C2H4(g) + H2O(g)

fHm J*Mol-1
vi, mol
-1
52510
-1
-241818
1
-235100
rH(298.15K,(g)) =

C2H4(g)
H2O(g)
C2H6O(g)

rHm
-45792

R( J/Mol*K)
8.314

H/R
-5507.8181380804

fGm J*Mol-1
vi, mol
-1
68460
-1
-228572
1
-168490
rG(298.15K,(g)) =

C2H4(g)
H2O(g)
C2H6O(g)

vi fHm J*Mol-1

-52510
241818
-235100
-45792

T (K)
298.15

A =

ln T
5.6975967156

- A(T)
410.2544

vi fGm J*Mol-1

-68460
228572
-168490
-8378

rGm
-8378

R( J/Mol*K)
8.314

T (K)
298.15

R*T
2478.8191

- A(lnT)
7.8398930806

- (BT)/2
-0.619704775

(-)J/R
17.8054292502

R( J/Mol*K)
8.314

T (K)
298.15

R*T
2478.8191

A(lnT)
-7.8398930806

(BT)/2
0.619704775

T (K)
330
338.7
347.3
356
358.1
360.3

ln K
1.5950183336
1.1649798249
0.7608920075
0.3718365357
0.2804858165
0.1859362056

Kc
4.9284194268
3.205858204
2.1401844298
1.450395874
1.3237727668
1.2043454274

rGm
-4376.1242003259
-3280.527034892
-2197.0393009305
-1100.5558290742
-835.0745460355
-556.9782628495

rHm
-45885.295270893
-45904.139937224
-45920.474371391
-45934.747647363
-45937.098250822
-45939.469562353

0.9078921578
0.8650784859
0.8106192907
0.7436417875
0.7258430386
0.7066322402

0.95
0.9
0.85
0.8

0.75
0.7
0.65
0.6
325

330

335

340

345
T (K)

350

355

360

365

0.65
0.6
325

330

335

340

345
T (K)

350

355

360

365

60

C2H6O(g)
A
1.424
3.47
3.518
-1.376

B =

B (x10-3)
0.014394
0.00145
0.020001
0.004157

- (BT^2)/2
-184.7649786663

- (CT^3)/3
14.2235846695

D/T
-40.5835988596

Fa0 kmol/h
Ca0 Kmol/dm^3
k1(h^-1)
T1 (K)
E (J/mol)

163
9.3
0.004
600
12141

- (CT^2)/6
0.0238530684

-D/(2*T^2)
0.0680590288

J
-44136.4381090078

(-rGm + J)/RT
-14.4255940698

I
-7.113493667

(CT^2)/6
-0.0238530684

D/(2*T^2
-0.0680590288

-J
44136.4381090078

I
-7.113493667

ln K
3.3798351804

k (h^-1)
0.0005460555
0.0006117892
0.0006807201
0.0007543886
0.0007727556
0.0007922388

X
0
0.1
0.2
0.3
0.4
0.5

(-ra) kmol/m^*h
0.0050783164
0.0049431989
0.0044729547
0.0034599183
0.0021404172
0.0006250617

C =

C (x10-6)
-0.000004392
0
-0.000006002
-0.00000161

J/R
J
-5308.6887309367 -44136.438109008

Fa0/-ra (m^3)
CSTR (dm^3)
32097.2518286625
0
32974.59857799 3297.459857799
36441.2362940714 7288.2472588143
47110.9386528966 14133.281595869
76153.3778735309 30461.3511494124
260774.25055332 130387.12527666

Discucin:
Los siguientes datos nos permiten sacar las siguientes concusiones

365

1. Es una reaccin que se desplaza a los productos ya que energia de reaccin de Gibbs es
negativa
2.La reaccin presente es una reaccin exotermica ya que entalpia de reaccion es negativa
3. Conforme aumenta la temperatura la constante Kc disminuye (el equilibrio se va hacia
reactivos).
4.- Una foma de comprobar que la reaccin es exotermica es viendo la grafica tipo z
presente.
5.- Los valores obtenidos para k a 600 K fueron obtenidos mediante el siguiente link:
http://yeahchemistry.com/questions/determine-rate-law-integrated-rate-law-and-value-rateconstant-dehydration-ethanol

