- WH (EDI MINISTERIO DA EDUCA’ : NII ly AGE ce fag ouapuncho mas PiU! L UFPI DISCIPLINA: : Mecanica Estatistica = SOR: Francisco Wallngion de Sousa Li ee Resolugao do capitulo 06 do livro: “Introducao 4 Fisica Estatistica” (Silvio R. A. 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(= 7. (2) (ie le (1d,sre ceil fence Como “wt € om mdupvo par ¢ positive, Vanes Cou- sidevay: M22 HL [herr FFL fbeced] AZ. ("¥. Gel a - _ * are IRF ies ©+ Conc com, 6 lovopdbniia A entvopia € dada pow: s--34 oT co 2 ( rerls(*te") F SE (hCR)) 6 Ss td ( th (%))oe ko] bn( 482) ox ts a reer ner Nea eer dS = *°| ier ‘o| iT ake tT fae wd (1h (#7) . ake as = fe) on BY ; TkKeT w wr #] : 6. wf () ] a ek) Portanto , 0 calor epecigico & clad pov: C.T ) bee a vola(tat) +m) “Be [a(hCE))] aks oT ifCCC eet eee ede e ee DDE DE” ® Conricevemes um sistema clgssico cle WN molkoolas diatdmicas muito racampen te intevagen tes ‘ © tamibloniano dk oma Onica wpleols € cach por: aoe B+ Pa ad -%e Har ge (7 he) ein Ie onde: K>0 ( constanle elslica) ny Obler uma express para a evevgia Cure a Helmbolts para esse sistema ; ne Cabeolar ° calor espeesqito d vollwp tons ante ; me Calwlar o lid metro moleclar medio : p= 1d mls ~“ Como fared as resportas anferieves para. u™) tamilloniano do tipo : Ho * ge Gs + te) + € |r -%]* onde: E © Yo -> Constantes positivas , c: va = \Wi- fe] :Levanclo em conta todes os datoves oe cov (ao, 4 fons de pay fica € dada ie * Ze Ze oe t I Nia qator de conte correla cle Soll; mann ; Lose: . ; . a Ze = [va -| sa | Uh | tn ef a2ucd { (es [tah |e ; NI a Wo aN: F cone B (ZAR 2, gh Fin i 3,51. is gee { fier [bin fe ~ B : am 2y Qu} xexp|-p( £22 Pa + Ae” [fi -Feal2)} ext! (a t-4 aoe 4-4, ” 7 UTTTATATAL TAT ETETILTCTTTETETEREC TEER ARERR ERR TTUUUEUURUULULUUUUUU UU U UU U Leese sees eee eee ze ae fra lth . cere] p(k SF + se! Wi ~ “ul a ae jer “{ Dy a fea . ret] EOP Je oP ish 5 evate| [are ia on £2 *) [er | Nu x x erp ( z eZ ta)! eng a sequinks aa Ty: [ote] oe f & ZF) 1, = ja¥e~ Jeti ef ( at & 1s Fat 2.» Be Tita Nt saben pe le \ di «| on(- £2 i) . E | dP, exp (2 ri’) [he og ni] “OF it) te | oe ae ¥4- a] |Ta=V =r) Vottanto a Noss4 fons & parti ca3N aM ze ) Je wut LP 3N Come: Ie- V™ Ge ~ 5 Sebstitumdo lems: oat (EGE Ze alti! * CNG) GF aWULEUEULUOREUUULLLLULLU LULU LEE UU EOD e eee eee ue uN © Gwe) "[(a)] (a). Uiz- bncv)- Loa(u) 2") + a b(g)-ah(~): os Qn Zs = Aaze hv =| bow + bae)| +a In(sz)- +38 Lo() . IB (az 4 nda = dan! = fn Cn") + 2 b(z)a hs) _Quz = wlav—Lnnt — anda hat et) sn baa): ~ mz = nouy - (wlan - N)-aubuh+ ax In( Jette W-tat*exp(-B) Lie dr, --.- Jai joa- j Xie = 3 + ia | fie LaF I su ~ [etantr- freely ~- ety 4 FAasbr-- <-> = . 