1

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 1

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Overall

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Liquid Phase

0.0000

1.0000

(F)

23.00 *

23.00

(psia)

14.50 *

14.50

Molar Flow

(lbmole/hr)

2205 *

16

Mass Flow

(lb/hr)

17

Std Ideal Liq Vol Flow

18

Molar Enthalpy

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

7.046e+004

2205
7.046e+004

(barrel/day)

6431

6431

(Btu/lbmole)

-1.060e+005

-1.060e+005

(Btu/lbmole-F)

-83.37

-83.37

(Btu/hr)

-2.338e+008

-2.338e+008

6456 *

(barrel/day)

22

6456

PROPERTIES

23
24

Overall

Liquid Phase

25

Molecular Weight

26

Molar Density

27

Mass Density

28

Act. Volume Flow

29

Mass Enthalpy

30
31
32

Mass Heat Capacity

33

Lower Heating Value

34

Mass Lower Heating Value

35

Phase Fraction [Vol. Basis]

36

Phase Fraction [Mass Basis]

37

Partial Pressure of CO2

38
39
40

Avg. Liq. Density

41

Specific Heat

42

Std. Gas Flow

43

Std. Ideal Liq. Mass Density

44

Act. Liq. Flow

45

Z Factor

46

Watson K

47

User Property

48

Partial Pressure of H2S

49

Cp/(Cp - R)

1.097

1.097

50

Cp/Cv

1.235

1.235

51

Heat of Vap.

52

Kinematic Viscosity

53

Liq. Mass Density (Std. Cond)

54

Liq. Vol. Flow (Std. Cond)

55

Liquid Fraction

56

Molar Volume

57

Mass Heat of Vap.

58

Phase Fraction [Molar Basis]

59

Surface Tension

60

Thermal Conductivity

61

Viscosity

62

Cv (Semi-Ideal)

63

Mass Cv (Semi-Ideal)

64

Cv

65

Mass Cv

66

Cv (Ent. Method)

67

Mass Cv (Ent. Method)

68

Cp/Cv (Ent. Method)

69

Hyprotech Ltd.

31.96

31.96

(lbmole/ft3)

1.501

1.501

(lb/ft3)

47.97

47.97

(barrel/day)

6278

6278

(Btu/lb)

-3318

-3318

Mass Entropy

(Btu/lb-F)

-2.609

-2.609

Heat Capacity

(Btu/lbmole-F)

22.55

22.55

(Btu/lb-F)

0.7056

0.7056

(Btu/lbmole)

2.816e+005

2.816e+005

(Btu/lb)

8810

8810
1.000

2.122e-314

1.000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

Act. Gas Flow

(ACFM)

Licensed to: LEGENDS

(lbmole/ft3)

1.465

1.465

(Btu/lbmole-F)

22.55

22.55

(MMSCFD)

20.04

20.04

(lb/ft3)

46.83

46.83

(USGPM)

183.1

183.1

1.865e-003

1.865e-003

11.26

11.26

(psia)

0.0000

(Btu/lbmole)

1.646e+004

(cSt)

0.5151

0.5151

(lb/ft3)

46.65

46.65

(barrel/day)

6456

6456

1.000

1.000

(ft3/lbmole)

0.6662

0.6662

(Btu/lb)

515.1
0.0000

1.0000

(dyne/cm)

44.50

44.50

(Btu/hr-ft-F)

0.1664

0.1664
0.3958

(cP)

0.3958

(Btu/lbmole-F)

20.56

20.56

(Btu/lb-F)

0.6435

0.6435

(Btu/lbmole-F)

18.26

18.26

(Btu/lb-F)

0.5715

0.5715

(Btu/lbmole-F)

3601

3601

(Btu/lb-F)

112.7

112.7

6.262e-003

6.262e-003

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 1 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 1 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Liquid Phase

12

Reid VP at 37.8 C

(psia)

78.43

78.43

13

True VP at 37.8 C

(psia)

49.22

49.22

14

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

6456

6456

15

Viscosity Index

-2.312

-2.312

16

COMPOSITION

17
18

Overall Phase

19
20

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

21
22

Methanol

23

Ethanol

24

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

429.9034 *

0.1950 *

13774.9217 *

0.1955 *

1185.3515 *

0.1843 *

6.5239 *

0.0030 *

300.5544 *

0.0043 *

25.8547 *

0.0040 *

diM-Ether

874.3342 *

0.3966 *

40279.7014 *

0.5717 *

4114.6604 *

0.6398 *

25

H2O

893.8386 *

0.4054 *

16102.5914 *

0.2285 *

1104.8151 *

0.1718 *

26

Total

1.0000

70457.7689

1.0000

6430.6817

1.0000

2204.6000

27

Liquid Phase

28
29

COMPONENTS

MOLAR FLOW
(lbmole/hr)

30
31

Methanol

32

Ethanol

33

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

429.9034

0.1950

13774.9217

0.1955

1185.3515

0.1843

6.5239

0.0030

300.5544

0.0043

25.8547

0.0040

diM-Ether

874.3342

0.3966

40279.7014

0.5717

4114.6604

0.6398

34

H2O

893.8386

0.4054

16102.5914

0.2285

1104.8151

0.1718

35

Total

2204.6000

1.0000

70457.7689

1.0000

6430.6817

1.0000

36

K VALUE

37
38

COMPONENTS

39

MIXED

LIGHT

HEAVY

Methanol

0.0000

0.0000

40

Ethanol

0.0000

0.0000

41

diM-Ether

0.0000

0.0000

42

H2O

0.0000

0.0000

43

UNIT OPERATIONS

44
45
46

FEED TO

PRODUCT FROM

Pump:

LOGICAL CONNECTION

P-100

47

UTILITIES

48
49

( No utilities reference this stream )

50

PROCESS UTILITY

51
52
53

DYNAMICS

54
55

Pressure Specification

(Active):

56

Flow Specification

(Active)

57

14.50 psia *
Molar:

2205 lbmole/hr *

Mass:

7.046e+004 lb/hr

Std Ideal Liq Volume:6431 barrel/day

User Variables

58
59

NOTES

60
61
62

Description

63
64
65
66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 2 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 2

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Overall

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Liquid Phase

0.0000

1.0000

(F)

23.87

23.87

(psia)

152.3

152.3

Molar Flow

(lbmole/hr)

2205

2205

16

Mass Flow

(lb/hr)

7.046e+004

7.046e+004

17

Std Ideal Liq Vol Flow

18

Molar Enthalpy

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

(barrel/day)

6431

6431

(Btu/lbmole)

-1.060e+005

-1.060e+005

(Btu/lbmole-F)

-80.54

-80.54

(Btu/hr)

-2.337e+008

-2.337e+008

6456 *

(barrel/day)

22

6456

PROPERTIES

23
24

Overall

Liquid Phase

25

Molecular Weight

26

Molar Density

27

Mass Density

28

Act. Volume Flow

29

Mass Enthalpy

30
31
32

Mass Heat Capacity

33

Lower Heating Value

34

Mass Lower Heating Value

35

Phase Fraction [Vol. Basis]

36

Phase Fraction [Mass Basis]

37

Partial Pressure of CO2

38
39
40

Avg. Liq. Density

41

Specific Heat

42

Std. Gas Flow

43

Std. Ideal Liq. Mass Density

44

Act. Liq. Flow

45

Z Factor

46

Watson K

47

User Property

48

Partial Pressure of H2S

49

Cp/(Cp - R)

1.097

1.097

50

Cp/Cv

1.233

1.233

51

Heat of Vap.

52

Kinematic Viscosity

53

Liq. Mass Density (Std. Cond)

54

Liq. Vol. Flow (Std. Cond)

55

Liquid Fraction

56

Molar Volume

57

Mass Heat of Vap.

58

Phase Fraction [Molar Basis]

59

Surface Tension

60

Thermal Conductivity

61

Viscosity

62

Cv (Semi-Ideal)

63

Mass Cv (Semi-Ideal)

64

Cv

65

Mass Cv

66

Cv (Ent. Method)

67

Mass Cv (Ent. Method)

68

Cp/Cv (Ent. Method)

69

Fluid Package:

31.96

31.96

(lbmole/ft3)

1.502

1.502

(lb/ft3)

47.99

47.99

(barrel/day)

6275

6275

(Btu/lb)

-3317

-3317

Mass Entropy

(Btu/lb-F)

-2.520

-2.520

Heat Capacity

(Btu/lbmole-F)

22.56

22.56

(Btu/lb-F)

0.7059

0.7059

(Btu/lbmole)

2.816e+005

2.816e+005

(Btu/lb)

8810

8810
1.000

2.122e-314

1.000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

Act. Gas Flow

(ACFM)

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

1.465

1.465

(Btu/lbmole-F)

22.56

22.56

(MMSCFD)

20.04

20.04

(lb/ft3)

46.83

46.83

(USGPM)

183.0

183.0

1.954e-002

1.954e-002

11.26

11.26

(psia)

0.0000

(Btu/lbmole)

1.426e+004

(cSt)

0.5117

0.5117

(lb/ft3)

46.65

46.65

(barrel/day)

6456

6456

1.000

1.000

(ft3/lbmole)

0.6659

0.6659

(Btu/lb)

446.3
0.0000

1.0000

(dyne/cm)

44.43

44.43

(Btu/hr-ft-F)

0.1664

0.1664
0.3934

(cP)

0.3934

(Btu/lbmole-F)

20.58

20.58

(Btu/lb-F)

0.6438

0.6438

(Btu/lbmole-F)

18.30

18.30

(Btu/lb-F)

0.5727

0.5727

(Btu/lbmole-F)

384.7

384.7

(Btu/lb-F)

12.04

12.04

5.864e-002

5.864e-002

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 3 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 2 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Liquid Phase

12

Reid VP at 37.8 C

(psia)

78.43

78.43

13

True VP at 37.8 C

(psia)

49.22

49.22

14

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

6456

6456

15

Viscosity Index

-2.328

-2.328

16

COMPOSITION

17
18

Overall Phase

19
20

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

21
22

Methanol

23

Ethanol

24

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

429.9034

0.1950

13774.9217

0.1955

1185.3515

0.1843

6.5239

0.0030

300.5544

0.0043

25.8547

0.0040

diM-Ether

874.3342

0.3966

40279.7014

0.5717

4114.6604

0.6398

25

H2O

893.8386

0.4054

16102.5914

0.2285

1104.8151

0.1718

26

Total

2204.6000

1.0000

70457.7689

1.0000

6430.6817

1.0000

27

Liquid Phase

28
29

COMPONENTS

MOLAR FLOW
(lbmole/hr)

30
31

Methanol

32

Ethanol

33

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

429.9034

0.1950

13774.9217

0.1955

1185.3515

0.1843

6.5239

0.0030

300.5544

0.0043

25.8547

0.0040

diM-Ether

874.3342

0.3966

40279.7014

0.5717

4114.6604

0.6398

34

H2O

893.8386

0.4054

16102.5914

0.2285

1104.8151

0.1718

35

Total

2204.6000

1.0000

70457.7689

1.0000

6430.6817

1.0000

36

K VALUE

37
38

COMPONENTS

39

MIXED

LIGHT

HEAVY

Methanol

0.0000

0.0000

40

Ethanol

0.0000

0.0000

41

diM-Ether

0.0000

0.0000

42

H2O

0.0000

0.0000

43

UNIT OPERATIONS

44
45
46

FEED TO
Mixer:

PRODUCT FROM
MIX-100

47

Pump:

LOGICAL CONNECTION
P-100

UTILITIES

48
49

( No utilities reference this stream )

50

PROCESS UTILITY

51
52
53

DYNAMICS

54
55

Pressure Specification

(Inactive)

56

Flow Specification

(Inactive) Molar:

57

152.3 psia
2205 lbmole/hr

Mass:

7.046e+004 lb/hr

Std Ideal Liq Volume:6431 barrel/day

User Variables

58
59

NOTES

60
61
62

Description

63
64
65
66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 4 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 3

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Overall

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Liquid Phase

0.0000

1.0000

(F)

25.98

25.98

(psia)

152.3

152.3

Molar Flow

(lbmole/hr)

2260

2260

16

Mass Flow

(lb/hr)

7.228e+004

7.228e+004

17

Std Ideal Liq Vol Flow

18

Molar Enthalpy

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

(barrel/day)

6587

6587

(Btu/lbmole)

-1.059e+005

-1.059e+005

(Btu/lbmole-F)

-78.13

-78.13

(Btu/hr)

-2.395e+008

-2.395e+008

6612 *

(barrel/day)

22

6612

PROPERTIES

23
24

Overall

Liquid Phase

25

Molecular Weight

26

Molar Density

27

Mass Density

28

Act. Volume Flow

29

Mass Enthalpy

30
31
32

Mass Heat Capacity

33

Lower Heating Value

34

Mass Lower Heating Value

35

Phase Fraction [Vol. Basis]

36

Phase Fraction [Mass Basis]

37

Partial Pressure of CO2

38
39
40

Avg. Liq. Density

41

Specific Heat

42

Std. Gas Flow

43

Std. Ideal Liq. Mass Density

44

Act. Liq. Flow

45

Z Factor

46

Watson K

47

User Property

48

Partial Pressure of H2S

49

Cp/(Cp - R)

1.096

1.096

50

Cp/Cv

1.233

1.233

51

Heat of Vap.

52

Kinematic Viscosity

53

Liq. Mass Density (Std. Cond)

54

Liq. Vol. Flow (Std. Cond)

55

Liquid Fraction

56

Molar Volume

57

Mass Heat of Vap.

58

Phase Fraction [Molar Basis]

59

Surface Tension

60

Thermal Conductivity

61

Viscosity

62

Cv (Semi-Ideal)

63

Mass Cv (Semi-Ideal)

64

Cv

65

Mass Cv

66

Cv (Ent. Method)

67

Mass Cv (Ent. Method)

68

Cp/Cv (Ent. Method)

69

Fluid Package:

31.98

31.98

(lbmole/ft3)

1.501

1.501

(lb/ft3)

47.99

47.99

(barrel/day)

6438

6438

(Btu/lb)

-3313

-3313

Mass Entropy

(Btu/lb-F)

-2.443

-2.443

Heat Capacity

(Btu/lbmole-F)

22.71

22.71

(Btu/lb-F)

0.7101

0.7101

(Btu/lbmole)

2.817e+005

2.817e+005

(Btu/lb)

8808

8808
1.000

2.122e-314

1.000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

Act. Gas Flow

(ACFM)

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

1.467

1.467

(Btu/lbmole-F)

22.71

22.71

(MMSCFD)

20.55

20.55

(lb/ft3)

46.90

46.90

(USGPM)

187.8

187.8

1.947e-002

1.947e-002

11.25

11.25

(psia)

0.0000

(Btu/lbmole)

1.424e+004

(cSt)

0.5142

0.5142

(lb/ft3)

46.73

46.73

(barrel/day)

6612

6612

1.000

1.000

(ft3/lbmole)

0.6663

0.6663

(Btu/lb)

445.2
0.0000

1.0000

(dyne/cm)

43.98

43.98

(Btu/hr-ft-F)

0.1648

0.1648
0.3953

(cP)

0.3953

(Btu/lbmole-F)

20.72

20.72

(Btu/lb-F)

0.6480

0.6480

(Btu/lbmole-F)

18.42

18.42

(Btu/lb-F)

0.5760

0.5760

(Btu/lbmole-F)

393.9

393.9

(Btu/lb-F)

12.32

12.32

5.765e-002

5.765e-002

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 5 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 3 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Liquid Phase

12

Reid VP at 37.8 C

(psia)

75.07

75.07

13

True VP at 37.8 C

(psia)

47.83

47.83

14

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

6612

6612

15

Viscosity Index

-2.314

-2.314

16

COMPOSITION

17
18

Overall Phase

19
20

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

21
22

Methanol

23

Ethanol

24

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

482.9714

0.2137

15475.3228

0.2141

1331.6734

0.2022

9.0619

0.0040

417.4806

0.0058

35.9131

0.0055

diM-Ether

874.3540

0.3868

40280.6140

0.5573

4114.7537

0.6246

25

H2O

894.0539

0.3955

16106.4702

0.2228

1105.0812

0.1678

26

Total

2260.4412

1.0000

72279.8876

1.0000

6587.4213

1.0000

27

Liquid Phase

28
29

COMPONENTS

MOLAR FLOW
(lbmole/hr)

30
31

Methanol

32

Ethanol

33

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

482.9714

0.2137

15475.3228

0.2141

1331.6734

0.2022

9.0619

0.0040

417.4806

0.0058

35.9131

0.0055

diM-Ether

874.3540

0.3868

40280.6140

0.5573

4114.7537

0.6246

34

H2O

894.0539

0.3955

16106.4702

0.2228

1105.0812

0.1678

35

Total

2260.4412

1.0000

72279.8876

1.0000

6587.4213

1.0000

36

K VALUE

37
38

COMPONENTS

39

MIXED

LIGHT

HEAVY

Methanol

0.0000

0.0000

40

Ethanol

0.0000

0.0000

41

diM-Ether

0.0000

0.0000

42

H2O

0.0000

0.0000

43

UNIT OPERATIONS

44
45
46

FEED TO

PRODUCT FROM

Heater:

E-100

47

Mixer:

LOGICAL CONNECTION
MIX-100

UTILITIES

48
49

( No utilities reference this stream )

50

PROCESS UTILITY

51
52
53

DYNAMICS

54
55

Pressure Specification

(Inactive)

56

Flow Specification

(Inactive) Molar:

57

152.3 psia
2260 lbmole/hr

Mass:

7.228e+004 lb/hr

Std Ideal Liq Volume:6587 barrel/day

User Variables

58
59

NOTES

60
61
62

Description

63
64
65
66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 6 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 4

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Overall

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Vapour Phase

0.0406

Liquid Phase

0.0406

0.9594

192.2 *

192.2

192.2

(psia)

152.3

152.3

152.3

Molar Flow

(lbmole/hr)

2260

91.78

2169

16

Mass Flow

(lb/hr)

7.228e+004

4070

6.821e+004

17

Std Ideal Liq Vol Flow

18

Molar Enthalpy

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

(F)

(barrel/day)

6587

411.2

6176

(Btu/lbmole)

-1.016e+005

-7.858e+004

-1.025e+005

(Btu/lbmole-F)

26.93

45.00

26.17

(Btu/hr)

-2.296e+008

-7.212e+006

-2.224e+008

441.1

6185

6612 *

(barrel/day)

22

PROPERTIES

23
24

Overall

25

Molecular Weight

26

Molar Density

27

Mass Density

28

Act. Volume Flow

29

Mass Enthalpy

30
31
32

Mass Heat Capacity

33

Lower Heating Value

34

Mass Lower Heating Value

35

Phase Fraction [Vol. Basis]

36

Phase Fraction [Mass Basis]

37

Partial Pressure of CO2

38
39
40

Avg. Liq. Density

41

Specific Heat

42

Std. Gas Flow

43

Std. Ideal Liq. Mass Density

44

Act. Liq. Flow

45

Z Factor

46

Watson K

47

User Property

48

Partial Pressure of H2S

49

Cp/(Cp - R)

50

Cp/Cv

51

Heat of Vap.

52

Kinematic Viscosity

53

Liq. Mass Density (Std. Cond)

54

Liq. Vol. Flow (Std. Cond)

55

Liquid Fraction

56

Molar Volume

57

Mass Heat of Vap.

58

Phase Fraction [Molar Basis]

59

Surface Tension

60

Thermal Conductivity

61

Viscosity

62

Cv (Semi-Ideal)

63

Mass Cv (Semi-Ideal)

64

Cv

65

Mass Cv

66

Cv (Ent. Method)

67

Mass Cv (Ent. Method)

68

Cp/Cv (Ent. Method)

69

Fluid Package:

Vapour Phase

Liquid Phase

31.98

44.34

31.45

(lbmole/ft3)

0.3861

2.177e-002

1.324

(lb/ft3)

12.35

0.9654

41.63

(barrel/day)

2.502e+004

1.802e+004

7004

(Btu/lb)

-3176

-1772

-3260

Mass Entropy

(Btu/lb-F)

0.8422

1.015

0.8319

Heat Capacity

(Btu/lbmole-F)

26.74

17.24

27.14

(Btu/lb-F)

0.8362

0.3889

0.8629

(Btu/lbmole)

2.817e+005

5.354e+005

2.709e+005

(Btu/lb)

8808

1.207e+004

8614

6.243e-002

6.243e-002

0.9376

5.631e-002

5.631e-002

0.9437

0.0000

0.0000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

Act. Gas Flow

(ACFM)

Hyprotech Ltd.
Licensed to: LEGENDS

70.26

(lbmole/ft3)

1.467

0.9540

1.501

(Btu/lbmole-F)

26.74

17.24

27.14

(MMSCFD)

20.55

0.8343

19.71

(lb/ft3)

46.90

42.30

47.21

(USGPM)

204.3
1.000

1.645e-002

11.37

11.24

1.080

1.130

1.079

1.005

1.130

1.079

11.25
(psia)

(Btu/lbmole)

204.3

0.0000

1.424e+004

(cSt)

0.6979

0.2076

(lb/ft3)

46.73

39.44

47.15

(barrel/day)

6612

441.1

6185

0.9594

0.0000

1.000

(ft3/lbmole)

2.590

45.94

0.7555

(Btu/lb)

445.2
0.0406

0.9594

1.297e-002

0.1526

1.079e-002

0.1384

0.0406
(dyne/cm)

30.60

(Btu/hr-ft-F)
(cP)

30.60

(Btu/lbmole-F)

24.75

15.26

25.15

(Btu/lb-F)

0.7741

0.3441

0.7997

(Btu/lbmole-F)

26.60

15.26

25.15

(Btu/lb-F)

0.8320

0.3441

0.7997

(Btu/lbmole-F)
(Btu/lb-F)

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 7 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 4 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Vapour Phase

Liquid Phase

12

Reid VP at 37.8 C

(psia)

75.07

113.5

72.45

13

True VP at 37.8 C

(psia)

47.83

110.1

45.30

14

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

6626

441.1

6185

15

Viscosity Index

16

COMPOSITION

17
18

Overall Phase

19
20

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

21
22

Methanol

23

Ethanol

24

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0406

LIQUID VOLUME
FRACTION

482.9714

0.2137

15475.3228

0.2141

1331.6734

0.2022

9.0619

0.0040

417.4806

0.0058

35.9131

0.0055

diM-Ether

874.3540

0.3868

40280.6140

0.5573

4114.7537

0.6246

25

H2O

894.0539

0.3955

16106.4702

0.2228

1105.0812

0.1678

26

Total

2260.4412

1.0000

72279.8876

1.0000

6587.4213

1.0000

27

Vapour Phase

28
29

COMPONENTS

MOLAR FLOW
(lbmole/hr)

30

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

4.060e-002

LIQUID VOLUME
FRACTION

31

Methanol

4.8205

0.0525

154.4595

0.0380

13.2915

0.0323

32

Ethanol

0.0667

0.0007

3.0743

0.0008

0.2645

0.0006

33

diM-Ether

83.6574

0.9115

3854.0145

0.9470

393.6961

0.9573

34

H2O

3.2319

0.0352

58.2234

0.0143

3.9948

0.0097

35

Total

91.7766

1.0000

4069.7718

1.0000

411.2468

1.0000

36

Liquid Phase

37
38

COMPONENTS

MOLAR FLOW
(lbmole/hr)

39
40

Methanol

41

Ethanol

42

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.9594

LIQUID VOLUME
FRACTION

478.1509

0.2205

15320.8632

0.2246

1318.3820

0.2135

8.9952

0.0041

414.4063

0.0061

35.6486

0.0058

diM-Ether

790.6965

0.3646

36426.5995

0.5340

3721.0576

0.6025

43

H2O

890.8219

0.4108

16048.2468

0.2353

1101.0864

0.1783

44

Total

2168.6645

1.0000

68210.1158

1.0000

6176.1746

1.0000

45

K VALUE

46
47

COMPONENTS

48

MIXED

LIGHT

HEAVY

Methanol

0.2382

0.2382

49

Ethanol

0.1753

0.1753

50

diM-Ether

2.500

2.500

51

H2O

8.573e-002

8.573e-002

52

UNIT OPERATIONS

53
54
55

FEED TO
Equilibrium Reactor:

PRODUCT FROM
ERV-100

56

Heater:

LOGICAL CONNECTION
E-100

UTILITIES

57
58

( No utilities reference this stream )

59

PROCESS UTILITY

60
61
62

DYNAMICS

63
64

Pressure Specification

(Inactive)

65

Flow Specification

(Inactive) Molar:

66

2260 lbmole/hr

Mass:

7.228e+004 lb/hr

Std Ideal Liq Volume:6587 barrel/day

User Variables

67

NOTES

68
69

152.3 psia

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 8 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 4 (continued)

7
8

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

NOTES

9
10
11

Description

12
13
14

Material Stream: 5

15
16
17

CONDITIONS

18
19

Overall

20

Vapour / Phase Fraction

21

Temperature:

22

Pressure:

23

Molar Flow

24

Mass Flow

25

Std Ideal Liq Vol Flow

26

Molar Enthalpy

27

Molar Entropy

28

Heat Flow

29

Liq Vol Flow @Std Cond

Vapour Phase

1.0000

0.0000

248.0 *

248.0

248.0

(psia)

152.3

152.3

152.3

(lbmole/hr)

1218

1218

0.0000
0.0000

(F)

(lb/hr)

4.963e+004

4.963e+004

(barrel/day)

4915

4915

0.0000

(Btu/lbmole)

-8.105e+004

-8.105e+004

-1.144e+005

(Btu/lbmole-F)

44.88

44.88

13.25

(Btu/hr)

-9.870e+007

-9.870e+007

0.0000

5177

0.0000

5177 *

(barrel/day)

30

PROPERTIES

31
32

Overall

33

Molecular Weight

34

Molar Density

35

Mass Density

36

Act. Volume Flow

37

Mass Enthalpy

38

Mass Entropy

39

Heat Capacity

(Btu/lbmole-F)

40

Mass Heat Capacity

(Btu/lb-F)

41

Lower Heating Value

(Btu/lbmole)

42

Mass Lower Heating Value

(Btu/lb)

43

Phase Fraction [Vol. Basis]

44

Phase Fraction [Mass Basis]

45

Partial Pressure of CO2

46
47
48

Avg. Liq. Density

49

Specific Heat

50

Std. Gas Flow

51

Std. Ideal Liq. Mass Density

52

Act. Liq. Flow

53

Z Factor

54

Watson K

55

User Property

56

Partial Pressure of H2S

57

Cp/(Cp - R)

58

Cp/Cv

59

Heat of Vap.

60

Kinematic Viscosity

61

Liq. Mass Density (Std. Cond)

62

Liq. Vol. Flow (Std. Cond)

63

Liquid Fraction

64

Molar Volume

65

Mass Heat of Vap.

