Flujo Tapn de Primer Orden

Valores iniciales

Tipo
de
Mineral
Cobre

Conc.
No.

Tiempo, t
(seg)

1
2
3
4
5
6
7
8
9
10

Factor
1

0.7137

k =

0.0192
Ensaye

20

Conc.
Masa
(g)
24.9

40
60

15.0
13.2

1.93
1.80

120

35.2

1.34

300

63.3

0.16

Colas

885.2

0.08

1036.8

0.24

Cab. Calc

Recuperacin (%)

Rinf =

(%)
2.47

Flujo Tapn de Primer Orden R = Rinf [1- exp(-kt)]

1

0.8

0.6

0.4

0.2

0
0

100

200
Tiempo de Flotacin (s)

0
0

100

200
Tiempo de Flotacin (s)

R = Rinf [ 1 - exp(-kt)]

(fraccin)
s

Masa inicial :

1036.8

-1

Ensaye
(%)

Cobre
Masa
(g)

2.47
1.93
1.80
1.34
0.16
0.00
0.00
0.00
0.00
0.00
0.08
0.2

0.62
0.29
0.24
0.47
0.10
0.00
0.00
0.00
0.00
0.00
0.72
2.44

Recovery (Cobre)
(exp)
(calc)
Re
Rc

Masa
Acum(%)

0.62
0.90
1.14
1.62
1.72
0.00
0.00
0.00
0.00
0.00

0.2522
0.3711
0.4688
0.6625
0.7045
0.0000
0.0000
0.0000
0.0000
0.0000

0.2274
0.3824
0.4880
0.6423
0.7114
0.0000
0.0000
0.0000
0.0000
0.0000

0.0248

0.0113
0.0192
0.0202
0.0069
0.0000
0.0000
0.0000
0.0000
0.0000

2.44

Suma de Error al Cuadrado

er Orden R = Rinf [1- exp(-kt)]

Exp data
Model

200
Tiempo de Flotacin (s)

Re-Rc
(dif)

300

400

200
Tiempo de Flotacin (s)

300

400

Flujo Tapn

(dif)^2

0.00061
0.00013
0.00037
0.00041
0.00005
0.00000
0.00000
0.00000
0.00000
0.00000
0.0016

ma de Error al Cuadrado

Tiempo
(s)
0
10
20

Recuperacin

30
40

0.31
0.38

50

0.44

60
70
80
90
100

0.49
0.53
0.56
0.59
0.61

110

0.63

120

0.64

130

0.65

140
150
160
170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340

0.67
0.67
0.68
0.69
0.69
0.70
0.70
0.70
0.70
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71

0.00
0.12
0.23

350
360

0.71
0.71

Modelo de Mezclado Perfecto

Rinf =
K
=

Tipo
de
Mineral
Cobre

Conc.
No.

Tiempo, t
(seg)
1
2
3
4
5
6
7
8
9
10

Factor
1

(fraccin)
s-1

Ensaye

20
40
60
120
300

Conc.
Masa
(g)
24.9
15.0
13.2
35.2
63.3

Colas

885.2

0.08

0.08

1036.8

0.24

0.24

Cab. Calc

Recupe racin (%)

0.8449
46.36

(%)
2.47
1.93
1.80
1.34
0.16

Cobre
Ensaye
(%)
2.47
1.93
1.80
1.34
0.16
0.00
0.00
0.00
0.00
0.00

Modelo de Mezclado Perfecto R = Rinf {1 - [1/(1+(t/k))]}

1

0.8

0.6

0.4

0.2

0
0

50

100

150
200 (s)
Tie m po de Flotacin

250

300

R = Rinf {1 - [1/(1 + (t/k))]}

Masa Inicial :

Cobre
Masa
(g)
0.62
0.29
0.24
0.47
0.10
0.00
0.00
0.00
0.00
0.00

Recovery (Cobre)
(exp)
(calc)
Re
Rc
0.2522
0.2547
0.3711
0.3914
0.4688
0.4767
0.6625
0.6095
0.7045
0.7319
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000

Masa
Acum(%)
0.62
0.90
1.14
1.62
1.72
0.00
0.00
0.00
0.00
0.00

0.72

2.44

2.44

Re-Rc
(dif)

