2.

1.5

120,18 C
122,28 C

Flujo de calor (W/g)

124,29 C
126,57 C

128,27 C

0.5

Tiempo(minutos)

120,18 C
Tiempo
F. Calor
min
W/g
0
0.2513685493
0.2961685493
0.3298685493
0.3718685493
0.4195685493
0.4559685493
0.4868685493
0.5232685493
0.5877685493
0.6186685493
0.6634685493
0.7111685493
0.7532685493
0.7924685493
0.8317685493
0.8738685493
0.9186685493
0.9663685493
0.9999685493
1.0504685493
1.0841685493
1.1205685493
1.1626685493
1.1934685493
1.2439685493
1.2944685493
1.3280685493
1.3981685493
1.4514685493
1.5159685493
1.6589685493
1.7991685493
1.9225685493
2.1720685493
3.7535685493

0
1.0449
1.2481
1.4218
1.6348
1.792
1.9138
1.9807
2.0046
2.0061
1.9516
1.8731
1.7693
1.6523
1.5163
1.3277
1.182
1.018
0.8559
0.7292
0.5925
0.4823
0.3911
0.3254
0.2727
0.2137
0.1659
0.1337
0.1083
0.0837
0.0642
0.0359
0.0231
0.0149
0.0015
0

122,28 C
Tiempo
F. Calor
min
W/g
0
0.0761685493
0.1761685493
0.2461685493
0.2811685493
0.3271685493
0.3625685493
0.4085685493
0.4509685493
0.4934685493
0.5288685493
0.5748685493
0.6137685493
0.6491685493
0.6810685493
0.7270685493
0.7800685493
0.8048685493
0.8579685493
0.9039685493
0.9393685493
0.9924685493
1.0207685493
1.0632685493
1.1056685493
1.1587685493
1.1870685493
1.2507685493
1.2826685493
1.3215685493
1.3604685493
1.4064685493
1.4383685493
1.4914685493
1.5232685493
1.5834685493
1.6258685493
1.6718685493
1.7355685493
1.7568685493
1.8205685493
1.8453685493

0.0000
0.1385
0.3501
0.5182
0.6084
0.7331
0.8339
0.9712
1.0632
1.1655
1.2513
1.3135
1.3578
1.3945
1.4181
1.4266
1.419
1.3842
1.3596
1.305
1.2484
1.2022
1.1118
1.0373
0.9892
0.9148
0.8441
0.7578
0.6504
0.5731
0.5071
0.435
0.3596
0.3266
0.2691
0.2324
0.2013
0.1645
0.1268
0.1023
0.091
0.0721

1.9443685493
2.0328685493
2.1531685493
2.3372685493
2.7689685493

0.0585
0.0415
0.0226
0.0132
0

124,29 C
Tiempo
F. Calor
min
W/g
0
0.0961685493
0.1961685493
0.2961685493
0.3961685493
0.4961685493
0.5366685493
0.5790685493
0.6108685493
0.6453685493
0.6798685493
0.7142685493
0.7487685493
0.7885685493
0.8177685493
0.8574685493
0.8946685493
0.9105685493
0.9582685493
1.0086685493
1.0590685493
1.1226685493
1.1783685493
1.2181685493
1.2525685493
1.2923685493
1.3241685493
1.3613685493
1.3984685493
1.4328685493
1.4673685493
1.5097685493
1.5363685493
1.5734685493
1.6105685493
1.6503685493
1.6821685493
1.7139685493
1.7563685493
1.7882685493
1.8226685493
1.8624685493

0
0.0310
0.0987
0.2027
0.3428
0.5192
0.6010
0.6929
0.7779
0.8455
0.9015
0.965
1.0087
1.0532
1.0874
1.1195
1.145
1.1673
1.1879
1.192
1.1904
1.1689
1.1409
1.1047
1.0709
1.0371
1.0058
0.9802
0.9275
0.878
0.8377
0.782
0.7268
0.6815
0.6353
0.5925
0.548
0.4718
0.4355
0.3811
0.358
0.3127

126,57 C
Tiempo
F. Calor
min
W/g
0
0
0.0461685493 0.0042031313
0.1461685493 0.0197176427
0.2161685493
0.035434655
0.3961685493 0.0942160852
0.4959685493 0.1382040129
0.5317685493 0.1559645522
0.6150685493 0.2013392122
0.6943685493
0.249797635
0.7459685493
0.2843
0.8293685493
0.3256
0.8610685493
0.3625
0.9126685493
0.4027
0.9602685493
0.4355
1.0792685493
0.4979
1.0951685493
0.5253
1.2102685493
0.5639
1.2261685493
0.5893
1.3014685493
0.6094
1.3729685493
0.6411
1.4403685493
0.6496
1.5078685493
0.6633
1.6109685493
0.677
1.7300685493
0.6792
1.8411685493
0.6728
1.9958685493
0.6326
2.1347685493
0.5967
2.1982685493
0.5787
2.2776685493
0.547
2.3093685493
0.5259
2.3847685493
0.5079
2.4045685493
0.491
2.4680685493
0.4762
2.4839685493
0.4593
2.5434685493
0.4424
2.6069685493
0.4064
2.6466685493
0.381
2.7180685493
0.362
2.7775685493
0.3271
2.8053685493
0.3049
2.9244685493
0.2706
2.9720685493
0.2526

