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uoxx+x
uoxx
z
y
x
(9.1)
Leaving:
o uox x x Ax t o uoy
(9.2)
y y
Ay t o uoz z z Az t
Oil can accumulate by: (1). Change in saturation, (2). Variation of density with
temperature and pressure, and (3). Change in porosity due to a change in confining stress.
Thus we can write,
o SoV t t o SoV t
9.1
(9.3)
(9.4)
(9.5)
The oil and water continuity equations assume no dissolution of oil in the water phase.
That is, no mass transfer occurs between phases and thus flow is immiscible.
The next step is to apply Darcys Law to each phase, i. For example in the xdirection,
uix
kix i i
i x
(9.6)
where uix is the superficial velocity of phase i in the x-direction, kix, is the effective
permeability to phase i in the x-direction, and is the phase potential. Substitute Eq.
(9.6) into (9.4), apply Leibnitz rule of differentiation, and combine terms, results in,
o g o So
x o x y o y z o z
t
(9.7)
w g w S w
x w x y w y z w z
t
(9.8)
Even though Eqs. (9.7) and (9.8) are written in Cartesian coordinates, they both can be
solved for a particular geometry.
saturation distributions, but also phase velocities at any point in the porous media.
To combine Eqs. (9.7) and (9.8) requires a relationship between phase pressures
and between phase saturations. The latter is easily understood from the definition of
saturations in Chapter 4, So + Sw = 1.0.
9.2
(9.9)
poL
poi
qo
D
Pwi
qw
PwL
d dpo
ko
0
dx dx
d dpw
kw
0
dx
dx
(9.10)
dpo
q
co o o
dx
A
dp
q
k w w cw w w
dx
A
ko
(9.11)
p oL
p oi
co
dx
ko o
(9.12)
qo o L
A( poi poL )
(9.13)
dpo
ko
9.3
gap
Pc=0
Po
P
Sor
Sw
Pw
Pc=0+
0
Swc
0
Figure 9.4 Pressure and saturation profile through a core of length, L, with capillary end
effect.
Mathematically, we can describe this effect by investigating Darcys Law for the nonwetting phase.
q nw
k nw A p w pc S w
nw x S w x
9.4
(9.14)
x L x
(9.15)
Two plausible methods have been applied to avoid capillary end effect. The first
is to inject at a sufficiently high rate such that the saturation gradient is driven to a small
region at the end of the core. The second method is to attach a thin, (high porosity and
high permeability) Berea sandstone plug in series with the test core sample. The result is
to confine the saturation gradient in the Berea plug and thus have constant saturation in
the sample of interest.
A consequence of the saturation gradient in the core is that effective permeability
can no longer be considered constant from 0 < x < L. Subsequently, the convenient
steady state method of obtaining relative permeability outlined in Section 9.2 is not valid.
A solution to the saturation gradient can be obtained be combining the definition of
capillary pressure with the steady state, incompressible diffusivity equations. Begin with
defining the boundary conditions. Illustrated in Figure 9.5 is the capillary pressure
saturation relationship in a core with end effects.
inlet
pc
Sw
outlet
9.5
dx
dx
dx
(9.16)
dpc pc dS w
dx S w dx
(9.17)
Since pc = f(Sw),
Substituting Eq. (9.17) into (9.16) for the capillary pressure gradient term, and Eq. (9.11)
into (9.16) for the oil and water gradient terms and rearranging, results in,
S wL
Sw
pc
dS w
L
S
w
dx
qw w qo o x
Ak w
Ak o
(9.18)
Equation (9.18) can be solved either graphically or numerically for saturation gradient.
The result will be a calculated saturation profile similar to the one shown in the righthand side of Figure 9.4.
9.4 Frontal advance for unsteady 1D displacement
The unsteady-state displacement of oil by water is due to the change in Sw with
time.
