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ju-= Afm/(M -+m) aad M —> (Mm) and with r taken a the body separation The distance of mass from the centre of mat i then rju/m (ee eae able on Reduced mas) (Other onital dimensions sale snialy, Note that ifthe toa enerzy, E, is < O thon e ~< 1 and te orks isan ellipse (a cite ife = 0). IPE = 0, then e = 1 and he oi is a parabola. If > O then ¢ > 1 and he ot becomes & hyperbola (00 Rucherford searing on neXt pare.n Rutherford scattering? Dynamics and mechanics any Scattering potential eee (3.115) Scattering angle 116 eu ‘Closest approach (3.118) Semi-axis 119) ae 4B? a x Eecen eee tricity (8 +1) 04 G19 ‘Motion trajectory* (3.121) Scattering centre (6.122) Rutherford G.123) scattering formula! (a)? at (qe) (3.124) UG) potential enerey particle separation 2 seauering angle wal energy (20) > impact perameter rain closest approach a hyperbola semiaxis coventry ‘5 postion with respect 19 hyperbola centr $ext catering beam Bux density AN numberof pares eateed soto e solid angle “Nonrelaivisic weatment for an iaversesquare fore law and a fed catering cents Similar scaring Feats fom either an attractive or repulsive force. See also Conie sections on page 38. The comet branch can be chovea by inspection. «Also the focal points of the hyperbola “nis the numberof partis per socond pasing through unit area perpendicular to the beam.34 Particle motion B Inelastic collisions” @ €@:1@ 6 Ray | Sey il Before collision 1 After collision : hot e012) 3125) |. couticient of setition Gocficent of cat if perfety caste (3.126) | 5, preollsion velocities fees €=0_ if perfectly inelastic (3.127) | 9% Posteoltiion velocities T,T" total KF in 2e19 Loss of kinetic © T—T" ‘momentum frame energy? tone (3.128) before and afer . a | cation moe, Germ, (3.129) Final velocities sete eer my pce mass gamer, Crem, 3.130) 2 ite mem i “Along he Hnw of ene, mr3 Ee , 8p nero momen fame Oblique elastic collisions" | 65°? m; | Before collision "| After collision mo m/ | H, @ ange becween asin conte fine and Directions of 88° 5, — 0820 30) | Soin eocty motion %=8 (3.132) | 6; fina trajectories rm sphere masses >ax/2 itmm g—2mymcos20)$? j= bE Pmummcos28)" | 613) |» ae wey Final velocities mt cfm cos (3.135) | of Aina velocities Collison between wo peHecy dastc spb" my Hay at Fe velocities €e.4. 35. Rigid body dynamics ‘Moment of inertia tensor Dynamics and mechanics ‘Moment of | A r Poe Pae inerea ears 29 f(6)—32)dm C19 | ter de ‘Jor+24)ém —fxydm — —fxzdm eee eee t=| —foydm — f(xt+e*)dm — —Syzdm ‘dm mass clement —Jxzdm —fyzdm — fo2-+y2) dm, 2 position vetor af 7 (337) iat iy components of Ig=Thy—masaa (2.138) | 5 er nh mip Parallel axis ates neem eae In Tit (ci +a) (3.139) | axe aston rector of Iy=Tj+m(ia?5y—aa)) G40) | rie “Angular Faas Gist | 2 aner momcatn momentum © angular velocity Rotational Kinetic energy 77 3OF = plyorey @.142) | 7 dace every “Ig aie the moments of inna of tbe body. Ty ([A]) are Ws products of inertia The inegrale ave over the Body "The elipsoid is tied by the varce of consaat T. slums Principal axes Principal Th 0 0) fa eae moment of oho 3143) | 5, etapa mamma of inertia tensor 0 0 hs, Inertia J angular momentum aoe J=(harhorlses) (B44) | oy components of » ‘momentum long pineal axes Rotational Line? 3 doe ex Kinetic energy T(t thoi +103) (3.145) | 7 kinetic energy Moment of T= T(1,02,05) (3.146) inertia iT i iL clipsoid® Jom 5p, Wis ellipsoid surface) (3.147) " h us Perpendicular 21s generally = 3.148) axis theorem nen{eP fiat lamina 1 to axis O48) i L#¢h#l; asymmetric top ‘Symmetries I=hh#l; symmetric top (3.149) Js spherical top3.5 Rigid body dynamics 18 Moments of inerti Thin rod, length 1 (3.150) SE : Is Ty b=0 (3.151) Solid sphere, radius? h=h=ty= 2m? @usy |) ALY Sn 1 ALES) Spherical shell, radius 7 Solid cylinder, radius r, length f cm =m _ G55) L ham@+e)/12 (3156) Solid cuboid, sides abc T= m(c? +a)/12 1s) | gly, Js (+B?) /12 158) 2 P 2 Sold ira one, base i" (r+4) G59) ius, radius r, height bed? a hen +-ay/s (161) Solid ellipsoid, semi-axes 2 ~ mica) 3.162) ma? +B?)/5 (3.163) mb /4 (3.164) Elliptical lamina, mat/4 G.165) semi-axes a,b 3.166) i iE Pes ; (167) eh Disk, radius r ia @ ‘Triangular plate® HHH +2) 16) | hie “With sept Wo pina aos For ods of mass wand ulform Geniy. The radus of gyrnon is Olinwd a kam) SOniein of anes is atthe centre of mass (h/4 above the bas) “Around an ats through the centre of mass and perpendicular tothe plane ofthe plate, wo16 Dynamics and mechanics ‘Centres of mass Solid hemisphere, radius r -d=3r/8. from sphere centre (3.170) Hemispherical shell, radius r d=r/2_ from sphere centre feral) Soo a, eae 42 eat ete cam a ‘sof eel radius rangle 280 om cic ote a Arbitrary triangular lamina, ae ea et| ee i/3. perpendicular from base 3.174) Solid cone or pyramid, bight 4.4/4 perpendicular from base (175) Qr— hy Spherical cap, height h, solid: d= 7S =" from sphere centre (3.176) sphere radius r shell: d=r—h/2 from sphere centre 177) Semi-elliptical lamina, 4h eae d= from base (3.178) ‘Tris te perpendicular distance between the base and apex ofthe Wand Pendulums P paiod Simple Fa. # sravttonal acekraton on P=mli(te fhe) um | Ra a Va" t6 maximum angular place Conical se)” Pain 3.180) | = cone bleangle pendulum ( @ (3.180) Torsional i? moment of inera of bob iulume P= 2n (2) (3.181) | C torsional sigidity of wire —Z e (seepage 81) 4 dstane of rotation axis L F ftom cence of mass Saad Pat | 1 tnt +c 1 See nan pendulum? : 272 1, principal moments of : > feria Sr theo 7 +1300: )| aie) eee ee [eee Shan pincpa ser | 7 foal eeepc eae] io 1 m double Px2n i Po Tet G89) 2, precession angulae velocity 21 1 c0S0—-QpJs+mga=0 (3.190) | @ anal fom vertical Steady gyroscopic 911 inet i ita angular momentum around precession wf Meal (Slow) ia joy) | tame as P™ [us/M{cos8) (fast) im mass gravitons acceleration 4. disaoe of centre of mass Gyroscopic Mapai 192) | _ tom support point stability FReATimg. (3192) | oe noment of inertia about ‘apport polat Gyroscopic mit 2193) (sleeping top") Nutation rate (3.194) | 9, nutation angular velocity Gyroscope Te 5) |e ae released from rest 2 Js (cost) (3.195) “ co) where af)! (3201) Logarithmic A logarithmic decrement decrement* (3.202) a, mth displacement maximum Quality factor % if O>1] 6203) | 0 quleyesor "The devanan unl he ato of aucotve nglaconent nasa bats somtins fc beat wma displacement exroms, reducing by & factor of 2 Logins re smmtine taken fo bas 10 itroding further factor of loge Forced oscillations 7 oag vac Differential x dx 1 time equation gi 127g tebe Foe" 209 | 4 separ eet x= AeK-9), where (3.205) | ep undamped angular frequency Steady. A=Foll@3—af)°+Qyan711? 2.206) | 7 fee amps (pr wnt state os) (3207) | & foeng angular foqueney solution* scored ? A amplitude ‘ of response behind 6208) | ° Sarioxe Amplitude x, amplitude resonant forcing resonance? (3.208) | Sora egueney Velosity 2 eee resonant forcing Neleaty , @u= Oy (6210) | & wai masean Quality ae i factor 2 2y G21) | quality fete oo} Impedance Z =2y4i7t (3.212) | Z impedence (per unit mass) ‘Bicading te fee ofcllation tome "Forcing frequency for maximum displacement. “Forcing frequency for maximum Wlocty Note 7/2 at thi frequency3.7 Generalised dynamies 3.7 Generalised dynamics Lagrangian dynamics action =O forthe motion Action [ vaane (2213) | ¢ generalized coordnatss Is generale veloc EnerLagange 4 (2) 2g aay|t toe equation Ea) ag? G2] me Lagrangian of 4m? —U(n) 215) |! esc particle in 3 { (3215) |» position vector external field =T-0 3.216) | U Potential ners Tet energy smo (ont) ass Relativistic 7 Lovet factor Lagrangian ofa L= e(—A-v) (3.217) | +2 positive charge charged particle 7 electric potential: A magnetc vector potenti Generalised OL gaan" (2.218) | px generalised momenta Hamiltonian dynamics T Tagrandian | Hamittonian = )pdi—L (3.219) | py generalised momenta 7 generale veloc Hamilton's H Hamiltonian equations (3.220) | 4 generatod condones pai speed Lees = Fret + Ue) (2221) |? Paton tenor external field = =T+U (3.222) | U Potential energy 1 Miaeic exergy Relativistic ai Hamiltonian = (mict +p —eAl2e2)¥?. fetter ect earned H=Umbet Hip —eaPe"?