SOLUTIONS MANUAL BASIC PRINCIPLES AND CALCULATIONS IN CHEMICAL ENGINEERING Seventh Edition David M. Himmelblau and James B. RiggsSolutions Manual to Accompany Basic Principles and Calculations in Chemical Engineering Seventh Edition David M. Himmelblau University of Texas James B. Riggs Texas Tech University PRENTICE HALL Professional Technical Reference Upper Saddle River, New Jersey 07458This work is protected by United States copyright laws and is provided solely for the use of instructors in teaching their courses and assessing student learning. Dissemination or sale of any part of this work (including on the World Wide Web) will destroy the integrity of the work and is not permitted. The work and materials from it should never be made available to students except by instructors using the accompanying text in their classes. All recipients of this work are expected to abide by these restrictions and to honor the intended pedagogical purposes and the needs of other instructors who rely on these materials. © 2004, 1996, 1989, 1982 by David M. Himmelblau © 1974, 1967, 1962 by Pearson Education, Inc. Publishing as Prentice Hall Professional Technical Reference Upper Saddle River, New Jersey 07458 All rights reserved. No part of this book may be reproduced, in any form or by any means, without permission in writing from the publisher. Printed in the United States of America First Printing ISBN 0-13-143221-4 Pearson Education, Ltd. Pearson Education Australia PTY, Limited Pearson Education Singapore, Pte. Ltd Pearson Education North Asia, Ltd. Pearson Education Canada, Ltd. Pearson Educacién de Mexico, S.A. de CV. Pearson Education -- Japan Pearson Education Malaysia, Pte. Ltd0 u TABLE OF CONTENTS othe tnsctor ample Course Syllbus Course Objectives am and Recitation Section Schedules Suggestions or Taking Exams ‘What You Should Know About This Course Standards for Chemical Engineering Homework ‘Typial Assignments or One Semester ‘Typical Examinations for a One Semester Course Solution to Problems Soltion o Thought Problems ACKNOWLEDGEMENTS. We want hank Christin Bair for rearing al of this Solutions Mansa, snd forthe may students and graders who have contd tothe stuns it oni David M, Himba James B. RigasTo the Instructor This Solutont Mena accompanies the bok Basic Principles and Calltiont in Chemical Engineering ™eton published by Prentice Hall nation tthe BaS +4C0 Clete the percent ences redctat and the dere of completion ofthe ection, PROBLEM 8 20%) ‘Ags cylinder to whic it atched an Bouden gage appear tobe ata pressure 27.38 ins get TPF the baometer ness 101 Pa A stent clans ht the presen tbe tank 13 pi, but ancter student points ot hat hiss imposible he pressure really 282 pin, Can | 3 pia be corest? Explain and show eslations to back up your planation,EXAMNO.2 (Open Book, ? hours PROBLEM 1 (25%) A chemist attempts to prepare some very pute crystals of NegSO4-108820 by iasoing 200 g of NapS04 (MoIWe=14208) in 400 g of boiling water. He then ‘aefly cols the solution showy nti some Na2S04 (OHO crystalies oa. Calsuae the of NapS04-10H0 recovered inthe entale per 100g of inal soto, i the ‘esd solution ser the crystal are removed contig 28% No50, Rightanswer but: 10ifanswerisin got -10 answer not 1Na2SO and nat got er 100g oft Nug80¢ 10430 sola PROBLEM 25%) iter pollution i he Hudson River has claimed conserable recent stenton, ‘yevisly potato om sevage outlets and nds wastes, To determine secre) ow such effluent enters the river is quite dificult Beaute to catch and weigh the ‘material is imosibl, weirs are hard to const, ec. One suggeion which had been offered so adda trace Bron a given sewage seam tte wel ond sample he Sewage sveam after it mixes well (pone test ofthe props you ad ten pound of Naf per hour for 24 hous oa sewage stream with esentially no Brin it Somewhat downea ofthe inaction iat» smplng ofthe sewage steam shows 012% Nadie. The sewage desi is 603 MI and ver water density i 624 To ‘What is the Now rato th sewage in Bin? 10 anawer based on 15 i€24 basis (0012 facia and not as sedan then 00012, ot converted back {oper bour bai PROBLEM 3 25%) in pepang 5.00 moles of» intr of tee gases ($0>, HS and C52) gases fiom three tanks ae combined ino «fourth tank. The nis have the follwing compositions (mole Factions) Gs Taok! Tank? Tank Tank SO 10 020 a2s ro) fas om 020 os 026 co 05060 050 oss How mach of Tanks 1,2, and 3 must be mixed 0 give prodet with composon of | Tank? 10 for comes newer but wrong 184 lot of peopl id no soln, ais ‘They wed wrong basse. No sola but conect mat altace (contnwes)PROBLEM 425%) 10% 2) Forthe given dslaion proces, calle the composition ofthe Botos 15% >) If seam leaked into the column st 1000 roleee and all ele was on, hat would the new Dots composition be? (Should be g-mol) if assumed oK-ole and ot stated canting Water 10% Etou ts ho ot aad. wt no Bettense? Ltetenss? Etohe? owt Shae PROBLEM 1 35%) [company bars an interment prodvct gs having the composition 4.3% CO, 27%CO, 10% Ho, 1.0% CH, andthe residual Np ogether with wae ol having the composiion 876, 13% Ho. Ansys ofthe sack ps giver en Ore! mast of 146% (003, 0.76% CO, and 7.65 Op andthe rest Np, Cakulate the faction of the tal carbon bred that eames om he pod a. PROBLEM 2 25%) Benzene, toluene and other aromatic compounds canbe recovered by solvent cexracio wih sulfur dios. Asan example, aay reformat stream contnng 50% by weight benzene and 30% non-benzene materials passed trovgh the counter current extractive recovery scheme shown inthe dng low. One dhousand pounds ofthe reformat seam and 3000 pounds of sulfur donde are fed tothe stem per hos “The benzve product sem (Ke erat contains 0.18 pound of sult dioxide pe pound ‘ofenzene. The rine stream consis ll the inaly charged non-benzene aera ‘swell as 025 pound of benzene er pound ofthe on-Beane meri. The emining ‘component inthe alinate steam the sli sid, (0) How many pound of benzene are extracted per hori arn the exrot? (©) _1£ 800 pounds of benzene conning in ton 0.25 pound ofthe non benzene "teil er pound of beazane are Mowing pe outpost A and 700 pound of ‘benzene containing 0.07 pound ofthe no-Senzene material per pound Of Daze ae fowing at pin B, how many pounds (excsive ofthe sulfa dixie) are Bowing at points Cad D? ‘emt nen ae te te soma he GomesPROBLEM 3 30%) Reactant ie polymerid a shown in the figure. tis mined with fesh catalyst. and recyeed cats. Conversion of Ai 40% on oe pas ough the rector. Fresh aly! () enes athe ate of 0.0 18G per bof Ai stream Th spertn removes 90% ofthe catalyst and cycles ia well eyeing vreacted A. Neverbeess, the product steam consi 594 ofthe unreacted A and 10% ofthe catalyst exiting Steam K aswell bth polyne product. Determine the rao of trea RG Note: cust doesnot ect inthe proces! Exam No.4 (open Book, 2 hous PROBLEM 1 25%) In the vapor recompresion eveportr (isu) shown in he Figur below, the vapors prodiced on evaporation ae compressed wa higher pes and parsed through he heating colo provide te energy fr evaporation. The sam entering he ‘compressor 9% gusty 10 pate sea sing the compressor fo 30 pin an {00°F and 6 Bru of oat are loa rom the compreso er pound of seam tog ‘Te condensate leaving th eating eal a $0 pla, 200°. The replacement gid at ‘he tempeatr of ts gud ise the evaporate. Comparer (3) the wok in Buu nae for compression pe pound of H20 ging trough the compress, (©) the Btu orbeatransiemed om he heating col othe gui inthe evaporate er pound of #20 trough he col Bonus ofS pin for comet answer to the question: Wht the otal het ined lat byte enti sytem, PROBLEM 225%) An insulated, sealed tank that 23 n volume old of water a 100°. A U8 ip ser mies the water fr I hour. Whit the faction vapor al the ed ofthe owe? Astrea the energy fom the motor eners the ak, For this problem you donot have to get numerical solution, Instead lis the folowing in hs oder: Sate what the system you selects Spey open or clos Draw a petere Putall th known or calulted aon the pict in he proper place. Whe down the energy bane (ase he symbol inthe ext) and impli as ‘mucha ponte Lst cach astmpton in so dong Cale W. List the equations with dat itroduce that you would wet ove the problem Explain sep by sep ho 1o solve the problem (bt 60 nto 3) PROBLEM 3 (15%) ‘Whats he entapy change in Btu when 1 pound mole of is cooled from OO"F 1 100 at atmosphere pressure ‘Compute your anne by two ways 1) Usethe bles ofthe combustion ges 2} Use the eat capacity equation for air, (cominues)ef PROBLEM 4 (10%) Answer the following questions by placing T fro tread F for false on your answer page. Grading 2 icone, Ola, 1 irene (0) Hestandherma enery re syonymous terms used to express one ype of (Youu find he enthalpy change a coastant presue of Substance such as CO> from he solid othe gaseous site by integrating fon (ok pent) Trg empire ‘eet oo pena (2) The enthalpy change of susan can never be nea (2 Heatand work arethe only methods of energy ante in a non-flow proves (Both Qand AH canbe clsed as sate fonctions (varibles) PROBLEM S@5%) or reaction product (sume they have the same popes asi) at 1000°F leave aseacir. In oder to prevent ter eatin, the process esigned wo reuce te temperate of he rodeo 400° by mmeinly sping us ar ath pa ow many Tb of water 70° are equi pe 1001 of products leaving at 120 ot 70°F aes 1000%F fares Reactor 2 Hor For this problem you do ot have to geta numerical solution, Instead isthe following in this ere, 1 Site wha te sytem you see. 2. Specify open or closed. 3 Dew apie 4. utallshe known o calelated data nthe pict inthe proper places SW down the material and energy balances (ue the symbols nthe text) and simplify them as mich as posible, is each assumption ino dine 6 ase the own daa ino the simpli equation) you would we to solve the problem. Exam No.5 (Open Book, 2 howry PROBLEM 1 (10%) Ansver he folowing questions rely (ne move than 3 sees); 4 oes the adton ofan ine distentto he estat entering an extherni proces merase, decrease, or make no change in the eet esr oF fom tbe proces? the reaction na process is incomplete, what ithe efet onthe valve ofthe standard heat of reacon” Does igo up, down, or ema the sare? Hw many properties are need to inthe state fag so taal of heather oper canbe determina? 4. Consider he reaction Hats) $ O38) HOW, {she Bear of reaction withthe reacts eerng athe products leaving a 00K ihe. ower, othe same asthe sandr heat fection? PROBLEM 2 (10%) Explain bow you woald caluitethe adiabatic reaction mparane fo Problem Selow ifthe oulet emperors ot specified. Lise step. (You cance some of "he stp iste in Problem $i you Tis them by number in Problem 5) PROBLEM 3 20%) ‘Aloe gas 750° and | atm of composition 140% CO;, 1.0% CO, 64% On. andthe tlance Nz the produc of eombustion with exces srt 750°F and 1 am dha ie used wo bum coke (C). (comtiaved)‘Whats the volume in fof he legs eaving he face per pound of carbon tured? ‘Wats the volume far in entering the fumace pr pound of C bums? M4202) ‘Seven pounds of Nz are store in cylinder 0.75 volume a 20°F. Coleulte the pes inthe ylndr in straps 8 Assuming Nz to beanie gas. 1 Assumiog 2 iss real gat and using compresbiliy fits ‘PROBLEM 5 (40%—one half each for the materil and enerzy balances) Porites (FS3) is converte to sul oxide (0) ge sconting ote reaction $FeS:() + 11 OxG)-» 2 F049) +8502) ‘Te airwhich is 35% excess bas on the above reacin) for combustion entra 27°C, the ore at 18°C nd te products lve a OOK. Bocuse of ment Sermon. tmbumed Fe exis fom te proces. In one hour 8000 of pyrite ae fed fo be proces, 200k of Fex03 ae produced. What ithe est ade or renoved from the process? Data: For FS, Cp= 4,77 +5590 x 10-27 where isin Kelvin and Cy in M(gmo1XK). For £03, Cp 1034+ 6:71 10-27 with the same units. Exam No.6 (Open Book, 2 hour PROBLEM 1 (20%) A high pesure tin caves trl gas (ll methane) a 1000 KPa and 40°C ow would you clelatthe volun ofthe gx under these convo tha inequivalent 10003 w of Cig a standard conditions using a equation of ate? Select ne eqttion ater than van det Wan equation, and lit ion your solution page, Give a liso epa ‘compete the elelaton. Include al the proper equations, nd icles te involved ut youd ar have te obtain 2 soltion forthe volume, PROBLEM 2 (20%) From the flowing dt estinte he vapor pressure of slr dioxide at 100°C. Temperature CC) yaa | sss ‘Vapor press (ai) PROBLEM 3(20%) ry atosphoi iat the ambient dies of 90°F and 29 42 i: Hg ‘solute passes trogh a all lower and Is buble up through water otha the ait leaving the woler ated The temperate ofthe water constant a [OM andbecase of the back pressr in the sytem, the pressure ithe vapor pace ‘nthe tp of te bottle 2.7 in, 0 grater tan Samnophrcprese ‘The ote is weighted ar the iis bown for 2 ‘ows, 13 minutes, 47 cons, andthe decrease in weight wae found to be 873 Bb. What asthe uty rat of flow of iat ambient conditions in? PROBLEM 4(20%) ‘A vessel witha volume of 283 m consis «mine of nitrogen and setoe at {40°C and 100.0 KP. The dew point of the mixture 200°C andthe relive saturation ofthe acne in the mixes 58.39%. The vapor prenure of aetne st 48.9 4 6535 Pad tis 2462 APs at 200°C What isthe pai reste of ton vapor inthe original mixture, in KPa? How many kz moles of acetone des the eign! mixture contain? the nitrogen acetone mixture i cooled with the volume remaining at 283 ost 0th 27.0 percent of he aston condense, whats the eal temperature ofthe mine in °C? (continued)mg bower and atthe The ese vapor space stow fr? 73h, What nd acetone st 14°C 65.35 kPa? 31283 fal (contnaed) ‘Awetsluge consis $0 percent water by welght This luge fest ceifiged, and. kilograms of water are removed per Kilogram of wet dg fed ‘The shdge idol fare sings ota the fal product conains 10 pce by weight wate. The ior dying i heted, passed ito an oven de, and vented back Jato the mosphere. Ona day when anospherc pressure i fom Hg, he tempera {70°F ad the enve hamid 5%, alent the cae meters of wel required 0 dry one llogram of shdge fed othe process. The air vented from the oven de iat 1OO°F and 7mm Hg, Tas ade point oF 94°FSolutions Chapter 1 ‘aif 30.0y(2 9) [28m | Te hia kre? a bea Tella ira) [risk 18° a ot [eo mil? yl, E> a Gainey rae Pw? Lasee” Pay Oe ee few] Seinen?) | 19? | Cin) | tye dy] he ‘Geno ¥°511 (2.58 e565 days 2 1A jas0i8 m Farge wl oe me |13.ThePasat is apesur ai dein anitie no he sane a mane vel. Teconect oven 39MatONEs). the Weta Te te soreninis comet Serb Engh ron nt pao "on wo ee {Conctis"3palton (142 LM Wiheton sa mets on, ten C2 aw CORE] Solutions Chapter 1 o M48 Bas: omen }" Soomajsial we asi $0.0 het sau, 1 in [1000 (2.54 em)’ 6 Basis 620emh0" ey te | ie [00 1m 10's) oem) Tm | (30 a? Nia a TOT Pens ‘ook sas It tS kgJi Solutions Chapter 1 aa 1br_{ 20000 mite Bsmt Te be 2000 ga{000 mite _ (2570p smile) the er Nowe: 20 gl mae ate ede 14 Leta bethe tine fr Ao paint one bus: for ‘doves bau or howe hr B dos oe howe howe Ste Ta Bae Ato n=te star 34, 1 _.ammpene a 1e_ldnen natn ; Slaven te tel cone (E) aaa Kamen rr Tre | a | 282 eat? fim 0 os Beker) (EX) og aay, iran) MO (2 eer ny lier sh nal 19a) mse, ome mses we balanced [°° Weehcteene ie ie eee etme pts ig 20.0g| 1 | 304te|36005| HOKE) |r? Good 10 1 we barra (e KO] G600) | | a 1.3 Notrelly- peopl donot ml tng berwen na neigh. 114 The objet ta masof 2.3 gina recon a 1). The weight the fore ‘wed iowppr he masSetttone Chapter 1 tn AmerianEapneig Stem Power = FV wonton A, 9 Ba 4000} ml ony.) TPs 1m 100 if hy f100 09! Taerigh « | \ 1 Bw faa mala Raa) ® Solutions Chapter 1 Busi: 1Otneat 6 6 Lem 2a tee © equ ‘make subtateC mot eC) mal” eau ‘mod obarieC 0 aut, serpy imolaubtrae The ine ising conven tor ‘Wha te sioner th uni comet.Solutions Chapter 1 Sotetions Chapter 1 Q-06is (EVP ssume tole isopento sincere », 4si'| 290, | 7 ingao7mn.ol 10 Te | ie Toe fie SOT RIO, lexatio ort OATHO gba - wee “Teenp | (aa) 2-008 se TTA | arstorn? Ne -tean] Eo | exe | Coney, he frm wil tot id 90.8 1, prema foal he shoul g fore nthe AE rem een, Bier) oe 9048 | re eral en aTSolutions Chapter 1 i ik, ing? (tbe? 1s the ria cece, Bs hand by multiplying By cnversion ts Let ithe lesa weigh of he compe Lt Yidemuilaseg eat basen) [MW tm, (sl a) (sits) feof eral] ‘hee handsets fet) ands neste sth the hd ‘The inside date of he bigs 635 -290.762)= 4.826 am Eq s267 nn? = AS22129 en? ‘Toe flow areas oo} fom? he vlc of he sample pie corm (orem TSSolutions Chapter orate tice 125 te ine oad othe ow i {ley time of 5 ec may be zee row enka, at ter eat wld be ‘ered for anger ovens oes pes ©) Tore amping ine: 1) aces he Now me fr sae dente wig. 2} Decree he ring date ose Now te, 3) Resoce tein kag Solutions Chapter 1 Pac unit rhe bos int pve eqn an equi the nto te ef ad ‘ight eso he quion by asigungappecprite us othe coef 083. Bs ts ata loot (2) ‘The ws ae he sme thigh a ef 0.93 bas oui cated wht * | Inde th ui. The a one eh someon ot se ofthe eon. [| com _jsoa|im Laliai2ste| 1 _jonglasesn| 1m lisoenen 5 Te Pat haa) tp loon ocalig) ta wren sempaiee|1_Wgletsin|_—o . Pl alae! te ic he aT? - loon Sa 1.20 Twobecase any numbers sed the igh hand id ofthe cial point in 0Solations Chapter 1 at Toe sumis 12871450, Bene 1234 holy signe figure thet of ple deca pi, he awer sald be 25 (no den pt 132 Themunberf significa ges oh sight of edi point | (oe 210.0m), eset ou of 71510 mol be ound 2151, | 193 Acar gh 9826 0m, eyo stares gna or | [M_Twosipifene gues (aed on 63). Use 810 Sp 1 The poder 324i mand of For absolut eo, te prod Aen 14005 Siatly3.8¢tasSolutions Chapter 2 Soltions Chapter 2 an Tenant eek, ne cd pangh te mer Tred nmr of moll and ot nese. paves 23 Amwieisamembe of lene, Molec weight the mast er mle 24 Alle snmersare wong. Ae isa mer of molec, 2) Wis noc umber of moles a volume 5) neta weit ©) insets mmber of mole na pa }—_iisoecanstam might or am ot ©) lienocamceir wii 25 Thesttemen is paral caret. Amol i umber fens, oat of ater. "Ouanv sly wnt conse 9 be ened 264) mot meas avec ofthe uit ol” ve p71. @2@ 2a omsigc ae Bai: 20m Nac: ABBAS RIAA pois demamieact AMSA BTR] bas toon, 2S el Fal 4 tds opm nact: 22, |e oT ea 0 (e) MW 40.08 g/g mots 1201 gine +2600) gel » ° ® ~ [TAT ERATED] 0g CACOULD g mol C200 sso fisscmal Caco aT E Ta BmaCo ji hesccn |Libmol CaCO, _ pron maICAOO] [ton08 Caco, ~ 2200 wel ca 2. mol CaCO, [00.09 CLO, & _prRTFETD] Te Ti mol CaCO, PSC som ing ceil esSolutions Chap Solutions Chapter 2 Pat St og 0828 Meh aro ‘enol MeCh, 2b mol GHyI(44099 Cyl 454g Cu fasoun ctu i's Oh D crn Th Oy S28 GS @ © » 1 [1 oot Ny 5 0 alors - Sarma] 2IBCH.O} 1 ol GLO [45 ol icon bCHOl Tete” PERTH) eit nC 194 wel KeI7455 KCL Tio 119 gm NINO,| 85_NINO,_[220s10% MA gmeINO SENN, fatal ~ ESB RNO] Ie pm015i0,| 01g, |220.10'% a ERS] 218 Basis 10 goth composnt em ew e an ry ° teh ea q oa "0g Maly by 11 comer he tis et integers ‘Theta becomer Crit (Checking M1212) 1115) + 221.08) = 342 coe enoagh)Solutions Chapter? | vain Vania w 200801 2865 [1 tL gorse oe = 200g 18 ni c= 2006 N6A| LB rE [rashes “CS * gore vue Ot 86 elie minx 0 el TE 54, e be ret Ea om Sotations Chapter? 