60

365

presente.
5.- Los valores obtenidos para k a 600 K fueron obtenidos mediante el siguiente link:
http://yeahchemistry.com/questions/determine-rate-law-integrated-rate-law-and-value-rateconstant-dehydration-ethanol

D =

D (105)
0
12100
0
-12100

300000
250000
200000
150000
FA0/-ra
100000
50000
0
0

PFR (dm^3)
0
3253.5925203326
6681.2294144898
10779.5885661654
16715.8417071294
27946.7626546911

ones

rgia de reaccin de Gibbs es

alpia de reaccion es negativa

ye (el equilibrio se va hacia

iendo la grafica tipo z

diante el siguiente link:

ated-rate-law-and-value-rate-

0.1

0.2

a
5.9284194268
4.205858204
3.1401844298
2.450395874
2.3237727668
2.2043454274

b
-10.8568388535
-7.4117164081
-5.2803688596
-3.900791748
-3.6475455337
-3.4086908548

X
0.1
0.2
0.3
0.4
0.5

Puntos
2
3
4
5
6

c
4.9284194268
3.205858204
2.1401844298
1.450395874
1.3237727668
1.2043454274

0.3

0.4

b^2
117.8709498918
54.9335401139
27.8822952934
15.2161762615
13.3045884201
11.6191733438

Utilizando regla de simpson

n
1
2
3
4
5

H
0.1
0.1
0.1
0.1
0.1

diante el siguiente link:

ated-rate-law-and-value-rate-

0.4

0.5

4ac
116.8709498918
53.9335401139
26.8822952934
14.2161762615
12.3045884201
10.6191733438

2a
11.8568388535
8.4117164081
6.2803688596
4.900791748
4.6475455337
4.4086908548

H/3 3/8H
0.05
0.0333333333
0.0375
0.0333333333
0.0333333333

F(X)
65071.8504066525
200436.882434694
287455.695097743
501475.251213883
838402.879640734

(-)R*T
-2743.62
-2815.9518
-2887.4522
-2959.784
-2977.2434
-2995.5342

R( J/Mol*K)
8.314
8.314
8.314
8.314
8.314
8.314

A(T)
-454.08
-466.0512
-477.8848
-489.856
-492.7456
-495.7728

(BT^2)/2
226.34865
238.440718665
250.703037265
263.420776
266.537715385
269.822743065

(CT^3)/3
-19.28619
-20.8521197936
-22.4811731851
-24.2133352533
-24.644362275
-25.1013689785

(-)D/T
36.6666666667
35.7248302332
34.8401957961
33.9887640449
33.7894442893
33.5831251735

J
-44136.43811
-44135.43811
-44134.43811
-44133.43811
-44132.43811
-44131.43811

J/R
-5308.6887310561
-5308.5684520087
-5308.4481729613
-5308.3278939139
-5308.2076148665
-5308.0873358191

A
-1.376
-1.376
-1.376
-1.376
-1.376
-1.376

B
0.004157
0.004157
0.004157
0.004157
0.004157
0.004157

C
-0.00000161
-0.00000161
-0.00000161
-0.00000161
-0.00000161
-0.00000161

D
-12100
-12100
-12100
-12100
-12100
-12100

A(lnT)
-7.9795514925
-8.0153579095
-8.0498600086
-8.0839046857
-8.0919976932
-8.1004253364

(BT)/2
0.685905
0.70398795
0.72186305
0.739946
0.74431085
0.74888355

(CT^2)/6
-0.0292215
-0.0307825802
-0.0323656395
-0.0340074933
-0.0344098887
-0.0348339842

D/(2*T^2)
-0.0555555556
-0.052738161
-0.0501586464
-0.0477370282
-0.0471787829
-0.0466043924

I
-7.113493667
-7.113493667
-7.113493667
-7.113493667
-7.113493667
-7.113493667

R*T
2743.62
2815.9518
2887.4522
2959.784
2977.2434
2995.5342

SUMA
-14.4919172151
-14.5083843676
-14.5240149115
-14.5391968741
-14.5427691817
-14.54647383