilibriun data ore given in Table 2-7 Calculate on the basis of 1 kmol of feed D6. We have a simple bateh still separating 1,2 dichloroethane from 1,1,2 trichloroethane. D7. Pressure js 1 atm. The relative volatility for this system is very ck value of 2.4. The use of Eq. (9-13) is recommended, a. The charge (F) is 1.3 kmol. This feed is 60 mol% dichloroethane. We desire a final still pot concentration of 30 mol% dichloroethane. Find the final moles in the still Pot and the average mole fraction of the distillate product. b. Repeat part a if the feed charge is 3.5 kmol, c If the feed charge is 2.0 kmol, the feed is 60 mol% dichlorocthane, and we want a distillate with an average concentration of 75 mol% dicholoroethane, find the final kmoles in the still pot and the final mole fraction of dichloroethane in the still pot. We plan to batch distill a mixture of methanol and water in a batch distillation system at 1.0 atm pressure. The distillation system consists of a large stillpot that is an equilib- num contact, a distillation column that acts as one equilibrium contact (total 2 equilib- lose to constant at a rium contacts), and a total condenser. The feed to the system is F = 10 kmol and x, = 6.6 (mole fraction methanol). We operate with a constant reflux ratio of L/D = 2 until x, = 0.7. Then, we switch to operation with constant X= 0.7 as we increase L/D. ‘The batch operation is continued until L/D = 4.0. CMO is valid. Equilibrium data is in Table 2-7. a. Find X51 b. Find W,,,, and D ©. Find Xp ap ae ols Trial-and-error is not required. If you use Simpson's rule, divide area into two parts. total’ 2 Wwotovial ay — C9, Fe 2M * ; i \\ re 1 xnto} = No yt A 2 Final eam 3 worerial 3 ell pot, pee Xyge 0-8 And ers, wnt= Fogtefie Az) = nett Wa Z ce Real oe ie Wa tw po ™ x = aa TEE Lhe Fearn \ XOWNL ave rAd see aarty 48 3-940 diag AS ALA {es wt. nanos mT —_ \ 40904 (4.040) 4 Lay | + 0623y A) Neva) = eng [ 000s] + one! 7) F = Waves Dasta) Dal = 1 o-53e) = 04y34 “) Th= Wena Lan t Deotal Co, ay OY03) = losser}Cor) 7 © 4034) X> “4 Yoon 2 0-53" a> aby fam VLE dota: Wray RAD AAS. iy ( )- Ba dn ( Seen) ye In ( Reciaaauat) i XWwhvar ) (A) §=13 emo) Fimd Wipwa) eer 4 Yy ced MR) is KE) Ob (I= 0-3) 2. NUgina\ = 0-303 Karate Firw = Naan Xt Dasa Xo a (5)(o4) = 4054)(03) + (rete Xen) Fe Neéinay ae Doral & ome = Moke Doral = 3-0-3036 = 1-003 ) ay = 3.5 m0 Weal = 631725 , Xoravgs Coan Cab Be a etnny Xe kms ob Fe Xe, Nginay Morand = oO Vtmo = Ww Xv + Deora Xa Fue = WN fing Xe + FNewa) Xs.0u F wo - eat) = Nawal (ated) Now Xwo- Koay 2 EES Pon tart rere EC I= Xw) Is w (snes) «ay de (Sete, ‘6 (=A) Xw = oberg SONS 1212 molew Add Methanol - water x avoye 8) 0-35 2p Ye oN oO ag a cicebie a ae Ya = 0-248 A Ones st yor # Ome equiliorium ANAC 2 Mages WECAnse qn a 2(CN3132€ - Separation Process tutorial #5 - chapter 12 (Avsexytiew ewiyying) Ibe Acetone is being absorbed from air using water as the solvent. Operation is at 1 atm and | _8 sothermal at 20°C. The total low rate of entering ais 100 kmol/h. The entering gas { 12. mol% acetone. Pure water is used as solvent. The water flow rate is 150 kmol/h. We desire an outlet gas concentration of 1 mol%. The equilibrium data are: ze ‘Mole frac acetone in liquid, x mole frac acetone in gas, y : 0 oO § 0.0333 0.0395, 0.0720 0.0826 0.1170 o.i24 es é - tan ly KA 7 a. Find the mole ratio of acetone in the outlet liquid. 