FUNDAO COMUNITRIA DE ENSINO SUPERIOR DE ITABIRA - FUNCESI

FACULDADE DE CINCIAS ADMINISTRATIVAS E CONTBEIS DE ITABIRA - FACCI

Elberto Vital do Carmo

EXERCCIOS 5 TERMOQUMICA

Disciplina: Qumica Geral Prtica

Curso: Engenharia de Produo
Turma: 1 Perodo - A
Professora: Graciane Fonseca

ITABIRA-MG
2014

1 - Se uma mquina realiza 4,8 x 10 3 kJ de trabalho aps uma entrada de 7,31 x 10 4 kJ de

calor, qual a variao de energia interna da mquina?
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2 - Qual sistema realiza mais trabalho?
a) E = -43 J, q = 400 J
b) E = 31 J, q = 347 J
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3 - Um aquecedor metlico feito de 26,0 kg de ferro. O calor especfico do ferro 0,449
J/g.C. Quanto calor deve ser fornecido ao aquecedor para aumentar a sua temperatura de
25,0 para 55,0 C?
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4 - O material normalmente usado para esquentar aquecedores metlicos a gua. Se
uma caldeira gera gua a 79,5 C, qual a massa de gua necessria para fornecer o calor
exigido no problema anterior? A gua tem um calor especfico de 4,184 J/g.C.
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5 - Uma moeda de cobre de 7,3 g est a uma temperatura de 18,8 C. Esta moeda
colocada em 10,0 g de gua a uma temperatura de 54,0 C. Qual a temperatura final da
moeda e da gua, supondo que nenhum calor perdido para as vizinhanas?
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6 - Usando os calores de formao tabulados, calcule os calores de reao para o
seguinte:
a) C2H2(g) + 5/2 O2(g) 2 CO2(g) + H2O(l)
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b) PCl3(g) + Cl2(g) PCl5(g)
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c) C2H4(g) + H2O(g) C2H5OH(g)
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d) Fe2O3(s) + 2 Al(s) Al2O3(s) + 2 Fe(l)
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Espcie
Hf (kJ/mol)
Espcie
Hf (kJ/mol)
C2H2(g)
226,7
C2H4(g)
52,26
CO2(g)
- 393,5
H2O(g)
- 241,8
H2O(l)
- 285,8
C2H5OH(g)
- 235,1
PCl3(g)
- 306,4
Fe2O3(s)
- 824,2
PCl5(g)
- 398,9
Al2O3(s)
- 1676
7 - Considere as seguintes reaes hipotticas:
A B H = 30 kJ e B C H = 60 kJ
Use a lei de Hess para calcular a variao de entalpia para a reao A C.
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8 - Dadas as seguintes reaes:
P4(s) + 3 O2(g) P4O6(s) H = - 1.640,1 kJ
P4(s) + 5 O2(g) P4O10(s) H = - 2.940,1 kJ
Calcule a variao de entalpia para a reao:
P4O6(s) + 2 O2(g) P4O10(s)
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9 - A partir das entalpias de reao:
H2(g) + F2(g) 2 HF(g) H = - 537 kJ
C(s) + 2 F2(g) CF4(g) H = - 680 kJ
2 C(s) + 2 H2(g) C2H4(g) H = 52,3 kJ
Calcule o H para a reao do etileno com o F 2:
C2H4(g) + 6 F2(g) 2 CF4(g) + 2 HF(g)
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10 - A mudana de fases entre grafite e diamante difcil de observar diretamente. No
entanto, ambas as substncias podem ser queimadas. Com base nas seguintes equaes,
calcule o H para a converso do grafite em diamante.
C(s,grafite) + O2(g) CO2(g) H = - 393,51 kJ
C(s,diamante) + O2(g) CO2(g) H = - 395,94 kJ
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11 - Para a reao N2(g) + O2(g) 2 NO(g) H = 180,5 kJ, qual a energia necessria para
gerar 35 mols de NO(g)?
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12 - O silano, SiH4, queima-se de acordo com a seguinte reao: SiH 4 + 2 O2 SiO2 + 2
H2O, com H = - 1429 kJ. Qual a energia liberada se 15,7 g de silano so queimados?
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