1S Bas 1000 i out sila 4B HO ot sah ion Fol ry wp Lo F778 oT aos a6 basis 010% {0.010 mf 1 gt Jose #2 sow pr totam . piesa’) visa mo osha aoa a eo seria ae Bass: 109005 opal vohne totaal: (00m) eyO0-10'mxO")=A95%10"% ams SiC™ (393810 (3.17e Kea = 12510Solutions Chapter 2 219 (a) Volume epider» y= 0.125m)'(1.00)= 495104 ‘Volume cline Value fier 49st! (625610) (=o ier Mass =(deniyivoume) = 225» 1ogin'x40%m = [ETO] SSO tote Lot 0) ange SERIE ut en 18 asst? 40.9000 (510% - (625e10%my'1= L110 (ino'e) LON - yeep ‘The back fl mus cnt 100g Fi tat wil eco te voids o 100002 = 500 gale rl. Te ey space mnt es 10,00 gl er hs ant pi $000 fre baci or 15,00 gal eile 005 eg 11600 SS HR 22st ot ms Chapter? 222 bai: So Bb of 28° AP et + 20,000 15° AP > ele. Pin thy (astme wohies ae dive 1 B= 42 ea Iy28* lls bg oll 878° oil! Poi) Taal vol $0007 20,000 bat ais a Say = TG 0887 py =(0887V62.4)= S536 BR] eas 0.955 pig =(0.9654624)=60.27 Ig? Var (5000 boXA2 gat /B0IN@ 7.481 gal) 2.807 10h? Vise=@0.000,42 gal HQ? /7.481 gal) L123 108R? (ssaetad™) 40-10 (arBal)(uanxio%nty Pa TAS IO TIERONE -BRa)- ETE ic} wes as So SE s,s °° GOR PAPI +1315 3841315 i) LoSolutions Chapter 2 Sotutions Chapter 2 P2100 em? nrc gen? Hol By Lyf 10? 227 Spar 1218 fr SO. 100 g/en? HO fie dzame @) [rm ) ae p=12185 ge saan 30(1.2165)= 036565 cn of SO. he ohion 5 : 2365610000 565.65 1,50,0. 1019 Be nacleas Be ,0 avid Se Ae Oana | rooBs 10 new 8 € | | ee 28 pat Dy oxyh feos BBS b : 200 mg HC, [1.48 gl18* [1 | got gc, Bis -— 1 gal | TR? 4/454 271.524 aC, Pane Hi ptf tmmot Hg |20.6 nal aor Hee ot 2126 The deny of water 25°C 0997 let and at °C L000 pe. tae sy chnge Indeasy othe ABO. 3.9010" EE.» 3.90:10'ppm 1" EEE 9010p £Ag,0!en" ; 7730; g.Ag,Olem = 7278 | | 0597 gH,0em@Isc | | Ticcasare for ana jet tlow be presides one sss Ie mae pry, von oct 1278 gAg,0len' 7000 gH, Oiem'@reSolutions Chapter Soltions Chapter2 ass: 1 Lof0.10 molar H:SO,soton = 1 Lola MW HSOy= 98.8 on ©1858 696% sole? 96% so, since spr. = L888 0.10 pmol H,S0,|9808 H,S0, 1.00 96% sla _ [032 Ee 8] © ST Thsola | gol $0, 096 84.80, sol oy Lemdeesoin 1022 296% win _ a -aTaR aL al TSE ¢96% soln] L soln (6) Assume no volume change on ising fer och te on omnson WOR 580 Ho sus ws Pec= 0917 gem Dewstyofice PHO = .00gfem3 Density of 1201) ‘Pact 0.791 genes of ue lab ete am is97 prot 48.5% Eo, he dey 0917 pom. Ashe pro ie he eniy of he laos deze iow tat fe, casing ei Sik. Poe °F = 09505 gi G0°E 0879 gem? Sp.ecotbomene at OFF ~ 0.99305 g/ ea? OR) ih HO. OO a. poo KEN] ED Le? _(32008 fossa ig meth im JP im 9S 5g Eg] Bass: L7O44gHNOS 1 hg HO 2 Comp. Kg musncton weigh pent Tou 2704 100 Igor the change of eso wate with epeeSolutions Chapter 2 P| 1.008 1, 0}0.63 g HINO,|I g mol HN LOOEHO| ow” HO g soln | 63 g HNO, Deny ofceieyde -a eof ote soem | mae eed vane vole of vessel = max. required voline = 411° rfGare) sue Aspe veel wih ie of 3 m cml be wed ae the igi 1H step -e H) sm ono cfo02 MOH I-07 fy ome 1 ig L Solutions Chapter 2 mL (esse aaa wi (08) pat Phe) 7 oe 0b Lov BAe [4 BHO) Ta fo pa ” Ral Perero| i te a sonpt em recone ae: Peace eee sera ae | Treempie! omni of ie opine compud i Ci.Seltions Chapter2 239. bain: 100 gamete: 495 6:52 ¢14:288 gN: 1650 2 vie ech ws umber bythe moar mas: (23012011 glgnoic) 4121 grote (52 gH/L008ggnol H)~ 5159 gral H (G88 gN'A007 pmo) ~ 2030 gol (065015909 pgm )= 1051 gol 2: Divide ech molar ann bythe smal molar amosat (121 mol COS mal O)= (6 mo CaO) (5159 mol WO mol O)=(5 ml HinolO) (2036 pol NLO3 ol O)= (2a NinolO) (0031 mot 01.031 mol O}=(1 ma O91) 4 Bipiia Fomala i then 240 Consost sol ct Mae of shi 10828 t soln, , 10 HO] 0828 we soln,» HO @ HD. ete Zor oan is fnton| cx) “Mase Satin KOH= "5 Os y oar Mas fraction 20 = 1-0.09-[024 | ~N, Moe feton ws tion _sMW,__ eM |—tihof 0 |tet goaSelatins Chapter 2 Sottions Chapter? 2.49 ne: 100kg lp 16 ase 20h a Some, Muemal s core, ee bat malt. e ® 2 2” © no ast ta x a a 1680 ” am Yoo to Tb Er) | | Ke nol = par ay ro Basis: 100 g moi gas » = 7 7 2g SEE ei app wh pe oa * aa \ os ma 2 } 3 es 2 | & ae a 248 On spe bs el pa: | to00 Brand A: 6060 ‘Brand B: 405 ppm | 33a ™ ™ | ve mot w= SBS, | The epi ma ft | ae | or ‘eae esi 24s, ‘Basis: 100 1b mot —— ceed sie 2000 ns cm. ww F 310 .g21¢ Maga 7-043 = rs 2 Bata: 60 00 ‘000 & 2 at * a | os Zao SL -0om ae amd: 405 ws 05 Ave MW=376 Ib ol2.49 ss: 1900 ppm $3000 g PCD gg Yes. Buca Sito 480 00 CC 0" patra 54 gC, 09 mg. 1 gnoisir [Kamar | 228m! [gnelcCl| gcth, 32-4 mg CCI which exceed the NIOSH stndards nes | | st anus rhea 1d pt pom mega | 19,050 4P runic 30,100 IPs 13.090 W4P pruncpal 0.70 | 1 ae 304100 RP [71 Pyouniigl]3,100 DP)og, Ford an asm tat (Potion rem enetanged, 4 Presinedyr 2240 +6240 07 « 19090-4500 17883 wae Pome inp = ee ea we atc | aes ra [TFei0% gal too 12345 1 galielion = ‘This grente than 10 ppb, (Euan WA wat Be etace] Preainedye= 2240 + 6740+03 x 19050-4500 10207 Pene np = 10.207 wales 2000, 2x10" gal tow ‘weet ep}Solutions Chapter? Solutions Chapter 2 ~ 20 as: 1 gl nse ew acon | S0gmolHhs|gomtgas|_ 34948 gmico, Ms aS 10'¢ mol gs [I gm C0,|'gmeIHO| 4 gO, . is _ 0 gS _ 270 gus 10008 C20 gmoI C0, gmaLCH 5p BCH, I $0, ~ 10" gould EmoiCa0, | temetcs |e05gcs 2? cx mas fraction HS = [2.7010] Simiely AEA BOIS age 28 © ioomotase > 10 moles 1 PPP ee Taal aaliy =250 860) 4118 )= [77 BED] ©) Baie: 100 mol me -—1 Gm Seat al, seals $5 roa onge= 270075 a alo a= 26 po 43, SS % on teats Ps 3 ost rat imo Tae 86 Net ee 1 or eit 1.20 pb | 2.57 Ona not bata het hie cet nai tot 380 prs erin {opm whl tat of eygen sos 209,50 pp he sop cone of ‘bor donde is inrensg at out 1 per ou Le 350 pn ti eu 03535 ‘pm next yen ad vt tpn hange nde cogent xe ‘rye concen fl a 207.3001 abot 209497 pom which in © ‘abs decease. Soar ino ee to wry swt an onygen GefenSolutions Chapter? Solutions Chapter 2 Basis: 100g of the sample “The biomass sample is = Side weiht fells 02 21 140 82 0 ws mers ‘00 = 0439 emo Ciemot ATP MOMS) NN(3)+300,(@) 210 stg me eo aime 2i0 dinteprtons|0—0 _ Tera] 8 The reltion use is fy emp AKKOW) with (OW) =1 5x10 kK nfowronty Methanol 0.15.10 joao) Ethanol xt" S6xt0t MTBE 60x10" To ‘The oor isin increasing persistence ethanol, MTBE, snd methanolSeluions Chapter 3 4 (9) Agnes sconvesis batso 1100 gles org oles (we St = (6) Agnes coment bas of or 1001 se (ie AE uni) | (©) Use 1 10 go cn 100 Bo. Recast ol ia slit and mas | (@) Vee 1100 les (Str AE) covet ai You ava | (0) Same savers ! 32 Stee mice a 000 mor AE) at [33 Pek one ya as which i equa to wat i pven-- wo somber ( 1842C1 107 «10 veSolutions Chapter 4 Tipe Hed) =470R 42 Yew fhe empertu sce incr elie oe ("Fo ogc sale eT iczeo) Nafte ele esi, bt ead. Wis J Chom Babes 7 518 | 2am) fora diteen nce [ele 43 canals 24600", own alte Sobie 18 TK=TR J (ta . setsaanenir p(t) fa] ore|iser) » Lod 52H orcs LOC score = (STOR) BETO ye eter eee ioe a Solutions Chapter 4 Fis lily te RS oe Sanion a Bu} sess | imme (hase "TBs a5 gat TTC sod ibinte Top = L6T3¢ +32 = fe488+0.5157210°( ie +32) 02159 10% AST 32P tr esosso'ast Jen Simon, Gy 3605 + D0447T-0.2814 10-472 60704 x 10873 “The ingrument doco onan ecu, bt bao conta i respons 76°C a canbe aber eset per ‘Theft eee ely mens tae it inerval AC =the ote AK. However, "C¢ Kas atenperue mene. The cond ence sity when ‘ceed tempentte, he "unly lence shad be oie. Tid vetoae ther io direc ne pelo bt the eo veo tps my oe ‘eure oft eave eve isi! ges ely sur ar ne igSolutions Chapter 4 48 Basic gies empeetest ~ -m « « f oe a i oS be OS B te im ts : or ee t 50 330 at a) wor fis mor > os Be | baie ns 18 a 0.1710 Bil. 8°R)|he_ | (ft) (in _|(100 em'| ica a hohe ea rae (nFlent 410. Ye ft id expo is ier wit temperate | [411 Youdo ot et sgh lie wid pe: but with np v7 [Ap bdo Mg, P= 364K: 42036 and b= 12% 10 wth he oi of Ksa Pane” 2080 ge? at += 1000 kg? Bast: Sem? water m=pV coreg omon|ossm {xoo0ig| Law hime lake aaa “7 mg _ 15.000%g|9.80m) a ° 1a70%Pa|_ Lai ore {Semito| 1in_ [10 | 14656pa_ I2s¥emlzin [3391 84,0 "2" ee L__]}} 00m —t Volume of once; S:m]302 mf200 mn]_s en_2 sides : el ea Solutions Chapter 5 S72 m)200mn]_im ends |, aspen fae enbetel ent a 00 = 166.590 mh Tot volume = 281352 n> Mass of concrete = 281.392! Volume of ispaced water ried to fot $8550.36 igh Lm HO sag s4y coo Wg #6 stn one | 506.54 [AbrSolutions Chapter 5 Solations Chapter S The pes ge eee = a Bas 500 4 20 piss1 9 0 Fe (trees) >. Re tmullerbage [Ara sohtions can be ppiving 20g yeep gg A a Basis: 5 in keroine 50 in berof2S4 mma? g/em? Vin 1136 g/cm? ~ =e) IF by > 1b, inthe AB system 5 ‘0 the procedure iso, hough the unit eonvesion i nore ss The eqton sp =4fo[ 28) (U0)] ‘The nis on the ight hand side (wi dimensiones) in Sl are bene the equations not dimensionally consistent because Ap has the units of Teg ise sth go the its woul be coreSolutions Chapter 5 Solutions Chapter 5 S1SY@GPV7P assume hoes ope to aosphere Bass: Dep= 000m p=po pe : LPs po Lato ~ Min!) 251m, , 73 in. ws |0.703H,0] 18 | 147 ig! 7 Ts [i2i8/3391|04,0) t 1 oa of en} J I ta =3579 wy? b oro jos -Lenlra aTT =| WHO Be - oe anemiven too gseat0l 1m [asr8H.0 oor = 0109106143 409:10 NNTOTTRIOR - ss6l “a — (Pane Pe (mam din) sus ng| erp ee fe) (Pees gore (Arianne | teste) (ses ) 147 pia Tia. tig} ‘enavso) (a 28s nls. Gea)Solutions Chapter $ Solutions Chapter S ye [Neither John is necessarily right. The pressure atthe top of Pikes Peak is (730.62-+ 730.62 + 1255.22) m? = 2716.46 m? Comyn SAME 1 Apso * 186 7646 n'ly350%9| 98 ec Aupsspa lee = eee Lps_[1 ue 12m ita Tig mfaoo re SERED] | 512 ap=pe | po ol eal a eats | | 0955 re ee) | ATop = 730.62 m* | Atel eatin | Aue = 206 9(08 m3) =12882 mt | 12on| tin Joso|18 [1013400 og SA= Any *A te + Asa Steal hain 3910115| Solutions Chapter § S13 Basi 750.0 Hg Atmospheric pressure + gauge presse absolute pressure pia ood LL] soe aolute pressure 265 mm Hl 1013KP pay F0-m tg~'ORP 40-102 = EEE] 1S Hg 101.3 KPa tera Soin 24a 0 440 Solutions Chapter 5 (Gage pressure most kel (fase aioli, then don ad barometric pressure below) () p= pehor we below hr He 4 ie asi: 2.5 Rot HC (ignore pressure exened by 4 ofa) 25AHC|092 04,0] 147 pia Trane [arene 7'7-% 0 e+ 20a +147 pi areca = [TT] |Solutions Chapter S Pressure reeds 27.8 in. Hg, -Asame the pressure readings comet and he Baroeter reds 101.8 Pa Conver al measrement 0 # coma et of wip Lai 4.696 psa TOLSRPS 4.77 pia forthe barometer 2738 Hg 14656 pia [a992iaHe 1345 pl forthe ending (Ube tank sat as han amospheric (Le. # vacuum) hen 1477-1845 = 12 psl is leptnate reading. In oter word, the reading i 1.3 pif vacuum but not 1.3 psi (reading of : 14711345= 13 psi Solutions Chapter 5 | © ttank seater than atmospheric presse then 14.774 13.45 282 pase legate reading, 1.3 psi isnot comet but he reading i ok. Bass: 262 in Hg vacuum 204-282 a He 1 a 92 m He O931=359) i Myf wm 6 srg) 29.92 in He ‘Vacuum Bass 51 pig Ope vaca sips 141 psi 735 mm He sm pee* 750 mm He 1), Assume the cometion tothe gauge reading is direty proportional othe {ug reading. The coreton 738760 tines te guge ening, and 51387760)" 49.3 pa 2) Analtemate covecon sto astume te needed eoretion sain Thethe concn te ed 70-3) ret 25 me The cond reading shouldbe $1251 (#22) = 50.5 pipSolutions Chapter Basie 31.548 _amospheric pressure + groge peer = absolute pressure 982-315 - ETS] Tel hi the tank key wil collapse ‘As the tak dns the pressure insiethe tank wil become mich es than the ‘outside pressure of Io; unless aii tin wil ole, The valve may ma et The pres of 50 psig is guage pesre Basis: 50.0 psig 2 ~ [T5 above smoapheri] (No) tnsuticent height Aemate solution can be obained by pelying Ap = i Solations Chapter § c+ pah+ pyshh=Py Pat pgh.+ pnb Py Pu Pe =p. p.8Ah-pih, peak = etn, ~padh= Babin,-9)) a. is elas: oxy Te ressire at Ais higher han he pressure a B. 46-091) |160 0 HE em Hg 1546/2957 HeSolutions Chapter 5 5.23 Bai: 20in He gauge pressure ont 18755 [92m He 43-948 524 Unis for gand p must be cm & cm? Pre Pressure a Presse a Pressures Pressure at 9) perme O0H-61fre) l= OT] 240 «aso [ea] » Bom PA800(Ou5)8 P4480) (090}8 (0x0) Pressre 4 1130) (Pn) (Pun) * (0m) F130) (Pao) (Pao) (Pm ]8-6(Poe P¥800 (040)8*8(Pua)8*6(0m)8-6(Pua)8 (Pao)8= meSolutions Chapters Bass: data given AL 2and3 the pressure isthe same nem sienonacooral’) conn, sothat +g thm +208 00 +0494) bon *a)=>. ais: Da genin ig nd rb terest “hs 7h A= —Pub 7080) se p= poh tie nf te CC i a ono aer at spe pe =1.958/ em = Pot Page Bo, FPA) thes, Per Pablth +75) Punt =Py* ate (= inches of war. Note phy = pay for wo difereat Mus exering the same r : Tose ae eatin net pa, Plot ra nit | | | =f FE dase Faw 9535 Prathy ince of 05 218.10 ho 199.7 +5322 [210m FEO]Solutions Chapter 5 527 Theyre: ee by te P= Pant Pago Pg Thepesue ite BE8Y Gr rg) 8 37 igh by (=) Wall: Dh = x(6mXI0m)= 251.3 m? Total area =301.6 m2 Vented are edd ~ O4108P2)"3O.6m") samt ‘Therefore, he ri [a ce fs iamne 0H0190) mee pa =646-3-200~ [ERT] pi) Salations Chapters Beene nn By m= 75 +P spuce963) somos =Potpetls + p06) dae TPO Path to) “IE spyosls Pa~Pa=@n.o ~ Paz 136.6)= | | (2977 -0.79)po40 cof36.5 cmff00 emf tug | tN | 1 a aah 531 gate he pres the tom of the wo leg ofthe manometer a he reference plone Lettnand eg posite poo, +(2.5+ 1 SKIS9O\OEI2} Nc, (136000 812)? Right hand leg pressure pu (15 + b(800)9.812)Nint Prey 5+ 1.158049 812) +8 (1360099 812)= pa (1.5 + 1Y800X9812), Manometer ResingSolutions Chapter 8 1532 Basis: Det shown in Figure a Spal. ee cote F a Pho Ase dees areas own (gprs tga cs) — P+ th Bap BBs = 185 a Ponty Paps Tepes us esis sal Poth —b iss 00m tale 1509-1669 = [pa Solutions Chapter 5 533. ais: 3.1 rn Mid am ud (.30-1.00)em H,0| Lin 1013 KPa [taetan astmkembooan” Alternate sluion PAtP uN —PetPeth Putt P= Pa=Pubh Paul Pgh, “Py 6H “Paull Py hlBAHrgs Py)‘The pressure at BG is ‘3.1 pig Om | = 324 kPa + 8 in oil -27 in Hg | Conve in oil and i, Hg to KP Pan 3244 159 91e [BSP]Solutions Chapter 6 Yes, The bleed asi: | minute [NACI balance: 025 (13,500) + 0.05 (26,300) 2.118 09.800) 4690 = 4696 ‘Accumalaion ig) Inka) ute) ‘The balances closely sted but ot eal, ee The closure i ood for indus protic. ag 20K “s Base on the poces measurements ther ar 5,00 lh mere flow forthe 204g\60 proces leaving th at exchanger tha he Feed rato the eat exchange: href, the ‘terial aloe fo the proses uid doesnot hse. The reason fortis screpcy ould be faulty flow sensor readings or possibly «ek ofthe condense o steam nto the Proce stream | vin | The Boss: 600 4g sain Ea Basi: | hour Accumlaion ig) _In outs nud = m500 0 veal material Balance ie aay uc a = 300 fo water evaposis in which cae es than 200g 76000 2 74000+ 38/00 = 108,000 wold rersin ‘The eworin he overall miei balances 2000 hho 1.94 therefore, the overall ateal balance is within th expesed err fr indus ow sensor. |pleaime: 07-106a00 2 0397 C4) (400 74200 2 73,778 +3400 7,178 G.8% ero) Propane tance: 04106,000 7 (0003974000) +09) (34000) Basi: he 31.800 7 222+30600=30622 (3.8% en) ‘Overall materia balance (kg: 1300+ 26,3002 39,800 "Note thatthe relative err fr the component blancs ae tice as lrg asthe elaine error fer the ovr msteral balance, dcating that thee is addtional eor inthe ompostion measurements sed fer the component balance.