KIMIA SET 4 Perfect Score

Set 4 Chemistry Perfect Score Module 2007
PAPER 2 : STRUCTURE
SECTION A
1 The diagram shows the chemical reaction of propanol.
D E
C3H8 C3H6
II
III
Propanol Propanoic acid
Heat gently with ethanoic acid and

IV concentrated sulphuric acid
(a) (i) Name process reaction I
………………………………………………………………………………………………………….
[ 1 mark ]
(ii) Write the general formula of compound E.
………………………………………………………………………………….................................
[ 1 mark ]
(b) (i) Name process II.
………………………………………………………………………………….................................
[ 1 mark ]
(ii) What is the catalyst used in process II?
…………………………………………………………………………………..................................
[ 1 mark ]
(c) Describe a chemical test to distinguish compound D and E.
………………………………………………………………………………………………………….
………………………………………………………………………………………………………….
………………………………………………………………………………………………………….
[ 3 marks ]
(d) (i) Name a chemical used in process III to convert the propanol to propanoic acid.
…………………………………………………………………………………………………………..
[ 1 mark ]
(ii) What is the observation in process III?
…………………………………………………………………………………………………………..
[ 1 mark ]
(iii) Propanoic acid can reacts with magnesium. Write the chemical equation for the reaction.
…………………………………………………………………………………..................................
[ 1 mark ]
1
(e) (i) A compound Y is formed in process IV. Name the compound Y
..........…………………………………………………………………………………..................................
[ 1 mark ]
(ii) What is the function of concentrated sulphuric acid in process IV?
………………………………………………………………………………………………………………….
.
[ 1 mark]
2 The diagram below shows the flow chart for the conversion of an organic compound to other
compounds through process I, II ,III and combustion of compound L.
Compound J Compound K
C2H6O C2H4O2
III
Acidified potassium dicromate(VI) solution
I II
Compound L Complete combustion in air Gas X + H2O

C2H4
(a) (i) Name the homologous series to which L belong.
………………………………………………………………………………….................................
[ 1 mark ]
(ii) Name gas X.
…………………………………………………………………………………..................................
[ 1 mark ]
(iii) Write a balanced equation for the combustion of L in air
…………………………………………………………………………………..................................
[ 2 marks ]
(iv) 0.5 mole of L burn completely in the air. Calculate the volume of gas X released.
3
(1 mole of gas occupies 24 dm at room temperature and pressure)
[ 2 marks ]
(b) What is the observation on acidified potassium dichromate(VI) solution in reaction III?
…………………………………………………………………………………………………………..
[ 1 mark ]
2
(c) Compound J reacts with compound K to form compound M.
(i) Name compound M.
…………………………………………………………………………………………………
[ 1 mark]
(ii) Draw the structural formula of M.
[ 1 mark ]
(iii) State one special characteristic of compound M.
…………………………………………………………………………………………………
[ 1 mark ]
(d) Draw the set up of apparatus used in process II.
[ 2 marks ]
3 The diagram below shows the chemical reaction of compound X.
I
Compound X, Porous pot chips Gas Q
C2H6O
Acidified potassium manganate (VII)