-+e6 (3293) | epee tare pa 4 secre potent A. vestor pote (3224) ‘p particle momentum Poisson fee brackets (3.225) | fog arbitrary functions Ty] Poisson bracket (also see fang | coms on rae ‘Hamilton— Tacobi 227) | 8 action equationDynamies and mechanics 38 Elasticity Elasticity definitions (simple)? FA = ae tz Stress t (3.228) | F spnlied fore A crocsoctionst |] Strain ft (8.229) | 51 cnange in egth 1 enh ea ‘Young modulus p—~ jp —cons eae (Hooks aw) z/e=constant (3230) | F Young modut aie a Potton rao Poisson ratio? f (8.231) | Sw change in width out ve wit "Tes apply To a thin wive under Tongitadinal aes ‘Solids obeping Hook's law are restricted by thermodynamics to ~1<0 1/2, but one are known with ¢-<0, Non-Hookean materials can show @>1/2 Elasticity definitions (general) ; force {direction saaees Sires tort «y= SS eee 6232) | sy fume = usin emer (amen) Strain tensor a3 (He 7) (8.233) | me dsplacement | 1024 iO cordate yen Elastic modulus =y=2uew (6.234) | isu cate modes Bhatic energy? U= P/aueyeu (3.235) |v —potena energy fe Volume strain av. Volume sian ceatay 289] 3 Swe volume = (eui— Fevbul+ deb 8.237 Shear strain aur ar— seu) goede 237) | iy, Kronecker delta pear anion Faisal py con ee ‘eg aie ponmal ree, oF) aS toRTonal TS, as usual, products are implicitly summed over repeated indies.3.8 Elasticity 81 Isotropic elastic solids aS (8.239) | 42 tam cooticients ‘Lamé coefficients i E Young modulus (8.240) | «Poisson ratio. Longitudinal ‘My longitudinal elastic modulus* 3241) modulus: usin in ition (3.242) | cj sess int iseton Diagonalised strain tensor equation? 6243) | tear ener (6244) [1 uit max 0) wace 24 |x emai Bulk modulus modulus (compression (8.246) | votume modulus pesmi G27) T temperature = ee olume sain shear modulus = 3.248) 7 ii sid M ite) (3.248) ‘# shear modulus Asser drcecee eS (9.249) | samsene soos eer iz iy shear strain 9uK modulus a 8.250) ‘Young modu OE (3.250) ; 3K—2u ison ratio = 51 Poisson rat ORD G21) faa ae Aes lige! along eigenvector ofthe stress and sain tenors. Torsion 7 owing cn (fora =ct 3.252) ‘homogeneous Sar (3282) i anes rod) ae t : 2 mts juan ewer C= 2na? ut (3.253) | ¢ wall thickness cylinder ‘a shear modulus ‘Thick circular al ay inner radius alec C= 5umtah—aty (3254) | SAR mae Arbitrary tat oa [4 ee thin-walled tube aed pera Xt Long flat ribbon (3296)| | eager2 Dynamics and mechanics Bending beams* bing momar (2257) | me sau or cema z : sof exis a now cocaine a (3.258) | € distance to neutral, aimee” | Sarmey moment of area Light beam, Aisplacement from horizontal at 1 ’ hozontl (3.259) | 7 endewcight x=0, weight beam length atx! x stance along beam ey vw beam weit per —, Heavy beam BIE =w() (3.260) suit length nd PEL/P ree ends) | seats RK Euler strut = da2B1/l? (fixed ends) |* fee ayaa failure SEI/(A) (1 free end) | 1 set kage (3.261) fixed "The radius of curvature is approximated by 1/R.= @y/=" Elastic wave velocities sped of tee wave m= (n/p)? (3.262) | ny speed of fongitudinal wave In an infinite = (Mi/p)'? (3.263) | # shear modulus isotropic solid® 2-28\"? bp density 2( = 2) (8.264) | Mi tongiadina! mats a \i=2¢ Cara.) Ina fluid = (K/py'? (8.265) |. butk modulus 1? speed of longitudinal (On a thin plate (wave travelling along x, plate thin in 2) Se eth {9 speed of transverse wave (3.266) : (displacement |i) 26) | mm in twtr 24/2 (3.268) | plate thickness (in z, <2) 620) 3.270) | 2 wrional wave velocity @ rod rive (<7) 27) ‘Waves that produce “bending” are generally Gapesie, Wave (phate) speeds are quoted throughout Transverse waves are also known as shear waves, or Sswaves. Longitudinal waves are also known as pressure waves, or P-naves.38 Elasticity ‘Waves in strings and springs? peed of ongiadial wave fe sing conan? In a sprit (3.272) ited spring 6272) | 5 ee Pr mas pr wait eth? On a stretched (3.273) | % sPeed of transverse wave string 3 T tension Ona sesshed fe/p4)7 (3274) | ¢ tenon per unit width sheet _mask pe uit rea {Wave anplinds emuaed < warckagh bin the sence w= fore /eresion ‘Messed slong the ti ofthe spring Propagation of elastic waves force : eceeeaie Se impedance Acoustic I response velocity et F ae force impedance =(E'p)? . (3.276) | u strain displacement z Ee Wave velocity/ if =-(2) 277) | # caste modus impedance ? deny relation then Z=(E'p)!?=po (2.278) | © ware phase velocty Mean energy BG (8.279) | ¥ sree desiy density ae (nondispersive ee ae Danae ae nave (3.281) | p mean energy tux ZinZe ded ZAts (3.282) ‘reflection coefficient : tranitsion coeticent Gceerearedt t 221 (3.283) | «stress Zi+2y G aaa 4 ange of incense Snell's law? finds sind, _ in (3.284) | 8, ‘ange of etecton ks a = 6 _ angle of refraction ‘For sizes and stain ampliudes Because Ue vefcction aad wansmiion Gefen are usually ened ta tems of ioplacement, x rather than stress, there are eiferences between these coeicient and their equivalents defined in electromagretism [ee Equation (7.179) and page 154) "Angles defined from the normal to the interface, An incident plane presuze wave will generally excite both sbsar and pressure waves in reflection and transmission. Use the weloiy agpreprate fo the wave De.Dynamics and mechanics 3.9 Fluid dynamics Ideal fluids* Continuity? 2 £¥-(p)=0 (3285) Saas uid velocity field time Ta frrdtmconstant (8.286) Kelvin ciroulation = fi ‘ods (3287) 5 céteuation oop element clement of surface bounded by loop vorticity (Ve) eed. ae vi Steve Pag (3288) Euler's equation® - or £(Vx0)=Valra(Vx0)] (3289) pressure revitaional eld sengih (6-9) agvectve operator ‘Bernouli’s equation 2 altitude ratio of specific heat capacities (,/ev) ep specific heat capacity at constant pressure Temperate 7 (incompressible flow) xpe+ptpge=constant — (3.290) Bernouli’s equation +2=constant (3.291) (compressible adiabatic flow)? T+e2 3292) Hydrostatcs 3.293) ‘Adiabatic Ia tiedga 29 !No thermal condacivigy oF WBC08 te general. ©The second form of Euler equstion apple 19 incompresibie ow only “zquation (2292) tre only for an Weal gas. Potential flow : atv (3295) locity potent spate nee Vorticity condition = @=Vxo=0 (3297) velocity velocity potential @ vorticity F drag force on moving splere force on a eee ai oa (8298) | {Fane aeton iat p Suid density gpa fd mas Forinonprsie Bal Th fect ofthis drag force isto give the sphere an additional effective mass equal to half the mass of Ouid spaced3.9 Fluid dynamics Viscous flow (incompressible)* “yy Hid tee tensor hydrostatic pressure Neglecting bulk (6econd visoosty. Laminar viscous flow Fluid stress (3.299) | shear viscosity 1 loi along as 4 Komeda I uid vl fed Navier-Stokes pete 3300) |e oricy equation? YP Nee, gravitational acceleration Petvete 330) diy Kinematic —— nip (2.02) | + inmate vieosiy ‘ie, Ve=O 70 Tow windy 2 diction of ow Beewe 1 21 y distance from paral plates “OI=z,"h-w)GE~ G09) |” sane pe 1 ther scaty y 7 peu 304) |r detune fom Along a 8308) | pe axis circular pipe* av _ xa‘ ap 2 pipe radius i Oe 830914 rom trewlating G, axial couple between = 428 oan) * Benen ides concentric Peo) porta eng SM a rotating (3.306) | angiar velocity cplinders! of th eviner | ime aan Along an 0-52 [4-4 Ba a etna a annular pig s (a3/ ay ‘volume discharge ae 6307 |? omc Rama How Const fo Drag’ On a sphere (Stokes’s law) F: (3.308) drag force a radius On a disk, broadside to flow F = 16anv (309) [2 Testy shear viscosity On a disk, edge on to flow For Reynolis mimes <1 8310)86 Dynamics and mechanics Characteristic numbers Reynolds gg _ PUL inert forse 454 number 7 viscous force Froude uw ertial force number Tg gravitational fore 912) Stroubal Ut _ evolution scale number? ~D ~ physical scale 313) Prandil nep___momentom transport ep _ momentum transport (3 314) number