| Base: Dats shown on owsheet uns are MTA | o ou 25x 108 404108 mE x10 15x10 Torx 61x10" 36x10 100x105 90108 RzTex10) Reasons: (1) Some ofthe material was bumed fil (2) Some ofthe materi formed gases that were exhausted to aosphere ste a 30, CO (eosin measurement (4) Some proces seams ar ot shown 244500 toy. acon Sutton 230000 CCombunibes 3,500 CCombusibes 39.500 Polyetyiee 30,00 Polystyrene 5,000 Pe 40,000 les Solutions Chapter 6 Phenol 10000, ‘Aceon 5.250 Rubber 10,000 LG 24,000 ‘Aromatics 48,000 Toot 244050 Banc isnot exact bt very good for an operating pan. Base 1 week in(ons)=820-+06=9206 cout (on) 38+ 620+001 +001 +008-+1.14275+20~920 ra 900 DB. 3000 ‘Boundary: Around toh pumps and include the soil atthe end ofthe pipes nynopen system, Ite at stendystate except ot startup (aoe syst bundy iu enters, unsteady st uid) oF Biter open (ow) or closed (bath is acepable if explanation i given (©) ow — material comes in ad out cominuouly over 8 suisbly long period of tie (2) Sach — materi injected note sytem, and then in short period oft, a eacton occurs wth he sytem valve loseleone leased sas ‘The system isthe radiator. ‘Stow. sosem —siemySne Un ie x x X Afr tiling) (Aer flag) (Belo) (9) openityou have so replace water, and water evaporates; tberwise closed © omen bd Solutions Chapter 6 4 rant (2) Unsteady state foray asemptions ' - ee ye closed aru water ty in sytem because thee ad water ; ae {eee remain on meking oy tasted sie pe wSolutions Chapter 6 17 _fste overall ows in nd out over aime period for sever batches are Considered, andthe loca batches ignore the process canbe ated as coninuous 618) water and i (8) nsltion sr and what isin the stmosphere {@) Yes oold water, ot water out) Ye a0 | Ie resetion occu, some ofthe entering males wil be used p, and new ones Produced tat ent but id nose. 20 “The dest ofthe coytaline slicen nthe cylinder is 24 gem’ Basi: 62g slicon ‘The system isthe mel and there o generation or consumption. Let Am be the acura Accumulsion — Ingut_ = Ouput ‘am = 0 (OS(6Ds) Solutions Chapter 6 jon Bass: 100 bg wet sludge The system tthe hickeer (an open system). No accumulation, generation, or consumption occu. The total rebalance mow inokg ” Tigre oem CConsequenty, he wate amounts ~ € an Ir the overal flows in and out over aime period fr several batches re | considered, an he local bates ignore the proces ca be Weed as cotinous oC : : a | | 62 [7 tdepends on the roses of interest —no Bue anewer an be givenSolutions Chapter 7 Four balances re possible, 3 component pls | tot 0.108, +0.50F, +020F, = 035P 020F,+0F, +0.30F, =010P (.70F, +0.50F, +0.50F, = 085? Toul balance Fi + F247) =P (Only 3 ofthe equations ae independent you sos FP, W, you can aut al ofthe rear variables Unknown: [i] stream vaes FP, W (plus tvo composition ifyou ake into | sccount alofthe variable) “The wo known compositions ae no given but may be calculated fom 2, “wo compints exis ace wo independent materi alos aa be writen, | ‘he problem (senate unless one seam ale i secifed. [Na] The equations have no solution ~ they are paral! ins, “Tera of the coefficient matrix is oly | Becase the Rs Lt 2] “The anf the augmented matric is 2 Solations Chapter 7 ar 2 3} iotonder ru Largest on 2e0 det. of | ‘Thus although the 2 equations ar independent and tne mmber of varies is 2 (he neces conden) te suiient eondtons ae not met (5 +e Ui=0 2 sohions 3; “The eqtlon are inependent “Two ston exist can be sen from the plot Dece so unique sluon exists 14 Thenumber of independent equations is jus 3, The number of usknown ante 3, Rene a unigue solution i posible ns _—_—________Sotaions Chapt? Solus Chater? =e = [aes ] OF ROI + A030)- M0175 hs Se Tot) +030) = ta) ttt @ Fea!) tata") “Play red ce 10a!) 610") Iba!) [1 2 3 lank mini. @ FO) ¥A020) = Peal) (3 5 7hmkoangnet nani Je 10) +6020 = 169 | x roan slips et « | oe : hon Pee |b) IS. 4 9 13cotumnissumof Ist twocolumas.so rank is2. a a La 4 6) smotangneitmanini on boo | reaaea spe shies et Two independent materi alae exit (the rank of the oefcent mati 2). Ina thre sum of moe fction equation ext. The al numberof equations Shere the depres ofredom=-l. The problem is overspecfe, and will requ feast suaessotuton 16 (FF; (oF (ibe maximum can be more than he aumber of independent uations. — re amine he row of. None of the concenratos ae greater than the desi 50% 0 i) |r | 50% inet achicreble by any combination fA, Bor. Orlook atthe CHOW ie roto i i woo a} LEI nis ——— E oe ——__—— ——___ f PO : 19 Abe D ~ [ Ase Bats: D=10018 noe i wr=030 soo 0: 1 Cocticent matrix] $0850 KO | Sa i a ant © $0 to: 126 aknwens (4): 0.4.04. | 0 0 m0: uy L___Ssaions continsed hom enceSottions Chapter 7 { Ro aigae vation exis wih equation and variable A Teast uaes waion ‘ould be determined, othe 4 equations wid the moet accurate ta saved “The rak ofthe coefficient mati 3 ‘Therank ofthe augmented mate & en i a LU ° You can se by inspection that no combination of aks 1,2 and 3 wil give a mole fraction of 052 forthe mitre Basis: 250 moloftenk 023x +020m +054) = 025025) 0625 Thebalances are O36) +0334: + 027) = 0290.5) ©0575 Dain, +0A7a +0194) = 05228) = 1300 Teowtiennnaeiagmtentenaneucete | r= | = 6a 0.327 ‘The vaues of xyand 3 re not pial reliable! a Solutions Chapter 7 TL Number of unkown FW, Pand 9 compositions aunts ‘Specifications: x3, =0 Sum of mole factions = 1 Matealbalences apes) «3 Degrees of feedom = s You can make any set of measurements thu resus independent equations essing ‘ul acura) For example you cans use al he ow, oll the somposion im ‘one seam. ste resulting seo materi balance will mo consist ofS inependen, lunes, but les umber — an The inert are weated at «compound Unknowns: $ compounds 5 rams plus Steams 30 Equation: Speciation: ‘Concent not shown nding assumed where : Concentrations wih % given Eitkg Mater blancs: 5 Inpikitewstions 4-1) Degres of feedom (adits specification) ‘You mus make 4 measurements that rw indpendent unions No.Solutions Chapter Sotations Chapter 7 na 1 e aee | ee | + Rem TORING ATarRn tetera, | i © Basis: 100 mot A i 4. Unknown 4B: uations: Ny nd R material balances Basis= A= 100 ma ‘Now: You could wet the Values of Ras unknowns in each team, q td then tee would be 3 more wnseowras and 3 moe depenct fsustons (Eel or Em, "wal as ow) EAE Ne 1090.90) + B(030)= C105) R 1000.10) + B(0.70)= C1035), Toa: 10 +B =e ‘Two ofthe above equations ar independent S & Soluion: — B=7L4mol C=1TLA ml ae oat. ater 2518 Wier fat or mat or tise Sy nb ‘The DT is the alaoe ofeach ream. Basis: F~ 100k Vninoens: F.W.P OR FLW. P,DT!,DT*. DT, 4.0 uations: Eatin Basi) F= 100g F= 100g Material Balsces: Water, DT. Maer Balances: Water, DT, (otal); 2 dependent (oul; 2 independent Speatestion: 3 for water Implicit equations: 3 of Zo, =1 Degrees of feedom = 0 Depress of feadom =0 Irtzoducing he specifications and basis nto the material balances Water (201)100= (1)W = (OOK DI. (@0)100=0 +0914)? atiecament Tout 100= W +P Wensig PSolutions Chapter? ‘Basis B= 100 mot Unknowns: ‘Assure ll ofthe varias except hoe tat re pid a zr re ‘sceamvacable _componcatvaabler Material balances: NCH Cl Speifd : nx/ton = 13 Speed values ofa: 2 +1 +0+2= Implicit oqusions (x = ia) (Note: the ipl eqtions of seams FA, and Bare redundct with he specications) Taal estes of edom = ____More information is ees to solve te problem uniquely. Solutions Chapter 7 116 Here are some possibilities. Consult he bless the end of ihe Chapeformare suggestions 1. Rophrase the problem to make sre you uderstand it? 2. Draw a simple diagram of what was bappening” 3. Think abut what was going ite the tank and what was coming out? 4 Imagine youself inside te tank, an ack what wis going on aud you? 5. Adewither there were any pyc! nwt conse (cha eonscraton ‘of mater or ener)? ‘Tey to imagine the answer as a number, graph table or whatever? ‘Tey wo Sdn eset vibes? Choose notation? Lok for ready-made forma for the answer? oak for simpiying assumptions? Try to ind near version ofthe robe? ‘Look or bounds (simple model tt would finely undeestinae or overestimate the sewer)?Solutions Chapter 8 100 evapo | ‘nial =a) aap | cosamer "Tg ™ S | war seks 02s Woke 100% 100% CCocumberbalnce: —G02P-001(100)=0 > ig) Aver ea fet [| rl i Anes aune5(8) -S6)= TSS) renese $B 8) as Solutions Chapter & Sim: Bais i vn (20001) shade Sina 1.2.3.4 Sige Dried Sludge 47080 F—~— 03511,0 Salis w 075 sae mm eras Ho. 0 Siena: Bais: 2000 F Bae: 110 sons: PW Sho sn Soi 2000030)=7 (0.75) P= 800m ‘w= 2000-800:Solutions Chapter 8 Destin | be Ho 20a, Howse, Sens Gant? Usinouns: a ands witht eats we and B60. Depes of ieioa= 0 Sena? (©) Oban: 220m 215 mL = |S} Uridine 2800200, _ ma Dit: 1500 $= 1505 mL ier 141 Coneninion: 1/905 = Ta) Solutions Chapter 8 Mo 9m ‘Senf Uatoowns 2: PW Sip: Belaces2: NOH, HO, wa of 3) Ste 82: Tost: 2=W+P NAOH: 2(03)=P(18) Ton eau)Basis: 3000 of poet Sins nd Unloowns: A nd: taline: a and poker Taal A+S+500°3000 Palmer 024450390 A=sc4o= [Eo] 82300-1700 fi “Treat problem sa sendy ste ow rote or ar anon ae a Stem Are ow en Solve to gst MBN 100% Fab) P1001 Ot rae PO N 005s S O95. Toe SupS: Bais: 100016 P ‘Steps and 7: Two unknowns, F and M, Two bane canbe made, N and, Stosslands N:—F(0055)+44(4.00}=1000(,008) S$ — FE.085)+(0) 1000.92)Mot. ton Wage cx, Syen [-_— te notin Molt a0 Peon 30 100 en, O50 fe_030, a Basie | min 100g mol F To geP, calculate fist the average mol. wt of FandP, or transom the role tos to mace reins Basie 100 mol F Mai Mw is os ne 920 08 Basi: 1.00 mol P Mal 050 230 100) ooKgmolr| 16keF |0.20%gP| tkgmolP TookgmolF| Tigk |10.01KgP Sottions Chapter 8 P=272 kg mel [ste 6.7.8and9 10409) = 2720050) ,} 120506 | wecell THO 25% cell, leas 1000 mF, 1000. in fermen] —_Gem'cet | Ligeet | 25gsde Poe toc ale (1a ai 700ea aermeie)Seltions Chapter 3 Solutions Chapter 8 fon stale tty molt ire it campo eit (CH (Ch (oy wnofin-snee | lec A.B. Crepe repent molt sch mit ee knowns —_ 025440390 +055¢=030 (Cy ace a vot | omy a ar ossa+0200+000¢ 030 (Ct tame 8 SS heme | 040k +0480 40056040 (Cy alae S4085C=040 ib Lease EP saya i ain te feo nb me) cs settee, (EGR E=SST—O=BOS bcos Bist mn spond pepe ef mi y Deng econ A, {oxo Uno: FP 05 rt ste spon ba ate wl See me ‘rin Gumi ne cee — a (CH: F(L00)+ A) P09796) cos F @ +220 (00204) P= 11141 met lb. Redo the problem wth new compasion for F cH, 099 0; 901 100) (continued)Solutions Chapter # Cs FOR) + O)=P OO) =3820 nin Co, F001) + 2.72=P 00204) | sao ror 2520-174 99» San 1007 Be] Ny. 723 kgm or 12 min |sups: Basis | he Pipcine [PAY nit (sien: Unknowns i hors: 2 a tat {susan |sups: Basie | min Be FO+10 (000012); P=833 10 he Ko: F(00)+0 = pu1-00012) [sep and7: Twourknown, F and P. Two balances cas be made, Nand gs cerest Tm You can use heal balance ae subatite, Tos! F+T23=P. Nay F (+723 P(0.00382) EWC] [FTG ooiginin or La Check using the gus balanceB16 Step Bass: I year seme 2 F-1» ——+| [—§<» reissue rer ver pn eam i vc am va he (pe) Stead [Two unknowns: F,W ‘Two'balances: PET, PVC Stand: Per tance ——F(O0)=P (00000) = 15 «10k PVCbalmce: ——-F(02)=W (L00)* P@ceapi0) Ws (18 x C10 ‘Totabelace coud be usd ie fone of the shove Feiss 1t+w From PET: We (133 x 10h (002)~15» 10°10) = GE) 12 153% 10 Jats jo Selaions Chapter 8 Basis, 30 ginal sokton MW Ne, $0, 1010183222 4 Mw gol Ou ean) NaS0, 100 1420s 0708 Na,S0,-108,0 100 O30 HO | 20 W801 i110 Maral ann ing mol = ot mm 2% NaSO¢ 0704*0510 Mem, Mang “OI SST HO 110=0310(10)+ Mo Myo AD MAL Moteur: [ReS0, WRG and HO TP scm Hon acalen pr cpRalTTOO Raa a] | Toa 838 20007 100 300 solsion |Solutions Chapter 3 16 Assume steady sate ow problem (alta is unsteady sat batch probiem) pn sono Fe Bue Te 8” tae Calsntcomosians Bsc 10m NiBs10140 lM, th weno, My aty es Das: 20 10100 5 80, Uainwas: FB ise NBO HO s020; 100-PesmH F029 i Toa: 0smo=P-F Use 1,0 and Toa to geP= 155 Sgand F= M45 @ 1555 a rio: !55 90) = [578e Na B,0,110081,0)] Sp 100) = Sig Na 8.0100 Solutions Chapter # (Check we Nasr 1000" 1000 sume he roses i dy ste one without actions. ns 2.3 nt |__.. reciy2six0 Fel, ton Fecheno 2032 Fechio, iao2e Fech2sHo 30126 Ho. ism Caleaatte compotion fru eon compound. Fe the simplest we. FeeFi; Bais 1g ml FocF: Bais: hg mo Fec,-64,0 Foci, 80 Som MWg tem MWg rec, wan Kan kaa Ho’ 6 a3 103 Ig ForP Bas: 1 kg at teal rect, i Ho 25Settons Chapter 8 Solutions Chapter 8 | Sun Baie 000g PCL as Uniaowns PF SoA. Boe) : ws (a) (a) =f ; va | 0 25587 | — See eee oe ae | The proces can be viewed ata unsteady proces without easton, or a flow proces | sips: Take as ahasis 100g of Be(NO> Sens f ‘The maximum solubility of Bu(NOs) in HO a 100°C i strated solution, 34/100 i Of HO. Thus the mount of water equed st 100°C is 10 gH.9 NON), «54 24,0 HgBaN0,, {the 100° soliton is cooked wo °C the BatNO,) solution wil sil be sured 0 that the compsion ofthe final sohtion is mas: | 5 Wom: 2-00 BANOO Tees (comme)Solutions Chapter 8 100. Ms 100 oss aa iors “Tae composition of the crystals is avons 22; 0s Hho: ct -oo3es iver ‘The composition ofthe origina soation it BuNO; 100g HO Bag Stns 6an 7 \Werhavewo unknowns, Fand Cand can make wo independent mass balances shat the problem has aunque solton, Ste 8 and 2 Transport though ‘Bnlnce ‘Finalsoluion ‘nol solution _—_—boundar ont) BuO); 0.0476) 100 = 09615, Ho: F095) 2341 = -co038s) Toul F o0+2 =e Solve the Ba(NO;) anal Balance to get F=m052_ CH 88898 Siep10 Check usng he water balance 305 2(09824) 298.17 -8,85(0.0385) Solutions Chapter 8 aa=342 ‘The Ba(NO tht precipitates out on dy basis is $699 4002615 BAO) GET FHATO] Tee, EBA On Mew 950 «182 . MEO Yo sda IBNe8,0, 51,0 county nw Binet Beaty wae NaS.0; 51,0 eats ‘ey sd. ol cysts Na,0, 5H,0 0.1% impurity died orale Bast: 1 Bo! NapS:03:$ HO, impurity fee Com, tbmel malt = bh tit cr aa 1a 1 ost Ho 5 8 0 0385 Toul 5 m 1.000 (consinues)Soletions Chapter 8 Basis: 10018 D Oies:0x 5 H:0= 99.9 8) Some. 2 NaS: 990612) ou #0 oyosss) = 88 impariy 0.1 Tout 100 ‘SeeamC —_Lety= 1b impuriy/1001b fe water in strted soition Bass: 100 Tb ry crystal, impr fee Woman ¢ —Iomating st comm, sa fusin iw» Tol ce em cea eee) is \240 + 9/ 240+ 9! 0 me) ae (884) inpciey _ oles) (ats . 240 +9) 240+, Totals 100.0 . 106 SreamS Basis: 1001b fe water in sad son, puri fce Como Ibfomslibfomfoewner Teal aiff atta NaS: 1461.2) 8568. ss7 0357 SI ee Born 10, 14038.8)=5432 100 1543 0.683 aa 0-9) Teas oe BOD Solutions Chapter 8 jr tae om Ctr en enn ie ri, Wc fon Tou 100+ W, =8+C 1 | UnknowneW..SCy | Uitnomew.scx “ ' raat Hp sew, cl | ‘Benson ntl nd awl besa anh exis Tuk Cae NaS,0, a Tout (equations and 6 unknowns "Note that te compen term involving y canbe elimianed o solve for D, Wo, W, and, ieuin (Continued)Solutions Chapter 8 fect making al NS 02 and HO balances overall the process. The sohuion of =D] (ORETT Bass: 1001 pulp as recived b= __ Sup0|20 TE Fei ToT Lm 100 520000 Assume ar ded pulp means th 12% mise pulp. 3B pup|i2mH,0 | (sie pup Allowed water= oss 4,0 Pulp on comract basis = 78+ 1065 = 88.45 1b Basi 1 tm pulp as recived coat = #865 12% pulp a shined S00 {001 sinp Vien You pay fer soap pus transportation, Bass: 100k sup with 30% water Comer Soap in wet soup to soap in dy soap. Dat: ‘Wet soa) 30K nis 1008s Soup lance 070W=095D or 0.7000) =0550 DTS. kgf which 7g insmp Cost o Wa your site (contining 70k sop):_100(8030-+ SEF 83608 Cont Da you ste conning 0kg soap 73.68 ("5 08 frase) lazz The problem beret decide onthe lances o make Nota wil be indept jsinces. [sie L.2. and I (comtiued)Solutions Chapter 8 F= 1008 Hi) Mas se ie niga ce ons H,0 0126 natal VM 0.1665 rym) $83 Costs eb Ou: Mast. Mass 000 0 “o107 ™o YM ayy Raw € ES Ash Oo Baw ° lus Bale F100 leas trtaves: mya. tarmeman Pt (6) Jue? Baers HO. YMG AS Ea.= mya? =0.10 tmelP 010. (dey 6 edad ben an low TaORNTHOR— = ma Hai) 00016581008) = ama em: — wosrenesm = me Jabee) 100001354) = at 100+ - oF 35 mgX BSL (conti) Solutions Chapter 8 [Not at ofthe equtons have tobe writen down a above. Noe that ash siecle {oP that the ash alone gives 100(0.135)+HO)=P(010) P= 13S and mya 35% from aaa balance He 100? [spo Check va HO balance saan 9)Soletions Chapter 8 la23. Sep: Basis | hy suns. 3 and Sins and: {rere aero unknowns, sd we have 4 independent equations, bt the precision of neasuremeat is ot the sein ach equation, bence deen resus are obtxned [spending on the egetons ne. Chore the mot scat tse —_____ou_| cx 001995806) Tom ie 9570+ 00118 ne 0.0090 + 0.9768 cr 018 Tos D+B lcs lars Solutions Ch seo abalone: ka moldey 2992=0975(5904-8) +0011 B Bical Use a= a.Ca ines: worm 2667 = 0.009 5804-8) +09768 Dasa [The other wo blancs give stetgeifociigonc| tam. yy Ht r ToOKginalF [TOM kgmoIC, |cst ana ie cement Signet ose late” 20 gm ay ftps 1.2. 3.and 4 |Assre the ote components have he same density a water in al ows. 3785 106Liday 150mg BOD la 5 mgt popA BoD=7=x 03m is Basi 1 ay (contimed) | |ieee soaxio"L day see [pop massa anf an00 nf 00 ao }zg00D 2892 10 kg +3785 x 105g = C= 29705 107g Sx 109 A+ 15010 B=xC 3107A 419010 B SAI 410) 9150 ONS A) ETT] 29708 10" a ] | I vist | or | fToaLmssinlace A+B=C éylA Utigh taf Lg _ ida Cg jay] CT Feel fay 1 530. 