These
schematics represent
Sor
Sor
Sw
Sw
Swi
Sor
Swi
Sor
Sw
Sw
Swi
0
x/L
Swi
1
x/L
injection, the front advances to a position as shown in B. Ahead of the front water
saturation is at irreducible, but behind the front water saturation is increased. Continuing
in time, eventually the water will breakthrough the end of the core (reservoir) and both oil
and water will be produced simultaneously, C. Continued injection will increase the
displacing phase saturation in the core (reservoir), D.
Two methods to predict the displacement performance are 1) the analytical
solution by Buckley Leverett (1941), and 2) applying numerical simulation. Only the
analytical solution will be described in this chapter.
9.4.1 Buckley Leverett (1941)
The derivation begins from the 1D, multiphase continuity equations.
ouox o So
x
t
(9.19)
wuwx wSw
x
t
(9.20)
o qo A o So
x
t
(9.21)
wqw A w Sw
x
t
(9.22)
Assume the fluids are incompressible and the porosity is constant. Eqs. (9.21) and (9.22)
simplify to,
qo
S
A o
x
t
(9.23)
qw
S
A w
x
t
(9.24)
Combining,
qw qo
S w So
A
0
x
t
(9.25)
The result is qT = qo + qw = constant, the total flow rate is constant at each cross-section.
9.7
qw f wqT
qo (1 f w )qT
(9.26)
qo (1 f w )qT
qw f wqT
ko A po
o g sin
o x
kw A pw
w g sin
w x
(9.27)
(9.28)
Rearranging Eqs. (9.27) and (9.28), we can substitute into Eq. (9.16) for the pressure
gradient terms. Solving the resulting equation for fractional flow of water, provides the
complete fractional flow equation.
ko A pc
g sin
1
q x
fw
o T
ko w
ko w
1
1
k w o
k w o
In the analytical solution it is difficult to analyze the derivative term (dpc/dx).
(9.29)
If we
pc pc S w
x S w x
(9.30)
pc
0
S w
Pc
Sw
Figure 9.7 Capillary pressure curve illustrating flat transition region at moderate to high
water saturations.
9.8
fw
1
k
1 o w
k w o
(9.31)
k w o
ko w
(9.32)
then fw = 1/(1+1/M).
If we return to Eq. (9.24) and substitute for qw, we obtain,
f w
A S w
x
qT t
(9.33)
To develop a solution, Eq. (9.33) must be reduced to one dependent variable, either Sw or
fw. Observe, Sw = Sw(x,t) or,
S
S
dS w w dx w dt
x t
t x
(9.34)
Let dSw(x,t)/dt = 0, (Tracing a fixed saturation plane through the core) then
dx
dt S w
S w
t x
S w
x t
(9.35)
where the left-hand side is the velocity of the saturation front as it moves through the
porous media.
Observe fw = fw(Sw) only, then,
f w f w S w
x t S w t x t
(9.36)
Substitution of Eqs. (9.35) and (9.36) into Eq. (9.33), results in the frontal advance
equation.
dx
q f
T w
dt S w A S w t
9.9
(9.37)
dx
0
Sw
t
1 f w
qT dt
A 0 S w t
(9.38)
qT t f w
A S w S
(9.39)
w
We can evaluate the derivative from the fractional flow equation (Eq. 9.31), either
graphically or analytical. Figure 9.8 illustrates the graphical solution.
Swbt
fwf
fw
Swc Sw
Swf
9.10
Vw S w Adx
(9.40)
x1
Vo Vw A ( x2 x1 )Swi
(9.41)
Figure 9.9 illustrates the recovery of oil both before and after water breakthrough. Note
the 45 degree slope up to breakthrough and then the decrease in slope (reduced
performance) after breakthrough.
