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JORDI LABS Integrity. Material Solutions.

Uncompromising
Analytical Services

Polymer Solubility Index

Jordi Labs was founded in 1980 to provide the highest quality analytical services and polymer based HPLC columns and packing media in the industry. Our customers come from a diverse background, including the polymer, pharmaceutical and specialty chemical industries. It is our goal to help our customers overcome their analytical challenges by providing excellent products and personal assistance from our highly trained staff. Our reputation has been built on the principal of outstanding customer service, quick turnaround times and expert analysis for every job. Our capabilities and available techniques service a much larger customer base than just the polymer industry. We strive to work closely with all of our clients to solve any and all analytical problems.

Products

Jordi offers a full line of products to support the chromatography industry such as Gel Permeation Chromatography (GPC) columns, Solid Phase Extraction (SPE) products and Bulk Packing Material. We have developed and consistently provide the highest quality divinylbenzene polymer packing materials in the industry. The Jordi Columns, SPE products and Bulk Packing materials are made from highly crosslinked polymeric resins resulting in long column life, extreme durability in nearly any solvent, pH stability from 0-14, and high temperature tolerance to 150C. Jordi also offers the widest selection of bonded phases and the most favorable pricing.

Problems We Solve
Polymer Analysis Contract Analysis Preparative HPLC Product Formulation Unknown Identification Polymer Filler & Addititves Quantitation HPLC Method Development Product Deformulation HPLC Training and Installation Services Expert Witnessing Good-Bad Comparisons Quantitative Analysis

Techniques We Offer
Particle Analysis Light Microscopy Supplemental Testing Mass Spectroscopy (MS) Gas Chromatography (GC) Fourier Transform Infrared Spectroscopy (FTIR) Nuclear Magnetic Resonance (NMR) Chemical Methods (Titrimetry, Extractions, Etc.) Gel Permeation Chromatography (GPC) Thermal Methods (DSC,TGA,TMA) High Performance Liquid Chromatography (HPLC) Elemental Analysis (PIXE, INAA)

Products
Columns Gel Permeation Chromatography (GPC) Organic Solvent columns Aqueous Solvent Columns Reverse Phase (RP) & Normal Phase (NP) Ion Exchange Guard Columns Solid Phase Extraction (SPE) Neutral Hydrophobic/Hydrophilic Balance Cation Exchange Anion Exchange Bulk Media

Jordi Labs 4 Mill St Bellingham MA 02019 Phone: 508 966 1301 Fax: 508 966 4063 www.jordilabs.com info@jordilabs.com

JORDI LABS Integrity. Material Solutions. Uncompromising


Polymer Solubility Index for GPC Solvents
Polymer
Acenapthylene/MMA Acenapthylene/styrene/acrylic Acetals Acetylene (LMW) Alginate A Acrylamide Acrylamide/Acrylic Acid Acrylics Acrylics(salts) Acrylic Acids Acrylic/Butadiene/Styrene (ABS) Acrylonitrile Acrylonitrile/Butadiene rubber (nitrile rubber) Acrylonitrile/Butadiene/Styrene Acrylonitrile/styrene Acrylonitrile/vinyl chloride Alkyd Resins Alkyl Resins Alkyene Glycols Alkyene Oxide Amides Amide/Imide Amidoamine Amines Amylose Acetate

Polymer Solubility Index

Solvents
THF, DMF THF, DMF HFIP, DMAC TCB, Toluene 1M NaOH in Water Water Water/NaOAc, Water/KH2PO4, DMSO THF, DMF, DMSO, Toluene Water Water/NH4AC+10% Methanol, 1M NaOH in Water THF,DMF DMF DMF, Toluene, TCB THF, DMF, DMSO THF DMSO THF, Toluene, Chloroform, DMAC THF, Chloroform THF, Toluene, TBC, ODCB, Chloroform Chloroform DMF, HFIP DMF, DMSO, DMAC HFIP n-Butylamine THF