1.8969685493
1.9393685493
1.9791685493
2.0109685493
2.0427685493
2.0852685493
2.1011685493
2.1514685493
2.1780685493
2.2390685493
2.3105685493
2.3583685493
2.4670685493
2.5784685493
2.7163685493
2.9761685493

0.2814
0.2451
0.2118
0.192
0.1681
0.1442
0.1228
0.1096
0.0898
0.0857
0.0618
0.0453
0.0354
0.0239
0.0131
0

3.0831685493
3.2299685493
3.3688685493
3.4005685493
3.4957685493
3.5870685493
3.6783685493
3.7775685493
3.8806685493
4.0354685493
4.2179685493
4.4203685493
4.9798685493
5.0710685493

0.2156
0.1712
0.13
0.1078
0.1025
0.0782
0.0655
0.056
0.0433
0.0296
0.0222
0.0137
0.0031
0

128,27 C
Tiempo
F. Calor
min
W/g
0
0
0.1961685493 0.0051599722
0.3961685493 0.0142583947
0.6961685493 0.0353534827
0.9961685493 0.0653855158
1.2961685493
0.104354494
1.3352685493 0.1100917467
1.3971685493 0.1194849123
1.5282685493 0.1406352511
1.6192685493 0.1563197393
1.6884685493 0.1687972532
1.8413685493 0.1980528474
1.9541685493 0.2211238332
2.0415685493
0.2314
2.1361685493
0.2552
2.1980685493
0.2671
2.3109685493
0.2756
2.3946685493
0.284
2.4856685493
0.3027
2.5657685493
0.3146
2.7004685493
0.3332
2.7987685493
0.3417
2.9079685493
0.3561
3.0462685493
0.3689
3.2683685493
0.3799
3.4576685493
0.3816
3.6032685493
0.3748
3.8544685493
0.3621
4.0947685493
0.3485
4.2003685493
0.3375
4.3350685493
0.3248
4.4405685493
0.3163
4.5388685493
0.3053
4.6262685493
0.2917
4.7245685493
0.279
4.8410685493
0.2747
4.9211685493
0.2603
4.9939685493
0.2484
5.0885685493
0.2399
5.1395685493
0.2272
5.2341685493
0.217
5.3252685493
0.206

5.4271685493
5.6091685493
5.7220685493
5.7547685493
5.8530685493
5.9404685493
6.0168685493
6.1115685493
6.2316685493
6.3845685493
6.5689685493
6.7409685493
6.9781685493
7.2805685493
7.6066685493
8.3003685493

0.1941
0.1712
0.1593
0.1492
0.139
0.133
0.1152
0.1025
0.0949
0.0771
0.0567
0.0456
0.0332
0.0221
0.0125
0

Tiempo
min
0
0.25136855
0.29616855
0.32986855
0.37186855
0.41956855
0.45596855
0.48686855
0.52326855
0.58776855
0.61866855
0.66346855
0.71116855
0.75326855
0.79246855
0.83176855
0.87386855
0.91866855
0.96636855
0.99996855
1.05046855
1.08416855
1.12056855
1.16266855
1.19346855
1.24396855
1.29446855
1.32806855
1.39816855
1.45146855
1.51596855
1.65896855
1.79916855
1.92256855
2.17206855
3.75356855

F. Calor
W/g
0
1.0449
1.2481
1.4218
1.6348
1.792
1.9138
1.9807
2.0046
2.0061
1.9516
1.8731
1.7693
1.6523
1.5163
1.3277
1.182
1.018
0.8559
0.7292
0.5925
0.4823
0.3911
0.3254
0.2727
0.2137
0.1659
0.1337
0.1083
0.0837
0.0642
0.0359
0.0231
0.0149
0.0015
0

1. Obtener los parmetros de Avrami para las diferentes temperaturas de barrido, Cmo se compara
2. Qu puede concluir acerca de la dependencia de la cintica de cristalizacin con la temperatura?
3. Calcule para cada temperatura la velocidad global de cristalizacin

4. Consulte el calor de fusin terico de un PP 100% cristalino. Con este valor calcule el grado de cris
compara los grados de cristalizacin obtenidos con los grados mximos reportados en la literatura?
5. Qu tan aplicable son los resultados obtenidos a procesos de transformacin de polmeros como l

de barrido, Cmo se comparan los valores de los parmetros con los sugeridos en la literatura para un PP?
talizacin con la temperatura?

te valor calcule el grado de cristalizacin absoluto que se obtiene a las diferentes temperaturas. Cmo se
s reportados en la literatura? Es dependiente este grado de cristalizacin con la temperatura?, comente
formacin de polmeros como la extrusin y la inyeccin? Se dan las mismas condiciones del ensayo? Comente

en la literatura para un PP?

s temperaturas. Cmo se
a temperatura?, comente
ndiciones del ensayo? Comente