'b. Find the number of equilibrium stages required including a fractional number. Work in mole ratio units. r Acetone is being absorbed from air into water, The feed gas flow rate is 1000 kmol/h. and the acetone mole fraction in the feed gasis 0.01. The absorber has 3.2 equilibrium contacts. The entering water is pure and liquid flow rate is 2000 kmol/h. Operation is ot 20°C and 1.0 atm. Assume total vapor and liquid flow rates are constant. Equilib- rium, is y = 1.186x (y and x in mole fractions). Use the Kremser equation and find the outlet mole fraction acetone in the gas. | D8, 10.9 kmol/h of a concentrated aqueous solution of ammonia is to be process stripping column. The feed contains 0.90 ke moles of ammonia/hr and 10 Ki water/h. We desire an outlet water stream that is 0.010 mole frac NH,, The sry gas is pure air at a flow rate of 9 kmol/h. Operation is at 30°C and 745 ‘Assume the air is insoluble, the water is nonvolatile and the stripper is is air = 29. a. Find the number of equilibrium stages required including the fractional an b. Find the minimum air flow rate. Note: This should be analyzed as a concentrated NOT diJute system. | Note: Watch your units! This problem can be solved in mole ratios, weight ra (vith care) in mixed ratio units. D9, Problem 17.D3 satisfies the ox! D14._ In an ammonia plant we wish to absorb traces of argon and methane from: a nitrogen stream using liquid aramonia. Operation is at 253.2 K and 175 atra pressure, The feed flow rate of gas is 100 kmol/h. The gas contains 0.09024 mole frac argon and 0.0C129 mole frac methane, We desire to remove 95% of the methane. The entering liquid ammonia is pure. Oporate with L/V = 1.4(L/V},,, Assume the total gas and liquid rates ae constant, The equilibrium data at 253.2 K are: Methane: partial pressure methane atm = 3600 Argon: partial pressure argon atm Reference: lesandi (methane mole frac in liquid) 7700(argon mole frac in liquid) : al. ind. Eng. Chem. Process Di oy 72) a. Find outlet methane mole frac in the gas. een b, Find (L/V),,, and actual L/V. Find outlet methane mole frac in the liquid. 4. Find the number of equilibrium stages required, ¢. Find the outlet argon mole fraes in the liquid and the gas, argoniin the liquid. : and the % recovery ofsme AS, an\wens water Vertiernaa), @ late, 20% CUA psa gtvo denn} oth Yaayren L150 x00) ant sow eFrower gestv) of oie Sev) + woo (= on) = BB emai aes “1 ou “ey fot Yo = EE SEs onneae untntrone WT cy Tape Te way At hasnt it win uted 317 awevefve 447, alsonoed, 7. acetone exits taies Reerort owt | SAT gammy 4 my ie Ye Slane RW ove TP fof solve OM, ‘aon hor nn sleet “tebe mfarege 8 ve BA (BB) (orseae) =Cm0)(aw)* Z8YCO ort) Xne oo A _ mor Fae tnaaid) af eolane OV ae = 1: s : / 00333 | oos4es cosas o-oune o.0%29 | oad 0.0826 | 0.04094 ono | e-13250 12663 HPF QTARN WH sae ao get eqvilliovien dave H Wee YL Yon Ye aoe por opevating JiveLee dunn GA ewoifw Ceuteaiv) Feed 8-Ay leno) amentgwia | Minos = FE A soem HONE NWiog £98 ont ort, Ma 4 Ans Kouy = 0-010 mo} NHS = sey SER 2 e-oy0y OLNN Ferdi 0 Cowverng 18 wet varia » KM NO May : Rs ESD sae eae MU ony ane x W rq Teor Ho bas | Yerahiaw, wy 190 eq tho Kenny Cryo hpgamyg ee ye ; ye tr vee Ye aes of XNY = regent fox more owner exre) £eed 7 ovtond fre wt. ls kaye R one (9) frowa qn Yong enone No wg ts 8) tek Ce)win feo ved dane om QT (th 2 82 ~o tog = (Gwin SREP 2 ve wee TA VGet GHo'e ao Por eayiivoninen ant ‘eno 3 wands, KARD y eels Tero heGs o Y cayytt EAMilioriawn A OTA ee : fre on te yy 3 enyilivovivn eraqer u G>\0 xeon] yay ® Yaw = 00083 He = Kw #00002 Ye rs eae 5 wa! yyy sin 8 weeeMeR tq Sy Se wan HREMER Eq) ™G <1, yo \- (&)e" ey oe minve (+ Wie : as t ve Me 1. a ) = any (0-002 \ \ ( a = 0-0001R28 ny 0. 