Abbreviations
THF=Tetrahydrofuran DMF=Dimethylformamide DMSO=Dimethylsulfoxide HFIP=1,1,1,3,3,3-Hexafluoroisopropanol TCB=1,2,3-Trichlorobenzene ODCB=Ortho Dichlorobenzen DMAC=Dimethylacetamide NMP=N-Methyl Pyrrolidone TFE=Trifluoroethanol

Jordi Labs 4 Mill St Bellingham MA 02019 Phone: 508 966 1301 Fax: 508 966 4063 www.jordilabs.com info@jordilabs.com

JORDI LABS Integrity. Material Solutions. Uncompromising


Polymer
Amylose Butyrate Amylose Propionate Aromatic Anhydride Complex

Polymer Solubility Index

Solvents
THF THF Acetonitrile

Aromatic Polyamide (KEVLAR) Asphalts Asphaltenes


Butene-1 Butyl Rubber (isobutylene/isoprene) Butyl Methacrylate BUNA-N (cured) Butylene Terephthalate (PBT) Butadiene (cis) Butadiene/Acrylic Butaduene/Acrylic Acid/Acrylonitrile Butyl Isocyanate Caprolactam Carrageenan Carbonates Carboxylated Polybutadiene Carboxylated SBR Carboxy Methyl Cellulose Carboxy Methyl Hydroxyethyl Cellulose Carbowaxes Cellulose (Quarternary Amine modified) Cellulose Acetate Cellulose Esters (general) Cellulose Nitrate Cellulose Sulfate Cellulose Trinitrate Chitosan Chlorinated Polyethylene (Chloroprene) (Neoprene)

None THF, DMF, Toluene, TCB, Chloroform, m-Cresol THF, TCB


Toluene, TCB, ODCB Toluene, TCB, ODCB DMF Toluene-limited HFIP, m-Cresol THF, Toluene, TBC, ODCB DMF, Toluene DMF, Toluene THF HFIP, m-Cresol 0.5 to 1M NaOH in Water THF, TCB, ODCB THF DMF Water, DMF, 0.1 to 1.0M NaOH in Water Water, DMF, DMSO DMF, TCB, ODCB, Chloroform Water, DMSO THF, DMF, DMSO, Acetone/Water THF THF, DMF 8:2 0.1M NaOH/DMSO THF 2% Acetic Acid in Water + 0.1M NaCI in Water Toluene, TCB

Jordi Labs 4 Mill St Bellingham MA 02019 Phone: 508 966 1301 Fax: 508 966 4063 www.jordilabs.com info@jordilabs.com

JORDI LABS Integrity. Material Solutions. Uncompromising


Polymer
Chlorinated Rubber Coal Liquids Coal Tar Pitches Cooking Oil(Soybean) Corn Syrup Dextrans Dialkyl Phthalate Dimethylsiloxanes Dodecyl Acrylate Dioxalane Drying Oils Epichlorohydran Epoxy Resins Esters Ethers Ether Ether Ketone (PEEK) Ether Sulfone Ethyl Acrylates Ethylene Ethylene/Acrylic Acid (Na+ Form) Ethylene/Acrylic Acid (Zn+ Form) Ethylene Glycol Ethyleneimine Ethylene/n-hexane Ethylene/Maleic Anhydride Ethylene/Methyl Acrylate Ethylene Oxide Ethylene Oxide/Butylene Terephthalate Ethylene/Propylene and EPR Ethylene/Propylene/Diamine (EPDM Rubber) Ethylene Terephthalate (PET)

Polymer Solubility Index

Solvents
Toluene, TCB TCB Toluene, TCB THF Water, 8:2 Water /DMSO Water, DMSO, 1N NaOH in Water Toluene, TCB, ODCB, Chloroform Toluene, TCB, ODCB, Chloroform THF THF THF, DMF, Toluene, TCB, ODCB, Chloroform TCB THF, Toluene, Chloroform THF, DMF, Toluene, TCB, HFIP, m-Cresol THF, DMF, Toluene, HFIP 3:1 Chloroform/Dichloroacetic Acid DMF, NMP DMF, Toluene, ODCB, HFIP, m-Cresol TCB, ODCB TCB Acidify with Glacial Acetic Acid, then TCB Water, THF, DMF, DMAC 95:5 Water/Acetic Acid TCB DMSO TCB Ethylene Oxide HFIP TCB, ODCB TCB HFIP, m-Cresol