heat transport Mach U___wpeed umber “e7 sound speed Cae Rossby U__ imertial force number Roma Coriolis force G316) Re Reynolis number e u L F 8 8 1 Ro Rossby number a density characters velocity characte scaleength shear viscosity Froude mumber gravitational acceleration Stroubal number characters timescale Prandtl number Specise heat capacity at constant presure ‘thermal conductivity ‘Mach simber sound speed angulac velocity “Sometimar the square root of tis expresion. L usally th Haid dept Sometimes the reciprocal of this expression. Fluid waves a 7 oa oad oe aa ‘K\" ap)" K bulk modulus: Somdwaves ya (E)"=(22) Gain) sions | Pp density, 7 of nat apes In an ideal gas 4 a2 Gedibats "(287)" (2) aatg |* ee i = : 318) | 7 abe empeae conditions} a fe | # mean molecular mass r oun spt of wave a= ghtanbkh (3.319) | ¥ gat cops Gravity waves on tyg\ia 2 mana aliquid surtace” 4,15 (E) 2 qagg) |e nevenuaber ant? nes) puvinonalacceraon & sogun etency iillary waves - ee oe (8321) | ¢ sutce tension Capillary-gravity waves (i> 2) a “Ifthe waves are otbermal rather than adiabatic thea v5 =(@/0)"™ amplitude wavelength athe limit > gp/e,3.9 Fluid dynamics Doppler effect? cae Va oe aay observer 3.323) |” Korieriaeety moving atu fa (ie sr k _ 8 Observer at # wosty rest, source G32) | ‘angle between w moving atu corer had pane wre A TaD TE Wave speeds pas oped fequney Phase speed (8325) | 6 guar fosseny (250 2 warckagth wavenumber (=24/2) (3.326) Group speed ep sed + 327) Shocks i weiss Mach wedge* sindy ="? (3.328) | vy wave (phase) speed ba vy body speed avd Ax characteristic Kelvin nate 6329) |* Sreenat wedge! y= aresin(1/3)=19°S (3.330) | € gezytonat stock Spherical eps 2 cw ris adiabatic ra(Z) (3331) |r time shock® Po (Po density of undisturbed atm 1 parca ae aon Pane Rankine 7eL P. prare Hugoniot 1 _ pa vel velocity Shock | tn ps GDH 2333) | emperatre relations! Ta _ BMI —N)R-+0— DM] Gitar? oe y ratio of sf ts rN G+lMt (3.334) : Pe ““Appronioating the wake geneaied by saperonic motion ofa body in @ nondiopersive medium. Ror gravity waves, ef in the wake of & Bost Note thatthe wedge eemi-ange is independent of vy. «SedorTeslor relation Solutions for a steady, normal shock, inthe frame moving with the shock front. f7=5/3 thea w/in <4.Dynamics and mechanles 38 Surface tension SEE 335) | ete nin cee surface tension Gitar suriece tension 3) | mney Tength Laplace's Tt 89 en iene haan over surface tome! (RR) OP) nea Capillary eae capi constant a lg deasiy constant e-(#) (3338) |¢ a pers i site Capillary rise 2oycosd i (Gireular tube) "=~ pga 389) 6 coma a "| eur wall/vapour surface Contact angle (6340) |. Sytguitsutice ‘Fora spherical bubble in a Wquid Ap=2y,/R For a soup Bub (wo Farlacs) Ap=4a,/RChapter 4 Quantum physics 4. Introduction ‘Quantum ideas occupy such a pivotal position in physics that different notations and algebras appropriate to each field have been developed. Inthe spirit of this book, only those formulas that are commonly present in undergraduate courses and that can be simply presented in [44 tabular form are included here. For example, much ofthe detail of atomic spectroscopy and of specific perturbation analyses has been omitted, as have ideas from the somewhat specialised field of quantum electrodynamics. Traditionally, quantum physics is understood through standard “toy” problems, such as the potential step and the one-dimensional harmonic oscillator, and these are reproduced here. Operators are distinguished from observables using the “hat” notation, so that the momenturh observable, ps, bas the operator Be=—ia/@x. For clarity, many relations tbat can be generalised to three dimensions in an obvious way hhave been stated in their one-dimensional form, and wavefunctions are implicitly taken as normalised functions of space and time unless otherwise stated. With the exception of the last pane, all equations should be taken as nonrelativistic, so that “total energy” is the sum of potential and kinetic energies, excluding the rest mass energy.20, Quantum phyjsies 42 Quantum definitions Quantum uncertainty relations A 4.1 De Broglie relation? 2 an pohk (42) Planck-Einstein a relation Di (44) dispersion” 45) (General unce aos General uncertainty (aap (asjta 5,6) (46) ‘Momentum-position i ‘uncertainty relation’ — 4P4*= > a) Energy-time he uncertainty relation — S24'= 3 48) ‘Number-phase 1 uncertainty relation "49> 3 (49) -P parle momentum pee P EE ab observabes* Planck constant ye) de Broglie wavelength de Broglie wavevestor came frequency angular frequency (=2nv) expectation vale Aisperson of a operator for observable a commutator (see page 26) particle postion ‘umber of photos wave phase ‘=Dispesion in quantum physics coresponde (0 variance in satis, "An observable ise irecly measurable parameter of a system. «Aloo known as the "Hetsenberg uacetaity relation” ‘Wavefunctions Probability b= olen? Sera tomy prixt) dx =|p(st)P de 410) | OF avefunction - 4d sob dense arent eH a (« eyo) (4.11) | i (ptamck constant)/C2) Probability a piussasnerore density [vel —vOIVy' Ee] (4.12) | & momen current® plate (413) | rea aot + time Continuity equation ae SchrBdinger (415) | a Hamitooian equation Particle aad potential ery | eicpr SO eveawd=Eve) 19) | foe eoey ‘or particles Tn thee dimensions aulable unis would be pavtces me Time independent Schrodinger equation fora partici in one dimension.42 Quantum definitions ot Operators Hermitian 7 Henin snore conjugate [oorve [eee (air) | * operator operator sora fneos Position (aus) | "complex convene operator | sp poston conto ‘Momentum fate integer 21 operator G19) Px Momentum coordinate : 7 Mowery ince enerey (4.20) | % (Planck constant)/(2n) a m particle mass ‘Hamiltonian: a1) ‘#H Hamiltonian operator (421) | potential exeray mn “Angular (422) | angular moment slong ‘momentum peorinereny operators (423) | 2 oul angus momentum > F patty oper =v" 424 Parity operator Py()=w(-) (42a |? aso Expectation value i @ eqs ae ofa Expectation @)=(@)= [ Wraver 625) | 2 Spemurtore value = (wlan) (4.26) | % (pti) wavefunction mil coordinate fs 427), Gas dependence 27) | (@lanck constant} /(2n) Azan of 8 Relation to aoe eigenfunctions (428) |r Sammy iter ce probably amples mm partie mass Ebrenfest’s 429) | position vector theorem > comet (4.30) potential energy "Tuation (426) wer the Dirac “bra et” notation for iniegrals Involving operator. The presence of vertical bars distinguishes this use of angled brackets from that on the lefchand side of the equations. Note that (a) and (@) are taken as equivalentQuantum physics Dirac notation Tim ipa ao on = f vim (431) | toe matic element Matrix element* parent = (alam) (432) | 2” operwor Suttons Bra vector bra state vector = (nl (433) | | ba Ket vector ket state vector =|m) (4.34) | 5) ket Scalar product (435) Gea v -functic Expectation waved ion (437) | & Pobstityexptade ‘The Dizas Bracket, Gdn), can also be written (yu va). 43 Wave mechanics Potential step* Vex) incident particle % 1 0 ‘0 eae 7 pane peal ay function veyn{o &0) (438) | 70. wep bis Yo (20) A Panck constant)/Qs) sem BRA nE <0) (438) | Ae ie ent Wavenumbers 9242 2m(E—Vo) (>0) (aq) | are mas = cal. cnn tion raid \ enc ira cocbcent FAmplioude ; transmission t= (44a) | * smpttewanssion coefficient ka coefficient Be Probability Fm GP) 443) | panies sone currents pee (aaa) | ele Bin ne “One-dimensional interaction with an incident panicle of ial envay E=RETY WE a) sags) | "ele function =% (x1a) (446) | paris nenunber eae Im(E+Ve) ((x\0 effect V+ Sma (452) | 5, Ramsauer energy \k/q_— even parity tanga= (4.53) ee (i odd parity ' i Pk? =2mVo/R? (4.54) ‘Ope Gimensional interaction with an incident parle of al eaegy E=KE+V>0, “Pato fax in the sense of increasing “Incident energy for which 27a", P| ~0, and (= 1. When E <0, kis purely imaginary.) and g are obtained by solving these implicit equations.Quantum physies ae (ira) function aes (455) Wavenunbery22namz ~~ el>a) 56) ad tunnelling constant Wx?m2m(Yo—E) ((x1 E Eigea- 8 \!?