1M4g + 15.8 1064g=C= 5458 «108k [pO mass Balance fx104+N<109B=5x 10% sto" r 2n10%gB00 | tif tfne 10% Idee U T las} ry Sx10°C-3110A, Is B _ SIO YEAS 10-810 ET TOTETT) oe 1sex107Soltions Chapter 8 oo Weta Wak ony anim tas The exrator issued oe a steady state process. = cot Simi L.23.a044 All ewe dts have een plied nthe gue a ore s7Ct +10C% =97085)CF + 100Cy Scent (ric sean) Waste (aqueous steam) [Pinal Eyer Trem we ee 2 OE ween — ceuset Seer ee A fe Onn, Balas ut set b oileg _ @ulPe cae eeeSolutions Chapter 8 NH, xi, A) sp ks 5 7 pi nest TI XH, Biggs = St : Sokg Fm) Tor way HE 1 X90 70 Basis 10h fence, we have an adequate numberof balance (ules some arent independent to halve te poblr [tsn4: (revised) Find the moles of F by geting the average molecu weight of. Basis: gol ‘|e 7. and Thee compound alae canbe made, Np NH, and 8. Oneretaonis | Solutions Chapter # mete Mw assis) hws 0.10 v0 103 Is 090 reo 3500 10 5903, 1000 ig gn 7170, oo beaten) Teste | ~___ ow __| (8) bg ol 0.10(97.171) + Ws ‘ [sasmen:aiocszin) + oon as- SE, e@wmey: 0077) + OUI) MWS a0) fsa: 011000) + 1000 —)5 4 9AM shasta, = L00 of, 401.00 INoandS are tie components. Let x, [Thea ny, +f, =A and my, +m [sme9: "A toa balms a 100+ 000i abt 0, py cen bevsedintevofeneorthe nore alee, a At sagt gh 8 (consid)Solutions Chapter 8 [SSR et Brordes Hg] (=n |Note: The se of xustions can be simplified bysubtiion Solutions Chapter # asi, 2 hours ‘The proces i ilstrted in the gure wera, | 9. MIBE | TBE mas f= 1.00 ‘The MTBE eiving the pond in 12 hous is 10 em |a72 ga 19g TRE TL (Vem? |Tggnoline ~ "7% ‘The pond holds ignoring the MTB in the pond which ineligible) nal oepmorgto arena Tm #0 ‘The inerese inthe concentration of MTBE isSelutons Chapter 9 Solutions Chapter 9 _ ‘ Problem Basis ner ‘ . Seagci 592 pAgNOS on BaCly+NigS04 4 BaSO4+2NaC} ‘ SgNsNO) 10.08 AgNOs a SpAgNO; L721 gNaCl Mowe: 2083 14205 7024 seas . SpAgcl 2otgnact ci STBNANO; 3.44 1B NaCI a Bass: 0 gNeS04 & SIbAgNOy —-AZIBARCL aie ms » Sib Nacl 1227 agcl fxmpie SENSO4. sel, 80,f Lema Bo, PRS AC i SWAN, ‘GEBARGL 12.05 Na, SOJT ¢ wel Ne,SO4] gol Bs y3 Base: Ion dolomite I 93 on dk | » SEBeSoy sa7g Bach (C2003-+ 12804» 64504 +1404 ‘Assume complete . SeNsCl 891 gach, eet ae é SeBach 341 gO « S—BsS0¢ 3.088504 MyCO) + 3504+ MaS04 + 20+ COp f STbNAC! ——GORTB NSO . Steals ‘$0 99280, . t ST)NaS0y 21 IB BS ome, * bake t SWNaCI 998 b BaS0g cao rs 13601000 Mgco3 » oa — SO; a a ao | AgNO) +NaCI-+ ACI NANOS sal co =n wn Mol.we: 16989 S8AS 1423 8501 20.7 rola mol COpprodesd| 44 Ja. Basis 5.0 g NaCl + apie | Trot rect — [Ti5mat C0; ~ BIE TS COy] i mol Naf! &mol AgNO 169.89 g ARNO, 7 mol H,S0, rad 98 H,S0, ed 8.45 gRaCIl I gmat NaCl || pmol AENO, ton dolomite motreact [TmoleH,S0,p4 BIL80,Solutions Chapter 9 oa The balanced equation: 3 AnS: +410 +28 HNO}=28NO + 6HsAS0.+9 #580. ond the reaction i unique win lative proportions. b, 2KCIO+4HCL=2KCL+2C10,+ C1; +2440 jor KIO) +6HCI=KCI 4301 4310 Jor AKCIO,+ OHCL =3KCI+2C10;+4Ch +5140 We classy these ection at nom unique snc they are nt spy proportions suena ney naapnen snd init pono obinshy Jos Basis: Daa given in problem tenet 7 Fe 1 pmol Ft pmo X,0,| 2 pmol X Te saiatel Zenit (Tem, |i ete gest | ego 1 8.87 ae] 2 gmat Fe |Tget¥,0, |r anol0 Tel Solutions Chapter 9 956 ais: Data given in problem statement | 1en2IC [2005 94s ge rel C0; gk Smee pt Smt a oa ee ear aaol pate a 06349 g C.H,0,-0437¢C-0031¢4g H=0.166150 Based on 0: £16120 gmalO , ROUSE RIO aro 1 [i605 "cates ora ae ame -Ssemtc <3 gmotth aves gm on mt Te foul in integer is thosMassofhydrate 10407 Massof ry sample 95208 Masofwater 087s SREB em B90 ott, 0887 HON ESIH2 «56455 gt. 0 {inca gio BORE 09,02 H,0 fort Bal, Tash yates Ba, 21,0. Basis: 2g mat fmol w= 7248+ 96176 2emot 176eL 1 dem ptt Solutions Chapter 9 29. Basis: 2000 tn 93.2% $04 day) 20s 053 $04 99H S04] tel _| sons | ee SO, at Sof ants cE} | 1 Smal 04 321000, om - wo P SHons Twat [ion moi0, 223 Be OD 7 | moet, 181000 Sion’ 1 Tmo [Ton mol,0 Mw. be Bases 1 Bey 2Be 1B, 2 +0 4201+ Be Bes + C4 GHB 2 1879 stot seawater aE gE ‘Worbreewsie] bb, mole, [1 mole] 709 Cl [5991 BrJt mole Br, mole, x10 seawater pe a Rane TE sea] snot Be_|t mol 59.9 | 1 mol Be, Tel GH85Solutions Chapter 9 Las Mw Mw FeS04-7H,0 F719 FSH 189 © ‘ " 0 Zn 1 ° “4 FeSO, 4H;0 239 FeSO, 119 Iti best to evalue the tree types of ferous sult inte ofthe cosvon of FeSO4 ‘Yes, the equation is balanced Bass 475 tom materi Fs$04-7H, by Basi 15g 250 a $83,766.25, LS kg 2a0|1000 ¢ 250] gol 200]t prot DEZ} 1234 =DEZ Fe ESE ea session FSO, 740 whichis ego oar 8176.35 ots vez 279 ton FeS0,-71 - AO kg DEZ _ are DIZ] a Tee wt FeSO, i000 g bez ~ EEEEE PEE I {on mol FESO, «393 on es 4 22! oft. g H0|L0 gmol Ho}. gnol Dez|I284 4 Dez {or aot FeSO 323000 FeSO, OF 180 g H,0 [5 gmot HO] gol DEZ F804 40: age) $323 [1519100 FeS0,] Hon mol FeSO, [1 oe m0 FeSO, 48.0 {on FeSO] on mot FeSO, | on mol FeSO, -4H,0|223 9 ton FeSO, 48,0 = [EDT FOAL] F:80, 1,01 $323 151.9100 FS0,| 1 ton mol FeSO,_| on mol FeSO, {on FeSO7|1 ton mt FeSO, | on mol FeSO, -H_O1169.9 on FeSO, H,0 =m FSO.)0 2 ° Solutions Chapter J043 Thereactionis Cato +6403» 4CO, +580 Basi: | mol Calo : Minioumn 0, 2 (LFL) (seo tsopce contain 1.9%) 650) p34 Baie 1 1 ston= 6008 10 B | soams)igmoinsh gma oct? 5 Hoc}oogHoc wt itgeid 3118 Tt rwoins bpm SHOOT | Wnel. Tat | You cn use the density of 0 forthe density ofthe softon athe HS comet has eile eect o the dnsiy Solutions Chapter 9 1NagCO3 +Ce{OH,)-+2NsOH + CC, Basis: | ton of sda sh (Na,003) {ton Na,C0, 1 ton mol Ns,CO,| 2 ton mo N9OH | 40.0 ton NaOH 106 ton Ns,CO, [ton mol Na,CO,|7 ton mo! NaOH 0.135 ton NaOH | | | $130__[1 ton Ns,CO, TTA Tron NaC Ten NasO0,] 0.755 NOH = Tae above result i forthe case of fee OH.) . Others, the value rust be redcedt | compensate forthe cost of tie CA(OH;) ~ which ight come from the CaCO, produced, snd possibly be cheaper than Ca(OH) purchased deySolutions Chapter 9 9.16 Basis: 1 kg dehorobenzene (DCB) The balanced stoichiometric ration for dchlorbenzen is shown below: GAC) +650,-+600, +1,042HC1 Therefore fr | kg of ichlrobenzene the following moles of HC are produced eg C81 tg mol DCB kg mol HCL |2KEmoL HC! 6 ors6ig met CI Tag DCB IT ke mor bcb 16M The belated stoichiometic escion for terachlorobiphenyl ia shown blow GAKCL, +1250, -912€0, +H, +4 racer for | Mofterachlorobiphony (TCD, the flloming moles of 11 are | produced Basis kg TCR Lig To) bg mot TCH seg aol HCH DOE TCR |r kpmor Tew "O18 MEM HE! | thas, the amount of ai produced does not change sigan (1%), and nether wil | he amount of bas required for newalizaton Co Solutions Chapter 9 joa Basi: 10 1 moles phosgene For phosgene: 182 [Brame eg Reese) = TT) 3-00 [Baal Bast: 135:mah CH,Solutions Chapter 9 Solutions Chapter 9 je19 2FeS +30: ~+ 2Fe0+ 280, 9.20 Basis: 1080 bate 27s 6 MW 8785 Bass: Use 10 sag |A}0\13H.$0,-6A1(80),#34,0 SAB ALO,I BROIALO, «55st a0, | 00 bvte|10L9 1,0, | 5.57 reacting moles was 0228 1B 60557 reacting moles 9-10 457 mating mol |AL:0- isthe liting reactant and H,S0. isthe exces reactant ssmownn on Basis 2000 % A1SO4 2000 AL, (60, | 8st A1,S0)4| Lb mt ALO, ®.1 TAL, ($0,) ma A,80,), 1019BALO, Hb 9 poe ibesntotfsseete, 8 223 00 = (1Solutions Chapter 9 921 Basis: 100 kgof fasion mass BaS0, + AC + BAS + 40 |com. Witeeks MW emo Bis, 2833 0a Bas ma 1300 c 9 no 16 Ash 22 169 B2SO, ay, = 0.0196 + 0.430 0.4776 mt ug: 1164 (0430)=2.8 mol Caton i the ining resto Needed for complete rettion = (0.4776)= 1.9104 a 0" amounts of etn ‘You could cleulatethe exten of eacton fom he aS and weit to gt the origina | Solutions Chapter 9 i922 cO+CI:~ COC Bass: 20g produ geal ons. ke ohms Clin Cin che 300 cock 10.00 oon co 022 3st 143 (male ¢) Cathe ising estan; CO isthe cre cat oasi-018 (0) [RSET S101 0) = ROTH, el] 1011 kgm COC, sagSolutions Chapter 9 ozs Sin “Te molecular weights note to solve the problem andthe xm roe forming Soneonent “kg “Mola “mo Shs 065033071766 Fe 020 © Ss85— 4476 eS 020 = as Bs 791, the proces is iuseate in Fig. P.19 Figure P19 [Ss: Basis: Da given in problem sutement (0) ond be Limiing reactant, we examine the cherical ection equation, The ‘io oF Sb 10 Fe the equations /3 = 033. Inthe sca ection the ‘onesponding rao 17664476 ~ 0.395, hence bythe exces react and Feistheimiting reactant. The SbS required woreact withthe liming reactant i 447613 L422 gl ‘The pecnage of exces reactants Hexen = 6-1 cay RESET) o @ Solutions Chapter 9 ‘hgh Fes he ting reactant, otal ie Wing rant rects We an ‘amp from the 164g wel of Sb bow much Fe actly does react 1.64 p00 S63 BOF 55 got re Beanotse “8 by the fntionl degre of completion it neant the fraction convenion of Fe to products, then Frctinal degre of completion = 246 035 ‘Lets assume tha the percent conversion refers the SbSs since the reference compound is ot pei in the question posed Let p15 1861S, 549 gmt, ss caoenin ofS, 84 28. The yield will be stated as ilograms of Sb frmed per llogram of Sh Sy that was fed the reaction orgs _ [0S] Dao Sb, [1 H,Amount of hyérlnd: “otal pron ens24 some Tel is 100k A og eNO 9 gm cg NOS em CBLNO| 3 mC Pra Sresens Pgoscaaoe arose + (6S incon eal conversion) Selaions Chapter 9 o Nis 713 kg mol 20000 bs C| [ENE cog; kg $96 sg mol NM gro CH, 0,95 kg mol NH 113k CH,O,N ‘Sky anol NH, 100 kg mol ed ig mol C,H,0,N OR]: Solutions Chapter 9 Solutions Chapter 9 are [patna who baw | [er ras | TB mal "°° ] | es 200% Fd male =2149 bootFe [ees eee | [a Theoriat C= 1839 FeO PETES, «255 mol FO | 100 ¥e£0420008 0)! baslFeOs | sBmle_[12%¢ or er Ser [sree Pee 8 Mot ba: Females | f(s 5 op EET |p, Luenes0] 1200 | tomot Fe |) mot Fe,O4 159.718 FeO, | TonFe,0,pS85bFq Th mole [Th wolFeD; [= 172016 Fep05 recs 20 100 = [RETR Fey | ABD 100 = 5H FED] bon Fe, 20 a oh were BeviFeO | Pmt COl 28800 smc 1 wimatFe]3 8 mol CO} 281CO ogy g S588 B Fo]? Bl Fe [TB eee Toul (35.62 00+ 9024 1 CO) = BHT OD) | ey L20FS01 200m Fe | mame [ Bat c 12 BC Tose; BSS BEE ea PPS aC LenFe0] iw m0 |paviFe0 | Bac [126 To Fe, LS BFSOP Biol OST 3871+ 153 = OER 16 Cw Ho FeO]Solutions Chapter 9 928 ly +2Na0H +» NaCI+ NaOCI+ HO MW: 710 4001 SS 745 180 ones naif hsaon: A Ionel (0286) 1.99 ot (@A19¥-1= 120 (minima) Bho NsOM in exes, b, Yoress Naor = MOTNAOHL nS (199) biol NaOH | [0.01 8 NaOH) 59g) (EEE Eee NAOH] (ism sont ‘aol Cl, wb tore orb = 20. eae e. Degre of complain = (EB eng oes AHC140,—201 280 sas 3271018 esis 100 mol gas mol 4a e098 396 ws (unxissy 20 1000 (The Ns balance gives the O> 813.8. Colette exten of ration for complete ection Foc Ct 2-88 (ee im) For 0s ) Gimtetmigmcan) = 0) Men = 10 +Solutions Chapter 9 dee of completion = (99 tom (41.0) 0.90 extent of rection ¢=!24=2- eating ols 5:30 Bais 30 a1 OO, 1 mal CO, 35 mal HO ed Th 60+ 1,0 * CO, +H; a wD Solutions Chapter 9 oa £09 (fo each mol of Hy produced, 1 mol CO resets) 1 ig fol H,I2016 kg H Lig mt 1,0 [kg mot HDS kg mol Ol TR kg HO CET 1 mot of CO, i padved fr cach mol oH, 2 Bo Se TE mg, 2C)H,+0, 92¢,8,0 For 100% conversion of i soning tection}: 2 mol CH, / time a Fr rection Lal oume 9 135.00 GHtine “Ooo ncame change Bass: 1001 meyer Gl) tons ae Ince fn Gay: 7 CHW 93~36.048065) 41.89 H+, +C\H,+CH, «a Hck DeceseinCiis (5 -26)(822) = -038 Gilly HH, +6, CH, Expense cage erase) Chang incntjt s: (00-0085) (825) = 013 Net change: a Toe ini selesiviy i: HICH, = 0.7 ands The munke of males ef alt inthe basis merc, Sa 0993 ho [20.11 CH, Beat 0) GH. +(0G,H, 0833 GWG 07 vith he res dom C= 0400 Gi, 0343 Fate selesivyof 2 theres ee cot =0489 Gi, -0370 Te caalatasdinche pectin cae is teat Selon 0f 07 — imoeem, Selec of 08Solutions Chapter 10 103 Basi: mol A Ana 50 percent conversion gives the produ: A oS, 20 uu (8) Mole fection A=05/20= [33] (©) Extent of rection 02 Assume assay se dow prces wi reason Sea Bai SeosJ.2.3an4 H@rSHICL @)>SiepeHICK®) hr (6.2 kg mal F622 kg mol J Woke mot) UCL ‘IHC, Xa, Ms 0.225 oy H, Mati ma Bac Solutions Chapter 10 rer Semi: Unknowns: WP, 3n, Step: Balances: clemen: lances ae H, SiC, 9, = W, ny, W (Or, sing the extent of ection . Hekemoty 6.2(0580%2)+040(1}= 4 has, + (2) Bass sing € [nu ~(0ssoy622)]=(-146) SiHCI,: [ag ~(0420K622)]=(-146) HI: [ys =0}=(03K5) | [nc -0] cng)Solutions Chapter 10 Species balances Ieappers tobe cabo balance Sip L.2.3.and 4: Tosolve this poblm you mus recall that 'HsSOsto form CaSO, nd tht CxCOs hen bated yells COs ad CaO whereas when (CaSO4 is ete tthe ame met des no decompose. Although the problem seems 0 | beundespecite, when you daw a dizam ofthe process and place the known dat on ‘the station becomes Clearer Assume the prea steady state open one With ‘exction. Then he element laces re st n= owt. you us the extent fraction, you make species blancs. Note we ae designed he compositor oP and Anes af he mss of och component mf, ue an tas aro obese cole mas he | sone or pcs batne ner eos proc sch 8 OP). ‘The COs liberated from the shige i equtaloet 19 {1bCO,|11bmalCO, 1 molCaCo. 100.09 C2CO, owe #410, | ImoiCo, | TemelCscO, 0227 WCACOwtOP Solutions Chapter 10 Hires ® 1,50, We Yoomen Ho 0, ass » Feed) » a 80, mt, cco, 095 inet, ion 005 rw sso Bln. 9207 Sica Thevainbes whoever sreunkpown aA, mi os | ta mbasP, Was ¥ a alo Seo The cement bales ttc be made fC, C0, 5, ner (6) |sttnetnowtin'= A, / Pan fan /P) 022 rata ie | eunions are independent, we an find ig ston, ‘Siepi8 and: The equations (in = ou) re (except ote inert Balance which isin) invmoes (cominSolations Chapter 10 £ [Gq BRGCO tomers, [Th moi 100.085 CsCO ib mol CAC, tle BOSCO hmoICaC0,|_tbmoIC_ foo opi» Caco oma Cac, q hee W880 | omaiCa$0,| toc 36 sia0TbmoicaS0, (¢, D9SIHCHCO,| 1 mol C0,| 11 maIC__¥ m1 CO_11 moIC 00.09 CaCO, met Caco, 71 ot CO, so, CHO, {Ib wot CACO, |_1 mot : 100.09 b CaCO} 17> mol CCO, «¢ Mew!¥H:S0,|1m mot #,S0,|__1 moIS ST (908 S07 mol HS, BCs once, |e | mia, BESO ~ Miia tpaelug i016 #,0] [8.0850 LO |_tme mein Fb H,S0, ‘pio BHO mott.0| 119 mol 1.016 H,O1i 116 molH,0] 1 mol Bilbo! C1004 118 mot CaCO, ioo,09 1 CsCO,| 176 mol CACO, ha, BH.SO) hsmaiso| emeio mol HO 1H 3m moo. tomo! Tibmol 1,80, Solutions Chapter 10 - tio HieHO| bmelli0 | Tbmoid i. 016168, 0f Bmolt,5 | _ YomiC0,| 2h m010, : imeico, eo, seo yma Caco, io. 09630) | bea, 1bCaS0,| ttmeicaco,| stomato_ | TB41SCSCO, |7TomolCSS0, } MBH motto | mo | T8016 HOT mols 6 Inert SB fer= m1 ine ‘The soln ofthese equations using computer code would ive all of the alas of the unknown qunies, However a review of the set of equations, afer baving ge ito {0 ge the desired answer, namely the Cs alae the in =P, and he net balance plus | eg = 0227 bo, ¢ ag 45* Pm 2cy (0207 ce 0949 = 0.010 mo, + 00073482, SRE at 2Sotations Chapter 10 em “This OuS doom ect This ca steady tate open proces with reaction. Stan: Bais: 100g ml P Stop and 7: Unkaowes: aggsA,G,Y Element balances: §,0,N, Ca ‘Step. and 9 Balances ate in kg mo on the ements Neal) GC) + 0072 (100) 021) =.) +100(0072 + 040.081) VC) 10010847) Solutions Chapter 10 er Solution yes ink mol} G~ 181, aog=Y=9.01 1s mo1S0,| tls m8, gan of cs that ret goes $0] Tama Caras) mS ‘roms yous te eaten you neal wre dow he ced ectens 08+0, 400450, () 50,+!9,550, @) Stns and 7: ‘The uskaowns: 4 above ps § nd & Balence: 6 species balances Stent and 2 oo oe) ° Me OE) room = noanscnereeey nas = A079 rao = SNeyecnen ‘ own) cia108 GIF) + SOLO) -HSIECQ*2H0 HSiR,() > Sif (g)+ 2H) o Te net reaction ie AHF +Si0, + Sif, +24,0 seo. a ig FE By ‘The proces i sn untedysnte open process Fs: Baie: | mol Fenn D seca i ‘Unknowns: 4m, P,& loss SiO, from wafer (L) H Batman fv 0/80. Goes) Oacegaing Ex =P lone sans 1 ue 0 =0590) 25%10* reacting moles Sif ng = +1250") 125% 10" mol Solutions Chapter 10 FO ayy =O OHI SSTIO" 22510 wal Nem 050m SiO aye hay IKE) ma Comoston ah [asl] oes ase Sik 135i? janis Ho 2010 [ams | sao 50s Soers | os_| you use element balances: Sin 6a082 “The unknowns: 4 PL The balances! H, FSi, 0, N presumably 4 are independent) Other equations: Zp, =P 1M Face Nem Pe oS) ty “trae Fe OSt)= Ba tou, Si (atan)" Mae O anart ease N: 2(050)= 2, a = O9DSOO4SSottions Chapter 10 109 We wl view his roves steady te proces nan pen ten wih Now ina ot and 2 ‘huge he mie nist om be ita he flees. Fae eomponen Eguton | (oj omer Egoaon (10), oot oSns ‘The blorgians donot ave be ined ite aon ofthe problen tpn, 2,3,a0d 4 Figure F109 isa shh of he roses H,0 (80%) #0 p= Chits0, 040129 catton CaH,COH igure 09 Step § Bais: 350085 F Step Conve the 300k ito mae of HO a CHO, = 380108) 35001012) Step6and? “The degre freedom ais a follows: Number faible: 9 Mita Mesto Aon te cont obs Nurterofeqatons: 9 Bais: F= 3500 gf inl aon (egal! intl moles of HO pas nels of west) ‘psi er alana: 5 10,4, 0,.C,H,0H.C.1,00,H, C0, Spsiowons: (3 indepen) hp 1704 oF Ag, =2382 (or independent te sams Fin od oo. “The dees edo ae 20 Step “Te mtr balance ution, er introducing the known vals fe he viable a: HO: A =1709+ 0, + 0%, GAO: 050042332408, +05, CON: ea 26, +08, | CHICOM: Aron +0410, 4 8s (comin)Solutions Chapter 10 Solutions Chapter 277=0-0K, +008, © Hyp drmueonpur he eet ee i he a eamoonena si,-0, 10,020 on eskimo 08 | = 0.460 kg ole acting > Eee Se Se am : “ey ian | ora, sie em mm a Hon rm W605 sea se ba enoiPt GHCOM one no cs a | ‘Sip 6.No. Unknowns: A,B,D.E, no, ® | bisa aan “eo imo 3s ‘Step 7: Element balances: Si, H, P,O, «fo, fo} | 0, osm wor mya 5 | Sths tu 1 | | eto mf 377 gis cao 300 bg ed wake eee ia ou esses | ‘ —— eee | 1 potPH|2emolROy| 2emolP | IEP 5, q ema got Orel ian, Lamiti|2pen126,| Sp10 [1640 0 | Stemi ig moi, o; Team Toat: ERO, CE eons) |Tanai i, Benol AO] 12 8FO, 71.9, sac lhe ein stream aS Sia: BamwlSit pemasio| pots | 28 gs hemotsiiligmolSi0,|igmaisi'P#S! 849- - 2850 Bemolsi| igmotSio,| 2gmoi0 igmol8i,| p01 ‘gm Toss BESO, Jos 355+300888=71 B=235em01 Tro ser, tein eg gol, 2SgmoISiO| 2.1881, 1 5 90, igmoisin, 186 [2,8] [ete | cust) .cl, ——e c Hon ——>| asi 1 board Tac catenin}. 