(dif)^2

0.0025
0.0203
0.0079
0.0530
0.0273
0.0000
0.0000
0.0000
0.0000
0.0000

0.00001
0.00041
0.00006
0.00281
0.00075
0.00000
0.00000
0.00000
0.00000
0.00000

Suma de Error al Cuadrado

expt
data

250

0.0040

= Rinf {1 - [1/(1+(t/k))]}

00 (s )
cin

1036.8

300

350

400

Modelo de Mezclado Perfecto

Tiempo
Recuperacin
0

0.00

10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190

0.15
0.25
0.33
0.39
0.44
0.48
0.51
0.53
0.56
0.58
0.59
0.61
0.62
0.63
0.65
0.66
0.66
0.67
0.68

200

0.69

210
220
230
240
250
260
270
280
290
300
310
320
330
340
350

0.69
0.70
0.70
0.71
0.71
0.72
0.72
0.72
0.73
0.73
0.74
0.74
0.74
0.74
0.75

Modelo de Klimpel
Valores iniciales

Tipo
de
Mineral

Conc.
No.

Tiempo, t
(seg)

1
2
3
4
5
6
7
8
9
10

Cobre
Factor
1

0.7960

k =

0.0386

Conc.
Masa
(g)

Ensaye

20

24.9

2.47

40
60

15.0
13.2

1.93
1.80

120

35.2

1.34

300

63.3

0.16

Colas

885.2

0.08

1036.8

0.23

Cab. Calc

Recuperacin (%)

Rinf =

(%)

Modelo de Klimpel R = Rinf [1 - (1/kt){1 - exp(-kt)}]

1

0.8

0.6

0.4

0.2

0
0

50

100

150
200
Tiempo de Flotacin (s)

R = Rinf [ 1 - (1/kt){1 - exp(-kt)} ]

(fraccin)

Masa Inicial :

1036.8

s-1

Ensaye
(%)

Cobre
Masa
(g)

2.47
1.93
1.80
1.34
0.16
0.00
0.00
0.00
0.00
0.00
0.08
0.23

0.62
0.29
0.24
0.47
0.10
0.00
0.00
0.00
0.00
0.00
0.71
2.42

Recovery (Cobre)
(exp)
(calc)
Re
Rc

Masa
Acum(%)

0.62
0.90
1.14
1.61
1.72
0.00
0.00
0.00
0.00
0.00

0.2538
0.3733
0.4713
0.6660
0.7078
0.0000
0.0000
0.0000
0.0000
0.0000

0.2414
0.3905
0.4862
0.6258
0.7272
0.0000
0.0000
0.0000
0.0000
0.0000

Suma de Error al Cuadrado

expt data
model

250

0.0124

0.0173
0.0149
0.0402
0.0195
0.0000
0.0000
0.0000
0.0000
0.0000

2.42

R = Rinf [1 - (1/kt){1 - exp(-kt)}]

150
200
Tiempo de Flotacin (s)

Re-Rc
(dif)

300

350

400

(dif)^2

0.00015
0.00030
0.00022
0.00161
0.00038
0.00000
0.00000
0.00000
0.00000
0.00000
0.0027

ma de Error al Cuadrado

Klimpel
Tiempo

Recuperacin

(s)
0

0.00

10

0.14

20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200
210
220
230

0.24
0.32
0.39
0.44
0.49
0.52
0.55
0.57
0.59
0.61
0.63
0.64
0.65
0.66
0.67
0.67
0.68
0.69
0.69
0.70
0.70
0.71

240
250
260
270
280
290
300
310
320
330
340
350
360

0.71
0.71
0.72
0.72
0.72
0.72
0.73
0.73
0.73
0.73
0.74
0.74
0.74

Modelo de Kelsall

Tipo
de
Mineral

Conc.
No.

Tiempo, t
(seg)

1
2
3
4
5
6
7
8
9
10

Cobre
Factor
1

0.2284
0.0174

ks =

-0.001

Conc.
Masa
(g)

Ensaye

20

24.9

2.47

40
60

15.0
13.2

1.93
1.80

120

35.2

1.34

300

63.3

0.16

Colas

885.2

0.08

1036.8

0.24

Cab. Calc

Recuperacin (%)

phi =
kf =

(%)

Modelo de Kelsall R = (1-phi)[1 - exp(-kf.t)] + phi[1 - exp(-ks.t)]

1

0.8

0.6

0.4

0.2

0
0

50

100

150
200
Tiempo de Flotacin (s)

R = (1 - phi)[1 - exp(-kf.t)] + phi[1 - exp(-ks.t)]

(fraccin)
s-1
s

Masa Inicial :

1036.8

-1

Ensaye
(%)

Cobre
Masa
(g)