Jordi Labs 4 Mill St Bellingham MA 02019 Phone: 508 966 1301 Fax: 508 966 4063 www.jordilabs.com info@jordilabs.com

JORDI LABS Integrity. Material Solutions. Uncompromising


Polymer
Ethylene/ Vinyl Acetate (EVA) Ethylvinyl Alcohol/Maleic Anhydride Fatty Acids Fluoroelastomer Furfuryl Alcohol Gelatins Gutta Percha (trans-1,4-isoprene) Glycerides Glycol/Glycerine Polyesters Glycols Glyconates Glycolic Acid Gum Arabic Hot Melt Adhesives Hyaluronic Acid Hydroxyethyl Cellulose Hydroxyethyl Methacrylate (HEMA) Hydroxyethyl Starch Hydroxypropyl Methyl Cellulose Isoprene (cis-1,4) (Natural Rubber) Isoprene (Trans-1,4) Isobornyl Methacrylate/Hydroxyethyl Methacrylate Isobutylene (Isobutene) Isocyanates Imides Imic Acid Isopropylidene-1,4-phenylene KELVAR (Aromatic Polyamide) KYNAR (Vinylidene Fluoride) KRATON Rubber (Styrene/Butadiene Elastomer)

Polymer Solubility Index

Solvents
TCB DMSO THF, TCB, ODCB, Chloroform DMAC THF, TCB, ODCB, Chloroform Water, DMSO, 80:20 Water/DMSO+10% Butylamine Toluene, TCB, Chloroform THF, TCB, ODCB DMF, DMF + 0.005% LiBr Water, THF, DMF, Toluene, TCB, ODCB HFIP HFIP 8:2 0.1M NaOH in Water/DMSO TCB 0.1N HN03, 1M NaOH/20% DMSO DMSO Water, THF, DMF, Methanol DMSO DMSO THF Toluene, TCB THF THF, Toluene, TCB THF, DMF, Toluene, Chloroform DMF, DMAC NMP THF None DMF, DMSO, DMAC, Cyclohexanone THF, TCB

Jordi Labs 4 Mill St Bellingham MA 02019 Phone: 508 966 1301 Fax: 508 966 4063 www.jordilabs.com info@jordilabs.com

JORDI LABS Integrity. Material Solutions. Uncompromising


Polymer
Leucine/Methyl Glutamate Lignins Lignin Sulfonates Lipids Melamine Resin Methacrylates Methacrylic Acid Methyl Cellulose Methyl Methacrylate Methyl Methacrylate/Styrene Methyl Pentane Methyl Vinyl Ether/Maleic Anhydride Methyl Siloxane Napthalene Sulfonate/ Formaldehyde Condensate Natural Rubber (Cis-1,4 Isoprene) Neoprene NORYL (Styrene/Phenylene Oxide) Novolak (Phenol/formaldehyde resin) Nylon 4,6,6/6,10,12, etc. Octadecyl Methacrylate Octadecyl Vinyl Ether Oxycarbonyloxy-1,4-phenylene Oxyethylene (20) Sorbitan mono-oleate Oxymaleoyloxyhexamethylene Oxymethylene Oxypropylene Oxysuccinyloxyhexamethylene Paper Pulp Phenol Phenol/Formaldehyde Resins

Polymer Solubility Index

Solvents
HFIP Water, THF, DMSO, 1M NaOH in Water Water, DMSO THF, Dichloromethane THF, TCB, HFIP, m-Cresol, TFE THF, DMF, TCB 8:2 0.1M NaOH in Water/DMSO Water, DMSO THF, DMF, Toluene, HFIP, m-Cresol, DMAC THF, Toluene, ODCB, Chloroform TCB 0.1 to 1.0M NaOH in Water TCB Water, DMSO THF Toluene, TCB TCB THF with 2% Methanol, 75:25 Methanol/0.1M NaOH HFIP, m-Cresol DMF, DMSO THF THF DMSO THF HFIP, DMAC THF THF Water, DMSO (HOT) DMF THF, DMF, TCB, 1.0M NaOH/Methanol

