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Assisgnment II 1.

The angle between the tetrahedral bonds of diamond is the same as the angle between the body diagonals of a cubic. Use elementary vector analysis to find the value of the angle? 2. Show that the c/a ratio for an ideal hexagonal close packed structure is 1.633. 3. Prove that the following conditions are nothing but various staements of bragg condition 2dsin = n, k = G; 2k.G = G2 4. Show that the volume of the first Brillouin zone is (2) 3/ V, where V is the volume of a crystal primitive cell. 5. For the Hydregon atom in its groud state, the number density is n (r) = ( a03)-1 exp(-2r/a0) where a0 is the Bohr radius. Show that the form factor is fg = 16/ (4+G2a02)2. 6. Find strycture factor of a square lattice with one basis and sketch reciprocal lattice with possible spots in the diffraction pattern.

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