solution II
III
Compound Y, Compound Z + water
C2H4O2 Reflux with compound as
X and concentrated
sulphuric acid
(a) Name compound X.
…………………………………………………………………………………………………………..
[ 1 mark ]
3
(b) (i) Name gas Q.
…………………………………………………………………………………………………
[ 1 mark ]
(ii) What is the use of porous pot chips in process I?
….................................................................................................................................
[ 1 mark]
(c) (i) What is the observation on potassium manganate(VII) solution in process II?
…………………………………………………………………………................................
[ 1 mark ]
(ii) Draw the structural formula of Y.
[ 1 mark]
(d) The mixture of compound X, Y and concentrated sulphuric acid are heated under reflux in
process III.
(i) What is the use of concentrated sulphuric acid?
…………………………………………………………………………………………………
[ 1 mark ]
(ii) Write a balanced chemical equation for the reaction.
…………………………………………………………………………………………………
[ 1 mark ]
(iii) State one special characteristic of compound Z.
…………………………………………………………………………………………………
[ 1 mark]
(iv) X is replaced with butanol. Name the product formed.
…………………………………………………………………………………………………
[ 1 mark ]
4
4 The diagram below shows the flow chart for the conversion of C2H4 and C3H7OH to other compounds.
C2H5OH C2H5 COOH
Process 1 Process 2
C3 H7OH
C2H4
Polymerization
Compound P C 3 H6
a) Name process I.
……………………………………………………………………………………………………………...........
[ 1 mark]
b) Draw the structural formulae of C2H4 and compound P in the equation below to represent the
polymerisation of C2H4.
. Polymerisation
C2H4 Compound P [ 2 marks]
c)(i) Name process 2.
………………………………………………………………………………………………………………........
[ 1 mark]
(ii) Acidified potassium dichromate(VII) solution is used in process 2. State the observation on the colour
change of acidified potassium dichromate(VI) solution.
……………………………………………………………………………………………………………………....
[1 mark]
d) Name the product formed from the dehydration of C3 H7OH
………………………………………………………………………………………………………………………
[1 mark]
e) The products from process 1 and process 2 react to form a sweet smell compound.
(i) Name the process for the formation of the compound.
…………………………………………………………………………………………………………………
[1 mark]
(ii) Draw the structural formula of the compound.
[ 1 mark]
(iii) Name the compound.
……………………………………………………………………………………………………………………
[1 mark]
5
f) C3 H6 in the above diagram undergoes polymerisation. Name the polymer formed.
…………………………………………………………………………………………………………………
[1 mark]
g) The boiling point of C3H6 is higher than C2H4. Explain why.
…………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………..
…………………………………………………………………………………………………………………
[3 marks]
5 The diagram shows an industrial preparation of compound X from suphuric acid and ammonia.
Contact Process Suphuric acid
Reaction A
Compound X
Haber Process Ammonia
(a) (i) Sulphur dioxide is produced at the stage I of contact process.

Name the reactants for the formation of sulphur dioxide.
……………………..…………………………………………………………………...........
[1 mark]
(ii) Write a chemical equation for the reaction in (a) (i)
……………………..…………………………………………………………………...........
[1 mark]
(b) In Contact Process, oleum is produced.
(i) Write the chemical equation for the formation of oleum.
………………………………………………………………………………..........................
[1 mark]
(ii) How is sulphuric acid produced from oleum?
……………………………………………………………………………............................
. [1 mark]
(c) Name the catalyst used in Contact Process.
………………………………………………………………………………………………………….
[1 mark]
6
(d) (i) Write the chemical equation for the formation of ammonia in Haber Process
....................................................................................................................................
[1 mark]
(ii) State the temperature, pressure and catalyst used in the Haber Process.
....................................................................................................................................
[1 mark]
(e) In the above diagram, sulphuric acid reacts with aqueous ammonia to form compound X.
(i) Name the reaction A.
...................…………………………………………………………………........................
[1 mark]
(ii) Write the chemical equation for reaction A.
……………………………………………………………………………............................
[1 mark]
(iii) What is the use of compound X in daily lives?
………………………………………………………………………....................................
[1 mark]
6.
 Bronze and pewter are two example of an alloy.
 Bronze is made up of copper as a major component and other
elements.
 Bronze is harder than pure copper.
(a) Name the main element added to copper to form bronze.
…………………………………………………………………………………………………………………….
[1 mark]
(b) What type of particles is present in pure copper?
……………………………………………………………………………………………………………………
[1 mark]
(c) Draw an arrangement of the particles in
(i) Pure copper
[1 mark]
7
(ii) bronze
[1 mark]
(d) Explain why is bronze is harder than pure copper?
..............................................................................................................................................................
..............................................................................................................................................................
..............................................................................................................................................................
[3 marks]
(e) (i) Name the major component of pewter.
...............................................................................................................................................................
[1 mark]
(ii) Beside hardness, state another purpose of alloying to produce pewter.
..............................................................................................................................................................
[1 mark]
7 The table shows the examples and uses of four types of manufactured substances in industry.
Type of manufactured Example Component