Jordi Labs 4 Mill St Bellingham MA 02019 Phone: 508 966 1301 Fax: 508 966 4063 www.jordilabs.com info@jordilabs.com

JORDI LABS Integrity. Material Solutions. Uncompromising


Polymer
Phenolics (NOVOLAC) Phenylene Oxide Phenylene Sulfide Photo Resists Pitch Polyols Propylene Propylene/n-butene Propylene Oxide Pullulan Rubbers(Chlorinated) (Neoprene) Rubbers (Uncured) Saccharides Silicones Siloxanes Starch Styrene Styrene/Acrylonitrile Styrene/Butadiene Rubber (SBR) (KRATON) Styrene/Butadiene Rubber (SBR) carboxcylated Styrene/Isoprene Styrene/Maleic Anhydride Styrene/Monoethyl Maleate Styrene/Phenylene Oxide Styrene Sulfonate Succinamide Sulfonates Sulfonated Styrene/Maleic Anhydride Sulfone Sulfur/Dicyclopentadiene (SULPHLEX)

Polymer Solubility Index

Solvents
THF, 95:5 THF/Methanol, Chloroform TCB 1-Chloro Naphthalene @ 235 oC THF, DMF, m-Cresol TCB THF, DMF TCB, ODCB TCB, ODCB TCB, ODCB, DMAC 8:2 0.1M NaOH/DMSO Toluene, TCB Toluene, TCB, ODCB Water Toluene, TCB, ODCB, Chloroform, Dichloromethane Toluene, Chloroform Water, DMSO THF, DMF, Toluene, TCB, ODCB, Chloroform DMF THF, Toluene, TCB, ODCB DMF THF,Toluene, TCB THF THF TCB Water, DMSO DMF THF 1M NaOH THF, TCB TCB

Jordi Labs 4 Mill St Bellingham MA 02019 Phone: 508 966 1301 Fax: 508 966 4063 www.jordilabs.com info@jordilabs.com

JORDI LABS Integrity. Material Solutions. Uncompromising


Polymer
Tetrafluoroethylene (TEFLON) Trifluorostyrene Urea/Formaldehyde Resins Urethane Urethane (RIM) Vinyl Acetate Vinyl Acetate/Ethylene Vinyl Acetate/Ethylene/Acrylate Vinyl Acetate Phthalate Vinyl Alcohol Vinyl Alcohol/Vinyl Acetate Vinyl Bromide Vinyl Butyral Vinyl Carbazol Vinyl Chloride (PVC) Vinyl Chloride/Vinyl Acetate/Maleic Acid Vinyl Esters Vinyl Ferrocene Vinyl Fluoride Vinyl Formal Vinylidene Vinylidene Fluoride (KYNAR) Vinylidene Fluoride/Hexafluoropropylene (VITON) Vinyl Methyl Ethers Vinyl Pyridine Vinyl Pyrrolidone Vinyl Pyrrolidone/Vinyl Acetate Waxes (Parrafin) Waxes (Microcrystalline)

Polymer Solubility Index

Solvents
None THF DMF, HFIP, m-Cresol THF, DMF, Toluene, HFIP, DMSO, Chloroform m-Cresol extracts only! THF, DMF, ODCB DMF DMF THF Water, THF, DMF, DMSO DMF, DMSO THF THF, DMF THF THF, Toluene DMF THF, DMF THF DMF THF DMAC DMF, DMSO, DMAC, NMP THF, Toluene THF, DMF 97:3 DMF/n-Butylamine Water, DMF, DMSO, NMP DMF, DMSO THF, DMF, Toluene, TCB, ODCB, Chloroform TCB, ODCB

Jordi Labs 4 Mill St Bellingham MA 02019 Phone: 508 966 1301 Fax: 508 966 4063 www.jordilabs.com info@jordilabs.com

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