66

Phase Fraction [Molar Basis]

67

Surface Tension

68

Thermal Conductivity

69

Aqueous Phase

1.0000

Vapour Phase
40.75

21.72

(lbmole/ft3)

2.005e-002

2.005e-002

2.335

(lb/ft3)

0.8173

0.8173

50.73

(barrel/day)

2.596e+005

2.596e+005

0.0000

(Btu/lb)

-1989

-1989

-5265

(Btu/lb-F)

1.101

1.101

0.6100

17.07

17.07

23.71

0.4190

0.4190

1.091

4.623e+005

4.623e+005

7.476e+004

1.134e+004

1.134e+004

3442

1.000
4.941e-324

1.000

0.0000

0.0000

0.0000

0.0000

1012

1012

(psia)

0.0000

Cost Based on Flow

(Cost/s)

Act. Gas Flow

(ACFM)

Hyprotech Ltd.
Licensed to: LEGENDS

Aqueous Phase

40.75

(lbmole/ft3)

1.059

1.059

(Btu/lbmole-F)

17.07

17.07

23.71

(MMSCFD)

11.07

11.07

0.0000

(lb/ft3)

43.16

43.16

(USGPM)

0.0000

55.24
0.0000

1.000

8.588e-003

11.37

11.25

1.132

1.132

1.091

1.132

1.132

1.180
0.1966

11.37
(psia)

2.543

0.0000

(Btu/lbmole)

1.161e+004

(cSt)

0.8871

0.8871

(lb/ft3)

40.98

40.98

56.82

(barrel/day)

5177

5177

0.0000

0.0000

0.0000

1.000

49.87

49.87

0.4282

1.0000

1.0000

0.0000

1.477e-002

1.477e-002

0.3081

(ft3/lbmole)
(Btu/lb)

284.9
46.98

(dyne/cm)
(Btu/hr-ft-F)

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 9 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 5 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

12

Viscosity

13

Cv (Semi-Ideal)

14

Mass Cv (Semi-Ideal)

15

Cv

16

Mass Cv

17

Cv (Ent. Method)

18

Mass Cv (Ent. Method)

19

Cp/Cv (Ent. Method)

20

Reid VP at 37.8 C

21

True VP at 37.8 C

Vapour Phase

Aqueous Phase

(cP)

1.161e-002

1.161e-002

(Btu/lbmole-F)

15.09

15.09

0.1598
21.72

(Btu/lb-F)

0.3702

0.3702

0.9999

(Btu/lbmole-F)

15.09

15.09

20.09

(Btu/lb-F)

0.3702

0.3702

0.9248

(psia)

113.1

113.1

77.14

(psia)

94.98

94.98

22.60

22

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

5177

5177

0.0000

23

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

24

COMPOSITION

25
26

Overall Phase

27
28

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

29
30

Methanol

31

Ethanol

32

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.0000

LIQUID VOLUME
FRACTION

54.0662

0.0444

1732.3851

0.0349

149.0742

0.0303

4.9657

0.0041

228.7692

0.0046

19.6795

0.0040

diM-Ether

955.0940

0.7843

44000.2235

0.8866

4494.7200

0.9144

33

H2O

203.6813

0.1673

3669.3391

0.0739

251.7571

0.0512

34

Total

1217.8072

1.0000

49630.7168

1.0000

4915.2307

1.0000

35

Vapour Phase

36
37

COMPONENTS

MOLAR FLOW
(lbmole/hr)

38
39

Methanol

40

Ethanol

41

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

54.0662

0.0444

1732.3851

0.0349

149.0742

0.0303

4.9657

0.0041

228.7692

0.0046

19.6795

0.0040

diM-Ether

955.0940

0.7843

44000.2235

0.8866

4494.7200

0.9144

42

H2O

203.6813

0.1673

3669.3391

0.0739

251.7571

0.0512

43

Total

1217.8072

1.0000

49630.7168

1.0000

4915.2307

1.0000

44

Aqueous Phase

45
46

COMPONENTS

MOLAR FLOW
(lbmole/hr)

47

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

48

Methanol

0.0000

0.0504

0.0000

0.0743

0.0000

0.0826

49

Ethanol

0.0000

0.0039

0.0000

0.0083

0.0000

0.0093

50

diM-Ether

0.0000

0.1031

0.0000

0.2186

0.0000

0.2885

51

H2O

0.0000

0.8426

0.0000

0.6988

0.0000

0.6196

52

Total

0.0000

1.0000

0.0000

1.0000

0.0000

1.0000

53

K VALUE

54
55

COMPONENTS

MIXED

LIGHT

HEAVY

56

Methanol

0.8812

0.8812

57

Ethanol

1.038

1.038

58

diM-Ether

7.610

7.610

59

H2O

0.1985

0.1985

60

UNIT OPERATIONS

61
62
63

FEED TO
Valve:

64

PRODUCT FROM
VLV-100

Equilibrium Reactor:

LOGICAL CONNECTION
ERV-100

UTILITIES

65
66

( No utilities reference this stream )

67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 10 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 5 (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

PROCESS UTILITY

10
11
12

DYNAMICS

13
14

Pressure Specification

(Inactive)

15

Flow Specification

(Inactive) Molar:

152.3 psia
1218 lbmole/hr

16

Mass:

4.963e+004 lb/hr

Std Ideal Liq Volume:4915 barrel/day

User Variables

17
18

NOTES

19
20
21

Description

22
23
24

Material Stream: 6

25
26
27

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

28
29

Overall

Vapour Phase

30

Vapour / Phase Fraction

31

Temperature:

32

Pressure:

33

Molar Flow

(lbmole/hr)

1218

1218

34

Mass Flow

(lb/hr)

4.963e+004

4.963e+004

35

Std Ideal Liq Vol Flow

36

Molar Enthalpy

37

Molar Entropy

38

Heat Flow

39

Liq Vol Flow @Std Cond

1.0000

1.0000

247.9

247.9

145.0 *

145.0

(F)
(psia)

(barrel/day)

4915

4915

(Btu/lbmole)

-8.105e+004

-8.105e+004

(Btu/lbmole-F)

44.98

44.98

(Btu/hr)

-9.870e+007

-9.870e+007

5177 *

(barrel/day)

40

5177

PROPERTIES

41
42

Overall

Vapour Phase

43

Molecular Weight

44

Molar Density

45

Mass Density

46

Act. Volume Flow

47

Mass Enthalpy

48

Mass Entropy

49

Heat Capacity

(Btu/lbmole-F)

17.06

17.06

50

Mass Heat Capacity

(Btu/lb-F)

0.4186

0.4186

51

Lower Heating Value

(Btu/lbmole)

4.623e+005

4.623e+005

52

Mass Lower Heating Value

(Btu/lb)

1.134e+004

1.134e+004

53

Phase Fraction [Vol. Basis]

54

Phase Fraction [Mass Basis]

55

Partial Pressure of CO2

56
57
58

Avg. Liq. Density

59

Specific Heat

60

Std. Gas Flow

61

Std. Ideal Liq. Mass Density

62

Act. Liq. Flow

63
64
65

User Property

66

Partial Pressure of H2S

67

Cp/(Cp - R)

1.132

1.132

68

Cp/Cv

1.132

1.132

69

Hyprotech Ltd.

(lbmole/ft3)

40.75

40.75

1.910e-002

1.910e-002

(lb/ft3)

0.7784

0.7784

(barrel/day)

2.725e+005

2.725e+005

(Btu/lb)

-1989

-1989

(Btu/lb-F)

1.104

1.104

1.000
4.941e-324

1.000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

Act. Gas Flow

(ACFM)

1063

1063

(lbmole/ft3)

1.059

1.059

(Btu/lbmole-F)

17.06

17.06

(MMSCFD)

11.07

11.07

(lb/ft3)

43.16

43.16

Z Factor

1.000

1.000

Watson K

11.37

11.37

Licensed to: LEGENDS

0.0000

(USGPM)

(psia)

0.0000

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 11 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 6 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

12

Heat of Vap.

13

Kinematic Viscosity

14

Liq. Mass Density (Std. Cond)

15

Liq. Vol. Flow (Std. Cond)

16

Liquid Fraction

17

Molar Volume

18

Mass Heat of Vap.

19

Phase Fraction [Molar Basis]

20

Surface Tension

21

Thermal Conductivity

22

Viscosity

23

Cv (Semi-Ideal)

24

Mass Cv (Semi-Ideal)

25

Cv

26

Mass Cv

27

Cv (Ent. Method)

28

Mass Cv (Ent. Method)

29

Cp/Cv (Ent. Method)

30

Reid VP at 37.8 C

31

True VP at 37.8 C

Vapour Phase

(Btu/lbmole)

1.166e+004

(cSt)

0.9297

0.9297

(lb/ft3)

40.98

40.98

(barrel/day)

5177

5177

0.0000

0.0000

(ft3/lbmole)

52.35

52.35

(Btu/lb)

286.2
1.0000

1.0000

(Btu/hr-ft-F)

1.474e-002

1.474e-002

(cP)

1.159e-002

1.159e-002

(Btu/lbmole-F)

15.07

15.07

(Btu/lb-F)

0.3698

0.3698

(dyne/cm)

(Btu/lbmole-F)

15.07

15.07

(Btu/lb-F)

0.3698

0.3698

(psia)

113.1

113.1

(psia)

94.98

94.98

32

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

5177

5177

33

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

34

COMPOSITION

35
36

Overall Phase

37
38

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

39
40

Methanol

41

Ethanol

42

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.0000

LIQUID VOLUME
FRACTION

54.0662

0.0444

1732.3851

0.0349

149.0742

0.0303

4.9657

0.0041

228.7692

0.0046

19.6795

0.0040

diM-Ether

955.0940

0.7843

44000.2235

0.8866

4494.7200

0.9144

43

H2O

203.6813

0.1673

3669.3391

0.0739

251.7571

0.0512

44

Total

1217.8072

1.0000

49630.7168

1.0000

4915.2307

1.0000

45

Vapour Phase

46
47

COMPONENTS

MOLAR FLOW
(lbmole/hr)

48
49

Methanol

50

Ethanol

51

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

54.0662

0.0444

1732.3851

0.0349

149.0742

0.0303

4.9657

0.0041

228.7692

0.0046

19.6795

0.0040

diM-Ether

955.0940

0.7843

44000.2235

0.8866

4494.7200

0.9144

52

H2O

203.6813

0.1673

3669.3391

0.0739

251.7571

0.0512

53

Total

1217.8072

1.0000

49630.7168

1.0000

4915.2307

1.0000

54

K VALUE

55
56

COMPONENTS

57

MIXED

58

Ethanol

59

diM-Ether

60

H2O

61

HEAVY

UNIT OPERATIONS

62
63
64

LIGHT

Methanol

FEED TO
Cooler:

65

PRODUCT FROM
E-101

Valve:

LOGICAL CONNECTION
VLV-100

UTILITIES

66
67

( No utilities reference this stream )

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 12 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 6 (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

PROCESS UTILITY

10
11
12

DYNAMICS

13
14

Pressure Specification

(Active):

15

Flow Specification

(Inactive) Molar:

145.0 psia *
1218 lbmole/hr

16

Mass:

4.963e+004 lb/hr

Std Ideal Liq Volume:4915 barrel/day

User Variables

17
18

NOTES

19
20
21

Description

22
23
24

Material Stream: 7

25
26
27

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

28
29

Overall

30

Vapour / Phase Fraction

31

Temperature:

32

Pressure:

33

Molar Flow

34

Mass Flow

35

Std Ideal Liq Vol Flow

36

Molar Enthalpy

37

Molar Entropy

38

Heat Flow

39

Liq Vol Flow @Std Cond

Vapour Phase

0.7672

Aqueous Phase

0.7672

0.2328

(F)

192.2 *

192.2

192.2

(psia)

145.0 *

145.0

145.0

(lbmole/hr)

1218

934.3

283.5

(lb/hr)

4.963e+004

4.146e+004

8171

(barrel/day)

4915

4194

721.0
-1.064e+005

(Btu/lbmole)

-8.516e+004

-7.871e+004

(Btu/lbmole-F)

39.62

45.01

21.87

(Btu/hr)

-1.037e+008

-7.354e+007

-3.018e+007

4505

713.6

5177 *

(barrel/day)

40

PROPERTIES

41
42

Overall

43

Molecular Weight

44

Molar Density

45

Mass Density

46

Act. Volume Flow

47

Mass Enthalpy

48
49
50

Mass Heat Capacity

51

Lower Heating Value

52

Mass Lower Heating Value

53

Phase Fraction [Vol. Basis]

54

Phase Fraction [Mass Basis]

55

Partial Pressure of CO2

56
57
58

Avg. Liq. Density

59

Specific Heat

60

Std. Gas Flow

61

Std. Ideal Liq. Mass Density

62

Act. Liq. Flow

63

Z Factor

64

Watson K

65

User Property

66

Partial Pressure of H2S

67

Cp/(Cp - R)

68

Cp/Cv

69

Hyprotech Ltd.

Vapour Phase

Aqueous Phase

40.75

44.37

28.82

(lbmole/ft3)

2.691e-002

2.073e-002

1.518

(lb/ft3)

1.097

0.9200

43.75

(barrel/day)

1.934e+005

1.926e+005

798.3

(Btu/lb)

-2090

-1774

-3693

Mass Entropy

(Btu/lb-F)

0.9722

1.014

0.7590

Heat Capacity

(Btu/lbmole-F)

19.13

17.30

25.17

(Btu/lb-F)

0.4694

0.3898

0.8732

(Btu/lbmole)

4.623e+005

5.362e+005

2.185e+005

(Btu/lb)

1.134e+004

1.208e+004

7579

0.8533

0.8533

0.1467

0.8354

0.8354

0.1646

0.0000

0.0000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

Act. Gas Flow

(ACFM)

Licensed to: LEGENDS

751.1

(lbmole/ft3)

1.059

0.9522

1.681

(Btu/lbmole-F)

19.13

17.30

25.17

(MMSCFD)

11.07

8.493

2.577

(lb/ft3)

43.16

42.25

48.44

(USGPM)

23.28
1.000

1.366e-002

11.38

11.30

1.116

1.130

1.086

1.087

1.130

1.236

11.37
(psia)

23.28

0.0000

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 13 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 7 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

12

Heat of Vap.

13

Kinematic Viscosity

14

Liq. Mass Density (Std. Cond)

15

Liq. Vol. Flow (Std. Cond)

16

Liquid Fraction

17

Molar Volume

18

Mass Heat of Vap.

19

Phase Fraction [Molar Basis]

20

Surface Tension

21

Thermal Conductivity

22

Viscosity

23

Cv (Semi-Ideal)

24

Mass Cv (Semi-Ideal)

25

Cv

26

Mass Cv

27

Cv (Ent. Method)

28

Mass Cv (Ent. Method)

29

Cp/Cv (Ent. Method)

30

Reid VP at 37.8 C

31

True VP at 37.8 C

(Btu/lbmole)

Vapour Phase

Aqueous Phase

1.166e+004
0.7373

0.2121

(lb/ft3)

40.98

39.34

48.95

(barrel/day)

5177

4505

713.6

0.2328

0.0000

1.000

37.16

48.23

0.6588

0.7672

0.2328

1.299e-002

0.1964

1.087e-002

0.1486

(cSt)

(ft3/lbmole)
(Btu/lb)

286.2
0.7672

(dyne/cm)

37.52

37.52

(Btu/hr-ft-F)
(cP)
(Btu/lbmole-F)

17.14

15.31

23.18

(Btu/lb-F)

0.4207

0.3451

0.8043

(Btu/lbmole-F)

17.60

15.31

20.36

(Btu/lb-F)

0.4318

0.3451

0.7063

(psia)

113.1

116.7

88.13

(psia)

94.98

111.5

43.43

32

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

5218

4505

713.6

33

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

34

COMPOSITION

35
36

Overall Phase

37
38

Fluid Package:

COMPONENTS

39
40

Methanol

41

Ethanol

42

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.7672

LIQUID VOLUME
FRACTION

54.0662

0.0444

1732.3851

0.0349

149.0742

0.0303

4.9657

0.0041

228.7692

0.0046

19.6795

0.0040

diM-Ether

955.0940

0.7843

44000.2235

0.8866

4494.7200

0.9144

43

H2O

203.6813

0.1673

3669.3391

0.0739

251.7571

0.0512

44

Total

1217.8072

1.0000

49630.7168

1.0000

4915.2307

1.0000

45

Vapour Phase

46
47

COMPONENTS

48
49

Methanol

50

Ethanol

51

diM-Ether

52
53

MOLAR FLOW
(lbmole/hr)

MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

LIQUID VOLUME
FRACTION

0.0269

806.7908

0.0195

69.4255

0.0166

2.0829

0.0022

95.9600

0.0023

8.2548

0.0020

863.2147

0.9239

39767.4388

0.9592

4062.3317

0.9686

H2O

43.8352

0.0469

789.6953

0.0190

54.1818

0.0129

Total

934.3121

1.0000

41459.8850

1.0000

4194.1938

1.0000

Aqueous Phase

55

COMPONENTS

57
58

Methanol

59

Ethanol

60

diM-Ether

61
62

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.2328

LIQUID VOLUME
FRACTION

28.8870

0.1019

925.5943

0.1133

79.6487

0.1105

2.8828

0.0102

132.8092

0.0163

11.4247

0.0158

91.8792

0.3241

4232.7847

0.5180

432.3883

0.5997

H2O

159.8461

0.5638

2879.6437

0.3524

197.5753

0.2740

Total

283.4951

1.0000

8170.8318

1.0000

721.0369

1.0000

63

K VALUE

64
65

MASS FLOW
(lb/hr)

0.7672

25.1792

54

56

MOLE FRACTION

Phase Fraction

COMPONENTS

MIXED

LIGHT

HEAVY

66

Methanol

0.2645

0.2645

67

Ethanol

0.2192

0.2192

68

diM-Ether

2.851

69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

2.851

Page 14 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 7 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

K VALUE

10
11

COMPONENTS

MIXED

12

H2O

LIGHT

HEAVY

8.321e-002

13

8.321e-002

UNIT OPERATIONS

14
15
16

Fluid Package:

FEED TO

PRODUCT FROM

Distillation:

T-100

Cooler:

LOGICAL CONNECTION
E-101

17

UTILITIES

18
19

( No utilities reference this stream )

20

PROCESS UTILITY

21
22
23

DYNAMICS

24
25

Pressure Specification

(Active):

26

Flow Specification

(Inactive) Molar:

145.0 psia *
1218 lbmole/hr

27

Mass:

4.963e+004 lb/hr

Std Ideal Liq Volume:4915 barrel/day

User Variables

28
29

NOTES

30
31
32

Description

33
34
35

Material Stream: 8

36
37
38

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

39
40

Overall

41

Vapour / Phase Fraction

42

Temperature:

43

Pressure:

44

Liquid Phase

0.0000

1.0000

(F)

110.0

110.0

(psia)

139.0

139.0

Molar Flow

(lbmole/hr)

956.0

956.0

45

Mass Flow

(lb/hr)

4.403e+004

4.403e+004

46

Std Ideal Liq Vol Flow

47

Molar Enthalpy

48

Molar Entropy

49

Heat Flow

50

Liq Vol Flow @Std Cond

(barrel/day)

4497

4497

(Btu/lbmole)

-8.662e+004

-8.662e+004

(Btu/lbmole-F)

37.85

37.85

(Btu/hr)

-8.281e+007

-8.281e+007

4878 *

(barrel/day)

51

4878

PROPERTIES

52
53

Overall

54

Molecular Weight

55

Molar Density

56

Mass Density

57

Act. Volume Flow

58

Mass Enthalpy

59
60
61

Mass Heat Capacity

62

Lower Heating Value

63

Mass Lower Heating Value

64

Phase Fraction [Vol. Basis]

65

Phase Fraction [Mass Basis]

66

Partial Pressure of CO2

67
68
69

Fluid Package:

Liquid Phase
46.06

46.06

(lbmole/ft3)

0.7799

0.7799
35.92

(lb/ft3)

35.92

(barrel/day)

5240

5240

(Btu/lb)

-1881

-1881

Mass Entropy

(Btu/lb-F)

0.8219

0.8219

Heat Capacity

(Btu/lbmole-F)

28.21

28.21

(Btu/lb-F)

0.6126

0.6126

(Btu/lbmole)

5.708e+005

5.708e+005

(Btu/lb)

1.239e+004

1.239e+004
1.000

2.122e-314
(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

Act. Gas Flow

(ACFM)

Hyprotech Ltd.
Licensed to: LEGENDS

1.000
0.0000

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 15 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 8 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Liquid Phase

12

Avg. Liq. Density

13

Specific Heat

14

Std. Gas Flow

15

Std. Ideal Liq. Mass Density

16

Act. Liq. Flow

17

Z Factor

18

Watson K

19

User Property

20

Partial Pressure of H2S

21

Cp/(Cp - R)

1.076

1.076

22

Cp/Cv

1.076

1.076

23

Heat of Vap.

24

Kinematic Viscosity

25

Liq. Mass Density (Std. Cond)

26

Liq. Vol. Flow (Std. Cond)

27

Liquid Fraction

28

Molar Volume

29

Mass Heat of Vap.

30

Phase Fraction [Molar Basis]

31

Surface Tension

32

Thermal Conductivity

33

Viscosity

34

Cv (Semi-Ideal)

35

Mass Cv (Semi-Ideal)

36

Cv

37

Mass Cv

38

Cv (Ent. Method)

39

Mass Cv (Ent. Method)

40

Cp/Cv (Ent. Method)

41

Reid VP at 37.8 C

42

True VP at 37.8 C

(lbmole/ft3)

0.9087

0.9087

(Btu/lbmole-F)

28.21

28.21

(MMSCFD)

8.690

8.690

(lb/ft3)

41.85

41.85

(USGPM)

152.8

152.8

2.915e-002

2.915e-002

11.38

11.38

(psia)

0.0000

(Btu/lbmole)

7981

(cSt)

0.1312

0.1312

(lb/ft3)

38.58

38.58

(barrel/day)

4878

4878

1.000

1.000

(ft3/lbmole)

1.282

1.282

(Btu/lb)

173.3
0.0000

1.0000

(dyne/cm)

9.257

9.257

(Btu/hr-ft-F)

7.011e-002

7.011e-002
7.548e-002

(cP)

7.548e-002

(Btu/lbmole-F)

26.23

26.23

(Btu/lb-F)

0.5695

0.5695

(Btu/lbmole-F)

26.23

26.23

(Btu/lb-F)

0.5695

0.5695

(psia)

120.4

120.4

(psia)

120.7

120.7

43

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

4878

4878

44

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

45

COMPOSITION

46
47

Overall Phase

48
49

Fluid Package:

COMPONENTS

50

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

51

Methanol

0.9385

0.0010

30.0722

0.0007

2.5878

0.0006

52

Ethanol

0.0100

0.0000

0.4627

0.0000

0.0398

0.0000

53

diM-Ether

955.0741

0.9990

43999.3107

0.9993

4494.6267

0.9994

54

H2O

0.0075

0.0000

0.1346

0.0000

0.0092

0.0000

55

Total

956.0302

1.0000

44029.9802

1.0000

4497.2635

1.0000

56

Liquid Phase

57
58

COMPONENTS

59

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

60

Methanol

0.9385

0.0010

30.0722

0.0007

2.5878

0.0006

61

Ethanol

0.0100

0.0000

0.4627

0.0000

0.0398

0.0000

62

diM-Ether

955.0741

0.9990

43999.3107

0.9993

4494.6267

0.9994

63

H2O

0.0075

0.0000

0.1346

0.0000

0.0092

0.0000

64

Total

956.0302

1.0000

44029.9802

1.0000

4497.2635

1.0000

65

K VALUE

66
67

COMPONENTS

68
69

MIXED
Methanol

Hyprotech Ltd.
Licensed to: LEGENDS

LIGHT
0.0000

Aspen HYSYS Version 7.1 (23.0.0.7119)

HEAVY
0.0000

Page 16 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 8 (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

K VALUE

10
11

COMPONENTS

MIXED

LIGHT

HEAVY

12

Ethanol

0.0000

0.0000

13

diM-Ether

0.0000

0.0000

14

H2O

0.0000

0.0000

15

UNIT OPERATIONS

16
17
18

FEED TO

PRODUCT FROM

Valve:

VLV-102

Distillation:

19

LOGICAL CONNECTION
T-100

UTILITIES

20
21

( No utilities reference this stream )

22

PROCESS UTILITY

23
24
25

DYNAMICS

26
27

Pressure Specification

(Inactive)

28

Flow Specification

(Inactive) Molar:

139.0 psia
956.0 lbmole/hr

29

Mass:

4.403e+004 lb/hr

Std Ideal Liq Volume:4497 barrel/day

User Variables

30
31

NOTES

32
33
34

Description

35
36
37

Material Stream: 9

38
39
40

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

41
42

Overall

43

Vapour / Phase Fraction

44

Temperature:

45

Pressure:

46

Aqueous Phase

0.0000

1.0000

(F)

320.5

320.5

(psia)

159.0

159.0

Molar Flow

(lbmole/hr)

261.8

261.8

47

Mass Flow

(lb/hr)

5601

5601

48

Std Ideal Liq Vol Flow

(barrel/day)

418.0

418.0

49

Molar Enthalpy

-1.133e+005

50

Molar Entropy

51

Heat Flow

52

Liq Vol Flow @Std Cond

(Btu/lbmole)

-1.133e+005

(Btu/lbmole-F)

15.54

15.54

(Btu/hr)

-2.966e+007

-2.966e+007

410.3 *

(barrel/day)

53

410.3

PROPERTIES

54
55

Overall

56

Molecular Weight

57

Molar Density

58

Mass Density

59

Act. Volume Flow

60

Mass Enthalpy

61
62
63

Mass Heat Capacity

64

Lower Heating Value

65

Mass Lower Heating Value

66

Phase Fraction [Vol. Basis]

67

Phase Fraction [Mass Basis]

68

Partial Pressure of CO2

69

Fluid Package:

Aqueous Phase
21.40

21.40

(lbmole/ft3)

2.332

2.332

(lb/ft3)

49.89

49.89

(barrel/day)

479.9

479.9

(Btu/lb)

-5296

-5296

Mass Entropy

(Btu/lb-F)

0.7262

0.7262

Heat Capacity

(Btu/lbmole-F)

22.69

22.69

(Btu/lb-F)

1.061

1.061

(Btu/lbmole)

6.577e+004

6.577e+004

(Btu/lb)

3074

Hyprotech Ltd.
Licensed to: LEGENDS

3074
1.000

0.0000
(psia)

1.000

0.0000

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 17 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 9 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Aqueous Phase

12

Cost Based on Flow

(Cost/s)

13

Act. Gas Flow

(ACFM)

14

Avg. Liq. Density

15

Specific Heat

16

Std. Gas Flow

17

Std. Ideal Liq. Mass Density

18

Act. Liq. Flow

19

Z Factor

20

Watson K

21

User Property

22

Partial Pressure of H2S

23

Cp/(Cp - R)

1.096

1.096

24

Cp/Cv

1.213

1.213

25

Heat of Vap.

26

Kinematic Viscosity

27

Liq. Mass Density (Std. Cond)

28

Liq. Vol. Flow (Std. Cond)

29

Liquid Fraction

30

Molar Volume

31

Mass Heat of Vap.

