Metodos electricos

W =G=n . F . E
o

G= G + RT .lnQ
E =Eo

[ analito ]
0,0592
log (
)
n
[ analito ox ]

anod
Ecelda=E cat
E

I L =6,07.104 . n .Cs . ( Dm ) 2 . tg 6 . mg 3
0

E=E[ M

+n

/M

( )

a M ( Hg)
0,0592
0,0592
I

log
=E 1/ 2
log (
)
]
0
n
n
I L I
aM
+n

Metodos pticos

A=log ( T )=log ( P/ P0 )= .b . C
Cromatografia

N=L/ H

H= 2 /L
=4 w
2

N=

16 L 16 t r
=
2
2
w
w

k =

R=

Vs . Cs tr
=
Vm . Cm tm

nm
1
=
nm+ns 1+k

R .u=u A
tr A =tm .(1+k A )

Rs=

trB tr A N 1
k2
=
.
.
wA+ wB
4

1+k 2
2

( )(

2 ( 1+ k B ) H
tr B=16. R s .
.
.
2
1
u
k B
2

( )

B
H= A+ +Cs . u+Cm . u
u
A=2. . dp
B=2. . Dm

2
k
df2
Cs= .
.
3 ( k +1 )2 Ds
2

Cm=

J .d p
Dm