Qumica Orgnica II, Soluciones Seminario 3

Curso 2014/15

6.COMPUESTO DE ADICIN DE MICHAEL

DONADOR DE ELECTRONES
O

H
O

O
O

N+
O

N+
O

O
N+
O

OEt

O
N+

OEt

ACEPTOR DE ELECTRONES

OEt
H

O
H
O

EtO

OEt

O
N+

OEt
H

O
N+

7.OH

+H+
-H+

OH OH

H
O H -H O
2

HO

+H2O
H

H
O

-H2O

OH

OH

+H2O

O H
H

8.O
H

Na*

O-

O
ETO-Na+

ETOH

O-

O
H
H

Na*
H

ETO-Na+

ETOH

Na*

H
ETO-Na+

ETOH

Na*

O
ETO-Na+

ETOH

O
O

Na*

ETO-Na+

ETOH

Na*

ETO-Na+
H
O

ETOH

O
OEt

ETO-Na+

Na*

O
OEt

OEt

H
O

ETOH

Na*
H

ETO-Na+

Na*

O
O

C N

ETO-Na+

ETOH

O-

C N
ETOH

C N
Na*

C N

C N

O
ETO-Na+
O

ETOH

O
O

C
N

C N

O
O
C N
O

Na*
O

C N

H
O

O
H

C N

ETO-Na+

ETOH

C
N

C N
Na*

ETO-Na+
O

O-

N
-O

O
C
N

ETOH