32

Phase Fraction [Molar Basis]

33

Surface Tension

34

Thermal Conductivity

35

Viscosity

36

Cv (Semi-Ideal)

37

Mass Cv (Semi-Ideal)

38

Cv

39

Mass Cv

40

Cv (Ent. Method)

41

Mass Cv (Ent. Method)

42

Cp/Cv (Ent. Method)

43

Reid VP at 37.8 C

44

True VP at 37.8 C

0.0000

0.0000

(lbmole/ft3)

2.677

2.677

(Btu/lbmole-F)

22.69

22.69

(MMSCFD)

2.380

2.380

(lb/ft3)

57.28

57.28

(USGPM)

14.00

14.00

8.144e-003

8.144e-003

10.64

10.64

(psia)

0.0000

(Btu/lbmole)

1.539e+004

(cSt)

0.1682

0.1682

(lb/ft3)

58.35

58.35

(barrel/day)

410.3

410.3

(ft3/lbmole)
(Btu/lb)

1.000

1.000

0.4288

0.4288

719.1
1.0000

0.0000
(dyne/cm)

38.26

38.26

(Btu/hr-ft-F)

0.2899

0.2899
0.1344

(cP)

0.1344

(Btu/lbmole-F)

20.70

20.70

(Btu/lb-F)

0.9677

0.9677

(Btu/lbmole-F)

18.70

18.70

(Btu/lb-F)

0.8741

0.8741

(psia)

4.481

4.481

(psia)

2.329

2.329

45

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

410.3

410.3

46

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

47

COMPOSITION

48
49

Overall Phase

50
51

Fluid Package:

COMPONENTS

52

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

53

Methanol

53.1277

0.2030

1702.3129

0.3039

146.4864

0.3505

54

Ethanol

4.9557

0.0189

228.3065

0.0408

19.6397

0.0470

55

diM-Ether

0.0198

0.0001

0.9128

0.0002

0.0932

0.0002

56

H2O

203.6738

0.7780

3669.2044

0.6551

251.7478

0.6023

57

Total

261.7770

1.0000

5600.7367

1.0000

417.9672

1.0000

58

Aqueous Phase

59
60

COMPONENTS

61

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

62

Methanol

53.1277

0.2030

1702.3129

0.3039

146.4864

0.3505

63

Ethanol

4.9557

0.0189

228.3065

0.0408

19.6397

0.0470

64

diM-Ether

0.0198

0.0001

0.9128

0.0002

0.0932

0.0002

65

H2O

203.6738

0.7780

3669.2044

0.6551

251.7478

0.6023

66

Total

261.7770

1.0000

5600.7367

1.0000

417.9672

1.0000

67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 18 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 9 (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

K VALUE

10
11

COMPONENTS

MIXED

LIGHT

HEAVY

12

Methanol

0.0000

0.0000

13

Ethanol

0.0000

0.0000

14

diM-Ether

0.0000

0.0000

15

H2O

0.0000

0.0000

16

UNIT OPERATIONS

17
18
19

FEED TO

PRODUCT FROM

Valve:

VLV-101

LOGICAL CONNECTION

Distillation:

20

T-100

UTILITIES

21
22

( No utilities reference this stream )

23

PROCESS UTILITY

24
25
26

DYNAMICS

27
28

Pressure Specification

(Inactive)

29

Flow Specification

(Inactive) Molar:

159.0 psia
261.8 lbmole/hr

30

Mass:

5601 lb/hr

Std Ideal Liq Volume:418.0 barrel/day

User Variables

31
32

NOTES

33
34
35

Description

36
37
38

Material Stream: 10

39
40
41

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

42
43

Overall

44

Vapour / Phase Fraction

45

Temperature:

46

Pressure:

47

Molar Flow

48

Mass Flow

49

Std Ideal Liq Vol Flow

50

Molar Enthalpy

51

Molar Entropy

52

Heat Flow

53

Liq Vol Flow @Std Cond

Vapour Phase

Aqueous Phase

0.2755

0.2755

0.7245

93.09

93.09

93.09

1.450 *

1.450

1.450

(lbmole/hr)

261.8

72.11

189.7

(lb/hr)

5601

1872

3729

(barrel/day)

418.0

150.3

267.7
-1.202e+005

(F)
(psia)

(Btu/lbmole)

-1.133e+005

-9.519e+004

(Btu/lbmole-F)

14.39

43.17

3.443

(Btu/hr)

-2.966e+007

-6.864e+006

-2.280e+007

148.3

262.7

410.3 *

(barrel/day)

54

PROPERTIES

55
56

Overall

57

Molecular Weight

58

Molar Density

59

Mass Density

60

Act. Volume Flow

61

Mass Enthalpy

62
63
64

Mass Heat Capacity

65

Lower Heating Value

66

Mass Lower Heating Value

67

Phase Fraction [Vol. Basis]

68
69

Vapour Phase

Aqueous Phase

21.40

25.96

19.66

(lbmole/ft3)

8.875e-004

2.445e-004

3.038

(lb/ft3)

1.899e-002

6.348e-003

59.73

(barrel/day)

1.261e+006

1.261e+006

266.9

(Btu/lb)

-5296

-3666

-6115

Mass Entropy

(Btu/lb-F)

0.6724

1.663

0.1752

Heat Capacity

(Btu/lbmole-F)

16.65

9.641

19.31

(Btu/lb-F)

0.7780

0.3713

0.9822

(Btu/lbmole)

6.577e+004

1.547e+005

3.198e+004

(Btu/lb)

3074

5957

1627

0.3595

0.3595

0.6405

Phase Fraction [Mass Basis]

0.3343

0.3343

0.6657

Hyprotech Ltd.

Aspen HYSYS Version 7.1 (23.0.0.7119)

Licensed to: LEGENDS

Page 19 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 10 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

12

Partial Pressure of CO2

13
14
15

Avg. Liq. Density

16

Specific Heat

17

Std. Gas Flow

18

Std. Ideal Liq. Mass Density

19

Act. Liq. Flow

20

Z Factor

21

Watson K

22

User Property

23

Partial Pressure of H2S

24

Cp/(Cp - R)

25

Cp/Cv

26

Heat of Vap.

27

Kinematic Viscosity

28

Liq. Mass Density (Std. Cond)

29

Liq. Vol. Flow (Std. Cond)

30

Liquid Fraction

31

Molar Volume

32

Mass Heat of Vap.

33

Phase Fraction [Molar Basis]

34

Surface Tension

35

Thermal Conductivity

36

Viscosity

37

Cv (Semi-Ideal)

38

Mass Cv (Semi-Ideal)

39

Cv

40

Mass Cv

41

Cv (Ent. Method)

42

Mass Cv (Ent. Method)

43

Cp/Cv (Ent. Method)

44

Reid VP at 37.8 C

45

True VP at 37.8 C

Vapour Phase

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

Act. Gas Flow

(ACFM)

Aqueous Phase

0.0000

0.0000

4915

(lbmole/ft3)

2.677

2.051

3.029

(Btu/lbmole-F)

16.65

9.641

19.31

(MMSCFD)

2.380

0.6555

1.724

(lb/ft3)

57.28

53.26

59.54

(USGPM)

7.783
1.000

8.048e-005

10.64

10.64

1.135

1.259

1.115

1.034

1.259

1.164

10.64
(psia)

7.783

0.0000

(Btu/lbmole)

1.854e+004
65.60

0.7669

(lb/ft3)

58.35

53.97

60.66

(barrel/day)

410.3

148.3

262.7

0.7245

0.0000

1.000

1127

4090

0.3291

0.2755

0.7245

9.102e-003

0.3213

6.670e-003

0.7337

(cSt)

(ft3/lbmole)

866.8

(Btu/lb)

0.2755

65.90

65.90

(dyne/cm)
(Btu/hr-ft-F)
(cP)
(Btu/lbmole-F)

14.66

7.655

17.32

(Btu/lb-F)

0.6852

0.2948

0.8812

(Btu/lbmole-F)

16.10

7.655

16.59

(Btu/lb-F)

0.7524

0.2948

0.8438

(psia)

4.481

4.488

4.470

(psia)

2.329

3.249

1.775

46

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

411.0

148.3

47

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

262.7
-0.8995

48

COMPOSITION

49
50

Overall Phase

51
52

Fluid Package:

COMPONENTS

53

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.2755

LIQUID VOLUME
FRACTION

54

Methanol

53.1277

0.2030

1702.3129

0.3039

146.4864

0.3505

55

Ethanol

4.9557

0.0189

228.3065

0.0408

19.6397

0.0470

56

diM-Ether

0.0198

0.0001

0.9128

0.0002

0.0932

0.0002

57

H2O

203.6738

0.7780

3669.2044

0.6551

251.7478

0.6023

58

Total

261.7770

1.0000

5600.7367

1.0000

417.9672

1.0000

59

Vapour Phase

60
61

COMPONENTS

62

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.2755

LIQUID VOLUME
FRACTION

63

Methanol

34.2410

0.4749

1097.1474

0.5860

94.4111

0.6283

64

Ethanol

3.2911

0.0456

151.6208

0.0810

13.0429

0.0868

65

diM-Ether

0.0195

0.0003

0.8995

0.0005

0.0919

0.0006

66

H2O

34.5561

0.4792

622.5315

0.3325

42.7125

0.2843

67

Total

72.1077

1.0000

1872.1992

1.0000

150.2584

1.0000

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 20 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 10 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

COMPOSITION

10
11

Aqueous Phase

12
13

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

14

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.7245

LIQUID VOLUME
FRACTION

15

Methanol

18.8867

0.0996

605.1656

0.1623

52.0754

0.1945

16

Ethanol

1.6646

0.0088

76.6857

0.0206

6.5968

0.0246

17

diM-Ether

0.0003

0.0000

0.0133

0.0000

0.0014

0.0000

18

H2O

169.1177

0.8916

3046.6729

0.8171

209.0353

0.7808

19

Total

189.6693

1.0000

3728.5375

1.0000

267.7088

1.0000

20

K VALUE

21
22

COMPONENTS

MIXED

LIGHT

HEAVY

23

Methanol

4.769

4.769

24

Ethanol

5.201

5.201

25

diM-Ether

177.7

177.7

26

H2O

0.5375

0.5375

27

UNIT OPERATIONS

28
29
30

FEED TO

PRODUCT FROM

Distillation:

T-101

Valve:

LOGICAL CONNECTION
VLV-101

31

UTILITIES

32
33

( No utilities reference this stream )

34

PROCESS UTILITY

35
36
37

DYNAMICS

38
39

1.450 psia *

Pressure Specification

(Active):

40

Flow Specification

(Inactive) Molar:

261.8 lbmole/hr

41

Mass:

5601 lb/hr

Std Ideal Liq Volume:418.0 barrel/day

User Variables

42
43

NOTES

44
45
46

Description

47
48
49

Material Stream: 11

50
51
52

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

53
54

Overall

55

Vapour / Phase Fraction

56

Temperature:

57

Pressure:

58

Liquid Phase

0.0000

1.0000

(F)

92.71

92.71

(psia)

3.755

3.755

Molar Flow

(lbmole/hr)

55.80

55.80

59

Mass Flow

(lb/hr)

1820

1820

60

Std Ideal Liq Vol Flow

(barrel/day)

156.6

156.6

61

Molar Enthalpy

-1.033e+005

62

Molar Entropy

63

Heat Flow

64

Liq Vol Flow @Std Cond

(Btu/lbmole)

-1.033e+005

(Btu/lbmole-F)

10.15

10.15

(Btu/hr)

-5.765e+006

-5.765e+006

156.2 *

(barrel/day)

65

156.2

PROPERTIES

66
67

Overall

68

Molecular Weight

69

Hyprotech Ltd.
Licensed to: LEGENDS

Liquid Phase
32.62

32.62

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 21 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 11 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Liquid Phase

12

Molar Density

(lbmole/ft3)

1.490

1.490

13

Mass Density

(lb/ft3)

48.61

48.61

14

Act. Volume Flow

(barrel/day)

160.1

160.1

15

Mass Enthalpy

(Btu/lb)

-3167

-3167

16

Mass Entropy

(Btu/lb-F)

0.3112

0.3112

17

Heat Capacity

(Btu/lbmole-F)

28.15

28.15

18

Mass Heat Capacity

(Btu/lb-F)

0.8630

0.8630

19

Lower Heating Value

(Btu/lbmole)

2.849e+005

2.849e+005

20

Mass Lower Heating Value

(Btu/lb)

8734

21

Phase Fraction [Vol. Basis]

22

Phase Fraction [Mass Basis]

23

Partial Pressure of CO2

24
25
26

Avg. Liq. Density

27

Specific Heat

28

Std. Gas Flow

29

Std. Ideal Liq. Mass Density

30

Act. Liq. Flow

31

Z Factor

32

Watson K

33

User Property

34

Partial Pressure of H2S

35

Cp/(Cp - R)

1.076

1.076

36

Cp/Cv

1.339

1.339

37

Heat of Vap.

38

Kinematic Viscosity

39

Liq. Mass Density (Std. Cond)

40

Liq. Vol. Flow (Std. Cond)

41

Liquid Fraction

42

Molar Volume

43

Mass Heat of Vap.

44

Phase Fraction [Molar Basis]

45

Surface Tension

46

Thermal Conductivity

47

Viscosity

48

Cv (Semi-Ideal)

49

Mass Cv (Semi-Ideal)

50

Cv

51

Mass Cv

52

Cv (Ent. Method)

53

Mass Cv (Ent. Method)

54

Cp/Cv (Ent. Method)

55

Reid VP at 37.8 C

(psia)

56

True VP at 37.8 C

57
58

Viscosity Index

8734
1.000

2.122e-314

1.000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

Act. Gas Flow

(ACFM)
1.523

(lbmole/ft3)

1.523

(Btu/lbmole-F)

28.15

28.15

(MMSCFD)

0.5072

0.5072

(lb/ft3)

49.69

49.69

(USGPM)

4.669

4.669

4.251e-004

4.251e-004

10.63

10.63

(psia)

0.0000

(Btu/lbmole)

1.624e+004

(cSt)

0.6411

0.6411

(lb/ft3)

49.83

49.83

(barrel/day)

156.2

156.2

(ft3/lbmole)
(Btu/lb)

1.000

1.000

0.6711

0.6711

497.9
0.0000

1.0000

(dyne/cm)

28.05

28.05

(Btu/hr-ft-F)

0.1017

0.1017
0.4992

(cP)

0.4992

(Btu/lbmole-F)

26.17

26.17

(Btu/lb-F)

0.8021

0.8021

(Btu/lbmole-F)

21.02

21.02

(Btu/lb-F)

0.6444

0.6444

(psia)

4.570

4.570

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

156.2

156.2

-1.755

-1.755

(Btu/lbmole-F)
(Btu/lb-F)

59

COMPOSITION

60
61

Overall Phase

62
63

Fluid Package:

COMPONENTS

64

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

65

Methanol

53.0662

0.9510

1700.3431

0.9341

146.3169

0.9344

66

Ethanol

2.5036

0.0449

115.3383

0.0634

9.9218

0.0634

67

diM-Ether

0.0198

0.0004

0.9128

0.0005

0.0932

0.0006

68

H2O

0.2086

0.0037

3.7578

0.0021

0.2578

69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

0.0016

Page 22 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 11 (continued)

7
8
9

11

Property Package:

UNIQUAC - Ideal

Overall Phase (continued)

12

Total

55.7982

1.0000

14

Vapour Fraction

1820.3521

1.0000

156.5898

Liquid Phase

15
16

Basis-1

COMPOSITION

10

13

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

17

MOLE FRACTION

MASS FLOW
(lb/hr)

0.0000
1.0000

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

18

Methanol

53.0662

0.9510

1700.3431

0.9341

146.3169

0.9344

19

Ethanol

2.5036

0.0449

115.3383

0.0634

9.9218

0.0634

20

diM-Ether

0.0198

0.0004

0.9128

0.0005

0.0932

0.0006

21

H2O

0.2086

0.0037

3.7578

0.0021

0.2578

0.0016

22

Total

55.7982

1.0000

1820.3521

1.0000

156.5898

1.0000

23

K VALUE

24
25

COMPONENTS

MIXED

26

LIGHT

HEAVY

Methanol

0.0000

0.0000

27

Ethanol

0.0000

0.0000

28

diM-Ether

0.0000

0.0000

29

H2O

0.0000

0.0000

30

UNIT OPERATIONS

31
32
33

FEED TO

PRODUCT FROM

Pump:

P-101

Distillation:

34

LOGICAL CONNECTION
T-101

UTILITIES

35
36

( No utilities reference this stream )

37

PROCESS UTILITY

38
39
40

DYNAMICS

41
42

Pressure Specification

(Inactive)

43

Flow Specification

(Inactive) Molar:

3.755 psia
55.80 lbmole/hr

44

Mass:

1820 lb/hr

Std Ideal Liq Volume:156.6 barrel/day

User Variables

45
46

NOTES

47
48
49

Description

50
51
52

Material Stream: 12

53
54
55

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

56
57

Overall

58

Vapour / Phase Fraction

59

Temperature:

60

Pressure:

61

Molar Flow

62

Mass Flow

63

Std Ideal Liq Vol Flow

64

Molar Enthalpy

65

Molar Entropy

66

Heat Flow

67

Liq Vol Flow @Std Cond

Liquid Phase

0.0000

1.0000

93.58

93.58

152.3 *

152.3

(lbmole/hr)

55.80

55.80

(lb/hr)

1820

1820

(barrel/day)

156.6

156.6
-1.033e+005

(F)
(psia)

(Btu/lbmole)

-1.033e+005

(Btu/lbmole-F)

17.57

17.57

(Btu/hr)

-5.763e+006

-5.763e+006

(barrel/day)

156.2 *

156.2

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 23 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 12 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Liquid Phase

12

Molecular Weight

13

Molar Density

14

Mass Density

15

Act. Volume Flow

16

Mass Enthalpy

17
18
19

Mass Heat Capacity

20

Lower Heating Value

21

Mass Lower Heating Value

22

Phase Fraction [Vol. Basis]

23

Phase Fraction [Mass Basis]

24

Partial Pressure of CO2

25
26
27

Avg. Liq. Density

28

Specific Heat

29

Std. Gas Flow

30

Std. Ideal Liq. Mass Density

31

Act. Liq. Flow

32

Z Factor

33

Watson K

34

User Property

35

Partial Pressure of H2S

36

Cp/(Cp - R)

1.076

1.076

37

Cp/Cv

1.337

1.337

38

Heat of Vap.

39

Kinematic Viscosity

40

Liq. Mass Density (Std. Cond)

41

Liq. Vol. Flow (Std. Cond)

42

Liquid Fraction

43

Molar Volume

44

Mass Heat of Vap.

45

Phase Fraction [Molar Basis]

46

Surface Tension

47

Thermal Conductivity

48

Viscosity

49

Cv (Semi-Ideal)

50

Mass Cv (Semi-Ideal)

51

Cv

52

Mass Cv

53

Cv (Ent. Method)

54

Mass Cv (Ent. Method)

55

Cp/Cv (Ent. Method)

56

Reid VP at 37.8 C

(psia)

57

True VP at 37.8 C

58
59

Viscosity Index

32.62

32.62

(lbmole/ft3)

1.490

1.490

(lb/ft3)

48.62

48.62

(barrel/day)

160.0

160.0

(Btu/lb)

-3166

-3166

Mass Entropy

(Btu/lb-F)

0.5385

0.5385

Heat Capacity

(Btu/lbmole-F)

28.17

28.17

(Btu/lb-F)

0.8633

0.8633

(Btu/lbmole)

2.849e+005

2.849e+005

(Btu/lb)

8734

8734
1.000

2.122e-314

1.000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

Act. Gas Flow

(ACFM)
1.523

(lbmole/ft3)

1.523

(Btu/lbmole-F)

28.17

28.17

(MMSCFD)

0.5072

0.5072

(lb/ft3)

49.69

49.69

(USGPM)

4.668

4.668

1.721e-002

1.721e-002

10.63

10.63

(psia)

0.0000

(Btu/lbmole)

1.275e+004

(cSt)

0.6371

0.6371

(lb/ft3)

49.83

49.83

(barrel/day)

156.2

156.2

(ft3/lbmole)
(Btu/lb)

1.000

1.000

0.6710

0.6710

390.9
0.0000

1.0000

(dyne/cm)

27.97

27.97

(Btu/hr-ft-F)

0.1016

0.1016
0.4962

(cP)

0.4962

(Btu/lbmole-F)

26.18

26.18

(Btu/lb-F)

0.8025

0.8025

(Btu/lbmole-F)

21.07

21.07

(Btu/lb-F)

0.6457

0.6457

(psia)

4.570

4.570

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

156.2

156.2

-1.766

-1.766

(Btu/lbmole-F)
(Btu/lb-F)

60

COMPOSITION

61
62

Overall Phase

63
64

Fluid Package:

COMPONENTS

65

MOLAR FLOW
(lbmole/hr)

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

66

Methanol

53.0662

0.9510

1700.3431

0.9341

146.3169

0.9344

67

Ethanol

2.5036

0.0449

115.3383

0.0634

9.9218

0.0634

68

diM-Ether

0.0198

0.0004

0.9128

0.0005

0.0932

69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

0.0006

Page 24 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 12 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

COMPOSITION

10
11

Overall Phase (continued)

12
13

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

14

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction

MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

15

H2O

0.2086

0.0037

3.7578

0.0021

0.2578

0.0016

16

Total

55.7982

1.0000

1820.3521

1.0000

156.5898

1.0000

17

Liquid Phase

18
19

COMPONENTS

MOLAR FLOW
(lbmole/hr)

20

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

21

Methanol

53.0662

0.9510

1700.3431

0.9341

146.3169

0.9344

22

Ethanol

2.5036

0.0449

115.3383

0.0634

9.9218

0.0634

23

diM-Ether

0.0198

0.0004

0.9128

0.0005

0.0932

0.0006

24

H2O

0.2086

0.0037

3.7578

0.0021

0.2578

0.0016

25

Total

55.7982

1.0000

1820.3521

1.0000

156.5898

1.0000

26

K VALUE

27
28

COMPONENTS

MIXED

29

LIGHT

HEAVY

Methanol

0.0000

0.0000

30

Ethanol

0.0000

0.0000

31

diM-Ether

0.0000

0.0000

32

H2O

0.0000

0.0000

33

UNIT OPERATIONS

34
35
36

FEED TO

PRODUCT FROM

Recycle:

RCY-1

Pump:

LOGICAL CONNECTION
P-101

37

UTILITIES

38
39

( No utilities reference this stream )

40

PROCESS UTILITY

41
42
43

DYNAMICS

44
45

Pressure Specification

(Active):

46

Flow Specification

(Inactive) Molar:

152.3 psia *
55.80 lbmole/hr

47

Mass:

1820 lb/hr

Std Ideal Liq Volume:156.6 barrel/day

User Variables

48
49

NOTES

50
51
52

Description

53
54
55

Material Stream: 13

56
57
58

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

59
60

Overall

61

Vapour / Phase Fraction

62

Temperature:

63

Pressure:

64

Liquid Phase

0.0000

1.0000

(F)

93.60 *

93.60

(psia)

152.3 *

152.3

Molar Flow

(lbmole/hr)

55.84 *

55.84

65

Mass Flow

(lb/hr)

1822

1822

66

Std Ideal Liq Vol Flow

(barrel/day)

156.7

156.7

67

Molar Enthalpy

(Btu/lbmole)

-1.033e+005

-1.033e+005

68

Molar Entropy

(Btu/lbmole-F)

17.57

17.57

69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 25 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 13 (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Overall

12

Heat Flow

13

Liq Vol Flow @Std Cond

(Btu/hr)

Liquid Phase

-5.768e+006
156.3 *

(barrel/day)

14

-5.768e+006
156.3

PROPERTIES

15
16

Overall

Liquid Phase

17

Molecular Weight

18

Molar Density

19

Mass Density

20

Act. Volume Flow

21

Mass Enthalpy

22
23
24

Mass Heat Capacity

25

Lower Heating Value

26

Mass Lower Heating Value

27

Phase Fraction [Vol. Basis]

28

Phase Fraction [Mass Basis]

29

Partial Pressure of CO2

30
31
32

Avg. Liq. Density

33

Specific Heat

34

Std. Gas Flow

35

Std. Ideal Liq. Mass Density

36

Act. Liq. Flow

37

Z Factor

38

Watson K

39

User Property

40

Partial Pressure of H2S

41

Cp/(Cp - R)

1.076

1.076

42

Cp/Cv

1.337

1.337

43

Heat of Vap.

44

Kinematic Viscosity

45

Liq. Mass Density (Std. Cond)

46

Liq. Vol. Flow (Std. Cond)

47

Liquid Fraction

48

Molar Volume

49

Mass Heat of Vap.

50

Phase Fraction [Molar Basis]

51

Surface Tension

52

Thermal Conductivity

53

Viscosity

54

Cv (Semi-Ideal)

55

Mass Cv (Semi-Ideal)

56

Cv

57

Mass Cv

58

Cv (Ent. Method)

59

Mass Cv (Ent. Method)

60

Cp/Cv (Ent. Method)

61

Reid VP at 37.8 C

(psia)

62

True VP at 37.8 C

63
64

Viscosity Index

32.63

32.63

(lbmole/ft3)

1.490

1.490

(lb/ft3)

48.62

48.62

(barrel/day)

160.2

160.2

(Btu/lb)

-3166

-3166

Mass Entropy

(Btu/lb-F)

0.5384

0.5384

Heat Capacity

(Btu/lbmole-F)

28.17

28.17

(Btu/lb-F)

0.8633

0.8633

(Btu/lbmole)

2.851e+005

2.851e+005

(Btu/lb)

8736

8736
1.000

2.122e-314

1.000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

Act. Gas Flow

(ACFM)
1.523

(lbmole/ft3)

1.523

(Btu/lbmole-F)

28.17

28.17

(MMSCFD)

0.5076

0.5076

(lb/ft3)

49.69

49.69

(USGPM)

4.672

4.672

1.721e-002

1.721e-002

10.63

10.63

(psia)

0.0000

(Btu/lbmole)

1.276e+004

(cSt)

0.6373

0.6373

(lb/ft3)

49.83

49.83

(barrel/day)

156.3

156.3

(ft3/lbmole)
(Btu/lb)

1.000

1.000

0.6711

0.6711

390.9
0.0000

1.0000

(dyne/cm)

27.97

27.97

(Btu/hr-ft-F)

0.1016

0.1016
0.4963

(cP)

0.4963

(Btu/lbmole-F)

26.18

26.18

(Btu/lb-F)

0.8024

0.8024

(Btu/lbmole-F)

21.08

21.08

(Btu/lb-F)

0.6459

0.6459

(psia)

4.562

4.562

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

156.3

156.3

-1.766

-1.766

(Btu/lbmole-F)
(Btu/lb-F)

65
66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 26 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: 13 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

COMPOSITION

10
11

Overall Phase

12
13

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

14

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

15

Methanol

53.0680 *

0.9503 *

1700.4011 *

0.9332 *

146.3219 *

0.9335 *

16

Ethanol

2.5380 *

0.0455 *

116.9262 *

0.0642 *

10.0584 *

0.0642 *

17

diM-Ether

0.0198 *

0.0004 *

0.9126 *

0.0005 *

0.0932 *

0.0006 *

18

H2O

0.2153 *

0.0039 *

3.8788 *

0.0021 *

0.2661 *

0.0017 *

19

Total

55.8412

1.0000

20

1.0000

156.7396

Liquid Phase

21
22

1822.1187

COMPONENTS

MOLAR FLOW
(lbmole/hr)

23

MOLE FRACTION

MASS FLOW
(lb/hr)

1.0000

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

24

Methanol

53.0680

0.9503

1700.4011

0.9332

146.3219

0.9335

25

Ethanol

2.5380

0.0455

116.9262

0.0642

10.0584

0.0642

26

diM-Ether

0.0198

0.0004

0.9126

0.0005

0.0932

0.0006

27

H2O

0.2153

0.0039

3.8788

0.0021

0.2661

0.0017

28

Total

55.8412

1.0000

1822.1187

1.0000

156.7396

1.0000

29

K VALUE

30
31

COMPONENTS

MIXED

32

LIGHT

HEAVY

Methanol

0.0000

0.0000

33

Ethanol

0.0000

0.0000

34

diM-Ether

0.0000

0.0000

35

H2O

0.0000

0.0000

36

UNIT OPERATIONS

37
38
39

FEED TO

PRODUCT FROM

Mixer:

MIX-100

Recycle:

40

LOGICAL CONNECTION
RCY-1

UTILITIES

41
42

( No utilities reference this stream )

43

PROCESS UTILITY

44
45
46

DYNAMICS

47
48

152.3 psia *

Pressure Specification

(Inactive)

49

Flow Specification

(Inactive) Molar:

55.84 lbmole/hr *

50

Mass:

1822 lb/hr

Std Ideal Liq Volume:156.7 barrel/day

User Variables

51
52

NOTES

53
54
55

Description

56
57
58

Material Stream: AGUA

59
60
61

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

62
63

Overall

64

Vapour / Phase Fraction

65

Temperature:

66

Pressure:

67

Aqueous Phase

0.0000

1.0000

(F)

203.0

203.0

(psia)

13.76

13.76

Molar Flow

(lbmole/hr)

206.0

206.0

68

Mass Flow

(lb/hr)

3780

3780

69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 27 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: AGUA (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Overall

12

Std Ideal Liq Vol Flow

13

Molar Enthalpy

14

Molar Entropy

15

Heat Flow

16

Liq Vol Flow @Std Cond

Aqueous Phase

(barrel/day)

261.4

261.4

(Btu/lbmole)

-1.201e+005

-1.201e+005

(Btu/lbmole-F)

5.664

5.664

(Btu/hr)

-2.475e+007

-2.475e+007

256.0 *

(barrel/day)

17

256.0

PROPERTIES

18
19

Overall

Aqueous Phase

20

Molecular Weight

21

Molar Density

22

Mass Density

23

Act. Volume Flow

24

Mass Enthalpy

25
26
27

Mass Heat Capacity

28

Lower Heating Value

29

Mass Lower Heating Value

30

Phase Fraction [Vol. Basis]

31

Phase Fraction [Mass Basis]

32

Partial Pressure of CO2

33
34
35

Avg. Liq. Density

36

Specific Heat

37

Std. Gas Flow

38

Std. Ideal Liq. Mass Density

39

Act. Liq. Flow

40

Z Factor

41

Watson K

42

User Property

43

Partial Pressure of H2S

44

Cp/(Cp - R)

1.122

1.122

45

Cp/Cv

1.182

1.182

46

Heat of Vap.