_ inx may. maz | Yne eigenfunctions fonctions Yie=( 52) sin sin in | ope toe dimensions (444) | tm cteaers 2 Energy BP me ciate HN we Planck eee Fa (Gt ETE) (465) ts | S] Mpa mass Density of arene HE) deny of Sats PE)ME=SOM*EaE (4.66) 2 et ‘Sino parce aa weal bar boone ie pan © =a yah re, The potential ‘sro inside and infinite outside the bo.44 Hydrogenie atoms 95 Harmonic oscillator Prana constants) Schridinger mn mas equation 467) | nt igentncion placement hi nm integer 20 fared (4068) | o angular fequency at Eq total energy in nth state (x/a)exp[—x?, Eigen- vt jae oo ee 3 Hy Hermite polynomials where a. (3) | Hermite L HiQ)=2y, Haly)=4y?—2 polynomials .y Hay) —21Fy-s(9) (470) | 7 SR varie ‘pie ao point cmgy Of te ono 44 Hydrogenic atoms : Bohr model’ mh or aos Quantisation Q orbital angular speed condition prinpal quantum sumer Go a Boke radius Bohr radius: reduced mass (~m) Me stetroni harge 2 stomic sumber Orbit radius hh Planck constant © Wen Ey tora energy of mh obit Total energy ) permit of fre spa im cleron mass Fine structure 4 fine sacar constant constant eres of fee space Hartree energy Ey =~ 4.36 10-5 (476) | Be Hare corey med Rydberg, mc? mae _ En Re Rydberg constant consent Re apa ae TD | Sere Rydberg’s Penis ian Ja photon wavelenath formula? Toa Reims 2 (ae ae, (478) | integer >n ‘Becanae th Bobs model ie tity a wo body problem, the equations we reduced mas, jm / (mPa) =, ‘where masei te nvcear mass, throughout. The orbit radis is therefore the elecron-nveleus distance. Wavelength of the spectral lie corresponding to electron transitions between orbits m and m96. Quantum physics ‘Hydrogenlike atoms — Schrédinger solution’ ‘Schrddinger equation Ev tn Ze tae Bon with a) Eigenfunctions (tym? 72\ tantieo= [SEM] (2) ears orred) (480) Smit yaad BELG) 3 OTe T= 1 with a= WeZ> Etta exey Total energy sare (4380) | oS permivity office space = 2b -10+1) eer o a ee (682) | cnr of ete n hie Radial SRG + I ST+DT (483) | assem) expectation fl roe mast of mules values aay (680) | Oe hee 2 Ze chatge of acieus apes (485) | Ae teezonc charge 3p. (4.86) | rf asocited Laren is ae polyoma eee 120,1,2,..0(1—-D) 87) | aia obit radio, a= ‘quantum ye Eyl (488) | ectromaucies separation numbers and (489) | y= spteial harmonics selection rules? (490) | a» Bobrradins = 2% 41 aan) 3/2 Map ar ae wpe Te tacingett Yaw = goa ge eos Ya =F gaa go *sinde’ a3 r BEGET) Fe yse Yow gig (21-2 ao GE (6-2) Leesa a? (61) Ts sesingetié ah e3c0s0— Ynsi =F gia (6-2) Se”sinde Yon= grein Be” “Geo OD ot 2 = ae sind costes You: ‘Fora sgl bound clecvon ina peviet nuclear Coulomb povealial (nonrelativistic and spin). For dipole transitions between orbials ©The sign and indening definitions for this fonction vary. This form is appropriate to Equation (48,44 Hydrogenie atoms Orbital angular dependence 3 orbital it (492) (493) p orbitals ay LP +Yacsindsing (asa) pe=Yicce0s0 (495) dp = stg (3+ ¥59) sin? 8082p (496) des = Fa =¥z")ccsinBecosBcosp (497) Ge da=YPoc(Bcor?#—1) (498) (V3 +Y$")ccsinBeosdsing 499) pa? Ys) ocsin’ osin2g (4.100) Yi spberieal ‘hermonis* 6,6 spherical polar Seordinatee “See page 49 for the definition of spherieal harmonies98 Quantum physics 45° Angular momentum Orbital angular momentum Lane (4101) | L angular mowextum La (4.102) | » —tinear momentarn eee postion vesor ‘momentum (4.103) | eemaud operators (4104 | sien por A (Planck (4.105) ‘constant)/(2x) til, (4-106) | 1 taader operators Ladder ne (icoto 2 ) (4.107) |" spherical operators (ors 30 (4107) | 0 mons LaYP =A +1) —mim-L DAY (4.108) | ByPaMsyeY" (20) (4.109) Eigen Ly =mny y (4.110) se einen tee em eigenvalues (m £1)RLL¥/"(8,0) (LLL) +1) (4.112) Angular momentum commutation relations Tapia momen Conservation of angular ?omencim momentum? Winta\=0 G13) | fy Hamitonin Ider opecotor Waly] =inl, (4.120) Gas) .La=int, (4321) (atts) ae (G.0,)=' (4.122) fae (4123) : i see 4.124) taf oe a ® a4 lafl= ) erga ae (ALI=.G1=0,61=0 27) ‘The commutation ofa and Bs defined as [ab] —ab—ba (ee pase 26). Similar expressions old for S and J. For motion under a central force4.5 Angular momentum 9 Clebsch-Gordan coefficients* A Ummm (Uno 23 Gime mt— mad APs) gS z Geng pee Aen fcvatie jm ma | coeicients 9 1/a3 13} fs im imst 2 ssn areata Dot aan exe alitea BML oe eae Rasa) saa Castayecieps or rales sede rami ve Rese 3 ao Banal aoa [a atis x(a] at 3/2x152] 4372 ears rap bees mona] 0 Brees] ay sata fas usher See Rae sa Seah as aa tops 0 iA A ve ous ais “3 vs Lethe 5) 3yax3/2i) oe Le isos 1 aati] a foes abs Pease Oras] a fiaseae ants ibaa Reausis ym] - ahs as iacas 0a] Rrojvis ue vio (ats 2 yop sles 2 tals aa i a0 ae ota a [ise abr. 4 1/20 a obs * an [iia sua ie i074 {ec sls <4 ye Lyftsalan aus of id wn 2x3/472) +52 feat ie “4 Samp ar| asa 2x2fe) 43 Cosa Sapa) | feats nahi 7s aap] a eteiawe iss 2] sa (ha sas whabt ss 1s pa ae propia ia an praises 2s 2s Eialan eso] tciius sie 0) a o aecie yh ery 8 ts “is is Us rae rio ara] |S Zaalaas ae ws i else us ase 3h tis “ate 340 : ash yr 45 ae maT ass [erate 28 eine o ofaas 0 an a. us 53 2 ata 80 to cal yr “ays Ss Or “Wigner cooicents” wing the Condon Shoriky Sgn ogmvention Note that a square root is asumed ‘yer all socficeat digits, 90 that "3/30" comesponds to. ~/3/10- Also for clarity, only vals of my =0 are ted Bere, The coefisens for my <0 can be obtained from the symmetry relation (j—m,—msfa—m) = (2)! Vymyligm stam).Angular momentum addition® (4.128) | 7,3 total angular momentum (44129) | LL oritl anguar Toul angular P=Lt+S+205 (4.130) | 5.5 spin angular momento momentum —— fy, =mjF Pm (4.131) | ¥ eigenfunctions . my magortc quantum Spin = IGE DEV iy (4.132) |" umber fy 1 Hx) eer ee ie Pyp(x)=tanhx 4.149) | yy Seana f * ‘number density of atoms yan toe Mean eB 8 = pa) fm Bohra magnesaicat (M=miateres (Jes) 4as0) Shee Bolen costar (8) for isolated, iB peeieeeogas spins (J=1/2) , (MMya=mastanh (or) (4151) | ap, ean magaetiatin for J=3/2 (and g)=2), OF en ensemble of atoms ia thermal equllbriam at temperature 7, each Wi tal angular momentum quanta number J102, Quantum physics 46 Perturbation theory Time-independent perturbation theory Tip wopertrbed Haniioian Unperturbed Aovn= Eve (4.152) | yy cigefunctins of fo states (wn nondegenerate) Ey eigenvalues of Ho miner 20 Perturbed or A perturbed Hamiltonian Hamiltonian fa fit tt 4153) ‘AY’ perturbation (¢ fla) Ea i Perturbed : apnea bee EL pertubed eigenvalue (24) ceigenvalues* pa te (il) Dirac bracket igen rire (ais) Poriurbed im : a nae Tet. (455 | poet demtacon functions” faerie "To second ore ott order ‘Time-dependent perturbation theory ‘He unperturbed Hamiltonian Specie wm eeafuncton of fly stationary lov = Enon (4.156) | Si ae states = ese i A perturbed Haitosian Perturbed (=. r( (f) perturbation Rerturbed A= Ma +4) (4150) | 9 prt semodinger n+ At} ¥e)—A (ass) | ¥en eae ¥(E=0)= 0 (4159) | (Planck constant)/(2x) Perturbed —¥(0)= )ealt)yacxp(—iEat/h) (4.160) wwave- 7 x robabliy amps function® where OFF f Wall @ipo)explilEn—Eo)t Md’ (4.161) : Ty transition probebity per Fermi's Fa Aaa) {ni tine om sate! golden rule T= WIA wo) (4.162) sate f AE) density of fina states To ira onde47 High energy and nuclear physics 4.7 High energy and nuclear physies 103, Nuclear decay 7 Toy mac oa Nacone decay y(n ()e™* (4.163) |" eacg ater tine Haltlife and (A168) | 2 dey constant i Typ baie mean (4165) | (2) mean iene Successive decays 1-+2-+3 (species 3 stable) N= Ni(Oe** > (4.166) ae 2%, popalton of eis 1 Na = Nao OWES) (4.67) | Na popaation of species 2 pean ees NO = NO-NO =e) +N (0) (144 AE THE) | gc o hy a , dq decay constant 2—+3 elit of partie Geiger’s law* (R—x) (4.169) | x distance from source Geiger-Nuttall isalsierecod Geiger-Nutall Jog 75 clog (4.170) | ie constants for each seen Bandy For a particles in air (empirical), Nuclear binding energy Liquid drop model? * ahha 2 ay NOP 2 Ba aA— ada ay +5(4) peepee (4171) | a, volume em (~158Mev) +a,A-** ZN both even ea gel eeety eConom te (~072Me) Oe eee heen (4.172) | asymmetry term (~235MeV) otherwise pang erm (~235MEV) ae MGA) stom mass Semiempiisl M(Z,A)=ZMir+Nrmy—B (8.173) | ye mss of hydrogen atom ‘Coeficent values ae exprial and approtimate- Quantum physics ‘Nuclear collisions sale oven rate weit Wine OM ESETE PETA 179 | 4 nominee sina att (4.175) | E total energy (PE + KE) 25+ YQ +1) ‘Ey resonant energy Tt of sonata & soe ae (4.176) | ray pari widt into a+ To patil with oo € eons ine Resonance J otal engier momenta lifetime (4177) |" Guantam aumber of R sink. ‘Kr Bom scattering 97. formula? a vera (A178) | adie distance ap spinn of ¢ and ME diferential colsion reduced mass aout (8 footnote) Vie) potential energy of interaction Molt scattering formula® 4B x, Aoos(Intan?f) 27° ~ sin? feos} J org ant als Ble x (4.179) | » closing velocity —12 RC in the ceae Of mas fame. ‘Rutherford seaterng formula (page 72). Relativistic wave equations* ora cental field. The Bora approsimation bolde when the potential energy of catering, V, is much less than the total Kinetic energy, K isthe magnitude of the change in the particle's wavevector due to searing ‘For identical particles undergoing Coulomb satering in the centre of mass frame. Nonidetical particles obey the (massive, spin where aun (S a) 1/2 particles) aoa OFaks G'P=07P=0°F Klein-Gordon fa equation —_ (massive, spin 181) |» oot zero particles) faeet Taste min Ya (oY rae.) cater) |S Borie mnene 1/2 particles) Oe Ox Oy Oe : cee (iy*Gu—m)v=0 (4.183) | oo Diss trices: assy] P=(6 5.) (G4 fy noen init matic Ay (4.185) ‘Wen in natural waits with ==.Chapter 5 Thermodynamics 5.1 Introduction The term thermodynamics is used here loosely and includes classical thermodynamics, statis- tical thermodynamics, thermal physics, and radiation processes. Notation in these subjects ccan be confusing and the conventions used here are those found in the majority of modern ‘treatments. In particular ‘The internal energy of a system is defined in terms of the heat supplied zo the system plus the work done on the system, that is, dU=@Q+aW. The lowercase symbol p is used for pressure. Probability density functions are denoted by pr() and microstate probabilities by p, With the exception of specific intensity, quantities are taken as specific if they refer to unit ‘mass and are distinguished from the extensive equivalent by using lowercase. Hence specific volume, v, equals V/m, where V is the volume of gas and m its mass. Also, the specific heat capacity of a gas at constant pressure is cp=Cp/m, where Cp is the heat capacity of mass m of gas. Molar values take a subscript “m” (e, Yq for molar volume) and remain in upper case, ‘The component held constant during a partial differentiation is shown after a vertical bar; ence gl is the partial differential of volume with respect to pressure, holding temperature constant The thermal properties of solids are dealt with more explicitly in the section on solid state physics (page 123). Note that in solid state literature specific heat capacity is often taken to ‘mean heat capacity per unit volume.106 Thermodynamics woe Ther oyna 5.2 Classical thermodynamics Thermodynamic laws 7 tenmodjaani operate Thermodynamic im m icapaate Tec lim(pv) (5A) | sium of «Sed mas of sas P saspresure lim(pV)r K kelvin unit Kelvin Lim temperate sale T/R=276Cfpipyy, 62) | # seperti at 4 ehange i tera exergy First law? au=a9+aw (53) | aw work dae oa system (20, beat supplied to sytem experimental entropy Entropy® (54) | 7 temperature s_ reverie change ‘Thermodynamic work* ‘Sag Recmaiaed wih & gas themnometss The Wea of temperature ie associated with the zeroth Taw of ther- rmotynarsics” If two systems are in thermal equilibrium with a third they are aso in thermal equliorim with each ther The @ notation represents diferetil change in quantity that i not a function of state of the sytem. Associated with te second law of thermodynamics: No process is possible withthe sole effec of completely consertng, eat into work (Kevin stateren). Hydrostatic gy pay (55) pressure Surface tension ¢W=yda (5.6) Blectric field © GW=E-dp (5.7) Magnetic field ¢W=B-dm (58) Electric current ¢W=Addg — (5.9) pChydrostatic) pressure 4Y volume change EW work dove on the system surface tension change in aren electric field induced electric dipole moment smagntic fox density indeed magnetic dipole moment potential diference charge moved erry ene "ie sours of sais and magnet feldk are taken as being outside the themmodyaamic sytem On which they ae working.5.2 Classical thermodynamics Cycle efficiencies (thermodynamic)* 107 Heatcodan = Taw ST io) | awry Refrigerator y= Matenmasied < Th (stn) Heat pump y= Mest supplied (612) Ono getty = Maen 603) / 7° atti "ealised reversible “petrol” (beat) engin. Heat capacit = e aes sig | F volume F ¢ : — 19/9 516 Difference in ee Pp heat capacities er a (317) oes oH | ‘Thermodynamic coefficients be wobare (5.19) | expansivity* r Totiernal * compressibility 620) P ‘Adabate ‘compressibility (21) | xs ermal otis (322) | ke Adiabatic bulk modulus (5.23) | Ks “Also called “ais expanshiiy” or "Yume expaminity” The near expanse ‘The equalities are for reversible Gyles, such as Carnot eyles operating between temperatures Ty and Th ‘eal capacity, V constant eat temperature volume internal energy entropy ‘beat capacity, p constant pressure enthalpy ‘aobaric expansiviy ‘sothermal compressibility ratio of heat capcities aiiabatc compressibility Teobaris expansiay volume temperature Isothermal compressibility pressure adiabatic compressitiity {isothermal bulk modulus adiabatic bulk modulus Pa108, ‘Thermodynamics 7 Toa exec Tempera pressure inter exer Cy eat capaci V constant - Yoxde-Kelva ooeficnt ¥ volume H etbalpy pet capacity p constant "Expannoa Wi Ho Gang i nteroal energy 2EcDunnon wth 0 change in enthalpy. Algo know ata “Joue-Taomson expansion” ot “trong” pros. ‘Thermodynamic potentials? 7 iotemal ery 1 tenpeatue| Internal energy aU=TdS—pdV+ydN (528) |S extony chemi poteatal 1 mumber of parle Baa =U+pV (529) | # eats nthalpy 7 Ppresure aH=Tds+Vap+udN (530) |, ame Helmholtz free U-TS 630 ze een cneray" aF=—sdT—pav+ndn (532) |" BA ~ G=U-TS+pV (633) Gibbs free energy P+pV=H-TS (634) |G Oibbs tee enerey dG=-SdT+VdptuaN (535) | OTP s36)| , ae See venue do=-sdT—pdv—Ndy (537) |° PO oe =SdT + Vdp—No (538) relation A avalbiy panes A=U-TS+ pV (539) |, cenperaute of pee dA=(T—To)dS—(p—po)AV (540) | surroundings 1mo_presure of suroundingt Dior a dosed Hatem Sometimes elle the "work function” ‘Sometimes called the “thermodynamic potential”5.2 Classical thermodynamies Maxwell’s relations 109 TU iateral neray Maxwell 1 (S41) | 7 temperate Y volume Hensley Maxwell 2 (542) | §eatony P presure Maxwell 3 (543) | F Hetahot fice enrey Maxwell 4 (544) | 6 Gibbs fee every 7 ota ee oy (645) | U jn cry © Gites eomay (646) | entaipy 7 cope (647) | prea Y_tolane Phase transitions ‘L (latent) heat absorbed (1-2) Heat absorbed L=T(S—S1) (5.48) | T temperature of phase change 3 entony Clausius-Clapeyroa Oe ee equation nme ces (2 phe ates Th) (5.50) | 1.2 Pt Coexistence curve? nryccexo(Z#) (5.51) | 2 moter gas constant ir. Sp _ ba Bo (552) | fy isobaric expansivity Ebrenfest’s OT era—er1 or isotbermal compress exuaton! 