substance
P Reinforced concrete Cement, sand, small pebbles and

steel.
Alloy Brass Copper and zinc
Polymer S Vinyl chloride
(a) (i) Name the type of substance P.
………………………………………………………………………………………….......…………………
[ 1 mark]
(ii) Concrete in an important component in construction. Suggest how the strength of concrete is
increased to be used as a pillars of building.
………………………………………………………………………………………………………………..
[ 1 mark]
8
(b) The diagram shows the structure of S.
H H H H H
    
C  C  C  C  C
    
H Cl H Cl H
Draw the structural formula for monomer S.
[1 mark
(c) The diagram below shows an industrial preparation of sulphuric acid by the Contact Process.
Compound X, 1 atm
Sulphur Sulphur Sulphur trioxide
dioxide +
o o
oxygen 450 C – 500 C
o
500 C
Concentrated
H2SO4
Sulphuric acid Compound Y
(i) Name compound X and Y.
Compound X :.............................................................................................................
Compound Y : ...............................................................................................................
[ 2 marks]
(ii) Write the chemical equation for the reaction between sulphur and oxygen to produce sulphur dioxide.
.......................................................................................................................................
[1 markah]
9
8 Diagram A shows the structural formula of a detergent and a soap.
O
//
C
O- Na+
Part P Part Q Part P Part Q
Detergent Soap
(a) Name part P and part Q of the detergent and soap molecules.
…………………………………………………………………………………………………………..
[ 1 mark]
(b) Differentiate the detergent and soap molecule the aspect of:
Detergent Soap
Name of part Q
Sources
Effectiveness in hard water
[ 3 marks]
(c) Some of detergent are not biodegradable .What is meant by not biodegradable?
…………………………………………………………………………………………………………..
[ 1 mark]
9 Soap, detergent, food additive and modern medicine are important chemicals for consumer.
a) The diagram shows the structural formula of a soap
CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2

- +
CH 2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 C-O Na
||
O
Hydrophobic Hydrophilic
i) State the property of hydrophobic and hydrophilic part of soap molecule.
........................................................................................................................................................
……………………………………………………………………………………………..........................
[2 mark]
ii) Detergent is more effective cleaning agent in hard water than soap. Explain why.
………………………………………………………………………………………………………………..
………………………………………………………………………………………………………………..
……………………………………………………………………………………………………………..…
[2 marks]
10
b) Preservative and antioxidant are two types of food additive.

i) State the function of antioxidant
………………………………………………………………………………………………………………..
[ 1 mark]
ii) Give one example of food preservative.
………………………………………………………………………………………………………………..
[ 1 mark]
c) What is the type of medicine should be given to a patient who is stress and depressed .
Give an example of the medicine.
i) Type of medicine:
………………………………………………………………………………………………………………..
[1 mark]
ii) Example of medicine:
………………………………………………………………………………………………………………..
[1 mark]
11
ESSAY SECTION B
10 (a)
Soap and detergent are two cleansing agents that we used in our
daily life.
(i) Explain the cleansing action of soap on greasy stains.

