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  • Results PFR

    Enviado por

    Muhammad Arshad
    10 visualizações3 páginas
    The document describes an experiment investigating the effect of residence time on a chemical reaction. Various flow rates of sodium hydroxide and ethyl acetate solutions were used to achieve different residence times in a reactor. The results show that conversion of the reaction increased with longer residence times up to a point, then levels off, with the highest conversion around 90% achieved at a residence time of 40 minutes. Calculations are shown for determining conversion, rate constants, and rates of reaction based on titration experiments analyzing samples from the reactor. A graph plots the relationship between conversion and residence time from the experimental results.

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    OUR GROUP RESULTS

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    The document describes an experiment investigating the effect of residence time on a chemical reaction. Various flow rates of sodium hydroxide and ethyl acetate solutions were used to achieve different residence times in a reactor. The results show that conversion of the reaction increased with longer residence times up to a point, then levels off, with the highest conversion around 90% achieved at a residence time of 40 minutes. Calculations are shown for determining conversion, rate constants, and rates of reaction based on titration experiments analyzing samples from the reactor. A graph plots the relationship between conversion and residence time from the experimental results.

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    © All Rights Reserved
    Baixe no formato DOCX, PDF, TXT ou leia online no Scribd
    Sinalizar o conteúdo como inadequado
    10 visualizações3 páginas

    Results PFR

    Enviado por

    Muhammad Arshad
    The document describes an experiment investigating the effect of residence time on a chemical reaction. Various flow rates of sodium hydroxide and ethyl acetate solutions were used to achieve different residence times in a reactor. The results show that conversion of the reaction increased with longer residence times up to a point, then levels off, with the highest conversion around 90% achieved at a residence time of 40 minutes. Calculations are shown for determining conversion, rate constants, and rates of reaction based on titration experiments analyzing samples from the reactor. A graph plots the relationship between conversion and residence time from the experimental results.

    Direitos autorais:

    © All Rights Reserved
    Baixe no formato DOCX, PDF, TXT ou leia online no Scribd
    Sinalizar o conteúdo como inadequado
    de 3

    1.

    Results

    Experiment 3 : Effect of Residence Time on the Reaction


    Total flow
    No
    .

    Flow rate

    Flow rate

    rate of

    of NaOH

    of Et(Ac)

    solutions,

    (mL/min)

    (mL/min)

    Vo

    Residence
    Outlet
    time,

    conductivity
    (mS/cm)

    (mL/min)

    (min)

    Reaction
    Conversion,
    X (%)

    Rate
    Constant
    (L/mol.min)

    Rate of
    Reaction,
    (mol/L.min)

    300

    300

    600

    6.67

    6.6

    86.8

    19.7273

    8.5932 X 10-4

    250

    250

    500

    8.00

    6.7

    72.8

    8.0294

    1.4851 x 10-3

    200

    200

    400

    10.00

    6.7

    58.8

    4.2816

    1.8169 x 10-3

    150

    150

    300

    13.33

    5.7

    79.00

    11.2857

    1.2443 X 10-3

    100

    100

    200

    20.00

    4.8

    93.8

    45.3871

    4.3617 X 10-4

    50

    50

    100

    40.00

    4.6

    83.2

    14.857

    1.0483 X 10-3

    2.0

    Calculations

    Total flowrate solution = 600 ml/min


    Reactor volume

    :4L

    Volume of sample, Vs

    : 0.05 L

    Concentration of NaOH in feed vessel, CNAOH, f

    : 0.1 mol/L

    Concentration of ethyl acetate in feed vessel, CEA,O : 0.1 mol/L


    Volume of HCl for quenching, VHCl, s

    : 10 ml

    Concentration of HCl in standard solution, CHCL, S

    : 0.25 mol/L

    Volume of titrated NaOH, V1

    : 21.7 ml

    Concentration of NaOH used for titration, CNaOH,s

    : 0.1 mol/L

    1. Concentration of NaOH entering reactor, CNaOH, o = (CNaOH, f) 2


    0.1 mol/L 2 = 0.05 mol/L
    2. Volume of unreacted quenching HCl, V2 = (CNaOH,s CHCl,s) V1
    (0.1 mol/L 0.25 mol/L) 21.7 ml = 8.68 ml
    3. Volume of HCl reacted with NaOH in sample, V3 = VHCl,s V2

    10 ml 8.68 ml = 1.32 ml / 0.0013 L


    4. Moles of HCl reacted with NaOH in sample, n1 = CHCl,s V3
    0.25 mol/L 0.0013 L = 0.00033 mol
    5. Moles of unreacted NaOH in sample, n2 = n1
    n2 = 0.00033 mol
    6. Concentration of unreacted NaOH in reactor, CA = n2 VS
    0.00033 mol 0.05 L = 0.0066 mol/L
    7. Conversion of NaOH in reactor, X = (1 (CNaOH CNaOH,O)) 100%
    (1 (0.0066 mol/L 0.05 mol/L) ) 100% = 86.8 %

    8. Residence time,

    V TFR
    V0

    4000 ml 600 ml/min = 6.67 min

    9. Reaction rate constant,

    0.6 L/min
    (4 L)(0.05 mol / L)

    k=

    Vo
    V TFR C

    AO

    [ ]
    X
    1 X

    0.868
    (10.868)

    = 19.7273 L/mol.min

    10. Rate of reaction, -rA = k (CA0)2 (1-X)2


    -rA = 19.7273 L/mol.min (0.05mol/L)2(1-0.868)2 = 8.593210-4 mol/L.min

    Conversion against Residence Time

    Conversion (%)

    100
    90
    80
    70
    60
    50
    40
    30
    20
    10
    0

    Y-Values

    10 15 20 25 30 35 40 45 50
    Residence Time (min)

    Figure 8.1: Graph of conversion (%) against residence time (min) obtained from different total
    flowrates of solution

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