PREGUNTA 1

CH3
a)

O
H2C

O
H
B

CH3
A
S

O-

CH3

b)

CH3

S-

C S

H3C

H3C

H3C

COCl

CONH2

CH2NH2

c)

Br

MgBr

OH

d)

COOH
K

NH2

CONH2

M
L
e)

COOH

H3C

H3C

COCl
N

f)

NaOH conc.

BH3THF

OH

OH

OH
Br

LDA (2 eq)

Br
S

H3O+

O
O

O
U
O

Et

Br2, P(cat)

N
Et

H3C

O
O

CONEt2

H3C

OH
OH

W
C8H14O2

g)

HO

KMnO4

H2O, OH

1. CH3Li

2. H3O+

HO
OH

PREGUNTA 2
a)
HO

Me

OMe

OH

Me

Cl

O
O
A
b)
Br

C
F

O
I

PREGUNTA 3

NH2
K

Cl

OH

N
J

PREGUNTA 4

CO2H

BH3THF

CH2OH

H+

OH

1) LiAlH4, THF
2) H3O+

OH

CO2H

O
PREGUNTA 5
KMnO4 conc.

COOH

HOOC

1) LiAlH4
2) H3O+

a)
Cl2SO

CH2OH

HOH2C
H3O+

NaCN
acetona

COOH

HOOC

COOH

Br
b)

CH2Cl

ClH2C

H3O

NaCN
acetona

c)

Mg

CO2

CH3

KMnO4/H2O

Br

d) Cl

e)

BuMgBr

CN

H3O+

Cl

COOH

CH2N2

COOH

H3O+
O

PREGUNTA 6
O
O
H3C

CH3

1) LiAlH4
2) H3O+

OH
H3C

O
1)BrMgMe (exc)
2) H3O+

HNO3, H2SO4

H3C

H3C

CH3
OH

H3C

O
O2N

CH3

Cl

COOCH
3