[6 marks]
(ii) Explain why detergent is more effective than soap as a cleansing agent in hard
water. [5 marks]
(b)
Aspirin is an example of analgesic that should never be given
to children.
(i) What is meant by `analgesic`? [1 mark]
(ii) State two examples of analgesics besides aspirin. [2 marks]
(iii) Discuss four uses of aspirin and two side effects on health of using aspirin.
[6 marks]
11 (a) Alcohol Q contains 52.2% carbon, 13.0% hydrogen and 34.8% oxygen by mass.
(i) Determine the empirical formula and molecular formula of alcohol Q if the
-1
molar mass of alcohol Q is 46 gmol .
Relative atomic mass of H=1, C=12 dan O=16 [6 marks]
(ii) Draw the structural formula of alcohol Q. [1 mark]
(b) Describe how you could produce alcohol Q from glucose, C6H12O6.
[8 marks]
(c) Describe how you could produce an acid from alcohol Q in the laboratory. In your answer,
include the chemical equation for the reaction involved.
[5 marks]
12
ESSAY SECTION C
12 (a)
Sulphuric acid is an example of manufactured substance in industry that has
many uses in our daily life.
(i) State three uses of sulphuric acid. [3 marks]
(ii) Describe the process of producing sulphuric acid in industry. [7 marks]
(b) .
Steel and stainless steel are examples of alloys and their major metal is iron.
Describe how you could compare the rate of rusting between iron, steel and stainless steel.
Your answer should include tabulation of data and conclusion.
[10 marks]
13 Diagram below shows the convertion of organic compound X to Z and organic compound X
to Y.
Z Oxidation X Dehydration Gas

(C3H7OH) Y
a) Compound X can form a few isomers.

(i) What is meant by `isomer`?
(ii) Draw the structural formulae and name all the isomers of compound X.
[5 marks]
b) Gas Y can be obtained from compound X through dehydration reaction.

Describe how you could produce gas Y from compound X. In your answer, include
(i) a labelled diagram to show the set-up of apparatus
(ii) name of gas Y
(iii) a test to confirm the presence of gas Y.
[10 marks]
c) Compound X can be oxidized to compound Z. Compound X can react with Z to produce an ester.
(i) Name compound Z.
(ii) Write the chemical equation for the oxidation of compound X.
(iii) Name the ester that is formed from reaction betwen X and Z.
State two physical properties of the ester.
[5 marks]
13
Paper 3
14 The diagram below shows the apparatus set-up for an experiment to compare the elasticity properties of
vulcanised rubber and unvulcanised rubber.
Clip
Rubber strip
Ruler
Weight
An experiment is carried out using weights of 10g, 20g and 30g to get the increase in length of the
vulcanised rubber and the unvulcanised rubber.
The table below shows the results obtained from the experiment.
Types of rubber Vulcanised Unvulcanised

rubber rubber
Weights (g) 10 20 30 10 20 30
Initial length, l1 (cm) 8 8 8 8 8 8
Length after stretching, I2 (cm) 10 12 11 12 16 20
Increase in length, I2 –I1 (cm)
Increase in length after weight is removed. (cm) 8.5 9 9.5 10 12 14
a) Complete the table above based on the above experiment.

[3 marks]
b) State one hypothesis for this experiment.
…………………………………………………………………………………………………
………………………………………………………………………………………………....
…………………………………………………………………………………………………
[3 marks]
14
c) Based on the information above, complete the following table.
Name of variables Action to be taken

(i) Manipulated variable: (i) The way to manipulate variable:
…………………………………….. ………………………………………..
…………………………………….. ………………………………………...
(ii) Responding variable: (ii) What to observe in the responding variable:

