(

95 g H 2 SO 4 R . P
100 g R . A

)(

1 mol H 2 SO4
98.01 g H 2 SO 4 R . A

)(

1.84 g R . A
1mL R . A

)( 10001 LmLR .RA . A )( 355 mLmL )=2.5478 M

2=log ( 2.5478 M )=0.4061

P SO 4

pH=-0.408
H 2 SO 4

2
SO 4

H SO 4

-3

1.8

Ecuacin

E 0=1.507 v
MnHSO 4

2+ + HSO4
Mn
2++ 4 H 2 O K=10 0.77
Mn
+ +5 e
+ 8 H
MnO4

+4 H 2 O
MnHSO 4
+ HSO 4
+5 e
++ MnO 4
8 H

GO =5 (1.507 v )=9.04 2
GO =0.05916 ( log 100.77 ) =0.3484
GO =9.3904 v
5 e=1.87808 v
G0 9.3904 v
0
E=
=

Reductor

++2 e
H 2 O2 O2 ( g )+ 2 H E 0=0.695
5
+4 H 2 O
MnHSO 4
} =1.87808v
+ 5 e E

+ 2 HSO 4
++ MnO 4
8 H
2

+8 H 2 O
+ 5 H 2 O2 5 O2 ( g ) +2 MnHSO4
+ 2 HSO 4
+ +2 MnO 4
6 H

K =10

HSO4

+
H

} = {10} ^ {196.7398}

10 (1.87808 v0.695 v)
0.05916

=10

200