clc

%CALCULO DE PROPIEDADES TERMODINMICAS CON LA ECUACIN DE ESTADO DE

%PENG-ROBINSON PARA SUBSTANCIAS PURAS.
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%PRIMERA PARTE%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
%%%%%%%%%%%%%%%%%%%%FORMA ESTANDAR%%%%%%%%%%%%%%%%%%%%
%
P=((R*T)/(V-b))-((a*alfa)/((V^2)+(2*b*V)*(b^2)))
%%%%%%%%%%%%%%%%%%%%PARAMETROS%%%%%%%%%%%%%%%%%%%%
%
A=(0.45724*alfa*Pr)/Tr^2
%
B=0.07780*Pr/Tr
%%%%%%%%%%%%%%%%%%%%FORMA POLINOMIAL%%%%%%%%%%%%%%%%%%%%
%%%%%%%%%%%%%%%%%%%%RELACIONES DE COMPRESIBILIDAD%%%%%%%%%%%%%%%%%%%%
%%%%%%%%%%%%%%%%%%%%COEFICIENTE DE FUGACIDAD%%%%%%%%%%%%%%%%%%%%
%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%SEGUNDA PARTE%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%
menu1=char(' Ingrese las Propiedades Solicitadas para la Ecuacion de Peng-Robins
on.',' Propiedades del Componente:')
Tc=input(' Temperatura critica. Tc = ')
Pc=input(' Presion critica. Pc = ')
w=input(' Factor acntrico de Pitzer. w = ')
menu11=char(' Propiedades del Componente en el Sistema (MISMAS UNIDADES):')
T=input(' Temperatura. T = ')
P=input(' Presion. P = ')
R=input(' Constante de los gases ideales. R = ')
%%%%%%%%%%%%%%%%%%%%PARAMETROS%%%%%%%%%%%%%%%%%%%%
a=(0.45724*(R^2)*(Tc^2))/Pc;
b=(0.07780*R*Tc)/Pc;
Tr=T/Tc;
alfa=(1+(0.37464+1.54226*w-0.26992*w^2)*(1-(Tr^0.5)))^2;
A=(a*alfa*P)/((R^2)*(T^2));
B=(b*P)/(R*T);
%%%%%%%%%%%%%%%%%%%%FORMA POLINOMIAL%%%%%%%%%%%%%%%%%%%%
polV=[1 -((3*b)+((R*T)/P)) (3*(b^2))+((a*alfa)/P) -(b*((b^2)+((a*alfa)/P)-((R*T*
b)/P)))];
V=roots(polV);
V=max(V)
%%%%%%%%%%%%%%%%%%%%RELACIONES DE COMPRESIBILIDAD%%%%%%%%%%%%%%%%%%%%
polz=[1 -(1-B) (A-(3*(B^2))-(2*B)) -((A*B)-(B^2)-(B^3))];
z=roots(polz);
z=max(z)
%%%%%%%%%%%%%%%%%%%%COEFICIENTE DE FUGACIDAD%%%%%%%%%%%%%%%%%%%%
fi=exp(z-1-log(z-B)-(A/(2*sqrt(2)*B))*log((z+(2.414*B))/(z-(0.414*B))));
f=fi*P
Resultados=struct('Volumen_Molar',V,'Factor_de_Compresibilidad',z,'Coeficiente_d
e_Fugacidad',fi,'Fugacidad',f)
'VERIFIQUE LAS UNIDADES! (%%%%%UNIDADES%%%%% EN "Ecs_de_Estado.m")'