………………………………………..
……………………………………
………………………………………..………
……………………………………
(iii) Controlled variable: (iii) The way to maintain the controlled variable:
…………………………………….. ………………………………………
…………………………………….. ………………………………………
[6 marks]
d) i) Based on the experiment above, which rubber strip is more elastic?
…………………………………………………………………………………………………………..
[3 marks]
ii) Explain your answer in (d) (i).
…………………………………………………………………………………………………………..
…………………………………………………………………………………………………………..
…………………………………………………………………………………………………………..
[3 marks]
e) Give the definition of vulcanised rubber?
…………………………………………………………………………………………………………………….
…………………………………………………………………………………………………………………….
[3 marks]
15
Copper wire in an electric cable can be bent with our bare hands. One cent shilling made from
the alloy of copper with tin and zinc cannot be bent easily.
Referring to the above situation, plan an experiment in the laboratory to investigate the effect of alloying
towards the hardness of pure metal.
Your planning should include the following:
(i) Statement of the problem
(ii) Hypothesis
(iii) Variables
(iv) List of substances and apparatus
(v) Procedures
(vi) Tabulation of data [17 marks]
15
Sample Answer
1
(a) (i) Dehydration 1
(ii) CnH2n+2 1
(b) (i) Hydrogenation / addition with hydrogen
(ii) Nicel/Platinum 1
(c) Add bromine water and shake 1
E decolourises the brown colour of bromine water.
D does not change the brown colour of bromine water. 1
(d) (i) Acidified potassium manganate(VII)/ Acidified potassium dichromate(VI) 1
(ii) Purple to colourless / orange to green. 1
(iii) C2H5COOH + Mg  (C2H5COO) 2Mg + H2
(e) (i) Propyl ethanoate 1
(ii) Catalyst
2 (a) (i) Alkene 1

(ii) Carbon dioxide 1
(iii) C2H4 + 3O2 → 2CO2 + 2H2O 1+1
(iv)
1 mol C2H4→2 mol CO2 //
0.5 mol C2H4 → 1 mol CO2 1
3 3
Volume of gas X / CO2 = 1 x 24 dm // 24 dm 1
(b) Orange to green 1

( c) (i) ethyl ethanoate 1
(ii) O
//
CH3-C – O – C2 H5 1
(iii) sweet smell 1
(d) Functional diagram 1

Label 1
12
3 (a) ethanol 1
(b) (i) ethane 1
(ii) Functional diagram 1
Label 1
(c) (i) Purple to colorless 1

(ii)
H O
H - C - C-O-H 1
H
(d) (i) catalyst 1
(ii) CH3CH2OH + CH3COOH CH3COOCH2CH3 + H2O 1
(iii) sweet smell 1
(iv) butyl ethanoate 1
10
16
4
a) Hydration
H H
b)
n C C
H H n 1
c) (i) Oxidation 1
(ii) Orange of to green 1
d) Propane 1
e) (i) Esterification 1
(ii)
H H O H H
H C C C O C C H
H H H H
1
(iii) Ethyl propanoate 1
f) Polypropane 1
g) The size of propane molecule is larger than ethane molecule 1
The intermolecular forces between propane molecules stronger than ethane 1
More energy is needed to overcome the forces between propane. 1
5 a(i) Sulphur and oxygen gas 1

(ii) S + O2 SO2 1
b (i) SO3 + H2SO4 H2S2O7 1

(ii) Dissolve SO3 in concentrated sulphuric acid 1
c Vanadium(v) oxide 1
d (i) 3H2 + N2 2NH3 1

o
ii) [450 C], [200 atm], Iron 1
e (i) Neutralization 1
(ii) H2SO4 +2 NH4OH (NH4)2SO4 +2H2O 1
(iii) Fertilizer 1
6
(a) Tin
(b) Atom
(c) (i) (ii)
Copper atom
Copper atom
Tin atom
(d) 1. Atoms of pure copper metal are the same size, they arranged orderly in layered pattern.
2. Layers of atoms are easily slide over each other when external force is applied on them.
3. Foreign atoms in alloy disrupt the orderly arrangement of metal atoms
17
4. Layers of metal atoms are prevented from sliding each other when external force is applied.
(e) (i) Tin
(ii) Improve appearance / prevent corrosion.
7 a) (i) Composite material 1

(ii) Add steel 1
b) H H
C=C
H Cl 1
f) (i) X : vanadium (v) oxide 1
Y : Oleum 1
(ii) S + O2 SO2 1
1
6
8 (a) hydrocarbon/ hydrophobic 1

(b)
Soap Detergent
Name of part Q Carboxylate Sulphonate
Sources Oil petroleum
Effectiveness in hard water Not effective Effective
1+1+1
(c) Cannot decomposed by microorganism 1