Np
breakthrough
Qi
Figure 9.9 Typical oil recovery performance plot for immiscible displacement
A solution for waterflood performance was developed by Welge in 1952. Define
the volumetric average water saturation as,
x2
Sw
Adx
x1
x2
(9.42)
Adx
x1
For constant cross-sectional area (A) and porosity (), Equation (9.42) reduces to,
x2
Sw
dx
x1
x2 x1
9.11
(9.43)
x dS w
x2 x1
x2 x1 1
2
Sw
(9.44)
Substitute the frontal advance equation (Eq. 9.37) for the integral and solve,
2
x dSw
1
2
qT t f w
dS w
A 1 S w S
w
q t
T f w 2 f w1
A
(9.45)
Sw
x2 S w2 x1S w1 qT t f w2 f w1
x2 x1
A x2 x1
(9.46)
A useful simplification is to consider x1 = 0 at the inlet and x2 = L at the outlet end of the
core,
Sw Sw2
qT t
1 f w2
AL
(9.47)
Qi
Wi
Vp
(9.48)
Sw Sw2 Qi 1 f w2
(9.49)
The cumulative oil displaced, Np, can be expressed in terms of the difference in the
average water saturation and the exit end saturation, i.e.,
N p Vp Sw Sw2
(9.50)
Consider a special case immediately before breakthrough. In this case, S w2 = Swi and fw2
= 0. Subsequently, Eq. (9.49) can be written as:
Swbt Swi Qibt
(9.51)
N p Vp Swbt Swi
9.12
(9.52)
Sw2 Sw Qi f 02
(9.53)
1
o
1
kw S w 2 w f w2
(9.54)
In this example, both gravity and capillary pressure components are considered negligible
and thus are ignored. The average fractional flow of oil at the exit end for a given time
increment is given by,
fo2
lim N p Wi Wi N p Wi
dWi Wi 0
Wi
dN p
(9.55)
where dNp is cumulative oil produced and dWi is water injected during t. Alternative
expressions for dNp and dWi can be written as,
dN p AL dS w
dWi AL dQi
(9.56)
fo2
dS w S w S w2
dQi
Qi
The slope of a plot of average water saturation vs PVs of water injected provides an
estimate of fo2 (Figure 9.10).
Sw
breakthrough
Sw2
Qi
(9.57)
qT dx
(9.58)
k
k
0
kb A ro rw
o w
Pressure drop is measured across the core during the constant rate test. From the single
phase, steady state experiment we obtain,
qb b L
pb
kb A
(9.59)
(9.60)
qT pb dx
qb b L 0
L
(9.61)
dx
0
x
(9.62)
dx
0
qb b p
qT pb
(9.63)
o f o 2
21
f
krw w 1w 2
2
kro
(9.64)
where the exit end apparent viscosity can be determined from the following relationship.
9.14
d 1
dQi
21 1 Qi
(9.65)
The derivative can be evaluated from the slope of a plot of the inverse of average
apparent viscosity vs. PVs water injected as shown in figure 9.11.
-1
breakthrough
Qi
Figure 9.11 Plot of inverse of average apparent viscosity vs Qi for determining fo2.
Example 9.1
An unsteady state test was performed at constant injection rate for the purpose of
determining the oil and water relative permeability curves.
parameters for the test.
Swi =
Vp =
w =
o =
q=
pb/qb=
0.35
31.13
0.97
10.45
80
0.1245
cc
cp
cp
cc/hr
psi/cc/hr
9.15
cumulative
Cumulative
wtr injection
oil produced
Wi, (cc)
Np, (cc)
0.00
3.11
7.00
11.20
16.28
24.27
39.20
62.30
108.90
155.60
311.30
0.00
3.11
7.00
7.84
8.43
8.93
9.30
9.65
9.96
10.11
10.30
p
psi
138.6
120.4
97.5
91.9
87.9
83.7
78.5
74.2
70.0
68.1
65.4
Qi
(PV)
0.000
0.100
0.225
0.360
0.523
0.780
1.259
2.001
3.498
4.998
10.000
Swave
fo2
0.350
0.450
0.575
0.602
0.621
0.637
0.649
0.660
0.670
0.675
0.681
Sw2
1.000
1.000
0.585
0.154
0.083
0.038
0.019
0.009
0.005
0.002
0.001
fw2
0.350
0.350
0.443
0.546
0.577
0.607
0.625
0.641
0.653
0.666
0.669
0.000
0.000
0.415
0.846
0.917
0.962
0.981
0.991
0.995
0.998
0.999
kro/krw
15.166
1.963
0.980
0.425
0.208
0.103
0.053
0.018
0.013
Sw ave
0.60
0.55
0.50
0.45
0.40
0.35
0.30
0.0
0.5
1.0
1.5
2.0
Qi
Figure 1. Plot of average water saturation vs. pore volume water injected. Slope provides
exit end fractional flow of oil.