47

Kinematic Viscosity

48

Liq. Mass Density (Std. Cond)

49

Liq. Vol. Flow (Std. Cond)

50

Liquid Fraction

51

Molar Volume

52

Mass Heat of Vap.

53

Phase Fraction [Molar Basis]

54

Surface Tension

55

Thermal Conductivity

56

Viscosity

57

Cv (Semi-Ideal)

58

Mass Cv (Semi-Ideal)

59

Cv

60

Mass Cv

61

Cv (Ent. Method)

62

Mass Cv (Ent. Method)

63

Cp/Cv (Ent. Method)

64

Reid VP at 37.8 C

(psia)

65

True VP at 37.8 C

66
67

Viscosity Index

18.35

18.35

(lbmole/ft3)

3.224

3.224

(lb/ft3)

59.17

59.17

(barrel/day)

273.1

273.1

(Btu/lb)

-6546

-6546

Mass Entropy

(Btu/lb-F)

0.3086

0.3086

Heat Capacity

(Btu/lbmole-F)

18.31

18.31

(Btu/lb-F)

0.9979

0.9979

(Btu/lbmole)

6405

6405

(Btu/lb)

349.0

349.0
1.000

0.0000

1.000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

Act. Gas Flow

(ACFM)
(lbmole/ft3)

3.369

3.369

(Btu/lbmole-F)

18.31

18.31

(MMSCFD)

1.872

1.872

(lb/ft3)

61.83

61.83

(USGPM)

7.965

7.965

6.000e-004

6.000e-004

10.76

10.76

(psia)

0.0000

(Btu/lbmole)

1.759e+004

(cSt)

0.3160

0.3160

(lb/ft3)

63.12

63.12

(barrel/day)

256.0

256.0

(ft3/lbmole)
(Btu/lb)

1.000

1.000

0.3102

0.3102

958.6
0.0000

1.0000

(dyne/cm)

59.02

59.02

(Btu/hr-ft-F)

0.3870

0.3870
0.2996

(cP)

0.2996

(Btu/lbmole-F)

16.33

16.33

(Btu/lb-F)

0.8897

0.8897

(Btu/lbmole-F)

15.49

15.49

(Btu/lb-F)

0.8442

0.8442

(psia)

1.102

1.102

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

256.0

256.0

-2.518

-2.518

(Btu/lbmole-F)
(Btu/lb-F)

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 28 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: AGUA (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

COMPOSITION

10
11

Overall Phase

12
13

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

14

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

15

Methanol

0.0615

0.0003

1.9696

0.0005

0.1695

0.0006

16

Ethanol

2.4521

0.0119

112.9681

0.0299

9.7179

0.0372

17

diM-Ether

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

18

H2O

203.4652

0.9878

3665.4467

0.9696

251.4900

0.9622

19

Total

205.9788

1.0000

3780.3844

1.0000

261.3774

1.0000

20

Aqueous Phase

21
22

COMPONENTS

MOLAR FLOW
(lbmole/hr)

23

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

24

Methanol

0.0615

0.0003

1.9696

0.0005

0.1695

0.0006

25

Ethanol

2.4521

0.0119

112.9681

0.0299

9.7179

0.0372

26

diM-Ether

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

27

H2O

203.4652

0.9878

3665.4467

0.9696

251.4900

0.9622

28

Total

205.9788

1.0000

3780.3844

1.0000

261.3774

1.0000

29

K VALUE

30
31

COMPONENTS

MIXED

LIGHT

HEAVY

32

Methanol

0.0000

0.0000

33

Ethanol

0.0000

0.0000

34

diM-Ether

35

H2O

0.0000

0.0000

36

UNIT OPERATIONS

37
38

FEED TO

PRODUCT FROM

39

LOGICAL CONNECTION

Distillation:

40

T-101

UTILITIES

41
42

( No utilities reference this stream )

43

PROCESS UTILITY

44
45
46

DYNAMICS

47
48

Pressure Specification

(Inactive)

49

Flow Specification

(Inactive) Molar:

13.76 psia
206.0 lbmole/hr

50

Mass:

3780 lb/hr

Std Ideal Liq Volume:261.4 barrel/day

User Variables

51
52

NOTES

53
54
55

Description

56
57
58

Material Stream: DME

59
60
61

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

62
63

Overall

64

Vapour / Phase Fraction

65

Temperature:

66

Pressure:

67
68
69

Fluid Package:

Vapour Phase

Liquid Phase

0.0133

0.0133

0.9867

(F)

106.2

106.2

106.2

(psia)

131.7

131.7

131.7

Molar Flow

(lbmole/hr)

956.0

12.75

943.3

Mass Flow

(lb/hr)

4.403e+004

587.2

4.344e+004

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 29 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: DME (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Overall

12

Std Ideal Liq Vol Flow

13

Molar Enthalpy

14

Molar Entropy

15

Heat Flow

16

Liq Vol Flow @Std Cond

Vapour Phase

Liquid Phase

(barrel/day)

4497

59.98

4437

(Btu/lbmole)

-8.662e+004

-7.872e+004

-8.672e+004

(Btu/lbmole-F)

37.54

42.87

37.47

(Btu/hr)

-8.281e+007

-1.003e+006

-8.181e+007

65.07

4813

4878 *

(barrel/day)

17

PROPERTIES

18
19

Overall

20

Molecular Weight

21

Molar Density

22

Mass Density

23

Act. Volume Flow

24

Mass Enthalpy

25
26
27

Mass Heat Capacity

28

Lower Heating Value

29

Mass Lower Heating Value

30

Vapour Phase

Liquid Phase

46.06

46.07

46.05

(lbmole/ft3)

0.5341

2.169e-002

0.7845
36.13

(lb/ft3)

24.60

0.9995

(barrel/day)

7651

2511

5140

(Btu/lb)

-1881

-1709

-1883

Mass Entropy

(Btu/lb-F)

0.8151

0.9307

0.8135

Heat Capacity

(Btu/lbmole-F)

27.86

16.27

28.02

(Btu/lb-F)

0.6050

0.3533

0.6084

(Btu/lbmole)

5.708e+005

5.711e+005

5.708e+005

(Btu/lb)

1.239e+004

1.240e+004

1.239e+004

Phase Fraction [Vol. Basis]

1.334e-002

1.334e-002

0.9867

31

Phase Fraction [Mass Basis]

1.334e-002

1.334e-002

0.9867

32

Partial Pressure of CO2

33

0.0000

0.0000

34
35

Avg. Liq. Density

36

Specific Heat

37

Std. Gas Flow

38

Std. Ideal Liq. Mass Density

39

Act. Liq. Flow

40

Z Factor

41

Watson K

42

User Property

43

Partial Pressure of H2S

44

Cp/(Cp - R)

45

Cp/Cv

46

Heat of Vap.

47

Kinematic Viscosity

48

Liq. Mass Density (Std. Cond)

49

Liq. Vol. Flow (Std. Cond)

50

Liquid Fraction

51

Molar Volume

52

Mass Heat of Vap.

53

Phase Fraction [Molar Basis]

54

Surface Tension

55

Thermal Conductivity

56

Viscosity

57

Cv (Semi-Ideal)

58

Mass Cv (Semi-Ideal)

59

Cv

60

Mass Cv

61

Cv (Ent. Method)

62

Mass Cv (Ent. Method)

63

Cp/Cv (Ent. Method)

64

Reid VP at 37.8 C

(psia)

120.4

65

True VP at 37.8 C

(psia)

120.7

120.6

120.7

66

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

4878

65.07

4813

67

Viscosity Index

(psia)

0.0000

Cost Based on Flow

(Cost/s)

0.0000

Act. Gas Flow

(ACFM)

9.792

(lbmole/ft3)

0.9087

0.9083

0.9087

(Btu/lbmole-F)

27.86

16.27

28.02

(MMSCFD)

8.690

0.1159

8.574

(lb/ft3)

41.85

41.85

41.85

(USGPM)

149.9
1.000

2.765e-002

11.38

11.38

1.077

1.139

1.076

1.007

1.139

1.076

11.38
(psia)

(Btu/lbmole)

149.9

0.0000

8026

(cSt)

0.5944

0.1330

(lb/ft3)

38.58

38.57

38.58

(barrel/day)

4878

65.07

4813

0.9867

0.0000

1.000

(ft3/lbmole)

1.872

46.09

1.275

(Btu/lb)

174.3
0.0133

0.9867

1.046e-002

7.093e-002

9.516e-003

7.696e-002

0.0133
(dyne/cm)

9.542

(Btu/hr-ft-F)
(cP)

9.542

(Btu/lbmole-F)

25.88

14.29

26.03

(Btu/lb-F)

0.5619

0.3102

0.5653

(Btu/lbmole-F)

27.66

14.29

26.03

(Btu/lb-F)

0.6006

0.3102

0.5653

(Btu/lbmole-F)
(Btu/lb-F)
120.4

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 30 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: DME (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

COMPOSITION

10
11

Overall Phase

12
13

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

14

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0133

LIQUID VOLUME
FRACTION

15

Methanol

0.9385

0.0010

30.0722

0.0007

2.5878

0.0006

16

Ethanol

0.0100

0.0000

0.4627

0.0000

0.0398

0.0000

17

diM-Ether

955.0741

0.9990

43999.3107

0.9993

4494.6267

0.9994

18

H2O

0.0075

0.0000

0.1346

0.0000

0.0092

0.0000

19

Total

956.0302

1.0000

44029.9802

1.0000

4497.2635

1.0000

20

Vapour Phase

21
22

COMPONENTS

MOLAR FLOW
(lbmole/hr)

23

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.333e-002

LIQUID VOLUME
FRACTION

24

Methanol

0.0004

0.0000

0.0139

0.0000

0.0012

0.0000

25

Ethanol

0.0000

0.0000

0.0001

0.0000

0.0000

0.0000

26

diM-Ether

12.7452

1.0000

587.1565

1.0000

59.9793

1.0000

27

H2O

0.0000

0.0000

0.0000

0.0000

0.0000

0.0000

28

Total

12.7456

1.0000

587.1706

1.0000

59.9805

1.0000

Phase Fraction

0.9867

29

Liquid Phase

30
31

COMPONENTS

MOLAR FLOW
(lbmole/hr)

32

MOLE FRACTION

MASS FLOW
(lb/hr)

MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

LIQUID VOLUME
FRACTION

33

Methanol

0.9382

0.0010

30.0616

0.0007

2.5868

0.0006

34

Ethanol

0.0100

0.0000

0.4626

0.0000

0.0398

0.0000

35

diM-Ether

942.3289

0.9990

43412.1493

0.9993

4434.6469

0.9994

36

H2O

0.0075

0.0000

0.1346

0.0000

0.0092

0.0000

37

Total

943.2846

1.0000

43442.8081

1.0000

4437.2828

1.0000

38

K VALUE

39
40

COMPONENTS

41

MIXED

LIGHT

HEAVY

Methanol

3.431e-002

3.431e-002

42

Ethanol

1.988e-002

1.988e-002

43

diM-Ether

1.001

1.001

44

H2O

1.237e-002

1.237e-002

45

UNIT OPERATIONS

46
47

FEED TO

PRODUCT FROM

48

Valve:

49

LOGICAL CONNECTION
VLV-102

UTILITIES

50
51

( No utilities reference this stream )

52

PROCESS UTILITY

53
54
55

DYNAMICS

56
57

Pressure Specification

(Inactive)

58

Flow Specification

(Inactive) Molar:

59

131.7 psia
956.0 lbmole/hr

Mass:

4.403e+004 lb/hr

Std Ideal Liq Volume:4497 barrel/day

User Variables

60
61

NOTES

62
63
64

Description

65
66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 31 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: P-R

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Overall

12

Vapour / Phase Fraction

13

Temperature:

14

Pressure:

15

Vapour Phase

Aqueous Phase

0.0000

0.0000

1.0000

(F)

248.0

248.0

248.0

(psia)

152.3

152.3

152.3

Molar Flow

(lbmole/hr)

1043

0.0000

1043

16

Mass Flow

(lb/hr)

2.265e+004

0.0000

2.265e+004

17

Std Ideal Liq Vol Flow

18

Molar Enthalpy

19

Molar Entropy

20

Heat Flow

21

Liq Vol Flow @Std Cond

(barrel/day)

1753

0.0000

1753

(Btu/lbmole)

-1.144e+005

-8.105e+004

-1.144e+005

(Btu/lbmole-F)

13.25

44.88

13.25

(Btu/hr)

-1.193e+008

0.0000

-1.193e+008

0.0000

1704

1704 *

(barrel/day)

22

PROPERTIES

23
24

Overall

25

Molecular Weight

26

Molar Density

27

Mass Density

28

Act. Volume Flow

29

Mass Enthalpy

30
31
32

Mass Heat Capacity

33

Lower Heating Value

34

Mass Lower Heating Value

35

Phase Fraction [Vol. Basis]

36

Phase Fraction [Mass Basis]

37

Partial Pressure of CO2

38
39
40

Avg. Liq. Density

41

Specific Heat

42

Std. Gas Flow

43

Std. Ideal Liq. Mass Density

44

Act. Liq. Flow

45

Z Factor

46

Watson K

47

User Property

48

Partial Pressure of H2S

49

Cp/(Cp - R)

50

Cp/Cv

51

Heat of Vap.

52

Kinematic Viscosity

53

Liq. Mass Density (Std. Cond)

54

Liq. Vol. Flow (Std. Cond)

55

Liquid Fraction

56

Molar Volume

57

Mass Heat of Vap.

58

Phase Fraction [Molar Basis]

59

Surface Tension

60

Thermal Conductivity

61

Viscosity

62

Cv (Semi-Ideal)

63

Mass Cv (Semi-Ideal)

64

Cv

65

Mass Cv

66

Cv (Ent. Method)

67

Mass Cv (Ent. Method)

68

Cp/Cv (Ent. Method)

69

Fluid Package:

Vapour Phase

Aqueous Phase

21.72

40.75

21.72

(lbmole/ft3)

2.335

2.005e-002

2.335

(lb/ft3)

50.73

0.8173

50.73

(barrel/day)

1909

0.0000

1909

(Btu/lb)

-5265

-1989

-5265

Mass Entropy

(Btu/lb-F)

0.6100

1.101

0.6100

Heat Capacity

(Btu/lbmole-F)

23.71

17.07

23.71

(Btu/lb-F)

1.091

0.4190

1.091

(Btu/lbmole)

7.476e+004

4.623e+005

7.476e+004

(Btu/lb)

3442

1.134e+004

4.941e-324

0.0000

1.000

0.0000

0.0000

0.0000

(psia)

0.0000

Cost Based on Flow

(Cost/s)

Act. Gas Flow

(ACFM)

Hyprotech Ltd.
Licensed to: LEGENDS

3442
1.000

(lbmole/ft3)

2.543

1.059

2.543

(Btu/lbmole-F)

23.71

17.07

23.71

(MMSCFD)

9.478

0.0000

9.478

(lb/ft3)

55.24

43.16

55.24

(USGPM)

55.67
1.000

8.588e-003

11.37

11.25

1.091

1.132

1.091

1.180

1.132

1.180

11.25
(psia)

55.67

0.0000

(Btu/lbmole)

1.637e+004

(cSt)

0.1966

0.8871

0.1966

(lb/ft3)

56.82

40.98

56.82

(barrel/day)

1704

0.0000

1704

1.000

0.0000

1.000

(ft3/lbmole)

0.4282

49.87

0.4282

(Btu/lb)

753.4
0.0000

1.0000

0.0000
(dyne/cm)

46.98

(Btu/hr-ft-F)

0.3081

1.477e-002

0.3081
0.1598

46.98

(cP)

0.1598

1.161e-002

(Btu/lbmole-F)

21.72

15.09

21.72

(Btu/lb-F)

0.9999

0.3702

0.9999

(Btu/lbmole-F)

20.09

15.09

20.09

(Btu/lb-F)

0.9248

0.3702

0.9248

(Btu/lbmole-F)
(Btu/lb-F)

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 32 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: P-R (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

PROPERTIES

10
11

Overall

Vapour Phase

Aqueous Phase

12

Reid VP at 37.8 C

(psia)

77.14

113.1

77.14

13

True VP at 37.8 C

(psia)

22.60

94.98

22.60

14

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

1704

0.0000

1704

15

Viscosity Index

16

COMPOSITION

17
18

Overall Phase

19
20

Fluid Package:

COMPONENTS

MOLAR FLOW
(lbmole/hr)

21
22

Methanol

23

Ethanol

24

MOLE FRACTION

MASS FLOW
(lb/hr)

Vapour Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

52.5287

0.0504

1683.1186

0.0743

144.8347

0.0826

4.0962

0.0039

188.7114

0.0083

16.2336

0.0093

diM-Ether

107.4486

0.1031

4950.0491

0.2186

505.6584

0.2885

25

H2O

878.5611

0.8426

15827.3669

0.6988

1085.9316

0.6196

26

Total

1042.6346

1.0000

22649.2460

1.0000

1752.6584

1.0000

27

Vapour Phase

28
29

COMPONENTS

MOLAR FLOW
(lbmole/hr)

30

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

0.0000

LIQUID VOLUME
FRACTION

31

Methanol

0.0000

0.0444

0.0000

0.0349

0.0000

0.0303

32

Ethanol

0.0000

0.0041

0.0000

0.0046

0.0000

0.0040

33

diM-Ether

0.0000

0.7843

0.0000

0.8866

0.0000

0.9144

34

H2O

0.0000

0.1673

0.0000

0.0739

0.0000

0.0512

35

Total

0.0000

1.0000

0.0000

1.0000

0.0000

1.0000

36

Aqueous Phase

37
38

COMPONENTS

MOLAR FLOW
(lbmole/hr)

39
40

Methanol

41

Ethanol

42

MOLE FRACTION

MASS FLOW
(lb/hr)

Phase Fraction
MASS FRACTION

LIQUID VOLUME
FLOW (barrel/day)

1.000

LIQUID VOLUME
FRACTION

52.5287

0.0504

1683.1186

0.0743

144.8347

0.0826

4.0962

0.0039

188.7114

0.0083

16.2336

0.0093

diM-Ether

107.4486

0.1031

4950.0491

0.2186

505.6584

0.2885

43

H2O

878.5611

0.8426

15827.3669

0.6988

1085.9316

0.6196

44

Total

1042.6346

1.0000

22649.2460

1.0000

1752.6584

1.0000

45

K VALUE

46
47

COMPONENTS

MIXED

LIGHT

HEAVY

48

Methanol

0.8812

0.8812

49

Ethanol

1.038

1.038

50

diM-Ether

7.610

7.610

51

H2O

0.1985

0.1985

52

UNIT OPERATIONS

53
54

FEED TO

PRODUCT FROM

55

Equilibrium Reactor:

56

LOGICAL CONNECTION
ERV-100

UTILITIES

57
58

( No utilities reference this stream )

59

PROCESS UTILITY

60
61
62

DYNAMICS

63
64

Pressure Specification

(Inactive)

65

Flow Specification

(Inactive) Molar:

66

1043 lbmole/hr

Mass:

2.265e+004 lb/hr

Std Ideal Liq Volume:1753 barrel/day

User Variables

67

NOTES

68
69

152.3 psia

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 33 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Material Stream: P-R (continued)

7
8

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

NOTES

9
10
11

Description

12
13
14

Energy Stream: Q1

15
16
17

CONDITIONS

18
19

Duty Type:

20

Duty SP:

Direct Q
9.883e+006 Btu/hr

Duty Calculation Operation:

21

Maximum Available Duty:

COMPOSITION

22
23

( Not a material stream - No compositions exist )

24

UNIT OPERATIONS

25
26
27

E-100

Minimum Available Duty:

FEED TO

PRODUCT FROM

Heater:

LOGICAL CONNECTION

E-100

28

UTILITIES

29
30

( No utilities reference this stream )

31

PROCESS UTILITY

32
33
34

DYNAMICS

35
36

Pressure Specification

(Inactive)

37

Flow Specification

(Inactive) Molar:

Mass:

38

Std Ideal Liq Volume:

User Variables

39
40

NOTES

41
42
43

Description

44
45
46

Energy Stream: Q2

47
48
49

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

50
51

Duty Type:

52

Duty SP:

Direct Q
1.163e+007 Btu/hr

53

Duty Calculation Operation:

ERV-100

Minimum Available Duty:

Maximum Available Duty:

COMPOSITION

54
55

( Not a material stream - No compositions exist )

56

UNIT OPERATIONS

57
58
59

Fluid Package:

FEED TO
Equilibrium Reactor:

PRODUCT FROM

LOGICAL CONNECTION

ERV-100

60

UTILITIES

61
62

( No utilities reference this stream )

63

PROCESS UTILITY

64
65
66

DYNAMICS

67
68

Pressure Specification

69

Hyprotech Ltd.
Licensed to: LEGENDS

(Inactive)

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 34 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Energy Stream: Q2 (continued)

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

DYNAMICS

10
11

Fluid Package:

Flow Specification

(Inactive) Molar:

Mass:

12

Std Ideal Liq Volume:

User Variables

13
14

NOTES

15
16
17

Description

18
19
20

Energy Stream: Q3

21
22
23

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

24
25

Duty Type:

26

Duty SP:

Direct Q
5.013e+006 Btu/hr

Duty Calculation Operation:

E-101

Minimum Available Duty:

27

Maximum Available Duty:

COMPOSITION

28
29

( Not a material stream - No compositions exist )

30

UNIT OPERATIONS

31
32

FEED TO

PRODUCT FROM

33

Cooler:

LOGICAL CONNECTION
E-101

34

UTILITIES

35
36

( No utilities reference this stream )

37

PROCESS UTILITY

38
39
40

DYNAMICS

41
42

Pressure Specification

(Inactive)

43

Flow Specification

(Inactive) Molar:

Mass:

44

Std Ideal Liq Volume:

User Variables

45
46

NOTES

47
48
49

Description

50
51
52

Energy Stream: Q4

53
54
55

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

56
57

Duty Type:

58

Duty SP:

Direct Q
6.041e+007 Btu/hr

Duty Calculation Operation:

Condenser @COL1

Minimum Available Duty:

59

Maximum Available Duty:

COMPOSITION

60
61

( Not a material stream - No compositions exist )

62

UNIT OPERATIONS

63
64

FEED TO

65

PRODUCT FROM
Distillation:

66

LOGICAL CONNECTION
T-100

UTILITIES

67
68
69

Fluid Package:

( No utilities reference this stream )

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 35 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Energy Stream: Q4 (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

PROCESS UTILITY

10
11
12

DYNAMICS

13
14

Pressure Specification

(Inactive)

15

Flow Specification

(Inactive) Molar:

Mass:

16

Std Ideal Liq Volume:

User Variables

17
18

NOTES

19
20
21

Description

22
23
24

Energy Stream: Q5

25
26
27

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

28
29

Duty Type:

30

Duty SP:

Direct Q
5.166e+007 Btu/hr

Duty Calculation Operation:

Reboiler @COL1

Minimum Available Duty:

31

Maximum Available Duty:

COMPOSITION

32
33

( Not a material stream - No compositions exist )

34

UNIT OPERATIONS

35
36
37

Fluid Package:

FEED TO

PRODUCT FROM

Distillation:

LOGICAL CONNECTION

T-100

38

UTILITIES

39
40

( No utilities reference this stream )

41

PROCESS UTILITY

42
43
44

DYNAMICS

45
46

Pressure Specification

(Inactive)

47

Flow Specification

(Inactive) Molar:

Mass:

48

Std Ideal Liq Volume:

User Variables

49
50

NOTES

51
52
53

Description

54
55
56

Energy Stream: Q6

57
58
59

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

60
61

Duty Type:

62

Duty SP:

63

Direct Q
3.402e+013 Btu/hr

Duty Calculation Operation:

Condenser @COL2

Minimum Available Duty:

Maximum Available Duty:

COMPOSITION

64
65

( Not a material stream - No compositions exist )

66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 36 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Energy Stream: Q6 (continued)

7
8
9

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

UNIT OPERATIONS

10
11

FEED TO

PRODUCT FROM

12

Distillation:

13

LOGICAL CONNECTION
T-101

UTILITIES

14
15

( No utilities reference this stream )

16

PROCESS UTILITY

17
18
19

DYNAMICS

20
21

Pressure Specification

(Inactive)

22

Flow Specification

(Inactive) Molar:

Mass:

23

Std Ideal Liq Volume:

User Variables

24
25

NOTES

26
27
28

Description

29
30
31

Energy Stream: Q7

32
33
34

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

35
36

Duty Type:

37

Duty SP:

Direct Q
3.402e+013 Btu/hr

38

Duty Calculation Operation:

Reboiler @COL2

Minimum Available Duty:

Maximum Available Duty:

COMPOSITION

39
40

( Not a material stream - No compositions exist )

41

UNIT OPERATIONS

42
43
44

Fluid Package:

FEED TO
Distillation:

PRODUCT FROM

LOGICAL CONNECTION

T-101

45

UTILITIES

46
47

( No utilities reference this stream )

48

PROCESS UTILITY

49
50
51

DYNAMICS

52
53

Pressure Specification

(Inactive)

54

Flow Specification

(Inactive) Molar:

55

Mass:

Std Ideal Liq Volume:

User Variables

56
57

NOTES

58
59
60

Description

61
62
63
64
65
66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 37 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Energy Stream: Q-100

7
8
9

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

10
11

Duty Type:

12

Duty SP:

Direct Q
1372 Btu/hr

Duty Calculation Operation:

P-101

Minimum Available Duty:

13

Maximum Available Duty:

COMPOSITION

14
15

( Not a material stream - No compositions exist )

16

UNIT OPERATIONS

17
18
19

Fluid Package:

FEED TO

PRODUCT FROM

Pump:

LOGICAL CONNECTION

P-101

20

UTILITIES

21
22

( No utilities reference this stream )

23

PROCESS UTILITY

24
25
26

DYNAMICS

27
28

Pressure Specification

(Inactive)