1
9 a)
i) Hydrophobic dissolve in organic solvent 1
Hydrophilic dissolve in water 1
ii) Soap forms scum with the presence of magnesium ion and calcium 1
ion.
Detergent does not form scum in hard water.
iii) Not biodegradable. 1
1
b) (i) Prevent food from being oxidized by oxygen in the oxygen in the air.
(ii) sodium benzoate 1
c) (i) Antidepressant 1
(ii) Tranquilizer / Barbiturate
1
1
9
18
SECTION B
10 (a) (i) 1. Soap anion consists of hydrophilic and hydrophobic. 1

2. Hydrophilic dissolves in water. 1
3. Hydrophobic dissolves in oils/grease. 1
4. Soap reduces surface tension of water. 1
5. Hydrophobic emulsify oil or grease. 1
6. During rinsing, soap will remove the grease 1….6
2+ 2+
(ii) 1. Hard water contains calcium ions/Ca and magnesium ions/ Mg
1
2+
2. Soap anions react with calcium ions/Ca or magnesium ions/
2+
Mg to form scum 1
3. Scum is insoluble in water 1
4. Waste soap 1
5. Detergent does not form scum 1....5
(b) (i) Medicine used to relieve pain without causing numbness or

affecting consciousness 1…1
(ii) Paracetamol 1
Codeine 1…2
(iii) 1. Relieves pain caused by headache, toothache

2. Reduces fever
3. Treat arthritis /reduce inflammation of the joints
4. Reduces blood clotting / prevents stroke / prevents heart
attacks
a. Reduces inflammation caused by infection or injury
(any four) 1+1+1+1....4
1. Causes internal bleeding of the stomach / Ulceration

2. Causes brain / liver damage if given to children
3. Overdose causes death
(any two) 1+1....2
20
11
(a) Element C H O
1. Number of moles 52.2 13.0 34.8 1
of atoms 12 1 16
=4.35 =13.0 =2.175
2. Ratio 2 6 1 1
3. Empirical formula of Q is C2H6O 1

Relative molecular mass of (C2H6O) n = 46
4. 2n(12) + 6n(1) + n(16) = 46 1
46n = 46
5. n=1 1
6. Molecular formula of Q is C2H6O / C2H5OH 1
7. Structural formula is
H H
 
H - C - C -OH
 
H H 1....7
19
(b) 1. Add glucose into a conical flask. 1
2. Add water. 1
3. Add yeast. 1
4. Close the conical flask 1
5. Leave the flask for 1 to 3 days. 1
6. Filter the content 1
7. Distille the filtrate 1
0
8. Collect the fraction that boils at 78 -80 C 1....8
(c) 1. Add alcohol Q in a test tube. 1

2. Add acidified potassium manganate (VII) solution 1
3. Heat the solution. 1
4. The purple colour of the solution turns colourless 1
5. [Chemical equation] 1....5
20
SECTION C
12 ( a)(i) 1. Manufacture fertilisers
2. Manufacture detergents
3. As an electrolyte in car batteries
4. Manufacture paint pigments
5. Synthetic fibres
6. Plastics
7. Clean metals
8. Pesticides
[any 3 above] 1+1+1....3
(ii) 1. Sulphur is burnt in the air // Zinc sulphide is burnt to produce sulphur
dioxide // Equation
S + O2 SO2 //
2ZnS + 3O2 2ZnO + 2SO2 1
2. Sulphur dioxide react with oxygen to produce sulphur trioxide // Equation
2SO2 + O2 2SO3 1
3. Catalyst: vanadium(V) oxide 1
o
4. Temperature: (400 – 500 C) 1
5. Pressure: 1 atm 1
6. Sulphur trioxide reacts with concentrated sulphuric acid to produce
oleum // Equation:
SO3 + H2SO4 H2S2O7 1
7. Oleum is diluted with water to produce sulphuric acid // Equation
H2S2O7 + H2O 2H2SO4 1..7
b) 1. Material: iron nail, steel nail, stainless steel nail, jelly solution, potassium
hexacyanoferrate(III) solution 1
2. Apparatus: Test tubes, test tube rack 1
3. Put iron nail in test tube A, steel nail in test tube B and stainless steel in
test tube C 1
4. Add jelly solution and a few drops of potassium hexacyanoferrate(III)
solution into the test tubes 1
5. Pour the jelly solution until the nails are fully immersed 1
6. Leave the test tubes for 2-3 days 1
20
7. Observation 1
Test tube Intensity of blue colour

