REACTIONS at T = 773.

150
1
1.000 Cd + 0.500 O2(g) -> CdO
43329.200
2

G / cal
-

3.000 Cd + 3.000 O2(g) + 0.500 S2(g) -> (CdO)2*CdSO4

244125.000

3
1.000 Cd + 0.500 S2(g) -> CdS
33639.700

4
1.000 Cd + 2.000 O2(g) + 0.500 S2(g) -> CdSO4
154613.700
5

3.000 CdO + 1.500 O2(g) + 0.500 S2(g) -> (CdO)2*CdSO4

114137.400

1.000 CdO + 0.500 S2(g) -> 0.500 O2(g) + CdS

9689.500

1.000 CdO + 1.500 O2(g) + 0.500 S2(g) -> CdSO4

111284.500

0.333 (CdO)2*CdSO4 + 0.333 S2(g) -> 1.000 O2(g) + CdS

47735.300

0.333 (CdO)2*CdSO4 + 1.000 O2(g) + 0.333 S2(g) -> CdSO4

73238.700

10
1.000 CdS + 2.000 O2(g) -> CdSO4
120974.000

log pS2(g)
-8

Cd-O -S Phase Stability Diagram at 500.000 C

-10
-12
CdS

-14

(CdO)2*CdSO4
-16
CdO
-18
-20

Cd

-22
-26
-24
-22
File: C:\HSC5\Lpp\CdOS500.ips

-20

-18

-16

-14
log pO2(g)

REACTIONS at T = 1473.150
1
1.000 Cd + 0.500 O2(g) -> CdO
25986.700
2

G / cal
-

3.000 Cd + 3.000 O2(g) + 0.500 S2(g) -> (CdO)2*CdSO4

142144.000

3
1.000 Cd + 0.500 S2(g) -> CdS
17398.800
4
1.000 Cd + 2.000 O2(g) + 0.500 S2(g) -> CdSO4
80500.300
5

3.000 CdO + 1.500 O2(g) + 0.500 S2(g) -> (CdO)2*CdSO4

64183.900

1.000 CdO + 0.500 S2(g) -> 0.500 O2(g) + CdS

8587.900

7
1.000 CdO + 1.500 O2(g) + 0.500 S2(g) -> CdSO4
54513.600

0.333 (CdO)2*CdSO4 + 0.333 S2(g) -> 1.000 O2(g) + CdS

29982.533

0.333 (CdO)2*CdSO4 + 1.000 O2(g) + 0.333 S2(g) -> CdSO4

33118.967

10
1.000 CdS + 2.000 O2(g) -> CdSO4
63101.500
log pS2(g)
-1.5

Cd-O -S Phase Stability Diagram at 1200.000 C

-2.0
-2.5
-3.0
CdS

-3.5

(CdO)2*CdSO4

-4.0
CdO

-4.5
-5.0
-5.5

Cd

-6.0
-8.5
-8.0
-7.5
-7.0
-6.5
File: C:\HSC5\Lpp\CdOS1200.ips

-6.0

-5.5

-5.0

-4.5
-4.0
log pO2(g)