29

Flow Specification

(Inactive) Molar:

Mass:

30

Std Ideal Liq Volume:

User Variables

31
32

NOTES

33
34
35

Description

36
37
38

Energy Stream: W1

39
40
41

Basis-1

Property Package:

UNIQUAC - Ideal

CONDITIONS

42
43

Duty Type:

44

Duty SP:

Direct Q
4.993e+004 Btu/hr

45

Duty Calculation Operation:

P-100

Minimum Available Duty:

Maximum Available Duty:

COMPOSITION

46
47

( Not a material stream - No compositions exist )

48

UNIT OPERATIONS

49
50
51

Fluid Package:

FEED TO
Pump:

PRODUCT FROM

LOGICAL CONNECTION

P-100

52

UTILITIES

53
54

( No utilities reference this stream )

55

PROCESS UTILITY

56
57
58

DYNAMICS

59
60

Pressure Specification

(Inactive)

61

Flow Specification

(Inactive) Molar:

62

Mass:

Std Ideal Liq Volume:

User Variables

63
64

NOTES

65
66
67

Description

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 38 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Energy Stream: W1 (continued)

7
8

Fluid Package:

Basis-1

Property Package:

UNIQUAC - Ideal

9
10

Recycle: RCY-1

11
12
13

CONNECTIONS

14
15

Inlet Stream

16

Stream Name

17
18

From Unit Operation

12

Pump

P-101

19

Outlet Stream

20

Stream Name

21
22

To Unit Operation

13

Mixer

MIX-100

23

TOLERANCE

24
25

Vapour Fraction:

10.00 *

Temperature:

10.00 *

Pressure:

10.00 *

26

Flow:

10.00 *

Enthalpy:

10.00 *

Composition:

10.00 *

Q Maximum:

0.0000 *

27

NUMERICAL

28
29

Acceleration Type:

30

Maximum Iterations:

31

Wegstein Count:

Wegstein

Iteration Type:

10 *

Nested
0*

Iteration Count:

3*

-20.00 *

Q Minimum:

32

Iteration History

33
34

Iteration

35

Variable
*

Outlet Value

Inlet Value

Converged

36

User Variables

37
38

CONDITIONS

39
40

Name

41

Vapour

42

Temperature

43

Pressure

44

Molar Flow

(lbmole/hr)

55.7982

45

Mass Flow

(lb/hr)

1820.3521

46

Std Ideal Liq Vol Flow

47

Molar Enthalpy

48

Molar Entropy

49

Heat Flow

(F)
(psia)

12

13

0.0000

0.0000

93.5826

93.5961 *

152.2896 *

152.2896 *
55.8412 *
1822.1187

(barrel/day)

156.5898

156.7396

(Btu/lbmole)

-1.033e+005

-1.033e+005

(Btu/lbmole-F)

17.57

17.57

(Btu/hr)

-5.7633e+06

-5.7684e+06

50

PROPERTIES

51
52

Name

53

Molecular Weight

54

Molar Density

55

Mass Density

56

Act. Volume Flow

57

Mass Enthalpy

58
59
60

Mass Heat Capacity

61

Lower Heating Value

62

Mass Lower Heating Value

63

Phase Fraction [Vol. Basis]

64

Phase Fraction [Mass Basis]

65

Partial Pressure of CO2

66

12

13
32.62

32.63

(lbmole/ft3)

1.490

1.490

(lb/ft3)

48.62

48.62

(barrel/day)

160.0

160.2

(Btu/lb)

-3166

-3166

Mass Entropy

(Btu/lb-F)

0.5385

0.5384

Heat Capacity

(Btu/lbmole-F)

28.17

28.17

(Btu/lb-F)

0.8633

0.8633

(Btu/lbmole)

2.849e+005

2.851e+005

(Btu/lb)

8734

8736

2.122e-314

2.122e-314

(psia)

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

67

Act. Gas Flow

(ACFM)

68

Avg. Liq. Density

1.523

1.523

69

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 39 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Recycle: RCY-1 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Specific Heat

13

Std. Gas Flow

14

Std. Ideal Liq. Mass Density

15

Act. Liq. Flow

16

Z Factor

17

Watson K

18

User Property

19

Partial Pressure of H2S

20

Cp/(Cp - R)

21

Cp/Cv

1.337

1.337

22

Heat of Vap.

(Btu/lbmole)

1.275e+004

1.276e+004

23

Kinematic Viscosity

24

Liq. Mass Density (Std. Cond)

25

Liq. Vol. Flow (Std. Cond)

26

Liquid Fraction

27

Molar Volume

28

Mass Heat of Vap.

29

Phase Fraction [Molar Basis]

30

Surface Tension

31

Thermal Conductivity

32

Viscosity

33

Cv (Semi-Ideal)

34

Mass Cv (Semi-Ideal)

35

Cv

36

Mass Cv

37

Cv (Ent. Method)

38

Mass Cv (Ent. Method)

39

Cp/Cv (Ent. Method)

40

Reid VP at 37.8 C

(psia)

41

True VP at 37.8 C

42
43

Viscosity Index

12

13

(Btu/lbmole-F)

28.17

28.17

(MMSCFD)

0.5072

0.5076

(lb/ft3)

49.69

49.69

(USGPM)

4.668

4.672

1.721e-002

1.721e-002

10.63

10.63

0.0000

0.0000

1.076

1.076

(psia)

(cSt)

0.6371

0.6373

(lb/ft3)

49.83

49.83

(barrel/day)

156.2

156.3

(ft3/lbmole)
(Btu/lb)

1.000

1.000

0.6710

0.6711

390.9

390.9

0.0000

0.0000

(dyne/cm)

27.97

27.97

(Btu/hr-ft-F)

0.1016

0.1016
0.4963

(cP)

0.4962

(Btu/lbmole-F)

26.18

26.18

(Btu/lb-F)

0.8025

0.8024

(Btu/lbmole-F)

21.07

21.08

(Btu/lb-F)

0.6457

0.6459

(psia)

4.570

4.562

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

156.2

156.3

-1.766

-1.766

(Btu/lbmole-F)
(Btu/lb-F)

44

Heater: E-100

45
46
47

CONNECTIONS

48
49

Inlet Stream

50

STREAM NAME

51
52

FROM UNIT OPERATION

Mixer

53

Outlet Stream

54

STREAM NAME

55
56

TO UNIT OPERATION

Equilibrium Reactor

57

STREAM NAME

59

FROM UNIT OPERATION

Q1

61

PARAMETERS

62
63

Pressure Drop:

64

Function:

65

0.0000 psi *
Not Selected

Duty:

9.883e+006 Btu/hr

Zones:

Volume:

3.531 ft3

User Variables

66
67

RATING

68
69

ERV-100

Energy Stream

58

60

MIX-100

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 40 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Heater: E-100 (continued)

7
8
9

NOZZLE PARAMETERS

10
11

0.0000 ft *

Base Elevation Relative to Ground Level

12

13

Diameter

(ft)

0.1640

0.1640

14

Elevation (Base)

(ft)

0.0000

0.0000

15

Elevation (Ground)

(ft)

0.0000

0.0000

16

CONDITIONS

17
18

Name

19

Vapour

20

Temperature

21

Pressure

22

Molar Flow

23

Mass Flow

24

Std Ideal Liq Vol Flow

25

Molar Enthalpy

26

Molar Entropy

27

Heat Flow

0.0000

0.0406
192.2000 *

(F)

25.9755

(psia)

152.2896

152.2896

(lbmole/hr)

2260.4412

2260.4412
72279.8876

(lb/hr)

72279.8876

(barrel/day)

6587.4213

6587.4213

(Btu/lbmole)

-1.059e+005

-1.016e+005

(Btu/lbmole-F)

-78.13

26.93

(Btu/hr)

-2.3947e+08

-2.2959e+08

28

Q1

9.8829e+06

PROPERTIES

29
30

Name

31

Molecular Weight

32

Molar Density

33

Mass Density

34

Act. Volume Flow

35

Mass Enthalpy

(Btu/lb)

-3313

-3176

36

Mass Entropy

(Btu/lb-F)

-2.443

0.8422

37

Heat Capacity

(Btu/lbmole-F)

22.71

26.74

38

Mass Heat Capacity

(Btu/lb-F)

0.7101

0.8362

39

Lower Heating Value

(Btu/lbmole)

2.817e+005

2.817e+005

40

Mass Lower Heating Value

(Btu/lb)

8808

41

Phase Fraction [Vol. Basis]

42

Phase Fraction [Mass Basis]

43

Partial Pressure of CO2

44

4
31.98

31.98

(lbmole/ft3)

1.501

0.3861

(lb/ft3)

47.99

12.35

(barrel/day)

6438

2.502e+004

8808
6.243e-002

2.122e-314

5.631e-002

(psia)

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

45

Act. Gas Flow

(ACFM)

46

Avg. Liq. Density

47

Specific Heat

48

Std. Gas Flow

49

Std. Ideal Liq. Mass Density

50

Act. Liq. Flow

51

Z Factor

52

Watson K

53

User Property

54

Partial Pressure of H2S

55

Cp/(Cp - R)

56

Cp/Cv

1.233

1.005

57

Heat of Vap.

(Btu/lbmole)

1.424e+004

1.424e+004

58

Kinematic Viscosity

59

Liq. Mass Density (Std. Cond)

60

Liq. Vol. Flow (Std. Cond)

61

Liquid Fraction

62

Molar Volume

63

Mass Heat of Vap.

64

Phase Fraction [Molar Basis]

65

Surface Tension

66

Thermal Conductivity

67

Viscosity

68

Cv (Semi-Ideal)

69

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

1.467

1.467

(Btu/lbmole-F)

22.71

26.74

(MMSCFD)

20.55

20.55

(lb/ft3)

46.90

46.90

(USGPM)

187.8

204.3

1.947e-002

(psia)

11.25

11.25

0.0000

0.0000

1.096

1.080

(cSt)

0.5142

(lb/ft3)

46.73

(barrel/day)

6612

6612

1.000

0.9594

(ft3/lbmole)

0.6663

2.590

(Btu/lb)

445.2

445.2

0.0000

0.0406
30.60

(dyne/cm)

43.98

(Btu/hr-ft-F)

0.1648

(cP)

0.3953

(Btu/lbmole-F)

20.72

46.73

24.75

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 41 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Heater: E-100 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Mass Cv (Semi-Ideal)

13

Cv

14

Mass Cv

15

Cv (Ent. Method)

16

Mass Cv (Ent. Method)

17

Cp/Cv (Ent. Method)

18

Reid VP at 37.8 C

(psia)

75.07

75.07

19

True VP at 37.8 C

(psia)

47.83

47.83

20

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

6612

6626

21

Viscosity Index

(Btu/lb-F)

0.6480

(Btu/lbmole-F)

18.42

26.60

(Btu/lb-F)

0.5760

0.8320

(Btu/lbmole-F)

393.9

(Btu/lb-F)

12.32
5.765e-002

-2.314

22

PERFORMANCE PROFILES

23
24

0.7741

Zone

Pressure
(psia)

25

Temperature
(F)

Vapour Fraction

Enthalpy
(Btu/lbmole)

26

Inlet

152.29

25.98

0.0000

-105940.60

27

152.29

192.20

0.0406

-101568.53

28

PERFORMANCE PLOT

29
30
31

157.0

32
33

156.0

34
35

155.0

36

38
39
40
41
42
43

154.0

Pressure (psia)

37

153.0
152.0
151.0
150.0

44
45

149.0

46

148.0

47
48

147.0
20.00

49

40.00

60.00

80.00

100.0

120.0

140.0

160.0

180.0

200.0

50

Temperature (F)

51
52
53

PERFORMANCE TABLE

54
55

Overall Phase

56
57
58

Temperature
(F)

Pressure
(psia)

Heat Flow
(Btu/hr)

Enthalpy
(Btu/lbmole)

Vapour Fraction

59

25.98

152.29

0.00

-105940.60

0.0000

60

192.20

152.29

9882901.31

-101568.53

0.0406

61

Vapour Phase

62
63
64

Mass Flow
(lb/hr)

Molecular Weight

Density
(lb/ft3)

Mass Specific Heat

(Btu/lb-F)

Viscosity
(cP)

Thermal Conductivity
(Btu/hr-ft-F)

65
66

4069.77

44.34

0.97

0.39

0.01

0.01

67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 42 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Heater: E-100 (continued)

7
8
9

PERFORMANCE TABLE

10
11

Light Liquid Phase

12
13

Mass Flow
(lb/hr)

14

Density
(lb/ft3)

Mass Specific Heat

(Btu/lb-F)

Viscosity
(cP)

15

72279.89

47.99

0.71

16

68210.12

41.63

0.86

17

Thermal Conductivity
(Btu/hr-ft-F)

Surface Tension
(dyne/cm)
43.98

0.14

0.15

30.60

Heavy Liquid Phase

18
19

Mass Flow
(lb/hr)

20

Density
(lb/ft3)

Mass Specific Heat

(Btu/lb-F)

Viscosity
(cP)

Thermal Conductivity
(Btu/hr-ft-F)

Surface Tension
(dyne/cm)

21
22
23

DYNAMICS

24
25

Model Details: Supplied Duty

26
27

Zone

28

Volume

29

Duty

1*
3.531 *

(ft3)
(Btu/hr)

(psi)

0.0000 *

(lb/hr/sqrt(psia-lb/ft3))

8.341e-002 *

Delta P
Overall K

9.883e+006

30

Holdup Details

31
32

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

Volume
(ft3)

34

Vapour

0.0000

0.0000

0.0000

35

Liquid

0.0000

0.0000

0.0000

36

Aqueous

0.0000

0.0000

0.0000

37

Total

0.0000

0.0000

0.0000

33

38

Individual Zone Holdups: Zone 0

39
40

Delta P Specs and Duties

41
42

Zone

dP Value
(psi)

43
44

0.0000

45

dP Option

Duty
(Btu/hr)

not specified

3.658e+006

Zone Conductance Specifications

46
47

Zone

48
49

k
(lb/hr/sqrt(psia-lb/ft3))

Specification

8.341e-002

Disabled

50

NOTES

51
52
53

Cooler: E-101

54
55
56

CONNECTIONS

57
58

Inlet Stream

59

STREAM NAME

60
61

62

STREAM NAME

64

TO UNIT OPERATION
Distillation

66

T-100

Energy Stream

67

STREAM NAME

68
69

VLV-100

Outlet Stream

63

65

FROM UNIT OPERATION

Valve

Hyprotech Ltd.
Licensed to: LEGENDS

TO UNIT OPERATION

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 43 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Cooler: E-101 (continued)

7
8
9

CONNECTIONS

10
11

Q3

12

PARAMETERS

13
14

Pressure Drop:

15

Function:

0.0000 psi

Duty:

Not Selected

16

Volume:

3.531 ft3

User Variables

17
18

NOZZLE PARAMETERS

19
20

5.013e+006 Btu/hr

Zones:

0.0000 ft *

Base Elevation Relative to Ground Level

21

22

Diameter

(ft)

0.1640

0.1640

23

Elevation (Base)

(ft)

0.0000

0.0000

24

Elevation (Ground)

(ft)

0.0000

0.0000

25

CONDITIONS

26
27

Name

28

Vapour

29

Temperature

30

Pressure

31

Molar Flow

32

Mass Flow

33

Std Ideal Liq Vol Flow

34

Molar Enthalpy

35

Molar Entropy

36

Heat Flow

(F)

1.0000

0.7672
192.2000 *

247.9137
145.0377 *

(psia)

145.0377 *

(lbmole/hr)

1217.8072

1217.8072
49630.7168

(lb/hr)

49630.7168

(barrel/day)

4915.2307

4915.2307

(Btu/lbmole)

-8.105e+004

-8.516e+004

(Btu/lbmole-F)

44.98

39.62

(Btu/hr)

-9.8701e+07

-1.0371e+08

37

Q3

5.0133e+06

PROPERTIES

38
39

Name

40

Molecular Weight

41

Molar Density

42

Mass Density

43

Act. Volume Flow

44

Mass Enthalpy

45

Mass Entropy

46

Heat Capacity

(Btu/lbmole-F)

17.06

19.13

47

Mass Heat Capacity

(Btu/lb-F)

0.4186

0.4694

48

Lower Heating Value

(Btu/lbmole)

4.623e+005

4.623e+005

49

Mass Lower Heating Value

(Btu/lb)

1.134e+004

1.134e+004

50

Phase Fraction [Vol. Basis]

51

Phase Fraction [Mass Basis]

52

Partial Pressure of CO2

53

6
(lbmole/ft3)

7
40.75

40.75

1.910e-002

2.691e-002

(lb/ft3)

0.7784

1.097

(barrel/day)

2.725e+005

1.934e+005

(Btu/lb)

-1989

-2090

(Btu/lb-F)

1.104

0.9722

0.8533
4.941e-324

0.8354

(psia)

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

54

Act. Gas Flow

(ACFM)

1063

55

Avg. Liq. Density

56

Specific Heat

57

Std. Gas Flow

58

Std. Ideal Liq. Mass Density

59

Act. Liq. Flow

60

Z Factor

1.000

61

Watson K

11.37

11.37

62

User Property

63

Partial Pressure of H2S

0.0000

0.0000

64

Cp/(Cp - R)

1.132

1.116

65

Cp/Cv

1.132

1.087

66

Heat of Vap.

(Btu/lbmole)

1.166e+004

1.166e+004

67

Kinematic Viscosity

(cSt)

0.9297

68

Liq. Mass Density (Std. Cond)

69

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

1.059

1.059

(Btu/lbmole-F)

17.06

19.13

(MMSCFD)

11.07

11.07

(lb/ft3)

43.16

43.16

(USGPM)

(psia)

(lb/ft3)

23.28

40.98

40.98

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 44 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Cooler: E-101 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Liq. Vol. Flow (Std. Cond)

13

Liquid Fraction

14

Molar Volume

15

Mass Heat of Vap.

16

Phase Fraction [Molar Basis]

17

Surface Tension

18

Thermal Conductivity

19

Viscosity

20

Cv (Semi-Ideal)

21

Mass Cv (Semi-Ideal)

22

Cv

23

Mass Cv

24

Cv (Ent. Method)

25

Mass Cv (Ent. Method)

26

Cp/Cv (Ent. Method)

27

Reid VP at 37.8 C

28

True VP at 37.8 C

6
(barrel/day)

7
5177

5177

0.0000

0.2328

(ft3/lbmole)

52.35

37.16

(Btu/lb)

286.2

286.2

1.0000

0.7672

(dyne/cm)

37.52

(Btu/hr-ft-F)

1.474e-002

(cP)

1.159e-002

(Btu/lbmole-F)

15.07

17.14

(Btu/lb-F)

0.3698

0.4207

(Btu/lbmole-F)

15.07

17.60

(Btu/lb-F)

0.3698

0.4318

(psia)

113.1

113.1

(psia)

94.98

94.98

29

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

5177

5218

30

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

31

PERFORMANCE PROFILES

32
33

Zone

Pressure
(psia)

34

Temperature
(F)

Vapour Fraction

Enthalpy
(Btu/lbmole)

35

Inlet

145.04

247.91

1.0000

-81047.22

36

145.04

192.20

0.7672

-85163.82

37

PERFORMANCE PLOT

38
39
40

150.0

41
42

149.0

43
44

148.0

46
47
48
49
50
51
52

Pressure (psia)

45

147.0
146.0
145.0
144.0
143.0

53
54

142.0

55

141.0

56
57

140.0
190.0

58

200.0

210.0

220.0

230.0

240.0

250.0

59

Temperature (F)

60
61
62

PERFORMANCE TABLE

63
64

Overall Phase

65
66
67

Temperature
(F)

68
69

Pressure
(psia)
247.91

Hyprotech Ltd.
Licensed to: LEGENDS

Heat Flow
(Btu/hr)
145.04

Enthalpy
(Btu/lbmole)
0.00

Aspen HYSYS Version 7.1 (23.0.0.7119)

-81047.22

Vapour Fraction
1.0000

Page 45 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Cooler: E-101 (continued)

7
8
9

PERFORMANCE TABLE

10
11

Overall Phase

12
13

Temperature
(F)

14
15

Pressure
(psia)
192.20

Heat Flow
(Btu/hr)
145.04

Enthalpy
(Btu/lbmole)

-5013275.30

16

Vapour Fraction

-85163.82

0.7672

Vapour Phase

17
18

Mass Flow
(lb/hr)

19

Molecular Weight

Density
(lb/ft3)

Mass Specific Heat

(Btu/lb-F)

20

49630.72

40.75

0.78

0.42

21

41459.89

44.37

0.92

0.39

22

Viscosity
(cP)

Thermal Conductivity
(Btu/hr-ft-F)
0.01

0.01

Light Liquid Phase

23
24

Mass Flow
(lb/hr)

25

Density
(lb/ft3)

Mass Specific Heat

(Btu/lb-F)

Viscosity
(cP)

Thermal Conductivity
(Btu/hr-ft-F)

Surface Tension
(dyne/cm)

Thermal Conductivity
(Btu/hr-ft-F)

Surface Tension
(dyne/cm)

26
27
28

Heavy Liquid Phase

29
30

Mass Flow
(lb/hr)

31

Density
(lb/ft3)

Mass Specific Heat

(Btu/lb-F)

Viscosity
(cP)

32
33

8170.83

43.75

0.87

34

0.20

37.52

DYNAMICS

35
36

Model Details: Supplied Duty

37
38

Zone

39

Volume

40

Duty

1*
3.531 *

(ft3)
(Btu/hr)

Delta P

(psi)

Overall K

0.0000
8.341e-002 *

(lb/hr/sqrt(psia-lb/ft3))

5.013e+006

41

Holdup Details

42
43

0.15

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

Volume
(ft3)

45

Vapour

0.0000

0.0000

0.0000

46

Liquid

0.0000

0.0000

0.0000

47

Aqueous

0.0000

0.0000

0.0000

48

Total

0.0000

0.0000

0.0000

44

49

Individual Zone Holdups: Zone 0

50
51

Delta P Specs and Duties

52
53

Zone

dP Value
(psi)

54
55

0.0000

56

dP Option

Duty
(Btu/hr)

not specified

-6.196e+006

Zone Conductance Specifications

57
58

Zone

59
60

61

k
(lb/hr/sqrt(psia-lb/ft3))

Specification

8.341e-002

Disabled

NOTES

62
63
64
65
66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 46 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Equilibrium Reactor: ERV-100

7
8
9

CONNECTIONS

10
11

Inlet Stream Connections

12

Stream Name

13
14

From Unit Operation

Heater

15

Outlet Stream Connections

16

Stream Name

17
18
19

To Unit Operation

5
P-R

Valve:

20

VLV-100

Energy Stream Connections

21

Stream Name

22
23

E-100

From Unit Operation

Q2

24

PARAMETERS

25
26

Physical Parameters

27

Delta P

28

0.0000 psi

Optional Heat Transfer:

Vessel Volume

29

Heating

Duty

Energy Stream

1.163e+007 Btu/hr

Q2

User Variables

30
31

REACTION DETAILS

32
33

Component

Molecular Weight

Stoichiometric Coefficient

34

Methanol

32.04

-2 *

35

diM-Ether

46.07

1*

36

H2O

18.02

1*

37

REACTION RESULTS FOR :

38
39

Set-1

Extents

40
41

Act. % Conv.

42

Rxn-2

Base Comp.
77.93

Eqm Constant

Methanol

43

Rxn Extent (lbmole/hr)

66.55

188.2

Balance

44
45

Total Inflow
(lbmole/hr)

46

Total Rxn
(lbmole/hr)

Total Outflow
(lbmole/hr)

47

Methanol

483.0

-376.4

106.6

48

Ethanol

9.062

-1.721e-015

9.062

49

diM-Ether

874.4

188.2

1063

50

H2O

894.1

188.2

1082

51

RATING

52
53

Sizing

54
55
56

Cylinder

Vertical

Volume

57

No

Height

Nozzles

58
59

Reactor has a Boot:

Diameter

0.0000 ft *

Base Elevation Relative to Ground Level

60

Diameter

Height

P-R

(ft)

0.1640

0.1640

0.1640

61

Diameter

62

Elevation (Base)

(ft)

0.0000

0.0000

0.0000

63

Elevation (Ground)

(ft)

0.0000

0.0000

0.0000

64

Elevation (% of Height)

(%)

65

PROPERTIES

66
67

Name

68

Molecular Weight

69

Hyprotech Ltd.
Licensed to: LEGENDS

P-R
31.98

5
21.72

Aspen HYSYS Version 7.1 (23.0.0.7119)

40.75

Page 47 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Equilibrium Reactor: ERV-100 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Molar Density

13

Mass Density

14

Act. Volume Flow

15

Mass Enthalpy

(Btu/lb)

16

Mass Entropy

(Btu/lb-F)

17

Heat Capacity

(Btu/lbmole-F)

26.74

23.71

17.07

18

Mass Heat Capacity

(Btu/lb-F)

0.8362

1.091

0.4190

19

Lower Heating Value

(Btu/lbmole)

2.817e+005

7.476e+004

4.623e+005

20

Mass Lower Heating Value

(Btu/lb)

8808

3442

1.134e+004

21

Phase Fraction [Vol. Basis]

22

Phase Fraction [Mass Basis]

23

Partial Pressure of CO2

24

4
(lbmole/ft3)

P-R

0.3861

2.335

2.005e-002

(lb/ft3)

12.35

50.73

0.8173

(barrel/day)

2.502e+004

1909

2.596e+005

-3176

-5265

-1989

0.8422

0.6100

1.101

6.243e-002
5.631e-002

4.941e-324

4.941e-324

(psia)

0.0000

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

0.0000

25

Act. Gas Flow

(ACFM)

26

Avg. Liq. Density

(lbmole/ft3)

1.467

2.543

1.059

27

Specific Heat

(Btu/lbmole-F)

26.74

23.71

17.07

28

Std. Gas Flow

(MMSCFD)

20.55

9.478

11.07

29

Std. Ideal Liq. Mass Density

(lb/ft3)

46.90

55.24

43.16

30

Act. Liq. Flow

(USGPM)

204.3

55.67

0.0000

31

Z Factor

32

Watson K

11.25

11.25

11.37

33

User Property

34

Partial Pressure of H2S

0.0000

0.0000

0.0000

35

Cp/(Cp - R)

1.080

1.091

1.132

36

Cp/Cv

1.005

1.180

1.132

37

Heat of Vap.

1.424e+004

1.637e+004

1.161e+004

38

Kinematic Viscosity

39

Liq. Mass Density (Std. Cond)

40

Liq. Vol. Flow (Std. Cond)

41

Liquid Fraction

42

Molar Volume

43

Mass Heat of Vap.