A (Iron nail) High
B (Steel nail) Low
C (Stainless steel nail) Nil
8. Potassium hexacynoferrate(III) solution to detect iron(III) ions 1

9. The higher the intensity of the blue colour, the higher the rate of rusting 1
10. Rate of rusting of iron is the highest follow by steel and stainless steel
does not rust 1..10
20
13
(a) Isomers are molecules/compounds which have same molecular 1
formulae but different structural formulae.
H H H H OH H
│ │ │ │ │ │
H─C─ C ─ C─ OH H – C─ C ─ C ─ H
│ │ │ │ │ │ 1+1
H H H H H H 1+1..5
Propan-1-ol Propan-2-ol
(b) 1. Functional set-up of apparatus 1

2. Label 1
3. Place the glass wool in a boiling tube. Add propanol/C3H7OH to the
glass wool. 1
4. Place the porcelain chips in the tube. 1
5. Heat the porcelain strongly. 1
6. Heat the glass wool. 1
7. Collect gas Y using test tube. 1
8. Gas Y is propene. 1
9. Add bromine water (acidified potassium manganate(VII) solution) to
the test tube. 1
10.Brown colour of bromine decolourised (purple colour of potassium
manganate(VII) decolourised) 1..10
(c) (i) X –propanoic acid 1

(ii) C3H7OH + 2[O] → C2H5COOH + H2O 1
(iii) Ester –propyl propanoate 1
Sweet pleasant smell (fruity smell)

Less dense than water
Insoluble in water
Colourless liquid
Volatile
(any two) 1+1..5
20
21
Paper 3
14 (a) To measure using numbers
Score Explanation
3 Able to record all the six readings correctly.
Suggested answer
Vulcanised rubber: 2, 4, 6
Unvulcanised rubber: 4, 8, 12
1(b) To make hypothesis

Score Explanation
3 Able to relate between the manipulated variable and the responding variable.
Suggested answer
Vulcanised rubber is more elastic than the unvulcanised rubber// Unvulcanised rubber is
less elastic than the vulcanised rubber
1(c) To control variable

Score Explanation
Suggested answer
6 Variable Action to be taken
(i) Manupilated variable (i) The way to manupilate variable
Vulcanized and unvulcanized Repeat by replacing vulcanized rubber with
rubber// Mass of weight unvulcanized rubber//Use weights with
different masses
(ii) Responding variable (ii) What to observe in the responding variable
Increase in length of rubber To measure length of rubber strip
strip//elasticity
(iii) Fixed variable (iii) The way to maintain the controlled variable
Initial length of rubber strip Use the same length of vulcanized and
unvulcanized rubber strips
1(d) To make inference

Score Explanation
3 Able to make the correct inference
Suggested answer:
(i) Vulcanized rubber
(ii) Presence of the sulphur cross links between the chain of rubber polymers in
vulcanized rubber makes the small increase in length and can return to its
original length after stretching.
1(e) Operational definition:

Score Explanation
3 Able to make an operational definition correctly:
Suggested answer:
Rubber that can stretch a bit and returns to its original length when not stretched.
22
15
Rubric Scor e
(i) [Able to give the correct problem statement.] 3
Suggested answer:
How does alloying affects the hardness of metal?//What is the effect of
alloying towards the hardness of metal?
(ii) [Able to state all the variables correctly] 3
Suggested answer:
Manipulated variable: metal and its alloy//copper and brass/bronze// iron
and steel
Responding variable: size/diameter of dent