1 Cane ig55)| hates poo a Beat aac (peo WFig-ia : Pnomber of phases ia issn Gibbs’s phase rule P+F=C+2 (5.54) | F number of degrees of freedom [esuecamtaas ‘Phase boundary gradient fora fstorder transition Equation (350) i sometimes called te "Clapeyron equation” For ¥2>>V;,e8, if phase 1 is 2 liquid and phase 2 e vapour Fora second-order phase transition.110 Thermodynamics 53. Gas laws Ideal gas Joule’s law u=U(T) (GSS) eterna 7 tenperature Boyle's law pV |r =constant (5.56) |) me Equation oF state py number of males (Ideal gasiawy PY "AT 557 | on pe coat pV? =constant (5.58) Adiabatic (559) | » rato of hea capaciies (Gp/Cv) a (5.60) | aay work done on sytem (361) Tinternal energy (562) Reversible pee isot AQ=nRT In(¥ Steerer eect saateaeienlaeidy 63) | > inal and fil ses Joule expansion® AS =nRin(V2/Vi) (5.64) | 48 change in entropy of the system Virial expansion "Since AQ=0 for a Toale expansion, AS W due enely to Brevenibllty, Bosause entropy i & Function of state it ‘asthe same value as forthe reversible isothermal expansion, where AS=AQ/T. temperature rear (9 2D) Visi expansion 65 pe PAD) (565) vi Boyle B,(Ts)=0 (5.66) Purse pressure volume solar gas constant temperature rial coecients Boyle temperature3 Gas laws Van der Waals gas P pese Vg mola volume Equation of state (5167) | molar gas constant 1 temperature ‘ab van der Waa’ constants (5.68) | 7, critical temperature Critical point (5.69) | jo crite presure (5:70) | Vie evita! molar volume aeacneas me Pie te (5:11) |; Vaio q -1/% Dieterici gas P presure Yq tla volume Equation of state (5:72) | R nolar exe constant T tempat 1. Dinter conta Tema /(4RD’) (5.73) | To coi tempersture Hs ab ye cca preware Critical point jae) (7) | eee eae (575) |e” =ame, Reduced equation ane cree Pe (5.76) | Ve =Va/Voe T._=T/T : Dieterici gas 4 18 12 16 1 14 12 = 08 £1 06 os 04 06 oa 02} fo. 02 0 0 (Geere itera teasers Qe eee attests2 Thermodynamics eee CEE 5.4 Kinetic theory Monatomic gas ? Pressure (5.77) | m @ ¥ volume Equation of state of an ideal pV =NET 57 |*, Batansna oman eae T temperature 3 Non e Internal eneray U=3NkT=Sm{c*) (6:7) | viata ene Cy=5Nk (5.80) G_s “ i Gr beat capacity, constant ¥ Heat capacities, Gy-=Cy +Nk=5Nk (5.81) | cheat capaci, constant p 1” rato of eat capucites CG 3 (682) Ea net ap 5 entropy Se sem (ME) "eM h] an] 2 ee amnen equation)* Dri © 271828. Broglie wavelength, 2, approximately equals n@", ‘Maxwell-Boltzmann distribution’ “Foc tke econ es Toe actor (AZ) ite quantum concentration of te pris mT heal reise get itden(5r)"m0 (SE distribution 684) Particle energy 2EW? distribution = PAE) GE = Srger Tae (Ge) dE (585) wer Mean speed (y= (HT z speed (e} ( = ) (536) sms speed (587) ‘Most probable no ‘De probabiny densi me particle mass Boltzmann constant T temperature partie speed E particle Kinedo energy (=me"/2) (2) mean speed ems Foot mean squared & most probable speednetic theory 113, 5 Kinetic theory ‘Transport properties T mean ice pat (5.89) | 4 molecular diameter parse mumber density Mean free path Survival aoa pe probability equation? Eee 690) | ea distance Flux through a _1 J woleclar Bux plane tagn (590) | (mean molecular speed Selfitfusion J=—DYn 692) 1 D> difion coefiient Be (593) HE bat Sx per ut area (589 | 1 smal conductivity Thermal (595) | 7 tapeatare conductivity » deasiy (596) | ¢r speci eat opacity, 7 constant : 1 z dynamic viteosy Viscosity = 5ple)=pD (597) | x displacement of epee in SE dimetion ater tine [Browalen gp, | Batman constant were tm ETE fay) fea sphere) ma a sphere raius ‘BE mats How rate Free molecular dM _4R} (2nm\"? (py po Ry pipe radius fow (ease (A) (Benge) |e peeks ow 1 TE Go) | m pare ase presse ‘fora petec ins of ard sphetal parties wi a Nanwel-Boizmann sped tiburon. Spobabliy of taveing distance x without a olson Prom te ide where the mimber deny, asuming en isotopic velocity dstibuton, Also know a “olsion umber” "Down a pipe from end 1 40 end 2, assuming p difion coefiient Be (593) HE bat Sx per ut area (589 | 1 smal conductivity Thermal (595) | 7 tapeatare conductivity » deasiy (596) | ¢r speci eat opacity, 7 constant : 1 z dynamic viteosy Viscosity = 5ple)=pD (597) | x displacement of epee in SE dimetion ater tine [Browalen gp, | Batman constant were tm ETE fay) fea sphere) ma a sphere raius ‘BE mats How rate Free molecular dM _4R} (2nm\"? (py po Ry pipe radius fow (ease (A) (Benge) |e peeks ow 1 TE Go) | m pare ase presse ‘fora petec ins of ard sphetal parties wi a Nanwel-Boizmann sped tiburon. Spobabliy of taveing distance x without a olson Prom te ide where the mimber deny, asuming en isotopic velocity dstibuton, Also know a “olsion umber” "Down a pipe from end 1 40 end 2, assuming pm) ate eee ueue ee a 2a Hee ec on/p! 2(a/m)" = : ae — l ° | xi" [NE : | (22/mz)*” TT k | | | on = 5 ok =F monatomic chain diatomic chain “&)- (634) [© von nerfs Monatomie ain ena linear chain (5) "sie(D) (635) | 5, phase speed (sinex= 425) % group speed (636) | 2 phoaon wavelength A wavenumber (=25/2) pane wa @ atomic separation Tears | (637) | m_stomie mass (>) 1 reduced mass (Emm fom +m) Identical oP BF2 4 12 24 omarcoska)!/? | % altemating spring contents masses, mm alternating, (6.38) td spring O, Aa +o)/m ifk=0 Laie, 3 Sous of AS TE, oom] “Along fale Hear sonic cians, considering sinpe hamnonl are acghbour VeaGoes cay The Wade ‘egion of the dispersion relation is outside the first Brillouin zone of the reciprocal lattice. * ia the sense x fring force/raatve displacement. ‘Noe that the repeat distance for chis casi is 2, so thatthe frst Bellin zone extends to [ki <1/(2a). The optic tnd acoustic branches are the + and ~ solutions respectively.130. Solid state physics Debye theory DH man weayhamok wo perptonon (@)=} fe (620) 0 green ee phonon (E)= Shot — Me _ phonon ery Be On * spa beens! Temperate i fom Date (engl) fremseney Debye momen iV" (641) | OP etectve sound sped freq ie caaegengeegs acy |e oom par pond ion eeti deere note (642) | name pe pd N-number of tom nesta Debye 6p =hop/ke (643) | v_ crystal volume temperature Sp. Debye tnertae He) deaty of ate Phonon (648) | Cy beat capaci, ¥ constant density of thermal poonon enerey states stim est 4s) Debye freon ean PMT capacity cy nine [ wor ¢ S) o Dulongand 3k (T > 60) (645) Petits law ebye T? a yg T? ee mee a a a LA peerintanae ee 6.48) Internal una I's sate T= (648) thermal i energy? where pw=4 3h a= ea (6.49) [Or aay Ganj Faron oollaor in thermal equilbrium af Temperate T. Negleting naropoint enerzy4 Lattice dynamies 131 Lattice forces (simple) ionic crystals) Van der Waals interaction? (650) (651) Lennard-Jones 6-12 potential (652) (molecular exystals) (653) De Boor h parameter etme on, Coulomb interaction (655) co) % & « AB ele ‘wo parile potential enezy parte separation article polaisbility (Planck constant)/25) permit of fee space angular frequency of polarised orbital constants Lenoasé-Tones parameters 6 Boer parameter Planck constant particle mase lattice Coulomb enersy per ion pair ‘Madelung constant tectonic charse nearest neighbour separation Lattice thermal expansion and conduction “Tondon’s Tormula Tor fctuating pele interactions, noglocng the propagation Ue beiwoen particles a phonon gas 1 phonon mean free path ‘Umklapp mean free path® Jy ocexp(0./T) (659) |, umblapp mean fre path 8 _umklapp temperatare (~@/2) aes 7 Giiaeisen parameter (6.56) | « — normel mode fequency parameter? a 4 lnees expansivty ; Kr isothermal bulk modulus Linear expansivity® fo feeder temperature Gy etce beat capacity, constant Thermal 2 thermal conductivity conductivity of (6.58) | 2, efective sound speed ‘Sire, the Grinelsn parameter bts mean GF ove all normal mods, weighted by the mode's contribution to 80r “coeticient of thermal expansion” for an isotropically expanding ental ‘the scattering of phonons outside the fst Brillouin Mean fee path determined solely by “umklapp procesSolid state physics we 65 Electrons in solids Free electron transport properties J caneat density nn fice electron number deasity Current density — J=—neva (60) |", eee a mean alexa dit velosty ae veep |" mypete beens tain drift velocity aia ae dd, electrical an | Eset conductivity (662) | 4 ae conductivity U=eE) ‘ac. electrical % © ac angular fequeney = 3) fe ety — Toa 6) | coyas consuviy ae Cy tal ltr heat capacity, V content a aren (6.64) | V_ volume Thermal 3 (2) mean square lect spend conductivity (P< Tq) | #2 Botemann contat Temperature (6.65) | rp Fermi temperature ‘Wiedemann ar Loren constant (224510 WOK) Franz law are Be (6:66) |, thermal conductivity Jy ‘Ry