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Zement’)|ae 1.12 o wl W 2 at fe ~ ff | Hl . coe )foal (crear ‘ ye ale |i wnt F(Zeemenyl. jefe ort (ZF) pe It Ze oT {Jef . | Peay Jttaeeta(g r( in AM) i. ft afte POPNPODOLLHPLOLTLELCLALALLELLL CLEC COOOL ODDO; _f#) yep. EX i ‘i ® -Lipaten fangs ——so~ 5 ; i ~ reer Zenen)ht * a (=) i pi ot pZere aa Z. a (‘) ‘je cel Zn aa PT eo 2 oR (Fy Jorjarme e Peli noe ee a «4 -Pe|l¥ep-1-You) -¥] 2 | | Pins jdtvae I paar ve) PUUUUUULUUUUULULULUUULULUU CUR UCU COUR eee eeu t eee >‘ 2 (2) [v brie (even (es CTL erent 0 jor exp (“Px )ae = 5 ae ho pve meh ‘ oo M20 + Fomeig nO al) 2 ( NG , » | (x-apeng (# - wy" )dc = ae wy ~ (a-b) Nee 3) ° CLEDALELECELOLOLERELEL ELLE ERE CELE LE CLO ERLE LERRAeae T aa R UU TUN UU EUR U eee eee eee eee eee divpnpio al, polo ole beico loniano ? L, obler oma mpleeo Z, O Leqvangiano de uma mpiew Le Kirke -&) Una mmphecola diatsmnica pock ser tratecla tomo um > yeher ae ( do pregando ° “pvimento vibracionaQ) tye ® © Hamibtonrane da molécul E escrito come: ¥ Hy > berm hawlzional | leek > Levmo vofacioyal; ne Obler ump tapress® para Hrot em toorcknadlas exfevicas; aS So ponba que a vplula ported um moment i"; Janey ve = Le Como se mock git ‘a parle rolccronal clo Hamjb_ express para a polovisacap~ por je duas party eulas consti luintes € dado pr UY, + Ky Ke > enevgia cinetica para dvas avticobs { a P P e« UP entvgid potentialos Karke -O * nh = inves Sait" -U Vanes Consickvar as coor chemacles : }: € fe . - Lme (IBY? , Lang (de rae . oe ie (#) 3m (#)*- U (1g fal) Vamps conpiclera aera 3 vinte welanca ad vavi dvel : d " ofthe ga" ates eu 2 Rab = mavet MV fos Bes ou tacde + Bi jinn wedi dk | > Pe mg a Mae * tii ome 2 - EO a Cnrpte ep LOMB = mugs + Me fe R= mages mage R= megs megs ms +me VV YVV VV VV Vad CLOLCLCLOOOLCLLLOLRL ELEN LTO R PERE RCC CeCe TCT TTT = \a8 4 » bub 4 y 3 BODDDRLEUULELEOUUAUEE ORE E PPA saa eeD Povtanto, teoges: rE RR Contem) = maze ala + R Comes ma) = me ( Fag) meg 2 mt +m gs +a ga = R Cmy+ mo) | : mage Fada = RCmiem) -may - B Ga (rareme) = R( mime) —m¥ x ( 4 ) Cmaemny), . - Pz mr Pe N ~ Gaae = P28 fr fee r o-fe=7-f xO ESI Rm ms) = anger mega © ROmim) = wg vime(fi-¥)- = ROM me) = amejt Made meV ~ x magi wags ~My ® R Cm ma) _ : me Git me fe = Rima m) + mer. mga magi = ROH) + May . —_ = RCmitm) + maf «| 4 ] : Cmitmy) e me ¢ ale ete) th Logo, ports yeocrever o Lagrangiano ols jor ai of = donflgt) dom ( 4e)- one gr- gal) s ‘geeaeed ciinehidanbebennaeummeneane pl ca ~UW) ads tm (z rediyes + tme/ AR tas = dy (i anne ds (tts = (sett Grays ~ Ytr) "= anVULUEEREPR DR URUOUUULUR UU D Ue UE pe eae, @ oe ae) or ais wee “4 ~ UW mer EGoema (fy [4 zoe mel - Ulv) he Lm) (IR), meme [dex . a ple Stee’ —Utly) = onde: « M- Cm 4+) mime «fe (9)CLUKELEL EEE TL ELECTR EC eLE CN CLT T TT dy x + X=¥ WsPsind “xeY Me -v9 J ‘coy 7 X= Yeas sine YPrysne + voy ee ; — + yersing sand “y =V Hing 8 + rp Coy sing + ve sind —_ + jr rte + J > reese -vésine = — <= = —= eR ( [ ¥ xk y$r33 “ ¢ = XK H9+35 rt, ( ¢ghee’ bb, SS (e ond: (i ): re + Cresine)*s (vé)* Portante, 0 Layvangiano ew toorcheyacks opfriee €, . } ol m= 3M ($y es o[Fetrpsve)® Ceor >| d Comp as mplicolls se Iralices como ror raid: ile igi Gl = Constante “4-0 © ol m= fm (Reo 83) + A417 sino f+ 136") x een s dn = v2 9 Sin2Q = Up .|g-—te_| 1 ame Lage, 0 pares congo lyacos 5X Ri Pes dean Mii. 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