0083- 0.0003928 ss Ee an aye Sd ©-0005 - 0.0001838 Mong a Levee, fund a ‘nh y att ey = aot 40 2-4) ~ 3F-0D. Ls HoQN12023b gave to - striNREY, 8 ae Xa 0.05 on 15 02 0.25%, 03 0.35 QN12D23 pvt Awsov wey tol of dane, Ye rgxt Jone 7 a 2M x + o-aninn 1s (stop) WAX + veiw Mw | 01(CN3132E - Separation Process tutorial #6- chapter 13 UInqwid- iqned Eeacion) ® D2 Wefare extracting ‘acetic acid from benzene (diluent) into water (solvent) at 25°C. 100.0 kg of a feed tht is 0.0092 wt frac acctic acid and 0.990 wt frac benzene is fod {to acohumn, The inlet water (solvent) is pure and flows at 25.5 /h. We desire an out- let weight fraction of 0.00040 acetic acid in benzene. Asstime total flow rates are com stant. water and benzene are completely immiecble. equilibsium linear, egy yge kre MICOY K ~yis = wt frac. in extract (water)/w, frac. in ralfinate (benzene) = 30.488, Find: & The outlet wt frac of acetic acid in the water '. The number of equilibrium stages required. The minimum solveitt rate & DB. A feed at is 0.008 w: frac acetone in wacer ie fed tA singhe mixer setter that has an ‘lficieney of 100 *%. The total flow rate of the feed is 15010 kgh. We contse: this with, 500 kg’k of pure chloroform. Determine the outlet 1" fracs cf acetone in tre exteact ‘and ralfinate You may assume that water and chloroform are iman'seib.e end that the ‘equilibrium expression for agetone is K = ists, & Solve this graphically like a fash calculation (operating line has a nagotive slope). 1, Solve using the Kremser saustion with N= 1 DIO. Two feed solutions of dioxsne m water are beang extracted with benzene in the 4 stage cross-flow system, The entering benzene solvert to each stage is pure (¥4, 4,0). The solvent flow rate to each stage is 2U kg/h. Entering feed to stage 1 has a toial flow rate Of 100 kg/h and is Xouser, = 015 wt frac dioxare. Entering food 2 has a total flon Tate of 70 kg/h and is X,..,,.r9=UULS wt frac dioxane. Feed 2 is mixed with the raff nate leaving the second stage, and this mixture is ‘ed to the third stage. Assume hat Denzene and water are completely immiscible and that the total tlow rates 0° ralfinare and extract entering and leaving daek: stage are corstant ‘The equilibriam for cioxane distribu:ing between benzene anc wate: is Yai Kae, WRCTE Sige is the WE fF06 Of dioxane in zhe extract (benzene phase) and Ney isthe ‘wt frac of dioxane in *he raifinate (water phase). End :he following dioxane wt frac: ralfinate wt frac leaving stage 2, he ralfinate wi frac entering stage 3, the raffinate wt frac leaving siage 4, and the extract wt frac ear. DIL" The feactional extraction systein shows in Figure 13-3 is separating abiotic acid from other acids, Solvent |, heptare, enters at F = 1000 kg/h and is pure. Sclvent2, eth. cellosolve + 10% water, is pure end luay 4 tow rate of R = 2500 kz/h. Feed iy 5 wt 20 abietic acid in solvent 2 and flows at 1 kg/h. There axe only traces of other acide in the food. We desire to recover 95% of the abuetic avid in the bo.wm raffinate stream. Feed ‘gi stage 6. Assume that the solvents are completely immiscibie and that the sistem cam be considered lw be very dilute, Equilibriam data are given in Taale 15-3. Find N. Did The equilibrium data for the system water-acctic acid-isopropyl ether are given in Table 13-5, We have a feed that is 30 wt % acetic acid and 70 wt % water, The feed is to be treated wih pure isopropyl ether. Abie eatmstog done in» mixed tank wil process 15 kg of feed. Ne ginant GA Oat, a If 10 kg of solvent is used, find the outlet extract and raffinate compositions. b. Ifa raffinate composition of x, = 0.1 is desired, how much solvent is needed?