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  • WK 9 TUTE AnswerSheet

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    SenanLg
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    1. This document contains tutorial solutions for transport phenomena problems involving diffusion. The first problem involves steady-state diffusion through a plane wall membrane. 2. The second problem involves steady-state diffusion of water vapor in air. It calculates evaporation rates using both diffusion-only and combined diffusion/convection models. 3. The third problem involves steady-state diffusion of NO gas through a film. It derives an expression for the NO mole fraction at the catalytic surface and calculates the molar flux of NO.

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    transport phenomena tutorial

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    1. This document contains tutorial solutions for transport phenomena problems involving diffusion. The first problem involves steady-state diffusion through a plane wall membrane. 2. The second problem involves steady-state diffusion of water vapor in air. It calculates evaporation rates using both diffusion-only and combined diffusion/convection models. 3. The third problem involves steady-state diffusion of NO gas through a film. It derives an expression for the NO mole fraction at the catalytic surface and calculates the molar flux of NO.

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    © All Rights Reserved
    Baixe no formato PDF, TXT ou leia online no Scribd
    Sinalizar o conteúdo como inadequado
    38 visualizações2 páginas

    WK 9 TUTE AnswerSheet

    Enviado por

    SenanLg
    1. This document contains tutorial solutions for transport phenomena problems involving diffusion. The first problem involves steady-state diffusion through a plane wall membrane. 2. The second problem involves steady-state diffusion of water vapor in air. It calculates evaporation rates using both diffusion-only and combined diffusion/convection models. 3. The third problem involves steady-state diffusion of NO gas through a film. It derives an expression for the NO mole fraction at the catalytic surface and calculates the molar flux of NO.

    Direitos autorais:

    © All Rights Reserved
    Baixe no formato PDF, TXT ou leia online no Scribd
    Sinalizar o conteúdo como inadequado
    de 2

    Transport

    Phenomena CHEN 3001


    Week9tutorialsolutions

    1. Assumptions:steadystateconditions,1dimensionaldiffusioninaplanewall,stationary
    medium,uniformC=CA+CB.
    Diffusionfluxthroughthemembrane=DAB(CA1CA2)/L=1.5x10^8kmol/s.m2

    2. Assumptions:steadystateconditions,1dimensionaldiffusion,constantproperties,
    temperatureandpressure,idealgasbehaviour.
    At300Kand1atm,DAB(watervapourair)=0.26x10^4m2/s,vapourpressure=0.03513
    bar,specificvolume=vg=39.13m3/kg.

    a) Evaporationrate,consideringdiffusiononly:

    N A D AB A

    C A , C A , S
    D A
    AB C A,sat 1
    L
    L

    Twowaysofcalculatingsaturationconcentration:

    C A,sat

    Psat
    1

    0.00142kmol/m3.
    RT v g M A

    Theseareessentiallythesame,asthespecificvolume,vg,isessentially v g

    RT
    ,
    PM A

    fromouridealgaslaw,PV=nRT.

    istheratiobetweentheconcentrationofwatervapourintheairstreamandat
    saturationcondition,sothisisessentiallytherelativehumidity.
    So,theevaporationrate=1.087x10^8kmol/s

    b) Evaporationrate,consideringbulkfluidmovementaswellasdiffusion:

    NA

    cDAB A 1 x A,
    ln

    L
    1 x A, s

    Theconcentrationparameterinthiscontextisthetotalconcentration,so c

    P
    ,
    RT

    whereP=atmosphericcondition=1.01325bar.

    x A,s =Psat/P=0.0348
    x A, = (Psat/P)=0.0087
    So,theevaporationrate=1.107x10^8kmol/s
    Asexpected,theconvectiveeffect,althoughsmall,doesincreasetheevaporationrate.


    3. Assumptions:Steadystateconditions,1dimensionaldiffusion,effectsofbulkmotiononNO
    transferinthefilmarenegligible,nohomogeneousreactionsofNOwithinthefilm,constant
    properties,aswellasthetotalmolarconcentrationthroughoutthefilm.
    Simplifiedcontinuityequation:
    where N NO cDAB

    N NO
    0
    x

    dx NO

    dx

    Boundarycondition1:(catalyticsurface) D AB
    Boundarycondition2: x NO

    x NO

    k1 x NO

    x 0

    DAB

    xL

    N NO
    x

    k1 x NO
    x 0

    x NO , L

    x L xNO xL

    So,themolefractionofNOatthecatalyticsurfaceis0.10.

    MolarfluxofNO: N NO cDAB

    4.

    x NO
    >
    x

    x NO , L

    x NO , 0

    N NO x cD AB

    x NO

    Molarflux=9.35x10^5kmol/m2.s
    NOremovalrateoversurfacearea=5.61x10^5kg/s

    Thisresultcouldbeviewedasafirstapproximation,asbulkmotionislikelytoalso
    contributesignificantlytothetransferofNOwithinthefilm.

    a.Asteadystatedifferentialequationthatdescribestheevaporationoftheherbicideinto
    theair:

    N AZ

    cDAB y A

    1 y A z

    b. Adifferentialequationthatdescribesthe(unsteadystate)diffusionoftheherbicideinto
    thesoil:

    c A
    2c A

    D AB
    t
    z 2

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