2.47
1.93
1.80
1.34
0.16
0.00
0.00
0.00
0.00
0.00
0.08
0.24

0.62
0.29
0.24
0.47
0.10
0.00
0.00
0.00
0.00
0.00
0.72
2.44

Recovery (Cobre)
(exp)
(calc)
Re
Rc

Masa
Acum(%)

0.62
0.90
1.14
1.62
1.72
0.00
0.00
0.00
0.00
0.00
2.44

0.2522
0.3711
0.4688
0.6625
0.7045
0.0000
0.0000
0.0000
0.0000
0.0000

0.2227
0.3789
0.4881
0.6525
0.7055
0.0000
0.0000
0.0000
0.0000
0.0000

expt data
model

250

0.0295

0.0078
0.0193
0.0099
0.0010
0.0000
0.0000
0.0000
0.0000
0.0000
Suma de Error al Cuadrado

)[1 - exp(-kf.t)] + phi[1 - exp(-ks.t)]

150
200
Tiempo de Flotacin (s)

Re-Rc
(dif)

300

350

400

Kelsall

(dif)^2

0.00087
0.00006
0.00037
0.00010
0.00000
0.00000
0.00000
0.00000
0.00000
0.00000
0.0014

ma de Error al Cuadrado

Time
(s)
0
10

Recovery

20

0.22

30
40
50
60

0.31
0.38
0.44
0.49

70

0.53

80
90

0.56
0.59

100

0.62

110
120
130
140
150

0.64
0.65
0.67
0.68
0.69

160

0.69

170

0.70

180

0.70

190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340
350

0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.70
0.70
0.70
0.70
0.70

0.00
0.12

Modelo Modificado de Kelsall

Tipo
de
Mineral

Conc.
No.

Tiempo, t
(seg)

1
2
3
4
5
6
7
8
9
10

Cobre
Factor
1

0.678
0.7196
1.8000

ks =

0.0175

Conc.
Masa
(g)

Ensaye

20

24.9

2.47

40
60

15.0
13.2

1.93
1.80

120

35.2

1.34

300

63.3

0.16

Colas

885.2

0.08

1036.8

0.24

Cab. Calc

Recuperacin (%)

phi =
Rinf =
kf =

(%)

Modelo Modificado de Kelsall R = (1-phi)[1 - exp(-kf.t)] + phi[1 - exp(-k

1

0.8

0.6

0.4

0.2

0
0

50

100

150
200
Tie m po de Flotacin (s )

250

0
0

50

100

150
200
Tie m po de Flotacin (s )

250

R = (Rinf - phi)[1 - exp(-kf.t)] + phi[1 - exp(-ks.t)]

(fraccin)
(fraccin)
s-1
s

Masa Inicial :

1036.8

-1

Ensaye
(%)

Cobre
Masa
(g)

2.47
1.93
1.80
1.34
0.16
0.00
0.00
0.00
0.00
0.00
0.08
0.24

0.62
0.29
0.24
0.47
0.10
0.00
0.00
0.00
0.00
0.00
0.72
2.44

Recovery (Cobre)
(exp)
(calc)
Re
Rc

Masa
Acum(%)

0.62
0.90
1.14
1.62
1.72
0.00
0.00
0.00
0.00
0.00
2.44

0.2522
0.3711
0.4688
0.6625
0.7045
0.0000
0.0000
0.0000
0.0000
0.0000

expt data
model

250

0.0104

0.0117
0.0133
0.0261
0.0115
0.0000
0.0000
0.0000
0.0000
0.0000
Suma de Error al Cuadrado

-phi)[1 - exp(-kf.t)] + phi[1 - exp(-ks.t)]

0
200
e m po de Flotacin (s )

0.2418
0.3828
0.4822
0.6364
0.7160
0.0000
0.0000
0.0000
0.0000
0.0000

Re-Rc
(dif)

300

350

400

0
200
e m po de Flotacin (s )

250

300

350

400

Modelo Modificado de Kelsall

Tiempo
Recuperacin
(s)

(dif)^2

0.00011
0.00014
0.00018
0.00068
0.00013
0.00000
0.00000
0.00000
0.00000
0.00000
0.0012

ma de Error al Cuadrado

0.00

10
20
30
40

0.15
0.24
0.32
0.38

50

0.44

60
70

0.48
0.52

80

0.55

90
100
110
120
130

0.58
0.60
0.62
0.64
0.65

140

0.66

150

0.67

160

0.68

170
180
190
200
210
220
230
240
250
260
270
280
290
300
310
320
330
340
350
360

0.68
0.69
0.70
0.70
0.70
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.72
0.72
0.72
0.72
0.72
0.72
0.72
0.72

370

0.72

Modelo Gamma

Tipo
de
Mineral

Conc.
No.