Hal coeticiet be By Hatewenc tee — LBs fp J. applied caret density [7 | ‘b magnetc fx deasty, (C774 [Halwa Vg Hal youuge Ve (rectangular (668) | Le appli current (=. erosional es) strip) ve _ sp thicknes in "Foran deve Bala vanog ws = ‘Mllds for an arbieary band trocar (Holds foe oar ron in ve, where ¢ i the clementary charge (approximately +16%10-C). The Hall SO SEATS reir a negave number when te dominant charge carers ae cetons65 Electrons in solids 133 Fermi gas V (im)? E denron amy OO) tron demsty E— z(t) B® (665)| ge eaig eras of states* Preis eae (670) | me Sextronie mas (anc comsasty(2) Fermi eas se Femi wavenumber wavenumber r= Gen)" (671) |» tuaabe of eeetons per unit Fermi velocity or=hkr/me (6.72) | op Feemi wiociy Fermi eneray (T=0) (6.73) | Bs Fermi cacrey Fenn Te Fermi temperature temperature (674) | 2 Bolumenn conssat Electron heat 675 ‘capacity? (675) ‘Cre beat capacity per electron ren (erg [7 see | Total kinetic aed) (627) | Up wat Knee enrey Sn Pat agai ucepity nae M=jueH (678) | Ht maga Ste srenh 3n 2M magpetanion i Paramagnetism = Fou (679) | po permet offre space fe ote magneton Landau sin, Landa magnetic diamagnetism = *#t (680) suscepebility ‘The densi of sales often quoted pr wit volume aad pace Ue SEIT ew) Equation (675) hols for any Ges of sates Thermoeleetricity 7 eisosienial Baa? Thermopower? 45:07 (681) | 4 cent density 2 eit conductivity Sr dermopower Peltior effect. = -H=IIJ—VT (682) | 7 temperatuze AE beat x per uit area Kelvin relation 1I=TSp ‘ (683) | 7 Pie cociient 2 thermal eonduetvy £Or abaalate ena pow” ‘The electrochemical Geld is the gradient of (u/e)—d, where sis the chemical potential, -e the electronic charge, aod the ela potenti, :134 Solid state physics Band theory and semiconductors Faction digest lochs theorem WHR expe OH) (684) | se ecor positon ves fy ckctton vl (for waverestor » Electron 1 conta aie = ZTE) (6a) |» Pana carne ft) corey bad Effective mass PEK) mij elective mass tensor a mar (Se (686) | A components of ‘Scalar effective, _,)[02Es(k)] rt scalar effective mass oa =f ae snp Si pace motiiy Se ean dit wloiy applied cet eld Mobility (eat) eee D. —didusion coeficient 7 temperature aa J carentdesity eee T= (ete + man yeE (6.89) | nay electron, hole, umber densities zi ‘Han Clectron, bole, mobilities fe (haT)? «e329 Bul hy Boltzmann coastant eae rem = eM SaltheT) | Fand gap cn (6:90) | my letz00, ote, effective masses {$$$ came iy Ig satan cent [=f [ew (&) = (691) | Fas voage oe forward BT intrinsic carrier concentration a Ds aca of uncon pajuncion BONA (Bact a) (692) | D5 eon ta, ison Len Oen} 2 (633) Lax electron, hoi, diffusion lengths (Dyes) (6.94) | cy electron, hole, secombination Nya acceptor, donor, concentrations i \ jai Tor Teions Of Papas Te which By(h) can be tka as idependeat ofthe direction ofChapter 7 Electromagnetism 7.1. Introduction The electromagnetic force is central to neatly every physical process around us and is a major component of classical physics. In fact, the development of electromagnetic theory in the nineteenth century gave us much mathematical machinery that we now apply quite generally in other fields, including potential theory, vector calculus, and the ideas of divergence and carl. Tt is therefore not surprising that this section deals with 2 large array of physical quantities and their relationships. As usual, SI units are assumed throughout. In the past clectromagnetism has suffered from the use of a variety of systems of units, including the ‘gs system in both its electrostatic (esu) and electromagnetic (emu) forms. The fog has now all bat cleared, but some specialised areas of research still cling to these historical measures. ‘Readers are advised to consult the section on unit conversion if they come across such exotica in the literature. Equations cast in the rationalised units of ST can be readily converted to the once common Gaussian (unrationalised) units by using the following symbol transformations ‘Equation conversion: SI to Gaussian units em 1/4) Hoda Bo Ble te>4ngs eda Hcl (an) A-Alo MucM Di D/(ax) ‘The quantities p, J, E, , 6, P, é and y, are all unchangedEe seeeeseeeeen 136 Electromagnetism 72. Static fields Electrostatics aaa Electrostatic vant potential ei potential a Potential potential at b difference as ca eae charg densiy Poisson's Equation yg. —F (73) | ey pect oF (free space) e0 ‘free space = Eto (74) imac Point charge at 7 ~~ point charge as vations yk fa ae de vome cement charge distribution £0") “pre 8) | postion year (free space) “biaoe : ‘cteeza pois @ tad aoa a PRE Magnetostatics” Magnetosta ts 7-5, “sagaess ar | Magnetic scalar po age an\. me potential 7 2 manele | ga inten of ie solid angle of a bani cn |® snp ee generating current an Toop, : 4 in dementia Biot-Savart law (the dh") as) ae dieton o aa feld from a line sg or eC 2 Pete , current) lie a Bee Serer oeceaeeese eee Ampéce’s law VeB=, (7.10) | jo permeability of (diferential form) bat renest ‘Ampére’s law (integral fo ae ay | tialeaent form) Hols i ‘tough loop Sin Tice ae12 Static fields Capacitance? ‘ Of sphere, radius a Cadzeona (7112) Of circular disk, radiusa— C=Beveea (733) OF two spheres, radius ai Coenae ain aa contact : OF circular sold eylinder, —_¢— "anna 7 radius a, length 1 CoB +AlU/aP Moe. Aire Of nearly spherical surtace, G~3439x19 Hes ary area S Of eube, side a 2728310" ea aa) Betwoen consenttie sphere —ananeanboay? 7 radii a>a nb (a!2-2) “For carats confined tothe sures of pion condasion Ia We space per unit length, (24°>-a) 725) (7.26) 137138 Electromagnetism Electric fields* Uniformly charged sphere, radius a, charge q Uniformly charged disk, radius a, charge q (on axis, 2) Tine charge, charge density) 2 per unit length FO=st (7.29) lectrie dipote, moment p (13) f (spherical polar o coordinates, angle oper between p and r) (731) ‘Tharge sheet, surface [ey density ¢ For g-=1 in be oding Magnetic fields? [Uniform init solenoid, aa Saeaeaeea] carrent I,m toms per unit B= {eer inside (axial) 73 feng 0 outside Uniform cylinder of _ fuotr/Ona) dees momet Generalised electric cast |p See cemiy dipole moment Ge woh element ? vector 4? & Gio pote Electric dipole (72) | * ete fom dipole potential fo pei of ee te | Dipole moment per Ppl ‘unit volume P=np (783) |» ‘number of dipoles per (polarisation)? nt whe Taduced volume aaa ee eae aa (788 | pag von gy Tadveed sarfacs (ras) | toe sre charge diy charge density ton) + ‘unit normal to surface Definition of electrie Dect dlopacenent =e 786) displacement ona (7.86) E eectric field Definition of eects p—, te decal smentity susceptibility coe an (nay be a tensor) fini A+xe (7.88) Definition of relative ee lave peg permitivity? — (789) | F ermitvty =E (7.90) Riomie a 2 polity polarisability? eee (791) |. ea erie Sd Ey depoaing eld Na depolariing factor 1/3 pe) (792) =i (hin sab 2 to) =o thin deb | 10 P) 1/2 Gong ccalar Slings ane 10 P) Depolarising fields Eg. Clausius-Mossotti na ex equation! 3eq eet? ‘Assan apo ae prac. The cquvalet of Equation (7-112) bolds for «Bot gar Of Seetc dipoles 'Ratative permittivity as defined ere i fora liner isotropic medium. The polansahility of a conducting sphere radius ais z= rego! The definition pag sso used. ‘athe substitution ey fet Equation (7.195) with ue= I] tis is also known asthe “Lorentz-Loren formula” (793)74 Fields associated with media Magnetisation : Ge dipole monest Definition of 1 oop eurent magnetic dipole (7.94) | 4s loop area (right-hand moment sense with rept to toop cuenty mole momeat Generalised magnetic dipole 195), mace moment Pyetr to de f= mate Magnetic dipole dlr) (796) | + vector from dipole (calar) potential nF 5 eras ince Dipole moment per M-agneiton unit volume M=nm (7397) | m umber of pts (magnetisationy? per unt volume Induced volume oe Jat volume curest current density acre 798) sity Ge, A) ng sce creat Induced surface ae desig Ge, A) current density aoe (799) | sai onal 0 mite | Deiaition of pages fi density magnetic field oH) — (7.100) | agnosie nis strength, suena (7101) Definition of a magnetic magnetic ae Soe (ed susceptibility ais tetas) (7.104) Definition of relative (7105) | 4, selaive permenbtty permeability’ (7106) | permeasity (707) ira) ‘Aspuming all the poles ae paral. See Equation (7112) for a dasscal paramagnetic gat aad ‘page 101 for the quantum gencralistion, ‘Relative permesbilty as defined ere is fr linear isotropic medium. 