44

Phase Fraction [Molar Basis]

45

Surface Tension

46

Thermal Conductivity

47

Viscosity

48

Cv (Semi-Ideal)

49

Mass Cv (Semi-Ideal)

50

Cv

51

Mass Cv

52

Cv (Ent. Method)

53

Mass Cv (Ent. Method)

54

Cp/Cv (Ent. Method)

55

Reid VP at 37.8 C

56

True VP at 37.8 C

1012

(psia)

(Btu/lbmole)
(cSt)

0.1966

0.8871

(lb/ft3)

46.73

56.82

40.98

(barrel/day)

6612

1704

5177

0.9594

1.000

0.0000

(ft3/lbmole)

2.590

0.4282

49.87

(Btu/lb)

445.2

753.4

284.9

0.0406

0.0000

1.0000

(dyne/cm)

46.98

30.60

(Btu/hr-ft-F)

0.3081

1.477e-002

(cP)

0.1598

1.161e-002

(Btu/lbmole-F)

24.75

21.72

15.09

(Btu/lb-F)

0.7741

0.9999

0.3702

(Btu/lbmole-F)

26.60

20.09

15.09

(Btu/lb-F)

0.8320

0.9248

0.3702

(psia)

75.07

77.14

113.1

(psia)

47.83

22.60

94.98

57

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

6626

1704

5177

58

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

59

DYNAMICS

60
61

Vessel Parameters: Initialize from Product

62
63

Vessel Volume

64

Vessel Diameter

65

Vessel Height

66

Liquid Level Percent

67

Level Calculator

(ft)
(ft)
(%)

Vertical cylinder

Fraction Calculator
Feed Delta P
50.00

Vessel Pressure

Use levels and nozzles

(psi)

0.0000

(psia)

152.3

Holdup: Vessel Levels

68
69

(ft3)

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 48 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Equilibrium Reactor: ERV-100 (continued)

7
8
9

Phase

Level
(ft)

10

Percent
(%)

Volume
(ft3)

11

Vapour

0.0000

12

Liquid

0.0000

13

Aqueous

0.0000

14

Holdup: Details

15
16

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

18

Vapour

0.0000

0.0000

0.0000

19

Liquid

0.0000

0.0000

0.0000

20

Aqueous

0.0000

0.0000

21

Total

0.0000

0.0000

17

22

Duty Valve Source :

23
24
25

SP
(Btu/hr)

26

1.163e+007

Volume
(ft3)

0.0000

0.0000

Direct_Q

Min. Available
(Btu/hr)

27

Max. Available
(Btu/hr)

Liquid Heater Height as % of Vessel Volume

28
29

Top of Heater :

5.00 %

30

Bottom of Heater :

Heat Flow into the PFR:

31
32

0.00 %

Heating

NOTES

33
34
35

Mixer: MIX-100

36
37
38

CONNECTIONS

39
40

Inlet Stream

41

STREAM NAME

42
43
44

FROM UNIT OPERATION

13
2

Recycle

45

STREAM NAME

47

TO UNIT OPERATION

Heater

49

E-100

PARAMETERS

50
51

User Variables

52
53

NOZZLE PARAMETERS

54
55

P-100

Outlet Stream

46

48

RCY-1

Pump

0.0000 ft *

Base Elevation Relative to Ground Level

56

13

57

Diameter

(ft)

0.1640

0.1640

0.1640

58

Elevation (Base)

(ft)

0.0000

0.0000

0.0000

59

Elevation (Ground)

(ft)

0.0000

0.0000

0.0000

60

CONDITIONS

61
62

Name

63

Vapour

64

Temperature

65

Pressure

66

Molar Flow

(lbmole/hr)

67

Mass Flow

(lb/hr)

68

Std Ideal Liq Vol Flow

69

Hyprotech Ltd.
Licensed to: LEGENDS

13

0.0000

0.0000

0.0000

(F)

93.5961 *

23.8698

25.9755

(psia)

152.2896 *

152.2896

152.2896

(barrel/day)

55.8412 *

2204.6000

2260.4412

1822.1187

70457.7689

72279.8876

156.7396

6430.6817

6587.4213

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 49 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Mixer: MIX-100 (continued)

7
8
9

CONDITIONS

10
11

Molar Enthalpy

12

Molar Entropy

13

Heat Flow

(Btu/lbmole)

-1.033e+005

-1.060e+005

(Btu/lbmole-F)

17.57

-80.54

-78.13

(Btu/hr)

-5.7684e+06

-2.3371e+08

-2.3947e+08

14

-1.059e+005

PROPERTIES

15
16

Name

17

Molecular Weight

18

Molar Density

19

Mass Density

20

Act. Volume Flow

21

Mass Enthalpy

22
23
24

Mass Heat Capacity

25

Lower Heating Value

26

Mass Lower Heating Value

27

Phase Fraction [Vol. Basis]

28

Phase Fraction [Mass Basis]

29

Partial Pressure of CO2

30

13

32.63

31.96

31.98

(lbmole/ft3)

1.490

1.502

1.501

(lb/ft3)

48.62

47.99

47.99

(barrel/day)

160.2

6275

6438

(Btu/lb)

-3166

-3317

-3313

Mass Entropy

(Btu/lb-F)

0.5384

-2.520

-2.443

Heat Capacity

(Btu/lbmole-F)

28.17

22.56

22.71

(Btu/lb-F)

0.8633

0.7059

0.7101

(Btu/lbmole)

2.851e+005

2.816e+005

2.817e+005

(Btu/lb)

8736

8810

8808

2.122e-314

2.122e-314

2.122e-314

(psia)

0.0000

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

0.0000

31

Act. Gas Flow

(ACFM)

32

Avg. Liq. Density

33

Specific Heat

34

Std. Gas Flow

35

Std. Ideal Liq. Mass Density

36

Act. Liq. Flow

37

Z Factor

38

Watson K

39

User Property

40

Partial Pressure of H2S

41

Cp/(Cp - R)

42

Cp/Cv

43

Heat of Vap.

44

Kinematic Viscosity

45

Liq. Mass Density (Std. Cond)

46

Liq. Vol. Flow (Std. Cond)

47

Liquid Fraction

48

Molar Volume

49

Mass Heat of Vap.

50

Phase Fraction [Molar Basis]

51

Surface Tension

52

Thermal Conductivity

53

Viscosity

54

Cv (Semi-Ideal)

55

Mass Cv (Semi-Ideal)

56

Cv

57

Mass Cv

58

Cv (Ent. Method)

59

Mass Cv (Ent. Method)

60

Cp/Cv (Ent. Method)

61

Reid VP at 37.8 C

(psia)

62

True VP at 37.8 C

(psia)

4.562

63

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

156.3

6456

6612

64

Viscosity Index

-1.766

-2.328

-2.314

65

1.523

1.465

1.467

28.17

22.56

22.71

(MMSCFD)

0.5076

20.04

20.55

(lb/ft3)

49.69

46.83

46.90

(USGPM)

4.672

183.0

187.8

1.721e-002

1.954e-002

1.947e-002

10.63

11.26

11.25

0.0000

0.0000

0.0000

1.076

1.097

1.096

1.337

1.233

1.233

(Btu/lbmole)

1.276e+004

1.426e+004

1.424e+004

(psia)

(cSt)

0.6373

0.5117

0.5142

(lb/ft3)

49.83

46.65

46.73

(barrel/day)

156.3

6456

6612

1.000

1.000

1.000

(ft3/lbmole)

0.6711

0.6659

0.6663

(Btu/lb)

390.9

446.3

445.2

0.0000

0.0000

0.0000

(dyne/cm)

27.97

44.43

43.98

(Btu/hr-ft-F)

0.1016

0.1664

0.1648
0.3953

(cP)

0.4963

0.3934

(Btu/lbmole-F)

26.18

20.58

20.72

(Btu/lb-F)

0.8024

0.6438

0.6480

(Btu/lbmole-F)

21.08

18.30

18.42

(Btu/lb-F)

0.6459

0.5727

0.5760

(Btu/lbmole-F)

384.7

393.9

(Btu/lb-F)

12.04

12.32

5.864e-002

5.765e-002

78.43

75.07

49.22

47.83

DYNAMICS

66
67

Pressure Specification:

Set Outlet to Lowest Inlet

Holdup Details

68
69

(lbmole/ft3)
(Btu/lbmole-F)

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 50 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Mixer: MIX-100 (continued)

7
8

Holdup Details

9
10

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

12

Vapour

0.0000

0.0000

0.0000

13

Liquid

0.0000

0.0000

0.0000

14

Aqueous

0.0000

0.0000

15

Total

0.0000

0.0000

11

16

Volume
(ft3)

0.0000

0.0000

NOTES

17
18
19

Pump: P-100

20
21
22

CONNECTIONS

23
24

Inlet Stream

25

Stream Name

26
27

From Unit Operation

28

Outlet Stream

29

Stream Name

30
31

To Unit Operation

Mixer

32

Energy Stream

33

Stream Name

34
35

From Unit Operation

W1

36

PARAMETERS

37
38

MIX-100

Adiabatic Efficiency (%):

75.00

137.8 psi *

Delta P:

39

41

Delta P:

42

Coefficient A:

137.8 psi *
0.0000 *

Parameter Preferences

Duty:

19.62 hp
0.0000 *

Coefficient B:

Units for Delta P:

44

Flow Basis

0.0000 *

Coefficient C:
ActVolFlow

Units for Flow:

m3/h

User Variables

45
46

RATING

47
48

Characteristic Curves

49
50

Speed:

51

Flow

Head

52

Efficiency (%)

NPSH

53
54

19.62 hp

CURVES

40

43

Duty:

NPSH Required

NPSH Available

55

Enable NPSH Curves:

No

NPSH Curves

56
57

Nozzle Paramaters

58
59

0.0000 ft *

Base Elevation Relative to Ground Level

60

61

Diameter

(ft)

0.1640

0.1640

62

Elevation (Base)

(ft)

0.0000

0.0000

63

Elevation (Ground)

(ft)

0.0000

0.0000

64

Inertia

65
66

Rotational inertia (lb-ft2)

67

Radius of gyration (ft)

0.3281

Mass (lb)

110.2

Friction loss factor (lb-ft2/s)

1.187

Start Up

68
69

11.87

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 51 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Pump: P-100 (continued)

7
8
9

Design Flow Typical Operating Capacity

1510 barrel/day

10

CONDITIONS

11
12

Name

13

Vapour

14

Temperature

15

Pressure

16

Molar Flow

(lbmole/hr)

17

Mass Flow

(lb/hr)

18

Std Ideal Liq Vol Flow

19

Molar Enthalpy

20

Molar Entropy

21

Heat Flow

0.0000

0.0000

(F)

23.0000 *

23.8698

(psia)

14.5038 *

152.2896

2204.6000 *

2204.6000

70457.7689

70457.7689

(barrel/day)

6430.6817

6430.6817

(Btu/lbmole)

-1.060e+005

-1.060e+005

(Btu/lbmole-F)

-83.37

-80.54

(Btu/hr)

-2.3376e+08

-2.3371e+08

22

4.9931e+04

PROPERTIES

23
24

Name

25

Molecular Weight

26

Molar Density

27

Mass Density

28

Act. Volume Flow

29

Mass Enthalpy

30
31
32

Mass Heat Capacity

33

Lower Heating Value

34

Mass Lower Heating Value

35

Phase Fraction [Vol. Basis]

36

Phase Fraction [Mass Basis]

37

Partial Pressure of CO2

38

2
31.96

31.96

(lbmole/ft3)

1.501

1.502

(lb/ft3)

47.97

47.99

(barrel/day)

6278

6275

(Btu/lb)

-3318

-3317

Mass Entropy

(Btu/lb-F)

-2.609

-2.520

Heat Capacity

(Btu/lbmole-F)

22.55

22.56

(Btu/lb-F)

0.7056

0.7059

(Btu/lbmole)

2.816e+005

2.816e+005

(Btu/lb)

8810

8810

2.122e-314

2.122e-314

(psia)

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

39

Act. Gas Flow

(ACFM)

40

Avg. Liq. Density

41

Specific Heat

42

Std. Gas Flow

43

Std. Ideal Liq. Mass Density

44

Act. Liq. Flow

45

Z Factor

46

Watson K

47

User Property

48

Partial Pressure of H2S

49

Cp/(Cp - R)

50

Cp/Cv

1.235

1.233

51

Heat of Vap.

(Btu/lbmole)

1.646e+004

1.426e+004

52

Kinematic Viscosity

53

Liq. Mass Density (Std. Cond)

54

Liq. Vol. Flow (Std. Cond)

55

Liquid Fraction

56

Molar Volume

57

Mass Heat of Vap.

58

Phase Fraction [Molar Basis]

59

Surface Tension

60

Thermal Conductivity

61

Viscosity

62

Cv (Semi-Ideal)

63

Mass Cv (Semi-Ideal)

64

Cv

65

Mass Cv

66

Cv (Ent. Method)

67

Mass Cv (Ent. Method)

68

Cp/Cv (Ent. Method)

69

W1

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

1.465

1.465

(Btu/lbmole-F)

22.55

22.56

(MMSCFD)

20.04

20.04

(lb/ft3)

46.83

46.83

(USGPM)

183.1

183.0

1.865e-003

1.954e-002

11.26

11.26

0.0000

0.0000

1.097

1.097

(psia)

(cSt)

0.5151

0.5117

(lb/ft3)

46.65

46.65

(barrel/day)

6456

6456

1.000

1.000

(ft3/lbmole)

0.6662

0.6659

(Btu/lb)

515.1

446.3

0.0000

0.0000

(dyne/cm)

44.50

44.43

(Btu/hr-ft-F)

0.1664

0.1664
0.3934

(cP)

0.3958

(Btu/lbmole-F)

20.56

20.58

(Btu/lb-F)

0.6435

0.6438

(Btu/lbmole-F)

18.26

18.30

(Btu/lb-F)

0.5715

0.5727

(Btu/lbmole-F)

3601

384.7

(Btu/lb-F)

112.7

12.04

6.262e-003

5.864e-002

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 52 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Pump: P-100 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Reid VP at 37.8 C

(psia)

78.43

78.43

13

True VP at 37.8 C

(psia)

49.22

49.22

14

Liq. Vol. Flow - Sum(Std. Cond)

(barrel/day)

6456

6456

15

Viscosity Index

-2.312

-2.328

16

PERFORMANCE

17
18

Results

19
20

Total Head

21

Total Fluid Head

22

Pressure Head

-4.865e-003 ft *

Velocity Head
413.6 ft *

23

Delta P excluding Static Head Results

DYNAMICS

24
25

Dynamic Specifications

26
27

Head

28

Fluid Head

29

Adiabatic Efficiency

(rpm)

30

Polytropic Efficiency

(%)

75.00

31

Pressure Increase

(psi)

137.8

(ft)

Not Active

(lbf-ft/lbm)

Not Active

Power

(Btu/hr)

Capacity

4.993e+004

(barrel/day)

Not Active

6431

Not Active
Active
*

32

Active

Use Characteristic Curves

Not Active

Pump is Acting as a Turbine

Not Active

Holdup Details

33
34

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

36

Vapour

0.0000

0.0000

0.0000

37

Liquid

0.0000

0.0000

0.0000

38

Aqueous

0.0000

0.0000

39

Total

0.0000

0.0000

35

40

Volume
(ft3)

0.0000

0.0000

NOTES

41
42
43

Pump: P-101

44
45
46

CONNECTIONS

47
48

Inlet Stream

49

Stream Name

50
51

From Unit Operation

11

Distillation

52

Outlet Stream

53

Stream Name

54
55

To Unit Operation

12

Recycle

56

Stream Name

58

From Unit Operation

Q-100

60

PARAMETERS

61
62

Adiabatic Efficiency (%):

75.00

Delta P:

63

148.5 psi

Duty:

0.5393 hp

CURVES

64
65

Delta P:

66

Coefficient A:

67

RCY-1

Energy Stream

57

59

T-101

Parameter Preferences

148.5 psi
0.0000 *

Duty:

Units for Delta P:

0.5393 hp
0.0000 *

Coefficient B:
m

Flow Basis

0.0000 *

Coefficient C:
ActVolFlow

Units for Flow:

m3/h

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 53 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Pump: P-101 (continued)

7
8
9

User Variables

10
11

RATING

12
13

Characteristic Curves

14
15

Speed:

16

Flow

Head

17

NPSH

18
19

Efficiency (%)

NPSH Required

NPSH Available

20

Enable NPSH Curves:

No

NPSH Curves

21
22

Nozzle Paramaters

23
24

0.0000 ft *

Base Elevation Relative to Ground Level

25

11

12

26

Diameter

(ft)

0.1640

0.1640

27

Elevation (Base)

(ft)

0.0000

0.0000

28

Elevation (Ground)

(ft)

0.0000

0.0000

29

Inertia

30
31

Rotational inertia (lb-ft2)

11.87

Radius of gyration (ft)

32

Mass (lb)

110.2

Friction loss factor (lb-ft2/s)

1.187

Start Up

33
34

0.3281

Design Flow Typical Operating Capacity

1510 barrel/day

35

CONDITIONS

36
37

Name

38

Vapour

39

Temperature

40

Pressure

41

Molar Flow

(lbmole/hr)

55.7982

55.7982

42

Mass Flow

(lb/hr)

1820.3521

1820.3521

43

Std Ideal Liq Vol Flow

44

Molar Enthalpy

45

Molar Entropy

46

Heat Flow

11

12

0.0000

0.0000

(F)

92.7101

93.5826

(psia)

3.7550

152.2896 *

(barrel/day)

156.5898

156.5898

(Btu/lbmole)

-1.033e+005

-1.033e+005

(Btu/lbmole-F)

10.15

17.57

(Btu/hr)

-5.7647e+06

-5.7633e+06

47

Q-100

1.3723e+03

PROPERTIES

48
49

Name

50

Molecular Weight

51

Molar Density

52

Mass Density

53

Act. Volume Flow

54

Mass Enthalpy

55
56
57

Mass Heat Capacity

58

Lower Heating Value

59

Mass Lower Heating Value

60

Phase Fraction [Vol. Basis]

61

Phase Fraction [Mass Basis]

62

Partial Pressure of CO2

63

11

12
32.62

32.62

(lbmole/ft3)

1.490

1.490

(lb/ft3)

48.61

48.62

(barrel/day)

160.1

160.0

(Btu/lb)

-3167

-3166

Mass Entropy

(Btu/lb-F)

0.3112

0.5385

Heat Capacity

(Btu/lbmole-F)

28.15

28.17

(Btu/lb-F)

0.8630

0.8633

(Btu/lbmole)

2.849e+005

2.849e+005

(Btu/lb)

8734

8734

2.122e-314

2.122e-314

(psia)

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

64

Act. Gas Flow

(ACFM)

65

Avg. Liq. Density

1.523

66

Specific Heat

67

Std. Gas Flow

68

Std. Ideal Liq. Mass Density

69

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

1.523

(Btu/lbmole-F)

28.15

28.17

(MMSCFD)

0.5072

0.5072

49.69

49.69

(lb/ft3)

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 54 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Pump: P-101 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Act. Liq. Flow

13

Z Factor

14

Watson K

15

User Property

16

Partial Pressure of H2S

17

Cp/(Cp - R)

18

Cp/Cv

1.339

1.337

19

Heat of Vap.

(Btu/lbmole)

1.624e+004

1.275e+004

20

Kinematic Viscosity

21

Liq. Mass Density (Std. Cond)

22

Liq. Vol. Flow (Std. Cond)

23

Liquid Fraction

24

Molar Volume

25

Mass Heat of Vap.

26

Phase Fraction [Molar Basis]

27

Surface Tension

28

Thermal Conductivity

29

Viscosity

30

Cv (Semi-Ideal)

31

Mass Cv (Semi-Ideal)

32

Cv

33

Mass Cv

34

Cv (Ent. Method)

35

Mass Cv (Ent. Method)

36

Cp/Cv (Ent. Method)

37

Reid VP at 37.8 C

(psia)

38

True VP at 37.8 C

39
40

Viscosity Index

11

12

(USGPM)

4.669

4.668

4.251e-004

1.721e-002

10.63

10.63

0.0000

0.0000

1.076

1.076

(psia)

(cSt)

0.6411

0.6371

(lb/ft3)

49.83

49.83

(barrel/day)

156.2

156.2

(ft3/lbmole)
(Btu/lb)

1.000

1.000

0.6711

0.6710

497.9

390.9

0.0000

0.0000

(dyne/cm)

28.05

27.97

(Btu/hr-ft-F)

0.1017

0.1016
0.4962

(cP)

0.4992

(Btu/lbmole-F)

26.17

26.18

(Btu/lb-F)

0.8021

0.8025

(Btu/lbmole-F)

21.02

21.07

(Btu/lb-F)

0.6444

0.6457

(psia)

4.570

4.570

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

156.2

156.2

-1.755

-1.766

(Btu/lbmole-F)
(Btu/lb-F)

41

PERFORMANCE

42
43

Results

44
45

Total Head

46

Total Fluid Head

47

Pressure Head

440.0 ft *

48

50

Dynamic Specifications

51
52

Head

53

Fluid Head

54

Adiabatic Efficiency

(rpm)

55

Polytropic Efficiency

(%)

Pressure Increase

(ft)

Not Active

(lbf-ft/lbm)

Not Active

(psi)

Power
Capacity

(Btu/hr)

1372

(barrel/day)

156.6

Not Active

Not Active
75.00

Active

148.5

Active

57

Use Characteristic Curves

Not Active

Pump is Acting as a Turbine

Not Active

Holdup Details

58
59

Delta P excluding Static Head Results

DYNAMICS

49

56

-1.155e-006 ft *

Velocity Head

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

61

Vapour

0.0000

0.0000

0.0000

62

Liquid

0.0000

0.0000

0.0000

63

Aqueous

0.0000

0.0000

64

Total

0.0000

0.0000

60

65

Volume
(ft3)

0.0000

0.0000

NOTES

66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 55 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-100

7
8
9

CONNECTIONS

10
11

Inlet Stream

13
14

Stage

STREAM NAME

12

7
Q5

Cooler

15

18
19

E-101

Outlet Stream

Stage

STREAM NAME

16
17

FROM UNIT OPERATION

4__Main TS
Reboiler

Q4
8
9

TO UNIT OPERATION

Condenser
Condenser
Reboiler

20

Valve

VLV-102

Valve

VLV-101

MONITOR

21
22

Specifications Summary

23

Specified Value

Current Value

Active

Estimate

Used

24

Distillate Rate

956.0 lbmole/hr

1.000e-002

2.205 lbmole/hr

Off

On

Off

25

Reflux Rate

6614 lbmole/hr

1.000e-002

2.205 lbmole/hr

Off

On

Off

26

Btms Prod Rate

261.8 lbmole/hr

1.000e-002

2.205 lbmole/hr

Off

On

Off

27

Comp Fraction

1.000e-003 *

1.000e-003

3.893e-006

1.000e-002

1.000e-003

On

On

On

28

Comp Fraction - 2

1.000e-003 *

1.000e-003

2.353e-005

1.000e-002

1.000e-003

On

On

On

29

31

Abs. Tol.

Column Specification Parameters

32

Distillate Rate

33
34

Fixed / Ranged:

35

Stream:

Fixed
8 @COL1

Primary / Alternate:

Primary

Flow Basis:

Lower Bound:

Upper Bound:

Molar

36

Reflux Rate

37
38

Fixed / Ranged:

39

Stage:

Fixed
Condenser

Primary / Alternate:

Primary

Flow Basis:

Molar

40

Lower Bound:

Upper Bound:

Liquid Specification:

---

Btms Prod Rate

41
42

Fixed / Ranged:

43

Stream:

Fixed
9 @COL1

Primary / Alternate:

Primary

Flow Basis:

Lower Bound:

Upper Bound:

Molar

44

Comp Fraction

45
46

Fixed / Ranged:

47

Stage:

48

Components:

Fixed
Condenser

Primary / Alternate:
Flow Basis:

Primary
Mole Fraction

Methanol

Lower Bound:
Phase:

Upper Bound:
Liquid

Ethanol

49

H2O

Comp Fraction - 2

50
51

Fixed / Ranged:

52

Stage:

53

Components:

Fixed
Reboiler

Primary / Alternate:
Flow Basis:

Primary
Mole Fraction

Lower Bound:
Phase:

Upper Bound:
Vapour

diM-Ether

54

SUBCOOLING

55
56

Condenser

57

Degrees of Subcooling

58

Subcool to

59

User Variables

60
61

PROFILES

62
63

General Parameters
Sub-Flow Sheet:

T-100 (COL1)

7*

Number of Stages:

Profile Estimates

65
66

Temperature
(F)

67
68
69

Wt. Tol.

SPECS

30

64

Wt. Error

Condenser

Hyprotech Ltd.
Licensed to: LEGENDS

Net Liquid
(lbmole/hr)
110.0

Aspen HYSYS Version 7.1 (23.0.0.7119)

Net Vapour
(lbmole/hr)
6614

1.279e-018

Page 56 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

7
8

Profile Estimates

9
10

Temperature
(F)

11

Net Liquid
(lbmole/hr)

Net Vapour
(lbmole/hr)

12

1__Main TS

111.8

6086

7570

13

2__Main TS

139.9

4511

7042

14

3__Main TS

216.6

3892

5467

15

4__Main TS

258.8

4206

4848

16

5__Main TS

282.3

4112

3944

17

6__Main TS

291.8

4014

3850

18

7__Main TS

302.0

3833

3752

19

Reboiler

320.5

261.8

3571

20

EFFICIENCIES

21

Stage Efficiencies

22
23

Stages

Overall Efficiency

Methanol

Ethanol

diM-Ether

H2O

24

Condenser

1.000

1.000

1.000

1.000

1.000

25

1__Main TS

1.000

1.000

1.000

1.000

1.000

26

2__Main TS

1.000

1.000

1.000

1.000

1.000

27

3__Main TS

1.000

1.000

1.000

1.000

1.000

28

4__Main TS

1.000

1.000

1.000

1.000

1.000

29

5__Main TS

1.000

1.000

1.000

1.000

1.000

30

6__Main TS

1.000

1.000

1.000

1.000

1.000

31

7__Main TS

1.000

1.000

1.000

1.000

1.000

32

Reboiler

1.000

1.000

1.000

1.000

1.000

33

SOLVER

34
35

Column Solving Algorithm:

Acceleration Parameters

37

Maximum Iterations:

38

Equilibrium Error Tolerance:

1.000e-05

39

Heat/Spec Error Tolerance:

5.000e-004

40

Save Solutions as Initial Estimate:

41

Super Critical Handling Model:

42

Trace Level:

43

Init from Ideal K's:

10000

Accelerate K Value & H Model Parameters:

Off

On
Simple K
Low

Damping Parameters

Off

Initial Estimate Generator Parameters

44
45

HYSIM Inside-Out

Solving Options

36

Azeotrope Check:

Iterative IEG (Good for Chemicals):

Off

Off

Fixed Damping Factor:

46
47
48

SIDE STRIPPERS

49
50

SIDE RECTIFIERS

51
52

PUMP AROUNDS

53
54

VAP BYPASSES

55
56

RATING

57
58

Tray Sections

59
60

Tray Section

61

Tray Diameter

(ft)

4.921

62

Weir Height

(ft)

0.1640

63

Weir Length

(ft)

3.937

64

Tray Space

(ft)

1.804

65

Tray Volume

(ft3)

34.32

66

Disable Heat Loss Calculations

67

Heat Model

68

Rating Calculations

69

Hyprotech Ltd.
Licensed to: LEGENDS

Main TS @COL1

No
None
No

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 57 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

7
8
9

Tray Hold Up

(ft3)

3.120

10

Vessels

11
12

Vessel

Reboiler @COL1

Condenser @COL1

13

Diameter

(ft)

3.914

3.914

14

Length

(ft)

5.871

15

Volume

(ft3)

70.63

16

Orientation

17

Vessel has a Boot

18

Boot Diameter

19

Boot Length

20

Hold Up

5.871
*

70.63

Horizontal

Horizontal

No

No

35.31

35.31

(ft)
(ft)
(ft3)

21

Other Equipment In Column Flowsheet

22
23
24

Pressure Profile

25
26

Pressure (psia)

Pressure Drop (psi)

27

Condenser

139.0 psia

28

1__Main TS

139.0 psia

3.333 psi

29

2__Main TS

142.3 psia

3.333 psi

30

3__Main TS

145.7 psia

3.333 psi

31

4__Main TS

149.0 psia

3.333 psi

32

5__Main TS

152.3 psia

3.333 psi

33

6__Main TS

155.7 psia

3.333 psi

34

7__Main TS

159.0 psia

35

Reboiler

159.0 psia

36

0.0000 psi

0.0000 psi

Pressure Solving Options

37
38

Pressure Tolerance

1.000e-004

Pressure Drop Tolerance

1.000e-004

39

Damping Factor

1.000

100

Q5

Q4

5.1655e+07

6.0414e+07

CONDITIONS

40
41

Name

42

Vapour

43

Temperature

44

Pressure

45

Molar Flow

(lbmole/hr)

1217.8072

956.0302

261.7770

46

Mass Flow

(lb/hr)

49630.7168

44029.9802

5600.7367

47

Std Ideal Liq Vol Flow

48

Molar Enthalpy

49

Molar Entropy

50

Heat Flow

0.7672

0.0000

0.0000

(F)

192.2000 *

110.0070

320.5048

(psia)

145.0377 *

139.0000

159.0000

(barrel/day)

4915.2307

4497.2635

417.9672

(Btu/lbmole)

-8.516e+004

-8.662e+004

-1.133e+005

(Btu/lbmole-F)

39.62

37.85

15.54

(Btu/hr)

-1.0371e+08

-8.2809e+07

-2.9664e+07

51

PROPERTIES

52
53

Name

54

Molecular Weight

55

Molar Density

56

Mass Density

57

Act. Volume Flow

58

Mass Enthalpy

59
60
61

Mass Heat Capacity

62

Lower Heating Value

63

Mass Lower Heating Value

64

Phase Fraction [Vol. Basis]

65

Phase Fraction [Mass Basis]

66

Partial Pressure of CO2

67
68
69

Max Press Iterations

40.75

46.06

21.40

(lbmole/ft3)

2.691e-002

0.7799

2.332

(lb/ft3)

1.097

35.92

49.89

(barrel/day)

1.934e+005

5240

479.9

(Btu/lb)

-2090

-1881

-5296

Mass Entropy

(Btu/lb-F)

0.9722

0.8219

0.7262

Heat Capacity

(Btu/lbmole-F)

19.13

28.21

22.69

(Btu/lb-F)

0.4694

0.6126

1.061

(Btu/lbmole)

4.623e+005

5.708e+005

6.577e+004

(Btu/lb)

1.134e+004

1.239e+004

3074

0.8533
0.8354

2.122e-314

0.0000

(psia)

0.0000

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

0.0000

Act. Gas Flow

(ACFM)

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 58 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Avg. Liq. Density

13

Specific Heat

14

Std. Gas Flow

15

Std. Ideal Liq. Mass Density

16

Act. Liq. Flow

17

Z Factor

18

Watson K

19

User Property

20

Partial Pressure of H2S

21

Cp/(Cp - R)

22

Cp/Cv

23

Heat of Vap.