Factor
1

0.7163
560850

10622

Conc.
Masa
(g)

Ensaye

20

24.9

2.47

40
60

15.0
13.2

1.93
1.80

120

35.2

1.34

300

63.3

0.16

Colas

885.2

0.08

1036.8

0.24

Tiempo, t
(seg)

1
2
3
4
5
6
7
8
9
10

Cobre

Rinf
=
lambda =

Cab. Calc

(%)

Recupe racin (%)

Modelo Gamma R = Rinf (1 - [lambda/(lambda+t)]^P)

1

0.8

0.6

0.4

0.2

0
0

50

100

150
200
Tiem po de Flotacin (s)

250

0.2

0
0

50

100

150
200
Tiem po de Flotacin (s)

250

R = Rinf (1 - [lambda/(lambda + t)]^P)

(fraccin)
Masa Inicial :

Ensaye
(%)

Cobre
Masa
(g)

2.47
1.93
1.80
1.34
0.16
0.00
0.00
0.00
0.00
0.00
0.08
0.24

0.62
0.29
0.24
0.47
0.10
0.00
0.00
0.00
0.00
0.00
0.72
2.44

Recovery (Cobre)
(exp)
(calc)
Re
Rc

Masa
Acum(%)

0.62
0.90
1.14
1.62
1.72
0.00
0.00
0.00
0.00
0.00
2.44

0.2522
0.3711
0.4688
0.6625
0.7045
0.0000
0.0000
0.0000
0.0000
0.0000

expt data
model

250

0.2259
0.3805
0.4864
0.6425
0.7139
0.0000
0.0000
0.0000
0.0000
0.0000

Re-Rc
(dif)
0.0263

0.0094
0.0176
0.0200
0.0093
0.0000
0.0000
0.0000
0.0000
0.0000
Suma de Error al Cuadrado

nf (1 - [lambda/(lambda+t)]^P)

200
m po de Flotacin (s)

1036.8

300

350

400

200
m po de Flotacin (s)

expt data
model

250

300

350

400

Modelo Gamma
Tiempo

Recuperacin

(s)
0
10
20
30
40

0.00
0.12
0.23
0.31
0.38

50

0.44

60
70
80
90

0.49
0.53
0.56
0.59

0.00069
0.00009
0.00031
0.00040
0.00009
0.00000
0.00000
0.00000
0.00000
0.00000

100

0.61

110
120

0.63
0.64

130

0.66

140
150
160
170
180

0.67
0.67
0.68
0.69
0.69

190

0.70

0.0016

200

0.70

210

0.70

220
230
240
250
260
270
280
290
300
310
320
330
340
350
360

0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.71
0.72
0.72
0.72

(dif)^2

ma de Error al Cuadrado

Celda en Operacin Continua

k
Tipo
de
Mineral

Celda

Tiempo
de Residencia, t
(min)

1
2
3
4
5
6
7
8
9
10
11
12

Cobre

0.0004

Grado
%

Recuperacin
por Celda
(calc)

0.0842
0.0771
0.0706
0.0647
0.0592
0.0542
0.0497
0.0455
0.0417
0.0381
0.0349
0.0320

0.288
0.288
0.288
0.288
0.288
0.288
0.288
0.288
0.288
0.288
0.288
0.288

Re cupe racin

0.8

0.6

0.4

0.2

R
A

0
0

6
Nm ero de Ce ldas

0
0

6
Nm ero de Ce ldas

R = 1 - (1 + k)^-N

R' = k/(1 + k)

s-1
Acum.
Rec.
(calc)

Alim.
Total Conc
Colas

0.0842
0.1613
0.2319
0.2965
0.3557
0.4100
0.4596
0.5051
0.5468
0.5849
0.6199
0.6519
1.0000
0.6519
0.3481

No. De Celdas: 12
Grado de Alim(%): 1.76
Grado en Conc(%): 5.35
Grado en Colas(%): 0.78

Recuperacin
(exp)

dif.

(dif)^2

0.6519

0.0000

0.00000
0.0000

Suma de Error al Cuadrado

0.35

0.3

Tie m po de Res idencia (m in)

0.25

0.2

0.15

0.1

Rec uperac in
Ac umulada

0.05

0
6
Nm ero de Ce ldas

10

12

0.05

0
6
Nm ero de Ce ldas

10

12