143, iHaad lees sdsdndasasenaaadasenasdncenseeeeee Paramagnetism and diamagnetism 7 (7) ‘mean squared orbital radius Diamagnetio (ai deseo moment of en atom (7.108) ) = seniommnter nent fx dey ne son mae 7 atone are Intrinsic electron J) total angular momentum ragastio moment "~~ Bry (718) | La tne 2 a : G(x) =cathx—* (7.110) Langevin function x 26) tanga action ~x/3 (x21) (7111) Classical gas (Mf) apparent magnetisation paramagnetism (=m (BE) rary) | aged often ple (>) nn dipole number density: 7 wenpenue Curie’s law (7.113) | k Boltzmann constant fae mere ces peel of i se Crie-Weiss law aang | meio Sea Fae Paalel Perweueat ofthe Fy continuona .(7Ats) |! Spore ent dle el FerpendiculiF : component ofthe, coatiauous (7116) ) "eens © magnetic fox reat density Diz seta denen pent) Electric & = unit normal to surface, $Dy-D)=2 st displacement? (Pa Dr) (7437) directed 12 ose deny fe oe sng mand sags EE aan meen raat maaates strength’ aH), ce ie ee ate a "AY the plane srface between (vo uniform media, Sita=0, then D, is continuous. if j,—0 then Hy is comtinuows2.3 Force, torque, and energy 75 Force, torque, and energy Electromagnetic force and torque 145, Force between two static charges: Coulomb's law Force between two current-carrying elements = Ha al aad a (7.120) aF, Force ona ‘current-carrying element in a magnetic field GF =1dbkB > (7.121) Force on a charge (Lorentz force) FeqE+eB) (712) Force on an electric aes F=(@-VE- (7.123) Fores onamagnetie paGm-yyB (7124) owe Gipole GaprE (7.125) oa ce 7126) Torque on a Gan f ralatyeB) (112) current loop op Fe a2 ah, Tors on fe barges vector from Ito 2 permittivity of fee Space line elements currents flowing along iy and dl, farce on dlp permeability of free space line element fe current flowing along 6 magnetic flux desity clove fle charge velocity electric dipole moment magnetic dipole moment rogue Hine-element (of lop) position vector of dh, utreat axound loop ‘EF simples to Vip-E) i pis intinsie,VipE/3) i pi induced by E and the medium i isotropic. °F simples to Vm-B) ifm is intrinsic, VomB/2) if m s induced by B and the medium i isotropic.146 Electromagnetism Electromagnetic energy Electromagnetic field i 1B [To eneray deasity energy density (in free uw: xo ta, (7.128) : eee ie 22) eo peritvity of fee space to permeability of espace eee foeewny — 03)| 5 Se a ‘H magnetic field strength sped flight Energy flow (Poynting) yy pay (7.130) | jv Sheep fw rate per uit ‘veoor ‘area to the flow direction spite of dipole moment Mean fux density at a neue Pir fom dipole Gistance r from a short (N)= 222352, q3yy | Conran oscillating dipole Baxter? © angle between p and r © onsllationfeqency Total mean power as from oscillating we wae (7.132) | total mesa radiated power Seve Us total energy 1 drome eenent, Sel-enery of a 5 f{ dlr)p(r)dz (7.133) |r postion vector of de charge distribution aye ee > charge density i Yi potetil of th cepastor Energy of an assembly 7,5 SS CyViV) (7-134) | cy mutual capacitance betwoon of capacitors? ea Spscton 08) Energy of an assembly yy. 15ST ry, (7.135) | Hv urea inductance berneen Tntrinsie dipole in an are Tag | Uae carey iole RIE Ug OO | SO Sean Intrinsie dipole in a (7137) | m— marnate siole moment magnetic fold aa HH Hanitosian Hamiltonian of a ‘pm parle momentum charged particle in an (7.138) | @ particle charge ae [i arise ec ‘Sometimes elled “Lansors formula” jis the self-capacttance ofthe ith body. Note that Cy = Cy. Ey is the sitinductance ofthe ib body. Note thet Ly = Ly. “Newtonian Limit, ie, velocity <7.6 LCR circuits 4a7 7.6 LCR circuits LCR definitions —_ Current (7.139) Ohm's law V=IR (7.140) Chas ew (eld ag (741) Resistivity, (7.142) Capacitance (7143) case rah (7.44) Selfindvetance (7.145) incur iia Moral (aan) Soxmiat onary =kVEl; (7.148) Linked magnetic vg (7.149) flux through a coil imgedance on nse 2, immpedance connect 2aff \ts ‘ae 2% 3 Star Zin impedances "737,425 (7.168) Delta eat impedances (4+3+4) (7.169) .150 Electromagnetism wo Eero 7.7 Transmission lines and waveguides ‘Transmission line relations Transmision Hine ean a | Loss a cum |” ee 1 curate cna a oo cuiny | ie pa Ccapacitaace per nit length ev Wave equation for a a (1172) lossless transmission 2 cere Tine Fe (1.173) | Characteristic impedance of (1.174) | Ze characteristic impedance | lossless line character 2 resiance por wnt length aracteristic ofeondcor Rial impedance of loss faa 1175) | 6 conductance per wit a ee G+iot (7478) | © (ih of tnd ‘© angular fequeney Wave speed alonga (aire | * moet lossless line eM Te 176) | 6 group speed Fi Z.coskl —1Z,sinkl (complex input impedance Input impedance of Zj,= 7,26 —Zssink Taput impedance of Zin 207, congi—izasink! 77? | 2, compe) eminning line Zi/Z, il=i/4 (7.178) Reflection coefficient from a terminated line (7.179) |r eomples) vokage wavenumber (=2x/2) 1 distance from termination ‘ellesion coeicient Line voltage standing wave ratio ‘Transmission line impedances (7.180) RaCuEe Coaxial line (7.481) Open wire feeder (7.182) Paired strip (7.183) Microstrip line Ze (7.184) %_ Garaceric impedance (0) (2 ads of iner conductor radius of outer conductor © penmitivity (=0e) permeability (po) 1 4 ris of wires distance between wires (2r] step separation step width (>) ‘aight above earth plane 5) “Forlosias ae2.7 Transmission lines and waveguides 151 Waveguides’ wavenumber a guide © angie frequency Waveguide 4 ide eit =n fs eae el ‘and Gatges) © speed of ht Guide cutot mt 7ayt Ye cual frequency frequency TVG) Ge) 8] ae Phase velocity arya |e» phase roa above cutoff f (ve/¥F C187 TP Freneney Group velocity : city aro aier cyte (7188) | soup vetocty Zine wave impedance fr tyes Za=Zoy/1—(ve/¥? Cito) aaa eee ae impedances oe ig ‘transverse electric modes Zra=2o/\i-Cu/eP (1190) | 2, janetc at tee ome Yi) Field solutions for TEs, modes” ikge? 0B. Bea ox gc? 2B: (7.191) OF 5 sett mx nny = cos =O B,=Bocos™ cos, Field solutions for TMye, modes* gc? OE a? ox kc OB. ay dy in gin MY E,=Bgsin = sin {Eguaios ae roan waepadey ib ROAUar Gow Hons and wo GSE ‘rt of the esti dt the magnet Held stegts in the my plane ‘Both TE and TM modes propagate ia the 2 direction with a further factor of expli(igs—a)] on all components, By and Ep ar the amplitudes of the = components of magnetic fx density and elect ld respectively. (7.192)152 Electromagnetism PS See secs eseeseseeCeS eee eee eee ec ronan 78 Waves in and out of media ‘Waves in lossless media Electric field (7.193) Magnetic field (7.194) Refractive index (7.195) Wave speed (7.196) Impedance of free space (7197) ‘Wave impedance (7.198) ™ zo Z H Teste Bald pemmeabiity (=p) permitsivity (eve) magnetic fox density time speed of ight refiactive index speed of ight impedance office space wave impedance magnetic field strength Radiation pressure* Radiation - @ maneatae desi momentum 2 (7.199) | Poynting vector density speed ofiht ‘pe normal pressure Isotropic 1 1 jeat radian po=4ul+R) (7.200) |" eoeray density radiation 3 ee ceeticieat, Specular Pa =u(1+R)cos? Bi (7.201) | p, tangential pressure reflection Pe=u(1—R)sinBjcos6; (7.202) | & angle of incidence 1 speci intensity From an 14R , fenied AEE [ [110.908 nage source’ (7.203) | @ angle between do fd somal plane From a point L-souree luminosity sources As8) (7204) | Ges tadiant power) luminosity L itt distance fom source "On an opaque surface ig pera polar coordinates. See page 120 for the meaning of specific intensity. “Normal to the plane.