2. stem AY 3 aogmaca [a conte aa 2 Caremaining =279 221 2M01C 9 ssp motu Suovtal towne C.D. Bane CC. gone |sentante: —asebeet) comin toate _|Solutions Chapter 10 Solutions Chapter 10 Benoiduitiy Cy 2.219gmotCus BEBICUNTL) CL _IgmoiCe HgmolCu(NIh).Cl, 1464 gota BEACH 4 gmoicy TgiolCu(NH C1 cuBalanc: BgmelCuNH),CL| 2gnolCl __ Dgmolutit),C|__tgmotc molCucNe,).cr, malCu(NH,),Cl | CgeaINt On| 1 gmotn eases txt | jgmolCu(NH,),Cl; jgmolNH,OH -_ Damol Cunt) cl] _ Agron marca I Solon; Gown: A+B=F+DA+B=F+@8) 22194 B=0555+ GB) B=2219-0555= L664 g mol CuNHNCI: Gk D= 28+ 21.668) = 3.328 g mol CNH HCL ap+cm4p 66 gol NHLOH 35gNH,OH| 6.656901 pee EO CuNHICL | o 83 1 ee | &, Tam | unas 202.45 (ole (1.664 g mot) = BSSEBRCR NCH) | 10.102 | : rer] ae | a oon combustible. " Coie, | hexane Pome Breen Base Smt oamnietnde e sesctetnts LEE EO comenames | era ee sere fonsead+PCHl ton PCB “SO TPPCE went ed bets combaibis nest te sn iaesomponn | ‘Asad balance around te fo mixer: 16000(0.7)= (04) s F'=2,000 | ‘A total bulnce around the fend miner: P+ = P= = [ELOOOTE ane] wonton)CGE F150, THO, TTS HTD Ci #850, + 600, 7 Even wth tol combuston, we wil produce undesirable HCI which wil avery atfet the environment fit simpy vented Therefore, i would be wise condense {he HCI and HzO by cooling. Pere the sid sluon might be old bel pay | fete process o 21.62 moles PCB 1654%400, 1220%0, 199s moles aC, H0*? Ha=? catches (40%05 0%.) By ate component fr COs, we know 120142) +1395 (6) = 0.1684 P hence P= 6629 mo By an Oe: 0.40(2)A = 0.16542 6625) + 012200216629) +5 (1) (6629) sutsatman 0 46 taal Ryo 01872 From O te balance: A= 6065.4 mol of 40% Or sit (506547369. el Solutions Chapter 10 8 6639.0 21. 6PCBReated 24C1 fcan get HC by aCbaance: 2USPCBRERHE 2HCY 45 ont ctin product ‘We cn get HCI by a Clb ssf C sr" 0.0065, 10, fot 0; vo 0, 8) (6065.4) = 24252 mol O> Werknow %encess Op used is: Heres = Atco since we hve tot combason, (©; 944)= (0 consumed) = (Oz fo 02 out = 24262 - 01220629) = 16175 moles rit (2262-16175) _ : ‘ras, 0; = 109 (A2SZ=ISIES) reed]Selaions Chapter 10 3 Bass: 100 kg mo} syatiess pf Bumer — L-—b nue gas . ¥ ‘One compositions unknown, he legs. Afr selection of basi the at ow i aown ence this problem con be solved by direst dition and subeacton Unknowns: (COs Hy0,N2.03)=4 Balances: (C,H,0,N)=4 Gono. Sema ~Reacton reals Os HO Solutions Chapter co, 464130 HO 08143 N, 406s 676 st Tous 356.0 1000 a4 Fevoiget—Sef Le c+03-960; = }co; 64 — 64 0, 02 = 402) Steps: co 400 CO+120,9C0; 200 400 ie 508 HrH120r-%H0 254 508 Sr Ms 26 mm 26 X80; (040\452)= 18.08 1808 {erent ct mel, Pome N "16g moIN, in “Tot O2 in 6.28 Vol [21 mot O, ° [zim with 03 (63.28)7972 23805 Tous 46a 508 24065 181 en Unknowns: moles (n) COs, Op end No in P, and P Balances elements C,0,N Bquations: Za!

‘Aer sltn: Use etn of rection ad pci lanes Chale: 202=F | Arter une ede 8eCO:" C0130, "9C0" 20 eee ee | spovesatances to gt 6 an 2HTbalance: 2F = W, W = 404 } conn, sng eg | con g7=09 (8 & = 4 racing ole CO. LO=0¥ (0g, = LO mating oles [ajmamecomee) 2O balance: O48 = 12 W 202441, 5050202420244, | tau as, =8:7+1.0=9:7 mol and other compounds follow rae ec ms a mass fins ‘a o, “oc “OMe N;_079 nen 090 exited & 4 | 1.00 1.0 yo ‘pS Basi 100g mt P te al Bass 100 ol P ‘Stes snd 7 LUninows:F, A W all compasions known) (aieompos Uskoowms: FR, AW (continued)Solutions Chapter 10 es Banas: CH.O.iomt ‘Sic and 9: Balances in moles F090) 21010), 2 cc B02 ma rs990.008)+ 8019) + wo) From2N, From20, W~S2863 emo! Fromil, F=19698 kg Frominer, R= 8.1548 kg 19698006 _ 5, 2 $94 55 Onin: $3421 ‘Sten. 10 (Check via C: 19698 (090) /12= 1000.14 +7548 0.10912) ok Required Ox; 14.7+(5865/2)~ 17.63 kg mol Toul Oxin= 1023 02.62159 Excess 21.83 -1763y1763 = [LET W IY Alls soon sng extent of asin: 0,400, closco @) oo @) fyl3enig 08, G19 HORDE goon mesio-at A=1025 mol ihr 0210025)+215 aa ( Or 43=21s HEINE) EKE HEL Oaks CINIRO+E08) af =147 wa He 0 nj+€2)(290) ae S80mol ome ond ot —Solutions Chapter 10 Solutions Chapter 10 | Maso ts clement m+ ina +2 00)45+ 60(4)+20(6 5 omox S45 Mots 021 0, 38 oO i ® New te™ wuss. 16240 moi) cH, +20, +0, +21,0 02) 120, CH +350, +200, +3810 fy, = 9875 Less Oia eameet os Total mole= 144678 802189565)" a Teal (continued)ait co, 007 fa 40 01s Fai x, Toe ari Mon To8 Unknowns A,F.P,Xo,.%y, + Pick F= 100s basis ® Dae CH.0,N Gere retndes pis SarsidSsene ene ans Soc +1005 e)¢10015) =PoaTE) Ne t0(05)+094 ‘ m2 Wo@Ma)= 1090054 = F(012/ (etm wd) cm 9015 $+1m.09+A0) =F [aura] . orm =e ny SeveClr Hamer; P18 Solve N2.02 and Ex Sralaneously fA, Xo, 8 ay “ coi Solutions Chapter 10 ‘A= 1208 moles Xo, "00548 and xy, = 0.734 not needed) Caletion ofthe required Os Rewiced 0: CH,+20, +00, +280 70@) +140 6H +50,+C0, +4H,0 59) =25 coro, co, sd yan a present in F 0 To7Sread NO2I)~ 252.5403 in less 167Sreqd 03, #504380) sz0¢ 100)~|Solutions Chapter 10 oat F100) wi, ca cone “or oy gar feta aes to lags ome Sam Aono ‘imo ats ORs Step Bass: 100 01 F ‘Sten.6: Unknowns: P.x,9.2 Sp7: Balances C,H,0,N ok ‘tens amd: Air in is based on complet combustion 160+ 10, -+€0, aH, =20, -+€0,+28,0 04020675) = 827 ‘alo; 28048 ras Neinwithaie 2545 (2 ) = 10889 mot y Solutions Chapter 10 CO wik= 1554+ SES HSE ak H.O out= 1501+ 20.20) 2141 mat 3.948 + B54 1529-31 96-2 at T exncr,on 100 ae as a temo exo a en cy 26 38 icon i cotees Sup: Basis: 100 molP Step 6: Unknowns: FA, BW StepT: Balances C,0,H,N ok Siena and Vio alge 2Nbalnce: ALT9)= 852 A=10785 Chaance: FA)=50)+56 DHblane: _F)= 82) + WO) 123 (comtinves)Solutions Chapter 10 Settons Chapter 10 20 bale. FE) +2DA=BCE)+WOE) 395 ‘ewes DBE pcan 3 Dew Ose | Soluion: Bak mol | Sieos67.8and® F469 a0) W=402n01 Senn and gations sige sltion Atmlact| gat | 100m Pero BOM 555 eld | lent lanes nol [kg eels ml OT] ke ‘ees | comment Melia Moto | Aerts solution: Use etn of ation nd mis alines, bat tire é ‘00 Pen comple | 4 : 2 S00 +400 Soom 20 Yoo! 60074218, 040+ .N 98 (55-002 2H ‘00 w P= 8D) <9 | | ones | x seg 2B I, 9 Bod ~ Tia | Mos iho Me ‘Alera soon: Us exten of reaction ad species anes. l ‘Basis: 100 mols fat; same complete combustion Equations: (5,30, 00, +250, samsics,Now Stes Bass: P= 100 not SHEP Unies: FARW ] adcgacy anes one | sep? Bac: €H,0.%ath lance ot independent | Sicneands: —alltalanesin moles ance: MOM +i2-136 302) €CH,,O..Ny, +4 CHO+e C0, +F 15,0 Pex abass of skp of HOH (CHLO, MW = 4507) 1600 g HOH}! gol OH [4607 gEOH 100 ¢ 1 XOH produced Totelnce te chemical rctn equine leet aus, Tate x basitofa 1. Assume {ers conveion fhe gcse meas il |e of pcan paces OS ml ea a | cxeroie a core rues 3 mol of ioc © Gacsadee He Ta Stem tse ree ar © Grosetdraert No baode SpecifesoneO60—¢ _comtoaey Solutions Chapter 10 Reals sri (hetase) — d=06 Sco s ognal HOH) galGH.O, Ray 100g not BOI e mol G0, 125 mol NH, 08 gm0INH, [sam Base: F= 00 gen in Example 109 This bass gves P= 50 moles. Note: Ite pobem caleatons wes rane aise fie sted ado exc, he ase of P= 0 fron infin fas wos nt hang, ima coher alae he oes in Pal Change. Tote 9, * COs 0.154 (30)"7.7 Wa. Tae ae te perientcompaners er NO, we NO) fr prose te and MW ay Rhus BLY no; (oom === TD. Hs GE Eo } co: oormean =o 8 ase 027 ant | sos omen = 002 6 orm 009 oor co cosaee77) = 759 eh 064 eal a) ‘het mel foes (Netra i 150) (0.86) +0001 = 80.6Solutions Chapter 11 2 (The two overall balances on A and B sum up tothe overall balance on the sytem) 4 (sch 2s 2 component balers for ach uit) Unit involves AB, 3 2 4 Unit rvoves Dy E Unit voles A,B,C, D WA and Bare stays combined inthe same rt, then you have o reduc he independert Blanes by I fr Unit and I for Unit MU, atl of2 ns (Giiniepenat cqations Fal compontionsweiown] Thesum ofthe components (oles) would equal the tlw, hence atl of the gations ‘hat could be writen would be independent, oly 3 pe suber | soot tater: | Condens FL=Fy+Fs (Fydoes not mis ence canes outa abe oid) Ccoluon Solutions Chapter 11 Beboiler FaoFy+Fr (Fe does not mix, ence cancels ou oan be omits) ‘Somponen alness: In addition, eormponeat alnces ould be wes for ech component for each Leubeysem std above Mulipy Fy the composition ¥ Unknowns: steam Nows including F Mass acon (7 plus 3a F) Indepsodes mei lances: Species 2 3 ‘the ndepedent uations: ‘Do. ineach wre inching FSolutions Chapter 11 Solutions Chapter 11 8: my, = 20) | a (sinc Basi F= 100 kg m=mas fraction | (OB me = O8SP + Ee dee | MEE | eo [he eee "Bfo] | Jal eu t_ | 1.00 ‘Unknowns © indept. Fans. of fieedom = | Cohumn (1) balances . “ee puehi | orc: esse =wiy+nioan iemem oe egreeoffeedom a elonSeltions Chapter 11 Solutions Chapter 11 ‘ANALYSISOF OVERALL SYSTEM Sysom overall alsnces (A: 100(0.1) =P, 0)+P, (0.10) +20 0.002 mies @ B: 100030) =F (020) +P, 85) +20( ©) Ci 1009055) =F, (020)+P, 005) +20¢m2) [* BAP ees (0.002 + mt me Unknowns: RsP.mj.m> unknowns 4 40 deres of freedom a expected The resus show ta the system of equation i very sensitive to smal perarbatios in she cafikent(meneerement)Solutions Chapter 11 Solutions Chapter tt Basis: 1 he (1000 kg) aul: 1000-W + D 1 Overall balances: Salt 1000(0.0345)=0 + 0.0690 | ECT ET |. Saenaance o the renzo: 1000 (0.0385) oso — (B=7i8 75 ‘Total balance on the freezer | to00=A+8 (RHR) “ota blance srsnd iter: B=n875 +D (cez1e75ig) Basis: 220g IgG from he reactor wo. action recovered = “07 Fr ered = = oe) 1140 I ‘Sheps. 123. and4 This isa steady state proces with no reaction aking place All the ‘compositions ar known except for eam C. We can ick the overall system fist o get and then make balances he is (or second) units to gC and is composi. SlepS: Basis +290 equivalent wot second) SD Unknowns: A,B,C, DandE andthe composition of Slee: Balances: NaCI, HCI, H;S0u 1:0, net solid Overall balances (ke) | —— | “Two ofthe equation re ot indepengea HC and 380, | HCL: DyO420) +E 0018) 740-3.00=2.40 H,S0¢ 140.020) +E (0015)= 641 400=281, Ths, over he deges of feedom are 0 ‘Sto and | The solution ofthe equations isin ke) _ continuesSolutions Chapter 11 Solutions Chapter tt ‘Addtional Equations: oof, andoi,= a, (he elated equation for benzene are redundan), Total equation (Eto. (D=@0| ana E= a0] ‘rom whic [T= 150) vi ttl balance abou the Gratuit The solution i simplified i two balances are made fir (oot nese sep All materi aloes ar in mat Sods balance on Unit 2 and also Unit Notation: Subecints Benzene = bz, Xylene = xy, Solids = ‘We mas faction F'=igldweain, $= sls sear 2000(09)=F'(09) = 2000 2000(09)=F (09) F=2000 eae | ToL tatnceon Unit and ako Unie “ 2000+ '~2000+5' | si=st | 1000+ 2000 2500+! 100 ‘The ther balances are eae eos) 1000(t—1)= 200011) + 100118) oom on 200401) + 100, = 26000, + 1004, Step Basis |e ("= 2000 and S*= 1000) . 1.4100) + 200001") = 20001) 1001-8) a +206, = 20000) +00) 100-0 Unc fof SEP] Neen Uakaowas ees aia ano. S\F.8] Solve the eqtons gt compotion ofthe rem Unit: bays Maer Balowees ya: bangsSolutions Chapter 11 Component ‘Sra Conga we wr Br 10 e Br 09) xy 00 xy 01 Br 097 Be 0082 idan) Xy 0083 Xy 0018 s Br 082 F Be 0097 xy a8 Xy 0003, Xylene in Feed = 2000 0.1 = 200 ig Xylene in Produ = 1000 0.8 80g (eResven] - «100 ‘Bel 7 5 ‘Adsinal information: Py=3D5= 30 kg robs nn fp =-4mp Sten Base: F= 100 kgand Ds = 104g Begin wih overall lances. Unknowns: B,D, m9 Balances (3): A,B,C (pa total) Implicit equation (1: 2+ m2) = 10g Stand 2 vei tances aSolutions Chapter 11 Solutions Chapter 11 100 SBD; +1030 © 100(30)=0270, +073: +0 Solve these two equations o get, =30 and D; = 30 (Get mand from A balance and m+ 10($0) = 30,50) +30(.17)+ 10m +30(.70)30, m2 = 0.89 mii tmp=ts0 — mP'=01 Supio Note =Can check using the B balance (at independent) ‘alanst.on Unit No.3 A 8 c (y= 1; Py=30) Takrowns (Ew mls, mb Batnces 2): A,B Implicit uations (2). ml +m =30, m+ mf = 8 Otte equations: = Sm) Steps Rand Tosi30-+E=D5+?,=10+30=40 ‘One component balance: AA: 30m + 10m =10(89)+301,70)= 299) Be som + 10m = 10.11) +306 3) =101 | "PEE Em =m +m i p00 30(80)+ 10m $-=299 so tat mn =0.59 emf > SS Two subsystems ens, hence 4 componeat balances canbe write. No eseton eccurs andthe poeas is assumed be inthe steady st. Step ate omited here The balances ae Sisto: Soite Sistem Stok Chest Tout R=E+P Tok P+N=L Fiber: 2.36 xP (Rhee tre%103 26 (__Water 7452 = 416143291 _ Water: 3291 +18 3209 (coined)Solutions Chapter 11 Solutions Chapter 11 Pen =< focoenest | —— cunts | Soca ain eee | temintaase Water: 7452+ 18 = 4161 + 3309 | Sees Pe A eee eee ements M egmolgas — ligmolSic ‘gmol gas caeaea ; a (eS HEM gasp 0, | mol HSiCY, | ori RBH AbgwolHCl hg 01 pip! OLE ISI gmat irae eee a es, we 4 to soonsi a 0% 8c, an sicl 2ame ee {00681 Renae |] —°—fSeprcor}190 Egmolgas—[kgmolH.Sicy, | eg mol Sic, i, Sc, HSI i Dose | SieSiais 100k oc male 7 oni wo igiftg mas : : PO so gets Unknowns: _A,D.E. BalancesSolutions Chapter Solutions Chapter 11 ‘Akgmol HC] Tega mm oe SE gn Ee gmail mH) Tpmolem | kgm, 222g HSC igri}, 8 gmolHSiC ig molgs— [igmol HSI | een, Laie 35711D +E =Dt3E Oo E 742 1D ssp @ DO +356 -o3sp +0381 p D498 een 1032 13345 kpimal TSasig HSI gino HSICI, nus eka wel. ere HICH) StpS Bais: 100g mol =F Sepa 1.23.8 "t ho Ge a0 Asse frst an Duct sf Geen) Oa 0 ons, tirleak occurs and use materi Balances o calculate the amount. This a steady sate flow proces without reaction Overall stem Sep: Unknowns ares A, BW, PX (0F4,)s Key ) | seo: Balances are: GH.O.N, Ealot oe Lal =F)Salation Chapter 11 Seaton Chapter 1 ak ‘Solunen Mm ou kmoline tema Cogmey: 07000) ForoKTOOR Re te, ° AR Sc, 50K a the 190 E17 Negra: 070110094 + 02010012) +-01010046)= Wea) % 215 W190 kel %, : 1.0, i, m6 20 (hemo: 021A+021B $28.0 50.0088 i mod: O79A4 =m, Al ha 9+ 0.79 8 ms ‘From the overall 2N balance 0.79(982) + 0.79B = af, Oo 90+ 0068+ of - ‘Atalance about the face or sout he dt it sede, o those to alone would have bee stile, omiting the overalblce ‘Sustem:_ Doct Hen: Usa: AE, 8 hs S07 Ramen 40, Ne Bal 8 Stonand? Cékemot: 070100) +010400)0)~ Hh af, =O nol H (kg mot); 0.70(100\4) + 0.20 (100) (2) + 0.10100) (6) = nix, ho = 190 Okemo): 021A= +904 Nike: OA af 90+ 190+ af, +08, | | (0.036 mol H,018 mol sie 18. inlet water = 2036 mol H,O|18 molar 18.1 ‘oli lpmoi” {7 HO ie | Mami = (15.0 1b #0 + 11.7 Te HoOVS22 fa = [CTT OT a] © Thepounds of 0: produced | ‘By reaction (3), 0876) mo of T10SO, goes 0 TI (0876) 799) = [108] Tio; eo Solutions Chapter 1 nas Sem5: Basis: 100kg mol =F ieady ste low proces wihow'recfon, Overs |steoS: ——Unknownsare: A.B, WP, 25, (Ora ke, (Fea) Siea2 — Balueesare: §— GHLO.NE supe and ln “ tee mah; 0.70100)+ 0.10(000)2 - ho co" 90K el (omnes) | _]Solutions Chapter 11 T70 0Ha) + O30 TOOK +0.10 (10046) wa, Wo = 190Kg mot 20 (ego) 0214 +0218 00) 99,0067 2N (kg mol): 0.79A-+0.79B 90+ 006" + af, [Abalance about the furnace or sbout the duct ie ned or hese two alone woul! hive bee suc, omit the over balance Sse: Funaee (or Dut Stef; Unknowns: A, ay tho Sip I;Beloness: C,H,0.N, Zh Stepaand 9 Chg mod: 0.70(100)+ 010 (10092) ny, fy, 90 kg mol ‘H (kg mol): 0.70 (100%) + 0.20 (1002) + 0.10 (100)(6) = a, Ma = 204gmb: 0214 ah, sso 2N gms) 079A =a, 90+ 190406, 605, =E From the overall N> bales Op balance 222+ 0218= 008 m6 ons 079,982) +079B = of 021 982) +0.21B= 185 +0060 B 207 kg mol 90 + (0.794982) +0798 ~0.94P Po 1095 kg mol aTRgmalODREmeIr) Ieigan ir leak,Solutions Chapter 11 eee Bass: Dan gen sae (ir) ommin Gowna sl” ne | Atertgs 5880143 wo | Seapine |Solutions Chapter 12 m2 SienS. Basis: kg W Pickthe overall system ‘Stone 6 and Unknowns: FP Balances” A,B ‘Sieos and Toale=60+P )F=380K¢ 1: O40 -0+095P]P~ 320g Stone and? Unknowns: GR Balances. A, (or tua alterate) ‘StensSiand 2 Tet 380°R=0 Ya tog 3B: 0380) + 0) 0406) & 252 .Guptanngr ns Basis: 100g of resh feed (veal blanc round juntion 00+R=F KCI balance around mixing point 204 06R=04F=04(100+R) 20+06R=40+04R = [00g RIO ea) rl [> pew 5 100 3, 095 so (continued)Solutions Chapter 12 Teas Bas A= SOI) Select whole process as the system. Sens 6 and 7 Unknowns: B,D Balance. Total By, BS (ntl! independent) | Soman? | Total palence: $000" B-+D By balance $000 (0.75)= B(1) +6005) D=1316 Th B=3684 ‘Apparently th cleulated values are nt caret. (The vale for Ccan be obtained fom banees on Unit or}. as Basis: 1 bour ‘An overall bolance shows tht Ru fom the adsorber mas ql Ry tothe adsorber ia ‘eeady at exiss. Let = R, Adzorber balance of U (ants are U}: SOMLNITY , RwL|S2U _ GOO mL|OO8Y , Rm 93 Treat fer Solutions Chapter 12 ———— re | sts: Basis 1000kg=W =1 hour Steps! Revised compositions ae in mass factions Note: compositions iene! mus) = 0004s Foe | Wetceeal Exiair asc 1 0 cecal 2800, ms) of a8) ede $4 WO oss Fre ie Conversion of moe fractions to mas factions is no required, but since both nas factions and mo factions ae listed a dat, conver allo mas fraction (cant conver, cereal to mol) 0 avid confusion in making the balances, (cominved)Solutions Chapter 12 Tisha Bans mal FRiLa, Bas LO nol MW mas) mae mol MW mas maa sir 9868 29° "2861.7 OSS2O737 29-2137 O89 HO 1 18 2375 cos 028 18 47 10000 28BS a8 L000, 100 26:11 1000 ‘Acaterng dries bass LOO mol mol MO mass mask sir O83¢ 292709 “0958 HO 0066 18 “LI9 oouz 2827 1.000 Qverall balances (anknowns D, EF balances HO, cereal sit) =E+D ‘ota: canbe made inmass 1000+ areal (dn) 1000(080) + FO) = E@)+D(O9%) De srkg Ho 1000020) + F (0.0082)=E (0.181) + D (0.050) ar 43000(0) + F(0.992) =ECO8I9}+D(0) ‘are naependent eqns. check by &* eqn stole Balmcson ing mit inst) | tea RaF tr OED) Fass2)=0,0950 Ho, Rois) Fone) toa8) f 2 equations are independent, check via 34 equation h 2 Sia L.2.2and sain va_o Sets 10 ens na (ssi) So os st a 198 Boy | ‘Step S; Bass 1 r= 1.000 kg KNOs solution Compute the weigh action composition of R. On the basis of I kg of wate, the saturated recyele seam contains (10 kg of HzO +06 kg of KNOs)= 1 6 total The reeyele steam composition is QGEEKNO! EHO gap, 1g sotto 1g H,0 [6 ig solution ~ 0775 #8 KNOs/ 0h 0" 37.5% KNO) and 62.5% H0 (which hs been added to the figure). (Continued) —___|Solutions Chapter 12 Analysis of complete process (6 streams) Unknowns: W.M.C.R, Mo thao, Belences; (2 units + 1 mix pont) 2 components (Other compositions are (in %) M E w #0 50 % KNO} 50 2 ° StensGandT: Unknowns: W,C, | lances: 2 components Overall bance tocaleuateC, Tota: ogo swe. KNO,, 10,00(020) =W)+€(096) 10,000 loan UgeYSEI8 _sogsyg/ teense C Tr | tkgF [0 96kgKNO, = 10.000 -2083 = 7917 kg “Todeermine te reeele steam R, we need to make a balance that involves the stream R Ether (2) a tlance around the evaporator or (9). balance around the eystalize wil do ‘The laters easier since oly tee ater than four (urknown) seams ae involved Toul Solutions Chapter 12 M=28+R = @ (Component (KNO» balance on erste Moy = Coc + Ro 05M =0596C + (0375) Solving equations @ and © we bain 05 2083 + R)=0375R +2000 Steps: Basis: 1000 bse water Unknowns: B.D Balances salt, water Steosand 9 (Overall mas balance: B += 1000 Ove st balance: 00525B + 50% 104 / (coninves)Solutions Chapter 12 Balances” salt water Mass balance sround the justin; 1000+ R= W ® where R = brine recycle; W = tot soln entering the cll Sa balance ound tention: 31400825 R=004w From(1)8.