Fixed variable : Mass of weight//height of weight//type of metal of
ball bearing// size of ball bearing
(iii) [Able to list completely the substances and apparatus] 3
Example:
Metal (named), its alloy(named)
Steel ball bearing, weight, ruler, rope/thread, retort stand
(iv) [Able to state the procedures correctly] 3
Example:
1. Put a ball bearing on a metal block/its alloy.
2. Hang a weight until (50-100 cm) above the metal block/its alloy
3. Let the weight fall.
4. Measure and record the diameter of the dent formed.
5. Repeat the activity a few more times
6. Repeat steps 1 – 5 by replacing the metal with its alloy// alloy wits
metal
(v) [Able to show the correct tabulation of data] 3
Table with the following elements:
1. 4 colums and 3 rows
2. Titled metal (named), its alloy (named), diameter (with unit),
Average (with unit)
Example
Diameter (cm) Average(cm)
1 2
Metal (named)
Alloy(named)
23

KIMIA SET 4 Perfect Score

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Set 4 Chemistry Perfect Score Module 2007

Heat gently with ethanoic acid and

(a) (i) Name process reaction I

(c) Describe a chemical test to distinguish compound D and E.

(e) (i) A compound Y is formed in process IV. Name the compound Y

Compound L Complete combustion in air Gas X + H2O

(a) (i) Name the homologous series to which L belong.

(c) Compound J reacts with compound K to form compound M.

(i) Name compound M.

(d) Draw the set up of apparatus used in process II.

3 The diagram below shows the chemical reaction of compound X.

Acidified potassium manganate (VII)

(a) Name compound X.

(ii) What is the use of porous pot chips in process I?

(ii) Draw the structural formula of Y.

(i) What is the use of concentrated sulphuric acid?

(ii) Write a balanced chemical equation for the reaction.

(iv) X is replaced with butanol. Name the product formed.

C2H5OH C2H5 COOH

C2H4 Compound P [ 2 marks]

c)(i) Name process 2.

(i) Name the process for the formation of the compound.

Contact Process Suphuric acid

Haber Process Ammonia

(a) (i) Sulphur dioxide is produced at the stage I of contact process.

(ii) Write a chemical equation for the reaction in (a) (i)

(b) In Contact Process, oleum is produced.

(i) Write the chemical equation for the formation of oleum.

(c) Name the catalyst used in Contact Process.

(i) Name the reaction A.

(ii) Write the chemical equation for reaction A.

(iii) What is the use of compound X in daily lives?

(a) Name the main element added to copper to form bronze.

(b) What type of particles is present in pure copper?

(c) Draw an arrangement of the particles in

(i) Pure copper

(d) Explain why is bronze is harder than pure copper?

(e) (i) Name the major component of pewter.

(ii) Beside hardness, state another purpose of alloying to produce pewter.

Type of manufactured Example Component

P Reinforced concrete Cement, sand, small pebbles and

Alloy Brass Copper and zinc

Polymer S Vinyl chloride

(a) (i) Name the type of substance P.

Draw the structural formula for monomer S.

Sulphuric acid Compound Y

(i) Name compound X and Y.

Part P Part Q Part P Part Q

Effectiveness in hard water

a) The diagram shows the structural formula of a soap

CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2

i) State the property of hydrophobic and hydrophilic part of soap molecule.

b) Preservative and antioxidant are two types of food additive.

(i) Explain the cleansing action of soap on greasy stains.

(i) What is meant by `analgesic`? [1 mark]

(ii) State two examples of analgesics besides aspirin. [2 marks]

(ii) Draw the structural formula of alcohol Q. [1 mark]

(i) State three uses of sulphuric acid. [3 marks]

(ii) Describe the process of producing sulphuric acid in industry. [7 marks]

Z Oxidation X Dehydration Gas

a) Compound X can form a few isomers.

b) Gas Y can be obtained from compound X through dehydration reaction.

Types of rubber Vulcanised Unvulcanised