p
psi
138.6
120.4
97.5
91.9
87.9
83.7
78.5
74.2
70.0
68.1
65.4
fo2
1.000
1.000
0.585
0.154
0.083
0.038
0.019
0.009
0.005
0.002
0.001
fw2
0.000
0.000
0.415
0.846
0.917
0.962
0.981
0.991
0.995
0.998
0.999
Qi
average
-1
(PV)
0.000
13.50
0.100
11.73
0.225
9.50
0.360
8.95
0.523
8.56
0.780
8.15
1.259
7.65
2.001
7.23
3.498
6.82
4.998
6.63
10.000
6.37
m*
-17.80
-10.68
-3.14
-1.90
-1.24
-0.76
-0.37
-0.20
-0.07
-0.05
2-1
13.50
13.50
11.90
10.08
9.56
9.12
8.60
7.97
7.51
6.98
6.90
Sw2
0.350
0.350
0.443
0.546
0.577
0.607
0.625
0.641
0.653
0.666
0.669
krw
0.000
0.000
0.034
0.081
0.093
0.102
0.111
0.121
0.129
0.139
0.141
9.16
kro
0.774
0.774
0.514
0.160
0.091
0.043
0.023
0.012
0.007
0.003
0.002
16
14
-1
)ave
12
10
8
6
4
2
0
0.0
5.0
10.0
15.0
Qi
9.17
Qi
Wi
Vp
Step 2:
Calculate the average water saturation from Eq. 9.50.
S w S wi
Np
Vp
Step 3:
Calculate the exit end fractional flow of oil from the slope of Figure 1.
fo2
S w
Qi
Step 4:
Calculate the exit end water saturation from Eq. 9.49.
Sw2 Sw Qi fo 2
Step 5:
Calculate exit end fractional flow of water by,
f w2 1 f 02
Step 6:
Calculate the relative permeability ratio as shown in Table 2 from Eq. 9.54.
ko
1
o
1
kw S w 2 w f w2
Step 7:
Find the average apparent viscosity from Eq. 9.63.
qb b p
qT pb
9.18
m*
Q
i
Step 9:
Calculate the exitend apparent viscosity from Eq. 9.65. Results shown in Table 3.
21 1 Qi m *
Step 10:
Calculate the individual relative permeabilities with respect to the outlet end,
where Sw2 is known,
o f o 2
21
f
krw w 1w 2
2
kro
The following data were obtained in a laboratory experiment to determine the relative gas
and oil permeability. Plot kro, krg vs. So.
9.19
Time (secs)
0
104
134
199
238
276
381
447
518
577
635
693
750
Cumulative Cumulative
gas injection oil produced
(cc)
(cc)
0
0
50
42.5
75
49.0
150
56.0
200
58.5
250
60.3
400
63.7
500
65.5
600
66.3
700
67.4
800
68.1
900
69.0
1000
69.7
Solution
A laboratory experiment was run with a constant pressure drop between the inlet and
outlet. Measured were time, cumulative gas injected, and cumulative oil produced. Also
known are the oil and gas viscosities, pore volume of the sample and the single phase oil
rate prior to gas injectionsaturate the core with oil, steady state process, at irreducible
water saturation.
Step 1: Plot cumulative oil production (Np) vs time. Determine oil flow rate by,
dN
p
q
o
dt
Step 2: Calculate the cumulative gas injected in terms of mean pressure and expressed in
pore volumes.