@) [ESSER 8 From (3). & R= 0 be 551 Tos 586 By Basis: Ihe =1L=F all concentations are g/L "x 100 Figure P19 Pick the overall process asthe system Balances: 3 H,0,2a,Ni (ain) sutbant? zm 1ooqnso = PEIPHOE sr aso grt) Ne mp4 =DK.00+%a70 SolvetogetPo=0S25L = 1.056 Pick Unit 3a the system Siens Gand 7. Balances) 3 HO, 2,Ni Unknowns: 3 W. Ra, Ps Sten S and: Za: Ps (3.50) +0=0.10(1 056) + Rss (435) Ni Pr@19)+0= 1.001.056) +R (2.36) Solve to get, (alin 7Solutions Chapter 12 D0 gavaay mast oil+die 0229 40 om F000 oil dito HO) on alain 0329 HO om 1000) F oil die 00073 H,0 0.9927 3000 gatiay 7000 Pick the total pooes the system Step: Basis 1 day (equivalent D = 90 gal, F 3000 gl, P=2910 gal) ‘Sten 6nd 7 Unknowns! Gh, Bho Balances: il +i, HO ups 8nd In ow Overall ol + dit balance: _3,000(0.0073)=2,910(a,)+90(0228) Solutions Chapter 12 2 “To soive for, make balances onthe mixing point the fier andthe spite. Not all of the balances are independent 0229 =0.225(90)+0225(8) 08,0 = 2910.43 104+ 140229) Mixina point 3000+ R= (0.0073 (3000) + 02298 = WG Balances: 6 (independent) Stns Rand 2: Thesolationis (REST galy)Selutions Chapter 12 nan Start withthe overall system olf asf ce 095 oom H,0 005 o9sa7 = Paw) mo |» Rice Produ bral) Fab) Wabmod olf. 44: Inthe diagram ute mol and mass percent for ‘compositions and mol and mass for ow specified SoS Bais. = P= 1001 suns Unknown: FS, W ‘Step 7 Canmake total and 3 component balances rice, Hs0, dry ea (G) Stensands, Ib Rice F0.75)=P (095) =100(095) Tomol —Drygas—$(09527)= W (09068) | homer ns «£10299 9931), 2009) [ipmottio 8 00475) + O29 -w(o 8 AOS Solutions Chapter 12 F= 1266716 #2735 fmol W= 2875 te mot R . sel doer ‘Make tlances.on the mixing point eae " Tomo ans (273509527) + 8 (09089)= Fix, pmol HO: 2739)00473)+R (0.0831) =Fixtie Tmo oa: 2135+R=F, Nhe tho R=3.12lhmol/ 10016? 0.0931 H,0 3078 tome R ea 00931 H,0 Ho: R (0.0931) #30768 (00831), total (0) (caly independent exuation) 0.0473 5+0.0881 R=F, (0052) 2735+R=F) (continued)‘Solutions Chapter 12 ee \ ops 1 ee ? cPa001g/L. Aqueous Phose >} Fy 10 Limin = 10 Limin ch= 1008. C-o1nt Fermentation prodact blanc: rnd] gy Abia er 1000 Fe 9.900 ri Solutions Chapter 12 1oLnin Fetou 1 Far wounin TT ch = 1008 eP=o1ch cP _o1cd Femenstion balance Assuming F 10 Ma cr s0Yeqe io, HOFia. o3 101, | sotving (1), 2) and 3) Simultaneously ctai00% cfu10%f Pfam Pon C10 int Gta ct Exo1c _ E,acra cfa0i5f (contived)\ Solutions Chapter 12 | Fermentation rodut Balance: 123 | Frect-10 |sim2.tank (00 82isso tomer) | ms etsg80 ~ rat beens ae 2192898 or) Ch=t05g/L cf ‘This one ithe least | | 10g/L = ——— | Seu. | comosstions a? 0, 215889, vor0 ee) (comin $$” ?Solutions Chapter 12 Unknowns: P, Sm (4) Balances: Bz, $03,n0n Bz, minty eos Band? Balances are in kg ‘Tal 3000+ 1000= P+ w Be 1000(0.70)= P(t) Non Bz: 1000 (0.30) P(Q)+ mt 0° 200k 18), 8 rs 18), ax, mig 300(025)-75 ep iad | Solution >= [ta] Suen: Unit 8 pyaim) Tinks Unknowns: mf, mam, ‘lens .and9: Balances we inks |e Bet nonbe B= A375 r= 1000 +375 ‘Sustem_ Unit? B W0dkg 8 (0.01)c50\=¥Ahyasl @ L—s D-F cu C'Chy Be+-83) _ (connedSolutions Chapter 12 Sten Gand 7 Steps 8.and 9: Balances are inka | e+ monte: © = 100g 13 © can9+37s ~ 1000 375k Singl pas conversion inf « tk Single puss convesion based on Hs athe ining reactant ‘Use Bg (12.1) and Ea. 12.2 with Hs the limiting reactant Solutions Chapter 12 80 24098 1989 © Oveal conversion of Hs ett | wn Te Ett tims smo ne | igs a se | || ss Bois: P= Pick the overall proces asthe system Sea Unknowns aly, Sep Balances: 61,0 Stes Band Element balancesSolutions Chapter 12 $$, Clos nga 4452 H(a0): Myp@)482) Op Sea1O —O(AP, gpl) Fg (N)=A8O)+4 checktsok Composition of fesh fed URS Oand Alternate solution, Use extent of reaction Bosedon Ov ¢ Then niyede gad nyo Or §=a8 “Toge the ecyele, make «balance about the senator (0 reaton ecu) H, balance mel) 14003) = 48) 11600 mol Tot nat 100+ | Re1S00 mel 100m TH m6 Steps 23.and4 MW Ca(Ae)=1581 MWHAc= 60 Yo Hg CA) tg DCAD, 435 ol CA, TSR. hg Cacao, StenS: Basis: 1000kg of CA) feed Solutions Chapter 12 Re Calhele + HaSdp ——> Cason + 2Hhe Inspection af the diagram shows that the oveal conversion of Ca(Ae) i 100% (one leave the process). Thus, fo, 1. Youre piven f= 0.90, Then 5 OF mal The single pas conversion for {ACs i 090. 1 Over HAC blanc: 633 kg mol Ca(ADh| ZKEMOIHAC 1966 bg mol HAC oF Tg mol CalAs), MW CathB = 345 MW Zn=6537Solutions Chapter 12 7 a nS Bais thr +000 0, (2504 |e ance Pee OF 07 2850=1)(5) ¢ 2.890 reacting moles blot, = 0 (142890) 2.890 kg 2890 260 2a, ble: Ray, * 0 22890) Aten solution 0 es CHD kp mel GHB, 2648, a5) Teg CH emt, Reeve “Make bolance on the mixine soit First zetthe feed of CHB othe reactor CBB blancs: 2890+ S61 R=072kpmol 0.72 (46)= (27m) ‘Altemute solution (inks), Balance over separator (4000 kg +R) (020) = R=250kg Solutions Chapter 12 1000 H,B4 | 8g leezbatrnte. rang | P| SORE H [Fa HBr egal Zn Za egred” 22] 4. Molerato of 2B Casini pradus 21 4 per tection) Fs ssc ae Get, it Sens Basis: 100g Fi =r | ral | Sensiand? Unknowns: FPP | lemen laces Cs Na, C1, COs (nag, ntalindependent) 0, taleoe ] 2EbECACo,|t Re mLCACO, THEO, 965 emai co, TOOKGCICO, [Tigmcace, ~ 28 consmues) _}Solutions Chapter 12 Tig al CO, —_ 094g moO, 706 Kg NCO, [Tg mal e,CO, 2.94 kg mat CO, otk moto ke mIN 60,1660, ET 1kg0O, — |T kgmol Na,CO, creo balance a tor pu 1 (om (2 +E [vets samo tte nee Steps 12,3, and 4 001 Nas #5 ia SA Took | Mol. We: Nass, 78; C200, 100; Nas COs, 106; C35, 72 Seas Bae Tir Sips 6.7.8. and ct mA) Na Balance | mts (voDy nas isl 2h Ib NaS [I Tb mot NaS [TbmotNa,CO,| S018 Ne,C0, bees ‘Sytem: Reaciorpiu sensor (System B ical aun Consumption accum Tas tan 104045) | R]_R, 5-10 (veo) Le (10009045) + "NaS i the imtng reactant (LR). Mole NaS = (045) 1000)78= 577. allofit ope (IKE (continued)Solutions Chapter 12 [Overall frsction conversion of NaxS is 100%, fox = 1 | fe - 08, as Ton ap eae aT si9+0sR=577 [EOS] (r50 1) — R n20 A basis of |r requires the listing and solution of many simultaneous equations A bass of 100 mol of toluene in is more convenient Myots Gs Recycle Prue oa ae a {= “et a, Basis: 100 mol toluene instream G (gross fed) ‘Sustem: Reaso lus separator | Species bale Ow om, (ten m0 om -100(80+08) #0 Gm wow gto swenenosen)) -0 CCH 194) =n, L440 -0} Solve above for System : Mixer lus mau point ® ®@ @ ® © (yTowene: F$ 0 + OH OR: 0 + = 400 o 400 Jone 0 + Solve (3) for Ra = 434 mol Solve(1)forF=88 mol M=366 Change basis ot hourSolations Chapter 12 3430 1b|L Te m0 = 35 515 mot of toluene in F 30 5.1 mol Ror Heoladno aster lama, wibmolF | thr — [iG0lbmolvolinG [325] 4341 mol Re 135 mol Rye 100 fo mot olin 375p mat oftoloene is elected as the bass, you have to make the same balances a above plus benzene and diphenyl balanes onthe eater plus separator because F isa known but Gbesomes an unknown, ‘The unknowns would be CRU RoD.BM ath, crate ion Cate the extent of reaction fr cach ection and se hema shown in the book to gt the outputs of the reacioe plus Separnoe system instead OF sing generation and consomption ems. Solutions Chapter 12 FL Fe Fe Sn Mena» ME seins Balances: MiiogPoit: GACH, | Rector HCH} | ® Avis: CHACHA) Use oer balances a subsite for some ofthe above ‘Qexzl balances (clement balances bacon ofthe ection) ®@®@ © FO)=FO) Fy =50 kg mol HF =FQ+F,6) 50) « 2F, +506) } acne ® e Gil: Foe F(OReal, «504088, FOO) #02), (continued)Setuons Chapter 2 lation | b 04 Gonctst ‘uomnet Cth aka, = -FyORD) +0 oanty, =o (rome (008F.-080F- 04150408, Regcle Fy=S8T8kgmol aly #25+50= 125 ka GH: aby + a(20)-504 DU OFORED 0 =o ma, = 175g | Dates FF Fs =$0 49875014825 nol (eter sy) lg, 0.2,F, = 1875p mo Fy 1875+ 125 143.75 kg mo } Omit balance (Use CH, ) GH =F, =S0kgmol Hy nfy= Fy = SOkgmol | tou Fak +F, +F,= 504509375 =193 75kgiol jy, = 198 75-100 93.75 =F, (akg mo Solutions Chapter 12, F=30——F. @ |F=137s F=s0 ROT AT) Fy=19375 Fe 9375 Alternate solution using extent of reaction | fyroae DE lg" 125g mol Also = C285) -1875 gmat srsei2s-10975 ‘Similar caleulations to these wil yield the same results asin the original solution, nn Tins steady state process with reaction and recyele. Pick the overal processas the system Basis 100 kg mol Ce (cominus)Solutions Chapter 12 TTT ‘Steps 1.2.3.and4: The system is as shown inthe diagram with eeyete ade, | om 09 TOURS Gl R Clealate the moles of ech component entering CH, (@)+20, (@)-+C0,(8)+2H,0%@) Caleuation o te equies Oy and accompanying Na in moles reqdO; — 100@)=200 s 2001015) = 30 Tol 02 20 we olS)- | ‘The exit concentrations (via stoichiometry) ate Po co, o Ho. NO N 119524 Next, consider adding reeyele as shown in he diagram, Recyete i not involved in the ‘over balance, hence the concentration of NO wil tbe aflectedbecase the exten of reaction with and without reycle remains the same. The recycle does reduce the ombuston temperature which in tum wil redue the ext concentaion of NO. nas “This in a steady ne prom with ation and esc Sten, Basis: 100 mol F ‘Steps L.2.3 and Make the overall balances Ussatinan He spa crate a 109 _ Fema) a) Piel) $0} 00510) = 030 Sons or 30 Etael p Grcall) Pino) OF 348) 43 Oo NP 810 : aio A850 3 Tor] ‘Siep6: The unknowns are the exit compositions plus the extent of reaction fit ‘Sto be use, ‘Stent 7.8.and 9: We hve 3 element balances plu the faction conversion ofthe $030 0, 04 species balances ($03, $03, Nz.03). We ean use a mixture of element aed cies balances, (coninvedSolutions Chapter 12 Solutions Chapter 12 Tamed male] Element S: 10 =0.95(10) + 0.05 (10) ‘check is ok SO, 80: 950 0.100 | ie |. so, 25 $0: 050 o0nss cement bg 0, 525 0; 425 cous | | select ni as he system N, 8100 N: 8100 ass | | R 7 i , J Syten ‘same composition as P nal salah. mal iat 75 kes pci tlae on $02 50, 100 fae me Mak species lance 0 0, ied a 07s . $328 N; 810 o Or b Qu Consumption Gsneration : N10 sl (25+ R(G25)- (050+R(000525), +0 425+ Re00s259065~0 075 | sow ete 8:75 | Sm 80, : 25 lon 3 om 1 Steady ste roe with eaton Bement 20: 90+ 10 5(75)+25+ mp,21125425+ ny, 5 L2aandé Getheamountf (eq exes) NOs in f nan 528 | 2 Suns. Bass thr : lesz rund conser? lu spar. Note we nesd = P'+Randobsee tthe Conporton oH Pan Ri tee {stig GheerndVigmalGy 10 6¢gne | "92.11kgGiy “1° 86K8 molly | Seed. Gheoine C1H,0,43HN0, -161,0,0N0,) 38,0 Requred: HNO, #31085) ~258hgmol (continues)Solutions Chapter 12 Solutions Chapter 12 f TOS mol Gye wa wv HNO. is 32 $6(20)= 6516 () Mol HNO,rega = 8Smole GhePamal HINO, tlhe Tota: 39.10 kg mol in G = 32.58 mol " Sten and? som is overall ‘Actus HNO, Reqd = 1 200(32.58)=39.10 mol | Unknown ae F. Pm and mis HNO, ink 3910-3258 ~652 mol Equation ate C, HS, 0,N = 652(6301)=411 ke (oryou can use stoichiometry and make species balances, o use the extent HNO, i87000%R, 0.7000R =411 of reaction) | 9650 P '= 11.25 kg mol or 11.25 (227.09) INO, in @= 39.10 mol = 2464 kg HNO, in R=411 kg FHR=6 HNO, Balance) F+411=2464 F-20531 HINO, Unknowns: F is 43.00% HNO, so that 4300 F «2083 © Balances: HSO,.H.0, HNO, ard my. Myo, +3919-G © HS0, inF 0.5000 (4778) =2387 kg 000 = H180, in (a) Glycerine Fe -=10.86 kg mol @a a) x a H0ink = 0.0700 (4774) = 334 kg 1086 kg Nitoglyoerine Produced HO Generated by reaction = 1086 Mole Glye x3 0.9650 P= 2465 = (10.88) 3)(18.02)= 587 kg, 10 inseam P 00350 2555) — [0 iow= Solutions Chapter 12 | Somes H0, Ho rr asss a ‘0000 Sram WOT Ar HO, = 715% Ho zis] seo Do numbers check? Ghent = RaW toot Bese m29 ome ome Solutions Chapter 12 2b wee a omen | Cenc Rec Dae, + conan (efomersit ay © 20040,-»200, (CO comer C0443,» 08-110 toxtaniney | CH, feed is 1% Nz or 1 kg mol No | se sn) 29kgmol Ch, (248AHL) ignolam 11099) =21784g osm |Solutions Chapter 12 Tasis TOO Ks mal CH, fed SteosGand?. Unknowns 6-002 makeup Tosreactor product Svoformer product 731 HYCO: Methanol slain 4-02 fed, stoichiometric Breeyee, HC | eondenser ops 5-00 conv. products Sirectr fod, HICOP3—13-purge, 5% Reformer balance Condenser bilince COcon. balance purgerecycle balance (C02 makeup bance Feedlecyle balance | Methanol reetor balance Steps and 9; Solve balances serially. Reformer balance gives steam 3 co, = S2HERO!CH, conv 0 9convty al] IkgmolCO, = 892hgmol (CO= 950.1) 994g mol CO Ho reateg = 2EBLH.O}89.1kgmalCO, Ores = Tem CO, Hamel? tam eget k,0 A 178. 188.1=29.7kg mol H Hy= 40891) +309) =386.1 gm Hy = 1kgmol CO conv balance gives streams 4.8 5 Steam 4 o,- BBSRC. ato, TigmoicO CO, =89.1 + 99= 9g mal CO, HO =29.7kg mol LO y= 386.1 kg mol Hy Nz =1 kgimot Np ‘C0: makcup ives reams 6.and 7. ‘sream Tis 3:1 HYCO, 28.7 kg mol CO; needed 1287.99 continued)Solutions Chapter 12, Solutions Chapter 12 ‘Nrisnen paces Seam 11 | : LOLS stage | sera Tea gman = DHBMeL eave 10-2974 12398 153.65 kg mol HO | Siren 13 (CHOH = 12395 kg mot CHLOH ro ra. of COs instream 13 ‘mass steam 11 = 15365 (18)+ 123.9532) HyCO» Let 00543061 123.9532) we cron = 238562) cron ~ 23556 4x=095, «©0275, Mathano rector balance fn 55% conversion Na 1 kg mol Nz From special balance, ach pas ses 123.95 kg mol CO; 55 (COshn 50 (CO z= 20 8)(02375) . : na Steam 8 seam 9- steam 7 €0,~20(02375)=45kg ml COs Seas blins sss LL Sua 8:CO;=22536- 1287 so nl. 9566 : "8705 9 pe TBS barge 78 - | 3078 sho L__ p> 1m | 1226 ton By inspection yo can sett the ow of Is nH in the separator ig te wong ence elton mak no soe 1 non oc (CO; reacted = 128.7- 4.75 = 123.95 kg mot CO, reacted mat x on co emai lo purge seam exits out ofthe spurt otha CO wil bud up. Hyremted ©3861 1425 371.85 ig mol Hy rected _ nas CCHOH produced = 12395 kg mol HOH No. they all contain AN andor NH (continued) H0 produced ~ 123.95 kg me! H:0.Solutions Chapter 12 "Tie batom steam fom the dation column and We wasiewaie seam Fam | the condenser are candidates, The botoms stream from the dilation column ‘contains ao NH ad has the highest mass facton of AN of any wast steam 30 ‘hat theetie stream could be fd othe serbber The chang in th scrubber eed vl not aFet any ofthe steam flows or compositions upstream of the serbber that reconnected wo the srubber, namely those associated with he reactor and the subsoquent condenser, nor any downstream flow nt connected to the seruboer, A Sequel set of material balances canbe used o get the flows and eoncertations in theres ofthe process. Basis 1 second ‘The wate flow rates wil not change except forthe seam going to eatment, which wl be (10.1-0.7)=94 kas Ie AN clues he steams can be determine tom the following Lette the kg of AN entering or leaving a particular unit Scrubber balance Sane =A 1580078) isan column pls to condenser ous steam jet lus produ siream balance Distribution of AN emerig the dsilation column She 01 2 Solaions Chapter 12 ee | One of hse elation is redundant wth he tiation column balance. ‘The soltion ofthese equation is inh (nae the changes are quite smal, hence | tne mamber of significant figures is exaggened}. ebay 4302 ehyy 0102 xhe= Xft 0205 xf, «3.995 Because the changes are so small, the NH concentration changes ae negligible,Solutions Chapter 13 Solutions Chapter 13 ae "ect -nae p= L5SK0420000) 560594 bmn) | ‘@anyrosysss) “0008 bs |e ,0=(aosae4) = [paw] | 1a Basis: 1 L gas at 780mm Hg and T 2Spsa i 460+70~ 530°R 60 +90" 550°R tmospheve pressure = 2092, Hg st atm = 147 pia 20 rig 14.7 pis29 92m 7 = a 13.4 Specific volume: MW = moksol weight ria He = XD _ mW (154830897) (+460) ce) presse =2992in ig + i tO [2092 Hg Tin HO}s3.91 01,0 | RHO sem, (continues) |Solutions Chapter 13 =2992+029=2021 in Hg Bass: 1 RY of oxygen t 70°F and200 pig in vume = 20084 S80°R| 437m Sore POE = [SORT aa in 150 gaa) | oma te sme aetna be made wing Tow CO, agen aL Sc Seton We can wre ie subscit | stands for standard conditions, 2 forte condtions ‘nth tk) | Solutions Chapter 13 Araidiow cos nel coy 30 BO 45 1 Tarnco: hi nalaot fe ea vce pon wl el oan a ites ee prs al te aw ois 67 pay e66- Ie? GLa Asse puz0~ 624 I par = 1.696 pia MLM LA, 414.696 pia =231.387psin R91 80 pV=aRT eB ggitite past in! | cunen a 10001. [8.314 (KPAX)Solutions Chapter 13, Be ‘You mus first convert he temperatures and petsres nt absolute ui desman | fon pene = 2999. H+ HOOT HO 999 +029 = 30.28 in. He sacle “The smplest way to proceed, now thatthe data are in good ocr, 0 apply the eal gas | tne. Take as asi 1601 not forget nlc he el af fk oe | system) of 0, a1 75°F and 3028 in Hy Determine the inal pressure othe Oy ask | sone | oD emasne[ S18 20) ayn ese In guge pressure, | (480-29 9) Ms [16m ara asain ig “EELS Solations Chapter 13, ia ] Basis: Data inthe diagram Sate 1 i before coring; state 2 i after equim i reached a fling. Assue pq = 21 =2992in, Hgabs. pra Pa + Pygh = 2992 +h where pa isin inches He ‘Use the idea gas lew: pz Vea = priVz1 23" 29.92 (86) ~3989 in. Hg B289-299+h of h=95Tin He oor Anamaot 48 1 | ~ srs of manometer L 6 PATS p= M0 p= 760 Ve i PISTS-T48=Tomle Le TBH (I) [mat40 736-4 __b=736+%2 (2) _7Abi=4AR2 oni) |Solutions Chaper 13, p= 700-(L-h) Thm 6) Gamp=74 Solving @)and (4: by 16 mm L.