Experiment 12 Period 4 AP Chemistry The Determination of Keq for FeSCN2+ OBJECTIVE: 1.

To determination of Keq for FeSCN2+ PROCEDURE: See laboratory worksheet The Determination of Keq for FeSCN2+ attached. EXPERIMENTAL DATA: Reference Solution Temperature Sample Reference Solution #1 Reference Solution #2 Reference Solution #3 Reference Solution #4 Reference Solution #5 20.25C [FeSCN2+] 4.0 x 10 M 6.0 x 10-5 M 8.0 x 10-5 M 1.0 x 10-4 M 1.2 x 10-4 M Test Solution Temperature Sample Reference Solution #1 Reference Solution #2 Reference Solution #3 Reference Solution #4 Reference Solution #5 20.25C [FeSCN2+] 1.0 x 10 M 1.0 x 10 M 1.0 x 10-3 M 1.0 x 10-3 M 1.0 x 10-3 M
-3 -3 -5

Austin Grant Miranda Began January 5, 2012

Absorbance 0.150 0.184 0.316 0.365 0.454

[SCN-] 2.0 x 10 M 4.0 x 10 M 6.0 x 10-4 M 8.0 x 10-4 M 1.0 x 10-3 M

-4 -4

Absorbance 0.112 0.182 0.264 0.357 0.407

Results Solution Sample Reference Solution #6 Reference Solution #7 Reference Solution #8 Reference Solution #9 Reference Solution #10 Average Value Average deviation Calculations: Calculating Resultant Concentration of [FeSCN2+] using slope formula and absorbance Y = 3945X 0.021 Test Solution #6 Absorbance = 0.112 X = 3.37 x 10-5 M FeSCN2+ 0.112 = 3945X 0.21 [FeSCN2+]eq 3.37 x 10-5 M 5.15 x 10-5 M 7.22 x 10 M 9.58 x 10 M 1.08 x 10-4 M
-5 -5

[Fe3+]eq

[SCN-]eq

Keq 210 155 147 150 137 160 20

9.66 x 10-4 M 1.66 x 10-4 M 9.48 x 10-4 M 3.49 x 10-4 M 9.28 x 10 M 5.28 x 10-4 M 9.04 x 10 M 7.04 x 10-4 M 8.82 x 10-4 M 8.92 x 10-4 M
-4 -4

Calculating Resultant Concentration of [Fe3+] and [SCN-] using ICE [Fe3+]eq I C E 1.0 x 10-3 M -3.37 x 10-5 M 9.66 x 10-4 M + SCN1-eq 2.0 x 10-4 M -3.37 x 10-5 M 1.66 x 10-4 M FeSCN2+ 0 0 3.37 x 10-5 M

Calculating K for the Test K K K Graph: Equation Determined by Calculator Y = 3945X 0.021
Calibration Curve for Absorbance of FeSCN2+

= = =

[FeSCN2+] / [Fe3+] x [SCN1-] [3.37 x 10-5 M FeSCN2+] / [9.66 x 10-4 M Fe3+] x [1.66 x 10-4 M SCN1-] 210.2 = 210 M-1S-1

0.500
Absorbance at 450 nm

0.400 0.300 0.200 0.100 0.000 2.00 4.00 6.00 8.00 10.00 12.00 14.00
Molar Concentration of FeSCN2+ (x 10-5)
Absorbance Linear regression for Absorbance