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Chemical Equilibrium
1.
Write the Kc expressions for the following & classify them as homogeneous or
heterogeneous equilibria:
a. SO2(g) + 2H2S(g) 2H2O(g) + 3S(s)
b. NH3(g) + 5/4O2(g) NO(g) + 3/2H2O(g)
c. 2HNO3(aq) + Ba(OH)2(aq) Ba(NO3)2(aq) + 2H2O(l)
d. Mg(OH)2(s) + CO32-(aq) MgCO3(s) + 2OH-(aq)
2. In the reaction CO(g) + 2H2(g) CH3OH(g) carried out at 483 K, the following equilibrium
concentrations are measured: [CO] = 1.03 M; [CH 3OH] = 1.56 M; [H2]= 0.332 M.
Calculate the Kc of this reaction.
3. At a certain temperature, Kc= 1.8 x 104 for the reaction
N2(g) + 3H2(g) 2NH3(g).
If the equilibrium concentrations of N 2 & NH3 are 0.015 M & 2.00 M respectively, what is the
equilibrium concentration of H2?
5. A 5.00 L evacuated flask is filled with 1.86 mol NOBr. After equilibrium is established at
25C, it is found that there is 0.082 mol of Br2 present. Determine Kc for the reaction:
2NOBr(g) 2NO(g) + Br2(g).
6. A 0.0240 mol sample of N 2O4(g) is allowed to come to equilibrium with NO2(g) in a 0.372 L
flask at 25C. Calculate the amount of N2O4 present at equilibrium.
N2O4(g) 2NO2(g) Kc = 4.61 x 10-3 at 25 C
7. The following Kc value is given at 298 K for the synthesis of NH3(g) from its elements.
N2(g) + 3H2(g) 2NH3(g) Kc = 3.6 x 108
What is the value of Kc at the same temperature for the reaction:
NH3(g) N2(g) + 3/2H2(g)
8. Explain how each of the following factors affects the amount of H 2 present in an
equilibrium mixture in the reaction
3Fe(s) + 4H2O(g) Fe3O4(s) + 4H2(g) H = -150 J
a.
b.
c.
d.
H = 198.2 kJ
IONIC EQUILIBRIA
10. Nitric acid is used in the production of fertilizer, dyes, drugs & explosives. Calculate the
pH of a HNO3 solution having a hydrogen ion concentration of 0.760 M.
11. The OH- ion concentration of a blood sample is 2.5 x 10-7 M. What is the pH of the
blood?
12. The pH of a solution of HCl in water is found to be 2.50.
concentration?
13. Butyric Acid, HC4H7O2, is used to make compounds employed in artificial flavorings and
syrups. A 0.250 M aqueous solution of butyric acid is found to have a pH of 2.72.
Determine Ka for butyric acid?
14. The much-abused drug cocaine is an alkaloid. Alkaloids are noted for their bitter taste,
which indicates that they are bases. Cocaine, C 17H21O4N, is soluble in water to the extent
of 0.17g/100 mL solution, and a saturated solution has a pH of 10.08. What is the K b for
cocaine?
C17H21O4N + H2O C17H21O4NH+ + OH15. What is the percent ionization of 0.010 M acetic acid HC 2H3O2? Ka = 1.8 x 10-5