= 764mm HAN) =[160-(L MDLCAD AD) (3) Subang valves of hy, Lin (3), on bins: hy=18mm ‘The eight of trometer = Lh mua Basi: Sat atmandT Assume Ti constant thoughout the dive Ate endothe dive the presureis p= ph orcas let x= depth in “The presture for IL isabined fom Bp; Poh (#) = ata FE) =m 4 neces iia] Solutions Chapter 13, Bass: ir a 30 ps and 75° in volume of tre Final Saie pra. pia ne? Tea8R Tre cumbeofimot ate same 502-147-385 pia Basis he ava = Haapanguson A aq lazing Low QS) me pus (continued)Solutions Chapter 13, Rea AosOF ie] a a, n= none g|etsonoF a att ezine” OS TRIS Basis: Flue gas at 180°F, constant pest, and given volume 1. Calculate the inlet rose sectonl are | Asam eaeyenasrA |2 Cabal the ike votumene ow te Q (> (esp osetnl es) = 251257) —D1416 6 | 3 Calais the ott volumetric Now te king the ideal a aw = @,c477)=314168460+ S460 + 1800)= 140400 | 4. Caeulte the oe croe-sectina ares = QU, = Madane= 702 5. Calealae the oe duet diame: (0, = aay 4a) | , = (47.2ya = A Solutions Chapter 13, Buss: 1OkgFes (MW=879) | FeS+2HCI + HS FeCl, Miah EMTS os eit ‘Asumepressre most ely is gage. Absolute pessue= 15.71 + 760 =91.71 emg. m2 kre a7 | Apply PY =nRT twice or use i once with R | 7302X560) 134 (0) 10° (0) a1. | (2 SF ase") an aS) Basis 1 pound mole fe Enea) 3908 fr om [RIL Sem L Tibial Stun (bmi)Solutions Chapter 13, Solutions Chapter 13 Apply pV=aRT to gettte volume of VC a SC and then se the mole ation Bass: 1 hr = $00 waste (W) lnformtion get the volume of i (the ado of VC ir as negligible eft on the | ohne) Get pal at SC 1 pgm = 0.0019; ignore HC iting W ” Mw ve=78 | sem wf glo] ae __nvcRT _ 0.0101 ig VeIt ig mot Vo31S (PaY0"| 298K som w lass |_____- = Sa210'gCn'sc We eee (at T EW (a27,000 RSC u | ° T8kgVC | CepmolXk) [V013 KPa The nro volume of oe gis |-01x10%m vease | Veta faction the same a ok ton bere. . eel f'SC___| 1p [10 e|25 mL _ Fearatec) | eo} VE at $C 10% oa? ni SSD EAC poe | Pabst weal 2 — SOLE st et | | TaVe 06510) inin on aise If bod is se ap |_1e (237.000 | aL at 7 | =f Timi ster amount fs. | esis inconvenience the dncharge concentration rom th hod vet may Be | anaoseubl. a T=28¢ _ YE=1ROM 101.34eee ; : Solutions Chapter 13, 1320 Basis 100 ppm of TCE (MW 1315) nie p= 2M where WV isthe average MW. AL 100 ppm, ROW = o0«10*)031.5) ~100«10*}29)=20.013 (ie Say eset same a ta ofa] wat Base | in T=(68+ 460) 18- 293K MW benzene 78.11 sige! Psy =03879glom? pV kr R= 008206 (LotmyigmoIKK) 25. He0879 Be eft got Br _ 59g Amol nin Tem W811 gB 78" ain 20281 groans Yom] _ 200% L v= 2G sot | 293K. ogg ‘nin ‘G@moiXk) [G40760)am is | To dite 10 pr, multiply by 106 or we [S420 Limin](698 m* ino (2300 ni Solutions Chapter 13, na | Dh: aig °F an tm. 60 a a (ame 1p. Ty = 20K, T= AR tm? [s20R [anor 1.106? | Since the mols and mass ae directly proportional o vue at constant rssie, % Basis: COs in yin Volume of einer ‘Assume 100% CO; noylinder at °C | 191 nfs26peialssore | ova ne mal OER 11350) w 7p 07 al 1A ssa 147 a 01 18 gas a 7p ‘You have mare than enough CO; filth ching operates under atmosphere Ie the machine sa 4 gl capacity | pressure. __— J)Sotetions Chapter 13, Solutions Chapter 13, ne [ ) nas oo HE © | o | | | | | | ais 1g mot gs 2200 kPa and 40°C arp 3902 Van eee 228 fora ai) Rosary Tower 1013 10°Ni 2.4m? Mw =44 epg mol = 2004 0132 10° 224@| 1) | kgot © TEEROT TTT} Dassiy=patwone aT oni a “Ear aoe er a (ie Ga Foe Fe wl iamonXe) (©) Sposite gravy here ie ssumed tobe density of propane at SCidensiy of Lam| 3908 _ Er fe seasc | o LBS rsoa Fam oo ma Pease Mien Sm RT [Pa Me 29 RT, 1am 22.40 or? © aed tpt Bass: 18° O; a 100°, 740 mm Hig __c40yta7Kt) = 0.01238 met | aytoaysrRy ~ 0028 Pot | Densiy a 100°, 740m | (00023832) _ [0.0761 vit] jena Lo‘Solutions Chapter 13, Solutions Chapter 13 - vo. of mols of = —_ S08 | Basis: Hy aan 1104 1796 Keema lars | | | ee er | Terai jo zt [beget os | Tikg mot Ha] 29 kg air kg mol ” } — 7 density of gas at 9°C and 600kP=: sas ‘Specie gavity= density of gas at SC | | Basis: 10 kg mol gas, a os) ed Mal Mw ke xt | ro “a ‘44 235 ee | | Tout io ie Tone |) compostion in vol. perce = mol percent [i55 omen a 7G Os or ce 81% Cally 12% | Calls 1% TT fo) MWofgas= 29K _ 17 og HE ae 100 kg mot = SF mai | | J R=8314 (PANO Vg me)Solutions Ch 120 asi: 100 mol mixure Sone Mal Mot wt Ae * » Be a. 198 100 © meusc~ 22 2020 pe. = 2920 _ gr pg = OS - Oi 203] a92)/0147) (G59) |(60)) 04.1) ‘Gm | 2 | 0 (639)| 520 | 3993 | mene Ave Mot w= M30 figs 100 ~P2? tym er 13 2870 woe oon = 100.00 Solutions Chapter 13 Pc, 2008) = iGO Basis Gag at 30 pig and 20°C Assume the barometepressre~ 147 pia 17 +300 447 pia 447 00) ai paar Basis ter final vole Assumptions |) Tempenur is constant (2) deal yas aw apie (60 + 760)= 1.520 mem Hg Pr=Po, +PSolutions Chapter 13, Solutions Chapter 13, | aes fom, calculate | 02040)= 18 emg Fe a e below | | Je, co “35 | PoP, 060140) = 44 © too CH T00x Rl ass i # yoo aie ]A 0 021 a Pas" 0.20740) 1 a | 300 aa Me, $23, i+ 3205 > 00+ 2H AL4OSC the presareis GF F0, 5 CO; THO Ome. 0 sy Sten4: Unknowns: Pad al he compositions o (5 enknowns) bak Step 5 Balances: C.HLOLN + fet that 30% 0F + C0 (02%, “Reo, * 02047905) [ET HT] | |Sieré Rese 100m (oh “Ro, "06090 = [STC] — | (Po), = Pa, ~ (0.200790 5)» FSET ma ‘Chalance: 100 mol in CO = 30 wo CO, = 79 mol} ou = — = — 100 wal | q q 1 | AN balance: Regd Or: 200 mot | XS 0p 020(0)¢ a | Tota in 240 mol (comtinved)Poo= Pico Solutions Chapter 13, atumate X50; +O; mad fr C0 = 4032» 55 wt sow a) Solutions Chapter 13 ‘SiS: Bais: Gas ted inthe figure Stee 6 and: ‘Unknowns p (Goal, V (fn: Equations: ideal ps laws Sps.and 2 BM 9, BM gy BML err, (Goo yom) , (S0KPaKO Sa) pePa\.Oe) (er 366ur]Sotutions Chapter 13 = 7 areas | i ‘ Sion Bs: 1008 100 sind 6 a ‘ Seman p.=55+ 147667908 Sion Boss: 1008 Ns 100 ig and 6 fa os | Sens: Bas: Gas wt given da Ena Moles | Loom 14. p21 wet 2: Valmont (40050450 8 | won eo senssant ToT Tam) (V,=400450= 4508") "pin Sor e5g° 708° Mt Jerson pion Rr, ~2072 1! | piv. =n, R, | RT _ 2082 mol (60+ 730218? atm) ae v0 | F aomene®) PN, = Baas 0212 pin | no BM 2 1062.7) (1065.5 pig) RT” RT | [ces c ere eee | oman BO Rr | 13.40 ] p= | | ar ‘Steps 2. 3, and 4: 2 RDO) 2S «S| - [a] SF, = apne | | aa9 TeGore q Tipe | ba ° Sp a a oa iste jaa9 Stspa2.3.and4 she oe st 2b Tomo 100 psig = 1147 pia (continaes) |2830 HSC|_1bg mt 945 aot tw SC Sep6 Unknowns: ®F Step: Indep balances: air, SF6 Steps 8-9: Balances arin moles, Sh; F(O)+129=P(4.188104) hence P= 3.098 10" kgm | oe npmaliada? Sclo+29 SEER] Sb apraen tn! uC 2) ea | Tkgmot | 273 (eso ram’ mscl3siK| 1 i teen lox 35 [sat Step. Basis: 1515 00; added #30 i Ste 2.2.and Pm Le aie (oe em, Mok ly sie Be 13 thcos Cortana) EMH Oh Gay tf) 0.8/8 Pry) ene IE SHEE ©, sens Sup7 Balances as,CO> Supsi.and 9; lane ovealon process in les cas: 0988 F)= P0968) cos 0012 (F) +0341 = P0034) | rout Pose = P= 16790! P1513 Tool Boran| 312in He | (modCR) | | | Lem mralaisirign|éorsore Gas | va aati | 60 MOR eae) | erro 3120g |Solutions Chapter 13, fae | ‘Tein ol compe arty of NO ad pry of NO, We can ete Ke piv | {easing mae peel tee Bak: 10? fp 70 ad 370 7am) WL3 we | AIL | DER’ 6 RE pea ee ees ot -—_nim MOER «gers gm arrears ‘ea 1 ie mic compe of NO OMW = 30) and NO, OM = 0, dca we sow tet sa nh el ee oa he at fay NO Let = pe ‘ovinen 0291 =) = gO) In ae mat be aon Compost og MLW. gol | | rooms we SBE aS aos | a | w eo ase +0 ~ 09 = ass teats Te wi nO see, BE 100) = 38 ed the ee pret NO 0006650 _| 1p wai NO TaN gat war | 3058 (Cn yore be te oe fon NOs bla he sae ee (Ato Ye) eres eee 000) = 188 | Selene Chapter 13 Sn Bas: 2 in| | seou.2.tnd2 2201 amr. 760 men Hg |520°R [359 f° smo of eso nl 0 me 40162 M0100, «nos. CO, ig | rat | gO Tussin tar a mor ole nn on myth en do cnain asa ek would ing no ado CO oem sore 0; talc cleans nat the given sans pbubly const —Basis 1 mol of NH fod osR=02 (omni soe ‘mol NH, fed SOKPONH, ft |025 mo eye (150+ 275)K Til NH, fed (100-273) 1a recjled at 180°, 150 ka im Ni, fa IOP, 150k, as, Pret: Sead wate with ection and eyele SuspS: Basic 1min__—_2601._Cotls Solations Chapter 13 Sisps2..and 9501. Hy Celie 3 Ha > Cotta Cove -+ ma ft aed poisin ma 4596 ma T= 1c +273 37K reese 7 Ge moxk) ‘Selec th overall stem for he rst balances In Out + generation — Consumption = Hy 4596 ap, tO 07514596) Colle: 1258 ey +O ~ 0781459654 Cli: «= teyu, + 0751159694 ° fom ig, = 1.50 se 21.09 ¢ me fom: yy = S801 Volumetric ow mies: T= 200°C = 473K P= 100 kPs=0987 umSolutions }en, = 452 erin Ve" 428 erin Cy 452 Hernin © Hy balance on Reactor + Separator (8595+ 0.908) -(090R +11.5) +0-0.48 4595 +0.90R) <0 ‘Subsite or aj, and ove to get R= 28.7 kg mol Gia ‘Volume tow rate (R) = 136 Basis | day = 10k CHO To0% C3Hiy R10", 1008Pe | 5 mat. SE 040 So conwinf 100 70% convenion of aso © 3 {tie overall sat cose, te unknowns ae Fr adm ad Wie dependent | eustions canbe writen fom C,H, and Obalce pit acon ~ igo Pick the system ofthe reas pls separator, awe the dat fr the conversion. Solaons Chapter 13 Sins: Bass 0g Oe 2074p wl Cay | Siea6.1.8and Mixing point F +8 FF Rint ate Reactor pus separator fags Rp3-0 inl eR} catatamee: AOR) atu tate: 0-21 FTOA+ RJOSOROTD)=0 =t11 94g may R=2247 gol Fr +RoRp=113649 (o W2AStemal2Ao aC _ RS STEER] dy TT tgmol [este somrerte 32471 bg mol of Hy io pesom! sca Ed | (y) GT179{040)kg mot of CHa [22.40 mPa SCl273K) 100 kPa sal cst. drones" bataceD) ‘ {continSolutions Chapter 13, WI O=BATO co, £811.19 40) 4) 2273 + mw s1179 4a) @)=23 +1968) G= 19685 + 196834 81.18 47088 £70.84 ig mot Pd 22 4m ws hs3 1101.3 |i -RESREIOT aT pila nore me 10S] Tops IAD 19489 419485 (+902) ao “BLS Solutions Chapter 13 =H eaten Geno) | ssestgm RT earaca yo) aR ae sel Cah = 0.8505 mol Cathy ay nol feed mol Cg fed” (rss BCE osallmaltislance (00 rection) FeL+v V=P-L=845635--57535~27026 kg mat pV=aRT —__|Solutions Chapter 13 1348, | Sins 1.2.3.4: Stey ste problem with a ection, ‘Sten 5: a 1 reg mo Cae 651040) = 260 kg mol Os xs T0kg moO, oa Solutions Chapter 13, 910 0%) = M23 ag mal N Sies.A.0049 | | puncte nt es c 1) = 0 ty" | bi 100) = nyo) Oe | on 910 = raging eB ng 26 ma a= my, Pea e5+26+3423 4585 kg mol | ART _ 4583 ig mot 16(4P Oo" 99. 1K | DP” 1000% | (kee Go iy |Solutions Chapter 13, (ie go asi kg mol a 8 | su as | 6 | say [a 5B (10 py, Hie 100% S1100% 64495 mot ibatnce Frgmol HSC] I gmolsi si name Fy Lrpdarrsier; 7” 01S Bence Fa= P Hal belese Augmti|2ema gaetescy tem warn gmat | qo) Ene MOSEL Salon re Solutions Chapter 13 Pot gaol HSICl 2Fy=W=3 gol HCL 2 += __ 64495 gol $2066 Jun) xT) Ge melKK SgmolCl__WenalHiCl temoicl {Teast HST, ~ {Fz cT iors k|_1. atm 17000 eaSelutons Chapter 13 ns t 1,0 (100%) OF and 30a Hg ab | | isomer © for, Co, 122% 40% cos G0 ‘a7 ears 60 oe 2s cil W= 1200 @sareans Nz FEM | 6% us “Wing 2 fos% cH These Ca 16 N} Sip 1.23.and4: Steady sate proces with easton sun Bait Sup 6.2.8.9 | temettlance: have C,H, Nand hae 4 unknowns P, YF. A ‘Basis: 1200 6 of W a 60°F and 20. Hg fe te Bn fa c @ossonesome + “Ss emsczormw “8 - @asaane 0 Ne sr tame OM aarw a> Cae Le te fone = "9" 2 ganow 2¥ > O% a OF moray Somat ON oY” ezaiaoromse 20 Incas W = 12008 [BS Shag 2H EBS Solutions Chapter 13 {sove: Eaaa7587 a A=19S108 Yess P= 20.60 8° ‘hivin« SION OOF & 3Oinches Hels 30 inches iy _ s20°RI296 inches He a Basi: | Thmol of 0% Hy and $0 CHO pvi=aRT) — pVaemRTs Ty: | eon tig Lat y 2 mol of C10 formed ence 93° 0.922 mo (@5-y+ 05-9) +y 0922 fiom which y= 0.791 mol C3H40 formed | 207, Degree of completion = 2.27 050 ) Ci, iowa CHO, seen! ‘The reaion equation Nas + BNE, +264, 0, (comms)Solations Chapter 13 +4C,H0, +200, + #N, +8H,0 | ‘The smn of CO; messed (S24 95 Pan 300K) is | seatco,|1 | Ge 0VK) 2,10 kg malor2.00 gol Ue lant alan and spsetns oe the coe nhe exton ution. Let ‘eet forcing cules: ten here se Sankrowns, quis slo ‘pence: ce atbese+ 200 He tases ends 2g Spitenions fat aa f-2 3 ‘ Team fe ction a=, 69224 42010, £2224, 40755 “he gyn prio oe OTE. ond ‘The tiomas reacted woe (6D ml] Solutions Chapter 13, Bais the 2:t0'gnol0,|29+10" clei! nto? mgnet _ Fan (veto | ak [Tenet "|e ‘sgnleaouo,huns|ter| — | oan Settee | TTC seK|astatrayar) | =799% 10" kemolir oe [Fg wale] hema) Dai: In? a SC of CH turned comple arr horton of, eC gag 10 CO in te mil alr split the alent ecu oe prod ave eh ett onthe Ns aed CO, pede (CH.(g) +20,» C0,(8)+2H,06) Coles te kg a of CH une {0fma SC] ig mot 44.613 kg ol laaisa J sume LO exces aie. Bate th Cn tein fctr ve wena “Ba sl) Enision ft £05505 .1K89220) eect oat: BRL Neening .U90921)= 369227Solutions Chapter 13, Solutions Chapter 13, aa em ams | saan om | oa Pe = tor tbe | 48 santo? cs 7 mal WasContietaa | site| $0 wos=ts% 6s ~ 6s |s0, c6(0as)-0s0 $0 33 oie 80, s % im as | co a. a 2 ass 0. Sis a Sense 180 | sample feng he st SC on he basi | meta (107 ko No, 6 il ure so, 229 kgm [22415 m acl keel) ESTES Seno" emo! 2 asun? | | Toate sta “Tam Onsen mt | so, x10? | NO, 110,820" a 78210 egy jase Basis: 10" of, 6 tit IPL ei}086 61000 1% gor 86s10" bg ofa To gt the moles of plluion component sloe in he prs. ve fo convert ‘sig MW (pce te prune ae) Base: 10°L ofNe 6 fil 100 en? 1 10’ Loijonsg| Tom 8.610 ¢or8.610" kei! Caleta the ml fea compound in te i Mastin bg aw tenet c oer oe as | Bio sont tome ° netst0 5s axe N o2exi0” 2 “ a7 s oseei0” 22 2 03 04xi0? os | | cate he mates of proc ans eeSolutions Chapter 13, = €40,-+€0, Ns0,+NO, gu? “ 1 “Th $0, and SOs ae om he EPA dt rd Problem 13.55 rs kena! 305 oe 0078 50, 15960209 IitheS +04 SO, esd ate pod tm the inte ithe valve oF 23 canbe compared wiv 028 inn the 80).Solutions Chapter 14 a Base 1172-025 al Ju reetmak — pessstam te arse? f wake EO Tee mM Gea Ba gM ca) a ea stint =(43)450 "144m | Sot: You cute 2 tom Tyan V;,and tense p= 287 a Basi: 2 gmol GH pe=S0Sam To BSIK; p=? T=984273.1~3681 K ie Ble $2.06? 88.1 460 ee Be @mobK) [505 aim Solations Chapter 14 +209 enigma 368 21 130 From chap, 2, bece p= 101 atm. Use ofthe Pitzer ascetic fitor would require a ial ander sltion, J [us | | Dai 3 hla 20°C 4 Volume = 50° | Atma) acon?) mop 273) "7° Tome) Y a Te mnns | s ‘The Pitzer ase actors not a convenient ous the compresbilty chars From compresibiliy chars (Sethe CD fo beter precision) 2-076 prot (coniued)_Seltions Chapter ta espa gy R , = (Gps. 0 wm Basi 1 Toate o2s-R ham | MWe tld n po geno ‘To ptt empersre of the gat 1b mel |3s9 SC] aon | 7 Tam traf Tents aT, = 41025-0825, From he compressibility Chart Fig 144 (expanded in he CD) ead T= 1.16 s0 that T= (1641028) = 1897] (29°F) | Avert sution: Calculate 2=0.71 and use pV = za. Solutions Chapter 14 Basis $0 COs ($044)= L138 mel COs veson > 1600 + 14.7 = 1614. pia Pe=l0vOpsia Tye SATSR 21ST 31 59 = 440870 mot 1070 8 2580.0 mol sothat vy = $49 = 0.800 1 rom Figure 14.4 (expanded in the CD) i 1.44 1.40) (5475) [ER] 28°F) “The Pz asec factor isles convenient ous otis problem Basis 10 kg CH 10g ke met MW CH= 1 ~ 0624 kgm a 1603 kg T.