24

Kinematic Viscosity

25

Liq. Mass Density (Std. Cond)

26

Liq. Vol. Flow (Std. Cond)

27

Liquid Fraction

28

Molar Volume

29

Mass Heat of Vap.

30

Phase Fraction [Molar Basis]

31

Surface Tension

32

Thermal Conductivity

33

Viscosity

34

Cv (Semi-Ideal)

35

Mass Cv (Semi-Ideal)

36

Cv

37

Mass Cv

38

Cv (Ent. Method)

39

Mass Cv (Ent. Method)

40

Cp/Cv (Ent. Method)

41

Reid VP at 37.8 C

42

True VP at 37.8 C

(lbmole/ft3)

1.059

0.9087

2.677

(Btu/lbmole-F)

19.13

28.21

22.69

(MMSCFD)

11.07

8.690

2.380

(lb/ft3)

43.16

41.85

57.28

(USGPM)

23.28

152.8

14.00

2.915e-002

8.144e-003

11.37

11.38

10.64

0.0000

0.0000

0.0000

1.116

1.076

1.096

1.087

1.076

1.213

1.166e+004

7981

1.539e+004

(psia)

(Btu/lbmole)
(cSt)

0.1312

0.1682

(lb/ft3)

40.98

38.58

58.35

(barrel/day)

5177

4878

410.3

0.2328

1.000

1.000

37.16

1.282

0.4288

(ft3/lbmole)
(Btu/lb)
(dyne/cm)

286.2

173.3

719.1

0.7672

0.0000

0.0000

37.52

(Btu/hr-ft-F)
(cP)

9.257

38.26

7.011e-002

0.2899

7.548e-002

0.1344

(Btu/lbmole-F)

17.14

26.23

20.70

(Btu/lb-F)

0.4207

0.5695

0.9677

(Btu/lbmole-F)

17.60

26.23

18.70

(Btu/lb-F)

0.4318

0.5695

0.8741

(psia)

113.1

120.4

4.481

(psia)

94.98

120.7

2.329

43

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

5218

4878

410.3

44

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

45

SUMMARY

46
47

Flow Basis:

Molar

49
50

The composition option is selected

Feed Composition

48

7
Flow Rate (kgmole/h)

1.217807e+03

52

Methanol

0.0444

53

Ethanol

0.0041

54

diM-Ether

0.7843

55

H2O

0.1673

51

56

Flow Basis:

Molar

58
59

The composition option is selected

Feed Flows

57

7
Flow Rate (kgmole/h)

1.217807e+03

61

Methanol (kgmole/h)

54.0662

62

Ethanol (kgmole/h)

4.9657

63

diM-Ether (kgmole/h)

955.0940

64

H2O (kgmole/h)

203.6813

60

Products

65
66

Flow Basis:

Molar

The composition option is selected

Product Compositions

67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 59 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

7
8
9

SUMMARY

10
11

Flow Rate (kgmole/h)

956.0302

261.7770

14

Methanol

0.0010

0.2030

15

Ethanol

0.0000

0.0189

16

diM-Ether

0.9990

0.0001

17

H2O

0.0000

0.7780

12
13

18

Flow Basis:

Molar

20
21

The composition option is selected

Product Flows

19

Flow Rate (kgmole/h)

956.0302

261.7770

23

Methanol (kgmole/h)

0.9385

53.1277

24

Ethanol (kgmole/h)

0.0100

4.9557

25

diM-Ether (kgmole/h)

955.0741

0.0198

26

H2O (kgmole/h)

0.0075

203.6738

22

27

Flow Basis:

The composition option is selected

Product Recoveries

28
29

Flow Rate (kgmole/h)

956.0302

261.7770

32

Methanol (%)

1.7359

98.2641

33

Ethanol (%)

0.2023

99.7977

34

diM-Ether (%)

99.9979

0.0021

35

H2O (%)

0.0037

99.9963

30

Molar

31

36

COLUMN PROFILES

37
38

Reflux Ratio:

6.918

Reboil Ratio:

13.64

The Flows Option is Selected

Flow Basis:

40

Temperature (F)

Pressure (psia)

Net Liq (lbmole/hr)

41

Condenser

110.0

139.0

6614

42

1__Main TS

111.8

139.0

6086

7570

43

2__Main TS

139.9

142.3

4511

7042

44

3__Main TS

216.6

145.7

3892

5467

45

4__Main TS

258.8

149.0

4206

4848

46

5__Main TS

282.3

152.3

4112

3944

47

6__Main TS

291.8

155.7

4014

3850

48

7__Main TS

302.0

159.0

3833

3752

49

Reboiler

320.5

159.0

Net Vap (lbmole/hr)

Net Feed (lbmole/hr)

51

956.0

1218

261.8

3571

Temperature (F)

Liquid Enthalpy (Btu/lbmole)

Vapour Enthalpy (Btu/lbmole)

52

Condenser

110.0

-8.662e+004

-7.866e+004

53

1__Main TS

111.8

-8.699e+004

-7.864e+004

54

2__Main TS

139.9

-9.113e+004

-7.836e+004

55

3__Main TS

216.6

-9.695e+004

-7.929e+004

56

4__Main TS

258.8

-9.976e+004

-8.245e+004

57

5__Main TS

282.3

-1.017e+005

-8.576e+004

58

6__Main TS

291.8

-1.039e+005

-8.753e+004

59

7__Main TS

302.0

-1.077e+005

-8.945e+004

60

Reboiler

320.5

-1.133e+005

-9.279e+004

61

Flow Basis:

Molar

64

66

Stream
Condenser

67

1__Main TS

68

2__Main TS

69

Heat Loss (Btu/hr)

FEEDS / PRODUCTS

62

65

Net Draws (lbmole/hr)

Column Profiles Energy

50

63

Molar

Column Profiles Flows

39

Hyprotech Ltd.
Licensed to: LEGENDS

Type

Q4

Energy

Draw

Duty

(kJ/h)

6.041e+007

State

Flows

(kgmole/h) Enthalpy

(kJ/kgmole Temp

(C)

Liquid

956.0

Aspen HYSYS Version 7.1 (23.0.0.7119)

-8.662e+004

110.0

Page 60 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

7
8
9

FEEDS / PRODUCTS

10
11

3__Main TS

12

4__Main TS

13

5__Main TS

14

6__Main TS

15

7__Main TS

16
17

Reboiler

Feed

Q5

Energy

Draw

Mixed

1218

-8.516e+004

192.2

Liquid

261.8

-1.133e+005

320.5

5.166e+007

18

SETUP

19
20

Sub-Flowsheet

Feed Streams

21

Product Streams

22

Internal Stream

External Stream

Transfer Basis

Internal Stream

External Stream

Transfer Basis

23

P-H Flash

Q4

Q4

None Req'd

24

Q5

Q5

None Req'd

P-H Flash

P-H Flash

25
26
27

VARIABLES

28

Column Flowsheet Vars Available as Parameters

29
30

Data Source

Variable

Component

Description

31
32

COMPONENT MAPS

33

Feed Streams

34
35

Feed Name

36

37

Q5

In to SubFlowSheet

Out of SubFlowSheet

Product Stream

38
39

Product Name

40

Q4

41

42

In to SubFlowSheet

43

Out of SubFlowSheet

DYNAMICS

44
45

Vessel Dynamic Specifications

46
47

Vessel

Reboiler @COL1

Condenser @COL1

48

Diameter

(ft)

3.914

3.914

49

Height.0

(ft)

5.871

5.871

50

Volume.0

(ft3)

70.63 *

70.63 *

51

Liquid Volume Percent

(%)

50.00

50.00

52

Level Calculator

Horizontal cylinder

Horizontal cylinder

53

Fraction Calculator

54

Vessel Delta P

55

Fixed Vessel P Spec

56

Fixed P Spec Active

57

Use levels and nozzles

Use levels and nozzles

(psi)

0.0000

0.0000

(psia)

159.0

139.0

Not Active

Not Active

Other Equipment in Column Flowsheet

58
59
60

Holdup Details

61
62

Pressure
(psia)

63

Volume
(ft3)

Bulk Liquid Volume

(ft3)

64

Condenser

0.0000

0.0000

0.0000

65

1__Main TS

0.0000

0.0000

0.0000

66

2__Main TS

0.0000

0.0000

0.0000

67

3__Main TS

0.0000

0.0000

0.0000

68

4__Main TS

0.0000

0.0000

0.0000

69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 61 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

7
8
9

Pressure
(psia)

10

Volume
(ft3)

Bulk Liquid Volume

(ft3)

11

5__Main TS

0.0000

0.0000

0.0000

12

6__Main TS

0.0000

0.0000

0.0000

13

7__Main TS

0.0000

0.0000

0.0000

14

Reboiler

0.0000

0.0000

0.0000

15

NOTES

16
17
18

Distillation: T-101

19
20
21

CONNECTIONS

22
23

Inlet Stream

25
26

Stage

STREAM NAME

24

Q7
10

Valve

27

30
31

VLV-101

Outlet Stream

Stage

STREAM NAME

28
29

FROM UNIT OPERATION

Reboiler
10__Main TS

Q6
AGUA
11

TO UNIT OPERATION

Condenser
Reboiler
Condenser

Pump

32

P-101

MONITOR

33
34

Specifications Summary

35

Specified Value

Current Value

Active

Estimate

Used

36

Reflux Ratio

3.753e+007

Wt. Error

1.000e-002

Wt. Tol.

Abs. Tol.
1.000e-002

Off

On

Off

37

Reflux Rate

2.094e+009 lbmole/hr

1.000e-002

2.205 lbmole/hr

Off

On

Off

38

Comp Fraction

1.000e-003 *

3.738e-003

0.4221

1.000e-002

1.000e-003

Off

On

Off

39

Comp Fraction - 2

1.000e-003 *

1.220e-002

0.8845

1.000e-002

1.000e-003

Off

On

Off

40

Comp Recovery - 2

0.0010 *

0.0010

-1.613e-003

1.000e-002

1.000e-003

On

On

On

41
42

SPECS

43
44

Column Specification Parameters

45

Reflux Ratio

46
47

Fixed / Ranged:

48

Stage:

Fixed
Condenser

Primary / Alternate:
Flow Basis:

Molar

49

Lower Bound:
Liquid Specification:

Upper Bound:
---

Reflux Rate

50
51

Fixed / Ranged:

52

Stage:

Fixed
Condenser

Primary / Alternate:
Flow Basis:

Primary
Molar

53

Lower Bound:
Liquid Specification:

Upper Bound:
---

Comp Fraction

54
55

Fixed / Ranged:

56

Stage:

57

Components:

Fixed
Condenser

Primary / Alternate:
Flow Basis:

Primary
Mole Fraction

Lower Bound:
Phase:

Upper Bound:
Liquid

H2O

58

Comp Fraction - 2

59
60

Fixed / Ranged:

61

Stage:

62

Components:

Fixed
Reboiler

Primary / Alternate:
Flow Basis:

Primary
Mole Fraction

Methanol

Lower Bound:
Phase:
Ethanol

63

Upper Bound:
Liquid
diM-Ether

Comp Recovery - 2

64
65

Fixed / Ranged:

66

Draw:

67

Primary

Fixed
11 @COL2

Components:

Primary / Alternate:
Flow Basis:

Primary

Lower Bound:

Upper Bound:

Molar

H2O

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 62 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

7
8
9

Column Specification Parameters

10
11
12

Fixed / Ranged:

Primary / Alternate:

13

Draw:

Flow Basis:

14

Lower Bound:

Components:

15

SUBCOOLING

16
17

Condenser

18

Degrees of Subcooling

19

Subcool to

20

User Variables

21
22

PROFILES

23
24
25

Upper Bound:

General Parameters
Sub-Flow Sheet:

T-101 (COL2)

15 *

Number of Stages:

Profile Estimates

26
27

Temperature
(F)

28

Net Liquid
(lbmole/hr)

Net Vapour
(lbmole/hr)

29

Condenser

92.71

2.094e+009

6.835e-006

30

1__Main TS

93.96

2.071e+009

2.094e+009

31

2__Main TS

102.6

2.063e+009

2.071e+009

32

3__Main TS

111.9

2.045e+009

2.063e+009

33

4__Main TS

121.1

2.025e+009

2.045e+009

34

5__Main TS

129.5

2.009e+009

2.025e+009

35

6__Main TS

136.6

1.998e+009

2.009e+009

36

7__Main TS

142.5

1.992e+009

1.998e+009

37

8__Main TS

147.5

1.989e+009

1.992e+009

38

9__Main TS

151.7

1.989e+009

1.989e+009

39

10__Main TS

155.5

1.989e+009

1.989e+009

40

11__Main TS

158.9

1.989e+009

1.989e+009

41

12__Main TS

162.2

1.987e+009

1.989e+009

42

13__Main TS

165.7

1.979e+009

1.987e+009

43

14__Main TS

170.4

1.950e+009

1.979e+009

44

15__Main TS

182.8

1.912e+009

1.950e+009

45

Reboiler

203.0

206.0

1.912e+009

46

EFFICIENCIES

47

Stage Efficiencies

48
49

Stages

Overall Efficiency

Methanol

Ethanol

diM-Ether

H2O

50

Condenser

1.000

1.000

1.000

1.000

1.000

51

1__Main TS

1.000

1.000

1.000

1.000

1.000

52

2__Main TS

1.000

1.000

1.000

1.000

1.000

53

3__Main TS

1.000

1.000

1.000

1.000

1.000

54

4__Main TS

1.000

1.000

1.000

1.000

1.000

55

5__Main TS

1.000

1.000

1.000

1.000

1.000

56

6__Main TS

1.000

1.000

1.000

1.000

1.000

57

7__Main TS

1.000

1.000

1.000

1.000

1.000

58

8__Main TS

1.000

1.000

1.000

1.000

1.000

59

9__Main TS

1.000

1.000

1.000

1.000

1.000

60

10__Main TS

1.000

1.000

1.000

1.000

1.000

61

11__Main TS

1.000

1.000

1.000

1.000

1.000

62

12__Main TS

1.000

1.000

1.000

1.000

1.000

63

13__Main TS

1.000

1.000

1.000

1.000

1.000

64

14__Main TS

1.000

1.000

1.000

1.000

1.000

65

15__Main TS

1.000

1.000

1.000

1.000

1.000

66

Reboiler

1.000

1.000

1.000

1.000

1.000

67

SOLVER

68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 63 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

7
8
9

Column Solving Algorithm:

Acceleration Parameters

11

Maximum Iterations:

12

Equilibrium Error Tolerance:

1.000e-05

13

Heat/Spec Error Tolerance:

5.000e-004

14

Save Solutions as Initial Estimate:

15

Super Critical Handling Model:

16

Trace Level:

17

Init from Ideal K's:

10000

Accelerate K Value & H Model Parameters:

Off

On
Simple K
Low

Damping Parameters

Off

Initial Estimate Generator Parameters

18
19

HYSIM Inside-Out

Solving Options

10

Azeotrope Check:

Iterative IEG (Good for Chemicals):

Off

Off

Fixed Damping Factor:

20
21
22

SIDE STRIPPERS

23
24

SIDE RECTIFIERS

25
26

PUMP AROUNDS

27
28

VAP BYPASSES

29
30

RATING

31
32

Tray Sections

33
34

Tray Section

35

Tray Diameter

(ft)

4.921

36

Weir Height

(ft)

0.1640

37

Weir Length

(ft)

3.937

38

Tray Space

(ft)

1.804

39

Tray Volume

(ft3)

34.32

40

Disable Heat Loss Calculations

41

Heat Model

42

Rating Calculations

43

Tray Hold Up

Main TS @COL2

No
None
No
(ft3)

3.120

44

Vessels

45
46

Vessel

Reboiler @COL2

Condenser @COL2

47

Diameter

(ft)

3.914

3.914

48

Length

(ft)

5.871

49

Volume

(ft3)

70.63

50

Orientation

51

Vessel has a Boot

52

Boot Diameter

53

Boot Length

54

Hold Up

5.871
*

70.63

Horizontal

Horizontal

No

No

35.31

35.31

(ft)
(ft)
(ft3)

55

Other Equipment In Column Flowsheet

56
57
58

Pressure Profile

59
60

Pressure (psia)

Pressure Drop (psi)

61

Condenser

3.755 psia

62

1__Main TS

3.755 psia

0.7143 psi

63

2__Main TS

4.469 psia

0.7143 psi

64

3__Main TS

5.184 psia

0.7143 psi

65

4__Main TS

5.898 psia

0.7143 psi

66

5__Main TS

6.612 psia

0.7143 psi

67

6__Main TS

7.327 psia

0.7143 psi

68

7__Main TS

8.041 psia

0.7143 psi

69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

0.0000 psi

Page 64 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

7
8
9

8__Main TS

8.755 psia

0.7143 psi

10

9__Main TS

9.470 psia

0.7143 psi

11

10__Main TS

10.18 psia

0.7143 psi

12

11__Main TS

10.90 psia

0.7143 psi

13

12__Main TS

11.61 psia

0.7143 psi

14

13__Main TS

12.33 psia

0.7143 psi

15

14__Main TS

13.04 psia

0.7143 psi

16

15__Main TS

13.76 psia

17

Reboiler

13.76 psia

18

0.0000 psi

Pressure Solving Options

19
20

Pressure Tolerance

1.000e-004

Pressure Drop Tolerance

21

1.000e-004

Damping Factor

1.000

Max Press Iterations

100

Q7

Q6

3.4021e+13

3.4017e+13

CONDITIONS

22
23

Name

24

Vapour

25

Temperature

26

Pressure

27

Molar Flow

28

Mass Flow

29

Std Ideal Liq Vol Flow

30

Molar Enthalpy

31

Molar Entropy

32

Heat Flow

(F)

10

11

AGUA

0.2755

0.0000

0.0000

93.0852

92.7101

202.9636

1.4504 *

(psia)

3.7550

13.7554

(lbmole/hr)

261.7770

55.7982

205.9788
3780.3844

(lb/hr)

5600.7367

1820.3521

(barrel/day)

417.9672

156.5898

261.3774

(Btu/lbmole)

-1.133e+005

-1.033e+005

-1.201e+005

(Btu/lbmole-F)

14.39

10.15

5.664

(Btu/hr)

-2.9664e+07

-5.7647e+06

-2.4745e+07

33

PROPERTIES

34
35

Name

36

Molecular Weight

37

Molar Density

38

Mass Density

39

Act. Volume Flow

40

Mass Enthalpy

41
42
43

Mass Heat Capacity

44

Lower Heating Value

45

Mass Lower Heating Value

46

Phase Fraction [Vol. Basis]

47

Phase Fraction [Mass Basis]

48

Partial Pressure of CO2

49

10

11

AGUA

21.40

32.62

18.35

(lbmole/ft3)

8.875e-004

1.490

3.224

(lb/ft3)

1.899e-002

48.61

59.17

(barrel/day)

1.261e+006

160.1

273.1

(Btu/lb)

-5296

-3167

-6546

Mass Entropy

(Btu/lb-F)

0.6724

0.3112

0.3086

Heat Capacity

(Btu/lbmole-F)

16.65

28.15

18.31

(Btu/lb-F)

0.7780

0.8630

0.9979

(Btu/lbmole)

6.577e+004

2.849e+005

6405

(Btu/lb)

3074

8734

349.0

0.3595
0.3343

2.122e-314

0.0000

(psia)

0.0000

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

0.0000

50

Act. Gas Flow

(ACFM)

51

Avg. Liq. Density

52

Specific Heat

53

Std. Gas Flow

54

Std. Ideal Liq. Mass Density

55

Act. Liq. Flow

56

Z Factor

57

Watson K

58

User Property

59

Partial Pressure of H2S

60

Cp/(Cp - R)

61

Cp/Cv

62

Heat of Vap.

63

Kinematic Viscosity

64

Liq. Mass Density (Std. Cond)

65

Liq. Vol. Flow (Std. Cond)

66

Liquid Fraction

67

Molar Volume

68

Mass Heat of Vap.

69

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

2.677

1.523

3.369

(Btu/lbmole-F)

16.65

28.15

18.31

(MMSCFD)

2.380

0.5072

1.872

(lb/ft3)

57.28

49.69

61.83

(USGPM)

7.783

4.669

7.965

4.251e-004

6.000e-004

10.64

10.63

10.76

0.0000

0.0000

0.0000

1.135

1.076

1.122

1.034

1.339

1.182

1.854e+004

1.624e+004

1.759e+004

(psia)

(Btu/lbmole)
(cSt)

0.6411

0.3160

(lb/ft3)

58.35

49.83

63.12

(barrel/day)

410.3

156.2

256.0

0.7245

1.000

1.000

1127

0.6711

0.3102

866.8

497.9

958.6

(ft3/lbmole)
(Btu/lb)

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 65 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Phase Fraction [Molar Basis]

13

Surface Tension

14

Thermal Conductivity

15

Viscosity

16

Cv (Semi-Ideal)

17

Mass Cv (Semi-Ideal)

18

Cv

19

Mass Cv

20

Cv (Ent. Method)

21

Mass Cv (Ent. Method)

22

Cp/Cv (Ent. Method)

23

Reid VP at 37.8 C

(psia)

4.481

24

True VP at 37.8 C

(psia)

25

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

26

Viscosity Index

10
(dyne/cm)

11
0.0000

65.90

28.05

59.02

0.1017

0.3870

0.4992

0.2996

(Btu/hr-ft-F)
(cP)
14.66

26.17

16.33

(Btu/lb-F)

0.6852

0.8021

0.8897

(Btu/lbmole-F)

16.10

21.02

15.49

(Btu/lb-F)

0.7524

0.6444

0.8442

2.329

4.570

1.102

411.0

156.2

256.0

-1.755

-2.518

(Btu/lbmole-F)
(Btu/lb-F)

SUMMARY

28

Flow Basis:

Molar

The composition option is selected

Feed Composition

30
31
32

0.0000

(Btu/lbmole-F)

27

29

AGUA

0.2755

10
Flow Rate (kgmole/h)

261.7770

34

Methanol

0.2030

35

Ethanol

0.0189

36

diM-Ether

0.0001

37

H2O

0.7780

33

38

Flow Basis:

Molar

40
41

The composition option is selected

Feed Flows

39

10
Flow Rate (kgmole/h)

261.7770

43

Methanol (kgmole/h)

53.1277

44

Ethanol (kgmole/h)

4.9557

45

diM-Ether (kgmole/h)

0.0198

46

H2O (kgmole/h)

203.6738

42

Products

47
48

Flow Basis:

Molar

50

11

AGUA

Flow Rate (kgmole/h)

55.7982

205.9788

53

Methanol

0.9510

0.0003

54

Ethanol

0.0449

0.0119

55

diM-Ether

0.0004

0.0000

56

H2O

0.0037

0.9878

51

The composition option is selected

Product Compositions

49

52

57

Flow Basis:

Molar

59
60

The composition option is selected

Product Flows

58

11

AGUA

Flow Rate (kgmole/h)

55.7982

205.9788

62

Methanol (kgmole/h)

53.0662

0.0615

63

Ethanol (kgmole/h)

2.5036

2.4521

64

diM-Ether (kgmole/h)

0.0198

0.0000

65

H2O (kgmole/h)

0.2086

203.4652

61

66

Flow Basis:

Molar

The composition option is selected

Product Recoveries

67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 66 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

7
8
9

SUMMARY

10
11

11

AGUA

Flow Rate (kgmole/h)

55.7982

205.9788

14

Methanol (%)

99.8843

0.1157

15

Ethanol (%)

50.5191

49.4809

16

diM-Ether (%)

99.9998

0.0000

17

H2O (%)

0.1024

99.8976

12
13

18

COLUMN PROFILES

19
20

Reflux Ratio:

3.753e+007

Reboil Ratio:

9.283e+006

The Flows Option is Selected

Flow Basis:

22

Temperature (F)

Pressure (psia)

Net Liq (lbmole/hr)

23

Condenser

92.71

3.755

2.094e+009

24

1__Main TS

93.96

3.755

2.071e+009

2.094e+009

25

2__Main TS

102.6

4.469

2.063e+009

2.071e+009

26

3__Main TS

111.9

5.184

2.045e+009

2.063e+009

27

4__Main TS

121.1

5.898

2.025e+009

2.045e+009

28

5__Main TS

129.5

6.612

2.009e+009

2.025e+009

29

6__Main TS

136.6

7.327

1.998e+009

2.009e+009

30

7__Main TS

142.5

8.041

1.992e+009

1.998e+009

31

8__Main TS

147.5

8.755

1.989e+009

1.992e+009

32

9__Main TS

151.7

9.470

1.989e+009

1.989e+009

33

10__Main TS

155.5

10.18

1.989e+009

1.989e+009

34

11__Main TS

158.9

10.90

1.989e+009

1.989e+009

35

12__Main TS

162.2

11.61

1.987e+009

1.989e+009

36

13__Main TS

165.7

12.33

1.979e+009

1.987e+009

37

14__Main TS

170.4

13.04

1.950e+009

1.979e+009

38

15__Main TS

182.8

13.76

1.912e+009

1.950e+009

39

Reboiler

203.0

13.76

Net Vap (lbmole/hr)

