t (min) Grfico de los residuales

0.08

0.06

0.04

0.02

Residuos

0
0

20

40

60

80

-0.02

-0.04

-0.06

-0.08
t (min)

100

120

140

160

t (min) Curva de regresin ajustada

0.0000
0

20

40

60

80

100

120

140

160

-0.5000

-1.0000

Log [EtAc]
Log [EtAc]

-1.5000

Pronstico Log [EtAc]

-2.0000

-2.5000

-3.0000
t (min)

Resumen
Estadsticas de la regresin
Coeficiente de0.99170024
Coeficiente d 0.98346937
R^2 ajustado 0.98140304
Error tpico
0.04032785
Observacione
10
ANLISIS DE VARIANZA
Grados de libertad
Suma de cuadrados
Promedio de los cuadradosF
Valor crtico de F
Regresin
1 0.77405449 0.77405449 475.949991 2.0555E-008
Residuos
8 0.01301069 0.00162634
Total
9 0.78706518
Coeficientes Error tpico Estadstico t Probabilidad Inferior 95%
Intercepcin -0.33509524 0.0190653 -17.5761858 1.1216E-007 -0.3790599
t (min)
-0.00567011 0.0002599 -21.8162781 2.0555E-008 -0.00626944

Anlisis de los residuales

Observacin
Pronstico Log [EtAc]
Residuos
Residuos estndares
1 -0.33509524 -0.01153014 -0.30325343
2 -0.36401279 0.01738741 0.45730503
3 -0.39344064 0.03767829 0.99097413
4 -0.44963141 0.01289885 0.33925181
5 -0.50519846 -0.00401743 -0.10566205
6 -0.6188841 0.00624545 0.16426121
7 -0.73239965 -0.03969309 -1.04396523
8 -0.84285334 -0.0702603 -1.84791148
9 -1.01295655 -0.01376777 -0.36210527
10 -1.18833297 0.06505873 1.71110529

Resultados de datos de probabilida

Percentil
5
15
25
35
45
55
65
75
85
95

crtico de F

Superior 95%Inferior 95.0%

Superior 95.0%
-0.29113058 -0.3790599 -0.29113058
-0.00507077 -0.00626944 -0.00507077

Grfico de
0
Log [EtAc]

ultados de datos de probabilidad

-0.5
-1
-1.5

Log [EtAc]
-1.12327424
-1.02672433
-0.91311364
-0.77209274
-0.61263865
-0.50921588
-0.43673255
-0.35576236
-0.34662538
-0.34662538

10

Grfico de probabilidad normal

0
Log [EtAc]

-0.5

10

20

30

40

50

60

-1
-1.5
Muestra percentil

70

80

90

100

W BHK

M BHK

g
0.4785
0.4785
0.4785
0.4785
0.4785
0.4785
0.4785
0.4785
0.4785
0.4785

g/mol
204.22
204.22
204.22
204.22
204.22
204.22
204.22
204.22
204.22
204.22

Vg NaOH NC NaOH
mL
5
5
5
5
5
5
5
5
5
5

0.468612
0.468612
0.468612
0.468612
0.468612
0.468612
0.468612
0.468612
0.468612
0.468612

Vtit HCl

Vg NaOH

[HCl]

D 20 EtAc

5
5
5
5
5
5
5
5
5
5

10.6
10.6
10.6
10.6
10.6
10.6
10.6
10.6
10.6
10.6

0.9935
0.9935
0.9935
0.9935
0.9935
0.9935
0.9935
0.9935
0.9935
0.9935

(g/mL)
0.9003
0.9003
0.9003
0.9003
0.9003
0.9003
0.9003
0.9003
0.9003
0.9003

T AcEt

D 36 EtAc

T AcEt

V EtAc

M EtAc

C
20
20
20
20
20
20
20
20
20
20

0.001389
0.001389
0.001389
0.001389
0.001389
0.001389
0.001389
0.001389
0.001389
0.001389