=3054K and pe 4885 BP ¥=00250 mn! p= 14.000KPs gauge = 14015 kPa boolte ois HOS a7 cm 4883 mad) Solutions Chapter 14 From the compressibity chat, T, = 10S hence T=(1.05(305.4)= UK] Basis 19 CH pV aRTe e247 pia p= 1028ipsiane’) ij (eR) 220995 = 21830) 5636 ms "Tomasi ~°EP Met ih es) = (0.038) (1603) = [EZR By use ofthe Pier seni ft (= 0.008 fa CH) z=2'+2'e=0976+ 00% (0.008) 0976 Solutions Chapter 1 Basi: 251 of CO; a1 25°C and 200 kPa ForCOs pee BASKPa Team2k | = 2 20k 3,” 7385 kPa 027i (542K _ S042 098 “2 Tr From the compresility chart, at these coordinates, 2099 pV= mkt over tem_ fst gmoney | Tora ural [rbe206c xm 2580.95 =204 pmol | macon ieee o aR] 4 Basi: 106 a °F and 147 pia PN,=20,R,7, —atheresenoir pV=anRT usc 1 _ 120+ 460 80 6 (contin) 7" tows) — 5aSolutions Chapter 14 000 1000 Garman” ors For propane: Te 370K pe and R= 018855 (Pay ka) 204272 _ Reduce temperature = 136 Reduced pressure Froma generalized compressiliy chat 408 sad T= 135, 2 080 ar Solutions Chapter 14 Bass: | gio! GCI caw = 11256) pe 4518 kPa T.624k 2 ons: x0 is mao! These values fl below the gaseous region inthe compressibility chart here uC! it ota gus. Tesa liquid (pgr= 1.107, so hat the volume (1) 112 861.107 = aa Basic Dats on gases cited in rblem, The cubic fut stsocaed wih “165 and 240 probably means that the ‘alues seth reapectv volumes ofan ies aro standard conditions, bec he ‘lume aust forthe gates in part below ae gute diferent than the ated luc. (continir | ee | fa m2 52) | | sete gas wa aos | Veen wetcn 29 Paes 2, 28 es wrorcy= 288 Hay jmorcne= (aml Trereore hen, > Men, | | pw, ~ Rr, | Bocca Te=288 Kno" 508 aim | RT OHSKOTNSID, Jen I5— au Tans“) - BER) (Atstndar conditions: = 1.00) | bec | px USING eH encores) “TECH Check with ine - 163-90 = 123 beyindr 105-95 = 135 b epinderau | The answer sit depend on the gs temperate andthe presse, pV =zaRT apis the eal pas li represented by = Iv and fora on-idesl gs, canbe gene et sa eprint p= EE, Sopa pa tie Vf te of oles and temperate (he volume of yiner is xed). The pressure prditon by ‘heen pa nw wil be conservative higher han he epee) for 2 I and lower than the te pressure forz 2) MrzaRT R= constant Pavia 2an2R constant, th vol ofelinder peo 345 oom monnigsied 147 pigiaen [343 am 390 Solutions Chapter 14 er eee Soe Sy <0 1073 Ts molKeR) 0.47 wf 0.73680} sre 2014.Tpsia | (Ib molX°R) Lee Me _ 1924 7px _[u26n RT os) | 6k TomoiyrR costae “(0447-04279 mol 3 0.020 met se oflos= ee or i 175 mole) 100 ppm = 100 (0°*)4.09 1 mot) = $4.09 10-4 aol (continued)Solutions Chapter 14 467 10467, 9) 6m 0.0279 me coon 20278 on 227 Bet a5530 700 ime ra 8) TheCO slams would go ono ale people in the building 1416 | 8) Thedensiy ofthe gt mst be 2.0 gm? MW ie Sis 2808620 |W ~@228086)= 0.0712 golem LetT-298K. Alboz= 1 and V, very pe peta. v ssa emoixky Atm Jf “>A »)— Foralower pressure, we aes dene gas (ower MW), ©) Ato high temperate, you cnnot pet adequate density, unr Basis 240" methane a 80°F and 19647 pia. Assume the muberof moles doesnot change 2M aTy, baVa” aRT2; — Solutions Chapter 16 mde Tae pelea 2 | cateuaon of | Metane > 1, =1907K — 7) =0°F > 29980 29922K | 6 Tonk 77 1337 am ise "299 2,083 Caklaon of 2; 1 = (1980 pig 147 pint 5 pig) 138.7 p= 00 e+ 147 79g) 208.08 | | _ 208.08 am “8am 78 v= 200 9868225107 Yoo) = 62797108?Solutions Chapter 14 Rr HoGaifomieno Om) te ‘58am 41.68 ‘smi (458.1m)(6797« 10cm") kh" GSBEDKVRZONONS) #152445 gel ¥ S797 «006 7152485 gel wise SE o1305 106119647 pss) cs) Solutions Chapter 14 @uaes 23099 ny=105 Ifyou use the Pitzer acetic, fr air isabout 0036 [ane vze 211999 + 0.22 (036)~ 1.00 | n= 1.05 +003 0036)= 105 1s Bass: Gas 50am and 640PR From te compresibiy chars Serres} sohao2 11 mot _[359(0.88) act | 0 _ fais actual Ry ouanate em pees 10 Gre 1 ad | ruse pV = 2aRT twice scottSolutions Chapter 14 Sotuions Chapter 16 pa eeRT ivi aniRT, » ny I rol = 415 cra 1420 Basis intl gas a 200 pig and nal ga at 100 psig MW CsHle=28 ‘nit an 2g a0 r= 105 we as) ae Aterate way ges owe the Pitzer ascent fact. sftre cosine) 210.910 + -0023,0085) «0.91 3037 + (01059X0085)=038 trial balance | wiswenae Wa-Wi=281 m—m=2828=1 a) Wee We=250 ‘Soe (and (1 yield; 0089 2 Mass of ini (28 by ($0.41) = SITAR ag) We oteytinder= (222 249) - TEE) (0.089) (28) =249 <_ vate samsteniomn ery van = 180 urn = Pais 3.616 ws eon tee tsa an | Liss: 100 gas (contin) _Solutions Chapter 4 mol mol, co. 1 4-440 ay” cata 30 100 ns a-2S.135 m0 BS 1asm Ty’ = 0.10 08.2) +040 (190.7) +0.50 280.1) = 24825 K ‘= 010,729) +040 (458) +050 (505) ~ $0.86 am aus Gace? Gao From Fig. intext, 2.78 sak , st aft (* Jos ° Gaede) | ‘LeAis pra —_ Solutions Chapter 14 aa 020 10H | ganco, 100 Bass: gasas above 1° = 120) (63.0) (0.80) 72.9)= 7092 am Te = (020 (5163) + (080) 804.2)" 3466K 00 68 3, Auman jon Re OTS KM gm) Lat 180 1804s i Ye From he compressibility chan, p22 ,p = 77)Solutions Chapter 14 Basis: S40 kg gus @ 393 K, 3500 kPa absolute Commonest kg ktmal moleftstion pam TAK ch i) Co =o a alls m0 800 os2 2s cate 0 34S at a0 M 2 12 om Bs Las Toul so 1945 1.000 | Fe= (0329 an +(o4ay 00s +017) (97 +080 (126)~2628.K = (0.321) (45890412) (48.2)(0.175(42.1940.092) 3.5) ~ 4496 atm 393 3300) wn 39 mya BR= 1.0 pi 3500 0 From Nelson nd Obert Chant, x= 0935 MW (avenge) = p= 300K 7.8 eg (K) eg ma 393K [0.935 [eg mot [8.31 Pom) ws K and 5500 40/1945 =27.8 keke mol Solutions Chapter 14 Sommonnt on me cate 0s7 soso * ow 480192 te ons 1026 zane 48.31 y= 120. 28 30 wR 20 BE 30 (07018205909) _ Feo ma - = (ease vee any BE sm pmel sain (L2EHP) 00 i 2 107 19 Enq 2-070 ae 612 02 0395 msSolutions Chapter 14 = ne creams come hs | ere 5 | B02 os | wy = 35 : fo Bola m oS ‘Avg Mol wt = (0.60428) +(0 4040) ~32.8 hb mot pV mT pe. (00K18.71300) BAT * (095K I0.71,760) =570 mal Assume capacities ae given a storage conditions. Then ype IA is selected becuse it (he cheaest, ‘Naber of tanks required = sagen Solutions Chapter 14 1426 Steps 2,3. and Assumes contauou process although bch process Would be acceptable and give the fame resus, su po gas et we; Mae wan ‘e aos; { to Lc @ pn Sen5: Basis Gat given condos Stepan: Vatsowne EP alaces CHa, N ett eet of fea =0 Siensands cota 480 ayy 83 so 147 75 29 - 2540) (cootived) a7Solutions Chapter 14 Soltis Chapter 4 254014659492 Basis: 1004g=F AS 6SD) = 1.157 mol | 1A. TKS30NO30) | consent MW emo mol TAK) atm is ee ca, F(020)+ 1.157 =P(050) Ta oss oz sagas | Tou FeList=P 0616 gtk Fe1928ibmol —P=3.085 fom 100 1082 1.000 | uat SiS: Basis: Uh , = 48.6 (0.592) + 403 (0.299) + 34.6 (0.109) =446 —_ Colette the kg fF pet | Stps2,3.and 4: Stendy ste open system | = $62.6 (0.592) + 593.9 (0.299) + 619 (0.109) ~ 578.1 | | 258.0 25a 96 a sa eat rp oma M00 FT Seprmar 2 "tte oy fe Toptier aso ed Ste a 2 -28tamlas | _ho.sa agenda i eens mer (0) Tm BS1AGPaN OTR 247g mol = €247) (100)(1.082)= 30017 ke, ey 30,000 kg ‘The materiel blaces are ink. Beene ey 7 ee Fe ‘Convert Fo moles and hen o mas Steps Unknowns: Fy her hy (oniSotetions Chapter 14 “The balance inka only 3 ate independent ass balances) (0895) + +P (0.06) (0088) + mu (009) Xp 30000(020)~ (0021) +m,,+ (085) Toa! 30000 = + 98004F) ry, yy + my = 900 Solutions Chapter 14 sent Solutlon: Using (1). 2, (and (6 via Polynath is y= $500 kat = 14,700 keeImmediate but approxinte peer. 2e ct butrequves aces to handbook 3b Good accuracy, neds clelation of 42 Good accuracy, more complicated calculation than b even in. program q vith data bve | se May requ ong search tof out a good value For other answers ok at the anaver P15. 182 Wit et the mos accurate valu, and be quick, assuming you have the handbook tat comans the required dat. For her anawer, look te answer o PIS Some valid anowers re (1) ccatinaous analytical functions, and hese functions can bediteentised [ saditegrted (2) bighersecumcy (with complex equations) 184 pe Bef. 2 ‘The results for BY = ae shown inthe Excl able Below. You can deci how much sccurny is node am. terms taco 100, 1.90 oss 095 190 so oe oss 00 10 =a 076 00 20 oo 079 00 5090 90 00 1000 as 095 100, soc 0.98 099 100, Iss Basis: 460g CO, 1 RK Equation | SPACOAht AE soassipmolco, = 304.2K, pe= 7385 kPa 658 Pa) CK" ot? | b=00297 mg mot Geroxe") Gemoixk) R=8314 0995 imal (3141290) _ ess [P0995 0.097” asasomes--oaRTTIGT" _ (conta)Solutions Chapter 15, Solutions Chapter 15. SRK Equation: Te= 29020420953, ed Rts = AAESESL S02) sy spear? PR Pe nou 31990082 , eo oa Oa wt = 1670 pia 8)" (00 mol 1909) __G79290.040)_ b=0.3536 io mel ‘985—0uT97 O95099S +0057) a9 no 82.1997 he ate An(1+ 0863-0959) «1080 ve 355 £216 mel | paints we No significant difference. Solving p= 1335 psa 156 Therefore, th reding on the presur gauges incre ’ vnc) “ eee eee b= Ugmot Pact Colelate he mols oN. => dean ‘ Te4053K + 29K PLoUiaim — 16X6peia 20250 sor 860k R=10.73 (sin) (8) (m0 CR). 20 tm = 29339 psa Tee Wa Mtt7295= 1179Solutions Chapter 15 Solutions Chapter 15 Tere e={l+x1—12°yf «09890 = 037464 +1 54260-02690 o? = 0.1276 9-299 8/to mot 120-4 n+ 568 Pie ens Fou 0» 558-1497 8m ot 50°F 810 Invoduce Vito he PR egation. Prom Polymath 189 Basic CO; a0 81 prigand 25°C | | Prem in cen (8.0 psig 147 psi) (a7 si) = 651m | Temperanse 25°C = 298.15K =3042k VentbasemFl706n)=s156m? 729 um n= 200; 1225 Cath Oy +NaHiCD, + COs" H0+ NCH, Using Peng-Robiason equation 2 (00a b7RT-H'p)-2*(VYa 208-3 uations => {(e)= a1 (0K)-(02Jop-—RI)-V 96 Jon=nr)—v4 a=bea—b'eT-b'p p= an-20RT-26"p sro BEE s-o4n( #2) b= 0.07780(RT,/p,)=26064 Ty9388:1519082~0980 (002739810) 17.1240.984) i chy? =0990 | Pfr 0372 TADAU ABT «03720 40.721 OSTA e-[iext-ert)"] «1007 | 0316426002090" 070 cians)Solutions Chapter 15 R= 82.06 (em Yay. molNK) The idea gas aw gives 0233 mol CO; Ta20818K | p26 aim Inada he values int the PR equation o get = 0.220 ol CO; 42420 e1CO, |) mo NaHCO,|84.00 NSFC, TE TETCOT Tmo CO, | Tmo! Ne HCO, oo 200mm ec Cale he mole entering the compres 00 Solutions Chapter 18 | vars Soot, nassis Aa oni 8 ea “8 meni Use Van der Wal equation: (o Ae the inti ges forthe numberof moles in tte 1 se he del gs ow some) RF, stays) HOSEA The numberof molest condition 1) is btn’ fom (son QE ana) 314129, oo a a pom THI nectigeel | | soe or v | v= fai a SK an 60Solations Chapter 15, sit Pa" Pe*barometic pressure T=273-50=223K ew39-+1=40 0mm at: amt owns ‘atten weave ae Ikekeme ttm! sa cao ccc, Enea tgmo! Tem For propane: WO9K, peo 42.004, w= 0.152 = 0.374641 5472(0.152)-0.269920.152) = 0.60289, Sotto Chapter 15 | e=11+0.60283-L00686)F =0.92 a —. RK oS xtoaanyK"Xentyg me? 62.7 enigma PR 1O04xt0%(amyen')ig:m0)' $63 enigma! Radich Kwong: | Pee Robinson: Desermie the volume at condition of ate 2 (383 K, 4900 kPa) (10: 225086), ons99)-conoeaion) (=26m) state? 1813 FerC0, $0225 and T.=3042K, p= 729aIm 62.751 Kem a b=299em/g mt | Compute resus: Redich-Kwong=[1559.6 00 (ctSolutions Chapter 15 ‘The experimental molar volume = ast R= 8314 Pa) (weg ml) (K) = 6458 kPa) (0) (KS beg 0.0297 mgm) 1230) 6458 W291 10) WaT I 1.876 mg mal fom Poh 104 v Ss4kg ol vie T=420R (REV) gc gnyyp MO end yea) R707 yee) Bass: 1.0 mot sh ioe a moun “Taos Gamma) sen 39240 Jom) |= Gaa say om Ts) 3593 sa 20° Fa) Gra-w) 393 _ sor 420° Tye -) (741-0)Laon $9206)900)__—_ 1001617206 an ‘qens21.) Goo Ueosyvante TH “7-79 Basis: 0 1 water a 900°K \aem'ignel ‘7 | | Foret Te s163undp.= 634m | 16.3 am fom Appendix DI (27.6 atm forthe CD) ead 1 Use Vander Waal” equi, 2064cnym| 674K . ; CRXg a) ISS | Basi: Ethane a 10°F and 200 pig (MW = wos rite P2014 pia 108 T= S60 18 osm 1-2-2 19 ssc (S25 ares | i B | tengo ' Tes 474K; Penn 900 - E fon (one junepn sae ere tow where a=0.4278 EE | st : vuln 200 nen . ee od ~ fee staornoté Yee - ‘erate to find value of n. Use Exel ave this cube (continue)Sottions Chapter 18 1, Use the compressibility eto method 1 709 psa Sa9R nse 1 [20147 pi|_CRB mo weal od he Propane wilt] ‘SRK suiaon ‘Solutions Chater 15. [ies wane eh poe wit be higher for bo net System: Miter pls engine ope, steady ste tems] Mi Engine 299 wascar apm os ae [sims nas 1 espa ase | op etsettamaie sud | Unknowns: regu] dee eedom 0-1 ‘leet ances: CN HO [to senda! the equator re independent, _ cosines)Solations Chapter 15, Tu = SORES OE TIE aga 2N: A(0.29)= 115.680.7441) A= 108.96 kgm 20: aonsoy020 1154 oon noses. 208, 2002) | neg not | | T=-16C-2556K — V=0190m0? 190s en) | ‘Vander Wl’ ent: exe") pay) setae HEE) 5 are . rae SE 5 ars at penis poset ml Test | sonnon: p= (S=IOTaR) Use Relish Kwong eanation: as tsesnn EAM ro oS ‘Selutons Chapter 15 1520 ‘sume a continuous proces although batch proces Would be acceptable and ve the | same reat, ‘Sto. 3.and a ‘i mol, MW ier git oso N00 2 me, 0 O20 cate T | Bio No Timms @ so pigane 7 ‘Sten: Basis: G at given conditions Uninowne: FP ° Di ema Stee 6 and 7 | Sten and: | { Calculate G: Use Vander Wass ogution 6s aamyen’) = 8 9m Re sagg emten) war eam 84K cat ws a= 44810! aim (en!ig mol? D=S72 cng molSolutions Chapter 15 : | (ae be Hgeeit [822 73] mammans 216 =F) | [pe Stat with n= 550 en! olymath Resale ___ ti Gees 7s6omte 4776806 550 | MLE Renn seen) ening equations {IY Ra) = (9.8 00239%0°3)943262.57.240) 2416790 Sexings ‘Mc Herations = 150 TolernceF =O 0000001 Tolerane X Bolesss Let Pe the bt of gsi the fd and Fe the bol of swith 20% Ci Solutions Chapter 15 [Cie FO 155= POSH [tou + L655=P (=PSolutions Chaper 16 Solutions Chapter 16 1: 2.0% 3.6) 46% 5.0% 6), (©) 40°C; 6) 190; 6) 60; (6) Compound B @ gh isthe saruated curve 0 alee the sated tigi curve |) canis the saturated vapor curve (@) fst the ei the gud phase (6) heph othe ight the vapor phase (0 aegh below ithe aud vapor region (cin the xia point Rigi conn eperaas Te (© igeinn constant pressure ine tea | centinktepnpe cthal pt Lit-#/- Conta purse iw | - soburate carve, satu igais | ray Sa ce oa ea phe tein ms 0 fie Ate 7 (oh tower (0 higher over (0 cans: (ower {Shihes 0 mee (ite ore ower ihr 1s From the p-T dag for water you can sce that sing the pressure by large mov on acon empresa po fom te pho a *Solutions Chapter 16 169 ‘The vpor pret of methanol i ess tha that of gasoline so that at ower tempeatres the flor mitre flint or combustion. Astomotve pars canbe made of seo tolernt trials sucha suisse or other ‘uosin resistant materi and ative tothe methanol such t 15% gasoline ean ‘sipsove the problem of difcul cold-wenher engine arts, Append G(T sink) cD dicinc (0) Acetone 0" teen hy 726 a = 7055 mmHg ogo) nr tsa742 mat p= 12289 mm Hg tet ithe Antoine Equstion sing the tre data pois to get A,B, and. In a ig ke nis 253 1898 150 ase Solutions Chapter 16 33904 11898)" ara” 1254)= A-< Bwana IANS MT (441.90)= AB —__ 0011 IMLS)" Aan a | Te station fom Polymath is Jawi6sss6— B=27078 NAC, no 16338 p= 939 mm ig Ate rpe pon al he phases (oi gid ad vapor exist equibam. Therefore, the vapor presure of gud ammonia = the vapor pressure of oid ammonia 15.16 ~ 306377 = 187-3754 1683 No. Itita ype, Probably the number was 38.8°C because if you equal the pressures fom the two equations, T= 371. 75K, or 8.7C.Solutions Chapter 16 Solutions Chapter 16 DATA: Focbenzene (p*is in He snd Tink) [tone ogc? (oecty* ry earn . soo 31477 1165329 0.1130 opry= 159008 2788p 760mm Hig ng) = 6.6331 Sis 323331 15.5619, 3.53600 Spa Maes 195.0208 1721000, T= 359K agree wih database on CD Samer Mau 23.9313 213000 Som 382856 2osaarr 12880000 Seis 358576 aisars 245.60000 Le Sous Sener n03t67 4§3700000 | 7 poe Sones 370488 nssor9 73320000 Inipty= 160137 2962p 760mm Hg Gis27 378561 2sit6 143400000 | e2iag3a2I4 2wn0166 2537.00000 | 7 =383-7 agree wih daa base on CO Inpt=atbla T+ (aT reas +a? "THR COFFFICIENTS ARF Merge the wo equations (AL MW=27) sriggaset a 790261 « an tte smaris & 39s 6 We 1058310? PO2T hee p, ON” = coe eee 3 aon 1617 Bavedon doa fom he stem bles Thesohtion fom Polynath is Site 1 aid Soe 3: said Sate 5: gui (surat) rar ‘State 2: sperbected vapor State 4: saturated vapor State 6: vapor (saturated) ‘You can oes the properties ofa mixture of vapor and guid in euilibram (fora single component) fom te individual properties of he sauated vapor and sxustd Tui by verging the roperis ofthe evo satused phases ‘The weghts ae the teapetive seus ofeach phase.Solutions Chapter 16 1618 Based on dss fo the stem abies ‘Seat: satuated vapor Sate 3: wo phase (stuated gud and wap) Site 2: saturated gud State: supebeated vapor | atorthe values of specie volume ae obtained using VR agg ge Wi | | ¥ da fom the stam ble | [ia 9-05 (1.673) +05 (2001083) ~0.837 mag | ) ¥=05 (06058) +0. (0.001073)= 0.305 mg (© ¥=0313808)+07 0.01613)= 10525 9m (@ 9 =0.7(1.888 +03 0.0187) = 1.2968 frase Jonononanonor j — | ss21 ! Use ota fom he steam bles athe initia onion of p= 101.33 kPa and ature vtr etm phases. | ij=1oucmPgand 9 =1673 0m ‘Then th mas of bth phases in the container an be called Solutions Chapter 16 | (008m) (00 emim)*/ LOM emg 283768 7297! (00enin'/16B.0emiig~ L238 ., =30511¢ ‘the ial contons al ofthe gud has been evaporate, and oly saturated vapor will exit ving specie volume of (6.00 (100 cain? 30,511 9983 cag Interpolating inthe on bes Jenene onssyenlgpsiessan cae (eazd (1985.29) kPa 1985 2:2055.1 kPa = (9.09.98) ig (9.09-95 28) omg Basi: 10 bot water Sotevoume: Vo !28 ase From stam ables (in fb) at 80 psa 4, -000157 ae 545Selutions Chapter 16 ss (0-xY0.01757) + x{5.475) = 4975 | =i) | Masso 2(001)- 0164 Mast apr i 210506 L818 The yohue oli Nema 0qaartsy | Teli of vaperis | an 8.09- 5) | Basis: 210 1b water Specie vole: V=(1-0)9, 24%, 3 osha Specific volume of water = From the stem bles Specific volume of sturted gui, F000 088 mg Solutions Chapter 16 ‘Then, 0.175 »(1~x) 0.001 088+ (0.414) | The quality = =H) 164 ‘Sine the two phases coexstin equilibrium, we havea sarated mitre, andthe Pressure must be he saturation pressures the given temperate: =p" @.90tc= TA] [ALOIC, Vand, value eV, = 2001056 gan 9, = 2361 hg A oe votume occupies By ean pase | vewe wend om9, ~( kgh0.001 mg) + (244y2361 ming) = [ETE] ny (ripe eee | Azzememmncttetat nines