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Chemistry

Questions (1-6) (+3, 0) [Single Option Correct]


1. In an Hydrogen atom, an e- is given energy equal to 1.5 times that of Ionization
energy, when it is present in its ground state. What is the wavelength of e - wave?
a) 2.12 Ao
b) 4.24 Ao
c) 1.06 Ao
d) None of these
2. A Gas cylinder of volume 3L is placed at STP. Suddenly the gas is transferred to
another Vaccum cylinder of volume 5L which is placed at temperature 409.5 K
through a narrow tube. What is the final pressure in 1st Cylinder?
a) 0.74 atm b) 0.44 atm c) 0.47 atm d) None of these
3. The average velocity of X molecule at STP is 347 m/s. What is the root mean
square velocity of the same gas molecule at 1092 K and 1 atm pressure?
a) 753 m/s b) 697 m/s
c) 850 m/s
d) 700 m/s
4. The value of Electrode potential of a few half reactions are given below:
a) Cu
Cu2+ + 2e1
2+
b) Cu + e
Cu+
2
+
c) Cu + e
Cu
3
What is the relation between
a)

1+ 2+ 21=0

1, 2 & 3?

b) 2+

3= 1 c) 1+ 22= 3 d) None of these

5. Which is the pair of iso structural species?


a)SO2 & CO2
b) NCl3 & BCl3
c) SCl2 & H2O d) PCl5 & ICl5
6. Which of the following ion has largest radius Aq. Medium?
a) Li2+
b) Be2+
c) Mg2+
d) K+
[Multiple Options Correct] (+4, 0)
7. Which of the following statement is/are true regarding POCl 3?
a) Hybridization of POCl3 is SP3d
b) % of s-Character is hybridization of P is 25%
c) POCl3 is a non-polar molecule
d) P-Cl bondlength is longer than P-O
8. If 5L of H2O2 produces 50L of O2 at NTP, H2O2 is
a) 50V
b) 10 V
c) 0.89 M

d) 10 M

9. In which of the following species atleast one S atom has O.N=2?


a) S2O32b) S4O62c) Cinnabar d) Zinc Blende
10. Choose the correct relation on the basis of Bohrs theory.

Z
n

a) Velocity of Electron

b) Radius of Orbit

n2 Z

c) Frequency of revolution

Z2
n3

1
n4

d) Force on Electron

11. C(s) + 2H2(g) + 1/2 O2(g ) CH3OH(l)

H1= 110kJ

CO2(9) + 2H2(9) CH3OH(l) + 1/2O2(9) H2= 105kJ


C(s) + O2(g) CO2(g)

H3= ?

Find H3.
12. What is the amount of work done by the system when one mole of an ideal gas
STP is expanded against vacuum?
13. What are the numbers of covalent bonds in Cu2SO4 molecules?
14. What will be the nearest integral value of pH of a solution made by mixing
20ml of 0.1 M HCl, 10ml of 0.1 M H2SO4 & 370ml of water.
15. What is the number of unpaired e-s in an O2 molecule?

Answers
1. A
2. C
3. B
4. A
5. C
6. B
7. B,D
8. B,C
9. A,B
10. A,C
11. 5
12. 0
13. 6
14. 2
15. 2

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