G
2Pi
Q (pv) i
i
V (P P )
p i
o
Step 3: Calculate the average gas saturation by,
N
p
Sg
S gi
Vp
Step 4: Determine the oil cut from the slope of a plot of average gas saturation vs Qi
9.20
dS
g
dQ
i
Step 5: Determine the relative permeability ratio,
k rg 1 f g
o
k ro f o o
q oi o L
k
q oi
0.4
Ap
Step 8: Determine the gas relative permeability
k rg
*k
k rg
ro
k ro
time
secs
0
104
134
199
238
276
381
447
518
577
635
693
750
Cumulative
Cumulative
Gas injection, oil produced
Gi, (cc)
Np, (cc)
0
0
50
42.5
75
49.0
150
56.0
200
58.5
250
60.3
400
63.7
500
65.5
600
66.3
700
67.4
800
68.1
900
69.0
1000
69.7
production
rate
qo (cc/sec)
0
0.366
0.142
0.091
0.056
0.036
0.030
0.019
0.015
0.015
0.014
0.014
0.012
9.21
Cumulative
Gas injection, Average gas
Qi, (pv)
saturation Sg
0
0
0.370
0.236
0.556
0.272
1.111
0.311
1.481
0.325
1.852
0.335
2.963
0.354
3.704
0.364
4.444
0.368
5.185
0.374
5.926
0.378
6.667
0.383
7.407
0.387
oil cut
fo
1
0.490
0.101
0.057
0.032
0.020
0.016
0.010
0.007
0.007
0.006
0.006
0.005
Np, cc
60
50
40
30
20
10
0
0
100
200
300
400
500
600
700
800
time, secs
Sg (ave)
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
0
Qi, pv
9.22
Cumulative
Gas injection, Average gas
Qi, (pv)
saturation Sg krg/kro ratio
0
0
0
0.37
0.236
0.016
0.56
0.272
0.133
1.11
0.311
0.248
1.48
0.325
0.450
1.85
0.335
0.754
2.96
0.354
0.947
3.70
0.364
1.523
4.44
0.368
2.090
5.19
0.374
2.207
5.93
0.378
2.485
6.67
0.383
2.485
7.41
0.387
2.842
Exit end
saturation
Sg2
0
0.055
0.216
0.248
0.277
0.299
0.308
0.328
0.337
0.339
0.343
0.343
0.348
Exit end
saturation
So2
1
0.945
0.784
0.752
0.723
0.701
0.692
0.672
0.663
0.661
0.657
0.657
0.652
Kro
1.000
0.914
0.355
0.228
0.140
0.091
0.076
0.047
0.037
0.038
0.034
0.035
0.031
Krg
0
0.014
0.047
0.057
0.063
0.069
0.072
0.072
0.076
0.085
0.086
0.086
0.087
Kro or krg
kro
krg
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
So2
Figure 3. Oil and gas relative permeability curves as a function of exit end oil saturation
9.23
Sor
w) Sor
o )Swi
w) Swf
Swi
D
d
(9.66)
where,
D w
d o
kw
Sor
(9.67)
ko
S wi
Note both permeabilities are evaluated at the endpoints, Swi and Sor, respectively.
If no sharp front is evident, we define the apparent mobility ratio, Ms, as:
Ms
krw
S wf
o
kro
(9.68)
S wi
where the water mobility is evaluated at the average water saturation behind the front.
The apparent mobility ratio is a measure of the relative rate of oil movement ahead of the
9.24
Ms = 1
Ms > 1
Ms
1
3
ED
Qi(pv)
Figure 9.12 Effect of apparent mobility ratio on displacement efficiency
In general form,
M
Si
Sd
(9.69)
where i is the mobility of the injected fluid evaluated at the average saturation of the
injected fluid at breakthrough, and d is the mobility of the displaced fluid evaluated at
the average saturation of the displaced fluid. Typical values are Ms of 0.2 to 10 for water
displacing oil, up to Ms of 1000 for gas displacing oil.
Wettability
The shape of the relative permeability curves are influenced by wettability, subsequently
impacting mobility ratio and fractional flow.
wettability on the fractional flow of water.
