Formulario

Gases ideales
Ley de Charles
Ley de Gay Lussac
Ley de Boyle
Fraccin mol
Presin parcial

PV=nRT
V1/T1=V2/T2
P1/T1=P2/V2
P1/V1=P2/V2
ni/nT=Yi
PtYi=Pi

Gases reales

P=RT/Vm-b a/Vm2
Vm=V/n
Z=Vreal/Videal
Z=PVm/RT
Tr= T/Tc
Pr=P/Pc
Vmr =Vm/Vcm
Vc=V1=V2=V3
a=3PcVcm2
b=Vcm/3
R=8PcVcm/3Tc
P=(RT/Vm-b)-(a/Vm2)
Vm=zRT/P
Monoatmico
Diatmico

Cp = 5/2R
Cv = 3/2R
Cp = 7/2R
Cv = 5/2R
= Cp/Cv

T2/T1=(P2/P1)( -1)/
T2/T1=(V1/V2) -1
P2/P1=(V1/V2)
Eficiencia

= (1-(T1/T2))*100
= (-Wtotal/Qa)*100
= (QTQc/Qa)*100

A= U -Ts V = cte
G= H - Ts P = cte
Kp = e-G/RT
G = nRTln(P2/P1)
G = H - TS - ST
A = -nRTln(P1/P2)
A = nRTln(P2/P1)
A = nRTln(V2/V1)
A = H - TS - ST