Problema 7.

5:
Flujo Total:

230.64

kmol/h

zi
H2
0.31447277
N2
0.03459938
Benceno
0.00056365
Ciclohexano 0.6503642

P sistema=
T sistema=

300
120

Psia
F

Ki=iLo
Chao - Seader
De tablas:
zi
H2
0.31447277
N2
0.03459938
Benceno
0.00056365
Ciclohexano 0.6503642

Tc(R)
59.7
221.3
1012.7
995.3

Tc(K)
32.9833333
122.761111
562.427778
552.761111

()=24_(=1)^ (_
(1_))/(1+(_1))=0

Equilibrio L-V:
fiv=fiL

zi
H2
0.31447277
N2
0.03459938
Benceno
0.00056365
Ciclohexano 0.6503642

Pc(Psia)
190.8
492.9
714.2
591.5

Pc(kPa)
1315.5151062
3398.4140242
4924.2184948
4078.2347237

Solve en TI:
=

0.30067

Ai
0.00104485
0.00336065
0.01871327
0.02012198

Bi
6.75009E-006
9.72513E-006
3.07497E-005
3.64902E-005

_=(_
_^)/_

Tr(K)
9.763685363
2.6232972802
0.5725870976
0.5826004804

Pc(kPa)
1315.51511
3398.41402
4924.21849
4078.23472

A= 0.0014463129
B= 7.36147E-006

^3^2+(^2/1)^2/
()^2=0
P(kPa) para Z y para iV

Correlacin de Chao - Seader

De tablas:
Vol Molar a
298.15 K
3
Tr a 298.15K i (cal/cm^3) iL (cm /mol)
9.03941385
0
31
2.42870073
4.44
53
0.53011251
9.158
89.4
0.5393831
8.193
108.72
De tablas:

zi
H2
0.31447277
N2
0.03459938
Benceno
0.00056365
Ciclohexano 0.6503642

Tr(K) a T sist.
9.763685363
2.6232972802
0.5725870976
0.5826004804

Sum Xii= 105.53670333

Sum ii= 8.0195842536

R=

1.987

_=(_
_^)/_
i=1
i=2
i=3
i=4

iL

iV

iL0

27.7160089
3.0313324
1.20229129
1.00521359

1.0121468163
1.004672971
0.9590950602
0.9626219809

25.6708129
0.57140927
0.01984968
0.01981766

()=_(=1)^ (_
(1_))/(1+(_1))=0

Ki
702.953827
1.72407489
0.02488294
0.0206945

Solve en TI:
=

2068.41998 kPa
322.038889 K

0
0.0206
0.2116
0.2149

Yi
0.9590151
0.02269498
1.5863E-005
0.01827436

iL(0)

Si es: CH4

Si es: H2

iL(0)

iL(0)

Tr(K)
9.76368536
2.62329728
0.5725871
0.58260048

Pr(kPa)
1.572327044
0.6086427267
0.420050406
0.5071851226

1824.84144 3.3786E-007 25.6708129

3.61618327 10.5111464 523.508823
0.05260667 0.1219759 4630094.62
0.05101447 0.11451378 3176369.87

Ki
25.6708129
0.57140927
0.01984968
0.01981766

Xi
0.03735819
0.039717553
0.000799164
0.922124967

Yi
0.9590151
0.022695
1.586E-005
0.0182744

AiYi
0.00100203
7.6270E-005
2.9685E-007
0.00036772

BiYi
6.47344E-006
2.20712E-007
4.87786E-010
6.66835E-007

iV
1.01214682
1.00467297
0.95909506
0.96262198

Solve en TI:
Z=

1)^2/

1.01107

a Z y para iV

Factor de
correcion de Vol Vol
del
Molar

Molar a T
sist.
iL (cm3/mol)

i
i
Xi
Xii
ii
0.94459662 33.0524333 0.0116999966 0.03735819 1.23477907
0
4.08128623 55.3826127 0.0208426244 0.03971755 2.19966187 0.09254125
12.2628067 90.962573 0.0006888032 0.00079916 0.07269402 0.00630806
14.8562151 110.64614 0.9667685758 0.92212497 102.029568 7.92073494

(Cal/mol-K)

0.336495

Ki
702.95382658
1.724074894
0.0248829366
0.0206944987

Xi
Yi
0.0013257 0.9319399
0.0278209 0.0479653
0.0008389 2.087E-005
0.9700144 0.020074

CORRECTOS:
iL(0)

iL

(1)

iL

CORRECTOS:
iL0

25.670812888
0
Err:502
25.6708129
3.6161832738 1.26412E-039 0.57140927 0.57140927
0.0526066694 0.0099905134 0.01984968 0.01984968
0.0510144684 0.0122787157 0.01981766 0.01981766

Ki=iLo
25.6708129
0.57140927
0.01984968
0.01981766

iL
27.716008865
3.0313324024
1.2022912915
1.0052135892