Net Feed (lbmole/hr)

41

55.80

261.8

206.0

1.912e+009

Temperature (F)

Liquid Enthalpy (Btu/lbmole)

Vapour Enthalpy (Btu/lbmole)

42

Condenser

92.71

-1.033e+005

-8.667e+004

43

1__Main TS

93.96

-1.042e+005

-8.707e+004

44

2__Main TS

102.6

-1.056e+005

-8.776e+004

45

3__Main TS

111.9

-1.077e+005

-8.911e+004

46

4__Main TS

121.1

-1.101e+005

-9.109e+004

47

5__Main TS

129.5

-1.122e+005

-9.330e+004

48

6__Main TS

136.6

-1.139e+005

-9.530e+004

49

7__Main TS

142.5

-1.151e+005

-9.687e+004

50

8__Main TS

147.5

-1.159e+005

-9.799e+004

51

9__Main TS

151.7

-1.164e+005

-9.877e+004

52

10__Main TS

155.5

-1.168e+005

-9.930e+004

53

11__Main TS

158.9

-1.171e+005

-9.966e+004

54

12__Main TS

162.2

-1.173e+005

-9.994e+004

55

13__Main TS

165.7

-1.177e+005

-1.002e+005

56

14__Main TS

170.4

-1.185e+005

-1.005e+005

57

15__Main TS

182.8

-1.199e+005

-1.010e+005

58

Reboiler

203.0

-1.201e+005

-1.021e+005

59

Flow Basis:

Molar

62

64

Stream
Condenser

65

1__Main TS

66

2__Main TS

67

3__Main TS

68

4__Main TS

69

Heat Loss (Btu/hr)

FEEDS / PRODUCTS

60

63

Net Draws (lbmole/hr)

Column Profiles Energy

40

61

Molar

Column Profiles Flows

21

Hyprotech Ltd.
Licensed to: LEGENDS

Type

Q6

Energy

11

Draw

Duty

(kJ/h)

3.402e+013

State

Flows

(kgmole/h) Enthalpy

(kJ/kgmole Temp

(C)

Liquid

55.80

Aspen HYSYS Version 7.1 (23.0.0.7119)

-1.033e+005

92.71

Page 67 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

7
8
9

FEEDS / PRODUCTS

10
11

5__Main TS

12

6__Main TS

13

7__Main TS

14

8__Main TS

15

9__Main TS

16

10__Main TS

17

11__Main TS

18

12__Main TS

19

13__Main TS

20

14__Main TS

21

15__Main TS

22
23

Reboiler

10

Feed

Q7

Energy

AGUA

Draw

Mixed

261.8

-1.133e+005

93.09

Liquid

206.0

-1.201e+005

203.0

3.402e+013

24

SETUP

25
26

Sub-Flowsheet

Feed Streams

27

Product Streams

28

Internal Stream

External Stream

Transfer Basis

Internal Stream

External Stream

Transfer Basis

29

Q7

Q7

None Req'd

Q6

Q6

None Req'd

30

10

10

P-H Flash

AGUA

AGUA

P-H Flash

11

11

P-H Flash

31
32
33

VARIABLES

34

Column Flowsheet Vars Available as Parameters

35
36

Data Source

Variable

Component

Description

37
38

COMPONENT MAPS

39

Feed Streams

40
41

Feed Name

42

Q7

43

10

In to SubFlowSheet

Out of SubFlowSheet

Product Stream

44
45

Product Name

46

Q6

47

AGUA

48

11

In to SubFlowSheet

49

Out of SubFlowSheet

DYNAMICS

50
51

Vessel Dynamic Specifications

52
53

Vessel

Reboiler @COL2

Condenser @COL2

54

Diameter

(ft)

3.914

3.914

55

Height.0

(ft)

5.871

5.871

56

Volume.0

(ft3)

70.63 *

70.63 *

57

Liquid Volume Percent

(%)

50.00

50.00

58

Level Calculator

Horizontal cylinder

Horizontal cylinder

59

Fraction Calculator

60

Vessel Delta P

61

Fixed Vessel P Spec

62

Fixed P Spec Active

63

Use levels and nozzles

Use levels and nozzles

(psi)

0.0000

0.0000

(psia)

13.76

3.755

Not Active

Not Active

Other Equipment in Column Flowsheet

64
65
66

Holdup Details

67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 68 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

7
8
9

Pressure
(psia)

10

Volume
(ft3)

Bulk Liquid Volume

(ft3)

11

Condenser

0.0000

0.0000

0.0000

12

1__Main TS

0.0000

0.0000

0.0000

13

2__Main TS

0.0000

0.0000

0.0000

14

3__Main TS

0.0000

0.0000

0.0000

15

4__Main TS

0.0000

0.0000

0.0000

16

5__Main TS

0.0000

0.0000

0.0000

17

6__Main TS

0.0000

0.0000

0.0000

18

7__Main TS

0.0000

0.0000

0.0000

19

8__Main TS

0.0000

0.0000

0.0000

20

9__Main TS

0.0000

0.0000

0.0000

21

10__Main TS

0.0000

0.0000

0.0000

22

11__Main TS

0.0000

0.0000

0.0000

23

12__Main TS

0.0000

0.0000

0.0000

24

13__Main TS

0.0000

0.0000

0.0000

25

14__Main TS

0.0000

0.0000

0.0000

26

15__Main TS

0.0000

0.0000

0.0000

27

Reboiler

0.0000

0.0000

0.0000

28

NOTES

29
30
31

Valve: VLV-100

32
33
34

CONNECTIONS

35
36

Inlet Stream

37

STREAM NAME

38
39

FROM UNIT OPERATION

Equilibrium Reactor

40

Outlet Stream

41

STREAM NAME

42
43

TO UNIT OPERATION

Cooler

44

E-101

PARAMETERS

45
46

Physical Properties

47
48

Pressure Drop:

7.252 psi

49

User Variables

50
51

RATING

52
53

Sizing

54
55

Sizing Conditions

56

Inlet Pressure

57

Valve Opening

152.3 psia
50.00 % *

Molecular Weight

7.252 psi

Current
Flow Rate

4.963e+004 lb/hr

Valve Manufacturer and Valve Type

59

Manufacturer:

Universal Gas Sizing

60

Type:

---

Valve Operating Characteristic and Sizing Method

61

Linear
C1

25.00

Sizing Method: Cg

Km

0.9000

63

Cv

903e+004 USGPM

Cg

1.476e+006

Nozzle Parameters

64
65

40.75

Delta P

58

62

ERV-100

0.0000 ft *

Base Elevation Relative to Ground Level

66

67

Diameter

(ft)

0.1640

0.1640

68

Elevation (Base)

(ft)

0.0000

0.0000

69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 69 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Valve: VLV-100 (continued)

7
8
9

Elevation (Ground)

10

Elevation (% of Height)

(ft)

0.0000

0.0000

(%)

11

CONDITIONS

12
13

Name

14

Vapour

15

Temperature

16

Pressure

17

Molar Flow

18

Mass Flow

19

Std Ideal Liq Vol Flow

20

Molar Enthalpy

21

Molar Entropy

22

Heat Flow

1.0000

1.0000

248.0000 *

(F)

247.9137
145.0377 *

(psia)

152.2896

(lbmole/hr)

1217.8072

1217.8072
49630.7168

(lb/hr)

49630.7168

(barrel/day)

4915.2307

4915.2307

(Btu/lbmole)

-8.105e+004

-8.105e+004

(Btu/lbmole-F)

44.88

44.98

(Btu/hr)

-9.8701e+07

-9.8701e+07

23

PROPERTIES

24
25

Name

26

Molecular Weight

27

Molar Density

28

Mass Density

29

Act. Volume Flow

30

Mass Enthalpy

31

Mass Entropy

32

Heat Capacity

(Btu/lbmole-F)

17.07

17.06

33

Mass Heat Capacity

(Btu/lb-F)

0.4190

0.4186

34

Lower Heating Value

(Btu/lbmole)

4.623e+005

4.623e+005

35

Mass Lower Heating Value

(Btu/lb)

1.134e+004

1.134e+004

36

Phase Fraction [Vol. Basis]

37

Phase Fraction [Mass Basis]

38

Partial Pressure of CO2

39

5
(lbmole/ft3)

6
40.75

40.75

2.005e-002

1.910e-002

(lb/ft3)

0.8173

0.7784

(barrel/day)

2.596e+005

2.725e+005

(Btu/lb)

-1989

-1989

(Btu/lb-F)

1.101

1.104

4.941e-324

4.941e-324

(psia)

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

40

Act. Gas Flow

(ACFM)

1012

1063

41

Avg. Liq. Density

(lbmole/ft3)

1.059

1.059

42

Specific Heat

(Btu/lbmole-F)

17.07

17.06

43

Std. Gas Flow

(MMSCFD)

11.07

11.07

44

Std. Ideal Liq. Mass Density

(lb/ft3)

43.16

43.16

45

Act. Liq. Flow

(USGPM)

0.0000

46

Z Factor

47

Watson K

48

User Property

49

Partial Pressure of H2S

50

Cp/(Cp - R)

51

Cp/Cv

1.132

1.132

52

Heat of Vap.

(Btu/lbmole)

1.161e+004

1.166e+004

53

Kinematic Viscosity

54

Liq. Mass Density (Std. Cond)

55

Liq. Vol. Flow (Std. Cond)

56

Liquid Fraction

57

Molar Volume

58

Mass Heat of Vap.

59

Phase Fraction [Molar Basis]

60

Surface Tension

61

Thermal Conductivity

62

Viscosity

63

Cv (Semi-Ideal)

64

Mass Cv (Semi-Ideal)

65

Cv

66

Mass Cv

67

Cv (Ent. Method)

68

Mass Cv (Ent. Method)

69

Hyprotech Ltd.
Licensed to: LEGENDS

1.000

(psia)

11.37

11.37

0.0000

0.0000

1.132

1.132

(cSt)

0.8871

0.9297

(lb/ft3)

40.98

40.98

(barrel/day)

5177

5177

0.0000

0.0000

(ft3/lbmole)

49.87

52.35

(Btu/lb)

284.9

286.2

1.0000

1.0000

(Btu/hr-ft-F)

1.477e-002

1.474e-002

(cP)

1.161e-002

1.159e-002

(Btu/lbmole-F)

15.09

15.07

(Btu/lb-F)

0.3702

0.3698

(dyne/cm)

(Btu/lbmole-F)

15.09

15.07

(Btu/lb-F)

0.3702

0.3698

(Btu/lbmole-F)
(Btu/lb-F)

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 70 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Valve: VLV-100 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Cp/Cv (Ent. Method)

13

Reid VP at 37.8 C

(psia)

113.1

113.1

14

True VP at 37.8 C

(psia)

94.98

94.98

15

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

5177

5177

16

Viscosity Index

17

DYNAMICS

18
19

Dynamic Specifications

20
21

Total Delta P

22

Pressure Flow Relation

(psi)

7.252

Not Active
Active

23

Dynamic Parameters

24
25

Valve Opening

26

Conductance

50.00 *

(%)
(USGPM)

5.903e+004

27

Mass Flow

(lb/hr)

4.963e+004

(psi)

7.252

Friction Delta P

Pipe Model Parameters

28
29

Material

30

Roughness

(ft)

31

Pipe Length

(ft)

0.0000 *

Velocity

32

Feed Diameter

(ft)

0.1640

Reynolds Number

Cast Iron

Darcy Friction Factor

8.497e-004

33

Pipe k

0.0000 *

(lb/hr/sqrt(psia-lb/ft3))

798.2 *

(ft/s)

1.371e+007 *

Hold-Up Volume: 0.0000 ft3

34
35

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

37

Vapour

0.0000

0.0000

0.0000

38

Liquid

0.0000

0.0000

0.0000

39

Aqueous

0.0000

0.0000

40

Total

0.0000

0.0000

36

41

43

Parameters Mode: Instantaneous

44
45

Actuator Time Constant

(seconds)

46

Valve Stickiness Time Constant

(seconds)

1.000 *

47

1.000e-002 *

Actuator Linear Rate

Activator Position

48
49

Fail Position: None

50

Min
(%)

51
52

54

0.0000

0.0000

Actuator Parameters

42

53

Volume
(ft3)

Valve
Actuator

Max
(%)

Current
(%)

Desired
(%)

0.00

100.00

50.00

0.00

100.00

50.00

Offset
(%)
*

0.00
50.00

55
56

Valve: VLV-101

57
58
59

CONNECTIONS

60
61

Inlet Stream

62

STREAM NAME

63
64

65

STREAM NAME

67

69

T-100

Outlet Stream

66

68

FROM UNIT OPERATION

Distillation

10
Hyprotech Ltd.
Licensed to: LEGENDS

TO UNIT OPERATION
Distillation

Aspen HYSYS Version 7.1 (23.0.0.7119)

T-101

Page 71 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Valve: VLV-101 (continued)

7
8
9

PARAMETERS

10
11

Physical Properties

12
13

Pressure Drop:

157.5 psi

14

User Variables

15
16

RATING

17
18

Sizing

19
20

Sizing Conditions

21

Inlet Pressure

22

Valve Opening

159.0 psia

Molecular Weight

50.00 % *

23

157.5 psi

Manufacturer:

Universal Gas Sizing

25

5601 lb/hr

Type:

---

Valve Operating Characteristic and Sizing Method

26

Linear
C1

25.00

Sizing Method:

Km

0.9000

28

Cv

Cv (standard) cal/min.sqrt(psi)
Cg

Nozzle Parameters

29
30

Current
Flow Rate

Valve Manufacturer and Valve Type

24

27

21.40

Delta P

0.0000 ft *

Base Elevation Relative to Ground Level

31

10

32

Diameter

(ft)

0.1640

0.1640

33

Elevation (Base)

(ft)

0.0000

0.0000

34

Elevation (Ground)

(ft)

0.0000

0.0000

35

Elevation (% of Height)

(%)

36

CONDITIONS

37
38

Name

39

Vapour

40

Temperature

41

Pressure

42

Molar Flow

43

Mass Flow

44

Std Ideal Liq Vol Flow

45

Molar Enthalpy

46

Molar Entropy

47

Heat Flow

10

0.0000

0.2755
93.0852

(F)

320.5048

(psia)

159.0000

(lbmole/hr)

261.7770

261.7770
5600.7367

1.4504 *

(lb/hr)

5600.7367

(barrel/day)

417.9672

417.9672

(Btu/lbmole)

-1.133e+005

-1.133e+005

(Btu/lbmole-F)

15.54

14.39

(Btu/hr)

-2.9664e+07

-2.9664e+07

48

PROPERTIES

49
50

Name

51

Molecular Weight

52

Molar Density

53

Mass Density

54

Act. Volume Flow

55

Mass Enthalpy

(Btu/lb)

-5296

-5296

56

Mass Entropy

(Btu/lb-F)

0.7262

0.6724

57

Heat Capacity

(Btu/lbmole-F)

22.69

16.65

58

Mass Heat Capacity

(Btu/lb-F)

1.061

0.7780

59

Lower Heating Value

(Btu/lbmole)

6.577e+004

6.577e+004

60

Mass Lower Heating Value

(Btu/lb)

3074

61

Phase Fraction [Vol. Basis]

62

Phase Fraction [Mass Basis]

63

Partial Pressure of CO2

64

10
21.40

21.40

(lbmole/ft3)

2.332

8.875e-004

(lb/ft3)

49.89

1.899e-002

(barrel/day)

479.9

1.261e+006

3074
0.3595

0.0000

0.3343

(psia)

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

65

Act. Gas Flow

(ACFM)

66

Avg. Liq. Density

67

Specific Heat

68

Std. Gas Flow

69

Hyprotech Ltd.
Licensed to: LEGENDS

(lbmole/ft3)

2.677

2.677

(Btu/lbmole-F)

22.69

16.65

(MMSCFD)

2.380

2.380

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 72 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Valve: VLV-101 (continued)

7
8
9

PROPERTIES

10
11

Name

12

Std. Ideal Liq. Mass Density

13

Act. Liq. Flow

14

Z Factor

15

Watson K

16

User Property

17

Partial Pressure of H2S

18

Cp/(Cp - R)

19

Cp/Cv

1.213

1.034

20

Heat of Vap.

(Btu/lbmole)

1.539e+004

1.854e+004

21

Kinematic Viscosity

22

Liq. Mass Density (Std. Cond)

23

Liq. Vol. Flow (Std. Cond)

24

Liquid Fraction

25

Molar Volume

26

Mass Heat of Vap.

27

Phase Fraction [Molar Basis]

28

Surface Tension

29

Thermal Conductivity

30

Viscosity

31

Cv (Semi-Ideal)

32

Mass Cv (Semi-Ideal)

33

Cv

34

Mass Cv

35

Cv (Ent. Method)

36

Mass Cv (Ent. Method)

37

Cp/Cv (Ent. Method)

38

Reid VP at 37.8 C

39

True VP at 37.8 C

10

(lb/ft3)

57.28

57.28

(USGPM)

14.00

7.783

8.144e-003

(psia)

10.64

10.64

0.0000

0.0000

1.096

1.135

(cSt)

0.1682

(lb/ft3)

58.35

(barrel/day)

410.3

410.3

1.000

0.7245

58.35

(ft3/lbmole)

0.4288

1127

(Btu/lb)

719.1

866.8

0.0000

0.2755

(dyne/cm)

38.26

65.90

(Btu/hr-ft-F)

0.2899

(cP)

0.1344

(Btu/lbmole-F)

20.70

14.66

(Btu/lb-F)

0.9677

0.6852

(Btu/lbmole-F)

18.70

16.10

(Btu/lb-F)

0.8741

0.7524

(psia)

4.481

4.481

(psia)

2.329

2.329

40

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

410.3

411.0

41

Viscosity Index

(Btu/lbmole-F)
(Btu/lb-F)

42

DYNAMICS

43
44

Dynamic Specifications

45
46

Total Delta P

47

Pressure Flow Relation

(psi)

157.5

Active

48

Dynamic Parameters

49
50

Valve Opening

51

Conductance

50.00 *

(%)
(USGPM)

Mass Flow
Friction Delta P

52

(lb/hr)

5601

(psi)

157.5

Pipe Model Parameters

53
54

Material

55

Roughness

(ft)

56

Pipe Length

(ft)

0.0000 *

Velocity

57

Feed Diameter

(ft)

0.1640

Reynolds Number

Cast Iron

58

8.497e-004

Darcy Friction Factor

Pipe k

0.0000 *

(lb/hr/sqrt(psia-lb/ft3))

1.475 *

(ft/s)

1.337e+005 *

Hold-Up Volume: 0.0000 ft3

59
60

Not Active

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

62

Vapour

0.0000

0.0000

0.0000

63

Liquid

0.0000

0.0000

0.0000

64

Aqueous

0.0000

0.0000

65

Total

0.0000

0.0000

61

66

0.0000

0.0000

Actuator Parameters

67
68
69

Volume
(ft3)

Hyprotech Ltd.
Licensed to: LEGENDS

Parameters Mode: Instantaneous

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 73 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Valve: VLV-101 (continued)

7
8

Parameters Mode: Instantaneous

9
10

Actuator Time Constant

(seconds)

11

Valve Stickiness Time Constant

(seconds)

1.000 *

12

Activator Position

13
14

Fail Position: None

15

Min
(%)

16
17
18
19

1.000e-002 *

Actuator Linear Rate

Valve
Actuator

Max
(%)

Current
(%)

Desired
(%)

0.00

100.00

50.00

0.00

100.00

50.00

Offset
(%)
*

0.00
50.00

20
21

Valve: VLV-102

22
23
24

CONNECTIONS

25
26

Inlet Stream

27

STREAM NAME

28
29

FROM UNIT OPERATION

Distillation

30

Outlet Stream

31

STREAM NAME

32
33

TO UNIT OPERATION

DME

34

PARAMETERS

35
36

Physical Properties

37
38

7.252 psi *

Pressure Drop:

39

User Variables

40
41

RATING

42
43

Sizing

44
45

Sizing Conditions

46

Inlet Pressure

47

Valve Opening

139.0 psia
50.00 % *

Molecular Weight

Current
Flow Rate

Manufacturer:

Universal Gas Sizing

50

Type:

---

Valve Operating Characteristic and Sizing Method

51

Linear
C1

25.00

Sizing Method:

Km

0.9000

53

Cv

84.16 USGPM

Cv (standard) cal/min.sqrt(psi)
Cg

2104

Nozzle Parameters

54

0.0000 ft *

Base Elevation Relative to Ground Level

56

DME

57

Diameter

(ft)

0.1640

0.1640

58

Elevation (Base)

(ft)

0.0000

0.0000

59

Elevation (Ground)

(ft)

0.0000

0.0000

60

Elevation (% of Height)

(%)

61

CONDITIONS

62
63

Name

64

Vapour

65

Temperature

66

Pressure

67
68
69

4.403e+004 lb/hr

Valve Manufacturer and Valve Type

49

55

46.06
7.252 psi *

Delta P

48

52

T-100

DME

0.0000

0.0133

(F)

110.0070

106.2195

(psia)

139.0000

131.7481

Molar Flow

(lbmole/hr)

956.0302

956.0302

Mass Flow

(lb/hr)

44029.9802

44029.9802

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 74 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Valve: VLV-102 (continued)

7
8
9

CONDITIONS

10
11

Std Ideal Liq Vol Flow

12

Molar Enthalpy

13

Molar Entropy

14

Heat Flow

(barrel/day)

4497.2635

4497.2635

(Btu/lbmole)

-8.662e+004

-8.662e+004

(Btu/lbmole-F)

37.85

37.54

(Btu/hr)

-8.2809e+07

-8.2809e+07

15

PROPERTIES

16
17

Name

18

Molecular Weight

19

Molar Density

20

Mass Density

21

Act. Volume Flow

22

Mass Enthalpy

23
24
25

Mass Heat Capacity

26

Lower Heating Value

27

Mass Lower Heating Value

28

Phase Fraction [Vol. Basis]

29

Phase Fraction [Mass Basis]

30

Partial Pressure of CO2

31

DME
46.06

46.06

(lbmole/ft3)

0.7799

0.5341
24.60

(lb/ft3)

35.92

(barrel/day)

5240

7651

(Btu/lb)

-1881

-1881

Mass Entropy

(Btu/lb-F)

0.8219

0.8151

Heat Capacity

(Btu/lbmole-F)

28.21

27.86

(Btu/lb-F)

0.6126

0.6050

(Btu/lbmole)

5.708e+005

5.708e+005

(Btu/lb)

1.239e+004

1.239e+004
1.334e-002

2.122e-314

1.334e-002

(psia)

0.0000

0.0000

Cost Based on Flow

(Cost/s)

0.0000

0.0000

32

Act. Gas Flow

(ACFM)

33

Avg. Liq. Density

34

Specific Heat

35

Std. Gas Flow

36

Std. Ideal Liq. Mass Density

37

Act. Liq. Flow

38

Z Factor

39

Watson K

40

User Property

41

Partial Pressure of H2S

42

Cp/(Cp - R)

43

Cp/Cv

44

Heat of Vap.

45

Kinematic Viscosity

46

Liq. Mass Density (Std. Cond)

47

Liq. Vol. Flow (Std. Cond)

48

Liquid Fraction

49

Molar Volume

50

Mass Heat of Vap.

51

Phase Fraction [Molar Basis]

52

Surface Tension

53

Thermal Conductivity

54

Viscosity

55

Cv (Semi-Ideal)

56

Mass Cv (Semi-Ideal)

57

Cv

58

Mass Cv

59

Cv (Ent. Method)

60

Mass Cv (Ent. Method)

61

Cp/Cv (Ent. Method)

62

Reid VP at 37.8 C

63

True VP at 37.8 C

(lbmole/ft3)

0.9087

0.9087

(Btu/lbmole-F)

28.21

27.86

(MMSCFD)

8.690

8.690

(lb/ft3)

41.85

41.85

(USGPM)

152.8

149.9

2.915e-002
11.38

11.38

0.0000

0.0000

1.076

1.077

1.076

1.007

(Btu/lbmole)

7981

8026

(cSt)

0.1312

(lb/ft3)

38.58

(barrel/day)

4878

4878

1.000

0.9867

(ft3/lbmole)

1.282

1.872

(Btu/lb)

173.3

174.3

0.0000

0.0133
9.542

(psia)

(dyne/cm)

9.257

(Btu/hr-ft-F)

7.011e-002

(cP)

7.548e-002

38.58

(Btu/lbmole-F)

26.23

25.88

(Btu/lb-F)

0.5695

0.5619

(Btu/lbmole-F)

26.23

27.66

(Btu/lb-F)

0.5695

0.6006

(psia)

120.4

120.4

(psia)

120.7

120.7

64

(barrel/day)
Liq. Vol. Flow - Sum(Std. Cond)

4878

4878

65

Viscosity Index

66

(Btu/lb-F)

DYNAMICS

67
68
69

(Btu/lbmole-F)

Hyprotech Ltd.
Licensed to: LEGENDS

Dynamic Specifications
Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 75 of 76
* Specified by user.

1
2

LEGENDS
Burlington, MA
USA

3
4
5

Case Name:

DFP FINAL.HSC

Unit Set:

Field

Date/Time:

Wed Mar 21 00:56:33 2012

Valve: VLV-102 (continued)

7
8

Dynamic Specifications

9
10

Total Delta P

11

Pressure Flow Relation

7.252 *

(psi)

Not Active
Active

12

Dynamic Parameters

13
14

Valve Opening

15

Conductance

(%)
(USGPM)

16

50.00 *

Mass Flow

84.16

Friction Delta P

(lb/hr)

4.403e+004

(psi)

7.252

Pipe Model Parameters

17
18

Material

19

Roughness

(ft)

20

Pipe Length

(ft)

0.0000 *

Velocity

21

Feed Diameter

(ft)

0.1640

Reynolds Number

Cast Iron

Darcy Friction Factor

8.497e-004

22

Pipe k

0.0000 *

(lb/hr/sqrt(psia-lb/ft3))

16.11 *

(ft/s)

1.872e+006 *

Hold-Up Volume: 0.0000 ft3

23
24

Phase

Accumulation
(lbmole/hr)

Moles
(lbmole)

26

Vapour

0.0000

0.0000

0.0000

27

Liquid

0.0000

0.0000

0.0000

28

Aqueous

0.0000

0.0000

29

Total

0.0000

0.0000

25

30

32

Parameters Mode: Instantaneous

33
34

Actuator Time Constant

(seconds)

35

Valve Stickiness Time Constant

(seconds)

1.000 *

36

1.000e-002 *

Actuator Linear Rate

Activator Position

37
38

Fail Position: None

39

Min
(%)

40
41

43

0.0000

0.0000

Actuator Parameters

31

42

Volume
(ft3)

Valve
Actuator

Max
(%)

Current
(%)

Desired
(%)

0.00

100.00

50.00

0.00

100.00

50.00

Offset
(%)
*

0.00
50.00

44
45

Equilibrium: Rxn-2

46
47
48

STOICHIOMETRY

49
50

Component

Molecular Weight

Stoichiometric Coefficient

51

Methanol

32.04

-2 *

52

diM-Ether

46.07

1*

53

H2O

18.02

1*

54
55

Balance Error :

0.0000

Reaction Heat (25 C) :

56

BASIS

57
58
59

-5035 Btu/lbmole

Basis

60

Activity

61

Approach
(F)

Phase
VapourPhase

Min. Temp
(F)

Max. Temp
(F)
-459.7

5432

PARAMETERS

62
63

Source : Gibbs Free Energy

64
65
66
67
68
69

Hyprotech Ltd.
Licensed to: LEGENDS

Aspen HYSYS Version 7.1 (23.0.0.7119)

Page 76 of 76
* Specified by user.