CAo=CBo

0.05
0.05
0.05
0.05
0.05

t
0
10.2
26.5
36
78

XA
0
0.176
0.344
0.402
0.513

CA=CAo*(1-XA)
0.05
0.0412
0.0328
0.0299
0.02435

CB=CA
0.05
0.0412
0.0328
0.0299
0.02435

(1/2m)*(ln((Z-m)*(Zo+m)/(Z+m)*(Zo-m))
m(cte)
(metodo integral rev)
(metodo
k2=pendiente
integral rev)
/ k-2=(k2/Keq)
(CA^2)-(1/Keq*CC^2)
0.1390495435
0
0.4223488
0.2953488372
0.0025
0.1390495435 1.29847
0.0016432862
0.1390495435 3.38292
0.0008689589
0.1390495435 4.57376
0.0006114855
0.1390495435 9.92247
0.0001328368

Rx irreversible metodo integral

50
40

f(x) = 0.2644573913x + 21.8836997047

R = 0.9534636314

30
1/CA

t vs 1/CA

Linear (t vs

20
10
0
0

10

20

30

40

50

60

70

80

90

Rx irreversible metodo diferencial

0.0012
0.001

f(x) = 0.4539011949x - 0.0001130374

R = 0.9792575144

0.0008
(-dCA/dt)

CA^2 vs (-dCA/dt)

0.0006

Linear (CA^2 vs (-dCA

0.0004
0.0002
0
0

0.0005

0.001

0.0015
CA^2

0.002

0.0025

0.003

Linear (CA^2 vs (-dCA

0.0004
0.0002
0
0

0.0005

0.001

0.0015

0.002

0.0025

0.003

CA^2

Rx reversible metodo diferencial

0
-0.0002
-0.0004
(dCA/dt)

0.0005
0.001
0.0015
0.002
f(x) = - 0.3681201608x - 7.68346369465195E-005
R = 0.9718224778

-0.0006
-0.0008
-0.001
-0.0012
(CA^2)-(1/Keq*CC^2)

0.0025

0.003

CC=(CAo*XA)
0
0.0088
0.0172
0.0201
0.02565

CD=CC
0
0.0088
0.0172
0.0201
0.02565

1/CA
20
24.27184466
30.487804878
33.444816054
41.067761807

met dif K2
0.368

met dif K-2=(K2/Keq)

0.2573426573

|
-0.0010040282
-0.0007121654
-0.0003623837
-0.0002247002
-0.0002000042
RX IRREVERSIBLE
INTEGRAL
K=0.264
R=0.953

o integral

Polinomio t vs
0.06
t vs 1/CA

0.05

Linear (t vs 1/CA)

CA

70

80

90

f(x) = - 9.00517862264068E-008x^3 + 1.568426355498

R = 0.99995734

0.04
0.03
0.02
0.01
0
0

10

20

30

40

50

60

70

diferencial

Rx reversible metodo
12
(1/2m)*(ln((Z-m)*(Zo+m)/(Z+m)*(Zo-m))
CA^2 vs (-dCA/dt)

10

Linear (CA^2 vs (-dCA/dt) )

8
6
0.003

f(x) = 0.1271849
R = 0.99999724

Linear (CA^2 vs (-dCA/dt) )

R = 0.99999724

8
6
0.003

4
2
0
0

todo diferencial

5
0.002
69465195E-005

CC^2)

0.0025

0.003

Column I
Linear (Column I)

10 20 30 4

(-dCA/dt)
0.0010040282
0.0007121654
0.0003623837
0.0002247002
0.0002000042

CA^2
0.0025
0.00169744
0.00107584
0.00089401
0.0005929225

RX IRREVERSIBLE
DIFERENCIAL
K=0.453

0.0025
0.0025
0.0025
0.0025
0.0025

-0.1
-0.1
-0.1
-0.1
-0.1

0.3006993007
0.3006993007
0.3006993007
0.3006993007
0.3006993007

RX REVERSIBLE
INTEGRAL
DIFERENCIAL
K2=0.422
K2=0.368
K-2=0.295
K-2=0.257
R=0.1
R=1

R=0.979

Polinomio t vs CA

-008x^3 + 1.56842635549884E-005x^2 - 0.0010040282x + 0.049973644

Polinomio t vs CA
Polynomial (Polinomio t vs CA)

40

50

60

70

80

90

ersible metodo intgral

12

-m))
10
8
6
4

f(x) = 0.1271849321x + 0.0021702844

R = 0.99999724
Column B
Linear (Column B)

Z
-0.16627907
-0.15747907
-0.14907907
-0.14617907
-0.14062907

R = 0.99999724

Column B

Linear (Column B)

4
2
0
0

10 20 30 40 50 60 70 80 90
t

Zo(cte)
-0.1662790698
-0.1662790698
-0.1662790698
-0.1662790698
-0.1662790698