(g/mL)
0.8807
0.8807
0.8807
0.8807
0.8807
0.8807
0.8807
0.8807
0.8807
0.8807

C
36
36
36
36
36
36
36
36
36
36

mL
5.0000
5.0000
5.0000
5.0000
5.0000
5.0000
5.0000
5.0000
5.0000
5.0000

g/mol
88.106
88.106
88.106
88.106
88.106
88.106
88.106
88.106
88.106
88.106

W EtAc

n EtAc

V_final

g
4.4036
4.4036
4.4036
4.4036
4.4036
4.4036
4.4036
4.4036
4.4036
4.4036

mol
mL
0.049981
100
0.049981
100
0.049981
100
100
0.049981
100
0.049981
100
0.049981
100
0.049981
100
0.049981
100
0.049981
100
0.049981

[EtAc] inicial
mol/L
0.4998
0.4998
0.4998
0.4998
0.4998
0.4998
0.4998
0.4998
0.4998
0.4998

[HCl] inicial

mol/L
0.9437851337
0.9437851337
0.9437851337
0.9437851337
0.9437851337
0.9437851337
0.9437851337
0.9437851337
0.9437851337
0.9437851337

0
1
2
3
4
5
6
7
8
9

0.5000
0.4500

f(x) = 0.46227713
R = 0.983470353

0.4000
0.3500
0.3000
0.2500
0.2000
0.1500
0.1000
0.0500
0.0000
0

20

40

Vgastado
NaOH (mL)

min
0
5.1
10.29
20.2
30
50.05
70.07
89.55
119.55
150.48

10.6
10.6
10.7
11.5
12.1
12.8
13.6
14.1
14.4
14.6

V titular
Solucion
mL
5
5
5
5
5
5
5
5
5
5

[HCl+HAc] [HAc]
(mol/L)
0.9934
0.9934
1.0028
1.0778
1.1340
1.1996
1.2746
1.3215
1.3496
1.3683

formado

(mol/L)
0.0496
0.0496
0.0590
0.1340
0.1902
0.2558
0.3308
0.3777
0.4058
0.4245

[EtAc]
libre
(mol/L)
0.4502
0.4502
0.4408
0.3658
0.3096
0.2440
0.1690
0.1221
0.0940
0.0753

0.5000
0.4500

-7.50

f(x) = 0.4622771328 exp( -0.0130562067 x )

R = 0.9834703539

0.4000

-7.00

0.3500

f(x) =
R = 0

0.3000
0.2500

Column Z

0.2000

Exponential (Column Z)

0.1500
0.1000
0.0500
0.0000
0

20

40

60

80

100

120

140

160

ln
velocidad

velocidad
0.0060
0.0056
0.0053
0.0046
0.0041
0.0031
0.0024
0.0019
0.0013
0.0008
pendiente
orden
-7.50

Ln [EtAc]
libre

-5.1143
-5.1806
-5.2481
-5.3769
-5.5043
-5.7650
-6.0253
-6.2785
-6.6685
-7.0706
0.9792
1.0000

-7.00

-6.50

-0.7981
-0.7981
-0.8192
-1.0056
-1.1725
-1.4107
-1.7778
-2.1026
-2.3642
-2.5865
-0.0131
0.0131 k
-6.00

-5.50

0.00
-5.00
-0.50

0.0000
0
-0.5000

f(x) = 1.0043235949x + 4.3648688216

R = 0.9834703539

-1.00
-1.50
-2.00

-1.0000
-1.5000
ln [EtAc]
free
-2.0000
-2.5000

Column AC

-2.50
-3.0000
-3.00

f(x) =
R =

Ln [EtAc] free vs t (min)

0.0000
0

20

40

60

80

100

-0.5000
-1.0000

f(x) = - 0.0130562067x - 0.7715907132

R = 0.9834703539

-1.5000
ln [EtAc]
free
-2.0000
-2.5000
-3.0000
t (min)

120

140

160