9.25
oil wet
fw
Slightly
Water wet
=180
=47
Sw
Figure 9.13 Effect of wettability on fractional flow of water
The mobility term increases and thus becomes more unfavorable; i.e., poorer
0.4
Np
(pv)
47
Incremental due
to wettability
0.3
180
Qi(pv)
2.5
9.26
=0.5
0.4
=40
Np
(pv)
0
Qi(pv)
In displacement, the
capillary pressure gradient is included in the fractional flow (See Eq. 9.29). Therefore,
the weak function suggests capillary pressure is not a dominant component of
displacement.
Viscosity Ratio
As the viscosity of oil increases the mobility ratio will correspondingly increase,
resulting in an increase in the fractional flow of water. Figure 9.16 illustrates the effect
for three arbitrary viscosity ratios, 100, 10 and 1, respectively.
fw
o/w=
100
10
Sw
9.27
o=1.8cp
Incremental due
to oil viscosity
Np
(pv)
o=151cp
Qi(pv)
oil
wtr
The subsequent
heterogeneity and properties of the displacing fluids. As an example, consider for water
9.28
ED
S /B
1 o o
So1 / Bo1
(9.70)
Where, So1 is the volumetric average oil saturation at the beginning of the waterflood and
So is the volumetric average oil saturation at a particular point during the waterflood. The
oil displaced is given by;
N p w EDV pw
So1
Bo1
(9.71)
where Npw is the oil displaced by water and Vpw is the pore volume swept by water to the
volumetric average residual oil saturation.
The dependence of residual oil saturation on capillary and viscous forces was
verified by a series of experiments.
NCA
v w
ow cos
(9.72)
Where v is the interstitial velocity (u/) and w is the viscosity of the displacing fluid.
Experimental data was obtained by measuring the oil saturation in cores when the first
water is detected at the outlet. Since the oil volume produced after breakthrough is small,
the results represent the trapping process. Figure 9.19 illustrates the general behavior of
the reduction in oil saturation in the core at breakthrough with increasing capillary
number.
9.29
So,%pv
50
10-8
10-3
NCA
w
v w
0.4
(9.73)
transition
Correlating residual oil saturation with capillary and viscous forces has several
important implications for fluid flow in porous media. It demonstrates the independence
of Sor from flood velocity at reservoir rates. Furthermore, correlations illustrate that Sor
can be reduced below field waterflood residual in the laboratory corefloods if the lab
experiments are conducted at large NCAM.
In many field applications reservoir pressure has depleted to the point where
appreciable free gas saturation exists in the pores. Subsequently, prior to water injection
both a residual oil and gas saturation co-exist. If re-pressurization occurs during water
injection, the gas will dissolve back into the oil with little, if any, effect on the residual oil
saturation. However, if a trapped gas saturation is present at the time the residual oil is
trapped by water, a substantial reduction of residual oil saturation will occur.
For
example, a correlation shown in Figure 9.20 illustrates the reduction in residual oil
saturation for a water-wet, consolidated rock. Implied in the figure is that an increase in
9.30
Sor,%
10
Sgi,%
30
(9.74)
The left-hand-side is known as the critical scaling coefficient. If the numerical value of
this coefficient exceeds the critical value, then stabilized flow will occur. Since rate and
length effects occur when capillary forces become important in the displacement process,
this scaling factor also indicates when capillary forces are minimized. In applications,
under field conditions the displacement process is almost always stable. Under lab
conditions, to compute relative permeabilities from linear displacement tests, it is
9.31
This value is an order of magnitude greater than the critical values observed in lab
experiments, and therefore flow is stabilized.
Example 2
It is desired to conduct a laboratory waterflood experiment under stabilized conditions in
a core 2.54 cm in diameter and 5 cm long. The porosity of the core is 15% and the
viscosity is 1 cp [1 kPa-s]. Estimate the volumetric injection rate in cubic meters/second
if the critical scaling coefficient is 5.85 x 10-9 N.
Solution
q uT A 1.17 x10 4 (0.0254m) 2
4
8 3
q 5.93x10 m / s
9.32
Subsequently, the